Material Safety Data Sheet SECTION 1: PRODUCT AND COMPANY
Contents
1. MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 Material Safety Data Sheet Copyright 2013 3M Company All rights reserved Copying and or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that 1 the information is copied in full with no changes unless prior written agreement is obtained from 3M and 2 neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red MANUFACTURER 3M DIVISION Industrial Adhesives and Tapes Division ADDRESS 3M Center St Paul MN 55144 1000 Issue Date 05 14 13 Supercedes Date 11 27 12 Document Group 23 2991 0 Product Use Limitations on Use Sale and use severely restricted due to high VOC in CT DE ME MD NH NJ NY PA RI VA DC IL IN OH in CA per R 1168 Specific Use general purpose solvent based adhesive Intended Use Industrial use SECTION 2 INGREDIENTS Ingredient C A S No by Wt Hydrotreated Light Naphtha 64742 49 0 15 40 N J T S Reg No 04499600 5776P Trade Secret 20 30 Dimethyl Ether 115 10 6 10 30 Cyclohexane 110 82 7 10 30 Propane 74 98 6 3 7 Isobutane 75 28 5 3 7 Hexane 110 54 3 1 2 SECTION 3 HAZARDS IDENTIFICATION 3 1 EMERGENCY OVERVIEW Odor Color G2. remain in area where available oxygen may be reduced Use general dilution ventilation and or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and or control mist vapor or spray If ventilation is not adequate use respiratory protection equipment 8 2 PERSONAL PROTECTIVE EQUIPMENT PPE 8 2 1 Eye Face Protection Avoid eye contact with vapors mists or spray The following eye protection s are recommended Safety Glasses with side shields Indirect Vented Goggles 8 2 2 Skin Protection Avoid skin contact Select and use gloves and or protective clothing to prevent skin contact based on the results of an exposure assessment Consult with your glove and or protective clothing manufacturer for selection of appropriate compatible materials Gloves made from the following material s are recommended Nitrile Rubber Polyvinyl Alcohol PVA 8 2 3 Respiratory Protection Avoid breathing of vapors mists or spray An exposure assessment may be needed to decide if a respirator is required If a respirator is needed use respirators as part of a full respiratory protection program Based on the results of the exposure assessment select from the following respirator type s to reduce inhalation exposure Half facepiece or full facepiece air purifying respirator suitable for organic vapors For questions about suitability for a specific application consult with your respirator manufacturer Organic vapo
3. Cylinder Spray Adhesive clear or red 05 14 13 SECTION 5 FIRE FIGHTING MEASURES 5 1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 50 F Test Method Closed Cup Details Flammable Gas Flammable Limits LEL 1 2 volume Flammable Limits UEL 27 volume 5 2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents e g dry chemical carbon dioxide 5 3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures Water may not effectively extinguish fire however it should be used to keep fire exposed containers and surfaces cool and prevent explosive rupture Water may be used to blanket the fire Wear full protective equipment Bunker Gear and a self contained breathing apparatus SCBA Unusual Fire and Explosion Hazards Flammable liquefied gas Extremely flammable liquid and vapor Vapors may travel long distances along the ground or floor to an ignition source and flash back Note See STABILITY AND REACTIVITY SECTION 10 for hazardous combustion and thermal decomposition information SECTION 6 ACCIDENTAL RELEASE MEASURES 6 1 Personal precautions protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area The spill should be cleaned up by qualified personnel Remove all ignition sources such as flames smoking materials and electrical spark sources Use only non sparking tools Ventilate the area with fres
4. ICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and or its components SECTION 12 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined CHEMICAL FATE INFORMATION Not determined SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal Method Incinerate in a permitted hazardous waste incinerator As a disposal alternative dispose of waste product in a permitted hazardous waste facility The facility should be equipped to handle gaseous waste EPA Hazardous Waste Number RCRA D001 Ignitable Since regulations vary consult applicable regulations or authorities before disposal SECTION 14 TRANSPORT INFORMATION ID Number s 62 4979 8030 0 62 4979 8032 6 62 4979 8830 3 Page 6 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 For Transport Information please visit http 3M com Transportinfo or call 1 800 364 3577 or 651 737 6501 SECTION 15 REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information 311 312 Hazard Categories Fire Hazard Yes Pressure Hazard Yes Reactivity Hazard No Immediate Hazard Yes Delayed Hazard Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 EPCRA Ingredient C A S No by Wt Cyclohexane 110 82 7 10 30 STATE REGULATIONS Contact 3M for
5. Solubility in Water Evaporation rate Hazardous Air Pollutants Volatile Organic Compounds Kow Oct Water partition coef VOC Less H20 amp Exempt Solvents VOC Less H20 amp Exempt Solvents VOC Less H20 amp Exempt Solvents Viscosity Solids Content liquid solvent odor red or clear Gas No Data Available 50 F Test Method Closed Cup Details Flammable Gas 1 2 volume 27 volume lt 68 F 0 735 g ml gt 1 0 Ref Std AIR 1 84 7 psia 68 F 0 735 Ref Std WATER 1 Not Applicable Not Applicable Nil No Data Available 0 93 weight Test Method Calculated 535 g l Details EU VOC content No Data Available 535 g l Test Method calculated SCAQMD rule 443 1 4 47 lb gal Test Method calculated SCAQMD rule 443 1 72 7 Test Method calculated per CARB title 2 Not Applicable 20 30 SECTION 10 STABILITY AND REACTIVITY Page 5 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 Stability Stable Materials and Conditions to Avoid 10 1 Conditions to avoid Heat Sparks and or flames 10 2 Materials to avoid Strong oxidizing agents Hazardous Polymerization Hazardous polymerization will not occur Hazardous Decomposition or By Products Substance Condition Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion SECTION 11 TOXICOLOG
6. d Page 7 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 DISCLAIMER The information in this Material Safety Data Sheet MSDS is believed to be correct as of the date issued 3M MAKES NO WARRANTIES EXPRESSED OR IMPLIED INCLUDING BUT NOT LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user s method of use or application Given the variety of factors that can affect the use and application of a 3M product some of which are uniquely within the user s knowledge and control it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user s method of use or application 3M provides information in electronic form as a service to its customers Due to the remote possibility that electronic transfer may have resulted in errors omissions or alterations in this information 3M makes no representations as to its completeness or accuracy In addition information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www 3M com Page 8 of 8
7. entral Nervous System CNS Depression Signs symptoms may include headache dizziness drowsiness incoordination nausea slowed reaction time slurred speech giddiness and unconsciousness Prolonged or repeated exposure may cause Peripheral Neuropathy Signs symptoms may include tingling or numbness of the extremities incoordination weakness of the hands and feet tremors and muscle atrophy Contains a chemical or chemicals which can cause birth defects or other reproductive harm SECTION 4 FIRST AID MEASURES 4 1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed Eye Contact Flush eyes with large amounts of water If signs symptoms persist get medical attention Skin Contact Remove contaminated clothing and shoes Immediately flush skin with large amounts of water Get medical attention Wash contaminated clothing and clean shoes before reuse Inhalation Remove person to fresh air Get immediate medical attention If Swallowed Do not induce vomiting unless instructed to do so by medical personnel Give victim two glasses of water Never give anything by mouth to an unconscious person Get medical attention 4 2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability Do not administer sympathomimetic drugs unless absolutely necessary Page 2 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77
8. h air For large spill or spills in confined spaces provide mechanical ventilation to disperse or exhaust vapors in accordance with good industrial hygiene practice Warning A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode Close cylinder If the cylinder can t be closed place in a well ventilated area preferably an operating exhaust hood or if necessary outdoors 6 2 Environmental precautions Collect the resulting residue containing solution Place in a metal container approved for transportation by appropriate authorities Dispose of collected material as soon as possible Clean up methods Refer to other sections of this MSDS for information regarding physical and health hazards respiratory protection ventilation and personal protective equipment Call 3M HELPS line 1 800 364 3577 for more information on handling and managing the spill Clean up residue with an appropriate solvent selected by a qualified and authorized person Ventilate the area with fresh air Read and follow safety precautions on the solvent label and MSDS In the event of a release of this material the user should determine if the release qualifies as reportable according to local state and federal regulations SECTION 7 HANDLING AND STORAGE Page 3 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 7 1 HANDLING Do not eat dr
9. ink or smoke when using this product Wash exposed areas thoroughly with soap and water Contents may be under pressure open carefully Keep away from heat sparks open flame pilot lights and other sources of ignition Ground containers securely when transferring contents Wear low static or properly grounded shoes Avoid breathing of vapors mists or spray Avoid skin contact Avoid static discharge Avoid eye contact with vapors mists or spray Vapors may ignite explosively May cause flash fire Prevent build up of vapors open all windows and doors Maintain vapor concentrations below recommended exposure limits Use only with cross ventilation Without adequate ventilation vapors may settle in low lying areas Keep away from heat sparks and open flame Do not smoke or ignite matches lighters etc For industrial or professional use only Avoid contact with oxidizing agents Use general dilution ventilation and or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits If ventilation is not adequate use respiratory protection equipment 7 2 STORAGE Store away from heat Store out of direct sunlight Keep container in well ventilated area Keep container tightly closed Store away from oxidizing agents SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION 8 1 ENGINEERING CONTROLS Use with functioning spray booth or local exhaust Do not use in a confined area or areas with little or no air movement Do not
10. more information CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances EINECS or are exempt polymers whose monomers are listed on EINECS Contact 3M for more information INTERNATIONAL REGULATIONS Non hazardous according to WHMIS criteria Contact 3M for more information WHMIS Non hazardous This MSDS has been prepared to meet the U S OSHA Hazard Communication Standard 29 CFR 1910 1200 SECTION 16 OTHER INFORMATION NFPA Hazard Classification Health 2 Flammability 4 Reactivity 0 Special Hazards None National Fire Protection Association NFPA hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short term acute exposure to a material under conditions of fire spill or similar emergencies Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities Revision Changes Section 1 Product use information was modified Section 14 ID Number s Template 1 was modified Section 15 EPCRA 313 information was modified Section 8 Exposure guidelines ingredient information was modified Copyright was modifie
11. r cartridges may have short service life 8 2 4 Prevention of Swallowing Do not eat drink or smoke when using this product Wash exposed areas thoroughly with soap and water Page 4 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 8 3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Cyclohexane ACGIH TWA 100 ppm Cyclohexane OSHA TWA 1050 mg m3 Dimethyl Ether AIHA TWA 1880 mg m3 Dimethyl Ether CMRG TWA 1000 ppm Hexane ACGIH TWA 50 ppm Skin Notation Hexane OSHA TWA 1800 mg m3 Hydrotreated Light Naphtha CMRG TWA 50 ppm Propane OSHA TWA 1800 mg m3 Substance s refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye either by airborne or more particularly by direct contact with the substance Vehicles can alter skin absorption SOURCE OF EXPOSURE LIMIT DATA ACGIH American Conference of Governmental Industrial Hygienists CMRG Chemical Manufacturer Recommended Guideline OSHA Occupational Safety and Health Administration AIHA American Industrial Hygiene Association Workplace Environmental Exposure Level WEEL SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Odor Color Grade General Physical Form Autoignition temperature Flash Point Flammable Limits LEL Flammable Limits UEL Boiling Point Density Vapor Density Vapor Pressure Specific Gravity pH Melting point
12. rade liquid solvent odor red or clear General Physical Form Gas Immediate health physical and environmental hazards Flammable liquefied gas Extremely flammable liquid and vapor Page 1 of 8 MATERIAL SAFETY DATA SHEET 3M Scotch Weld Super 77 Cylinder Spray Adhesive clear or red 05 14 13 Vapors may travel long distances along the ground or floor to an ignition source and flash back May cause target organ effects Contains a chemical or chemicals which can cause birth defects or other reproductive harm 3 2 POTENTIAL HEALTH EFFECTS Eye Contact Mild Eye Irritation Signs symptoms may include redness pain and tearing Skin Contact Moderate Skin Irritation Signs symptoms may include localized redness swelling itching and dryness Inhalation Respiratory Tract Irritation Signs symptoms may include cough sneezing nasal discharge headache hoarseness and nose and throat pain Single exposure above recommended guidelines may cause Cardiac Sensitization Signs symptoms may include irregular heartbeat arrhythmia faintness chest pain and may be fatal Intentional concentration and inhalation may be harmful or fatal May be absorbed following inhalation and cause target organ effects Ingestion Gastrointestinal Irritation Signs symptoms may include abdominal pain stomach upset nausea vomiting and diarrhea May be absorbed following ingestion and cause target organ effects Target Organ Effects C
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