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Feather Flickers COSHH Manual

1. This leaflet contains notes on good practice which are not compulsory but which you may find helpful in considering what you need to do This leaflet is available in priced packs of 15 from HSE Books ISBN 978 O 7176 6188 1 Single copies are free and a web version can be found at www hse gov uk pubns indg233 pdf Crown copyright This publication may be freely reproduced except for advertising endorsement or commercial purposes First published 03 07 Please acknowledge the source as HSE Published by the Health and Safety Executive INDG233 rev1 3 of 3 pages Health and Safety Executive SR COSHH essentials for service and retail m _ This information will help or gO y self employed and te franchisees comply with the Control of Substances Hazardous to Health Regulations 2002 COSHH as amended to control exposure and protect workers health ES sA employers including the B It is also useful for trade union safety representatives This sheet describes good practice using personal protective equipment PPE It covers the points you need to follow to reduce exposure to an adequate level It is important to follow all the points or use equally effective measures Some concentrates are biocidal products Authorised products are safe for use so long as you follow the instructions on the label Some chemicals can be flammable so your controls must suit thos
2. Health and Safety Data Sheet Identification of the Substance Preparation and Company Product name SELBRITE Supplier SELDEN RESEARCH LTD ASHBOURNE ROAD BUXTON DERBYSHIRE ENGLAND SK17 9ZR 01298 26226 01298 26540 Product Description Drybright metallised emulsion floor polish water based COMPOSITION INFORMATION AND INGREDIENTS An aqueous blend of acrylic copolymers resins and copolymer wax containing levelling agents and plasticisers and preservative Hazardous Ingredients CAS No w w Range Nature of Hazard Ammonia 7664 41 7 0 15 max CORROSIVE R34 R37 Causes Burns Irritating to respiratory system Occupational Exposure Standard O E S set Refer to Section 8 for Exposure Levels HAZARD IDENTIFICATION Product is not classed as hazardous under Chemicals Hazard Information and Packaging Regulations 1994 however commonsense precautions must be observed FIRST AID MEASURES Eyes Rinse well with large quantities of clean water for 10 minutes If irritation persists seek medical attention Skin Wash well with soap and water Ingestion DO NOT INDUCE VOMITING Give small sips of milk or water to drink and seek medical attention FIRE FIGHTING MEASURES Product is not flammable however irritating fumes may be given off in the event of a fire Treat fires with either dry chemical foam or waterspray do not use waterjet ACCIDENTAL RELEASE MEASURES Spillages need to be contained to pre
3. DOMESTIC PROPERTY MAINTENANCE OFFICE COMMERCIAL INDUSTRIAL We Nest You Rest The All n One Cleaning Service The All 9n One Cleaning Sewice The Ml In One Maintenance Senice Warner House Riverview Tarleton Nr Preston Lancs PR4 6EB T 0845 880 2530 M 07775 530 824 M 07778 300 087 F 01772 816 811 E info featherflickers co uk W www featherflickers co uk Commercial amp Domestic Cleaning and Property Maintenance Services throughout the Southport Ormskirk Liverpool Preston Wigan amp West Lancashire areas COSHH MANUAL Feather Flickers successfully undertook a large contract for IMG the worlds premier and most diversified sports entertainment and media company during the Royal Birkdale Open Golf in 2008 Turnberry in 2009 and St Andrews in 2010 Directors Greg Gottig FIH FCM FFA MBiCSc Managing faBICSc Ruth Goitig Feather Flickers is part of Warner House Companies Lid and is registered in England amp Wales gs CMI Registered Office Warner House Riverview Tarleton Nr Preston Lancs PR4 6EB Banking Details Natwest 130 Lord Street Southport PR9 OGB Sort Code 60 20 11 Account No 35746149 or f Sefton Company Reg No 6638525 VAT Reg No 998 8229 43 in DI Chambe Health and Safety Executive Working with substances hazardous to health Lge What you need to know about COSHH Ox Working with substances hazardous to health ae This is a web fri
4. Employee checklist _ Look for signs of leaks wear and damage Lit you find any problems tell your supervisor Don t just carry on working _ Use and store your protective equipment according to instructions _ Throw away single use gloves every time you take them off _ Wash your hands after use _ Never clean your hands with concentrated cleaning products or solvents _ Check your skin regularly for dryness or soreness tell your supervisor if these symptoms appear _ Use skin creams provided as instructed 10 06 Health and Safety Executive A short guide to the Personal Protective Equipment at Work Regulations 1992 HSE A short guide to the Personal Protective Equipment at Work Regulations 1992 A iz fs J Ex 1 This ts a web friendly version of leaflet INDG174 rev1 revised 08 05 Employers have basic duties concerning the provision and use of personal protective equipment PPE at work and this document explains what you need to do to meet the requirements of the Personal Protective Equipment at Work Regulations 1992 as amended What is PPE PPE is defined in the Regulations as all equipment including clothing affording protection against the weather which is intended to be worn or held by a person at work and which protects him against one or more risks to his health or safety eg safety helmets gloves eye protection high v
5. ammabile ammabDple e environmen can be used safely Safety data sheets can be hard to understand with little information on measures for control However to find out about health risks and emergency situations concentrate on Oxidising Corrosive New International symbols m Part 15 of the sheet which tells you what the dangers are m Parts 4 to 8 which tell you about emergencies storage and handling International symbols will replace the European symbols in 2009 Some of them are similar to the European symbols but there is no single word describing the hazard Read the hazard statement on the packaging and the safety data sheet from the supplier Assessing risk Hazard checklist Risk assessment is not just a paper exercise It s about taking Does any product you use have a sensible steps to prevent ill health You need to know how workers danger label are exposed and to how much before you can decide if you need C Does your process produce gas to do anything to reduce their exposure The COSHH Regulations fume dust mist or vapour require employers to assess the risk to their employees and to prevent or adequately control those risks Sometimes It s easy to judge the amount of exposure to substances and decide what you can do about it _ Is the substance harmful to breathe in _ Can the substance harm your skin When the task involves very small amounts of material even if these Is
6. Class Item Number Proper Shipping Name UN1950 IMDG 2 Aerosols ICAO IATA 2 2 Aerosols ADR RID 2 5 A Aerosols Aerosol Furniture Polish 15 16 Page 6 of 6 REGULATORY INFORMATION This product is classified as dangerous for supply in the EU as follows F EXTREMELY FLAMMABLE R12 EXTREMELY FLAMMABLE Pressurised container protect from sunlight and do not expose to temperatures exceeding 50 C Do not pierce or burn even after use Do not spray on a naked flame or any incandescent material Keep away from sources of ignition No smoking S2 Keep out of reach of children The following directives are relevant to the above classification and labelling of this product Council Directive 88 379 EEC of 7 June 1988 on the approximation of the laws regulations and administrative provisions of the Member States relating to the classification packaging and labelling of dangerous preparations Council Directive 75 324EEC of 20 May 1975 on the approximation of the laws of the Member States relating to aerosol dispensers as adapted for some technicalities by Commission Directive 94 1 EC of 6 January 1994 Directive 88 379 EC is implemented in the UK by the Chemicals Hazard Information and Packaging for Supply Regulations 1994 as amended OTHER INFORMATION This document complements the technical usage instructions but does not replace them The information contained herein is based on our best current tech
7. STAIN REMOVER Product 683953 Professional cleaning maintenance product for building care Code TO 2 COMPOSITION INFORMATION ON INGREDIENTS CAS No EINECS No 112 25 4 203 998 3 Ethylene glycol hexyl ether Xn R21 22 36 38 lt 5 7722 84 1 231 765 0 Hydrogen peroxide OES C O R8 34 lt 5 Full text of R phrases is given in section 16 3 HAZARDS IDENTIFICATION This product contains a material with an OES MEL published in HSE document EH40 4 FIRST AID MEASURES Eyes Rinse immediately with plenty of water holding the eyelids open and seek medical advice if effects persist Inhalation Remove from source of exposure Seek medical advice if effects persist Skin Wash thoroughly with soap and water Ingestion Remove product from mouth give the casualty a small quantity of water to drink and seek medical advice Do not induce vomiting 5 FIRE FIGHTING MEASURES NON FLAMMABLE In the event of a fire due to other causes the product is compatible with water foam carbon dioxide and dry powder extinguishers May evolve toxic fumes if involved in a fire Firefighters should wear self contained breathing apparatus 6 ACCIDENTAL RELEASE MEASURES Hose away with plenty of water diluting to at least 5 w v 50 g litre unless this would contaminate a water course or vegetation in which case either collect dilute as earlier and pour down wastewater drain foul sewer or absorb onto dry sand or similar material and dispose of safely as comme
8. Wash skin with soap and water Seek medical attention if any skin irritation persists Inhalation Get fresh air and seek medical assistance if breathing irritation persists Ingestion If swallowed DO NOT induce vomiting unless directed to do so by medical personnel If injured party is conscious give two glasses of water Seek medical attention SECTION 5 FIRE FIGHTING MEASURES Extinguishing Media Product is not flammable Use water carbon dioxide dry powder extinguisher or other media appropriate for materials actually involved in fire Fire Explosion Hazards No explosion hazard Less than 1 Less than 1 Decomposition Products Exposure to fire may liberate carbon dioxide carbon monoxide water and other unidentified thermal decomposition products from this product or its packaging Special Protective Equipment None recommended SECTION 6 ACCIDENTAL RELEASE MEASURES Personal Protection Protective clothing nitrile butyl rubber gloves chemical splash goggles Containment and Disposal Large spills should be treated with dry absorbent and disposed at legal waste disposal site Small spills can be flushed with water to sewage drain linked to waste treatment facility SECTION 7 HANDLING AND STORAGE Handling Precautions Wear nitrile butyl rubber gloves and safety glasses when handling concentrate Storage Precautions Avoid extremes of temperature Keep out of reach of children Keep in original container S
9. and managing risks at work from skin exposure to chemical agents Guidance for employers and health and safety specialists HSG205 HSE Books 2001 ISBN O 7176 1826 9 Preventing dermatitis at work Advice for employers and employees Leaflet INDG233 HSE Books 1996 single copy free or priced packs of 15 ISBN O 7176 1246 5 m Posters on protective gloves and skin care see www hse gov uk skin information htm Service and retail SR4 Harm via skin or eye contact Useful links m HSE priced and free publications are available from HSE Books Tel 01787 881165 Website www hsebooks co uk m For information about health and safety ring HSE s Infoline Tel 0845 345 0055 Textphone 0845 408 9577 e mail hse infoline natbrit com Contact the British Occupational Hygiene Society BOHS on 01332 298101 or at www bohs org for lists of qualified hygienists who can help you m Look in the Yellow Pages under Health and safety consultants and Health authorities and services for occupational health m Also see www nhsplus nhs uk This guidance is issued by the Health and Safety Executive Following the guidance is not compulsory and you are free to take other action But if you do follow the guidance you will normally be doing enough to comply with the law Health and safety inspectors seek to secure compliance with the law and may refer to this guidance as illustrating good practice Published by the Health and Safety Executive
10. away single use gloves every time they are taken off Provide protective goggles to protect eyes when using products that can cause burns eg acids caustics Skin creams are important for skin protection and help in washing contamination from the skin These are not barrier creams After work creams help to replace skin oils Health monitoring Ask your workers to check their skin for dryness or soreness every six months If these effects appear check the proper use of skin creams and PPE JY If you use a product labelled may cause sensitisation by skin contact or may cause sensitisation by inhalation seek specialist advice See Useful links Cleaning and housekeeping Clean up spills promptly practise how to do this Training and supervision Y Tell workers about the risks of using the product see products labels or Section 15 of the safety data sheet If products can cause skin or eye damage plan how to give first aid Y Working in the right way and using the controls correctly is important for exposure control Train and supervise workers See sheet SRO Service and retail SR2 Harm via skin or eye contact Further information Employee checklist m Assessing and managing risks at work from skin exposure to chemical agents Guidance for employers and health and safety specialists HSG205 HSE Books 2001 ISBN O 7176 1826 9 m Hyarofluoric acid poisoning Recommendations on first aid procedures L
11. contact with skin Prolonged contact of neat product may cause skin to dry out resulting in cracking and soreness Ingested Abdominal pain sickness and diarrhoea ECOLOGICAL INFORMATION Whilst this product is not considered to be biodegradable it would not normally be expected to enter a water discharge system DISPOSAL CONSIDERATIONS Dispose of according to local regulations TRANSPORT INFORMATION Product is not classed as hazardous for transportation purposes REGULATORY INFORMATION Product is not classed as hazardous under CHIP Regulations OTHER INFORMATION The responsibility to ensure safe working conditions within the workplace remains with the user The health hazard and general information contained within this Material Safety Data Sheet are given as a guide to the precautions required to maintain a safe work environment A05 Revision 4 March 1995 Johnson wax SAFETY DATA SHEET PROFESSIONAL Conforms to 93 112 EC and ISO 11014 1 Pledge Furniture Polish Aerosol Natural 1 IDENTIFICATION OF THE SUBSTANCE PREPARATION AND OF THE COMPANY UNDERTAKING Product name Pledge Furniture Polish Aerosol Natural Pack code 406450 Size 400 ml Supplier Johnson Wax Professional B V Filiaal Belgi Filiale Belge Noordzone Noordkustlaan 16 B 1702 Groot Bijgaarden 02 467 52 52 Emergency telephone number Poison Control Center 070 245245 2 COMPOSITION INFORMATION ON INGREDIENTS Substance preparatio
12. equipment like protective gloves aprons and eye protection e Practice good hand care remove contamination promptly wash hands properly dry thoroughly and use skin creams regularly e Keep the workplace well ventilated The controls you need will depend on the task Click the links below for more specific information e SR24 Storing chemical products small scale 30 7KB J po e SR2 Diluting chemical concentrates 37 8KB 3 po SR4 Manual cleaning and disinfecting surfaces 129KB 33 gat e SR1 Cleaning amp disinfection with low pressure washers 41 2KB J eo Link URLs in this page 1 SR24 Storing chemical products small scale 30 7KB http www coshh essentials org uk assets live SR24 pdf 2 SR2 Diluting chemical concentrates 37 8KB http www coshh essentials org uk assets live SRO2 pdf 3 SR4 Manual cleaning and disinfecting surfaces 129KB http www coshh essentials org uk assets live SR04 pdf 4 SR1 Cleaning amp disinfection with low pressure washers 41 2KB http www coshh essentials org uk assets live SR01 pdf http www hse gov uk coshh industry cleaning htm 25 01 2010 Health and Safety Executive Preventing contact dermatitis at work This leaflet tells you about a skin problem that you can get at work contact Preventing contact dermatitis dermatitis at work If you are an employer safety representative trainer or safety advisor you can influence work practice and
13. health and safety regulations SECTION 16 OTHER INFORMATION Risk Phrases R22 Harmful if swallowed R36 Irritating to eyes R41 Risk of serious damage to eyes R50 Very toxic to aquatic organisms For additional information on safety training and use of this product contact the supplier This product is intended for professional use only The information given is intended to be of assistance to users but is without guarantee Variations can occur in application and users are advised to conduct their own tests Suggestions for use neither give nor imply any guarantee as to the intended use Revisions Replaces SDS B144 Issue Revision Date 01 09 99 Revised Sections 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 SDS B144 Issue Revision Date 01 08 03 Page 2 of 2
14. information is based on the best knowledge of Colgate Palmolive at the time of issue of this SDS and is given in good faith but the Company cannot guarantee its accuracy reliability or completeness and therefore disclaims any liability for loss or damage arising out of the use of this data since conditions of use and handling are out of control of Colgate Palmolive the Company disclaims any liability for loss or damage when the product is used for other purposes than it is intended the information contained in this SDS does not constitute any kind of commercial contract or committment Page 4 of 4 Proctere Gamble SAFETY DATA SHEET Commercial Products Group Europe Chemicals Hazard Information and Packaging for Su Regulations 1994 ICP33UK Issue 4 Date July 29 1999 AW Code 49 10C PROFESSIONAL FLASH ALL PURPOSE Lemon Pine amp Ocean Fresh 4 Procter amp Gamble UK CPG E Brooklands Weybridge Surrey KT13 OXP UK _ Tel 01932 89 6000 Fax 01932 89 6200 A liquid household cleaning product containing Percentage Risk phrase of ingredients Nonionic surfactants 5 15 i R36 38 2 Anionic surfactants lt 5 R22 R36 38 This product is not classified as hazardous Skin contact Upon prolonged contact with skin the product may cause slight skin irritation Wash affected area thoroughly with water In case any irritation persists seek medical advice Eye contact If the product gets i
15. is advisable to use a hand care product If used as a spray use only at the recommended dilution and oray only in direction of application Avoid breathing mist spray shysical and chemical Appearance Smell Lemon yellow fluorescent liquid properties Cascade blue liquid Pine green liquid pH 10 aqueous solution ca 9 5 Flash point 80 100 C Not Flammable Non Explosive Non Oxidizing Relative density ca 1 020 g cc Water solubility high Packaging Polyethylene bottle with PP cap sal d reactiv ity Stable under normal conditions Do not store below 0 C oaical information This product is not acutely toxic after ingestion it may cause emesis If large 4 quantities are ingested treat symptomatically If irritant effects are seen these will be mild to moderate depending on exposure If in contact with eyes flushing with water is recommended Estimated acute oral toxicity LD50 rats gt 5g kg 1 Skin irritation May cause slight skin irritation Eye irritation May cause transient superficial irritation Mutagenicity Not mutagenic Sensitisation No evidence of skin sensitization information The surfactants used in this product conform to the EEC biodegradability oe legislation Ingredients have a known ecotoxicity supporting their safe use 43 Disposal Considerations Observe local legislation Not a dangerous material no speci
16. leaking aerosols should be removed immediately from their present location and stored separately in a safe place away from sources of ignition preferably in the open Small spillage up to 1 litre may be cleaned up with a mop or absorbent cloth Medium spillages up to 5 litres should be absorbed with sand earth sawdust or other inert material and transferred to a suitable container for subsequent disposal Larger spillages should be contained with sand earth sawdust or other inert material Do not pump to drain Do not contaminate water courses or ground water If necessary pump to a safe place Consult your local Water Authority Environmental Protection Agency local Council or an expert for advice on disposal 7 STORAGE AND HANDLING Handling Pack copy is recommended to carry the standard warning phrases taken from The Aerosol Dispensers EEC Requirements Regulations S I 1140 1977 as follows Pressurised container Protect from sunlight and do not expose to temperatures exceeding 50 C Do not pierce or burn even after use Do not spray on a naked flame or any incandescent material Storage Containers should be kept out of reach of young children The product should not be used in restricted areas especially where there is likely to be an ignition source Warehouses and stores containing aerosols should therefore be separated from other areas by fire resistant construction of at least one half hour duration Store
17. mild to moderate irritation e g redness stinging Rinse immediately and thoroughly with plenty of water for at least 5 minutes In case any irritation persists seek medical advice Ingestion If accidental ingestion should occur 1t may cause emesis or if not a mild mucosal irritation Drink water or milk Do not induce vomiting If any symptoms persists seek medical advice Inhalation If irritation should occur rinse mouth and throat with water and move to fresh air If irritation persists or asthma like symptoms occur seek medical advice 5 Fire fighting measures The product itself will not burn If anything packaging may be involved in a fire Use CO2 dry chemical powders or alcohol resistant foam If water is used contain run off 6 Accidental release Avoid spillage into sewers or surface water For small measures spills sluice to drain with plenty of water For large spills pump into plastic containers and rework dispose of as per local legislation 7 Handling and storage Store in a cool and dry area Provide sufficient ventilation 8 Exposure controls Not a hazard in normal use For prolonged or repeated contact wear Personal protection appropriate hand protection Rinse and dry hands thoroughly after each cleaning job If used as a spray use only in at the recommended dilution and spray only in direction of application Don t breath mist spray 9 Physical and chemical Appearance Green or yellow Lemon liquid Sm
18. number 01483 302222 COMPOSITION INFORMATION ON INGREDIENTS This window cleaner contains Ingredients EINECS Number Concentration Classification range Directive 67 548 EEC Symbol R phrases Butoxyprepanol l 225 878 4 less than 5 Xi 36 38 Alcohol 1 200 5786 less than 5 F 11 Perfume I INCI name International Nomenclature Cosmetic Ingredient R phrases texts are reported in section 16 HAZARDS IDENTIFICATION This product is not classified as dangerous according to the European Dangerous Preparations Directive FIRST AID MEASURES Eye contact rinse thoroughly with cold water Skin contact rinse with water ingestion drink a glass of milk or water Do not induce vomiting Contact poison center Inhalation in case of accident or important overexposure remove to fresh air PRODUCT AJAX Double Solvent Antistatic Triple Action Blue Page 2 of 4 window cleaner spray FIRE FIGHTING MEASURES Not flammable aqueous solution containing a major proportion of water Flashpoint 57 C closed cup Extinguishing media water spray all purpose dry chemical CO2 depending on fire circumstances and surrounding materials Special fire fighting procedures Self contained breathing apparatus and protective clothing should be worn when fighting chemical fires ACCIDENTAL RELEASE MEASURES Wipe up or wash out with plenty of water small to medi
19. of processes and activities and also produces advice for products that have safety data sheets However there may be no good practice advice available for your process Where this is small scale with obvious control measures you can do the assessment yourself In other cases or where you are not sure ask your supplier trade association HSE s Infoline or other reliable information sources You may need professional advice such as from an occupational hygienist see Getting help What are exposure control measures Control measures are always a mixture of equipment and ways of working to reduce exposure The right combination is crucial No measures however practical can work unless they are used properly So any standard operating procedure should combine the right equipment with the right way of working This means instructing training and supervising the workers doing the tasks You need control measures that work and continue to work all day every day Examples of control measures Substance Control Way of working Managing process equipment m Cleaning with m Use arag holder m Avoid skin contact m Check controls are solvent on rag mi Provide a small m Reduce solvent vapour from used Dust and Sparks from abrasive wheel Fume from cutting demolition scrap Cutting fluid mist from a lathe Swart Dust from disc cutter on stone worktop bin with a lid for used ra
20. prevent this disabling disease The leaflet shows you what to look out for and how to prevent dermatitis It also tells you where you can find more detailed practical advice for specific jobs and workplaces What is contact dermatitis Contact dermatitis is inflammation of the skin caused by contact with a range of This is a web friendly materials These include detergents toiletries chemicals and even natural products version of leaflet like foods and water if contact is prolonged or frequent It can affect all parts of INDG233 rev 1 the body but it is most common to see the hands affected There are three main revised 03 07 types of contact dermatitis E irritant contact dermatitis E allergic contact dermatitis mM contact urticaria Irritant contact dermatitis is caused by things that dry out and damage the skin eg detergents solvents oils and prolonged or frequent contact with water Allergic contact dermatitis occurs when someone becomes allergic to something that comes into contact with his or her skin The allergic reaction can show up hours or days after contact Common causes include chemicals in cement hair products epoxy resins and some foods Urticaria is a different kind of allergy It occurs within minutes of the material touching the skin Things like plants foods and natural rubber latex gloves can cause it What does contact dermatitis look like The signs and symptoms of the different types of
21. that the PPE satisfies certain basic safety requirements and in some cases will have been tested and certified by an independent body Personal Protective Equipment at Work Regulations 1992 3 of 5 pages Health and Safety Executive Other regulations The PPE at Work Regulations do not apply where the following six sets of regulations require the provision and use of PPE against these hazards For example gloves used to prevent dangerous chemicals penetrating the skin would be covered by the Control of Substances Hazardous to Health Regulations 2002 as amended The regulations are The Control of Lead at Work Regulations 2002 The lonising Radiations Regulations 1999 The Control of Asbestos at Work Regulations 2002 The Control of Substances Hazardous to Health Regulations 2002 as amended The Noise at Work Regulations 1989 The Construction Head Protection Regulations 1989 Key points to remember Are there ways other than PPE in which the risk can be adequately controlled eg engineering controls If not check that PPE is provided it offers adequate protection for its intended use those using it are adequately trained in its safe use it is properly maintained and any defects are reported it is returned to its proper storage after use Further reading Personal Protective Equioment at Work Regulations 1992 Guidance on Regulations L25 HSE Books 2005 ISBN O 7176 6139 3 COSHH a brief guide to the Regulation
22. thoroughly Drink plenty of water Get medical attention immediately SKI N Immediately remove contaminated clothing Rinse immediately with plenty of water Continue to rinse for at least 15 minutes Get medical attention if any discomfort continues EYES Promptly wash eyes with plenty of water while lifting the eye lids Make sure to remove any contact lenses from the eyes before rinsing Continue to rinse for at least 15 minutes and get medical attention FIRE FIGHTING MEASURES EXTINGUISHING MEDIA The product is non combustible Use fire extinguishing media appropriate for surrounding materials SPECI AL FIRE FIGHTING PROCEDURES Use special protective clothing Regular protection may not be safe ACCIDENTAL RELEASE MEASURES SPI LL CLEAN UP METHODS Wear necessary protective equipment Absorb in vermiculite dry sand or earth and place into containers Collect spillage in containers seal securely and deliver for disposal according to local regulations Inform Authorities if large amounts are involved HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling skin and eye contact STORAGE PRECAUTIONS Store separated from Acids USAGE DESCRI PTI ON Controlled substance storage Page 1 of 3 SAFETY DATA SHEET S20 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION I NGREDI ENT NAME CAS No STD LT EXP 8 Hrs ST EXP 15 Min POTASSIUM HYDROXIDE WEL 2 mg m3 PROTECTIVE EQUI PMENT 9 PHYSICAL AND CHEMI
23. 72 2 COMPOSITION INFORMATION ON INGREDIENTS This product includes in it s formulation EXXSOL DSP 145 16 Flammable R10 Less than 25 BUTANE Extremely Flammable R12 Less than 20 Key to Risk Phrases R10 Flammable R12 Extremely Flammable Aerosol Furniture Polish Page 2 of 6 3 HAZARDS IDENTIFICATION Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal Eye Contact Skin Inhalation Ingestion S O 0p x 5 Inhalation Ingestion Spray contact may cause minor irritation Prolonged contact can lead to de fating and irritation but should not arise from normal use of the product Except in cases of deliberate excessive inhalation no toxic hazard is believed to exist with this product Inhalation may cause nausea headache and dizziness and in extreme cases loss of consciousness Accidental ingestion of the spray is likely to be rare and the quantities that might be swallowed are so small as to constitute a negligible risk Deliberate concentration of the sprayed product and subsequent ingestion or inhalation could involve significant amounts of solvent If ingestion occurs small quantities may be aspired directly into the lungs or during any subsequent vomiting This may result in intense local irritation to the lung tissues and give rise to a chemical induced pneumonia FIRST AID MEASURES Rinse thoroughly with luke warm water for at least 10 minutes hol
24. 9577 e mail hse infoline natbrit com or write to HSE Information Services Caerphilly Business Park Caerphilly CF83 3GG This leaflet contains notes on good practice which are not compulsory but which you may find helpful in considering what you need to do This leaflet is available in priced packs of 10 from HSE Books ISBN 978 O 7176 6868 7 Single free copies are also available from HSE Books Crown copyright This publication may be freely reproduced except for advertising endorsement or commercial purposes First published 06 09 Please acknowledge the source as HSE Published by the Health and Safety Executive INDG136 rev4 10 of 10 pages COSHH and cleaners key messages Page 1 of 1 TE Health and Safety Executive HSE COSHH and cleaners key messages e Having your hands wet for a long time or having them frequently wet during the day can irritate your skin leading to dermatitis e Some ingredients in cleaning products can cause skin allergies and asthma e Some cleaning products are corrosive and can cause skin burns and eye damage There are simple things you can do to prevent ill health Preventing exposure to harmful substances usually means a combination of some of the following controls e Use good work techniques that avoid or minimise contact with harmful substances and minimise leaks and spills Store cleaning products safely e For some tasks you may also need to provide personal protective
25. CAL PROPERTIES APPEARANCE Clear Liquid COLOUR Brown ODOUR Odourless DENSI TY SPECI FI C GRAVI TY g ml 1 360 1 380 pH VALUE CONC SOLUTION gt 13 0 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions CONDITIONS TO AVOID Avoid contact with acids MATERIALS TO AVOID Strong acids Reacts strongly with light metals such as aluminium and zinc producing hydrogen which is Highly Flammable 11 TOXI COLOGY INFORMATION I NHALATI ON May cause damage to mucous membranes in nose throat lungs and bronchial system I NGESTI ON Causes severe burns Harmful if swallowed SKI N CONTACT Causes severe burns EYE CONTACT Causes severe burns Risk of serious damage to eyes 12 ECOLOGI CAL I NFORMATION ECOTOXI CI TY Not classed as Hazardous to the Environment but release to the environment should be avoided 13 DI SPOSAL CONSI DERATI ONS DI SPOSABLE METHODS Dispose of waste and residues in accordance with local authority requirements 14 TRANSPORT I NFORMATION LABEL FOR CONVEYANCE UN No ROAD 1719 UK ROAD TRANSPORT CLASS 8 UK ROAD PACK GR II ADR CLASS Class 8 Corrosive substances PROPER SHI PPI NG NAME I CAUSTIC ALKALI LIQUID NOS Sodium Hydroxide UN No SEA 1719 Page 2 of 3 SAFETY DATA SHEET S20 15 REGULATORY I NFORMATI ON ELDEN LABEL FOR SUPPLY RI SK PHRASES R35 Causes severe burns SAFETY PHRASES S1 2 Keep locked up and o
26. ECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION Exposure Limits Aminoethanol TWA 8 hours 7 6mg m STEL 15mins 15mg m Environmental Controls For additional guidance contact ENVIROWISE at WWW ENVITOWIS gOV UK jor telephone 0800 585794 Eye Protection Side shield safety glasses are recommended when handling concentrate Protective Clothing Standard work clothing and nitrile buty rubber gloves SDS B144 Issue Revision Date 01 08 03 Page 1 of 2 Respiratory Protection Not required in normal use Ventilation Normal air circulation Allow adequate ventilation in enclosed areas Hygiene Wash hands and clothing after use or spill Do not eat or drink when handling chemicals SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour State Moderate foam colourless liquid Odour Mint pH Concentrate 10 5 pH Diluted Not applicable Boiling Point Range C 100 Flash Point C None Method Not applicable Flammability Limit Not applicable Explosive Properties Not applicable Oxidising Properties Not applicable Vapour Pressure Not determined Relative Density Water 1 1 00 Solubility 100 Partition Coefficient N octanol Water Not determined Viscosity Not determined Vapour Density Not determined Evaporation Rate Not determined Active 6 5 Solids 4 SECTION 10 STABILITY AND REACTIVITY Stability Stable Conditions to Avoid Extreme heat can refract solvent content Incompatibility
27. Materials to Avoid Strong oxidising materials Hazardous Decomposition Products Exposure to fire may liberate carbon dioxide carbon monoxide water and other unidentified thermal decomposition products from this product or its packaging SECTION 11 TOXICOLOGICAL INFORMATION Eye Contact Contact with concentrate may produce moderate irritation if not promptly rinsed Skin Contact Possible dermatitis from prolonged or repeated contact Low skin absorption toxicity Inhalation Excessive exposure may produce respiratory irritation Ingestion Low oral toxicity Gastro intestinal irritation Possible systemic effects from glycol ether Acute and Chronic Effects Acute Toxicity LD50 gt 2000mg Kg Oral rat Ethyl diglycol LD50 gt 5660mg Kg Oral rat Butyl diglycol Corrosivity Irritation Skin eye and respiratory Sensitisation None known Repeated Dose Toxicity Not established Mutagenicity None Carcinogenicity None Teratogenicity None SECTION 12 ECOLOGICAL INFORMATION Ecotoxicity Contains less than 5 Ethyl diglycol LC50 Fish 96h gt 1000mg I Ethyl diglycol Contains less than 1 alcohol ethoxylate which is classified as toxic to aquatic organisms Mobility Soluble in water Persistence and Degradability The raw material ingredients in this product are biodegradable within the scope of current EC legislation The major packaging materials of polyethylene and fibreboard are recyclable Bioaccumul
28. SE MEASURES Personal precautions Put on appropriate personal protective equipment See Section 8 Environmental precautions and Inthe event of major spillage Use appropriate containment to avoid environmental contamination Take up with cleanup methods inert absorbing material Place in suitable clean dry containers for disposal by approved methods Use a water rinse for final cleanup 7 HANDLING AND STORAGE Handling Use only in well ventilated areas Avoid breathing vapours or spray mists Avoid contact with skin and eyes Do not puncture or incinerate Storage Store in a dry cool and well ventilated area Keep away from heat Protect from freezing Keep out of the reach of children For Professional use only Pressurized container protect from sunlight and do not expose to temperatures in excess of 50 C 8 EXPOSURE CONTROLS PERSONAL PROTECTION When handling product as supplied Engineering controls No special ventilation requirements General room ventilation is adequate Occupational Exposure Limits Date of issue 21 Jul 2000 Version 1 Page 1 3 SAFETY DATA SHEET Pledge Furniture Polish Aerosol Natural Chemical name OEL No occupational exposure limits have been established Belgium Personal protective equipment No specific personal protection equipment is required Information should be confirmed by workplace assessment 9 PHYSICAL AND CHEMICAL PROPERTIES Physical state Aerosol Colour C
29. afer form of the product eg paste rather than powder Change the process to emit less of the substance Enclose the process so that the product does not escape Extract emissions of the substance near the source Have as few workers in harm s way as possible Provide personal protective equipment PPE such as gloves coveralls and a respirator PPE must fit the wearer NOOR WD If your control measures include 5 6 and 7 make sure they all work together Control equipment Control equipment comes in many forms It includes ventilation to extract dust mist and fume glove boxes and fume cupboards spray booths and refuges clean rooms in dirty work areas It also includes using water to reduce dust and systems for disinfecting cooling water For control equipment your supplier should provide a user manual If you don t have one ask for it And if this is impossible you may need professional help to write one The user manual should set out schedules for checks maintenance and parts replacement For example it should include a description of the system the daily checks the worker or supervisor needs to carry out eg the ventilation is turned on the airflow meter gives the right reading the weekly or monthly checks the supervisor or owner needs to carry out eg of equipment wear and tear and that short cuts are not creating dangers details of any thorough examination and test signs of wear and control failu
30. al precautions 1 This product is not classified according to EU directive 88 379EEC and local implementation laws i All ingredients used in this formulation are EINECS registered matior This product does not require any special training before use Usage and handling instructions are mentioned on package and this Material Safety E 4 Data Sheet SAFETY DATA SHEET 1 Identification of Substance Preparation and of the company undertaking BELL MULTIPURPOSE DEGREASER 2 Composition Information on Ingredients Symbol Xn R22 36 38 Methoxy propanol F R10 Amphoteric surfactant Xi 36 38 1 5 3 Hazards Identification Irritating to skin and eyes 4 First Aid Measures Inhalation Remove from source of vapour or spray mist Seek medical attention if symptoms persist Eyes Rinse immediately with copious amounts of water holding the eyelids open Obtain immediate medical attention Skin Flush the contaminated area with plenty of water If irritation persists obtain immediate medical attention Ingestion Remove product from the mouth give plenty of water or milk to drink and obtain immediate medical attention Do not induce vomiting 5 Fire Fighting Measures Product is non flammable In the event of fire from other causes the product is compatible with water foam CO and dry powder extinguishers May evolve toxic fumes if involved in a fire Fire fighters should wear self contai
31. are mentioned on package and this Material Safety Data Sheet MATERIAL SAFETY DATA SHEET Reference HSBRLIQ Creation date 27 November 2001 Page 1 of 6 IDENTIFICATION OF THE PRODUCT AND THE COMPANY PRODUCT BRASSO LIQUID Cleaning household Items made of brass copper tin and chrome Company Reckitt Benckiser UK Ltd Delta 1200 Welton Road Delta Business Park Swindon Wiltshire SN5 7XZ Tel 014793 732000 Fax 01793 511572 COMPOSITION INFORMATION ON INGREDIENTS The product contains the following components Ammonia 25 R34 R37 50 75 White Spirit 150 200N R10 R51 53 R65 CAS No 64742 82 1 Key to Risk Phrases R10 Flammable R34 Causes burns R37 irritating to the respiratory system R51 53 Toxic to aquatic organisms may cause long term adverse effects in the aquatic environment R65 Harmful may cause lung damage if swallowed Amended 27 November 2001 For all correspondence please write to Reckitt Benckiser PO Box 118 Clevedon BS21 7ZH Tel 0845 7697079 Head office Reckitt Benckiser UK Limited Dolta 1200 Walton Road Delta Business Park Swindon Wiltshire SNS 7XZ Registered Office 103 105 Bath Road Slough Berkshire SLI JUH Reg No 3982446 Brasso Liquid Page 2 of 6 3 HAZARDS IDENTIFICATION Eye Contact Contact with eyes may cause irritation and conjunctivitis Skin Contact Repeated or prolonged exposure may cause defatting of skin leading to irritation and dermatitis Inhalat
32. ative Potential None known Other Effects None known or no relevant data available for substances in this preparation SECTION 13 DISPOSAL CONSIDERATIONS Waste cleaning effluent should be discharged to a sewage drain which is linked to a local sewage and waste treatment facility Empty containers should be rinsed with water then crushed and disposed of at legal waste disposal site Contact local Environment Agency office for waste holder requirements SECTION 14 TRANSPORT INFORMATION UN No None Classification Not classified as hazardous for transport Proper Shipping Name None Packing Group None Road ADR None Sea IMDG None Air ICAO IATA None Rail RID None SECTION 15 REGULATORY INFORMATION Classification Not classified as hazardous for supply Risk Phrases None Safety Phrases S2 Keep out of reach of children S24 25 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 37 Wear suitable gloves The information given has been compiled with reference to the CHEMICALS HAZARD INFORMATION AND PACKAGING FOR SUPPLY REGULATIONS CHIP 3 2002 as amended the CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH REGULATIONS COSHH 2002 as amended and the MANAGEMENT OF HEALTH AND SAFETY AT WORK REGULATIONS 1999 as amended This safety data sheet does not constitute the users own assessment of workplace risk as required by other
33. ble and unreactive under normal household conditions TOXICOLOGICAL INFORMATION See also Section 2 and 3 This product contains white spirit for which the following apply Inhalation Vapour concentrations above recommended exposure limits are irritating to the eyes and respiratory tract may cause headaches and dizziness are anesthetic and may have other central nervous system effects Skin Contact Low order of toxicity frequent or prolonged contact may cause dermatitis Eye Contact Irritating but does not injure eye tissue Ingestion Minimal toxicity The viscocity of this preparation mitigates the risk of aspiration into the respiratory system during ingestion or vomiting mended 27 November 2001 asso Liquid Page 5 c ECOLOGICAL INFORMATION See also Section 6 7 14 and 15 This product contains 50 75 of white spirit which is highly volatile and will rapidly evapora to the air if released into the environment Based upon data for similar materials white spirit classified as R51 53 Toxic to aquatic organisms may cause long term effects in the aquatic environment White spirit is expected to be biodegrade rapidly and be readily biodegradable according t OECD guidelines It can degrade rapidly in air and is expected to be removed in a waste wa treatment facility Although data exists to show that white spirit is not expected to persist in the aquatic environment European Classification rules require that it be c
34. clear thin liquid Odour perfumed liquid pH 7 2 as is Relative density 1 00 Solubility fully miscible in water Viscosity same as water STABILITY AND REACTIVITY Stable in normal conditions No hazardous reactions expected TOXICOLOGICAL INFORMATION This product has not been tested as a whole In case of accidental ingestion of a small quantity transient gastro intestinal effects discomfort may occur but no acute harmful effects are anticipated Mild eye irritation may occur Inhalation of vapors during several hours may cause discomfort LD 50 gt 2000 mg kg body weight based on the toxic contributions of the components ECOLOGICAL INFORMATION Major ingredients in this product are readily biodegradable OECD 301 test series DISPOSAL Any disposal practice must be in compliance with local country laws and regulations TRANSPORT INFORMATION to be completed if needed Page 3 of 4 PRODUCT AJAX Double Solvent Antistatic Triple Action Blue window cleaner spray REGULATORY INFORMATION This product is NOT classified as Dangerous according to the Directive 1999 45 EC on the classification packaging and labelling of dangerous preparations The primary biodegradability of the surfactants present in the product is higher than 80 in compliance with Directives 73 404 EEC and 73 405 EEC and amendments 82 242 EEC and 82 243 EEC to be completed eventually by local regulatory req
35. d importers through improved safety data sheets Further information can be found on HSE s website www hse gov uk reach and on the European Chemical Agency s website www echa europa eu home_en asp Working with substances hazardous to health 7 of 10 pages Health and Safety Executive Getting help Trade Consultants service Local health and What and who ee association suppliers safety groups Good control J Testing LEV Health checks This is not an inclusive list but some useful sources of information and help are ee a m British Occupational Hygiene Society BOHS 5 6 Melbourne Business Court Millennium Way Pride Park Derby DE24 8LZ Tel 01332 298101 www bohs org BOHS is the professional body for occupational hygienists who understand how workplace hazards affect worker health and systems to control risks to health from work The website has a list of consultants E Health amp Safety Laboratory HSL Business Development Group Health amp Safety Laboratory Harpur Hill Buxton Derbyshire SK17 QUN Tel 01298 218000 www hsl gov uk HSL s services include specialist advice and consultancy risk assessment and workplace monitoring including biological monitoring E Institution of Occupational Safety and Health IOSH The Grange Highfield Drive Wigston Leicestershire LE18 1NN Tel 0116 257 3100 www iosh co uk IOSH is the association for health and safety professionals The website al
36. d protect health These measures can also improve production or cut waste Looking after your business Your aim in running your business is to make a profit You know what you do and how you are doing it You know what processes and tasks are involved You know the short cuts Ensuring your workers remain healthy may also lead to healthy profits Which substances are harmful m Dusty or fume laden air can cause lung diseases eg in welders quarry workers or woodworkers Metalworking fluids can grow bacteria and fungi which cause dermatitis and asthma Flowers bulbs fruit and vegetables can cause dermatitis Wet working eg catering and cleaning can cause dermatitis Benzene in crude oil can cause leukaemia 1 of 10 pages Myth It s natural so it can t be harmful Reality Natural materials can be harmful For example henna can cause dermatitis and asthma wood dust can cause asthma stone or concrete dust can cause lung disease such as silicosis and citrus oils can cause skin problems Myth I don t work with harmful substances Reality Most businesses use substances that can be hazardous to health even something as simple as flour can act as a substance hazardous to health Health and Safety Executive Many other products or substances used at work can be harmful such as paint ink glue lubricant detergent and beauty products Ill health ca
37. d texture change before proceeding Apply B144 solution directly to stain with sprayer and blot with white towel or tissue sna ea SECTION 2 COMPOSITION INFORMATION ON INGREDIENTS Repeat until there is no further improvement Do not rub On wool and all fabrics rinse treated area with B109 Fibre amp Fabric Rinse SUBSTANCE RISK See Section 16 EINECS NO CAS NO W W EC RANGE Water None assigned None None More than 30 Butyl diglycol Xi R36 203 919 7 111 90 0 Less than 5 Ethyl diglycol Xi R36 203 961 6 112 34 5 Less than 5 Aminoethanol Less than 1 Anionic surfactants Less than 1 Non ionic surfactant Xn R22 Xi R41 N R50 None 68131 39 5 Less than 1 Fragrance IFRA certified Preservative SECTION 3 HAZARDS IDENTIFICATION Classification Not classified Eye Contact Contact may cause moderate eye irritation Skin Contact Prolonged or repeated contact may cause mild irritation and or possible dermatitis Inhalation None expected in normal use Breathing spray mists may cause temporary irritation of the nose and throat Ingestion Deliberate ingestion may produce nausea and irritation due to alkalinity Possible systemic effects Environment No cumulative effects Raw materials are biodegradable See Ecological Information for further details SECTION 4 FIRST AID MEASURES Eye Contact Flush immediately with water for 10 minutes then seek medical attention if irritation persists Skin Contact
38. d the Safety Data Sheets Directive 91 155 EEC as amended by Directives 93 112 EEC and 2001 S58EC Revision Number 0 Date of Issue 16 1 03 Bell Brush 286 Alma Road Enfield Middlesex EN3 7BB Bell Multipurpose Degreaser CHE307 Page 2 of 2 SAFETY DATA SHEET Professional Cleaning amp Hygiene Products Europe Chemicals Hazard Information and Packaging for Supply Regulations 1994 Greenham Code 518437 CSDS No ICP 29 Issue 3 Date March 13 1997 AW Code 66 15C 1 Identification of the PROFESSIONAL FAIRY LIQUID or Substance Preparation PROFESSIONAL FAIRY LIQUID Lemon Company Procter amp Gamble UK Professional Cleaning amp Hygiene Products Europe The Heights Brooklands Weybridge Surrey KT 13 OXP UK Tel 01932 89 6000 Fax 01932 89 6200 2 Com position information A dishwash liquid detergent containing on ingredients Percentage Symbol Risk phrase of ingredients Anionic surfactants 15 30 Xi R36 38 Nonionic surfactants lt 5 Xi R36 38 lt 5 Xi R38 R41 lt 5 Xi R41 Amphoteric surfactants lt 5 Xi R36 38 Solvents 5 15 F RII 3 Hazards identification This product is not classified as hazardous 4 First aid measures Skin contact Upon prolonged contact with skin the product may cause slight skin irritation Wash affected area thoroughly with water In case any irritation persists seek medical advice Eye contact If the product gets into the eyes it will cause transient
39. dance Note EH40 HSE Books 2005 ISBN 978 O 7176 2977 O Fire and explosion How safe is your workplace A short guide to the Dangerous Substances and Explosive Atmospheres Regulations Leaflet INDG370 HSE Books 2002 single copy free or priced packs of 5 ISBN 978 O 7176 2589 5 www hse gov uk pubns indg370 pdf Preventing contact dermatitis at work Leaflet INDG233 rev1 HSE Books 2007 single copy free or priced packs of 15 ISBN 978 O 7176 6183 1 www hse gov uk pubns indg233 pdf Read the label How to find out if chemicals are dangerous Leaflet INDG352 HSE Books 2002 single copy free or priced packs of 15 ISBN 978 O 7176 2366 2 www hse gov uk pubns indg352 pdf Respiratory sensitisers and COSHH Breathe freely An employers leaflet on preventing occupational asthma Leaflet INDG95 rev2 HSE Books 1995 single copy free or priced packs of 15 ISBN 978 O 7176 0914 7 www hse gov uk pubns indg95 pdf Working with substances hazardous to health 9 of 10 pages Health and Safety Executive Further information HSE priced and free publications are available by mail order from HSE Books PO Box 1999 Sudbury Suffolk CO10 2WA Tel 01787 881165 Fax 01787 313995 Website www hsebooks co uk HSE priced publications are also available from bookshops and free leaflets can be downloaded trom HSE s website www hse gov uk For information about health and safety ring HSE s Infoline Tel 0845 345 0055 Fax 0845 408 9566 Textphone 0845 408
40. dermatitis are similar Dry red and itchy skin is usually the first sign Swelling flaking blistering cracking and pain can follow Sometimes the consequences of contact with a material are immediately visible Sometimes contact occurs without apparent effect However every contact can Cause minute amounts of invisible damage to the skin that can build up until more serious signs are seen So don t be lulled into a false sense of security 1 of 3 pages Health and Safety Executive What are the high risk jobs and workplaces Certain workers are at greater risk of developing dermatitis They include healthcare workers hairdressers beauticians printers those in cleaning catering and construction and workers using metalworking fluids But remember dermatitis can occur in just about any workplace Managing the work to prevent dermatitis Following three simple steps can prevent dermatitis Avoid contact with materials that cause dermatitis Protect the skin Check for early signs of dermatitis No contact no dermatitis So take all the steps you can to avoid contact with materials that cause dermatitis by changing the task or process Some examples of how you can do this are given below Examples of how you can avoid contact are substitute a more hazardous material with a safer alternative automate the process enclose the process as much as possible use mechanica
41. ding the eyelids apart as soon as possible If in any doubt obtain medical attention If left in contact with the skin especially children some drying out and soreness may occur It is recommended that the affected area be thoroughly washed with cold water cover with a dry dressing and any impregnated cloth be removed In the event of pain or skin damage medical attention should be sought Ensure that the airways are clear and unobstructed Keep warm and at rest If there is any difficulty in breathing obtain medical attention urgently give oxygen lf breathing stops or shows signs of failing apply mouth to mouth ventilation In the event of deliberate ingestion medical help must be obtained urgently Ensure that airways are clear and unobstructed Wash out mouth with water Do not induce vomiting Keep warm and at rest If there is any difficulty in breathing obtain medical attention urgently give oxygen If breathing stops or shows signs of failing apply mouth to mouth ventilation Aerosol Furniture Polish Page 3 of 6 5 FIRE FIGHTING MEASURES Specific Dangers All aerosols are pressurised products and will eventually burst if exposed to very high temperatures or if involved in a fire Fires involving aerosols with flammable contents are severe and can spread very quickly Extinguisher Type In the event of a fire use Water Dry Powder or Foam extinguisher 6 ACCIDENTAL RELEASE MEASURES See also Sections 8 and 13 Damaged or
42. ducts flammable and non flammable liquids acids and alkalis and wastes Store products containing chemicals securely in a cool dry dark place capable of keeping in spills Don t store far more than you need gt Jeeves SS a cq 6014 bol PRODUCT SAFETY DATA SHEET 51 6015 PRODUCT WIPE OVER perfumed disinfecting spray cleaner Page 1 of 4 Reference 69 230 GB Creation Date 10 Oct 1996 Revision Date 27 Aug 1998 IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY 1 1 Product Identification WIPE OVER perfumed disinfecting spray cleaner 1 2 Company dentiflcation COLGATE PALMOLIVE Guildford Business Park Middleton Road Guildford GU2 8JZ 1 3 Emergency Phone no 01483 302222 COMPOSITION INFORMATION ON INGREDIENTS This liquid disinfecting cleaner contains lagredients Concentration range Nonionic surfactants less than 5 Disinfectant cationic surfactant less than 1 Phosphates less than 5 Perfume HAZARDS IDENTIFICATION This product is not dangerous in normal conditions of use Some hand skin dryness irritation may occur in case of prolonged exposure to the neat product Discharge of large quantities into the aquatic environment without appropriate sewage treatment may be detrimental to aquatic organisms FIRST AID MEASURES Eye contact rinse thoroughly with water Skin contact rinse with water Ingestion do not induce vomiting Contact poison center Inhalation
43. e according to new formulation Changes versus previous issue of this SDS References Header Footer 1 Identification of the i i Substance Preparation Professional Ariel Non Bio Regular Powder Company Name Procter amp Gamble UK Brooklands Address Weybridge Surrey KT13 OXP UK Telephone 01932 89 6000 Fax 01932 89 6200 Emergency phone 0800 716 854 UK 1800 535 119 ROD 2 Composition information A granular laundry detergent containing on ingredients 2 PROPENOIC ACID 2 5 FURANDIONE 52255 49 9 Polymer R53 1 5 POLYMER 3 Hazards identification This product is not classified as dangerous according to EU Directive 1999 45 EC Eye contact Transient superficial irritation Skin contact Prolonged exposure may cause skin irritation Ingestion Possible mild gastro intestinal irritation with nausea and vomiting Inhalation Inhaling of particles may cause mild irritation of the respiratory system 4 First aid measures Eye contact Rinse thoroughly with plenty of water for several minutes If symptoms persist seek medical advice Skin contact Rinse affected area with water If needed apply cold compress to relieve irritation If symptoms persist discontinue use of product and seek medical advice Ingestion Drink a glass of water to dilute product Do not induce vomiting Act immediately in order to prevent further irritation of mouth throat and stomach mucosa If symptoms persist if persistent vomit
44. e hazards too Look at the safety data sheet for more information Main points Avoid or minimise skin contact with chemicals Check that all the controls are being used properly Consider substituting with safer products Diluting chemical concentrates Control approach S Harm via skin or eye contact Access and premises Make sure there is enough room to do the job safely Y Provide good washing facilities Equipment Ensure the equipment used with the product works properly without leaks Provide protective gloves If diluting with a solvent make sure the room is well ventilated 5 10 changes per hour with a through draught Y Buy liquid chemicals in containers that are easy to pour from don t dribble and don t trap liquid in a rim Y Try to buy solid chemicals in tablet or granule form or in wide necked containers so it is easy to scoop out Caution Never decant concentrate into an unlabelled container Never re use a concentrate container dispose of it safely or return it to your supplier Don t store more than 50 litres of flammable liquid indoors use a flammables store Procedures Y Y Contractors using pesticides should have a British Pest Control Association BPCA qualification Y Y Store products containing chemicals securely in a cool dry dark place capable of retaining spills Don t store far more than you need Y Y Reduce skin contact workers should wash
45. eaflet INDG307 HSE Books 1999 single copy free or priced packs of _ Use and store your 25 ISBN O 7176 1751 3 Web version available at protective equipment hse gov uk pubns indg307 pdf according to instructions Preventing dermatitis at work Advice for employers and employees Leaflet INDG233 HSE Books 1996 single copy free or priced packs of 15 ISBN O 7176 1246 5 Lit you find any problems tell your supervisor Don t just carry on working _ Throw away single use gloves every time you take them off Useful links _ Wash your hands after m HSE priced and free publications are available from HSE Books use and before and after Tel 01787 881165 Website www hsebooks co uk eating drinking smoking and For information about health and safety ring HSE s Infoline Tel 0845 using the lavatory 345 0055 Textphone 0845 408 9577 e mail hse infoline natbrit com Contact the British Occupational Hygiene Society BOHS on 01332 298101 or at www bohs org for lists of qualified hygienists who can help you _ Never clean your hands with concentrated cleaning products or solvents Look in the Yellow Pages under Health and safety consultants and _ Check your skin regularly Health authorities and services for occupational health for dryness or soreness tell Also see www nhsplus nhs uk your supervisor if these symptoms appear _ Use skin creams provided as instructed This guidance is issu
46. ecords _ Do you tell workers about the dangers and how to use control measures properly Do you avoid increasing the overall health and safety risks when making changes Skills and experience Competence Ensure that whoever designs installs maintains and tests your control measures is competent they have the necessary skills knowledge and experience You can assess the competence of equipment and service providers with questions such as Have you done this sort of work before What are your qualifications Do you belong to a professional organisation Can speak to previous clients Ideally you want someone who knows your industry has a successful track record and gives good value for money Working with substances hazardous to health 6 of 10 pages Health and Safety Executive Worker involvement Involve your workers in developing control measures to make sure they are suitable for the way they carry out the work Encourage them to suggest improvements and to report anything they think might be going wrong Training instruction and information m Explain to your workers and anyone else who needs to know what the dangers are It is poor practice just to hand them a page of written information m Show workers how to use control measures properly and how to check that they are working E Carry out practice drills for cleaning up spills safely do this before any spillages happen m f workers need t
47. ed by the Health and Safety Executive Following the guidance is not compulsory and you are free to take other action But if you do follow the guidance you will normally be doing enough to comply with the law Health and safety inspectors seek to secure compliance with the law and may refer to this guidance as illustrating good practice Published by the Health and Safety Executive 06 06 Health and Safety Executive SR COSHH essentials for service and retail This information will help i PRN employers including the oe d self employed and franchisees comply with the Control of Substances Hazardous to Health Regulations 2002 COSHH as amended to control exposure and protect workers health T77 Mia ar It is also useful for trade union safety representatives This sheet describes good practice using personal protective equipment PPE It covers the points you need to follow to reduce exposure to an adequate level It is important to follow all the points or use equally effective measures Disinfectants are biocidal products Authorised products are safe for use so long as you follow the instructions on the label Some chemicals can be flammable so your controls must suit those hazards too Look at the safety data sheet for more information Main points Can you get products ready for use Avoid or minimise skin contact with chemicals Check that all the controls are bei
48. ell Perfume pH 10 aqueous solution ca 7 8 Flashpoint 51 54 C Not Flammable Non Explosive Non Oxidizing Relative density ca 1 02 g cc Water solubility high Packaging polyethylene bottle PP cap 10 Stability and reactivity Stable under normal conditions Do not store below 0 C 11 Toxicological information This product is not acutely toxic after ingestion it may cause emesis If large quantities are ingested treat symptomatically If irritant effects are seen these will be mild to moderate depending on exposure If in contact with eyes flushing with water is recommended Estimated acute oral toxicity LD50 rats gt 2 kg Skin irritation May cause slight skin irritation Eye irritation May cause mild irritation Mutagenicity Not mutagenic Sensitisation No evidence of skin sensitization 12 Ecological information The surfactants used in this product conform to the EEC biodegradability legislation Ingredients have a known ecotoxicity supporting their safe use 13 Disposal considerations Observe local legislation 14 Transport information Not a dangerous material no special precautions 15 Regulatory information This product is not classified according to EU directive 88 379EEC and local implementation laws All ingredients used in this formulation are EINECS registered 16 Other information This product does not require any special training before use Usage and handling instructions
49. em of PPE is being worn are they compatible For example does a particular type of respirator make it difficult to get eye protection to fit properly The hazards and types of PPE Eyes Hazards chemical or metal splash dust projectiles gas and vapour radiation Options safety spectacles goggles faceshields visors Head Hazards impact from falling or flying objects risk of head bumping hair entanglement Options a range of helmets and bump caps Breathing Hazards dust vapour gas oxygen deficient atmospheres Options disposable filtering facepiece or respirator half or full face respirators air fed helmets breathing apparatus Protecting the body Hazards temperature extremes adverse weather chemical or metal splash spray from pressure leaks or spray guns impact or penetration contaminated dust excessive wear or entanglement of own clothing Options conventional or disposable overalls boiler suits specialist protective clothing eg chain mail aprons high visibility clothing Personal Protective Equipment at Work Regulations 1992 2 of 5 pages Health and Safety Executive Hands and arms Hazards abrasion temperature extremes cuts and punctures impact chemicals electric shock skin infection disease or contamination Options gloves gauntlets mitts wristcuffs armlets Feet and legs Hazards wet electrostatic build up slipping cuts and punctures falling objects metal and chem
50. endly version of leaflet INDG1 36 rev4 revised 06 09 Myth Of course it s safe we ve always done it this way Reality Some diseases take years to develop If exposure is high because the task has always been done that way maybe it s time for a change Introduction This leaflet describes how to control hazardous substances at work so that they do not cause ill health It will helo you understand what you need to do to comply with the Control of Substances Hazardous to Health COSHH Regulations 2002 as amended which apply to the way you work with these substances If you run a small business or are self employed you need this information to make sure you are protecting your employees If you run a medium sized or large business where decisions about controlling hazardous substances are more complex you will also need professional advice The leaflet will also be useful for trade union and employee health and safety representatives Why do I need to read this leaflet Every year thousands of workers are made ill by hazardous substances contracting lung disease such as asthma cancer and skin disease such as dermatitis These diseases cost many millions of pounds each year to E industry to replace the trained worker E society in disability allowances and medicines and E individuals who may lose their jobs You as the employer are responsible for taking effective measures to control exposure an
51. ety Executive Assessing suitable PPE To allow the right type of PPE to be chosen carefully consider the different hazards in the workplace This will enable you to assess which types of PPE are suitable to protect against the hazard and for the job to be done Ask your supplier for advice on the different types of PPE available and how Suitable they are for different tasks It may be necessary in a few particularly difficult cases to obtain advice from specialist sources and from the PPE manufacturer Another useful source of information is the British Safety Industry Federation www bsif co uk Consider the following when assessing whether PPE is suitable m s it appropriate for the risks involved and the conditions at the place where exposure to the risk may occur For example eye protection designed for providing protection against agricultural pesticides will not offer adequate face protection for someone using an angle grinder to cut steel or stone E Does it prevent or adequately control the risks involved without increasing the overall level of risk m Can it be adjusted to fit the wearer correctly E Has the state of health of those who will be wearing it been taken into account m What are the needs of the job and the demands it places on the wearer For example the length of time the PPE needs to be worn the physical effort required to do the job and the requirements for visibility and communication m f more than one it
52. ge skin while others pass through it and damage other parts of the body Skin gets contaminated by direct contact with the substance eg if you touch it or dip your hands in it by splashing by substances landing on the skin eg airborne dust by contact with contaminated surfaces this includes contact with contamination inside protective gloves Exposure by swallowing People transfer chemicals from their hands to their mouths by eating smoking etc without washing first Exposure to the eyes Some vapours gases and dusts are irritating to eyes Caustic fluid splashes can damage eyesight permanently Exposure by skin puncture Risks from skin puncture such as butchery or needlestick injuries are rare but can involve infections or very harmful substances eg drugs Working with substances hazardous to health 2 of 10 pages Health and Safety Executive Safety data sheets European symbols Products you use may be dangerous for supply If so they will have a label that has one or more hazard symbols S These products include common substances in Toe Very toxic Harul itani everyday use such as paint bleach solvent or fillers When a product is dangerous for supply by law the supplier must provide you with a safety data sheet Note medicines pesticides and cosmetic products have different legislation and don t have a ale P Explosive SO to safety data sheet Ask the supplier how the product t i t
53. ght and do not expose to temperatures exceeding 50 Celsius Extremes of temperature can occur in motor cars and near ovens and fireplaces Do not place in contact with hot surfaces or near naked flames Materials to Avoid None known Hazardous Decomposition Products The product is stable and unreactive under normal household conditions of use Aerosol Furniture Polish 11 12 13 14 TOXICOLOGICAL INFORMATION See also Sections 2 and 3 This product possesses no known toxicological hazards when used as directed ECOLOGICAL INFORMATION See also Sections 6 7 13 and 15 Page 5 of 6 Butane is a volatile gaseous and will partition to the air phase If released to air it will disperse rapidly Photochemical degradation in air will proceed at a moderate rate Considered by the United Nations as less important in the formation of episodic ozone DISPOSAL CONSIDERATION Disposal Methods Consumer Instructions Bulk Quantities Containers may be disposed of by consumers in the normal household waste stream Do not pierce or burn after use Protect from sunlight and do not expose to temperatures exceeding 50 C Dispose of in accordance with local regional or national requirements For further information contact your local waste authority TRANSPORT INFORMATION UN Number International Transport Sea IMDG Class Proper Shipping Name Air ICAO IATA Class Proper Shipping Name Land
54. gs Put an enclosure around the wheel and extract the air to a safe place Ventilated welding helmet gloves Washing facilities Put an enclosure around the lathe and extract the air to a safe place Protective gloves Use an enclosure to extract air to a safe place High efficiency vacuum cleaner Working with substances hazardous to health used rags Check the airflow indicator Make sure the extraction works Work outdoors upwind of the fume wherever possible Allow the fume to clear before removing helmet Use skin care products Make sure the extraction works Allow time for the mist to clear from the enclosure before opening it Cut and polish worktops inside an enclosure Vacuum up dust Safe disposal Maintain controls Test controls as required by law Check if there is any lead paint on the scrap being cut Carry out health checks Train workers Check and maintain fluid quality Test controls as required by law Carry out health checks Test and maintain controls Carry out health checks 4 of 10 pages Myth They wouldn t sell it to us if it wasn t safe Reality Just because something is available CON 010 Ame elo Smale mean it is safe you can buy cyanide for industrial use Health and Safety Executive Choosing control measures In order of priority Eliminate the use of a harmful product or substance and use a safer one Use a s
55. ical splash abrasion Options safety boots and shoes with protective toe caps and penetration resistant mid sole gaiters leggings spats Training m Make sure anyone using PPE is aware of why it is needed when it is to be used repaired or replaced and its limitations E Train and instruct people how to use it properly and make sure they are doing this E Because PPE is the last resort after other methods of protection have been considered it is important that users wear it all the time they are exposed to the risk Never allow exemptions for those jobs which take just a few minutes m Check regularly that PPE is being used and investigate fully any reasons why it is not Safety signs can be useful reminders to wear PPE Maintenance Make sure equipment is m well looked after and properly stored when it is not being used for example in a dry clean cupboard or in the case of smaller items such as eye protection in a box or case E kept clean and in good repair follow the manufacturer s maintenance schedule including recommended replacement periods and shelf lives Simple maintenance can be carried out by the trained wearer but more intricate repairs should only be done by specialists Make sure suitable replacement PPE is always readily available CE marking Ensure any PPE you buy is CE marked and complies with the requirements of the Personal Protective Equipment Regulations 2002 The CE marking signifies
56. ices Caerphilly Business Park Caerphilly CF83 3GG This document contains notes on good practice which are not compulsory but which you may find helpful in considering what you need to do This document is available in priced packs of 15 from HSE Books ISBN O 7176 6141 5 Single free copies are also available from HSE Books Crown copyright This publication may be freely reproduced except for advertising endorsement or commercial purposes First published 08 05 Please acknowledge the source as HSE Published by the Health and Safety Executive INDG174 rev1 08 05 5 of 5 pages Health and Safety Executive SR COSHH essentials for service and retail self employed and franchisees comply with the Control of Substances Hazardous to Health Regulations 2002 COSHH as amended to control exposure and protect workers health AS EN This information will help f a gt employers including the LE gt ng al a he ae It is also useful for trade union safety representatives This sheet describes good practice using general ventilation It covers the points you need to follow to reduce exposure to an adequate level It is important to follow all the points or use equally effective measures Some chemicals can be flammable so your controls must suit those hazards too Look at the safety data sheet for more information Main points m Safe storage segregate chemicals that might react
57. ilation LEV and personal protective equipment PPE Local exhaust ventilation LEV If you use local exhaust ventilation to control exposure it needs regular checking and thorough examination and testing at least once a year Many people eg engineers or insurance companies can carry out thorough examination and testing of LEV Whoever does the work must be competent see Getting help Personal protective equipment PPE Personal protective equipment is often used as part of control measures This also needs checking and maintenance because if it fails it no longer provides protection and exposes the wearer to danger The users need to know exactly what they are doing and so do the supervisors PPE suppliers trade associations and HSE Infoline can tell you about training in how to use it properly See Getting help and Further information Checklist for good control practice Do you design and run your processes to keep the spread of contaminants as low as possible _ Do you think about all routes of exposure breathing in on skin or swallowing Do you choose control measures according to the amount of substance how it gets into the body and how much harm it will cause _ Do you make sure that measures are effective easy to use and work properly Do you also need to issue personal protective equipment PPE Do you check regularly that measures continue to work and keep simple r
58. ing occurs or if blood tinged vomitus is present seek medical advice Inhalation Go into open air and ventilate suspected area If irritation is experienced mouth and throat may be rinsed with water Particles adhering to the nasal cavity may be rinsed diluted with saline plain water If irritation or asthma like symptoms persist seek medical advice 5 Fire fighting measures Not explosive Not auto flammable Not flammable The product itself will not burn If anything packaging may be involved in a fire Use CO2 dry chemical powders or alcohol resistant foam If water is used contain run off Filename MSDS_Professional Ariel Non Bio Rgular Powder doc Page 1 of 2 Reference LMLC 68MHF8 PA0003917 19 Procter amp Gamble P amp G Professional Europe SAFETY DATA SHEET 2001 58 EC CPGO9 Issue 6 Issue Date February 21 2005 Valid until superseded Item code 45 107d 6 Accidental release Avoid spillage into sewers or surface water For large spills scoop up product measures mechanically ideally with vacuum cleaner and rework dispose as per local legislation For small spills product can be washed away with plenty of water 7 Handling and storage Assure adequate dust control Store in a cool and dry area 8 Exposure controls Not a hazard in normal use No personal protective equipment required Personal protection 9 Physical and chemical Appearance white powder properties Odour perfume OH 10 aqueous sol
59. ion Repeated and prolonged exposure to high concentration of vapour may result in central nervous system damage When vapour exposure is low there are no adverse effects Ingestion May irritate digestive tract and cause nausea vomiting and diarrhoea drowsiness and swelling of stomach Aspiration of liquid causes pulmonary edema chemical pneumonia 4 FIRST AID MEASURES Eye Contact Rinse thoroughly with copious amounts of water If in any doubt obtain medical attention Skin Contact Wash affected areas thoroughly with water using soap Inhalation Move victim to fresh air and keep in rest If in any doubt obtain medical attention Ingestion Do not induce vomiting Seek medica attention 5 FIRE FIGHTING MEASURES Specific Dangers This preparation is flammable and will support combustion Combustion produces toxic gases Extinguisher Type Use a dry chemical alcohol resistant foam water spray DO NOT USE WATER JET Amended 27 November 2001 Brasso Liquid Page 3 of 6 6 ACCIDENTAL RELEASE MEASURES See also Sections 8 and 13 Remove all sources of ignition and if possible ventilate the area Small spillages up to 1 litre may be cleaned up with a mop or absorbent cloth Medium spillages up to 5 litres may be absorbed into sand earth or other inert material and transferred to a suitable container for subsequent disposal Larger spillages contain with sand earth or other inert material Do not pump or release to d
60. isibility clothing safety footwear and safety harnesses Hearing protection and respiratory protective equipment provided for most work situations are not covered by these Regulations because other regulations apply to them However these items need to be compatible with any other PPE provided Cycle helmets or crash helmets worn by employees on the roads are not covered by the Regulations Motorcycle helmets are legally required for motorcyclists under road traffic legislation What do the Regulations require The main requirement of the PPE at Work Regulations 1992 is that personal protective equipment is to be supplied and used at work wherever there are risks to health and safety that cannot be adequately controlled in other ways The Regulations also require that PPE is properly assessed before use to ensure it is suitable is maintained and stored properly is provided with instructions on how to use It safely and is used correctly by employees Can I charge for providing PPE An employer cannot ask for money from an employee for PPE whether it Is returnable or not This includes agency workers if they are legally regarded as your employees If employment has been terminated and the employee keeps the PPE without the employer s permission then as long as it has been made clear in the contract of employment the employer may be able to deduct the cost of the replacement from any wages owed 1 of 5 pages Health and Saf
61. it likely that harm could arise are harmful when there is little chance of it escaping the risk Is low because of the way you use or But the risk in a different task such as cleaning up and disposal produce it will be higher because the harmful substance may be breathed in or C What are you going to do about it get onto the skin Use something else Use it in another safer way When the task involves larger amounts of material with obvious Control it to stop harm being leaks exposure is higher and so is the risk Whether the substance caused is harmful or not your need to control it is obvious Decide what measures you need to take and when Working with substances hazardous to health 3 of 10 pages Health and Safety Executive If you have five or more employees you must record your assessment but even if Myth What do you you have fewer than five it makes sense to write down what steps you have taken expect it s a dirty to identify the risks And the really important part is making a list of the actions job you are taking to control the risks to health You can look at examples of risk assessments for different industries on www hse gov uk risk casestudies Reality Why does your job need to be dirty Think about changing the way you work to produce cleaner processes HSE has developed a free internet tool for identifying good control practice www coshh essentials org uk It covers a wide range
62. l handling use equipment for handling don t use the hands as tools use a Safe working distance You will also need to protect the skin This is particularly important if the steps above aren t practical or aren t enough to totally avoid contact You can protect the skin by the following tell workers how to look after their skin remind them to wash any contamination from their skin promptly tell them about the importance of thorough drying after washing provide soft cotton or paper towels supply moisturising pre work and after work creams provide appropriate protective clothing gloves make sure gloves are made of suitable material select gloves that are the right size and right for the task to be done use and store gloves correctly replace gloves when necessary You will also need to make sure regular skin checks are carried out to look for early signs of dermatitis Regular skin checks can spot the early stages of dermatitis Early detection can prevent more serious dermatitis from developing Steps can be taken to start treating the condition Checks can help indicate a possible lapse in your preventative measures and the need to reassess the situation Preventing contact dermatitis at work 2 of 3 pages Health and Safety Executive What does the law require The law requires employers to adequately control exposure to materials in the workplace that cause ill health like dermatitis E
63. lassified as potentially causin long term adverse effects in the aquatic environment l DISPOSAL CONSIDERATION Consumer Instructions Containers may be disposed of by consumers in the normal domestic waste stream Bulk Quantities Containers can be disposed of in accordance with all applicable local regional and national requirements Operators should be informed that the product contains white spirit For further information contact your local waste authority TRANSPORT INFORMATION UN Number UN 1993 Sea IMDC Class 3 3 Packing Group iL Proper Shipping Name Flammable Liquid N O S contains TURPENTINE SUBSTITU Road ADR RID Class 3 Item Number 31 C Proper Shipping Name Flammable Liquid N O S contains TURPENTINE SUBSTITU imended 27 November 2001 Brasso Liquid Page 6 of 6 Air ICOA Class 3 Packing Group III Proper Shipping Name Flammable Liquid N O S contains TURPENTINE SUBSTITIUTE National transport regulations may apply 15 REGULATORY INFORMATION This product is classified as dangerous for supply in the EU as follows Risk Phrase R10 Flammable Safety Phrases S2 Keep out of reach of children S46 If swallowed seek medical advice immediately and show this container or label S62 part of If swallowed do not induce vomiting The following Directives are relevant to the above classification and labelling of this preparation Council Directive 88 379 EEC of 7 June 1988 on the app
64. likely to be irritant in normal use Inhalation Unlikely to be irritant in normal use Ingestion Unlikely to be irritant in normal use 12 ECOLOGICAL INFORMATION Ingredients according to EC 89 542 Less than 5 Anionic surfactants Less than 5 Nonionic surfactants 13 DISPOSAL CONSIDERATIONS This product does not contain any prescribed substance under the Environmental Protection Act Prescribed Processes and Substances Regulations 1991 and is not classified as special waste under the Control of Substances Special Waste Regulations 1996 but is classified as controlled waste under the Environmental Protection Act 1990 For small quantities dilute with water to at least 5 w v 50 g litre and pour down a wastewater drain foul sewer Rinse out containers at least twice and recycle if facilities exist or dispose of as commercial waste For larger quantities dispose of safely as commercial waste European waste catalogue 20 01 29 Detergents containing dangerous substances 14 TRANSPORT INFORMATION EEC Regulation Not regulated IMDG UN Not regulated RID ADR Not regulated ICAO IATA Not regulated 15 REGULATORY INFORMATION Hazard symbol None required Risk phrases None required Safety phrases S2 Keep out of reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 16 OTHER INFORMATION Handle and apply only as recommended for full information
65. lows you to search for consultants United Kingdom Accreditation Service UKAS 21 47 High Street Feltham Middlesex TW13 4UN Tel 020 89178400 www ukas com The UKAS website has a search function to find accredited testing and inspection service providers m Trade associations Health and safety information is often produced by trade associations and published in the trade press E Occupational health professionals doctors or nurses Look in Yellow Pages or other trade indexes for occupational health under Health and Safety Consultants or Health Authorities and Services or visit www nhsplus nhs uk m Safety Groups UK SGUk Edgbaston Park 353 Bristol Road Edgbaston Birmingham B5 7ST Tel 0121 248 2011 www safetygroupsuk org uk Working with substances hazardous to health 8 of 10 pages Health and Safety Executive Find out more A short guide to the Personal Protective Equioment at Work Regulations 1992 Leaflet INDG174 rev1 HSE Books 2005 single copy free or priced packs of 15 ISBN 978 O 7176 6141 1 www hse gov uk pubns indg1 74 pdf Clearing the air A simple guide to buying and using local exhaust ventilation LEV Leaflet INDG408 HSE Books 2008 single copy free or priced packs of 15 ISBN 978 O 7176 6301 9 FH40 2005 Workplace exposure limits Containing the list of workplace exposure limits for use with the Control of Substances Hazardous to Health Regulations 2002 as amended Environmental Hygiene Gui
66. mployers and employees need to comply with the Control of Substances Hazardous to Health Regulations 2002 as amended COSHH They require employers to assess risks provide adequate control measures ensure the use and maintenance of these provide information instruction and training and in appropriate cases health surveillance Where can I get more detailed information on the topics outlined Skin disease Skin diseases preventing skin disease legislation and other control information www hse gov uk skin www bsif co uk Catering HSE are developing catering web pages during 2007 Construction General construction information www hse gov uk construction Hairdressing Good practice advice www badhandday hse gov uk Metalworking fluids Good practice advice www hse gov uk metalworking ecoshh Printing Good practice advice www hse gov uk printing dermatitis Further information HSE priced and free publications are available by mail order from HSE Books PO Box 1999 Sudbury Suffolk CO10 2WA Tel 01787 881165 Fax 01787 313995 Website www hsebooks co uk HSE priced publications are also available from bookshops and free leaflets can be downloaded from HSE s website www hse gov uk For information about health and safety ring HSE s Infoline Tel 0845 345 0055 Fax 0845 408 9566 Textphone 0845 408 9577 e mail hse infoline natbrit com or write to HSE Information Services Caerphilly Business Park Caerphilly CF83 3GG
67. n Preparation Information on Hazardous Ingredients Chemical name CAS No EC Number Naphtha petroleum hydrotreated light 64742 49 0 10 30 265 151 9 R11 R51 53 R65 Occupational Exposure Limit s if available are listed in Section 8 3 HAZARDS IDENTIFICATION Physical chemical hazards No physical or chemical hazards have been reported or known Human health hazards This product is not dangerous according to the EU regulations 67 548 EEC 88 379 EEC Environmental hazards This preparation contains some materials classified as Dangerous to the Environment Use only as directed 4 FIRST AID MEASURES Effects and symptoms Inhalation None known Ingestion None known Skin contact May be mildly irritating to skin Eye contact May be mildly irritating to eyes First aid measures Inhalation No specific first aid measures are required Ingestion No specific first aid measures are required Skin contact Rinse with plenty of running water Eye contact Immediately wash out with water If irritation develops get medical attention 5 FIRE FIGHTING MEASURES Extinguishing media Dry chemical carbon dioxide Special fire fighting procedures Fight fire from protected location or maximum possible distance In case of fire and or explosion do not breathe fumes Unusual fire explosion hazards Carbon oxides may be formed Aerosol product Containers may rocket or explode in heat of fire 6 ACCIDENTAL RELEA
68. ned breathing apparatus and suitable protective clothing including gloves and eye face protection 6 Accidental Release Measures Wear suitable gloves and eye face protection Isolate the spillage Absorb onto dry sand or absorbent granules Scoop up and place in sealed bins to be disposed of by licensed waste management company Wash area down with plenty of clean water 7 Handling and Storage Contact with eyes and prolonged contact with skin should be avoided Wash and dry hands after use Do not mix with any other chemicals Store upright in original closed containers away from extremes of temperature 8 Exposure Control Personal Protection Hands Use rubber or chemical resistant gloves Eyes When handling neat product or concentrated solutions wear eye face protection to BS 2092C Skin Personal protection is not normally required unless a risk assessment indicates the need for it Respiration When the product is used as directed personal protective equipment is not required unless a risk assessment indicates the need for it OES MEL Methoxy propanol OES 100ppm 8 hr TWA sk Page 1 of 2 9 Physical and Chemical Properties Appearance Fluroscein Boiling Point 100 C Relative Density 1 055 1 065 Odour Lemon Melting Point 0 C Solubility Completely soluble pH gt 13 Flash Point None 10 Stability and Reactivity Product is stable Provided the product is stored in accordance with the guideline in section 7 there a
69. ng used properly Consider substituting with safer products Manual cleaning and disinfecting surfaces Harm via skin or eye contact Access and premises Mark any pedestrian routes that can become slippery when wet Y Provide good washing facilities Equipment Y Y Do you need colour coded cloths mops and buckets to minimise cross contamination Provide protective gloves Remove heavy dirt deposits first Caution Never decant concentrate into an unlabelled container Never re use a concentrate container dispose of it safely or return it to your supplier Don t store more than 50 litres of flammable liquid indoors use a flammable store Personal protective equipment PPE Y Follow the instructions on product labels Y Ask your supplier to help you choose the right PPE Provide protective gloves single use gloves are acceptable If you must use latex gloves use only low protein powder free gloves Throw away single use gloves every time they are taken off Provide waterproof slip resistant footwear Y Skin creams are important for skin condition These help in washing contamination from the skin After work creams help to replace skin oils Caution barrier creams do not make a full barrier Procedures Y Y Store products securely in a cool dry dark place capable of keeping in spills Don t store far more than you need Y Y Ensure that workers follow the instructions for
70. nhaled chronic Not known effect 12 ECOLOGICAL INFORMATION This product is inactive when diluted in sewerage and sludge and complies with EC regulations 13 DISPOSAL CONSIDERATIONS Spillages See Accidental Release Measures section 6 Waste Dispose of solutions or materials contaminated using a licensed contractor in accordance with Waste Disposal Regulations 14 TRANSPORT INFORMATION UN No 1791 Hazardous class 8 Packaging group lll 15 REGULATORY INFORMATION Relevant Statutory Instruments Labelling in accordance with EEC Directive Irritant Risk Phases 31 Contact with acids liberates toxic gases 36 38 Irritating to eyes and skin Safety Phases 2 Keep out of reach of children 26 In case of contact with eyes rinse immediately with plenty of water and seek medical attention 37 39 Wear suitable gloves and eye face protection 16 OTHER INFORMATION 3 PRODUCT WIPE OVER perfumed disinfecting spray cleaner Page 2 of 4 FIRE FIGHTING MEASURES Not flammable aqueous solution containing a substantial proportion of water In case of major fire plastic bottles may collapse or break due to pressure build up and plastic softening or melting thus releasing their liquid content in this case harmful or irritant fumes decomposition products may be produced as with any organic material Avoid release of large spills into the aquatic environment ACCIDENTAL RELEASE MEASURES Do not wash
71. nical knowledge of the product concerned and is given in good faith The attention of end users is drawn to amongst other things the element of risk consequent to use of the product for a purpose other than that for which it was intended In no way does this document remove the need of the user of the product to fully understand and apply statutory requirements It is user s sole responsibility to take due precautions relative to the use made of the product All information contained herein is included only to assist the reader in fulfilling his or her statutory duty connected with the use of hazardous materials This list of information must not be considered as exhaustive and does not exonerate the reader from taking precautions described in documents other than those mentioned concerning the storage and use of the product for which he or she remains the sole person responsible SHEEN is a Trademark VEVES Cores 5q E030 PRODUCT SAFETY DATA SHEET PRODUCT AJAX Double Solvent Antistatic Triple Action Blue Page 1 of 4 window cleaner spray Reference 29 1017 date 08 Aug 03 IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY 1 1 Product identification AJAX Double Solvent Antistatic Triple Action Blue 1 2 Product use liquid window cleaner spray 1 3 Company Identification COLGATE PALMOLIVE Guildford Business Park Middleton Road Guildford GU2 8JZ 1 4 Emergency Phone
72. not liable to occur with product in bulk after excessive inhalation of mist keep the person quiet and remove to fresh arr 6 ACCIDENTAL RELEASE MEASURES Personnel Precautions Avoid skin contact and wear protective equipment Environmental Precautions Do not allow to enter natural water courses Methods for Cleaning Up Wash small spillages away to the drain Contain large spillages with sand or earth DISPOSE OF IN ACCORDANCE WITH LOCAL AUTHORITY REGULATIONS aaa E e protection if splashing is possible 8 EXPOSURE CONTROLS PERSONAL PROTECTION Vapour Pressure at C Not applicable Not applicable Flammability Not applicable Auto Flammability Not applicable Relative density 1 05 1 15 10 STABILITY AND REACTIVITY Stability Avoid extreme heat Conditions to Avoid See Handling and Storage Materials to Avoid All acids Hazardous decomposition Hydrogen Chloride and Chlorine released during thermal decomposition 11 TOXICOLOGICAL INFORMATION Effect of Substance On Eyes Liquid severe damage even on short duration Vapour irritation Liquid severe irritation and burns if contact prolonged Vapour little or no effect By Skin Absorption No systemic effects by any route of exposure Severe irritation and corrosion of the mouth throat and digestive tract By Ingestion Exposure to the mist or spray causes irritation of the nose throat and respiratory tract When Inhaled acute effect When I
73. nto the eyes it may cause transient mild to moderate irritation stinging Rinse immediately with plenty of water for at least 5 minutes In case any irritation persists seek medical advice Ingestion If accidental ingestion should occur it may cause emesis or if not a mild mucosal irritation Drink water or milk Do not induce vomiting If any sympoms persist seek medical advice Inhalation If irritation should occur rinse mouth and throat with water and move to fresh air If any irritation persists or asthma like symptoms occur seek medical advice The product itself will not burn If anything packaging may be involved in a fire Use CO3 dry chemical powders or alcohol resistant foam Avoid spillage into sewers or surface water For small spills sluice to drain 41 with plenty of water For large spills pump into plastic containers and _ rework dispose of as per local legislation s Landing and stora Ges Store in a cool and dry area Provide sufficient ventilation Spray bottle dilution instructions Dosage 7 5ml Flash All Purpose per 600ml water From 2L bottle 7 5ml cap added to 600ml water From 5L bottle 7 5ml cap added to 600ml water e ENDOS ee ont rois E 7 Not a hazard in normal use For prolonged or repeated contact protection of Personal p protectic the skin may be necessary Rinse and dry hands thoroughly after each Hn cleaning job Before and after prolonged usage it
74. o use respirators they also need face fitting and training m If they need to use protective gloves they need to know how to put them on and take them off without contaminating their skin See Find out more Keeping workers healthy Monitoring exposure Monitoring normally means air sampling but it may also involve taking biological samples eg breath or urine Monitoring normally makes reference to Workplace Exposure Limits WELs published by HSE These limits should not be exceeded see EH4O in Find out more It is wasteful to try monitoring before you have put any control measures in place see COSHH essentials sheet G409 www hse gov uk pubns guidance g409 pdf on air monitoring Health checks If your trade press HSE or other information shows there is a problem with health in your trade such as asthma or dermatitis your employees may need special health checks The most common checks are for respiratory disease such as asthma and skin disease See Find out more REACH REACH is a new European Union regulation concerning the Registration Evaluation Authorisation and restriction of CHemicals It came into force on 1 June 2007 and replaces a number of European Directives and Regulations with a single system REACH will operate alongside COSHH and is designed so that better information on the hazards of chemicals and how to use them safely will be passed down the supply chain by chemical manufacturers an
75. off splashes immediately Ensure that workers follow instructions for use by reading the label and make up solutions for immediate use only Make sure they are aware of the following general guidelines m Add liquid concentrate to diluting liquid never the other way round unless the instructions say so m Make a thin paste of powders with a small amount of diluting liquid then dilute as for liquids Put the cap back on the container immediately and wipe the outside clean Service and retail SR2 Harm via skin or eye contact Special care Y Contact with many chemicals can lead to dermatitis Some can also damage the eyes Y Y Some products may cause asthma check the safety data sheet Y Avoid products that contain hydrofluoric acid Take special care using caustic soda sodium hydroxide This can erupt when mixed with water Splashes in the eye can cause blindness Y Y Never add any other chemical to concentrates that contain bleach sodium hypochlorite solution This can cause a dangerous gas chlorine to be given off Maintenance examination and testing Wash out mixing equipment after use Dispose of waste liquid safely Personal protective equipment PPE Y Follow the instructions on product labels Y Ask your supplier to help you choose the right PPE Provide protective gloves single use nitrile gloves are acceptable If you must use latex gloves use only low protein powder free gloves Throw
76. olourless Odour Characteristic Solubility Very slightly soluble in cold water pH Not available Specific gravity 0 926 Intermediate Flash point Not applicable Viscosity 900 1200 cP Dynamic 10 STABILITY AND REACTIVITY Stability The product is stable Conditions to Avoid Excessive heat Hazardous Reactions None known Hazardous decomposition products None known 11 TOXICOLOGICAL INFORMATION Acute Toxicity LD5 estimated to be gt 2000 mg kg Local effects Skin irritation See section 4 Eye irritation See section 4 Sensitization None known Chronic toxicity None known Specific effects Carcinogenicity None known Mutagenicity None known Reproduction toxicity None known 12 ECOLOGICAL INFORMATION This preparation contains some materials classified as Dangerous to the Environment Use only as directed 13 DISPOSAL CONSIDERATIONS Methods of disposal Disposal according to the local legislation 14 TRANSPORT INFORMATION International transport regulations UN number UN1950 Packing group None Land Road Railway Proper shipping name Limited quantity of 1950 aerosols ADR RID Class 2 ADR RID Item number SA Sea Proper shipping name Limited quantity of 1950 aerosols IMDG Class 2 1 Medical First Aid Guide MFAG 620 Emergency Schedules EmS 2 13 Marine pollutant None 15 REGULATORY INFORMATION National regulations Belgium No additi
77. onal national regulations are known to the supplier EU Regulations EU Classification Classified as non hazardous according to current legislation 67 548 EEC 88 379 EEC Additional label phrases Use only as directed Keep out of the reach of children Pressurized container protect from sunlight and do not expose to temperatures in excess of 50 C Do not pierce or burn even after use Do not spray on naked flames or on incandescent material Keep away from sources of ignition No smoking 20 BY MASS OF THE CONTENTS ARE FLAMMABLE Date of issue 21 Jul 2000 Version 1 Page 2 3 SAFETY DATA SHEET Pledge Furniture Polish Aerosol Natural EINECS Status All components are included in the EINECS inventories 16 OTHER INFORMATION Detergent Cleaner Labelling Not applicable 89 542 EEC HISTORY Date of printing 07 Nov 2000 Date of previous issue 28 Apr 1998 The information provided in this Safety Data Sheet is correct to the best of our knowledge at the date of issue and covers applications when used as directed MATERIAL SAFETY DATA SHEET Reference HSSHAER Creation date 27 November 2001 Page 1 of 6 1 IDENTIFICATION OF THE PRODUCT AND THE COMPANY PRODUCT AEROSOL FURNITURE POLISH BUTANE An aerosol product for cleaning and polishing surfaces in the home Company Reckitt Benckiser UK Ltd Delta 1200 Welton Road Delta Business Park Swindon Wiltshire SN5 7XZ Tel 01793 732000 Fax 01793 5115
78. ot Iceni csc to ADR IATAJMDG This product is not iicancls as dangerous according to EU Directive 1999 45 EC and national laws All substances in the preparation are registered in the EU 16 Other information This product does not require any special training before use Usage and handling instructions are mentioned on package and on this Material Safety Data Sheet 15 Regulatory im Filename MSDS_Professional Ariel Non Bio Rgular Powder doc Page 2 of 2 Reference LMLC 68MHF8 PA00039119 SAFETY DATA SHEET S20 1 I DENTI FI CATI ON OF THE PREPARATION AND COMPANY PRODUCT CODE J002 PRODUCT NAME S20 MANUFACTURER Selden Research Limited TELEPHONE 01298 26226 Staden Lane FAX 01298 26540 Ashbourne Road EMAIL safety selden co uk Buxton Derbyshire SK17 9RZ 2 COMPOSI TI ON INFORMATION ON INGREDIENTS NAME EI NECS Nr CLASSI FI CATI ON CONTENT POTASSIUM HYDROXIDE 215 181 3 C R35 Xn R22 5 10 SODIUM HYDROXIDE 215 185 5 C R35 10 30 The full text for all R Phrases are displayed in Section 16 HAZARDS DENTI FICATION R35 Causes severe burns FIRST AlD MEASURES GENERAL Chemical burns must be dealt with immediately do not delay CAUTION First Aid personnel must be aware of own risk of burns I NHALATI ON Remove victim immediately from source of exposure Provide rest warmth and fresh air Get medical attention if any discomfort continues I NGESTI ON DO NOT INDUCE VOMITING Rinse mouth
79. out large spills into the drain contain and collect in containers for subsequent handling by a specialist for appropriate treatment and disposal use of an inert absorbent may be helpful Use of gloves is recommended goggles may be useful to avoid splashes in the eyes Wash off the minor quantities remaining on the floor with copious amounts of water into the drain Note the neat product can render floors slippery HANDLING AND STORAGE 7 1 Handling no particular recommendations 7 2 Storage keep out of excessive heat to avoid bottle bulging and eventually leaks keep above freezing temperature EXPOSURE CONTROLS PERSONAL PROTECTION no particular recommendations PHYSICAL AND CHEMICAL PROPERTIES Appearance colourless clear thin liquid Odour perfumed liquid lavender pH 10 5 0 2 as is Relative density 1 04 Solubility fully miscible in water Viscosity same as water PRODUCT WIPE OVER perfumed disinfecting spray cleaner Page 3 of 4 STABILITY AND REACTIVITY Stable in normal conditions No hazardous reactions expected TOXICOLOGICAL INFORMATION in case of accidental ingestion of a small quantity transient gastro intestinal effects discomfort may occur but no acute harmful effects are anticipated As with any aerosol or spray delivered product projection into the eyes will cause irritation excessive inhalation of the mist can cause spontaneous coughing Skin irritation may occ
80. rain Do not contaminate watercourses or ground If necessary pump to a safe place Consult your local Water Authority Environmental Protection Agnecy local council or an expert for advice on disposal 7 STORAGE AND HANDLING Handling Wear suitable gloves if long or repeated exposure to the product is anticipated Storage Store in a cool dry frost free place away from sources of ignition and out of reach of children 8 EXPOSURE CONTROLS PERSONAL PROTECTING MEASURES See also Section 7 The following limits are taken from the UK Document EH40 Occupational Exposure Limits This product contains white spirit which has an Occupational Exposure Limit of OELsol 600mg m 8 hour Time Weighted Average Avoid contact with skin and eyes Do not breathe fumes Respiratory Protection None necessary under normal working conditions Hand Protection Wear rubber gloves if exposure is likely to be prolonged Eye Protection None necessary under normal working conditions Skin Protection Wear an apron or coveralls if exposure is likely to be prolonged Amended 27 November 2001 asso Liquid Page 4 of 6 PHYSICAL AND CHEMICAL PROPERTIES Appearance Viscous liquid Odour Ammonia pH Value 11 0 Flash Point of Contents 38 42C STABILITY AND REACTIVITY Conditions to Avoid Protect from sources of ignition Materials to Avoid Strong oxidising agents Incomplete combustion produces toxic gases Brasso Liquid is sta
81. rcial waste 7 HANDLING amp STORAGE Avoid contact with skin and eyes Do not mix with any other chemicals other than as advised by your JohnsonDiversey representative Store upright in original closed containers in a cool place out of direct sunlight ensuring that the vents remain effective 8 EXPOSURE CONTROL PERSONAL PROTECTION Hand Personal protection is not normally required unless a risk assessment indicates the need for it Eyes Personal protection is not normally required unless a risk assessment indicates the need for it Skin Personal protection is not normally required unless a risk assessment indicates the need for it Respiration Personal protection is not normally required unless a risk assessment indicates the need for it OES MEL Hydrogen Peroxide Dihydrogen Dioxide ref HSE publication EH40 O E S 2 8 mg cu m 15 min ref time O E S 1 4 mg cu m 8 hour TWA 9 PHYSICAL amp CHEMICAL PROPERTIES Appearance Clear colourless liquid Odour Characteristic pH 6 9 7 3 Solubility Fully miscible in water Date 07 01 2003 Revision Number Page 1 of 2 Product Name ENHANCE SPOT amp STAIN REMOVER Product Code 683953 Density 1 00 g cn Other Viscosity dynamic lt 5 cps 10 STABILITY amp REACTIVITY Provided the product is stored in accordance with the approved guidelines there are no known hazardous decomposition products 11 TOXICOLOGICAL INFORMATION Eyes Unlikely to be irritant in normal use Skin Un
82. re a list of replaceable parts a description of how operators should use the system so it works effectively Remedy defects in good time It is pointless making checks If you take no action when something is wrong And you are not managing health and safety properly if the thorough examination and test produces a long list of actions needed Keep simple records of your checks and actions eg in a logbook and keep these records for at least five years Staying in control checking and maintaining Once you ve got control you need to keep it As the employer you must make sure that the control measures equipment and the way of working keep working properly You should name someone to be in charge of checking and maintaining control measures It could be you or someone you appoint as long as they know what they need to do and are able to do it That is they are competent to m check that the process isn t emitting uncontrolled contaminants m check that the control equipment continues to work as It was designed m check that workers follow the right way of working Working with substances hazardous to health 5 of 10 pages Myth I ve given them all masks problem solved Reality his won t solve it Control the source of exposure and then they might not need masks Health and Safety Executive Two of the most common control measures where maintenance is critical are local exhaust vent
83. re no known hazardous decomposition products 11 Toxicological Information Eyes Irritant Causes irritation and redness Skin May cause irritation and redness on prolonged or repeated contact Inhalation Inhalation of use solution in spray mist will cause irritation of the respiratory tract Ingestion Causes irritation of gastro intestinal tract 12 Ecological Information Product is fully biodegradable 13 Disposal Consideration The product is not classified as hazardous waste under the special waste amendment regulation SI 1996 2019 For disposal contact a licensed waste management company Rinse out containers at least twice with water and recycle if facilities exist or dispose of as commercial waste 14 Transport Information Hazard Class Non hazardous Packing Group HazChem 15 Regulatory Information Hazard Symbol Irritant Risk Phrases R 36 38 Irritating to eyes and skin Safety Phrases S 2 Keep out of the reach of children S 26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S 28 After contact with skin wash immediately with plenty of water Methoxy propanol OES 100ppm 8 hr TWA sk EH40 16 Other Information The MSDS complies with regulation 5 and Schedule 4 of CHIP 3 which implements Article 27 of the Dangerous Substances Directive 67 548 EEC as amended by the Seventh Amendment 92 32 EEC Article 15 of the Dangerous Preparations Directive 1999 45 EC an
84. roximation of the laws regulations and administrative provisions of the Member States relating to the classification packaging and labelling of dangerous preparations Directive 88 379 EEC is implemented in the UK by the Chemicals Hazard Information and Packaging for Supply Regulations 1994 No 3247 16 OTHER INFORMATION BRASSO is a Trademark This document complements the technical usage instructions but does not replace them The information contained herein is based on our best current technical knowledge of the product concerned and is given in good faith The attention of the recipients is drawn to amongst other things the element of risk consequent to use of the product for a purpose other than that for which it was intended In no way does this document remove the need of the recipient of the product to fully understand and apply statutory requirements It is the recipient s sole responsibility to take due precautions relative to the use made of the product All information contained herein is included only to assist the recipient in fulfilling his or her statutory duty connected with the use of hazardous materials This list of information must not be considered as exhaustive and does not exonerate the recipient from taking other precautions described in documents other than those mentioned concerning the storage and use of the product for which he or she remains the sole person responsible Amended 27 November 2001 1 4
85. s What you need to know about the Control of Substances Hazardous to Health Regulations 2002 COSHH Leaflet INDG136 rev3 HSE Books 2005 single copy free or priced packs of 10 ISBN 0 7176 2982 1 Lead and you A guide to working safely with lead Leaflet INDG305 rev1 HSE Books 1998 single copy free or priced packs of 15 ISBN O 7176 1523 5 Noise at work Advice for employers Leaflet INDG362 HSE Books 2002 single copy free or priced packs of 10 ISBN O 7176 2589 7 Selecting protective gloves for work with chemicals Guidance for employers and health and safety specialists Leaflet INDG330 HSE Books 2000 single copy free or priced packs of 15 ISBN O 7176 1827 7 Selection of suitable respiratory protective equioment for work with asbestos Leaflet INDG288 rev1 HSE Books 2008 single copy free or priced packs of 5 ISBN 0 7176 2220 7 Personal Protective Equipment at Work Regulations 1992 4 of 5 pages Health and Safety Executive Further information HSE priced and free publications are available by mail order from HSE Books PO Box 1999 Sudbury Suffolk CO10 2WA Tel 01787 881165 Fax 01787 313995 Website www hsebooks co uk HSE priced publications are also available from bookshops and free leaflets can be downloaded from HSE s website www hse gov uk For information about health and safety ring HSE s Infoline Tel 0845 345 0055 Fax 0845 408 9566 e mail hseinformationservices natbrit com or write to HSE Information Serv
86. s should be well ventilated particularly at low levels The natural ventilation in a large open warehouse building will normally be suitable Aerosol Furniture Polish 10 Page 4 of 6 EXPOSURE CONTROLS PERSONAL PROTECTING MEASURES See also Section 7 Occupational Exposure Limits Aliphatic hydrocarbon average concentration of 1000mg cu m 8 hour Time Weighted Average Refined solvent mineral oil maximum admissible concentration of oil mist in air of 5mg cu m 8 hour Time Weighted Average Butane Long term exposure 8 hour Time Weighted Average is 1430 mg cu m Short term exposure limit 15 minutes is 1780 mg cu m Engineering Controls Avoid contact with skin Do not breathe fumes spray Use only in well ventilated areas Keep away from sources of ignition Provide local exhaust ventilation Personal Protective Equipment Respiratory Protection None necessary if used in well ventilated area Hand Protection Wear rubber gloves if exposure is likely to be prolonged Eye Protection None necessary under normal working conditions okin Protection Wear an apron or coveralls if exposure is likely to be prolonged PHYSICAL AND CHEMICAL PROPERTIES Physical State Pressurised aerosol Odour Perfumed with white spirit type solvent background Flammability The sprayed product is extremely flammable Internal Pressure 45 Psig 3 1 Bar at 25 Celsius STABILITY AND REACTIVITY Conditions to Avoid Protect from sunli
87. see product information sheet Internal Reference MSDS 16 May 2001 Spot amp Stain Remover Text of risk phrases associated with ingredients in section 2 R8 Contact with combustable materials may cause fire R21 22 Harmful by contact with skin and if swallowed R34 Causes burns R36 38 Irritating to eyes and skin Date 07 01 2003 Revision Number Page 2 of 2 Product Specification amp SAFETY DATA SHEET X CHIP EC FORMAT 91 155 EEC AMD 93 112 EC AMD 2001 58 EC PROCHEM B144 STAIN PRO SECTION 1 IDENTIFICATION OF THE PREPARATION AND COMPANY Product Name STAIN PRO Product Code B144 Manufacturer Prochem Europe Ltd Oakcroft Road Chessington Surrey KT9 1RH UK Telephone No 020 8974 1515 UK 44 20 8974 1515 EC Chemical Product ManagerE H amp S Emergency Action In the event of a medical enquiry involving this product please contact your doctor or local hospital accident and emergency department who may seek advice from the UK National Poisons Information Service where our full product details are held pn Stain Pro emma Product Description amp Directions For Use A water based solvent and alkaline spotter for neutralising acidic or oily stains such as most food blood vomit water based inks fresh tea and coffee milk cream and wine on carpet and fabric Scrape or blot up all excess soiling Stain Pro is ready to use Always pretest carpet or fabric for colour fastness an
88. together and contain spills from burst containers Check that all the controls are being used properly J J J J J J J J Storing chemical products small scale Control approach 1 General ventilation Access and premises Ensure that only trained workers have access to stored chemical products Keep the storage container locked Provide good washing facilities Smaller containers Labels facing forward Equipment Keep the store area well ventilated 5 10 air changes per hour with a through draught Keep a spill clean up kit nearby Ask your supplier for advice Caution Never decant concentrate into an unlabelled container Never amp Lipped tray to contain spills ap oe eee A A Large containers re use a concentrate container Dispose of it safely or return it to the supplier Don t store more than 50 litres of flammable liquid indoors Use a flammables store Personal protective equipment PPE Follow the instructions on product labels Ask your safety clothing supplier to help you get the right PPE You may need respiratory protective equipment RPE in case of a spill Seek advice from your RPE supplier Provide protective gloves single use nitrile gloves are acceptable If you must use latex gloves use only low protein powder free gloves Throw away single use gloves every time they are taken off Procedures Keep apart solid and liquid pro
89. uirements OTHER INFORMATION indicate disclaimers here in agreement with legal department e g this SDS has been prepared in accordance with the directive 91 155 EEC including the second commission amendment 2001 58 EC this safety data sheet complements the indications present on the packaging In particular directions for use and warnings stated on labe should be followed this information is based on the best knowledge of Colgate Palmolive at the time of issue of this SDS and is given in good faith but the Company cannot guarantee its accuracy reliability or completeness and therefore disclaims any liability for loss or damage arising out of the use of this data since conditions of use and handling are out of control of Colgate Palmolive the Company disclaims any liability for loss or damage when the product is used for other purposes than it is intended the information contained in this SDS does not constitute any kind of commercial contract or committment msds version 03 preparation date 08 Aug 03 modified sections 5 8 FORMULAS COVERED base number version 02 03 country code dkt0 gr10 pim ref 262811 259578 R PHRASES STATED IN SECTION 2 R11 Highly flammable Irritating to eyes and skin Procter amp Gamble P amp G Professional Europe SAFETY DATA SHEET 2001 58 EC CPGO09 Issue 6 Issue Date February 21 2005 Valid until superseded Item code 45 107d SDS NOTICE Updat
90. um spills Do not wash out large spills into the drain cover with inert absorbent material and remove to disposal container for subsequent handling by a specialist for appropriate treatment and disposal Flush residue with plenty of water Ensure good ventilation during cleaning Use of gloves is recommended goggles may be useful to avoid splashes in the eyes HANDLING AND STORAGE 7 1 Handling no particular recommendations store in a cool dry place Keep above freezing temperature 7 2 Storage EXPOSURE CONTROLS PERSONAL PROTECTION Avoid eye contact Avoid inhalation of vapors during long periods several hours Ensure good ventilation in case of extensive use e g large panes Protective clothing Under normal conditions of use no special protection for eyes or skin is required In processing and packaging operations where skin or eye contact are possible the use of safety goggles and rubber gloves is recommended l Occupational exposure limits Ethyl Alcohol TLV 1000 ppm 1900 mg kg as TWA 8 hours References International Chemical Safety card n 44 ILO INRS France reported as VME TDI amp hours There may be different national occupational exposure limits If it is the case they have to be reported here PRODUCT AJAX Double Solvent Antistatic Triple Action Blue window cleaner spray PHYSICAL AND CHEMICAL PROPERTIES Appearance pale blue
91. ur after prolonged or repeated contact with the product or its solutions LD 50 gt 2000 mg kg body weight based on the toxic contributions of the components ECOLOGICAL INFORMATION Like all laundry and cleaning products this product contains substances which can affect the aqueous environment The product does not present a problem for the environment when used and disposed of under normal conditions The preferred means of waste water disposal is through a municipal sewage treatment plant DISPOSAL Large quantities should be handled by a specialist in the treatment of chemical wastes in accordance with local regulations TRANSPORT INFORMATION to be completed if needed REGULATORY INFORMATION This product is NOT classified as Dangerous according to the Directive 88 379 EEC on the classification packaging and labelling of dangerous preparations The primary biodegradability of the surfactants present in the product is higher than 80 in compliance with Directives 73 404 EEC and 73 405 EEC and amendments 82 242 EEC and 82 243 EEC to be completed eventually by local regulatory requirements 16 PRODUCT WIPE OVER perfumed disinfecting spray cleaner OTHER INFORMATION indicate disclaimers here in agreement with legal department e g this SDS has been prepared in accordance with the directive 91 155 EEC this safety data sheet complements the indications present on the packaging this
92. use by reading the label and make up solutions for immediate use only Y Put the cap back on the container immediately Keep products off your skin Workers should wash off any splashes and avoid contact with surfaces until they are dry Service and retail SR4 Harm via skin or eye contact Special care Y Contact with many products can lead to dermatitis Some can also damage the eyes Y Y Some products may cause asthma check the safety data sheet Take special care using caustic soda sodium hydroxide Splashes in the eye can cause blindness Never add any other chemical to concentrates that contain bleach sodium hypochlorite solution This can cause a dangerous gas chlorine to be given off Health monitoring Y Y Ask your workers to check their skin for dryness or soreness every month If you use a product labelled may cause sensitisation by skin contact or may cause sensitisation by inhalation seek specialist advice see Useful links Cleaning and housekeeping Wash out the equipment after use Dispose of this waste liquid safely Y Clean up spills promptly practise how to do this Training and supervision Y Tell workers about the risks of using the product see products labels or Section 15 of the safety data sheet Y Working in the right way and using the controls correctly is important for exposure control Train and supervise workers See sheet SRO Further information m Assessing
93. used by these substances used at work is preventable Many substances can harm health but used properly they almost never do Find out the dangers in your business ask your supplier your trade association and check for your trade on HSE s website www hse gov uk Substances can also have dangerous properties They may be flammable for example solvent based products may give off flammable vapour Clouds of dust from everyday materials such as wood dust or flour can explode if ignited This leaflet does not deal with flammability or explosion hazards see Find out more Look at each substance Which substances are involved In what way are they harmful You can find out by checking information that came with the product eg a safety data sheet asking the supplier sales representative and your trade association looking in the trade press for health and safety information checking on the Internet eg HSE s website pages for your trade Think about the task If the substance is harmful how might workers be exposed Breathing in gases fumes mist or dust Contact with the skin Swallowing Contact with the eyes Skin puncture Bear these in mind when you look at the tasks Exposure by breathing in Once breathed in some substances can attack the nose throat or lungs while others get into the body through the lungs and harm other parts of the body eg the liver Exposure by skin contact Some substances dama
94. ut of the reach of children S23 Do not breathe vapour spray S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S27 28 After contact with skin take off immediately all contaminated clothing and wash immediately with plenty of to be specified by the manufacturer 536 37 39 Wear suitable protective clothing gloves and eye face protection S45 In case of accident or if you feel unwell seek medical advice immediately show label where possible S51 Use only in well ventilated areas STATUTORY INSTRUMENTS Chemicals Hazard Information and Packaging Regulations APPROVED CODE OF PRACTI CE Classification and Labelling of Substances and Preparations Dangerous for Supply GUI DANCE NOTES Workplace Exposure Limits EH40 CHIP for everyone HSG 108 DETERGENT LABELLI NG lt 5 Non ionic surfactants 16 OTHER I NFORMATI ON USER NOTES The following risk phrases relate to the raw materials in the product and not the product itself REVI SI ON DATE 20 04 2006 REV NO REPL SDS GENERATED 7 R PHRASES Full Text R22 Harmful if swallowed R35 Causes severe burns R35 Causes severe burns Page 3 of 3 1 SAFETY DATA SHEET DENTIFICATION OF THE SUBSTANCE PREPARATION AND OF THE COMPANY UNDERTAKING Johnson Diversey JohnsonDiversey UK Limited Weston Favell Centre Northampton NN3 8PD Tel 01604 405311 Fax 01604 406809 Emergency Call 0800 052 0185 Clearance Code ENHANCE SPOT amp
95. ution ca 10 5 Reserve alkalinity to pH 10 2 27 g NaOH 100 g Not Flammable Non Explosive Non Oxidizing Relative density ca 630 g l Water solubility high 10 Stability and reactivity Stable under normal conditions 11 Toxicological information Not acutely toxic may cause vomiting If large quantities are ingested treat symptomatically Do not induce vomiting If irritant effects are seen these will be mild to moderate depending on exposure If in contact with eyes flushing with water is recommended Estimated acute oral toxicity LD50 rats gt 2g kg Eye irritation Slightly irritating to eyes Skin irritation Slightly irritating to skin Chronic toxicity Repeated exposure to low levels e g on fabrics or diluted in washing water will not cause adverse effects Contact sensitization Does not provoke a sensitization reaction 12 Ecological information The product is intended for wide dispersive use and is compatible with the down the drain disposal route The product is not considered harmful to aquatic organisms nor to cause long term adverse effects in the environment The surfactants used in the product are biodegradable in line with the requirements of EU Directives 73 404 EEC and 73 405 EEC and their subsequent amendments 13 Disposal considerations Professional products ending up down the drain after use Observe safe handling precautions and local legislation 14 Transport information N
96. vent entering watercourse Absorb spillage in inert material e g dry sand earth and transfer into any secure container s for disposal If spillage is left it will dry out to form a film which is difficult to remove HANDLING AND STORAGE Store away from children Use only according to directions Do not mix with other chemicals Always ensure cap is replaced and tightened after use Do not store in temperatures greater than 35 C or less than 0 C Protect from freezing SO eS S A05 Revision 4 March 1995 10 11 12 13 14 15 16 EXPOSURE CONTROLS PERSONAL PROTECTION 1 Rubber gloves are recommended if skin contact Is likely 2 Always maintain a good standard of occupational hygiene when handling chemicals Exposure levels according to EH40 list issued by HSE Occupational Exposure Standard O E S Ammonia L T E L 8 hours 25ppm S FEL 15 minutes 35ppm PHYSICAL AND CHEMICAL PROPERTIES 9 1 Appearance Translucent cream emulsion 9 2 Odour Low slightly sweet 9 3 pH 8 0 8 2 9 4 Density 20 C 1 019 kg litre 9 5 Flash Point Not applicable 9 6 Solubility in Water Miscible STABILITY AND REACTIVITY Product is stable under normal conditions Prevent from freezing TOXICOLOGICAL INFORMATION No significant health hazard when properly used for the application it was designed for Effects due to overexposure when In contact with eyes Irritation redness and watering In

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