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Contents
1. G column G column G column 3 2 1 3 3 G 100 10m 1m G 100 20m 1um G 100 40m 1m Sample 1 1 Oc2. GC GC MS POO O90 OI OO 0 O bPOO x Ob PO x x x x bP ObP PO OP bP PIO OO O Ox x b x DIOOO OS 1 G column 2m 3000 G column 40m 20000 G columm 1 3 Ethylbenzene p Xylene Styrene o Xylene
3. JN 1 ON 2 FB 2A G column FB 2A G colum CH ON 2 G column 2 2 2 2 G column
4. 3 4 3 1 G column
5. 2 3 2 1 G column 2
6. Win CY JIS K 0114 2000 99 999 Snes ECD GC MS HO Ni 2 Ml Analytical condition 5 Van Deemter 9 Injvol 1gL a 3 11 42 4 2 1
7. JIS K 0114 2000 25 G column 2005 5 20 2011 3 11 CERI amp M Chemicals Evaluation and Research Institute Japan 345 0043 1600 TEL 0480 37 2601 FAX 0480 37 2521 e mail chromato ceri jp http www cerij or jp
8. G column 0 25mm 0 32mm 0 53mm 4 4 100ppm Co Cs k Capacity factor ChangeofN Analytical condition Column G 100 40m 1m Column Temp 120C Flow He 20mLmin Sample C10 C13 50ppm each in Hexane Injection Volume HL 4 4
9. 20 1 1000 2000ppm 2 40 lt 50 5 lt 10C min 3 4 6 G 250 8 Column Temp 50C 10 mn Column Temp 120 130 C 130 C ps ls Sample 1 BOB Be 130 C 10 20 C Shut 120 a
10. 9 5 0 ON 2 eel G column FB 2A 2 2 3mm 2 lt 3mm 3 2 GC 0 a HTH Emm Ns GC GC 4 0 5 1mm 5
11. G column 1 2 2 3 1 2 GC 0 GC GC 3 0 5 1mm
12. 1 40m 20m 10m G 100 G 205 1 m 2 Max Temp Prog Program Temp Program Temp 3 1 4 1 2 1 22 G column 40m 2m 30m 25m mm 1 2 0 53 0 25 100 20 4 mLmin 10 40 5 20 0 5 2 20000 10000 80000
13. G column 1 2 5 2 G columnm 2 1 G column RR Eh G column 23 1 1 G columm
14. Van Deemter 4 1 G column 20mL min 2 N Analytical condition Column G 100 40m 1 0m 30 000 Column Temp 120 C Sample Naphthalne 100ppm in Hexane Inj vol 1pL O 20 000 10 000 0 10 20 30 Flow Rate ml min 41 4 2
15. 21 4 6 G column G 300 G column
16. 0 5 1mm SN 2 SN 2A SN 1 M SC 1 SC 1 ON 2 24 8 2
17. 4 McReynold s Constant McReynold s Benzene 1 Butanol Nitropropane Pyridine 2 Methy 2 propanol 2 Octene Squalale McReynold s Constant 3 G 205 G 230 G 250 5 30 50 Naphthalene 2 6 Dimethylphenol 2 6 Dimethylaniine Naphthalene r 4
18. 2 3 4 24 4 1 2 3 4
19. 4 G1 3 0 5 gt 1mm SN 2 SN 2A RN 5 G1 2 2 3 2 4 1 G column
20. G column 10 20mL min 3 G column G column 2 R Resolution 2 tR2 tr1 W W tk 1 2 ts tsz Retention time tri trg W 1 2 Wi W Peak width R 3 1 R 1 5 2 R 1 N Number of theoretical plates tk 2 N 16 3 2
21. 4 5 0 5 L 8L N i RE RA 8gL N 0 5L 1 1 4 1 Analytical conditon Column G 100 40m 1m Column Temp 120C Sample C10 C13 50ppm in Hexane 0 0 Na 30 4 5 4 4
22. mL min V V zr 4 1 r L 3 8 tt 4 2 f 4 1 4 2 2 fa 4 3 0 0 L t t 4 3 G column 40m 1 2mm 0 6mm 8 x 0 06 x 40x100 452 2 26 58 20 0 mL min 4 52 f 10 0 mL min G 950
23. 1 G 300 1 Octanol 2 6 Dimethylphenol 2 G 100 G 205 G 230 G 250 G 300 2 6 Dimethylphenol 10 2 6 Dimethylaniline
24. Dodecane Tridecane G 100 G 205 G 230 Methyl Silicone 5 Phenyl Methyl Silicone 30 Phenyl Methyl Silicone 4 5 oo G 250 G 300 50 Phenyl Methyl Silicone Polyethylene Glycol 2 5 Flow He20mLmin Sample 1 1 Octanol 2 2 6 Dimethylphenol 6 3 2 6 Dimethylaniline 4 Naphthalene 2 5 Dodecane 1 6 Trdecane 100ppm each in Hexane 4 Injvol 1pL 3 1 2 6 Dimethylphenol Analytical condition Column Temp 120C Flow He20mLmin Sample 100ppm in Hexane Inj vol 1L 2 6 Dime ylaniline Naphthalene Tridecane 1 Octanol G 100 G 205 G 230 G 250 G 300 3 2 McReynold s Constant McReynold s 11 Constant
25. W W 3 1 3 2 1 g 1 k 3 3 R RI ATE a 6 1 tri to k Capacity factor R N w k 3 1 ts v 7 3 1 5 G column 3 2 1 1
26. G column G column 1 4 5 G column G column G 100 40m 1m SE 30 5 3mm x 2m 1 2 3 Sample 1 Ethylbenzene 2 p Xylene 4 3 Styrene 4 0 Xylene 100ppm each in Hexane 3 4 Cl Analytical condition Column G 100 40m 1um SE 30 5 3mm x 2m Column Temp 60 C Flow He20mLmin Inj vol 1uL 113 2 0 1 0 32mm
27. 3 3 10 Naphthalene 50ng L 1009 ChangeofN Analytical condition Column G 100 40m 0 5um 1um 2 m Column Temp 120 Flow He20mLmin Inj vol 1L Sample Naphthalne 50ppm 5 in Hexane 50 100 500 1 000 5 000 10 000 50 000 Injection Amount ng 3 10 3 11 1um 2m G 300 40m 2m G 300 40m 1um G 300 40m 1um Column Temp _ 40 C Column Temp _ 80 C Column Temp 80C Inj Vol 1pL Inj Vol 1zL Inj Vol 0 2L
28. 3 40m 40m 20m 10m 3 3 1 0 100 40m 0 5um G 100 40m 1 um G 100 40m 2m Sample 1 1 Octanol 2 2 6 Dimethylphenol 3 2 6 Dimethnylaniline 4 Naphthalene 5 Dodecane 6 Tridecan
29. 2 10 lt 20mL min 20 30 3 40C 15 20 30C 5 10 min 60 4 30 60 90
30. 2 G column Flow He 20mLmin Flow He 11mL min 10mL min 4 3 m p Xylene m Xylene 20mLmin See N 18000 2 m Xylene 100ppm each in Hexane 11mL min N 20000 8 14 1 2 Analytical conditon Column G 300 40m 1um Column Temp 60 C Inj vol 1uL 4 3 4 3
31. 0 5mm 1 5 G column 5 L G column G column 1 2mm 5 SE 30 5 3mm x 2m G column G 100 40m 1gm Sample 1 1 Octanol 2 2 6 Dimethylphenol 3 2 6 Dimethylaniline 4 Naphthalene 5 Dodecane 4 6 Tridecane 100ppm each in Hexane Analytical condition Column G 100 40m 1um SE 30 5 3mm x 2m Column Temp 120 C Flow He20mLmin Inj vol 1pL 1 4 0 53mm x 15m 1 5m G column G 100 15m 1 5m 4 Sample 1 1 Octanol 2 2 6 Dimethylphenol 3
32. AM LN_ ew 3 wu Analytical condition Column G 300 40m 1um G 300 40m 2m Flow He20mLmin Sample Styrene monomer 3 11 4 G column 0 1 m 0 5 m 3 m 5m 1 m 17 4 G column 4 1
33. 3 5 m G 100 G 205 G 950 4 GC MS GC MS FB 4A 5 G column
34. Change of N Analytical conditon Column G 100 40m 1 m Column Temp 120C Flow He20mLmin Inj vol 1pL Sample Naphthalene 100ppm in Hexane 350 0 200 Time Ir 1 8 2 G column 2 1 G column G column 2 1 ONS29 FB 2A JN 1 ON 1 0 2 1 G column 2 2 G columm
35. 1 1 G column 2 1 2 7 8cm 16cm 1 2 G column 40m 1 1 3 G column 7 1 1 1 1 G column Max Temp Prog 280 320 310 340 300 300 300 300 220 220 230 250 200 230 Methyl Silicone SE 30 OV 1 OV 101 SP 2100 5 Phenyl Methyl Silicone SE 52 SE 54 30 Phenyl Methyl Silicone OV 61 DC 550 50 Pheny Methyl Silicone OV 17 Polyethylene Glycol PEG 20M 5096 Trifluoropropy Methyl Silicone DC QF 1 Porapak Q
36. G column 1 2mm G columm 0 5mm Analytical conditon Column 15m 1 5m Sample Naphthalne 50ppm 5 in Hexane Inj vol 1L Change ofN Change ofts 9 6 50 100 500 1 000 5 000 10 000 50 000 Injection Amount ng 1 6 1 7 G columm 100L G column G column 2 Sample 1 2 3 Po a Analytical condition Column G 100 40m 1um Column Temp 50C 5min 3 C min 90 C 1 C
37. ts Df K 2Df 3 10 3 8 0 1gm 3 9 5 m Methane Ethane G column 25m G 950 ww amp KT Analytical condition Column G 205 40m 0 1m G 100 40m 5um G 950 40m 25um Column Temp 40 C Colu
38. 22 5 G column 5 1 1 G 300 G 300 PEG 0 60C 2 G 950 G 950 25 m
39. 25 435 I 9 A Analytical condition Column G 100 10m 1um G 100 20m 1um G 100 40m 1um Flow He 20mL min Inj vol 1uL 3 4 3 3 N R G column 40m R 2 4 3 5 G 300 G 300 20m 1 m G 300 40m 1zm m Xylene p Xylene 20m 2 40m 50 Sample 2 mylene 100ppm each in Hexane Analytical condition Column G 300 20m 1 m G 300 40m 2 m Column Temp 60C Flow He20mLmin Inj vol 1L 3 5
40. 2 6 Dimethylaniline 4 Naphthalene 5 Dodecane 6 Tridecane 100ppm each in Hexane eo x Analytical conditon Column G 100 15m 1 5um 0 53mm x 15m 1 5um Column Temp 100 C G column 80 C Flow He20mLmin Inj vol 5wL Tridecane k 115 20mL min 109 1 6 Naphthalene 50ng L 100
41. min 40m G column ECD GC MS k 1 2 1 1 1 1 2mm 1 6mm 40m 20m 10m
42. min 110 C Flow He20mLmin Inj vol 100gL Agilent 6890N FID 0 53mm 1 7 1 5 1 8 G column G 100 280 Program Temp 320C 350C G column G column
43. G colummn G column G column 1 G column 1 1 1 2 1 3 1 4 1 5 2 G column 2 1 2 2 G column 3 G column 3 1 3 2 3 3 4 G column 4 1 4 2 4 3 4 4 4 5 4 6 5 G column 5 1 5 2 oO MN MN oo 10 12 14 18 19 20 20 21 22 23 23 1 G column 1 1 G column 1 2mm 20mL
44. e 100ppm each in Hexane ML IM J PO Analytical condition Column G 100 40m 0 5um G 100 40m 1um G 100 40m 2um Column Temp 130 Flow He20mLUmin Inj vol 1L 3 6 14 3 6 G 100 3 7 Analytical condition Column G 100 40m 0 5um G 100 40m 1 m G 100 40m 2m Column Temp 130C Tridecane Flow He20mLmin Sample 100ppm each in Hexane Inj vol 1L Dodecane Naphthalene 2 6 Dimethylaniline min 2 6 Dimethylphenol 1 Octanol 0 5 1 2 wm 3 7 B 2Df 3 7 r Df K 6 K k 5 k Capacity factor 3 7 3 8 0 3 9 3 5 3 9
45. l 8 5 0 lt Anayical condition roy He2onumn njvol 1 En 45 G columm 1 G column
46. mn Temp 80C Flow He10mL min Flow He20mL min 123 1 Sample Sample Natural Gas 0 5W V iso 1 Methane 5 2 Ethane 3 Propane 4 4 iso Buthane 5 n Buthane Analytical condition Column G 100 40m 5um G 950 40m 25 rm Column Temp 220C 3C min 320 Inj vol 5gL Flow He20mLmin Inj vol 1L 3 8 3 9 2 H B H Co C u 3 11 H HETP Height equivalent to a theoretical plate H L N L B u cmmin 5 2k Df lt Ss a Cu GC rH D DL L 2r2 1 6k 11k2 lt Ce C ena Ds 9 24D k C Df H H
47. tanol 2 2 6 Dimethylphenol 3 2 6 Dimethylaniline 4 4 Naphthalene 5 Dodecane 1 6 Tridecane 100ppm each in Hexane Analytical conditon Column G 100 10m 1um G 100 20m 1um G 100 40m 1um Column Temp 120 Flow He 20mL min Inj vol 1uL 3 3 12 tt L 3 4 U u cm min ts k 1 3 5 k Capacity factor 3 4 3 5 ta kt ts L 3 6 2 3 4 G 100 20m 1um G 100 40m 1m G 100 10m 1um Column Temp 100C Column Temp 120C Colum Temp _ 85 C Sample 1 1 Octanol 2 2 2 6 Dimethylphenol 3 2 6 Dimethylaniline 4 Naphthalene 5 Dodecane 1 3 6 Tridecane 100ppm each in Hexane N Naphthalene N Naphthalene 9 684 N Naphthalene
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