Home

JAEA-Technology-2006-043:14.96MB

1. 1 20 TIC 74 GC MS DBP
2. DBP MS 1 155 2 171 3 227 155 100 171 45 227 209 21 2 1 2 TBP DBP MBP DBP 4 1 DBP ID MBP DBP MBP DBP MBP iA O 8 HBL ERR NEBR L LTA GC MS
3. 1 5mlGC MS 1ml 2 o gt JA EA Technology 2006 043 2 4 12 12 2 1
4. 5 6 809 TBP nDD IDBP MBP 100ppm DBP MBP MS 7 8 DBP MBPInDD 1000ppm DBP MBP MS DBP MBP 1 b 4 BSTFA 1 1 DINK 4 9 10
5. E ROW DCR Z JAEA Technology 2006 043 RN 7 10 3 m z18 m z28
6. 2 GC MS 2 1 IV GC MS 2 300kPa 980kPa 300kPa 2 He Tu 2 2 GC MS 1ml 1 5m1GC MS 0 5ml 3 GCMS
7. DBP DBP GC MS TMS DBP GC MS BP DBP MBP 1 TBP DBP MBP
8. 17 18 QC MS GC MS 15 GCMS
9. 3 HEY Ne say 2 4 DBP DBP GC MS DBP GC MS DBP V DBP DBP 1 TBP DBP MBP 2 JAEA Technology 2006 043 2 GC MS
10. 1 9V m z28 m z18 2 8 6 9 MS MS 69
11. JAEA Technology 2006 043 4 4 DBP Tet 1 BSTEFA H 1 24h 1 1 4 2 30 TBP nDD DBP MBP DBP MBP 100ppm DBP MBP nDD DBP MBP 1000ppm 2 a 1 24h
12. MOX E Fel XU E E DBP DBP 1 1 DBP 2 DBP 3 1
13. EA Technology 2006 043 JA 2 1996 2 HER 1 K Blau J Halket JA EA Technology 2006 043 1 DBP DBP 10 52 MBP 9 07 TBP 11 9 OFF nDD 6 6
14. DBP MBP MS 155 171 227 MBP GC MS 211 2483 227 30 TBP nDD DBP MBP 100ppm DBP GC 6 6 nDD HEL TORK 9 1 MBP 10 5 DBP 11 9 TBP DBP MBPI nDD 1000ppm 6 6 nDD H DBP HH 9 1 MBP 10 5 GC MS DBP 1 4
15. 1 1 1 GC MS GCMS QP2010 1 M GCH AC 100V 1800VA MS AC 100V 1000VA 18C 28C 40 70 RH HP 1 80mx0 25mmOD X0 25umID 60 C 325 C Film tin BE 300C MAX 12 10000 sec 99 9999 47L 11 76MPa GC 1 GC MS JAEA Technology 2006 043 uy 1 2 1 5mlGC MS 1ml 1 3
16. 10 1 3 DBP GC MS GC MS 11 12 My Document 13 10 1 4s S N
17. MANO G RTV 0 Q QD ANIH 5 x ota SQ ay ey ETI feel Ac shel sae eLa o faa allaa xi TIC amp MC 27 Ej eS Ja oO Pe 060313 CTMS 32 q FRI x100 000 000 Max Intensity 181 920 412 la 2 04 Time 11 583 Scan 781 Inten 247 723 Oven Tene 17383 BEZ Imaizumi 060413 Admin o 1 54 BraS 2006 04 13 1035 nDD FERIDAS 135628 zil 2006 04 13 11 15 D7 471 2006 04 13 11 55 8 SONTBP nDD 2006 04 13 1235 Ue S0NTBP nDD 2006 04 13 13 16 0 54 DBP MBP1000ppm TMS DBP MBP1 2006 04 13 1356 WD EDEP MBP1 2006 04 13 14 36 UNK 0007 ie TT IE 15 0 17 5 20 0 2215 25 0 27 5 30 0 Max Intensity 181 920 412 Time 12 792 Scan 936 Inten 2 055 279 Oven Temp187 82 x10 000 000 ric D gt 39 00 1 00 DBP 11 50 11 75 12 00 1225 12 50 12 75 lt a ese MAN aes 831 9 PER x Base Peak 99 2 014 276 Da 7 TSTD AE 0 7 we Abs Inten Rel Inten eed 9 L Ros wd MS DBP MB 997 ID UNK 0007 wt x 4 DBP MBP
18. 2 GQC MS 1 GCMS 22 H GC MS GCMS 23 JAEA Technology 2006 043 2 300kPa 980kPa
19. ppm 3 30 TBP nDD DBP MBP 100ppm DBP MS 4 DBP MBP 1000ppm nDD DBP MS 4 3 TMS 4 2 DBP GC MS DBP ppm GC TMS DBP 1
20. DBP 80 TBP n QDD nDD DBP MBP 4 1 GC MS DBP GC 1 Rtx 1MS 30mx0 25mmog 0 25um df 2 60 10 10 280C 10 280C S Et 60 C 0 22 32 min 3 280 C 4 4 5 5 He 45 0cm 6 7 1 100 8 EAS lul MS 1 RI 2 IF 280C 3 230 C 4 5 m z 45 500 6 1 2kV 7 0 5 JAEA Technology 2006 043 4 2 DBP GC MS
21. MS es 2 1 GC MS GCMS QP2010 1 GC AC 100V 1800VA MS AC 100V 1000VA T as 18C 28C 40 70 RH HP 1 380m X0 25mmOD X 0 25umID 60C 325 C 300C MAX 6 12 10000 u see 99 9999 47L 11 76MPa 7 oF N H 2 2 AY ZAER ae 1 GC MS 1 4ml 2 1
22. DBP Rs nDD DBP 0ppm DBP H 7 2 gt fi 10 100ppm 4 CHS H
23. TBP 97 3 DBP 30 000ppm 100 TBP DBP 122 3ppm 509 TBP DBP 1ppm DBP DBP DBP RT 99 MS TBP TBP TBP 4 7 TBP
24. 319 1195 2 4 JAEA Technology 2006 043 Analysis of Dibutylphosphoric Acid DBP in Degraded Solvent by Utilizing Gas Chromatograph Mass Spectrometry Hirobumi IMAIZUMI Yasutoshi BAN Toshihide ASAKURA and Yasuji MORITA Division of Fuels and Materials Engineering Nuclear Science and Engineering Directorate Japan Atomic Energy Agency Tokai mura Naka gun Ibaraki ken Received July 25 2006 In JAEA a washing process of tributylphosphate TBP in the Purex reprocessing have been investigated by means of n butylamine oxalate as a washing reagent which is decomposable by incineration or electrolysis The concentration of the dibutylphosphoric acid DBP in organic and aqueous phase has been determined by an ion chromatography In this analytical method however we found out that the quantitative analysis for DBP exhibited poor reproducibility because of low sensitivity for DBP Here we report a new analytical method for DBP by means of a gas chromatograph mass spectrometry GC MS From our investigation silylation of DBP was efficient to improve the sensitivity and the reproducibility of the quantitative analysis for DBP Moreover we found out that the silylation was effective for the analysis of monobutylphosphoric MBP Keywords Degraded Solvent Dibutylphosphoric Acid Monobutylphosphor
25. DBP PEL 4 1 DBP MBP 1 DBP DBP j DBP MBP MBP MBP TD DBP MBP ID 3 1 2 ID DBP MBP TBP DBP MBP 9 JAEA Technology 2006 043 DHI 1 4mlGCMS 1ml
26. OFF 1 4 DBP MBP ff DBP MS 1 155 2 171 3 227 MBP MS 1 211 2 243 3 133 2 E DBP Oppm 5ppm 10ppm 20ppm 50ppm 100ppm 200ppm 1 2 8ppm 5 4ppm 8 1ppm 16 4ppm 44 8ppm 2 a 2 7ppm 5 2ppm 7 7ppm 13 2ppm 43 6ppm 97 8ppm 205 5ppm 3 A 2 7ppm 4 3ppm 6 6ppm 13 5ppm 37 8ppm 97 6ppm 193 8ppm 4 a 0 1ppm 4 0ppm 8 5ppm 19 8ppm 54 1ppm 101 9ppm 5 E 4ppm 4 6ppm 7 6ppm 16 7ppm 52 4ppm 99 6ppm Sa 6 E 6 3ppm 9 4ppm 17 4ppm 46 7ppm 107ppm 7 E aa 1 5ppm 6 2ppm 18 2ppm 52 1ppm 99 7ppm 1 4 3 3
27. 15 GC MS GCMS GC MS DBP 16
28. 1852m y 1 YEE EI 1852 3600 m s a a dam 10 m MM ha 1ha 1 hm 10 n bar bar 0 1MPa 100kPa 1000hPa 10 Pa A A 0 Inm 10 mn b b 100fm 10 mn 9 CGS x A be eK F F H 10 HE rary pm P 1 dyn s cm 0 1Pa s St lcm s 10 mr s G 10 T e 1000 4z A m Mx 10 Wb sb 1cd cm 10 cd m ph 10 1x Gal lcm s 10 m s SI a Ci Ci 3 7X 10 Bq R R 2 58X10 C kg rad rad 1cGy 10 Gy Js rem rem 1 cSv 10 Sv X HO Ay X unit 1 002 10 nm ee g Jy Jy 10 W m Ha 7 x fermi 10 mn metric carat 200 mg 2X10 kg Torr 1 Torr 101 325 760 Pa me atm atm 101 325 Pa cal u v u 1 p tym 10n 7 1998 100 70
29. GC MS DBP 16 H r VA Sut JAEA Technology 2006 043 DEP GC MS 19
30. MS XF JAEA Technology 2006 043 Ds ow DBP MBP GC MS GC MS DBP MBP DBP MBP DBP MBP DBP MBP
31. DBP GC MS 1 2 We BT OT Bul a 30 TBP nDD DBP MBP DBP MBP 100ppm DBP MBP nDD DBP MBP 1000ppm 2 DBP GC MS 99 57 125 30 TBP nDD DBP MBP 100ppm 6 6 nDD 10 5 DBP 11 9 TBP MBP DBP MBPInDD 1000ppm 6 6 nDD 10 5 DBP MBP 309 TBP nDD DBP MBPI DBP DBP MBPInDD 10
32. C Documents and Sett bap 2 5 0000 C Documents and Sett bap 3 10 000 Efic Documents and Sett bab 4 20 000 C Documents and Sett hb 5 50 000 C Documents and Sett vA 6 100 00 E C Documents and Sett VAW 7 200 00 C Documents and Sett tensity 4 281 0 0 10 00 10 25 317 7 15500 6518 lt J 13 1GCMS m t Admin C osu S x oT BIE ny xb 000 000 My Documents Imaizumi 060222 PEA 060222 2006 02 28 15 08 Admin RF RF SD 9680660 17621 16 XRSD 54 93769 ID 1 gt 9 DRE 27 a n DD 363 723 1135373 all 100000 fF 2609241 NN 75 na 1 0 00000 ERC Documents and Sett Dh 2 5 0000 C Documents and Sett EAW 3 10 000 EBC Documents and Sett VAW 4 20 000 EB C Documents and Sett I DA 5 50 000 EBC Documents and Sett bh 6 100 00 E C Documents an
33. 3ml 1 2 GC MS 1 5ml 12 1ml 8 Sate 2 3 GC MS GC MS JAEA Technology 2006 043 3 rice T TBP 97 PIRK TEN DBP 95 DBP MBP MIX DBP MBP 6 4 n QDD 99 96 N O BSTTA 99 ALDRICH oun F won JAEA Technology 2006 043 4 GC MS
34. 2 3 24h DBP 10 100ppm DBP 5 10 DBP TBP DBP MBP MS TBP RARO DBP MBP DBP TBP nDD TBP DBP TBP DBP DBP TBP TBP DBP
35. 3 14 DBP DBP JAEA Technology 2006 043 4 6 TBPnDD TBP DBP TBP TBP DBP 1 TBP nDD 4 DBP 10 TBP nDD 30 TBP nDD 50 TBP nDD 100 TBP 2 4 30 TBP nDD 15 DBP 4 5 DBP DBP TBP DBP
36. BSTFA DBP JAEA Technology 2006 043 DBP CHs CH2 30 2P 0 OH 0 0 BSTFA aal ee C H 0 P OH IT C H 0 P OSi CH 0CH 0CH DBP MBP MBP CHs CH2 30 P O OH 2 0 0 BSTFA p _ C H 0 P OH mae ae C H 0 P MM aj 0Si CH DBP MBP OH BSTFA DBP 2 1 4m 23a TARZ 1ml 10vol1 BSTFA 0 1ml 80 1 2 GC MS 2
37. 1 1 4 DBP ETTOR DBP O 5 10 20 50 100 200ppm nDD 2 13 D i 2 oe eis clr TIC 0ppm N D 8 GC MS 5
38. DBP DBP TBP DBP DBP TBP DBP TBP DBP 1 TBP nDD JAEA Technology 2006 043 109 TBP nDD DBP DBP 1ppm 5ppm 10ppm 20ppm 50ppm 5 309 TBP nDD DBP DBP 1ppm 5ppm 10ppm 20ppm 50ppm 5 509 TBP nDD DBP DBP 1ppm 5ppm 10ppm 20ppm 50ppm 5 2 5 30 TBP nDD 5ppm 1 DBP 16 5 17 4 5 DBPnDD 2 2 30 TB
39. MBP MBP a EH 4 5 4 4 EH 1 1 7 JAEA Technology 2006 043 4 4 oe gt E DBP E 0 03 DBP 30 TBPnDD DBP MBP 100ppm DBP MBP 1 DBP MBP H 4 1 L MS 11 12 DBP MBPI nDD 1000ppm MS 1 1 HLM ORR DBP DBP
40. d m C SI 4 1 H ED x P i H v fe P rad s menm sles rad s mem e ss Wi kg s MAR JK Ie kg s2 kKT ee tee J kg K m s K S y Ee ee W m K Im kg es Kt g ZAE ag fags V m me kee seat VERVE H one tea fi Benes hs C m Im s A l F m H m J mol Ieee kg s mol f q gt RZ J mol K m kg s K mol X
41. 347 ISTD 3 1 JDBP BP 100000 989 697 120000 1 202692 140 000 1 391 525 760000 fF 1 603 701 F 97741 Eh 1 80 000 Acs DOCUMENTS AND S Eh 2 100 00 Ejc DOCUMENTS AND Vp 3 120 00 C DoCUMENTS ANDS LAW 4 140 00 2 FE wa x100 000 209 889 99 00 00 4 io is see MES 9900 139981 JER JAI EA Technology TMS 2 qgm 2006 043 BA Prt R D osa SC aif E E e e Bl DUE E sk x1 000 000 75 pele My Documents Imaizumi 060313 2006 03 13 14 08 2006 03 13 14 48 2006 03 13 15 27 2006 03 13 16 07 2006 03 13 16 46 2006 03 13 17 26 2006 03 13 18 05 2006 03 13 18 45 2006 03 13 19 24 2006 03 13 20 04 2006 03 13 20 44 2006 03 13 21 23 2006 03 13 22 03 2006 03 13 22 43 2006 03 13 23 22 2006 03 14 0 02 2006 03 14 0 41 10 TBP nDDC 10 TBP nDDC 0 TBPnDDC 30 TBP nDDC B50 TBP nDDC B50 TBP nDDC 1008TBP nD 100 TBPSnD gt 10 TBP nDD 30 TBP nDD 50 TBP nDD IRENA pemen em aeren EEE 2 10WTBP nDD 10 TBP nDD 30WTBP nDD 30 TBP nDD SOXTBP nDD SOXTBP nDD 100WTBP nD 100 TBP nD 10
42. DBP Oppm 5ppm 10ppm 20ppm 50ppm 100ppm 200ppm 1 A 4 2ppm 6 6ppm 9 3ppm 17 3ppm 40 9ppm 2 a N D 5 5ppm 8 5ppm 14 2ppm 43 5ppm 97 7ppm 206 0ppm 3 A N D 4 2ppm 6 4ppm 13 4ppm 37 6ppm 97 2ppm 193 3ppm 4 jE N D 4 0ppm 9 0ppm 19 0ppm 45 4ppm 97 2ppm 5 B N D 6 1ppm 8 2ppm 15 2ppm 47 5ppm 102 3ppm ae 6 E 4 9ppm 9 1ppm 19 3ppm 51 6ppm 103 2ppm 7 E 5 3ppm 9 5ppm 20 2ppm 50 0ppm 103 3ppm 1 4 3 13 4 TBP JAEA Technology 2006 043 TBP DBP TBP PELE 10 TBP nDD N D 4 0ppm 30 TBP nDD N D 38 5ppm 50 TBP nDD 1 0ppm 52 0ppm 100 TBP N D 122 3ppm 5 TBP DBP Ye yet PEE TBP DBP 1ppm 5ppm 10ppm 20ppm
43. fH C kg kg s A Gy s hes Wsr m tm kg sm kg s W m sr m m kg s kg s E 10 ae 10 2 eag e 10 yl m 10 u 10 F n o F z a p 0 Ff o 4 10 z 0 F y 6 SI min 1 min 60s lh 60 min 3600 s d 1 d 24 h 86400 s 7 180 rad gt 1 60 z 10800 rad 1 1 60 z 648000 rad 1 Lil 1 dm 10 my t t 10 kg Np Np 1 B B 1 2 1n10 Np 7 SI SI ERT eV 1 60217733 49 X 10 J ie ua 1 49597870691 30 X10 m 1 6605402 10 X10 kg 8 SI
44. GC MS 4 10 100ppm
45. CE G RTV E SI fa or Sle 2 15 Sle a its IARI AI PAARE DTP E safa IUA Imaizumi 060222 ITMS STD DBBP STD TMS STD DBP 0ppm DO1 ITMS STDDBP 5ppm_002 TWS STD DBP 10ppm 003 TMS STD DBP 20ppm 004 ITMS STD DBP 5nppm n05 TWS STD DBP 100ppm 00 TMS STD DBP 200ppm_00 ITMS STD DBP ppm TMSfESTD 0ppm 1st TMSfESTD ppm 2st ITMSfE STD 0ppm 1 ITMSf STD 0ppm 2 Cx100 000 000 Max Intensity 197 804 811 ric Time Scant Tnten Oven Temp so 75 mo a5 Two Ts arm PE EE as ao x100 000 Max Intensity 197 804 811 ric Time 9 528 Scan 544 Inten 509 398 Oven Temp155 28 a 155 00 1 00 ea 211 00 1 00 5 0 4171 00 1 00 2 54 bd o T T T T T T 4 ss ss 10 00 T025 10 75 TT Ties 1150 fai gt 10508 10475 lt gt 10608 ty 662 658 lt gt 674 Base Peak 155 862 660 PO Tss Mz 112 00 Abs Inten 6 Rel Tnten 0 00 x100 000 Max Intensity 663 682 A LEGAU 000 155 00 a c R T zl 1227 00 5 3 Ges PRE JAEA Technology 2006 043 EZ osal So e
46. J N m m kg s rs RI ba W J s m kg s Bow A uy C s A V W A m amp 7 F C V m Q V A m DYED AASS RA S A V m Ro Wb Ves m He T W m kg H Wb A m K x lm ed sr m m cd cd FR lx 1m m m m cdm cd a A Bq s lt Hee ee Sv J kg mes a 4 b rad sr 1 sr
47. K BA P P2790 HP 1 MS 000 3200 0 0 p71 CG 46GB Inten x100 000 Max Intensity o 1 754 E 1 504 1 254 1 004 a SPL1 VF 0 75 0 504 Rm y 150 175 20 0 2215 2510 27s 30 0 min ama poze io Z z SAF Inten x10 000 Base Peak 0 0 APACE 1 254 1 004 0 754 0 504 olsa Se oe E Bled ix Imaizumi 060413 yf 060313 ARC 2006 04 13 17 09 Z Microsoft Word ml allat MS7m U 000 1000 0 45 00 0 00 12 MS u oleo PT ia Bee cc SEE ey 2 ID 73 yh HP 1 MS FEIRE BT MS 000 3200 0 3S 0 FEIT C 46GB Inten x100 000 Max Intensity 9 1 754 aj ADE 1 504 1 254 a _______ 1 004 1 SPL1 VF 0 754 0 504 ae 0 254 En 5 Sao ASRS SMR 3S ALERT 7G RT aa aL Gama lo naan Gt Sage Oe a a AE m e 000 ARES 0 SRE Inten x10 000 Base Peak 0 o AFAEE F 1 254 1 004 0 754 0 504
48. 1 4 MBP OFfRH 10 309 6TBP nDD DBP MBPI 100ppm HH MS JAI EA Technology 2006 043 96 TMS 237 97 TMSE 21 Max Intensity 64 183 667 m a Time 10 353 Scan 643 Inten 1 298 324 a ine rid z mr am gt 2006 02 20 9 44 g 7 2006 02 20 1024 an 7 5 10 0 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 e t 116 2006 02 20 1 103 x10 000 000 Max Intensity 64 133 667 W s 2 6 2006 02 20 11 43 Time 10 929 Scan 712 Inten 21 897 593 a 317 2006 02 20 1222 w ails 2006 02 20 1302 o o 2006 02 20 1342 4 DBP 1 H DBP A 2006 02 20 1421 2006 02 20 1501 2006 02 20 15 40 i 129 179 207 243 281 325 362 389 429 492 49 Ohya 658 gJ im 130 zdo 230 ado 330 ado Ei 3 as 7 22 TMS TMS 0007 20 38 10475 ga ts1se 162 207 243 ze 325 343 373369 410 444463 495 ey 858 sl id 130 2d0 230 ado 330 ado 430 sdo z 29 MSE DEED TMSE D BE2 0008 20 pri 31 129 179 597 43 e1 g 3 40 443 465 497 BA 12 306 857 id 130 2d0 230 ado 380 ado 480 sdo 4 iss p24 TMS DEREP_TMSE 56E 2 0009 20 Fat e EP ban ith ra a e capt tas estan iiep St
49. Wl 060220 Time 8 619 Scan 435 Inten 4 992 817 a Imaizumi 23 F rrr am 4 gt MSE D 2006 02 20 9 44 3 TS Pa a TT nT SRR a oT ETT DG tlie 118 Cx10 000 000 Max Intensity 64 133 667 TMS Dia 2006 02 20 11 43 nora en ees S 3 7 TMSE 2B 2006 02 20 1222 04 BB ale TMS 2006 02 20 1302 o o TMS 2006 02 20 13 42 4 MBP jz 1 H MBP E EA TMse Dig 2006 02 20 1421 a TMS 2006 02 20 1501 MS 2006 02 20 15 40 q sl 1d0 130 2d0 230 ado 330 ado Ei sdo 5 37 129 163 207 239 281 299 339 359 401 417 459 4390 5l 100 150 200 250 300 350 400 450 500 a5 38 P 129 tet 207 255 281 299 327341359 403 447461 459 sl 100 130 EE 230 ado 390 ado a30 sdo ay 243 45 se 91 119133 1e1 zo4 269283 gna 359 39o 429 491 sl ido 180 ado 230 ado 330 ado 430 sdo zT Gs 243 a n 15 181195 269283 341 359 404419 453 480493 5l 100 150 200 250 300 350 400 0 500 T a E 73 a5 us 181195 269283 341 402 453469 496 5l im 190 2d0 230 ado 390 ado ago sdo ii 243 AS a 1 Bid 1811 269283 at as E im 130 ado 230 ado 330 ado ago sdo Tit 18 243 5 73 u5 181195 269283 341 aig ass a sl 100 150 200 250 300 350 ado 0 500 pra rT TMS 0006 20 486 ho TMS TMS 0007 20 9042
50. 0005 20 2 119133 teg 207 227 245 ze 325 341 s79398 ago Be 660 Bp ee sl 10 150 2do 230 ado 330 o 0 sdo yy 155 Pik TMSE mS vy 7h TMSB b ia Sl Be 2 D TMSE 55 3 267283 309 341 363 385 30 de2 aa 660 al 100 130 2d0 230 ado 230 o a0 sdo 155 TMSE TMSE 55 75 91 123 197 iii 267 283 355 414 436 46 391 een poal i 660 al 100 130 2d0 230 ado 330 o o sdo Hez PAT TMP TMSP 22 75 81 tas 197 237 7283 313 a 462 8 660 E 100 130 2d0 230 ado 330 o Ei so Stat eo aa TMSP 55 75 31 129 7 e 267 283 355 416 433 459 493 660 al 100 130 2d0 230 ado 380 o 30 sdo 7 F AAT Admi Th 414 Mic ft Word cm Olu 1425 1 4 DBP OFRH 9 309 TBP nDD DBP MBPI 100ppm H MS lacs Admin 7 1 x H7O RTV MIRO HIWRRO MARIW AIH 3X 2 a x a mE glaa ll s4 1 TMS 52TMS 93TMS 94 TMS 55TMS 86 TMS FhE237 97 MS 7 a x100 000 000 Max Intensity
51. GC 2 M MSiH Eco m Ea te 3 x AO1 E6010 Ox111e Admin JAEA Technology 2006 043 060313 TMS 2 ml 2 alalt los PT We BANE R Bd Osa ao a 2 A elo J 730927 0 9 22k ha Sh T Go PAE DUN hy seo Le Mimaizumi 060313 ai MS FEE RA rs 000 3200 TESO 30 PII 466GB 060313 AEC 2006 03 23 1031 KAD E E a ADE E 1 54 RIVONIA 1 04 az En x su yO NE zm R CM 7s toe BE KED T75 EH 225 Hg 275 3000 min Fa m z 000 NIE REE 0 intenCx10 000 Base Peak 0 0 1 25 a 1 004 0 754 emiso Go v azzemine A gt FEA MOB PEI TSP ARAB ie C p C DE BARV p e C p C IBE WENER Y c eE BEO x BA GE TIA OCTTFI E600T _ 2006703731 141447 GCMS ea TI ARF FP GCNMS
52. 4 029 282 6387 Fax 029 282 5920 7 319 1195 2 4 This report is issued irregularly by Japan Atomic Energy Agency Inquiries about availability and or copyright of this report should be addressed to Intellectual Resources Section Intellectual Resources Department Japan Atomic Energy Agency 2 4 Shirakata Shirane Tokai mura Naka gun Ibaraki ken 319 1195 Japan Tel 81 29 282 6387 Fax 81 29 282 5901 Japan Atomic Energy Agency 2006 JAEA Technology 2006 043 DBP RR MA 2006 7 25 PUREX DBP
53. si ny sb TMS 52TMS 3 TMS 94 TMS 55TMS 96 TMS 7 57TMS j x100 000 000 Max Intensity 189 472 200 ug F ImaizumiW060220 FE Time 10 730 Scant 689 Inten 31 638 a ne a Fl be sab f 1 04 2006 02 20 9 44 3 OGM 1024 Apap AAP RAED ETT a RIO RET TES tlele Ts x10 000 000 Max Intensity 189 472 200 2006 02 20 11 43 Tine 10 989 Seant 720 Inten 18 944 343 lt me 317 2006 02 20 12 22 ECS ale 2006 02 20 13 02 8 o o neea amore 4 DBP 1 DBP TMS 2006 02 20 1421 PAE TMS 2006 02 20 1501 ETMS Dig 2006 02 20 15 40 TSE SEE TSE DRE OOO 20 ee se ia 207 Shes 10402 Oy 183 256 355368 367 A7 444 as 495 FEE 660 sl 100 150 200 250 300 350 0 500 are aS p20 TMS TMS 0003 20 Aii 69 se iza 207 REI 10492 a3 1 7 443 660 gt sl 10 130 2d0 230 ado 330 o 430 sdo See NE a5 i2 i IREI ge aga apa 207 zasi zei es angaso ago ee PU sl 100 En EE 230 ado 330 o EE sdo 5 foy 4 me ea TMS
54. 4 GC MS 1 4ml GC 1 2 PO MS 1 300kPa 980kPa 2 GC MS GC MS SW PC CRT 1 GC 1 100 1hr 2 200 1hr 3hr 3 280
55. 6 754 do Ia sdo ado E WO 100 00 5713 m z 00 131 00 219 00 414 00 502 00 614 00 E 633080 362164 330999 33903 43710 2345 5221 535 689 037 AR RAE maz 340 01 470 5039 4944 35 104 200 98e 000 62e 004 lt lt lt lt kV Pa Pa 10 GC MS ADE e SPL1 Ea wa SAF AEE GC Ea fe VF FP GCMS 334 Admin JTO REO oela S IFW REO Bl a l E SS wl e altll Lu elol JAI EA Technology 2006 043 60202 2 qetl PA Dz Imaizumi 060413 yf 060313 C 2006 04 13 17 09 lt Zai PP GCMS 34 Admin FY 060313 Br REO RTV REO A foo C pao ATKO IF ii He 500 900 OO EN 45 kPa fs67 ml DARED 52 o m WERV M50 cm 0 BO ml ZIMER ham ajoo oo 000 3200 A HP B 025 um a RE 300m FYE 025 mm ID EO READY
56. png 14 No JAEA Technology 2006 043 QC MS
57. sl EE 130 zio 230 ado 330 do Ei sd 155 S85 TMS TMS ivi 227 faam ioaz 55 75 91123 137 267 203 355 394 4z9443 477 agg 658 a im 130 2d0 230 ado 390 ado 430 sdo TTT 36 TMG DDE TMSE ERD k ss 7 1 iz3 197 267 1 55 se 4 475 4 ie ey i a id 130 2d0 230 ado 330 ado Ei sdo 195177 FAT TMSE DEEZ E TMSE DHEERA TE 5s 75 91 ia 197 iess 267289 sl sss 381 oe ass a75 499 4 gJ id 130 2d0 230 ado 380 ado a30 sdo slo ia o Ha 2 g ahi ee 75 123 197 7 14 194 4 eee 658 amaa 3 CRAT DEE O 0 ado ado a0 a x KI iz Admi 11 E 414 Microsoft Word IDBP MBPI 1000ppm DBP MS SIGCMS m t Admin H FE RTV WEP YD 900 4 ae se si alg al pH ny sdb FIDRI MI TMS 52 MSE g 1 10 000 000 24 TMS 55TMS Max Intensity RE TMS 7237 17 TMSE 21 64 133 687 m a m z HTIRE IREN Ol Admin 2006 02 21 FPR KIRS IN TMS 2770 D TMSE D
58. 0 C FIERDE PERTO a5 2 ky UMA ESI JO u LEERD 0 320 PR GOMS Adm EA Technology 2006 043 art RRO IEW ARRA FRAO D X Ca oe se ETS af altl tu elol 080 kV pit zix nE TE ee oT o i wT Imaizumi 051216 method 1221 BEI MS Ts 59 99 7 60 00 REES 6600 ZEE 18462 1 50 2005 12 16 959 STD Wax Intensity 205 176 Om 2005 12 20 1757 2 00 ftic 0 10 a ADE SiE 9 00 1 00 2005 12 16 1353 eb VK RE 2005 12 16 1512 an 2005 12 16 11 32 oo G 1 25 1 ete Sn VF nee EEN 0 TR oe 0 25 a a are eee T ET 1510 2010 2510 soro 3510 40 0 45 0 5s0r0 55 0 min LE x ka ED m z 4505 F 5 2785 Base Peak 57 57 471 Ata Aaah lt Inten x100 3 ii g 95 oc amp MS Ti G GOMS QP2010 x ho so CC 0 JSS 45 fs ky 2 SIO Du Lanai DD M MS7m7 4 UD GC7m7 4 6000 60 00 000 Eo Z Y G IGCMS Hara Adm SE
59. 1hr GCMS OK Oa GCMS QB z 5 GC MS GC ID Admin 2 GCMS Nt Ni GC MS 3 5 TB 4 6 GCMS X AT 3
60. O 18 GO SHER MS RHA FASE 30 HT 46GB nE Max intensity oI EE 4 ADE 1 254 1 004 1 SPL 7y VF 0 754 0 504 AFR 0 254 MR 7s too Tals KED Ws 200 2205 2500 275 30r0 min a ma prt BAZ SAF 1 Base Peak 0 m z I Ch2 m z pit Word Sasar MS7h7 U GOC7m7 32 00 000 45 00 000 BAY BAY 500 00 000 ft 14 zix HPT MS aR i isase nan aoon n an 5 46GB C Documents and Settings Administrator My Documents X WS a a ADE E Sy BO TBP nDD DBP50ppm x ras PP IDO SP VF F770 BOXTBPSnDD DBP100ppm TMS 1_UNK 0003 20060413 5 1m FYH ma ma SAF 5 Base Peak 0 o AA j FAROU i BL WISE comem WH Sis FID a aI IAT pi Ea pe gt gt 1do ado a30 0 25 GC S ms GCMS QP2010 0 230 PARDED 280
61. x1 000 000 is 10517 gt 663 AE Admin soi i i 227 aaae d s ga e if actin i Pea 4 type 1 at ido 130 20 2350 ado 330 ado ado sdo ey ae Ware 1 743 TMSP TMS 2 0004_20 IYIN TMSP Cena essing 00517 2 D TMSP Hi Ziva 6al MS HA aie 1 227 ood ss gn 128 197 dess 267283 se sss a3 ss am rm 730 zo zo zio zio ado Bo sm 94 TMS TMSE 0005_20 x1 000 000 osi gt 663 TE m n 227 ie 197 dess 267283 313 sat aso 401 43o es ago st 100 190 200 250 300 350 ado 450 500 5 309 TBP nDD DBP MBPI 100ppm DBP MS RTV 0 2 5x fa a t 4 al Cx100 000 000 Max Intensity 185 725 014 m2 fc z GCMSsolution Data Project 2 04 Tima 3 109 Soank 434 Intan 204 628 ee rer am gt 1 04 2005 06 01 1212 20065712Z01539 5 0 7 5 10 0 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 t l 115 2005 12 20 1608 10 000 000 Max Intensity 185 725 014 uls 216 2005 12 20 1641 Time 3 663 Scan S61 Inten 15 461 002 lt 3 7 2005 12 20 1654 5 04 zm 2006 01 23 1353 px A a 3 2006 01 23 1433 tE eee as MBP E 2006 01 31 1022 2006 01
62. 060313 2006 09 23 1031 PNGGTBOS057 Wax intensity o 0 0 a ADE iioi RTIII RD see as 24 aay a x su w preis 0 0 ATE 5 0 7 5 10 0 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 min SRE m z 000 AREE 0 IntenCx10 000 Base Peak 0 9 ma s iot SAZ 1 004 EE 9 754 PR Goib amen sire 2 g s mM MSME O m Ea te FEIRE SRO TIENER U ma Cpa Cia BAKTIR moo ma Cpe Cie ma C ea AEN CEDIA RE x ia RGGTTF E600 TiTe Admin Admin ae Fr Gem PEL Ear u llelol Z GC MS P Q FAMOSES Bo T5Y RARE BR C pi 2 C p 000 3200 AEE 0 0 PIT C 466GB Inten x100 000 Max Intensity o 1 84 1 04 so 75 oro 1205 1500 175 2010 22 5 2510 275 50r0 min SRE m z 0 00 ACRE BEE 0 Inten x19 000 Base Peak 0 0 1 254 1 004 0 754 4 ADE i RTINT FD Jag 4 z seu a 24 pis a SAF AEE
63. 04 13 17 09 2006 04 13 1227 2006 04 13 13 07 2006 04 13 14 43 2006 04 13 16 30 2006 04 13 15 08 2006 0413 15 48 2006 04 13 11 07 2006 04 13 11 47 2006 04 13 16 29 2006 04 13 17 09 2006 02 01 133134 EDIDI z 9 635870 ag 336892 44855 10000 5298 705 060 058 060 eee m z 502 16045 Me Joo wx wz2 V323 WA RF RF AR RAE 340 01 470 5039 4944 35 104 200 98e 000 62e 004 lt kV Pa Pa Admin 060201 _2 qet GC MS ADE E AAR Ea wa TAZ SAF APALE F GOES ola 1 ae FE RTV REO A OD ea Sie fav a Sle wl 2 ee 2 gt ILIRI N gg IDBP MBP1 Z IREE 2006 04 13 17 09 2006 04 13 1227 2006 04 13 1307 2006 04 13 14 43 2006 04 13 16 30 2006 04 13 15 08 2006 04 13 15 48 2006 04 13 11 07 2006 04 13 11 47 2006 04 13 16 29 2006 04 13 17 09 fale Ey Fal x100 G 2006 02 01 13 31 34 Base Peak 69 00 633 980
64. 1000ppm nDD DBP MS JAEA Technology 2006 043 nDD TBP 1GCMS m t Admin ERIE RTV MBP ALEAR TN hh A GCMSsolution Data Project zl Max Intensity 185 725 014 m z i X Time 9 109 Scan 494 Inten 204 688 yyy am f gt tol 1 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 e 5 Wax Intensity 185 725 018 MS 2 6 Tine 11 051 Geant 727 Inten 204 588 lt 7 2l 2005 06 01 12 12 2005 12 20 15 39 2005 12 20 16 00 2005 12 20 16 41 2005 12 20 1654 2006 01 23 1353 2006 01 23 14 33 2006 01 31 9 43 2006 01 31 10 22 2006 01 31 11 02 2006 01 31 11 41 2006 01 31 12 20 2006 01 31 1300 2006 01 31 13 39 2006 01 31 14 19 2006 01 31 1458 2006 01 31 15 37 2006 01 31 16 17 2006 01 31 1657 2006 02 17 9 56 2006 02 17 10 36 2006 02 17 11 15 0 7 5 x10 000 000 MBP PERESA 11100 5 aE E r 1 af F A RNa tah 2006 02 17 1155 FSF NSE A 2 tee 2006 02 17 1234 npase nnn faan iosi 2 2006 02 17 1314 an aie amp 2006 02 17 1353 ee mm 227 awene s o a a Aa a a a aa i A S al id 130 2d0 230 ado 330 ado 430 sdo 5 ena 2006 02 17 1552 42 TMS TMSP 0003 20
65. 197 GaN Some tron 2006 1 ao frie Fa Tme 10h22 Scant 552 Inten 20 152 Oven renp164 22 a 10 TBP DBPG0ppm 1 UN 20067 155 00 1 00 att EA S0KTBP DBPCOppm 1_UN 2006 1 1 IANT EA OXTBP DEPEOppm 1_UN 2006 04 30wTBP DBPGOppm 1 UN 2006 04 30wTBP DBPQOppm 2 UN 2006 04 3 UNK 0008 2 2006 04 4_UNK 0003 2 2006 04 30 TBP DBP0ppm 3 UN 2006 1 5_UNK 0006 2 20067 6_UNK 0007 2 2006 ET Base Peak 155 353 209 IRENA 155 m z 266 00 Abs Inten 24 Rel Inten 0 01 200 x100 000 Wax Intensity 355 961 s x1 000 000 155 00 al 1 75 3 54171 00 1 pg i227 00 1 50 A 30 TBP DI 9 ID UNK 0008 DA soft Word 16 30 TBP nDD 5ppm 1 DBP MS JAEA Technology 2006 043 ppm 100 90 80 70 60 50 40 30 20 10 10 20 30 40 DBP ppm 17 TBP DBP 50 10 TBP nDD 30 TBP nDD 1 4 30 TBP nDD 2 gt lt 50 TBP nDD JAEA Technology 2006 043 GC MS GC MS
66. 486 MS 9 042 486 en TMSP 42 iny iei TMSE 0008 20 TMSE 0009 20 85 TMSE E235 t_TMSE DERA ara 9 042 eet eS 486 pr ae E TMSE 9 04 ee est FAT TMSE TMSE 0 042 Fees 486 p88 TMSE MERSE TMS Di AIL gang 9042 reyes 486 Uh 4 14 Mic 12 DBP MBPI 1000ppm 1 4 MBP MS 20 JAI EA Technology 2006 043 ER E RTV DEW MRE D WVEIW Dl a se BIS a e telat Al oleu a PA za Imaizumi 060220 5 0 4 0 afjoso222 REC 2006 08 22 10 31 3 0 x1 000 000 RF RF 175533 SD 9630399 RF SRSD 5486375 9 DRE ARO BRO BEG a g 70 ub 100 we 2R 1 1 0 000000 RPEN 2 5 00000 FZ 68175 3 70 0000 Fg 139 496 4 20 0000 FZ 363 723 5 _ 50nnn 1116211 5 100000 fs 2609241 a Nn wi 5797145 H aa 0 Sonia TIC 1 0 00000
67. 50ppm 10 TBP nDD 9 2ppm 13 1ppm 14 6ppm 24 8ppm 52 3ppm 30 TBP nDD 50 0ppm 53 0ppm 59 4ppm 69 0ppm 98 9ppm 51 7ppm 52 5ppm 63 6ppm 61 8ppm 93 1ppm 59 1ppm 53 8ppm 57 6ppm 43 0ppm 50 TBP nDD 60 6ppm 61 0ppm 63 5ppm 72 9ppm 98 6ppm JAEA Technology 2006 043 DBP org 1 org 6 1 org 6 2 org 6 3 S org 6 4 org 6 5 org 6 6 org 6 7 org 6 8 std25ppm 65mM NaOH 18 19 20 21 22 23 min 1 DBP DBP 2 DBP NaOH DBP JAEA Technology 2006 043 nDD TBP SIGCMS m t Admin 7 4 30 TBP nDD DBP100ppm TMS 3_UNK 0005_20060413_5 qgdl REPO G D O YD IIRI a 3x sa ale a E J glali eea yp aliea ES a gt ater a Te I Poel 060313 TMS 2 m Max Intensity 176 215 958
68. Admin T Mi Ca 060201 2 Admin get ae F RTV REO 0 D H olsa Sa faut se oT BIE wm 78 AS al gt EE ES ARE ef gt 2006 02 01 133134 IIb al wl _ GO FEWE YimaizumiW060413 F HA v MS PRE 2006 04 13 1709 Ea Fao vV ERR T 2006 04 13 1227 SN 23 pr v ADE e 2006 04 13 1307 brs Fv 2006 04 13 1443 Ry peg am 2006 04 13 1630 T page Raat ReAt oas J ea 2006 04 13 1548 Wor Fs Vv sel aye 2006 04 13 11 07 eal 2006 04 13 11 47 AT 2006 04 13 1629 Ree 2006 04 13 1709 o wy eH CR r E ee AFEEF GAZ Pa mae Pa mz e a mz fig m p2 J fo fs fo 8 YV 7Fa2yv7 ie nn EP GCMS Admin F JAI 060201 EA Technology 2006 043 gg F RTV REO ID 00 H osm aR a a E S l 2 ie ie A em gm 30 TBP nDD 30 TBP nDD H serena EP GCMS Admin 2006
69. TBP nDD 30 TBP nDD 50 TBP nDD ASTUTE p 14 294 59 629 192 883 70 0000 200000 50 0000 100 000 SFAORF 8202843 IRF SD 6 492 018 RF WRSD 7914351 VAW 4 20 000 C DOCUMENTS A IA 5 50 000 CpocUMENTS AND S Wh 6 100 00 C DoCUMENTS ND S LA 7 200 00 3 wr x100 Max Intensity 155 00 171 00 227 00 7 RT10500 FTF ee 657 100 00 000 000 22700 ol PO RRO RTU WW EED FORMA pleja ao ow gt wel 9 alfa l A Hona BP GC SET 2 SUN hyo ie lmaizumi 060313 Ea DYM HP Eoo EAD 1 MS 000 7 3200 SS n 0 2 1 465GB A060313 2006 03 23 1031 wae ESTOS Max Intensity oC OO p 4 ADE ite vee IKANI ED 4 er 82 1 04 oh EES ae VF 0 54 Bay 0 AAR ME M PREO Is 3000 i x ORES mz I OFF a a ma AS Base peak 0 0 SAZ SAZ a EE MS M A ago Ba SOs 7 z He M OU EN
70. ee es Se te eS wk WS GC M S a Be a i oe iii JAEA Technology 2006 043 Contents 1 Introduction 2 General Descriptions of GC MS 2 1 Specification of the Equipment 2 2 Specification of Sample 2 3 Equipment Operation Procedure Reagent 4 Result of Analysis Method A A A A A BB 1 2 3 4 5 6 7 Analytical Conditions Identification of DBP Peak in Chromatograms Tetra methyl silyl TMS Derivatization Method Identification of DBP Peak in Chromatograms with Silylation Quantitative Analysis Detection of TBP and DBP in TBP nDD solution with and without silylation Effect of TBP Concentration on DBP Analysis 5 Conclusion Acknowledgement References Appendix Operation procedure of GC MS o 0 NO OO fF A U N NY WY NY BAe N e e He BR N N oO JAEA Technology 2006 043 1 6 Na CO2 N HzO
71. 0 254 a ae Hi EI zio zio ao wo ado wo 5 25 esD GCMS QP2010 x p30 D 0 0 C ere G 45 12 kV HHE fO u LEGH O GC2m 5 JAI EEE m allal l lol EA Technology 2006 043 554 Admin 7 060313 TMS 2 qgm qed gt 1 060202 2 qgt a EZ 060313 REC 2006 04 13 17 09 a TBLIZIN 3 yf 060313 2006 04 13 17 09 afjosos1 3 TI Ose sje K REG wl x E g ol Bf B35 FD A lt gt F429 0 lt gt 0 3 DVD RAM 3200 m z EIEN 2 RES riage _ My Documents GOMS aP2010 F GCMS240UPJ EAN 23 TBP DBPPrintscreen PARRE D 280 ORR amumo pO p AEE UD o 3200 000 050 000 45 00 ES 000 lay 50000 000 Admi lala Lu
72. 1 MSH qem 1 UNK 0O15 0 13 TMS 2 qgm 12 UNK 0016 0 13 TMS 2 qgm 1 UNK 0017 0 13 TMS 2 qgm UNK 0018 LES 13 TMS 72 qgm gt SA serena gt _INUM 42 JAI EA Technology 2006 043 ER TIO G 0 MD MPP olsa Sa a ET E 9 e el 7 30 y 0 IRAk My Documents Imaizumi 060313 yf 060313 2006 03 23 1031 Admin 3 DRR ba i DE rh AE wF 10 06410 Max Intensity a 8 3b ido 349 rae 2 lt HA E M poleja ae x OT BI 9 Peal e x TNS My Documents Imaizumi 060131 2006 01 31 17 11 Admin Z 20 9995 694x 0 0 R 2 09991774 R 09995886 8 x1 000 000 9 PDRE ID
73. 189 472 200 TIC X 2 oat Tine 8 807 Scant 458 Inten 31 638 Wh yw aA gt 1 04 2006 02 20 9 44 4 2mm 024 DEE ziele 1 8 x10 000 000 Max Intensity 189 472 200 2006 02 20 11 43 oe ee S 7 2006 02 20 1222 au 5 a z ale 2006 02 20 1302 H eas H J 8 vw MBP t 1 MBP t 2006 02 20 1421 vice 4 2006 02 20 15 01 2006 02 20 1540 3 84 3 04 af 2 54 2 04 1 54 1 04 0 54 q ER ER eN ee on EAI CH 92 aTe oa 5 al F a TMS TMS 0002 20 s gt oe 129 iea 207 256 ase 401 421 443 a63 487 Sfr tan S 100 180 200 250 300 350 0 450 500 7 2399 1as 207 f gaar aea as o aoa fpei sl im En zio 20 sd EE o EE sd 5 hd TMGE MREP TMS 0004 20 ei soe en sl 1d Wo zio 230 j Eg jo Bo sd zr 4 TMSP TMSP 0005 20 sg 2H 9050 sein 163 Roz 243 2etzee 359 aao ag ez bie pono 5l 100 150 200 250 300 350 0 0 500 iii 35 MGE ERSTE TMSE Di 45 78 ns 3 181495 269283 314 359 415 aas ser Q 4871 5l Tdo En 2d 20 sd EE D 339 sd a eee ZIT PAIE TMS 73 133 zas aie rare 5 us 181195 263283 241 259 453 a69 492 bagel 487 5l ido En zh EN sd 280 o o sdo TT pred i alams TMSE 5 73 nis 138 1s119 269283 anasa aep agi ascasy 439 aem Gr J im Ei 30 EN sd En o o sdo ay 243 Pae TMSI SIE TMS DEF EA us 133 18119 269283 sts s41 s71 see 425 ss 439 Ree ual 3 im 130 2d 3235 sd Eg ado ago sd Gh 4 14 Microsoft Word
74. 2 he 2 He 1 4ml 5ml 83 GCMS JAEA Technology 2006 043 2222 yyy MATTE 4 5 GC Su gt JAEA Technology 2006 043 ML KO AAA ZZ PV MIVA fy MTL BR A _ a Trai AY i LAN REI EE 6 JAEA Technology 2006 043 GCMS Microsoft W 1 GCMS a a oo I h i fl i A 8 tay Sula us ite ICONS ainia ays gpul solujon b d sso pm 3 3 i 2 5 OS ee 3 a t g 4 gt T rs 7 2 Z JAEA Technology 2006 043 HP 1 1 MS 000 32 00 0 0 Ly oka C 466GB Inten x100 000 Max Intensity o 9 92 5 0 W REC m z 0 00 Inten x10 000 oro i
75. 31 11 02 2006 01 31 11 41 2006 01 31 12 20 2006 01 31 13 00 2006 01 31 13 39 2006 01 31 14 19 NOE 2006 01 31 1458 A 2006 01 31 1537 2006 01 31 1617 2006 01 31 1657 a ER 2006 02 17 956 E L2 2006 02 17 1036 AA 2006 02 17 11 15 2006 02 17 1155 FT E 2006 02 17 1234 peii r 20751 2006 02 17 1314 gt 490 2006 02 17 1353 Ch tat 283 2006 02 17 1512 1 1g J sf a als ao ado e Se 2006 02 17 1552 90050 7 52 TMS TMS 0003 20 zT 0075 3 04 REES 490 zas ootas 72 ni 181195 269255 ana aan ase so ee asa ag 3 4 4 a Wd 130 2d0 230 sd 380 ado ado LD Tes A EAA x1 000 000 A iu lt o WAN DIME ou ewe a MS WA 5 04 243 oo L4 115 181195 269 El 341 4 3 474 497 sl im 130 2d0 230 sd 390 ato ago sd ein cose x1 000 000 estan ga i2 i 490 3 04 2as ce 133 5 q ms us 181195 269 14 i 1 im 130 2d0 280 sd 390 ado ao sd xi 7 4 r Th 414 Microsoft Word 6 309 TBP nDD DBP MBPI 100ppm MBP MS ISIGCMS m t Adm JAI EA Technology 2006 043 H 77O RTV WEP D YD m z m a syr am h gt S aR fat m
76. 4 T55 T55 227 55 T3 dii 123 137 267283 313 355 381393 425 449 age 489 sh dm 130 200 230 ado 330 ado 430 sdo TMS 0006 20 iam tose 10508 i J Ee 602 g YES 662 H E RTV WEP D YD alal alal ait X EE NUM B1 TMSE DER TMS 2TMS 323 TMS TMS JTMSE 28 EA TMSe 18 EA Tse ia ETSE 8g ETSE ia TMSE ETs Dg ER TMSe n A4TMSE HED TMS 2752 SRST aE SS x10 000 000 Max Intensity 49 045 614 mf g v TE T Tine 3 222 Scang 506 Inten 103 136 a i F r aw el Boon re 2 54 a 2005 06 01 1212 E 2006 12 20 1699 Omen ee ORR ORER ORK CREE ORE OBER ORT ORE tile afs x10 000 000 Max Intensity 49 085 614 his 6 2005 12 20 1641 1 754 cant 770 Inten 5 830 606 lt 3 7 2005 12 20 1654 IAEA 2006 01 28 1353 alel 2006 01 23 14 33 2006 01 31 9 43 2006 01 31 10 22 2006 01 31 11 02 2006 01 31 11 41 2006 01 31 12 20 2006 01 31 13 00 2006 01 31 13 39 2006 01 31 14 19 2006 01 31 1458 2006 01 31 1537 2006 01 31 16 17 2006 01 31 1657 2006 02 17 9 56 2006 02 17 10 36 2006 02 17 11 15 2006 02 17 11 55 2006 02 17 12 3
77. 4 2006 02 17 1314 2006 02 17 1353 2006 02 17 14 33 2006 02 17 15 12 2006 02 17 1552 y 1 504 1 254 1 004 0 754 0 504 0 254 MBP 8 55 7s os os ons OO 5 Ei st 000 000 aT Er IMSE iaie 000620 zT fap 489 5 04 zas 0 0185 us iS 181495 269288 sis sar 359 aot aig ass a98 a do En zh 280 sd EI ado ago sdo sr 000 000 oer ore at Ses 8 5 04 eas zas PE E 1 1811 269283 gia 341 7 4 475 493 a im 130 2d0 280 sd 390 ado ado sdo TMSE TMSE 0008 20 1o tla000 000 2 067 489 5 04 ia zas 5 us KEE 269283 241 359 401417 453 461496 sl Tdo 130 sd 20 sd 390 ado ago sd x1 000 000 73 o E us 181195 269283 313 341359 393 420 454 476 498 sb im 130 ado 230 ado 390 ado aso sdo x1 000 000 243 133 Ai 243 133 EEE 115 1811 269283 31 4 a 3b im 130 TD 230 ado 330 ado rn sdo k eras 7 1 906 ae BB mene en 9 067 g 489 eee TMS 0009 20 LTMSE 0010 20 8 t Word DBP MBPI 1000ppm MBP MS 5 MS MS JAI EA Technology 2006 043 GH E RTV 2 alb at mE Es alg l YD 00 ANID
78. E e sel sel l FF SH TMSE 2ER TMS 2857 32 TMS 2ER _TMSE AREF 93 TMS 2ER _TMSE DEET 24 TMSE AEE _TMSE 71 SS Ola x10 000 000 Max Intensity 49 045 614 J GCMSsolution Data Project El s 04 Time 8 222 SeanW 508 Inten 103 136 2 84 a 2005 06 01 1212 a q SE iD sh 75 mm Tas To TE zoro zals En Ts enn x10 000 000 Max Intensity 49 045 614 2005 12 20 16 41 spar Tine 365 Font 767 Inten 5327 092 EA TSE 18 JTMSE 248 JTMSE 288 JTMSE 248 TMS TMS TMS TMS TMSE TMSE 2 2005 12 20 1654 2006 01 23 1353 2006 01 23 14 33 2006 01 31 9 43 2006 01 31 10 22 2006 01 31 11 02 2006 01 31 11 41 2006 01 31 12 20 2006 01 31 13 00 2006 01 31 13 39 2006 01 31 14 19 2006 01 31 1458 2006 01 31 15 37 2006 01 31 16 17 2006 01 31 1657 2006 02 17 9 56 2006 02 17 10 36 2006 02 17 11 15 2006 02 17 1155 2006 02 17 12 34 2006 02 17 13 14 2006 02 17 1353 2006 02 17 14 33 2006 02 17 15 12 2006 02 17 1552 gt geen Rien PINB fvse 7 ID TMS wr 1 504 1 254 1 004 0 754 0 504 0 254 DBP E 7 le 3 i E N x1 000 000 71 10 0 pee Ss 91 123 197 267283 303 341 363 403 434 ee 487 3b id 130 2d0 230 ado 330 ado a30 300 x10 000 000 1 0
79. HIY K 4 aw SR 3200 0 3 0 mL MA 9 Han HP B 025um 2 es ES 300m Pa 025 mm ID TIERA READYF 7 0 Admin 22 a RRO Prd WED JAEA Technology 2006 043 FF A 5 D DD Wi allat i lolelol B a a IW BSP MET ey 7 DID GC Pe MS MET MS 000 7 3200 THIES 0 0 PITA 465GB Inten x100 000 Max Intensity o 95 ADE 1 54 RITENE RD ae 1 04 EE co zeo SPL1 VF 9 54 x J ME 7 5 10 0 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 min REE REND mz 0 00 AAEE 0 a ms Inten x10 000 Base Peak 0 o SAF COMER Bmt 3 M MSE m azxanine SPL gt A fc cs po c x 71 5 han 7 He 500 900 HFW eae x 945 kPa isa mu DAR
80. JAEA Technology GAEA 2006 043 DBP Analysis of Dibutylphosphoric Acid DBP in Degraded Solvent by Utilizing Gas Chromatograph Mass Spectrometry FRA Hirobumi IMAIZUMI Yasutoshi BAN Toshihide ASAKURA and Yasuji MORITA Research Group for Aqueous Separation Process Chemistry Nuclear Science and Engineering Directorate September 2006 Japan Atomic Energy Agency gt TI a D 5 oe lt X http www jaea go jp index shtml 3 7319 1195 2
81. P nDD 10ppm 17 TBP DBP TBP DBP DBP TBP TBP DBP 4 DBP TBP 17 DBP TBP TBP DBP TBP DBP TBP TBP
82. RO 52_ wm s MEROV 0 cm 3200 3 Rie RE me Ea HP 1 BE 025um eS it RE 300m PAE 0 26 mm ID Rites m SI 2 SI igi SI MuE ne HE w E m E m s m s Bui 2 bom ml kg m kg E H FB Alt AM mol m yE cd m 1 1 3 SI SI Bs II i rad mm 1 4 f sr 9 m A i b Hz s W an t ibe SA N m kg s E JI s FS A Pa N m m kge s
83. a Time 11 700 Scan 805 Inten 35 244 Oven Temp177 00 BEZ Admin Dras 2005 11 15 17 42 2006 04 13 13 16 09 2005 10 05 17 39 Daw 3471 2005 10 06 17 44 j R 2005 10 0 1654 2005 10 17 18 49 o s4 30 TBP nDD DBP100ppm T 2005 10 18 19 04 WD 2005 10 19 20 05 UNK 0005 2005 10 26 17 47 5 0 7 5 10 0 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 FR WN 2005 10 27 17 27 UA 2005 10 28 16 42 2005 11 02 1658 2005 11 16 17 39 Max Intensity 176 215 958 Time Scant Tnten Oven Temp b ric 5 0 9 00 1 D0 2005 11 30 1815 me 2005 12 09 1831 3 04 9 2005 09 28 1815 DBP a 2006 01 05 1826 2 04 2006 01 11 17 45 2006 02 17 18 24 2006 02 20 17 45 0eoz22STD 2006 02 23 1551 w I060222 STD 2006 02 23 10 37 F wi 060222 TMS 2006 02 22 17 47 ah 06022771F 2006 02 27 18 45 Sere 051212 2005 12 12 1813 rae AES OT 060227 2006 02 27 1856 4 Base Peak 99 4 913 353 0511077 2005 11 07 17 38 m z 225 10 Abs Inten 443 Rel Inten 0 01 051 215 2005 12 15 17 03 051216 2006 12 16 1619 sid s 2005 12 21 1825 MS Aw 2006 01 24 16 38 804 2005 11 08 16 27 2005 12 22 17 56 2005 12 01 18 06 2005 12 05 1838 2005 12 06 18 20 2005 11 09 19 01 2005 11 04 1515 2005 11 01 1814 2005 10 31 1815 2005 09 30 1851 2005 09 15 17 07 2005 09 16 1703 gy
84. d Sett Eh 7 200 00 Bc Documents and Sett 6518 3708 1556 155 00 171 00 22700 29266 10537 155E 155 171 227 nDD JAEA Technology 2006 043 GCHS HARM Admin GAP RTV WP 2 AIH SIL ay aT Sle 9 tlala mm aH FT30WTBPSnDD TIS UNK 0005 20060313 5 qed 290WTBPqDDCTNS UNK O007 2D060313 5qd TDS 100 000 000 Wax Intensity 189 573 578 me MC X maiumiWn60313 Sa Time 10 353 Scan 643 Inten 3 668 137 a rr am gt 1 0 g a DDMS D UN 5 0 7 5 10 0 12 5 15 0 17 5 20 0 22 5 25 0 27 5 30 0 t 2 nl UN E x100 000 Max Intensity 189 573 578 Sj Rec 1 Time 10 553 Scan 668 Inten 43 365 a us 3 7 130XTBPnDD TMS _UN lt 4 k 30wTBPSnDDTMS _UN 7 5 va 418 SONTEP nDD TMS3EL _UN Vina Tia ai 5OXTBPnDDTMS _UN mj 100WTBPnDD TMS U 5 0 100wTBP3nDD TMS _U ef S 4 K Zil 2 5 A y E 10 TBP3nDD DBP5ppm_UN Sy 30WTBP3
85. e 1510 175 2050 mg 2500 ts 5oro min ACRE DRE 0 Base Peak 0 0 1 254 1 004 0 754 sb 1do TIRARE V RAIKI SEA MORGE PEIS 130 2d0 230 ado 330 ado 430 wwe ma che CIE pz ma che Cie ma C ea EROFA 0 0 a ADE YD xl su ty wF 23 ATR ma ma RR SAF A GGi g 3 H 7 MIME i fo Z YD HP 1 EEE GOWES r SPLIANJ TRA lost Ses SMES ann ll eit 283 1500 282 500 HIN 0 1500 APA 99 1500 F tees 283 6000 000 3200 PES 0 3 0 PUT C 466GB Max Intensity o 21 5614 25000 5614 25000 5615 8000 1471 3000 WRIT WRI FAN ok vt mmm w Fj ae TARET aA ET Py Su oY WF gra 28 nite a OE SAF ATARI g7 q 8 ct el 4 JAEA Technology 2006 043 GC imp six MS see AAMS 000 7 3200 E0 ST 466GB
86. ic Acid Tributyhphoshate GC MS Analyzer Silylation Cooperative Staff JAEA Technology 2006 043 H er a eae 0 WO 2 ee ee ee ee 2 2 1 2 2 2 3 OP EOD lel TE ET LE LO EE EL TESS el ED FELICE bs a AA EARE eck ke He ee ee SE ee ee ee ia 4 1 imi cle aie te AS ce ee eine oe Se fee eee ere a Ta aE a ies A tier ee 4 2 DBP 6 6 ee ee ee ee ee we ee ee ee ee ee ee 4 3 TMS 28 AE eee Sain Ga No ay tee ee Se ee a a ee Sr a 4 4 DBP ee ee eee ee ee we ee ee 4 5 BP a eee Be Te Re ete a ee ey a ee en eee ee ae he a ei les ae el Oe 4 6 TBP nDD TBP DBP 9 4 7 TBP DBP cect tt ett tees 5 4 BRE ee ee ee ee ee oe el fe eee a Case ee ee Te ce et ee a Se ret ves es Oe ee se Se Se
87. l 7 CHA PIWA amp A 7 anon Dg 080518 ETMS RD Aem FRE Vv sek w ADE RIVOLI ED oo SPL1 VF CH CF 1 eee lt IREME ansa j aT gt 4 4 4 ee Num Ae 1 ie 1531 17 cuments and Settings Administrator My Documents Imaizumi 060313 A NENAS and Settings Administrator My Documents Imaizumi 060313 Sdh a c aR haat Jai CH Documents and Settings Administrator My Documents Imaizumi 060313 ImaizumiW060313 X ae 2 41D TUNK 0002 0 2 10 TBP nDD TMS UNK 0003 0 3 10 TBP nDDTMS UNK 0004 0 4 30WTBP nDD TMS UNK 0005 0 113 TMS 2 on 5 30 TBP nDD TMS UNK 0007 0 13 TMS 2 qgm Roh TAD 6 50 TBP nDD TMS UNK 0008 0 113 TMS 2 qgm 7 50 TBP nDD TMS UNK 0009 0 8 10OWTBP nDD TMS UNK 0010 0 9 0 1 0 1 0 133 10 ESI
88. nDD DBP5ppm_UN 3 5OwTBPWnDD DBP5ppm_UN 10 35 oa oas 10 50 Toss Toe Toles ino 10 75 70 80 EN 5_UNK 0017 2 x B x 30WTBP nDDTMS UNK 0005 20 rog ta 10 402 2 660 1 784 A 1 504 155 Lash wes 1 004 0 754 0 504 0 254 g 0 00 2 30WTBPSnDD TMS _UNK 0007 200 e e 10492 2 54 FAVES 660 1 30 TBP n 2 04 97 ID UNK 0007 Wh 1 54 zt 15 30 TBP n DD SE FE ATW D APOO 2D 3x Sta B C ov oe Bel 2 Shell lo co sel le ole e a fun atte J 590927 0 9 PI Ol 060800 SE CTMSD OAS Max Intensity 189 386 197 2 0 Time 10 499 Scant 36 391 Oven Temp164 39 GEE Admin a kg 2006 03 09 17 2123 2 UNK 0002 2 un 7 3471 TBP Only UNK 0003 20060 2006 04 ER OXTBP DBPCppm 1_UNK 2006 04 E one 30 TBP DBPppm 1 UNK 2006 04 Bei 30WTBP DBP 5ppm 1 ER OxTBP DBPGppm 1_UNK 2006 04 fy FA S0NTBP DBPGppm 1_UNK 2006 04 s 27 5 3010 UNK 0008 10 TBP DBP0ppm 1 UN 2006 4 x100 000 Max Intensity 189 386

JAEA-Technology-2006-043:14.96MB

Contents

Download Pdf Manuals

Related Search

Related Contents