SPM による毛髪損傷評価の試み
Contents
1.2. 800 700 600 500 400 300 200 100 000 10
3. 47 48 a 4 1T B487 090 81720 32920 48800 5506 amp 118 1195 Z Ss mal isl 1 S 76 87750 51180 36560 52000 38 24 017 6 asm ozo oi sia ssm 10540 87560 36620 50930 42800 3 ld 113 950 a oraa ux 4 7 10 2 3 4 7612 Tus ong SS
4. 5 L UU 12 000 LFM O00000 LFMO OO Lateral Force Microscopy Frictional Force Microscopy 00 000000000000004 000000000000 LFM
5. UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUU 43 LU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUDU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUDUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 44 uuum UUUUUUUUUUUUUUUUUUUUUUUUUUUDUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUDU UUUUUUUUUUUUUUUUUUUULUOUUUUUUUUL UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 25 0 0
6. 0000 SRRz0 UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUU 1 LFMOOOOOOOOOOOOOOOOOVO NOOO 33 0 0000000000 No 11 15 19970 2 FRAGRANCE JOURNAL No 13 p 152 1994 BOOOOOOOOOOOOO 199400 60 2 00000000 48 5000 0 000000000000000 19950 1100000 U http www airi aichi iic or jp news news95 95113 html 160 000000000000 0 1994 1 oll 00000000 80 000000000 4200 1 P10 19970 9 000000 08000000000 19820 Par P 170 U BD EB D EB 7 D D 1 0 http members tri pod co jp ginji 2 h
7. UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 46 D 1986 U Frequency Modulation FMO OOOO 0000000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU
8. 0000 UUUUUUUUUUUUUUUUUUUUUUUUUUUDUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUU L 45 UUUUUUUUUUUUUUUUUUUUUUUDU UUUUUUUUUUUUUUUUUUUUUUUUUUUDUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 401501 80000 U 620 720000000000
9. L 2000000000060 LEM Torsion 9o 0000000 LFiMOOOOOOOOOOOOOO Data acquisition OOOOOOOOOOOOOOOOOOO Forward II D 0000000000 Reverse 000000000060 ON OFF OO 0000000000 O 10 20 100 200 1K 2K OF F uuum ON OFF OO 16 Spring constant D uum Thickness 25 422000 42000000 42 5 UUul Scanrotation 9 3 h acquisition 0 37N m 5 0nN 26 000 0000000 3 ms mel z t x ne Li y axa SRq rui x y dxdy x BRR L 7
10. UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUDU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 2090 00000 000000000000 5 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUDU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU L cun nb tut Weber 0 ITI UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 0 10 10 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUU U U OSPM UUUUUUUUUUUUUUUUUUUUU 5 5 5
11. 20 5 2 a b 29 000 204m0 0 610 8 510 7 410 310 6 210 5 110 4 10 3 90 000000 000 000000 000 000000 uut A SRRz Rkr SRa 5 2 200 m0 0 5 1 5 000 2 1000000000000 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUU 5 UUUUUUUUUUUUUUUUUUUUUUUUUO 3 12 00000000000000 UUUUUUUUUUUUUUUUUUUUUUUUUUU SRRzakrOOOOOOOOOOOOOOOOOOOO UUUUUUUUUUUUUUUUUUUUU 30 000 5 0m 80 70 60 50 40 30 20 10 0 000000 000 0000600 utl A SRRz 4 Rkr 09 0 5 2 0 5u mp O AFMOOOOOOOOO 20u m00
12. 000 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 100 1510 D D UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUDU 18 Dang 0 0 00 37 20 20 3 8 0000000 39 000000 136 0000 41 EN 000000 48 0000 64 00000 07 14796 2 4 000000000 0000 43 10 6 00000 85 0000000 1 0 0000 22 0000 5 5 00000 89 00000 12 uui 19 10 15 0000000 03700000 00000 3 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 1 2 0000000
13. 0 L OOOOOOOOOOOOOOO 2 21 dg UUUUUUUU
14. aedginpng 200000000 000 AFM UUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUU dg umm UUUUUUUUUUUUUUUUUUUUUUUUUDU 22 SPM 10 410000 E Login U UUUsOUUUUUUUUUUUUUU L 0 L 0 L3 L3 L3 L3 C3 L3 L3 E3 Dron 0go Lamm 1 Dronan 1 5 EX E LEE 73 C3 C3 0 5 E DE aa a a L3 a a OOO g E3 C3 L3 L3 oa L 0 pa m E mg
15. UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 23 a0000000000000 23 0 23 a D 23 0 0000000000 EE OOOO OOOO unn 038 022 OOO 012 000 019 025 000000 000000000000 5emi 000000000 0 25cm min eor D B U D U HOOOOOGOOOOOOGOOOOOOOOOOOOOGO
16. 1010197 1 20H m AFM 1 2 1 20H m 5 2 Hm 1 2 troscopy for Chemi s T m d un 7000 d 6000 Eso E 40 0 200 3000 ae 20000 00 10000 8 8 joo 1000 E 000 100 00 j 001 002 SPM Scanning Probe Microscope 20 mU U D 5H QU D UD 2 eR us 02 00000 nm SRq SRRZ Rsk Rkr Z 20H XY 1 5H 1 2 5 4 20 SPM AFM 20H AFM 1 5 1 H 26 C 20 20H m 5H 1 110 150 1997 AFM 20 FRAGRANCE JOURNAL 13 152 1994 3 800nm 800nm 800nm 800nm al O 10000 10000000 20000 10000000 1 1 21 AFM 58 EI LH 180 0000000000000 http www amy hi ho ne j p world ikuriron a htm 201 1 http www e2 el e eng osaka u ac jp N anoDynamics kaisetu h12 4 html 0 00 0 0000000000 21 59
17. 33 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU AOOO OOOO 0000 00000000000000 13 Laser diode 1 000 000000 00000 00000000 Albreht 000 DLC O Diamond Like Carbon O O SIN 6000000000600
18. UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUU 2 HEIR 1 HHH 1 v SPn x SVn 1 n l n l x SRRz SPn U SVn lU L I UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUU 6 n 1 NE RKr L Yi Rq i i 00000000 0 Rkuc 3 5 Rku 3 280 Rku 3 5 L UUUUUUUUUUUUUUUUUUUUU 27 OOO EL U D 000 0000 51 al 300000000 51 b 3 51 4 200000000 00 51 4 200000000000 51 e 200000000 51 200 000000000 300000000000 5 1 0 1 00 13 0 5 5 18 UUUUUUUUUUUUUUUUUUUUUUU TTD TD P Yu d U 5 1 200 000000 00 2 514 20 D 5rcpp 519000000000 1000000000600 L 28 262 D D D D U 3 D 5 1 f 200 000000000 D 51 51
19. 14 00000 5 3 4 a 00 34 5 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUDU 340 5 3 44 ZZZZZZZZZZZ LL LLL ES LA SiN 34 0 34 0 D 34 15 000 Hu 00000000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 35 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUU J Fi cortex B medulla iE cuticle 000 950 10600000 500 250 0000000000000
20. 0000 2400000000 1110 777 20986 LH HB DE 09 BEME UD ea 70 56 000 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 100000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 1 100 200000000000 6 Bogaty 1D D D D 22 5041 0 25 OD BBE 000000 Et 8n IL r P 000 0000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU uu 1 dan 6 00000000 00 8 dyn g x 980 6cmsecy
21. 0000 rJ 00000000000000000000000000 33 j uon uu UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUU 54 F 000000 100000000 20000 1000000 0000000000000000000060 5 2 0 000000000000000 uum UUUUUUUUUUUUUUUUUUUUUUUUU
22. 2 AD UU D D 5 1 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 1 5 5 gt l UUUUUUUUUUUUUUUUUUUUUUUUUUU 000 0000000000 SPM 2000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUDUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUD UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUU 100 000000000000 5 0 0 5 00 00000 100u mI O 20u mi o8umlOOOO 29u mi rn 0 37N m OOO 200 000 00000000 200000 200000 30000 UUUUUUU UUUUU
23. Lu SPM UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUU Dun gaudium 000 00000 oOOO VOOOO sunu A 0 7854D V20 7854D L Su2Dn L 21000000 0 21000000000000 RH RH D
24. 9 0 Md 0 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUU ESCA ESCA Electron Spectroscopy for Chemical Analysis O U 0 ESCA 00000000 00 000 58 5
25. 1 2000 1 3 102000 0 00000000000 31 5 0000000 530000 m V 90 80 70 60 50 40 30 20 10 0 000000 000000 000000 0 53 LFMOOOOO LFMOOOOOOOOOOOOOOOOOOOOOOO mv UUUUUUUUUUUUUUUUUUUUUU 53000000000000 10000000000000 2000 1000000000000 3 10 2 UUUUUUUUUUUUUUUUUUUUUUUUUUUUU um jpn 52 3 UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUU 32 600 0 10 5 5
26. LO N O Y N 55 0 12 1360 2450 39260 o7 009 325 677 95 55110 43530 11580 43320 585 22 26 097 804 897 26 6812 19840 10260 25360 1170 362 117 10 Y 51 in D 0 1 58x 199 10 717022 1336 Tr sea a 58 LEX m su SH 0 e 2325 2516 9j EE __ 195 4497 182a 144 A A 585 n 7477 mp mn val am COD a ale 7675 520 2582 AJ S3 O09 443 Bi oj ond ng 0 E sx E 7118 Lxx E co a o ix ue Ley 35e uj YE 107 Wag 52 OOOO 00000000 00000000 0000000 LU OOOO 53 U uuu U D 000 D 0000000000000000 D D 0 0 0 0 L3 o L3 L3 L1 mm o ja L1 ja L3 L3 L3 L1 L1 mm L1 L1 o ja D D D D D D D D 000000000 1 D N 51 L1
27. ngoja i a r3 r3 ma r3 r3 r3 r3 r3 aa r3 r3 1 2mA L LI LI L LO DB D EE ELO D DE EE D DE CEU U D ss 0 5 23 000 5 4 2 1SPM 000000 Scanner 0000 Area O00 0000000000000000 0 Wide Narrow 00000000 uu U XY srvlOOOOOOOOOOOOOOOOOOOO 0 10 10 00 0 A4A00000000000 uu Scanretd 1 uu 0 010 01 1 0000 64 0 10 100 1 512 UU O 2 chSPM 0000 0 10 10 00 D U U 1 512 H Scansizd 00000000000 Scan rotation 0 0000000000000090 00 UUUUUUUUUUUUUUUU U 0 90 180 2700 0 000000000000 D P aaindOOOOOOOOOOOOOOOOOOOOOOO umm 24 D 1 0000000000000000000000060 UUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUU
28. 1 d LU H D LO N mist O z R8 dus 0 O 39 nm 55 00 6 50 50 00 6 00 45 00 5 50 40 00 5 00 35 00 4 50 30 00 4 00 25 00 3 50 20 00 3 00 10000 40000 50000 10000 30000 40000 A 3 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 30000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 00000000000 1 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU uuu UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 40 B 0000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUDU dg
29. 6 aso cpa 7198 45310 680 2 026 565 7 sad 73460 2290 44190 aof nf 059 12860 95570 43600 51970 40370 29 16 004 6 reg Boo 46910 85990 sg a 504 101 Xp eap sap 460 7 E uem eem sex xs s ET 1222016370 117500 770 77730 sso af so os 70 rs mas aw 26610 sop 2 S 157 TLS 8905 11720 94330 31770 62560 43860 6 8 06 928 se wax 8504 102 0 sex 2 22 088 1043 49 a 69 518 7189 1770 sae 183 1 0 637 aj 10337 2314 esi if ajoa 47 a 8490 2689 5808 551 3 9 016 363 16 58 8 226 y TE al 2 em XE s a 48 15 5 0 20 soz a wl ax 8091 Ls os 7 11300 5499 5802 4360 10 11 03 532 Lp s sod 3 HS m 5 s Tus som x ap 148 65 a 258 3918 4722 15 025 748 og au sui 1 3 18 12 Ls p um 28970 17580 11390 14230 8 13 028 101 vam sso e san ag aso coal 50 SRR z SR pc SR vc 2946 12020 E N e N j 0 q OO 216 118 881 255 1 37 252 150 148 302 65 074 787 11 074 O04 10 574 575 477 0 72 274 9513 33450 860 ool oso 0 oso 185 an 004 248 2 28 mM 5 N d c E CN
30. 000000 50 10 10000 2000000000000000000000 30000 O 0 0 endwtideg 0000 16 Lu UUUUUUUUUUUUUUUUUUUUUUUUUUUUU 10 enr l UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU Lu UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUDU dg UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUDU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 3 60 ETN Sebaceous toil gland 3 6 Hp 000000000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUU U anagen 0 0000 eatagen 000000 00000 telogen r 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU Uum umum u u 8500000000 0000080 2000 60000000000 10000 10cm UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 000
31. 00060 20nm 000000000 3 2 UV gt Z 35368 hb k amp RFI 5 6 42st XYZ 4 818448 3 2 11 UUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU Lu
32. 0umOO AFMOO A 1ifnuugf20um ip AFMTI IE 36 1 9 0000 9200 AFM 1 A 1a x90 000000 UUUUUUUUUUUUUUUUUUUUUUUU 00000 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUU 20 0 0000000 SRRz00 UUUUUUUUUUUUUU 37 nm 90 00 7 00 80 00 6 50 70 00 6 00 60 00 5 50 50 00 5 00 40 00 4 50 30 00 4 00 20 00 3 50 10 00 3 00 a b d e f g 2 000 argu 0 uuu 5 2 RkrOOOOO Rkr UUUUUUUUUUUUUUUUU SRRz00 Rkrr UUUUUUUUUUUUUUUUUUUUUUUU 38 2 100 700400 300500 20000000000 300300 300400 200000000000 SRRzOOO Rkr D D U b 0000
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34. SPM IDLD DU D HEU D UU BER O L SPM FOS 2 3 D UNDER O Ep Tao EO 8 IOS TEE SS sen oe ke 0 14 352 6 D 15 2 6 EI BUE tdi to fed er ER tn 16 3 6 2 VEL eA a ies 5 18 36D MND E e Suo DXEPELELEPEUEDEEB EO sco s Quan 4 DDD 22 A 2 A2SPM NO testo ELHEUE 4 22 d Seales 8 26 ABT H WB re ss 28 ater halal E 50 Sono lo aes BONS 5 35 31 33 UUUUUuuun 33 34 A 35 35 00 5 000000000 A 1 AGG AAT TOE eee gg 41 00 gt 45 47 0000000000 49 LFMOO 55 57 59
35. U UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU UUUUUUUUUUUUUUUUU OOOO 000 SPM SPM Scanning Probe Microscope 000000000000 5 O Scanning Tunneling Microscope 0 0 0 U U 198100 5 5 7 3 1 a b 3 1 a 10 0 AFM D 3 1 b 40 AFM 10 AFM 00000 AFM 1 J Atomic F orce Microscope HH 0000000
36. UUUUUU UUUUUUUUUUUUUUUUUUUUUU 2 ZP J 55 Sin Ys Rf sx ER E EH Rf 0000 oeummu trit b 2 65 0000000 LFMOOOOOOOO 000000 000000000 000000000 sin Ys Rf sin1 0 6 62 5 0 55 degree 0 0096 rad 2 65 00000 LFM J J J 2V 4 9 24 82 V degree 276 V rad 0000 ugg 0 208 degreeV 0 0036 rad V 7 56 G UUUUUUUUUUUUUUUUU 57
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38. aircare html http home3 hi ghway ne j p concep mouhatu html 12 http pretty coara or jp wadasho kiken html 13 http pretty coara or jp wadasho kiken html 14 http rabitt hoops ne jp 1 15 http www2u biglobe ne jp shcsn ki kenbusitu html 16 http www page sann t ne jp iten sitei htm 170 00000 PI U 34 1 000000000 58620 0 100 UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU 10 20 AFMOOOOOOSAMOOOOOOOOOOOOOOO SRRz lt 0000000 A1000 8 20 0000 RET 2 5 6 f 9 oooooog a S b 3 c BE 1 52520 EE UUUUUUUUUUUUUUUUUUUUUUUUN eli 8 UUUUUUUUUUUUUUUUUUUUUUUUUUUUU 35 A 1 a gl 200 m00 16 A 1 e 0000 e2
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