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        Diesel Fuels - Goodheart
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1.   fuel can affect the operation of the engine  If an engine is not    developing the proper horsepower  an improper grade of diesel  fuel could be the cause  An easy way to confirm this is to use a  diesel fuel quality tester such as shown in Figure 14 3     Diesel Fuel Properties   In a diesel engine fuel system  the fuel itself performs  three functions  It supplies chemical energy to be trans   formed into mechanical energy  lubricates precision parts  in the fuel system components  and cools metal surfaces  operating in conditions of friction    The properties or characteristics of diesel fuel must  meet these three if the engine is to perform with reliability           This sample chapter is for review purposes only  Copyright    The Goodheart Willcox Co   Inc  All rights reserved           Chapter 14       Figure 14 3  A typical diesel fuel quality tester   Kent Moore Tools     Fuel processors  as well as engine manufacturers  run lab   oratory tests on all fuel used in diesel engines  These mea   sured properties give a good indication of the way the fuel  will perform  however  there is no real substitute for an  actual engine test  The major diesel fuel properties  affecting engine performance are    Heat value    Specific gravity    Flash point    Volatility    Cetane number rating    Pour point   Cloud point    Viscosity    Carbon residue    Sulfur content    Fungus and bacterial contaminants    Oxidation and water        OUUUUUUUOOUOUDU    Heat Value    The heat v
2.   will need to meet a limit of 15 ppm sulfur  and in 2012   locomotive and marine  LM  diesel fuel will also be regu   lated at 15 ppm     Fungus and Bacterial Contaminants  Fungus and bacteria are the most common contami   nants found in diesel fuels  Fungus and bacteria live in the       308    water and feed on the hydrocarbons found in diesel fuel   These contaminants are called hydrocarbon utilizing  microorganisms  HUM   HUM will soread through a fuel  system where moisture or trace amounts of water are pre   sent  The resulting bacterial problems can shorten engine  filter life  Draining the fuel system will reduce HUM activity   but will not eliminate it The only way to eliminate HUM  growth entirely is to treat the fuel system with a biocide     Oxidation and Water   Precipitants and particulates are noncombustible  materials formed when either two incompatible fuels are  mixed or when a fuel oxidizes  Oxidation can occur when  an unstable fuel circulates through a diesel engine   Precipitants and particulates will normally settle out in low  or slow flow areas of the fuel system or become part of the  tank   s bottom sludge  Both can get mixed into the fuel  system during fuel delivery and can plug fuel filters    Water causes the greatest concem because it is the  most common form of diesel fuel contaminant Water is  found in the fuel system in two forms  free and dissolved   Most diesel fuels contain some dissolved moisture  Diesel  fuel has a saturation level of 
3.  of low sulfur diesel fuel  as well as refor   mulation procedures  diesel engines will be performing  well into the 21st century     Total    monoxide hydrocarbons   grams bhp hr      grams bhp hr      1 Diesel         20  Biodiesel    20  Biodiesel    and catalytic converter    Figure 14 12  In the future  biodiesel fuels can play a role in reducing exhaust emissions   National Soy Diesel Development Board           This sample chapter is for review purposes only  Copyright    The Goodheart Willcox Co   Inc  All rights reserved           Chapter 14 Diese  Fuels    Summary    Only two recommended grades of diesel fuel are con   sidered acceptable for use in high speed trucks and buses  in North America  These are the number 1D and number  2D classifications  Grade 1D is generally the most refined  and volatile diesel fuel available  It is a premium quality  fuel used in high rom engines requiring frequent changes  in load and speed  Grade 2D is more widely used in truck  fleets due to its greater heat value per gallon  particularly  in warm to moderate climates    Diesel fuels are blended on a seasonal and geo   graphical basis to satisfy anticipated temperature condi   tions  In a diesel engine fuel system  the fuel supplied  chemical energy is transformed into mechanical energy   Diesel fuel also cools and lubricates precision parts in the  fuel system    The heat value of fuel is a general indication of how  heat energy is supplied to an engine  and thus  how well  the en
4. STM    Each individual refiner and supplier attempts to pro   duce diesel fuels that meet as closely as possible with  ASTM and American Petroleum Institute  API  standards   Figure 14 2  Depending on the crude oil source  the diesel  fuel end product may be on either the high or low end of  the prescribed heat energy scale in Btus per gallon  This is  why individual diesel fuels grades may vary slightly from  one supplier to another    Grade 1D is generally the most refined and volatile  diesel fuel available  It is a premium fuel used in high rom  engines requiring frequent changes in load and speed  Grade  2D is more widely used in truck fleets due to its greater heat  value per gallon  particularly in warm to moderate climates   Although Grade 1D fuel has better properties for cold     303         Condenser    a              Reflux    Crude oil  heater     lt     Steam     lt     Steam N  Heat exchanger JH    a gt   as  YY       Reboiler  heater    Gases    Gasoline    Kerosene    Cooler    Diesel fuel    Diesel Technology    Long residue lube oil feedstock    Crude oil    Figure 14 1  A fractionating column is used to separate crude oil into the various hydrocarbon products  As the vaporized products  rise in the tower  they settle onto trays at different levels and are then piped out to other equipment for further refining      Allis Chalmers Engine Div      General Fuel Classification    BTU Gal average  Gravity  API   Flash point  minimum     F    C    Viscosity  kine
5. This sample chapter is for review purposes only  Copyright    The Goodheart Willcox Co   Inc  All rights reserved           After studying this chapter  you will be able to   Explain diesel fuel grades    Discuss fuel properties and characteristics   Explain the reason for the use of fuel additives   Describe the proper procedures for handling and  storage of diesel fuel    Name the various alternative fuels and their  properties           All engines have a few things in common  One of them  is that they all need fuel in order to operate  Most mobile and  stationary engines use fuels derived from crude oil  Diesel  engines use several variations of diesel fuel  depending on  their application  In this chapter  you will learn about the dif   ferent types of diesel fuel used in diesel engines     Hydrocarbon Fuels    The liquid fuel used to operate diesel engines is  obtained from crude oil  Crude oil consists of a mixture of  hydrocarbons  hydrogen and carbon  and compounds  such as benzene  petane  hexane  heptane  toluene   propane  and butane  These compounds have different  relative volatility points because they will vaporize  or  flash  at different temperatures  Hydrocarbon fuels are sep   arated in a fractionating column    As crude oil is heated  these hydrocarbons are given  off as a vapor  Figure 14 1  After the natural gas is vapor   ized from the crude oil  the applied temperature is raised  and the hydrocarbon with the next highest vapor point is  obtained  The 
6. acteristics    Therefore  viscosity is a very important consideration  when selecting a diesel fuel        Carbon Residue   Ash or carbon residue is the deposit left in the com   bustion chamber due to incomplete combustion or the use  of fuels made from residual blends  It can be measured in  the laboratory by heating a measured fuel sample in a  closed container in the absence of air  Carbon residue is  the final product that remains in the container after  heating  This product is then expressed as a percentage by  weight of the original sample    The amount of carbon residue considered acceptable in  diesel fuel oil varies depending on the combustion chamber  design  the injector adjustments  and the general condition of  the engine  This amountis generally more critical in small high  speed engines than in large Sow speed industrial engines    Soot ash  which originates from either additives or the  crude oil itself  also causes wear of fuel injection compo   nents  the pistons  and the piston rings  Standard require   ments allow for a maximum of  001  soot ash content   Due to air quality concerns  future legislation may further  limit the amount of soot ash a diesel engine can produce     Sulfur Content    The wear of pistons  rings  and cylinders in a diesel  engine generally increases when there is an excessive  amount of sulfur in the fuel  Excess sulfur content also       Good Poor    spray pattern spray pattern    Figure 14 5  Proper fuel viscosity results in a g
7. alue of fuel is a general indication of how  heat energy is supplied to an engine and how well the  engine converts heat energy into work  The heat value can  be found by testing with a calorimeter  With this test  a pre   measured amount of fuel is burned and the amount of heat  emitted is carefully measured in Btus per pound of fuel  A  British thermal unit  Btu  is the amount of heat required to  raise the temperature of one pound of water one degree  Fahrenheit  The metric equivalent of this unit is Known as  a joule  To convert Btus into joules  multiply by 1054 8     Specific Gravity   The specific gravity of fuel is a ratio of the fuel den   sity to the density of water  It is measured using a hydrom   eter  Specific gravity affects the fuel   s spray penetration as  it is injected into the combustion chamber  Because water  is the standard  it has a specific gravity of one  Since oil  floats on water  a diesel fuel   s specific gravity is always less  than one  Diesel fuel   s specific gravity ranges from 0 8 to  0 94  Specific gravity is also a factor in measuring the heat  value of the fuel  In general  heavier fuels usually have a  greater heat value per gallon  Btus  than lighter fuels  Thus   specific gravity is a good indicator of the amount of heat   Btus  available in a given amount of fuel    The American Petroleum Institute  API  employs  another scale to determine specific gravity  Water has a  specific gravity of 20 on the API gravity scale  Ten is the  lo
8. blending  2 diesel fuel  with kerosene  Fuel suppliers will often do this themselves  and market it as    winter fuel     Although this fuel will be  more viscous at lower temperatures  its performance will  stll vary depending on where it was purchased  A 40 60  blend in one area may have a higher cloud point that a  40 60 blend in another  A fuel additive with a cloud point  depressant will have limited effect  At most  it will lower  the cloud point by 3 4       Pour Point   Pour point is another common way of measuring a  diesel fuel   s performance in cold weather  It is the min   imum temperature at which fuel can flow and is expressed  as the temperature 5  F  8 8  C  above the level at which the  oil becomes solid or refuses to flow  The pour point aver   ages about 10   lower than the cloud point  Fuel treated  with special additives called flow improvers or wax modi   fiers keep the wax crystals from forming clumps and  choking fuel lines  They will generally give satisfactory per   formance at 9   lower than untreated fuel  However  fuel  improvers do not have any impact on the fuel   s cloud  point  since they do not prevent the formation of wax or  paraffin crystals themselves     Viscosity    Viscosity or stiffness is the property of a diesel fuel that  resists the force which causes the fluid to flow  It is related  closely to specific gravity and pour point Two common  methods of measuring viscosity are the Saybolt test and the  kinematic centistokes test  Bot
9. cetane number required by most on highway  vehicles  cetane improvers are added to the blends  The  lower cetane compounds are less responsive to these  improvers than the higher cetane pareffin fuels        Octane    100  90           80 Slow burning  70    Fast burning    30  40  50    Cetane  Figure 14 4  Comparison of the relationship between octane  and cetane  Note that as the cetane number increases  the burn  rate increases     The improvers promote early  uniform ignition of fuel  and prevent high pressure increases in the combustion  cycle  Depending on the amount of cetane components in  the base fuel  typical alkyl nitrate additive treatment can  increase cetane by three to five numbers  1 1000 ratio   With  high natural cetane premium base fuels  containing a high  percentage of paraffins  and a 1 500 alkyl nitrate treatment  ration  cetane may increase as much as seven numbers    Most improvers contain alkyl nitrates  which break  down readily to provide extra oxygen for combustion   They also break down and oxidize fuel in storage   However  they also generate organic particulates  water   and sludge  all of which degrade fuel quality  Recently   several new cetane improvers or reformulaters without  alkyl nitrates have been used and  properly blended  will  improve oxidation stability while providing a cetane  increase of two to five increments    It is only recently that engineers have learned how  important the cetane level is in meeting the emissions  equat
10. eakage problem    O The visible leakage of fuel from a line during  operation and shutdown    O The opening in a suction line or fiting which  pulls foreign material into the system during  operation and may or may not present a visible  leak during shut down    Visible leakage should be stopped as soon as it is dis   covered  Loss of flow volume generally means a loss of  pressure  The leak which allows fuel contamination by  pulling in air  water  or dirt is more difficult to locate and  can be more damaging  Foreign materials  such as air  sed   iment  dirt   and water present problems and can enter the  fuel system in various ways     Air   Air drawn into the fuel system may make pick up of  fuel much more difficult or prevent it entirely  In addition   it may show up as   Q Low power  QO Gear pump wear   OQ Rough operation    OQO Soft or non responsive throttle    Air enters the fuel in any one or more of the following  ways    O Suction leaks  lines  fittings  filters  or tank    Q Fuel turbulence  especially when coupled with  poor tank venting           Q Fuel pick up point near retum   O Combustion gases entering injector           This sample chapter is for review purposes only  Copyright    The Goodheart Willcox Co   Inc  All rights reserved        Chapter 14 Diesel Fuels   Dirt  Dirt is as damaging to moving parts in the fuel system   as itis in any other part of the engine  Dirt can    Q Clog filters    Q Abrade metal surfaces    Q Increase combustion chamber dep
11. etermine the ignition quality of the fuel oil   Diesel fuel oil is injected into the combustion chamber in  liquid form  The fuel must then be able to vaporize quickly  and ignite without a flame or spark  This ability to vaporize  and ignite easily is called ignition quality    The ignition quality of a diesel fuel is determined by  its cetane number rating  or cetane value  The cetane  rating or value of a diesel fuel is based on the ability of the  fuel to ignite  The cetane rating of a fuel is determined by  comparing it with pure cetane  which is a test fuel  and is  identified by a cetane number  Figure 14 4  This cetane  number represents the percentage of pure cetane in a ref   erence fuel which will exactly match the ignition quality of  the fuel being tested  The cetane rating scale ranges from O  to 100  with 100 being the highest ignition quality    In general  the higher a fuel   s cetane rating  the lower  the emissions  Currently  a 40 cetane or above rating is  standard for all on highway diesel engines   In some areas   50 cetane and higher are current standards   Newer diesel  engines may require higher cetane fuel  The diesel engine  service manual will specify what cetane number to use     Improving Ignition Quality   Fuels with poor ignition qualities can be improved or  reformulated by blending them with fuels that have good  ignition properties  The cetane number of such blends are  an average of the cetane numbers of the individual fuels   To meet the 
12. first hydrocarbon engine fuel obtained is  high octane aviation gasoline  If everything is working  properly and you continue to raise the temperature  other  hydrocarbon fuels such as commercial gasoline  kerosene   diesel fuel  domestic heating fuel  industrial fuel oil     Chapter 1 4    Diesel Fuels    lubricating oil  and paraffin are obtained  Finally  only coke  and asphalt remain    The type of hydrocarbons obtained will vary depending  on the original geographic location of the crude oil  This  heating of crude oil to obtain various hydrocarbons is  known as distillation  It is a highly complicated process and  precision control of pressure and temperature is required        Diesel Fuel Grades    While the American Society of Testing Materials   ASTM  has divided diesel fuels into three classifications   only two recommended grades are considered acceptable  for use in high speed trucks and buses in North America    These are the number 1D and number 2D classifica   tions  Grade number 4D  the heaviest diesel fuel  is used in  large stationary constant speed engines or in some marine  applications  Number 4 and bunker fuels are not used in  high speed mobile diesel engines  which are continually  accelerating and changing speed  Grade number 3D was  discontinued a number of years ago and is obsolete    The Canadian govemment 3 GP 6D diesel fuel has its  own fuel specifications recognizing five categories of diesel  fuels  with even more restrictive standards set by A
13. found above ground    Tanks are made of steel  fiberglass  or steel clad with  fiberglass  Galvanized copper tanks are not used to store  diesel fuel  There is a chemical reaction between the fuel  and copper that produces a residue which will quickly clog  fuel filters  The term    tank systems    includes the piping  connected to the tank s     In some large industrial operations  diesel fuel is fed from  the main supply tank located  above or in the ground  outside  of the building to a one day tank in the engine room   Figure 14 7  This tank has a sufficient capacity to provide fuel  for one day of operation  The main storage normally stores  only a one week supply of fuel  Fuel stored for longer periods  of time can form gum which  along with corrosive com   pounds  causes deterioration  Many refineries are also using  additives that help stabilize the fuel in order to reduce gum for   mation  Moisture condensation inside a fuel storage tank  increases as the tank size increases  Condensation in a large  tank can be reduced by using a series of smaller tanks and con   necting them into the line as needed  The size of tanks is gen   erally controlled by the Bureau of Fire Underwriters and local  regulations     Alternative Fuels    The Clean Air Act of 1990 requires that all centrally  fueled on highway transportation operations of 10 or more  vehicles in certain high emission areas are to phase in  alternative fuel vehicles beginning in 1998  The act does  not mandate an
14. g oils in addition to soybean and processed animal  fats can be used in the making of biodiesel fuels    Industry interest is high in biodiesel since it is nota  stand alone fuel like the other alternative fuels  but rather a  blend with existing diesel fuels  This means little or no alter   ations to the fuel injection system are necessary  nor is any  special training of service personnel needed  The two most  popular blends today are 20 30  soybean oil to  80 70  diesel oil  In physical properties  biodiesel has  almost the same btu gallon ratio as number 1 diesel  Further   it has slightly better lubricating qualities than number 1  diesel  can handle winterizers and has a gel point slightly    Particulate    matter   grams bhp hr     higher than number 2  It has very low toxicity if ingested and  is actually biodegradable by some standards    The main drawback to biodiesel is its relative high  cost in comparison to regular diesel fuel  Biodiesel is now  being tested in some city buses and is seeing increased  popularity for use in marine diesel engines  In the near  future  biodiesel fuels may play a major role in the future  in reducing engine exhaust emissions  Figure 14 12    More money and time must be spent on alternative  fuel engine development  on board fuel storage  and  fueling facilities before they can become a reality  At the  present  diesel fueled engines are still cheaper and more  efficient than any of the proposed altematives  With the  federal mandate
15. gine converts heat energy into work  Specific gravity  is a ratio of the density of fuel to the density of water    The cetane rating or value of a diesel fuel is based on  the ability of the fuel to ignite  There is currently no  common method of removing dissolved water from diesel  fuel  Free or nondissolved water in the fuel tank usually  comes from bulk storage tanks  from condensation  or from  dissolved water  Free water gets into the fuel as storage  tank bottoms become agitated while dispersing or  receiving fuel    Fuel additives are commonly used to improve diesel  fuel flow properties under cold or winter like conditions   Additives can also help eliminate fuel contaminants    The importance of clean fuel in the operation of a  diesel engine cannot be overemphasized  Foreign mate   rials such as air  sediment  dirt   and water presents various  problems and can enter the fuel system in various ways  such as suction leaks  careless filling and handling  and  dirty fittings  and lines  It is important to periodically per   form inspection  cleaning  and maintenance checks on all  fuel handling and filtering equipment   The method of storing the fuel depends on the size of  storage tanks or drums  the frequency and method of fuel  delivery  climatic conditions  and local regulations  Fuel  stored above ground will deteriorate more quickly than  fuel stored underground due to the greater temperature  ranges found above ground  Underground storage tanks as  well as abo
16. h tests involve heating the oil  to an exact temperature and measuring its flow rate  through a standard sized orifice    The viscosity of diesel fuel is generally specified at  100  F  38  C   Viscosity of fuels for medium speed and high   speed engines normally ranges from 2 4 to 4 1 centistokes   cSt   or about 39 seconds Saybolt Universal  SSU   In gen   eral  any fuel with a viscosity lower that 2 4 cSt or 34 SSU   when measured at 100  F  38  C   will be too thin and could  damage injectors as well as other parts of the fuel system    Diesel fuel also has a low viscosity index  meaning that  itis thin when hot but gets thick when cold  A diesel fuel that  can go through an injection system easily in warm weather  may get too thick to flow propery in cold weather  As men   tioned previously  diesel fuel is supplied in several grades   Grade 1D is a winterized diesel fuel  It is thinner or less          This sample chapter is for review purposes only  Copyright    The Goodheart Willcox Co   Inc  All rights reserved           Chapter 14 Diesel Fuels   viscous than grade 2D  which is the fuel used at normal oper   ating temperatures  Diesel fuel viscosity also affects the spray  pattern in the combustion chamber  Figure 14 5  Low vis   cosity creates a fine mist  while high viscosity results in  coarse or heavy atomization  In other words  viscosity affects   Q Lubrication capability at various temperatures    Q Atomization  or spray capability    Q Ignition and buming char
17. ike ethanol  methyl alcohol is a colorless   odorous  flammable liquid  Methanol is currently being  used in several urban diesel powered bus fleets with some  success  It is one of the major contenders as a feasible alter   native fuel for heavy duty high speed diesel engines     Biodiesel Fuels  Biodiesel is a comparative latecomer to the alternative  fuels scene  but as on highway  off highway  stationary and    even marine engine manufacturers continue to investigate  any and all alternative sources of fuel  biodiesel is quickly       312    Second stage  regulators    ise aa                Fm        Solenoid shutoff vaive     ignition switch activated        First stage ean    Shutoff valve  Refueling receptacle  Refueling line    Protection ring    operating pressure OS    Engine  A 125 psig nominal pressure    coe Solenoid shutoff valve     low oil pressure activated             we i a       a CY    Check valve Fuel manifold tube    Diesel Technology        Manual shutoff valve   typical each cylinder     Composite cylinder    fuel storage    6 cylinders    Ze  Gey D        Fuel pressure  gauge         SaS    Figure 14 11  Schematic showing typical CNG tank arrangement under a bus   Diesel  amp  Gas Turbine Publications     gaining support in the transportation industry  At present  the  most popular is a biodiesel blend of number 1 diesel fuel and  soybean oils  There is also especially strong interest in  biodiesel from the agricultural community because used  cookin
18. introduce a biocide to  the fuel to prevent fungi and bacteria from growing in the  diesel fuel    There are a number of commercially available fuel  additives that will reduce smoke and corrosion of vital    Diesel Technology    parts  and others that are oxidation inhibitors  In addition   remember that geographical locations  operating condi   tions  type of fuel storage  handling methods  and mainte   nance procedures are all factors that can determine  whether or not a fuel additive might help a diesel fuel  In  most cases  the fuel supplier or marketer will select and  add the additive they believe will best improve the quality  of their fuels  Fuels containing special additives may be  more expensive than those without additives     Fuel Handling and Storage    The importance of clean fuel in the operation of a  diesel engine cannot be overemphasized  Diesel fuel is  generally delivered clean and free of impurities  However   every time it is transferred or handled  the risk of contami   nation increases  While fuel storage and its handling are  not normally within the engine technician   s job classifica   tion  the results of improper storage and handling certainly  are  A problem often found by the engine technician when  troubleshooting a diesel engine is dirty fuel    One of the major problems either in storage or in the  engine   s fuel system is leakage  Each connection or fitting  in either system is a potential source of leakage  There are  two phases to the l
19. ion  The airfuel mixing time in a direct injected  diesel is about one tenth the time of a carbureted gasoline  engine  Early ignition promotes smooth and complete  combustion  leading to reduced emissions  Excessive delay  can produce very high peak cylinder pressures which  make for rough and noisy engine operations  The higher  the cetane number  the shorter the ignition delay  which is  the time between the start of fuel injection into the cylinder  and the actual start of combustion     Cloud Point    Diesel fuel contains paraffin  and in cold temperatures  wax crystals can start to form  accumulate  and clog engine  filters  The temperature at which this happens is referred to  as the cloud point or wax appearance point  WAP    Generally  if the fuel   s cloud point is at least 10   below the    Diesel Technology    ambient temperature  engine performance will be satisfac   tory  The most commonly available and recommended fuel  oil  grade 2D  has a cloud point or WAP of 10  F   12  C    while the thinner grade 1D has a cloud point of  20  F    28 8  C   In extremely cold areas  engine clogging can be  minimized by using only grade 1D in winter  In most  places  mixing a base of grade 2D with grade 1D  or other  special additives will work well in colder weather  As a  rule  grade 2D   s cloud point drops two degrees for every  10  of grade 1D that is added up to a ratio of 50 50    One of the most effective chemical means for low   ering the fuel   s cloud point is by 
20. lfur diesel fuel  ULSD   ULSD  has a dramatically lower sulfur content than previous on   highway grade diesel fuels  The sulfur content of ULSD  cannot exceed 15 parts per million   0015  by weight     Using ultra low sulfur diesel dramatically reduces  diesel exhaust emissions  The lower sulfur content of ULSD  produces fewer sulfate emissions  It also enables use of  emissions reduction equipment  such as particulate traps  and catalytic converters  that lowers emissions of particles  and nitrogen oxides  NO    When these systems are used  with ULSD  emissions of fine particulates can be reduced  by more than 90  and emissions of hydrocarbons can be  reduced to nearly undetectable levels    Even without special emission reduction equipment   using ULSD reduces sulfate pollutants  ULSD fuel provides  significant clean air benefits while ensuring the same energy  and performance standards as regular highway diesel  Ultra   low sulfur  low aromatic  and high cetane number diesel  fuels enhance engine performance because improved engine  combustion results in easier starting  smoother running  less  noise  and less smoking during start up    Only off highway  non road diesel engines can cur   rently use higher sulfur content fuels  These include farm  tractors  boats  locomotives  and stationary engines  The  2007 sulfur content standard for non road  locomotive   and marine fuel  NRLM  is 500 parts per million  ppm   In  2010  all on  and off highway non road  NR  diesel fuel
21. matic at 100  F  40  C   cSt   Cloud point    F   Sulfur content  maximum  wt    Carbon residue on 10  maximum   wt    Accelerated stability total insolubles  maximum  mg 100 ml   Ash  maximum  wt    Cetane number  minimum  Distillation temperature    F    C    Initial boiling point  typical  10   typical  50   typical  90   Endpoint  Water and sediment  maximum        Figure 14 2  General classification chart for diesel fuel   Detroit Diesel     No  1 ASTM 1D    137 000  40 44  100  38   1 3 2 4  10  F  0 5  0 15  1 5   0 01   45    350  177   385  196   425  218   500  260  maximum  550  288  maximum  0 05    No  2 ASTM 2D    141 800  33 37  125  52   1 9 4 1  10  F  1 0  0 35  1 5  0 02   40    375  191   430  221   510  256   625  329  maximum  675  357  maximum    0 05          weather operation  many fleets still use Grade 2D in the  winter  Other cold weather aids include a fuel heater water  separator for easier starting  as well as fuel additive condi   tioners that can be added directly to the fuel tank    Like gasoline  diesel fuels are blended on a seasonal  and geographical basis to satisfy anticipated temperature  conditions  It is usually best and cheapest to bum the heav   iest fuel that will work under given circumstances  Heavier  grades of diesel can usually produce more energy than  light grades  just so long as the increased viscosity does not  make the fuel too thick to flow and inject properly    Itis important to remember that the wrong grade of diesel
22. nt of heat  emitted is called    A  British thermal unit  Btu     B  joule    C  flash point    D  Both A  amp  B        314    10       Volatility of diesel fuel is indicated when or    the fuel is distilled off    A  75     B  90     C  50     D  100       Sulfur is removed from diesel fuel by      A  distillation     B  hydrotreating     C  filtering     D  None of the above       Which of the following types of tanks should not be    used to store diesel fuel     A  Steel     B  Fiberglass     C  Copper     D  Steel clad with fiberglass       Fuel stored above ground will deteriorate    than fuel stored underground due to the greater tem   perature ranges found above ground       Name three ways air commonly enters diesel fuel     True or False  Flow improvers help redissolve paraffin  crystals that have formed in the diesel fuel     A Type Questions         Technician A says that grade 1D diesel fuel is gener     ally the most refined and volatile diesel fuel available   Technician B says that grade 2D is more widely used  in truck fleets due to its greater heat value per gallon   particularly in warm to moderate climates  Who is  right     A  A only     B  B only     C  Both A  amp  B     D  Neither A nor B       The of fuel is a general indication of how heat    energy is supplied to an engine and how well the  engine converts heat energy into work     A  heat value    B  viscosity    C  flash point    D  cetane number rating      All of the following are contaminants 
23. of diesel fuel    EXCEPT     A  water    B  dirt   C  cetane    D  air     10     Diesel Technology      All of the following are diesel fuel properties EXCEPT      A  heat value     B  pour point    C  specific gravity    D  octane rating       The temperature at which wax crystals begin to form    in diesel fuel is Known as the   A  cloud point    B  pour point    C  viscosity point    D  specific gravity level      The viscosity of diesel fuel affects all of the following    EXCEPT     A  the lubrication capability of the fuel at different  temperatures     B  the cloud point     C  the burn capability     D  the atomization capability       The of diesel fuel is based on the ability of the    fuel to ignite    A  volatility   B  specific gravity   C  cetane number   D  viscosity      Technician A says that fungus and bacterial growth in    diesel fuel can be eliminated by draining setted water  out of the fuel tanks at regular intervals  Technician B  says that the only way to eliminate bacterial growth  entirely is to treat the fuel system with a biocide  Who  is right     A  Aonly     B  B only     C  Both A  amp  B     D  Neither A nor B       Diesel fuel tanks can be made from     A  galvanized copper    B  aluminum    C  steel clad with neoprene   D  fiberglass    Technician A says that as the temperature of diesel  fuel goes down it will hold less dissolved water   Technician B says that there is no common method  now available for removing dissolved water from  die
24. ood spray pattern   However  improper viscosity will give a poor spray pattern     307    causes varnish to form on the piston skirt and creates oil  sludge in the engine crankcase  Sulfur also combines with  water to form corrosives as a result of the combustion  process  These corrosives can etch finished surfaces  accel   erate engine wear  attack softer metals  Such as bearings    and deteriorate engine oil  Similar corrosion damage from  sulfur is frequently found in the engine   s exhaust system    Sulfur and aromatic content of diesel fuel are most respon   sible for harmful exhaust emissions  Sulfur dioxide emissions  are reduced when sulfur content is reduced  The reduction of  aromatics will reduce carbonaceous particle emissions    Sulfur is removed from diesel fuel in a process called  hydrotreating  Hydrogen is used with a catalyst at temper   atures between 500 and 800  F  260 and 430  C  to react  with the sulfur compounds present  The reaction forms  hydrogen sulfide  which is separated from the hydrocarbon  and sent to a sulfur plant to be converted to elemental  sulfur  The sulfur content can only be determined by chem   ical analysis of the fuel    EPA regulations mandate the sulfur content in diesel  fuel  The 2004 standards called for a sulfur content of no  greater than 500 parts per million   05  by weight  and a  maximum aromatic content of 35  in all on highway  diesel fuels  EPA regulations for 2007 on highway engines  require the use of ultra low su
25. ose as possible to that of a diesel without  making major component changes  Figure 14 8     Compressed and Liquefied Natural Gas    Natural gas has been used for 60 years to power industrial  intemal combustion engines  Natural gas is one of the lightest  fractions  parts  of crude oil  Chemically  it is very similar to  gasoline  Unlike gasoline  natural gas contains several light  gases  heavy gases  and other impurities  For natural gas to be  used as an altemative fuel for on highway vehicles  it must be  refined into either compressed natural gas or liquefied    Compressed natural gas  CNG  is composed primarily  of methane and hydrocarbons that have a high carbon to  hydrogen ratio  Hydrogen is an ideal fuel that bums well  while producing litte pollution  It is the main reason CNG  is a very desirable fuel  It produces good power  economy   and low exhaust pollution levels     On board fuel tanks for the storage of CNG while the  vehicle is on the road is a problem that needs to be  addressed  For example  experimental taxi cab operations   using two or three tanks placed in the trunk  had a range of  only 120 160 miles  192 256 km     Liquefied petroleum gas  LPG  is mainly propane and  butane  along with small amounts of other gases  It has  combustion qualities equal to or better than high grade  diesel  LPG is a vapor or gas at normal room temperature  and atmospheric pressure  This presents some design prob   lems  In fact  since LPG is not a liquid  the entire f
26. osits    Dirt enters the fuel when    Q A suction leak is in an exposed area    QO Dirt collection in the tank allows it to be picked  up with the fuel          O Careless filling and handling permits mud  dust    or grime to enter tank or lines   The technician may unintentionally add dirt to the  fuel system by    O Using containers and tools exposed to dirt    O Using lines and fittings that have accumulated   dirt or dust without cleaning them out   O Allowing dirt to enter a line while it is removed  for repair  This is especially critical between filter  and pump     Water    Water in the fuel may show up as low power  also  but  it is even more damaging as already stated when it simply  contributes to corrosion on fuel system components  Water  enters the fuel system through    OQ A suction leak in an exposed location   QO As condensation due to warm fuel   O Careless storage and handling    Careless storage and handling of diesel fuels can be a  major concem in the engine   s operation  Figure 14 6  It is  important to periodically perform inspection  cleaning and  maintenance checks on all fuel handling and filtering  equipment  Many state and local regulations include  record keeping and periodic inspections     Storage Tanks   Diesel fuel tanks may be underground storage tanks   UST   or above ground storage tanks  AGST  systems   Fuel stored in AGSTs will deteriorate more quickly than the  fuel stored in USTs due to sunlight exposure and the greater  temperatures 
27. quate clearance underneath the bus  Figure 14 11  to allow  for several tanks  In addition  most city buses do not accu   mulate as many miles in a day as would a long haul  tractor trailer  Buses can also be fueled up locally at their       Figure 14 10  Buses in some major cities are now able to  operate on compressed natural gas  CNG    Pierce Transit  Inc      depot by a fast charge facility  which takes about the same  length of time as it would to fuel up a diesel powered bus     Alcohol Based Fuels    Alcohol based fuels are being studied as an altemative  fuel for the transportation industry  The two types used to  power intemal combustion engines are ethyl alcohol  ethanol    and methyl alcohol  methanol   Alcohols are especially desir  able as an automotive fuel because they can be manufactured  from sources other than crude oil  Alcohol intended as an  automotive fuel must be almost pure  Quite often  several  refining steps are needed to approach this purity    Denatured ethanol or    grain alcohol    is colorless   harsh tasting  and highly flammable  It can be made from  numerous farm crops such as wheat  corn  Sugar cane   potatoes  fruit  oats  soy beans  or any material rich in car   bohydrates  Crop wastes are also a source  One of the  major drawbacks of using ethanol  clean buming as it is  is  that it does emit carbon dioxide  CO 5     Methanol or wood alcohol can be made from wood  chips  coal  oil shale  tar sands  comstalks  garbage  or  even manure  L
28. sel fuel  Who is right     A  A only     B  B only     C  Both A  amp  B     D  Neither A nor B           
29. uel  system must be redesigned to handle it  Figure 14 9        Figure 14 8  Natural gas engines are used in place of basic  diesel engines in some mobile and stationary applications    Diesel  amp  Gas Turbine Publications           This sample chapter is for review purposes only  Copyright    The Goodheart Willcox Co   Inc  All rights reserved                     Chapter 14 Diese  Fuels 311  Control switch  Relief lhe Special LPG  valve L carburetor  mixer   Converter changes  d LPG from liquid to a gas eE        Fuel strainer  fuel lock    High pressure    EE  eee    To engine  cooling system     _  LPG tank    Toported                 E    wesectan       Ce ad    y        NS    vacuum source    Figure 14 9  Simple schematic for a liquefied petroleum gas  LPG  fuel system     LPG has operating characteristics almost identical to  those of gasoline and diesel  However  because it is  already a gas  the problem of breaking up liquid fuel is  eliminated  Since the fuel enters the intake manifold and  combustion chamber as a vapor  combustion is much more  efficient For this reason  LPG is generally an excellent  alternative fuel  Liquefied natural gas  LNG  has the same  characteristics as LPG    A heavy duty truck would need too many fuel storage  tanks to make it a feasible concept at this time   Conversions on city buses  however  are presently being  done in several big cities  since fuel tank storage is not as  great a problem  Figure 14 10  In most cases there is ade   
30. ve ground storage tank systems must meet rigid  safety and environmental regulations    Storage tanks should be made of either steel  fiber   glass  or steel clad with fiberglass  Galvanized and copper  tanks should not be used to store diesel fuel  The most  promising alternative fuels are compressed natural gas   liquefied petroleum gas  liquefied natural gas  methanol  and ethanol     313    Important Terms    Hydrocarbons Fungus   Relative volatility Bacteria   Distillation Leakage   Heat valve Foreign materials   British thermal unit  BTU  Air   Joule Dirt   Specific gravity Water   Flash point Underground storage tank   Volatility  UST    Ignition quality Above ground storage  tank  AGST     Cetane number rating  Altemative fuel vehicles    Ignition delay  Cloud point ka AAE  P int   Our poin Liquefied petroleum gas  Viscosity  LPG   Carbon residue Liquefied natural gas  LNG   Soot ash Ethyl alcohol  Sulfur Methyl alcohol  Hydrotreating Biodiesel       Review Questions    Chapter 14    Do not write in this text  Place your answers on a sep   arate sheet of paper     1  Which of the following grades of diesel fuel are rec   ommended for use in high speed trucks and buses    A  number 1D     B  number 2D    C  number 4D    D  Both A  amp  B     2  Like gasoline  diesel fuels are blended on a  and basis to satisfy anticipated temperature  conditions     3  Heavier grades of diesel fuel usually produce  energy than lighter grades     4  The value s  used to measure the amou
31. water at any given tempera   ture  As the temperature goes down  the fuel will hold less  dissolved moisture  There is currently no common method  of removing dissolved water from diesel fuel    Free or nondissolved water in the fuel tank usually  comes from bulk storage tanks  from condensation  or from  dissolved water  Free water mixes with the fuel as storage  tank bottoms become agitated while dispersing or  receiving fuel  When water in vapor form is present in air   itis called humidity  As air replaces fuel in storage tanks or  vehicle tanks when the tanks disperse or receive fuel  mois   ture in the form of humidity finds its way into the fuel  system  From there  moisture may condense as hot fuel  returning from the injectors flows back into the cooler fuel  tank  Free water in liquid form is heavier than diesel fuel  and settles on the low flow or slow flow areas of the fuel  system  The reverse is tue when water freezes  Ice is  lighter than diesel fuel and floats in the system to create  plugs in fuel separators  filters  even going as far as the fuel  pump injectors        Fuel Additives    Generally  no fuel additives are necessary when a  good quality  clean  and properly selected fuel is used   Certain fuel characteristics  however  can be improved by  treatment with a fuel additive or conditioner  As already  mentioned  additives are used to improve fuel flow prop   erties under cold or winter like conditions  increase the  cetane number of the fuel  and to 
32. west value on this scale  the reverse of the system just  described  Diesel fuels generally range from 20 to 45 on  the API gravity scale  with most ranging between 34 to 36  at 60  F  15 5  C      Hash Point   A fuel   s flash point is the lowest temperature at which  it will give off flammable vapors in sufficient quantity to  flash or momentarily ignite when brought into contact with  an open flame  The flash point has no effect on engine per   formance or on its ignition qualities  It is specified simply  as an index of fire hazard   a fuel oil with an extremely low  flash point is dangerous to store and handle  Diesel fuel  flash points are not an indication of how they will ignite in  an engine cylinder  however  This depends on the ignition  quality of the fuel  For example gasoline  which has a very  low flash point  would be a very poor diesel fuel due to its  ignition quality     Volatility   Volatility is a fuel   s ability to change to a vapor  It is indi   cated by the air vapor ratio that is formed at a specific tem   perature  Diesel fuel volatility is indicated by a 90   distillation temperature  the temperature at which 90  of the  fuel is distilled off   As volatility decreases  carbon deposits  and engine wear increase  Depending on such factors as the  combustion chamber condition  more smoke will also affect  power output  performance  starting  and warnrup     Cetane Number Rating    The ease of diesel fuel oil ignition and the manner in  which it bums d
33. y specific alternative fuels such as gasoline          Figure 14 6  Care must be taken whenever filling a storage tank  A   Below ground tanks can present as much danger as above   ground tanks  B   Always take care when filling any vehicle   s tank   Heavy Duty Trucking and Andrew Ryder        310       Pr  Final as        Ls stage Secondary  L  filter filter    Diesel Technology    Injector  return    Vent    Primary  filter       Figure 14 7  Schematic of a stationary fuel system with day tank and storage tank   Waukesha Engine Div      or diesel  The altemative fuels now being considered for  use with compressed  diesel  type engines are compressed  natural gas  CNG   liquefied petroleum gas  LPG    liquefied natural gas  LNG   and alcohol based products  such as methanol and ethanol    The Clean Air Act regulations are closely tied to clean  fuel vehicle programs in each state   s air quality implemen   tation plan  Since the supply of certain fuels varies across  the county  not all states favor the same fuel  Southem  states are a big supporter of natural gas  while some  western states favor liquid petroleum gas  and a number of  midwestem states actively tout ethanol    Some engine companies are devoting research and  testing to natural gas  Many of their initial products are  being offered for urban buses  which are on a stricter emis   sions schedule than medium and heavy duty trucks  Engine  makers face the challenge of designing new engines with  efficiency as cl
    
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