- ODS-instrumentatie NL
Contents
1. ODS s pecialist in Samplers amp Anal tical Systems L _ Online TC TOC TN COD TOD analyser model Quickultra The online Quickultra manufactured by LAR Process Analysers AG is a multi functional TC Quick U nlimited TOC COD TN analyser This analyser is designed and suitable for use in an industrial area Low Maintenance Common applications are the monitoring of process water waste water cooling water influent True TOC and effluent streams The Quickultra uses a patented injection system A precise volume of waste danaa water is injected into the thermal oxidation reactor At a temperature of 1200 C all species e g inorganic carbons organic carbons and organic nitrogen components are fully oxidised 100 recovery No catalyst is used The Quickultra is available as a Total Carbon Analyser TC analyser Total Organic Carbon analyser via the direct method TOC direct Total Organic Carbon analyser via the differential method TOC differential Total Nitrogen analyser TN Total Oxygen Demand analyser TOD synonym with fast Chemical Oxygen Demand COD o In principle any combination of above mentioned analysis methods is available TC TOC TN and TOD are measured simultaneously meaning that the measurement results are directly available after one analysis cycle typically 3 to 5 5 minutes The Quickultra operates via a fully programmable robot that controls the functions and positions of the robust inje2. TC TOC TN TP COD i model QuickKTOCNPO e Total Organic Carbon and Total Nitrogen by thermal oxidation at 1200 C multi loop injection and simultaneous analysis of TOC TN e Total Phosphorous Measuring principle molybdenum blue method Oxidation by UV persulphate to PO43 According to DIN ISO 6878 respiration TRUE TOC NPOC Projects ODS has the know how and experience to offer complete customized analyser projects We offer turn key projects Materials A walk in shelter Analysers TC TOC TOD COD OIW oil in water etc Power distribution power sockets lighting Junction boxes signal distribution Fluid piping e g a drain header HVAC coolers heater dehumidifier Utilities such as instrument air piping a Zero air supply or nitrogen generator e Extras such as a reagent cabinet arctic boxes e Waste water pumps e Fast sample loop Samplers e g anti isokinetic sampler Spare part kits Services e Application research sample tests e Recommendation reports e Engineering e Documentation package drawings and manuals FAT document SAT document system CE certification risk analyses etc In House test Factory Acceptance Test Shipment packaging crates insurance Installation and commissioning amp start up on site A Site Acceptance Test Training Measurement principles and hands on opeation After sales service Service contracts ODS Sampling amp Analytical Systems Phone 31180640
3. The Carbonate Removal System The sample is mixed with a strong acid solution for example 1 of HCl The pH of the mixture is lt 2 5 This acidified sample flows into a mixing vessel and during a specific period CO gt free carrier gas bubbles through At a pH lt 2 5 Inorganic Carbon Carbonates react as follows COs aq 2H aq H20 aq CO2 9 The carbonates bicarbonates and free CO are stripped out of the sample as CO gt gas Next the sample is drawn into the injec tion needle and injected into the high temperature reaction tube All exactly as with the TC method described left The outcome is presented and stored as the TOC concentration The TOC direct method is also known as the Non Purgable Organic Carbon method NPOC It is less suitable for samples with organics that are Purgable or volatile because they can be partially stripped out during the carbonate re moval step ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl Condensate drain of TIC measurement Block diagram of the TOC differential method Total Organic Carbon differential The TOC concentration is determined via two different analysing steps step 1 The Total Carbon content TC of the sample is analysed Same as TC Step 2 Then the Total Inorganic Carbon TIC content is analysed The Total Organic Carbon content is then calculated via TOC TC TIC Anal
4. a high load of suspended organic par ticles Not only can it easily process these samples it also completely oxidises all organics dissolved and organic particles The advanced robot driven injection technique in combina tion with a non catalytic 1200 C thermal oxidation make this possible The QuickTOCultra measures the sum of dissolved organic carbons particulate organic car bons and purgeable organic carbons Features of the Quickultra e Large touch screen e Intuitive software design Customisable configuration based on prepositional icons e Three user levels pass word protected De Quickultra ATEX Zone 2 1 Ex p e The thermal oxidation technique at 1200 C guarantees complete oxidation 100 recov cabinet with air air cooler ery e Also organic particles particulate organic carbon will be oxidised completely e At 1200 C memory effects are minimum resulting in a fast analyser response e Fast analysis time of 3 minutes TC and 5 5 minutes TOC e Very stable analysing results due to the batch injection technique auto zero technique and peak area calculation Zero drift 0 mg litre C per year e Programmable injection volume offers flexibility in optimising and setting the analyser range e Low Salt built up in the reactor due to the low volume injection method amp 1200 degree oxi dation e Free programmable robot technique offers configuration flexibility such as very low carry over effects making the analyser su
5. 879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com QuickTOC Ultra OT1 11107 Version 4 1 0 Mon Apr 23 16 51 20 CEST 2012 Please register your analysers at register lar com and receive free software updates Copyright c 1992 2012 LAR Process Analysers AG i ie ae k 7 i ik 4 f i5 r ate pase Quickultra analysers in end test The injection needle positioned in Training at LAR Process The Quickultra is equipped with a and almost ready for shipment the injection port of the reactor Analysers AG Berlin 10 4 inch touch screen coD TN_3 ODS engineer check of the pH of a Two sample vessels two calibra Flexibility multi tasking and easy Quickultra measurement of TC QuickTOCultra analyser tion vessels and one waste vessel control via icon driven menus COD and TN all in 3 minutes only wenn bbs ores ODS project with a walk in shelter Acid and demin water are safely Control of a skimmer via a A QuickTOC in an ODS and a QuickTOC stored in a reagent cabinet 2 stream QuickTOCultra analyser shelter F aL AC FaN n r 5 5 X 4 D 5 gt 2 1 ppe l Eh lt 6 ar ae ie y LO Re 3 5 ce G w i T7 yG Ds x eo z r S S i Ki l na ae A EA ae a a True TOC includes the measure Anti isokinetic flow samplers sepa ODS engineers installed another ment of particulate organic carbon fast
6. C Then the carrier gas flows through a gas sample cooler and a gas scrubber The dry and clean carrier gas then flows through the O2 sensor Prior to injection the O2 sensor measures the O value of the base line The robot controls the needle position and sample suction syringe The needle is positioned into the sample overflow vessel and is filled with a precisely pro grammed volume of fresh sample Then the robot positions the needle into the injection inlet port and is positioned deep into the 1200 C reactor tube A precise volume of sample is injected The sample is quantitatively oxidized The oxygen depletion is measured it correlates directly to the oxygen de mand of the sample The method in cludes the oxygen demand by non carbonaceous compounds n1 CxHyNz n2 O2 gt n3 CO2 n4 H20 n5 NO rest Via peak area calculation the amount of O depletion is determined By compar ing the outcome to wet calibrations the Total Oxygen Demand concentration in the waste water is calculated ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl Condensate drain of TN analysis Block diagram of the TNb method Total Nitrogen Bounded Dry and clean carrier gas flows through the high temperature reaction tube 1200 C after which it flows through a gas sample cooler and a gas scrubber The dry and clean carrier gas then flows through the electrochemic
7. ODS s S becialist in in AnicaMehicd Conform Ranges Repeatability Reproducibility Drift Cycle time Type of detector Carrier gas requirements e Quality e Consumption e Pressure Acid solution strength and consumption Outputs 4 20 mA data logging EEEE o Conform _ Ranges Repeatability Reproducibility Drift Cycle time Type of detector Carrier gas requirements e Quality Consumption Pressure Reagents acid a a panik mia cs logging mplers amp Analytical Systems gt 7 a e A two awa a ee P f lt A a a v ra 7 E Teal Lill Z ne ZA n 2 4 S A wey moa Online TC TOC TN COD TOD analyser model Quickultra Deteminaion of the organic Se E via TT combustion of the sample at 1200 C and the analyses of the resulting carbon dioxide DIN EN 1484 ISO 8254 en EPA 415 1 O to 10 up to 0 to 50000 mg l C to be specified Typical lt 2 CV of measured value 25 to 100 of scale Typical lt 1 CV 0 mg l C per year auto zero technique TC 3 minutes programmable TOC 5 5 minutes programmable NDIR infrared no moving parts maintenance free digital data transfer with integrated pressure and temperature compensation Dry and free of CO particles and hydrocarbons TC Typical 30 Ni h TOC direct 45 Ni h multi stream add 8 Ni h per sample stream 2 to 6 1 5 to 6 barg TC no acid needed TOC direct 1 w w hydrochloric acid 2 litre
8. al NO sensor Prior to injection this NO sensor meas ures the base line zero value The robot controls the needle position and sample suction syringe The needle is positioned into the sample overflow vessel and is filled with a precisely pro grammed volume of fresh sample Then the robot positions the needle into the injection inlet port and is positioned deep into the 1200 C reactor tube where a precise volume of sample is injected Nitrogen compounds e g organic nitrogen ammonium ammonium nitrogen nitrate nitrite particulate nitrogen are oxidized to nitric oxide NO The carrier gas transfers the NO gas to the electrochemical NO sensor Via peak area calculation the amount of NO gas is determined By comparing the outcome to wet calibrations the To tal Nitrogen concentration in the waste water is calculated www ods analytical systems com ODS specialist in Samplers amp Analytical Systems BT Foor ne ne P oa Ean w Online TC TOC TN COD TOD analyser model Quickultra Innovative Technique based on Proven Technology The Quickultra uses the identical proven technology as used in the previous Quick series The parts being used e g XY robot syringe oven reactor seals glass work are identical and fully exchangeable with parts of the previous Quick series Its technique is based on new electronics a different operating system and bus communication Unlimited Low maintenance e On
9. ction needle Only a few parts are in contact with the waste water sample inlet tube sample overflow vessel sample outlet tube and an optional sample pump After every waste water injection the injection needle is flushed with rinse water This all results in a minimum of maintenance The injection volume is fully programmable from 10 to 600 micro litre making the analyser very suitable for many applications from 0 1 to 50 000 mg litre carbon and up to 150 000 mg litre oxygen demand No sample dilution technique is needed For relatively clean water such as cooling water and effluent water a high sample volume is injected or and a more sensitive CO2 sensor is used For highly polluted water such as process water and influent water a low sample volume is injected and or a less sensitive NDIR sensor is used Proven technology XY robot ps and 1 to 6 sample vessels The peak area calculation method that is used results in an excellent repeatability and long term stability Furthermore the advantage of using the 1200 C thermal oxidation technique is e no memory effects e a rapid response to big concentration changes e A fast analysis cycle time e carry over effects cross contamination are very low meaning that this analyser is very suitable for multi stream and multi range applications ODS delivered many Quick analysers to all kinds of industries We have experience with e g influent waste water of a pulp amp paper mill wast
10. e water of a milk powder factory oil in water of a refinery spill detection of petrochemical industries waste water with waxes brackish salty cooling water discharge load monitoring and influent effluent control of a WWTP This QuickultraTC TOC COD TOD TN analyser measures quickly and accurately a E e veer The XY robot in combination with the free programmable multi task software offers unique flexibility Furthermore the hardware is designed and pre constructed in such a way that it is easy to change an analyser functionality or measuring principle Examples of standard functionality e Flush the sample system during service or set up e Measure a single point of a standard or a grab sample Evaluate the repeatability and mark outliers e Automatically analyse samples flush the sample system with water flush the rest of the water to drain e Perform a calibration routine manually or automatically 100 recovery with thermal oxidation at 1200 C ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com ODS specialist in Samplers amp Analytical Systems ee A P t pi ie Taal Hill e A path pass epee 5 teh in x are n N ae 7 i A F a J 5 z n i a7 piv iJ Online TC TOC TN COD TOD analyser model Quickultra True TOC The Quickultra is capable of handling waste water with
11. ement method is exactly the same as the TOC direct method so it actually is a carbon counting method The conventional laboratory Chemical Oxygen Demand method determines the oxygen that is needed to oxidise or ganic species in waste water This method takes about 2 hours per meas urement Harmful chemicals are con sumed As a consequence this CODai chromate Method is not suitable for online process monitoring However in many cases a useful and reproducible COD TOC correlation fac tor can be found In those cases the COD value is determined by the multipli cation of the measured TOC value times the COD TOC correlation factor Examples of correlation factors are Pulp amp paper mill 2 6 Milk whole 3 0 Cream 40 3 4 Whey ZU Saturated fatty acids a 3 8 In those cases where multiple facilities discharge waste water to the same sewer system and or the sample com position is widely variable a reproduci ble COD TOC correlation factor will be hard to find In those cases we recom mend the use of the TOD method COD 0 Injection modul nitrogen Condensate drain of TOD analysis Block diagram of the COD o TOD method Fast Chemical Oxygen Demand via the TOD method COD o A nitrogen carrier gas flows through a temperature controlled permeation box where a known constant amount of oxy gen permeates the nitrogen gas flow This nitrogen oxygen mixture flows through the high temperature reactor 1200
12. h contact closure free programmable fail safe Nylon Quartz Glass PVC Stainless steel 316 Ceramic Marprene Wall solid perfectly flat and horizontal for example a concrete wall Metal Frame steel coated free standing option free standing LAR frame 4 expender bolts M8 part of the delivery Measures status of Carrier gas consumption differential inlet outlet carrier gas Leakage in the gas circuit flowchecks sample injection via flow variations Blocking of the reactor output or gas circuit Checks good operation of cooler protects and bypasses gas sensors if needed Program parameter settings Data transfer of log files Screen shots User level control Flush injection system or sample lines Furnace on off Condensate pump on off Manually validation or calibration daily automatic calibration Relays signal outputs oven cooler etc Check settings and fine tune robot positions Pressure delta P carrier gas flow balancing and limits R H limits etc Gas sensor signal graphical curve carrier gas inlet and outlet etc ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com ODS s becialist in Sam olers amp Analytical Systems aw na i so Pk ee Pra z aa ch ae oe aw HE a om Online TC TOC TN COD TOD analyser model Quickultra A cification continued Display 10 4 igh TFT colo
13. hey are re freshed Reactor High Salt version Special reactor capable of handling brackish and salty waste water Note Salt is removed easily by shaking it out of the well accessible reactor foot Languages labels and soft keyboard e Standard e English German Korean Chinese to be specified e Special e Any language and character set to be specified RS232 and TCP IP communication ports even via e g remote control juip meni Analyser frame rack Stable E for the Quickultra and reagent cabinet Steel coated Reagent cabinet e For storage of 2 each 5 litre tanks e g demin water and a 1 w w acid solution Zero air supply e Passive e Cartridges with activated carbon and soda lime To be refilled every month e active e Pressure Swing Absorption maintenance once per 2 years Outlet CO2 lt 1 ppm Nitrogen generator e Pressure Swing Absorption maintenance once per 2 years Outlet O2 lt 10 ppm Sample delivery pump e Submersible e Type and model depends on application e g 400 VAC 3 phase 1 1 2 e Peristaltic e Type and model depends on application e g 1 230 VAC speed control Anti isokinetic sampler e Material e Several option e g PVC PE or SS e Size e Several option e g 1 2 1 e Arctic box e Insulated reinforced fibreglass box Space for 1 or 2 samplers ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com
14. ickultra multi range option is very suitable for applications where an extended rangeability is needed e g a TOC range from 10 to 50 000 mg C I To guaranty that the analyser also measures accurately at low levels it is equipped with two gas sensors working in parallel The NDIR gas sensor with a long gas cell measures accurate in the low TOC range the NDIR with the short gas cell is most suitable for precise measurements in the high range Online TC TOC TN COD TOD analyser model Quickultra LAR s Range of Online Water Quality Analysers toxicity LAR s range of water quality analysers Chemical Oxygen Demand analyser model ELOX 100 e This COD method is based on Electrochemical oxidation BOD and Respiration Analyser Model BioMonitor e Online fast and quick respiration measurement of the biological oxygen consumption e Determination of the self respiration of the activated sludge Toxicity analyser Model Nitritox amp Toxalarm e Measurement parameters e BOC Biological Oxygen Consumption with Correlation to BOD laboratory method e ASR Activated Sludge Respiration TC TOC analyser by UV persulphate Model Quick TOC UV e Its measuring principle is based on photochemical oxidation with use of persulphate oxidising agent and OH radicals produced by UV light TC TOC TIC VOC pure water analysers e Single and multi stream analysers for return condensate and boiler feed water applications
15. id to pH lt 2 Inorganic carbon reacts to carbon dioxide gas which is stripped out by use of a Carrier gas Determination of Total Organic carbon Some purgeable organic carbons can stripped out in the carbonate removal system The TOC concentration is calculated by difference TOC TC TIC TOC differential Determination of Total Carbon and TC is determined as described at Total Organic Total Inorganic Carbon and the Carbon calculation of Total Organic Carbon POC VOC Determination of Purgeable Organic Purgeable Organic Carbon VOC by use of a stripping Carbon technique The TIC is determined as described at CO free carrier gas bubbles through a vessel with sample Purgeable organics are purged out TOC included POC VOC Determination of the purgeable organic carbons by use of thermal oxidation and the measurement of the amount of CO2 Measurement of the amount of nitrogen oxide NO with an electrochemical gas sensor ECD TN TNb Total Nitrogen bounded Determination of the total nitrogen content by thermal oxidation and the analysis of resulting nitric oxide The TNb content is measured via thermal oxidation at 1200 C TN measures the sum of organic bound nitrogen C HyN free ammonia NH3 NH nitrite NO7 nitrate NO3 and nitrogen bounded particles The measured nitric oxide amount is linear proportional to the Total Nitrogen concentration in water Measurement of the am
16. itable for 2 stream analysis multi stream and multi range applications e Multi stream feature support up to 6 streams Touch screen with pictograms e Low maintenance because of a patented flush system that cleans the injection system multi language example Dutch needle after every sample injection e Sample inlet filtration or conditioning is normally not needed e Low consumption of a concentrated acid solution only TOC analyser uses acid e Easy manual or automatic daily calibration and easy validation due to internal robot select able calibration vessel e Easy analyser inspection due to self diagnostic software and extra diagnostic sensors such as Carrier gas inlet amp outlet flow measurement relative humidity sensor option circuit pressure measurement e Data presentation and data storage internal memory and data logger USB and RS 232 in terface e Cabinet with a separate dry compartment for all electrical parts and a wet compartment for all analyses parts Easy access for analyser maintenance e Optional TCP IP and or RS232 communication Sample pre treatment e g filtration is not needed TRUE TOC ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com p a Pe ODS specialist in Samplers amp Analytical Systems Online TC TOC TN COD TOD analyser model Quickultra Injection modul Condensa
17. l stainless steel cabinet The analyser is suitable for wall frame or strut mounting It has two separate compartments Both compartments are easy accessible for maintenance The analyser compartment have the following features e Dry compartments for the electrical distribution units power supplies electronics e g O nodes gas sensors and the panel computer with big touch screen display e Wet compartment for the XY robot sample vessels sample stirrers injection system electrical oven with reactor tube peristaltic pump peltier cooler etc Due to modifications or improvements specifications are subject to change by manufacturer or ODS without notice ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com revision 2012 07
18. ly a few wetted parts sample vessel sample tubes and injection needle e Low injection volume e The injection needles is flushed with water after every sample injection e No consumption of chemicals TC TN and TOD only TOC requires an Lowest detectable level 0 01 mg l C Highest range up to 50 000 TOC and 150 000 ppm TOD without using any sample dilution No use of an expensive Pt catalyst e Suitable for a variety of waste waters e Up to 6 sample streams e Up to 4 gas sensors Suitable for simultaneously analysis of TC TOC acid solution TIC COD i TOD and TNb e No use of an expensive catalyst e Fast response typical cycle time 3 to thermal oxidation at 1200 C 5 5 minutes Quick Unlimited e Fast replacement of only a few e High salt option up to 30 g l Low Maintenance consumables on a monthly basis e Cabinets standard NEMA4X True TOC e Preventative service is required once NEMA4Xx high temp ATEX Zone 2 Reliable per 6 month only ATEX Zone 1 Accurate True TOC Reliable Accurate e Direct analysis of raw waste water e Proved technology even for the most e Accurate analysis results at high No sample filtration needed demanding application dynamic ranges e True TOC soluble organics e High availability it uses only a few e Outstanding performance purgeable organics particulate wearing parts that can be replaced in e No zero drift due to the batch organics minutes injection and auto zero technique e At 1200 C al
19. lysed and the analytical method s These vessels are lined up with the injection port of the 1200 C reactor and if needed the TlC reactor A robust XY robot works in cooperation with an advanced injection system and a thick injection needle This needle is positioned above the row of quartz glass vessels and or reactor s The great advantage of the use of the XY robot and injection system is that a minimum of wetted parts are needed In this system no moving parts e g pinch valves solenoid valves and rotating valves are used Its an excellent system for multi stream applications cross over contamination and carry over effects are eliminated MULTI INJECTION VOLUME The Quickultra offers the capability to enter program parameters per sample stream An important parameter to enter is the sample injection volume The great advantage is that sample streams with relative big differences in concentration levels can be measured accurately with one gas detector For example The influent TOC level of a waste water treatment plant varies from 100 to 1000 mg l C The effluent TOC level of the treated waste water varies from 10 to 100 mg l C Influent and effluent water is measured with one QuickTOCultra with only one NDIR detector It is configured in such a way that the injection volume of the influent measurement is 30 ul and for the effluent measurement is 300 ul All TOC values in the range of 10 to 1000 mg l C are measured accurate MULTI RANGE The Qu
20. on condensing Cooling heat transfer by ambient air and a fan Integrated advanced air air heat exchanger Integrated advanced air air heat exchanger Integrated advanced air air heat exchanger Material of the cabinet Steel coated grey hinges right side Stainless Steel 316 brushed coated Stainless Steel 316 brushed coated Stainless Steel 316 brushed coated Excl glands connectors etc e 1 stream e 2 6 streams incl pumps e 1060x595x530 mm e 1060x750x530 mm Request for a detailed drawing e 1060x815x570 mm e 1060x935x570 mm Request for a detailed drawing e 1060x912x570 mm e 1060x992x570 mm Request for a detailed drawing window Securit transparent transparent transparent hinges right side hinges right side hinges right side window Securit window Securit window Securit Dimensions hxwxd hxwxd hxwxd hxwxd e 1060x915x570 mm e 1060x995x570 mm Request for a detailed drawing Weight 1 stream 105 kg 120 kg 120 kg 120 kg High temperature version Ambient air 5 to 50 C via an integrated compressor cooler Zero Air Supply e Passive by cartridges e Active by PSA Passive or Active e Yes e Yes recommended e Yes e Yes recommended e Yes recommended e Special via Ex d e Yes recommended e Option Special via Ex d Hardware analyser cabinet The Quickultra is built in a rugged stee
21. ount of oxygen depletion O2 with a zirconium oxide sensor ZrQ gt COD o Chemical Oxygen Demand Determination of the oxygen depletion via the Total Oxygen Demand method The sample is oxidised at 1200 C The oxygen depletion is measured in the Carrier gas ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 odsanalytical odsbv nl www ods analytical systems com All compounds that consume oxygen due to the oxidation process are measured e g organic hydrocarbons ammonia and organic bound nitrogen YOU NAME IT WE BUILD IT tit WE gt ri CAL STRM 1 WASTE CAL SAM STRIP WASTE TIC CAL 2 CAL 1 STRM 1 WASTE TC analyser TOC direct analyser TC TIC amp TOC analyser differential 1 stream 1 stream 2 streams H 4 a 242 ee A SS CAL1 CAL2 STR1 WASTE STRM 2 CAL STRM 3 WASTE RINSE STRM 2 STRM 1 TIC STRM 1 sia y S iai ee ee 6 TC amp TN amp TOD analyser TOC amp TN TC TIC TOC analyser differential 2 streams 3 streams 6 streams MULTI STREAM The Quickultra analyser is suitable for the sequential analysis of 1 to 6 sample streams This analysis uses a series of quartz glass vessels which are possitioned and mounted in a row The following vessel types are used 1 to 6 sample overflow vessels 1 or 2 calibration vessels and a waste vessel Its configuration depends on the specific application e g how many sample streams the ranges to be ana
22. s week or less when cycle time is longer TOC differential 1 w w phosphoric acid 2 5 litres week or less when cycle time is longer TC analyser TC one output per stream TOC direct TOC NPOC one output per stream TOC differential TC TOC and TIC amount of outputs to be specified Determination of the total nitrogen content by thermal combustion at 1 200 C and the analysis of the resulting NO gas DIN 38469 part 27 EN 12260 ISO TR11905 2 50 200 1000 mg I N to be specified Typical lt 3 CV of measured value 25 to 100 of scale Typical lt 2 CV 0 mg l N per year auto zero technique 3 minutes programmable Electrochemical solid state to be exchanged once per 1 1 2 year e Dry and free of particles and hydrocarbons e Typical 30 NI h 1 5 to 6 barg Not needed TN one output per stream TETEE Metod Conform Ranges Repeatability Reproducibility Drift Cycle time Type of detector Carrier gas requirements e Quality e Consumption Pressure Reagents Outputs 4 20 mA data logging Determination of the oxygen demand via thermal combustion of the sample at 1200 degrees Celsius and the measurement of the amount of oxygen depletion in the oxygen enriched nitrogen carrier gas ASTM D6238 98 2011 500 500 2000 8000 15000 30000 and 150000 mg l O to be specified Typical lt 3 CV of measured value 25 to 100 of scale Typical lt 2 CV lt 10 mg litre O2 per year due to auto
23. sample loop rate big particles from the sample online TOC analyser system ODS s becialist i in Samy lers amp Analytical Systems ad re al J 4 f T r a aau ont en ae a9 end ny bi et ha See kai m Aaa a del 7 ay ie Z WA Z p ee gs gt awa Oey ee wwe HED om Online TC TOC TN COD TOD analyser model Quickultra Type Manufacturer Analytical Method Use Typical applications Sample requirements Pressure Flow no internal sample pump Flow with internal sample pump Temperature maximum Size Organic Particles Salt as NaCl gram litre Sample conditioning e Filtration e Fast sample loop e Anti lsokinetic flow sampler Connections e Sample e Carrier gas e Exhaust carrier gas e Fluids to the drain header Power e Voltage Frequency V Hz e Power consumption Rinse water Certificate Electrical cables Signals e Analogue outputs e Relays alarms Materials wetted parts sample Inlet tube Overflow vessel Drain tube Injection needle Reactor Sample pump TOC Mounting e Basis e Rack Frame e Hardware Extra diagnostic sensors e Thermal Mass Flow carrier gas inlet e Thermal mass Flow carrier gas outlet e Pressure sensor reactor pressure and pressure pulse e Relative Humidity sensor after condensate cooler USB connection download upload Service menu e Service Calibrate Status tes
24. so organic particles are e A set of sensors and smart diagnostic e Stable and repeatable measuring fully oxidized 100 recovery software monitor the correct results due to peak area calculation e Analysis including purgeable organic functionality of the analyser e Repeatable sample injection volume carbons and volatile organic carbons e High availability suitable for process full oxidation stable and controlled via the TOC differential method control carrier gas flow stable smart gas e Suitable for 2 stage fluids dissolved sensors oil and free oil dissolved organics e Auto or manual calibration and and organic particles validation features ODS Sampling amp Analytical Systems x Phone 31180640879 Fax 31180640569 ba SS odsanalytical odsbv nl www ods analytical systems com ODS s becialist i in Sam olers Analy tical Systems A i J k ih eae _ Laas n ES a a Online TC TOC TN COD TOD analyser model Quickultra MULTI SUM PARAMETERS The Quickultra analyser can be equipped with 1 to 4 gas sensors Simultaneously the following parameters are measured e Total Carbon TC Total Inorganic Carbon TIC Total Organic Carbon TOC Purgeable Organic Carbon POC or Volatile Organic Carbon VOC e True TOC The sum of Dissolved Organic Carbon Suspended Organic Carbon SOC Purgeable Organic Carbons e Total Nitrogen TN TNb e Chemical Oxygen Demand by multiplying the TOC value wi
25. te drain of TC Messung Block diagram of the TC method Total Carbon Dry and CO gt free carrier gas flows through the high temperature reaction tube 1200 C Then the carrier gas flows through a gas sample cooler and a gas scrubber The dry and clean carrier gas then flows through the NDIR CO analyser Prior to injection the NDIR measures the base line zero value The robot controls the needle position and sample suction syringe The needle is positioned into the sample overflow cup and is filled precisely with a pro grammed fresh sample volume Then the robot positions the needle into the injection inlet port A needle sensor detects the needle and opens the inlet cock valve Then the needle is posi tioned deep into the 1200 C reactor tube and a precise volume of sample is in jected Organic carbon and inorganic carbon is completely oxidized to CO and H20 and NO etc No catalyst is used The carrier gas transports the CO to the NDIR CO gas analyser Via peak area calculation the amount of CO is determined By comparing the outcome to wet calibrations the Total Carbon concentration in the waste water is cal culated TC TOC TIC ANALYSIS METHODS Condensate drain of TC Messung Block diagram of the TOC direct method Total Organic Carbon direct The TOC concentration is determined by pretreatment of the sample via acid prior to injection of the sample into the thermal oxidation reaction tube
26. th a COD TOC correlation factor e Total Oxygen Demand TOD Stream 1 TOC Stream 1 TC sample carrier sample Stream 1 TC Stream 1 COD injection gas injection i NDIR low Te Stream 1 TIC Stream 2 TC i j co TOC Stream 1 COD Stream 2 COD l TIC i NPOC Stream 3 TN a NDIR high POC i TC TOC TIC co IY n reactor reactor voc Stream 1 COD 5 Stream 1 TOC 1200 C acia CLD or EC TN Stream 2 COD Stream 1 TNb gas COD cooler TOD condensate Analysis method and the types of gas sensors being used Measurement of the amount of carbon dioxide gas CO2 with a non dispersive infrared gas sensor NDIR TC Total Carbon Determination of the Total carbon Determination of total carbon content by The sum measurement of total organic amount Thermal combustion and analysis of the carbon and total inorganic carbon resulting CO2 TC TOC TIC TIC Total Determination of inorganic carbon The sample is injected in a TIC reactor The measured amount of CO gas is linear proportional to the amount of inorganic carbon in water carbonates en bicarbonates The inorganic carbon reacts with acid to CO gas A carrier gas transfers the CO2 gas to the CO2 sensor Inorganic Carbon NPOC TOC direct Total Organic Carbon The stripped sample containing only TOC is injected in the 1200 C reactor The measured amount of CO gas is linear proportional to the TOC concentration The sample is mixed with ac
27. ts Test run Setting of alarm parameters Observe measured values of sensors Model Quickultra LAR Process Analysers AG Germany Berlin TC TOC direct TOC differential COD i by COD TOC correlation TN TOD fast COD o via thermal combustion of the sample at 1200 C and the analyses of the formed carbon dioxide nitric oxide or measurement of the oxygen depletion Stationary Online Influent amp effluent of a WWTP storm water monitoring cooling water spill detection load monitoring process water monitoring and control etc Atmospheric to a slight overpressure 0 05 to 0 2 bar 50 to 200 ml min to internal sample overflow vessel 30 ml m pre pump time is selectable 60 C Typical up to 1 mm most particles are soft and spongy saturated with water Up to 15 gram litre Up to 60 gram litre by use of high salt option No not needed Yes recommended velocity of sample flow gt 1 m s Yes we recommend using the anti isokinetic sampling technique to separate big particles with high mass consult ODS BV for details 6 4 mm OD ID one per stream 6 4 mm OD ID instrument air nitrogen for COD o T OD 6 4 mm OD ID 10 8 mm OD ID PVC tubes to be connected into a drain header slope down 230 50 optional 110 60 950 VAaverage only during start up 600 VA typical 1 or 2 litre week depends on cycle time CE Via Glands top of cabinet 4 20 mA isolated active max 500 ohm free programmable 1 per stream 4 eac
28. ur touch s screen Menu Intuitive software design Configuration by use of pictograms Multi language standard English German contact your local LAR representative 3 user levels accessible by passwords Input via soft keyboard and soft numeric keyboard Modes Information visualising tables and graphs and peaks calibration amp validation measurement parameters service issues data logger etc Data logging Logger capacity for years of data Measuring values TC TOC TN COD etc Calibration data Log book of events Format csv text Warranty 1 year after delivery wearing parts and consumables excluded Documentation e Manuals drawings spare part listing e User manual available in the English language e Drawings schematics included e Technical training manuals on request Maintenance and routine service Calibration Cleaning of sample system e As needed e g 1x per month This analyse is very stable J e Inject port e e e 1x per month clean applications 1x per 2 month 1x per month o ring replacement Depends on salt content and injection volume 1x per 6 month 1x per month 4x per year replace Arpa laue content depends on sample composition Outlet reactor Pump tubes condensate pump and sample pump Scrubbers aerosol brass amp zinc Multi stream Up to TTT stream includes software upgrade sample vessels sample pumps sample tubes Sample and hold technique Output values are frozen till t
29. ysing total inorganic carbon TIC An extra TlC reaction vessel is used Via a peristaltic pump a 1 w w phosphoric acid H3PQ solution is pumped into this TlC vessel Via an overflow the solution level is kept con stant CO free carrier gas bubbles through the acid solution Then this car rier gas leaves the TlC vessel and flows to the NDIR gas analyser The CO3 baseline is measured and stored Now the robot positions the injection needle into the sample overflow vessel and draws an exact volume of sample The needle is moved and positioned into the TIC vessel and this sample is injected into the acid solution Inorganic carbon reacts with the acid pH lt 2 5 to COz gas The stripping gas bubbling through the T lC vessel then transports the CO gas to the NDIR analyser where the CO2 peak is measured and the TOC concentration is calculated The TOC differential method presents TC TIC and TOC data www ods analytical systems com ODS specialist in Samplers amp Analytical Systems io E pi T Ma i MA oe 3 Fie e el mie gt PE ai a gt a a lt n fs E z ih m J A ap A A Online TC TOC TN COD TOD analyser model Quickultra COD by correlation amp COD by Total Oxygen Demand amp TN ANALYSIS METHODS Block diagram of the COD i method Chemical Oxygen Demand by COD TOC correlation COD i The COD i measurement takes place in only 3 minutes The measur
30. zero technique 3 minutes programmable O2 sensor zirconium oxide e Nitrogen high purity grade 5 0 99 999 N2 lt 10 ppm Oz and C Hy required grade depends on TOD analyser range e Typically 20 maximum 28 1 each cylinder 50 200 bar nitrogen per week 1 5 to 6 barg Not needed TOD one output per stream ODS Sampling amp Analytical Systems Phone 31180640879 Fax 31180640569 www ods analytical systems com odsanalytical odsbv nl ODS s beClal Quick Unlimited Low Maintenance True TOC Reliable Accurate IS it aid ie mo D wa am n oy Online TC TOC TN COD TOD analyser model Quickultra cabinet t in Sam olers Anal tical Systems eee ona Purpose Standard industrial area e g an analyser shelter Industrial area with risk of corrosive vapours and Hazardous area with risk of explosive gasses or vapours Hazardous area with risk of explosive gasses or vapours building factory gasses according ATEX zone 2 according ATEX zone 1 IP classification IP54 IP64 IP64 IP64 Hazardous area according Exil 3G Expz iI T3 Ex I2 G Ex pxIIT3 Ambient air temperature e recommended e 5to 30 C e 5 to 25 C e 5 to 25 C e510 25 C e Minimum maximum e 0 to 38 C e 0 to 30 C e 0 to 30 C e 0 to 30 C Ambient air humidity Max 95 non condensing Max 95 non condensing Max 95 non condensing Max 95 n
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