家庭用殺虫剤概論 Ⅲ - 日本家庭用殺虫剤工業会
Contents
1.2.
3.
4.
5.
6.
7. 2
8. 6
9. 1
10. GLP
11. 38
12. lt
13. LI LI TRA
14. 2 3 00 OQ XX Xx
15. 17 9 1 _
16. 2 3 30
17. 2 5
18. pH
19. 4
20. LPG 2
21. 35 145 2 2 1 2 1
22. 8 BT Br coo m 9 9 6 Br coo ct_V ba CN CN mfo mixed function oxidase
23. 21 1 7 9 10 8 24 21 19 2 3 2 25 22
24. 3 4
25. 2 5 5
26. S 421 IBTA 2 3
27. 2
28. 1 1
29. 1 40 59 1984
30. 2
31. 5 dd T80 E 1 12 20 40 60 1 60 12 1 0 7mg 0 9 0 5 mg em 40 60 5
32. ET 3 UL
33. 1980
34. G G 2 2
35. lt ee mm 2 1 ON pp gs OT LDso ug LCso ppm LDso ug LCso ppm Re LDso g
36. 5 EE 1
37. Brs 7 7 Na
38. 6 2 Vo GABA y amino butyric acid 7
39. 4 vy 44 Vy 44 vy 44 Vy lt lt lt 4 1
40. 1m2 20 30g 3
41. 3 4 5
42. 2 18 1 7 8 1
43. 7 O VV 1
44. 2 1 NE
45. 90 2 1910 5 1 II I II I II 6 1958 6
46. I 1
47. 2002 14
48. y BHC
49. 2 2 3 2
50. 2 2 2 2
51. 1 3 3
52. I 1 1890 30cm 1 1 7 8 1
53. 6 L 7 7 x 7 7 gt ROD RT ee 3
54. 9 1 2mm 10
55. 2 3
56. 10 a ite fn L L D D D
57. 3
58. 4 4 2 6 1 3 5
59. PTC PTC PTC
60. PCO ULV 5
61. GABA LI 1 1 100 f
62. 90 5 4 6 7
63. d T80 3 d T800
64. 3 3 dldT80 2X10 6hPa 21 6 ddT80 1 33X10 7hPa 23 4 0X10 6hPa 20 1 96X10 hPa 25 10 3
65. 2 ULV 2 3 3
66. 3 3
67. 1987 a 3 2 2 Dl
68. 3 1989 DME LPG lt 1 1 9
69. 1 E V T E V T V 1 KTso g m3 24 24 30 100 100 0 5 60 100 100 30 100 100 1 0 60 100 100 30 100 100 1 5 60 100 100
70. 10ppm 30 BHC DDT 0 4
71. 2 4 2000 12 2 1 1
72. 11 d d T IGR 2
73. 700 800 Pi ee Er 6mm 8mm 700C 250 C UCC 1 6 8mm 250 1 7 8 1
74. Cl O _ 0 O LY p lt N CH2 S P N 0 CHs H3BO3 H HsC N ca Po X_ N N C CN CH CH NC N N CF3 FsC S ll o NH A de erg 2 CF3 3 3 500 51 6 Blattella
75. 1 2 1 3 1 E C QB A A B C 1 2 1
76. 4 1 15 40 1 2 3g 10g
77. 6 10 1 1 2 TRA 10 30 um 1 5zm
78. 5
79. Y 1 p 5 2006
80. 2 i DEET N N m 1 DEET 2 1 9 MGK 326
81. 6 6 2 1 1 2 12 1 3 I 1 a TD 0
82. 10 9 LDso mg kg LDso mg kg 1 441 1 464 gt 10 000 1 920 2 092 gt 10 000 25m3 6 1 2 6 17 40 1 9 4 6 12 3 25 8 4 LCso 40 1 2 8 0 79 1 4 5 4 1 4 1
83. dld T80 d T80 D d d T80 12
84. 3 2 V 3 1
85. CC lt ChE 40 60g 200ml 10 200 500ml 30g 200ml 250ml C 0 5ml A 1 10
86. x 3 1900 33 1947 22 1990 2 1 2 3 4 5 6 7 8 9 10 16 20 3
87. TRA 1 2
88. 3 1
89. 9 27 2 3 4 25 1 43 Pest Control Operator 60
90. 2 ea 2 g m3 1 7 17 22 34 1 0 91 9 93 7 97 4 98 6 1 1 2 3 4
91. 4 7 7 y 700 800C 2 150 170
92. LPG MA 3 2 11 CClsF 137 4 23 8 ET 2 CClsFs 120 9 29 8 20 C 1 49 6 vy kg cm2 20 C 4 113 CcCEClE gt 187 4 47 6 114 CCIF2CClF 170 9 1 47 a IT 20C 20C CHsCH2CH3 422 2 0 50 8 1 10 0 0 56 CH3 2CHCHs n CHsC
93. 6L 18L 200L PL
94. 1 1
95. 5 5 6 8 5 6 8 Ii 1 6
96. 2 3 2 1 5 40 60g 200ml 30g 200ml 250ml
97. 4 XX OO OX xX OO OD XOOOO x pxxx OXXXXXXxXXxx OO bbOXX
98. 2 170 0 50 100 10 20 250 8300 C 2 2 35mm X 22mm X 3mm
99. 2 1 2
100. 1 Aeroso1 1927 Erik Rotheim 1946 1950
101. 1 2 3 3
102. 12 1 1 5 3 6 4 5 10 1 12
103. 1 TRA I 1
104. 2 6 24m3 30 5
105. PCO PCO ULV Ultra Low Volume 20 2
106. 3
107. 1 3 20g m3 20 3 4 3 3 gt 20g m3 4 LDso mg kg 5000 amp 5953 _ 3732 4668 5
108. 27 2 61 2 1 2 2 2 3
109. 1 16 16 2 21 2 3 VP iE2 NP VP 2NP 5 0 5 0 5 0 5 0 05 10 5 2 6 0 5 ES 15 2 WM 1 0 3 3 23 1 0 5 5 0 10 20 lt 6
110. 8 12 2160 1 12 180
111. 100 200 80 5 16 900 1 1 11 0 31 15 1 11 8 4 9 13 6 4 8 32 6 16 1 1
112. 3 5mL 1 5 2L 2L 20 30cm 200 800
113. Si TH 03 5207 7451 03 5207 7461 3 27 12 03 3817 41111 03 3814 1664 gt 07S 492 3315 073 492 3314 ET gt X 1 13 20 06 6781 6151 06 6781 8750 2 U 0 0262 2 21 14 03 3835 2241 125 0737 67 2314 130 8544 1 2 22 03 3621 6180 03 3621 3 4 649 0311 1 1 0737 82 321110737 82 3214 550 0003 1 8 32 06 6443 61191 00 6443 4246 03 3835 2249 Good Manufacturing Practice 50 knock downtme 50 50 lethal concentration 50
114. 4 O 2005 1 1
115. 5 2 6 6 LD5o mg kg LDso mg kg LCso mg m O 260 900 1 350 5 000 A tuvFyYyI 1 SS 685 1 100 gt 2 500 gt 2 000 O O 2h 900 2 150 2 660 4 390 gt 3 875 4h dl d T80 pA gt gt 5 000 gt 2 000 gt 2 730 4h 3h 1 _ wo gt 5 000 gt 5 000 gt 1 180 0 0 d T80 500 0 OO O
116. DEET LDso 2 420mg kg LDso 4 223mg kg 3 4 5
117. I 1
118. 10 2 15 a WD II TRA TRA 1940 TRA Total Release Aerosol one shot aerosol 1970
119. 6 5 1 1 0 ER 3 0 5 200mL 100mL 2 1 30 10 6
120. N2
121. 2 77 ET 2 SI IO 3 4 2
122. 3 2 3 7 8 ULV 2 3 14 20 10
123. 6 13 10 11 12 25C 65 1 23 28C Pe 4 6 Ri _H SR J 0 HaC 2 wl TAN CH 0 C C C i 1 A a H a H 1R 3R trans L Crombie 1954 Scis Y Katsuda 1958 Y Inoue 1955 comseee OR EE sl wewr em em 0 sl jm em emem su 5 6 Jasmolin II COOCHs CH2CHs 5 5 A COO Pyrethrin D Pa Rs a O O LaForge 1947 Ko ja Barthel 1958 Allethrin Phthalthrin Dimethrin
124. 1 12 28 150 4 5
125. 3 1 LDso Ag I 1 2 4 28 dl d T80 EF 2 67 7 d T80 f 2 55 1 17 d T80 f 0 64 XD 4 65 d T80 E33 Dt 175 0 89 NR 0 64 dd T800 0 45 5 02
126. 4 LA W 5 2 3 na ww 6
127. 2 3 4 200mL 100mL 2 1 30 10 6 lm2 1m2 50mL 50mL
128. 4 dl d T80 d T80 d T80 d T80 1 2 3 4
129. M4 2 2
130. 1 1 2 2
131. 4 4 LDso mg kg 1168 2148 mg kg 2 13 46 7mg m 2400 3
132. dl d T80 d d T80 d T80 3 4 4 0 4
133. 2 6 2 95
134. 100 dl d T80 LDso 440 730mg kg 900 2 150mg kg 80 6 K 1 1kg 1 4 8g lt 1kg 4 8g 1 13g 1 3
135. dd T80 12 0 2 4 6 8 10 12 3 8 4 dd T80 dd T800 d T80 3 d d T80 F 1 1
136. 24 el 10g 6 100 98 6 0g 19 8 11 7 6 25m3 10g 2 5 10 8 9
137. 8 1 1 53 7T15y7
138. 2 Xx x x CO gt x 3 x O x Xx xX x O 2006 X 2 4 1
139. Mycobacterium leprae Ey RR pets G 3 4000 1
140. 1 40 60 mg 1 PTC positive temperature coeffi cient 7 7 7 7 7y ELXDE1TAROD
141. 5 3 4 5 5 ULV 3 1 lt 2g EE I
142. 1000 H 12 H 13 H 14 H 16 2000 2001 2002 2003 2004 51 254 44 670 38 230 40 456 44 033 39 954 36 444 29 771 27 851 25 774 91 208 81 114 68 001 68 307 69 807 56 449 55 685 57 419 54 755 51 927 28 497 15 026 725 1 460 24 110 69 818 61 444 56 219 52 957 57 060 63 405 101 901 97 561 98 046 91 092 80 847 644 503 448 17 091 16 072 15 401 17 046 19 158 68 203 12 13 10 22 951 19 646 18 563 15 876 11 068 56 050 75 529 65 858 75 124 76 685 29 834 35 872 34 742 34 669 38 114 289 983 301 605 286 027 290 880 289 287 3 428 23 667 442 15 067 42 604 3 489 2 871 2 402 2 339 2 054 35 452 34 178 35 091 31 110 29 956 38 941 37 049 37 493 33 449 32 010 26 18 34 31 19 436 507 659 1 888 1 280 12 332 12 860 14 147 14 405 17 118 12 794 13 385 14 840 16 324 18 417 573 870 2 681 3 037 0 5 0 5 1 4 5 4 5 2 me 16 202 a 34 25
143. 10 10 12 ON OFF 2
144. 5 100mL 1 7 20 50g 500mL C OO 300mL 4cm 30cmOD gt yyY 3 di 50 d2 di1 d2z 1 03 2 1 MI
145. DEET 4 1 DEET DEET 2
146. d d T80 lt gt la gt gt gt 1 1 2 3 1 1 mg 2
147. 3 e 3 45
148. MT 200mL 20 100mL 2 1 30 20 2 We N gt Co TO 3 1 ee nas Wa 3 A CR 4 330 45 m 85 4 1 2
149. 200 400 2L 7 10 1 2ppm lm 0 O oo 2 3 M lt 500mL 1970 Nuisance Nui sance lt 1950 1970
150. 3 4 3 1 2
151. 8 2 2 1 2
152. 3
153. 1m2 ll i 6 5 7 ei ee 1m2 1m2 Po So 15 40g 1rmz 20 60g 1m2 10 10 gt _ 5 10 0 20 30 1m 50mL 5 400 800 4L
154. V 1
155. 4 C9
156. 1 ese 10 ere 18 To 28 PP 54 TV LI 70 100 4
157. 10 300 300 200
158. 2 40 10 1 2 2 3 1
159. 7 8 700 800 6 8mm 250
160. DEET 40 CHs3 C2H5 gt C2Hs N N m DEET 1 3
161. Periplaneta 1 1 1 75 1 1
162. yy 88
163. dl d T80 1
164. 58 1 0 6 11 0 58 461 066 44 0 78 5 59 1 0 77 1 d T80 d T80 35 2
165. 2 1 dl d T80 Machilus thunbergii 7 10
166. 7 8 7 2 72 g 35m3 9 94 100 we 10 97 100 20 100 100 9 96 100 10 98 100 20 100 100 9 96 100 2 em 10 98 100 20 100 100 8
167. DEET DEET 1 30 0 1g 0 2g 1 5 6 DEET 3
168. 1975 2 lt 1982 EPA 33
169. 500 1 2 1 1
170. LDso mg kg LDso mg kg 260 900 1350 5000 685 1100 gt 2500 dl d T80 FE 900 2150 2660 4390 gt 5000 gt 2000 d T80 gt 5000 gt 5000 gt 2500 gt 3000 d T80 f 450 680 10000 D gt 10000 gt 5000 d T80 Df gt 10000 gt 3500 gt 5000 gt 5000 430 470 2500 dLT6O00 460 640 5000 3500 2000 2250 2640 gt 5000 d dT S 1080 1250 2000 _T 2400 4500 2000 gt 5000 gt 5000 2000 gt 2000 4
171. 1989 8 21 3 1 LPG LPG n 95 2
172. dHT80 i 21 11 3 30 4 1 36 61 12 26 109 25 5 4 120 61 3 28 41 1 25 16 16 2
173. 1 TRA
174. 19 2 2 1 25 212 16 2 2 16 16 2 1 3 1 1 4 8 16 2 3
175. 2 GMP Good Manufacturing Practice 1 2 2 10 2 I
176. 2 3 7 8
177. 28 2 16 8 1 0728001 3
178. 1 1 2 3 4 9 11 9 30 24 3 24 10 35 8 10 145 18 3 31 10 6
179. dl d T80 0 3 qld T80 d dT 4 dd T80
180. 2 1 2 3 4 5 3 6 7 8 9 10 11 2
181. 5 OD 6 2 2 3 mg 3 0 1 12 30 mg 1 12
182. w v 3 5 1 3 Pe 10 700zm 50 300zm 10 1700 zm 50 300zm 10 50g 3
183. 1980 1 TRA TRA fog TRA 1998 TRA
184. PCO PCO PCO 11 20 1900
185. 2 15 2 2 5 os hh 2 3
186. 1 63 2 3 TP ee eK Nui ie 1
187. 2 000 100 4
188. Maximization 6
189. DME 1974 2 uma 3
190. 2 20 40 2 5 2
191. 200mm 45mm 100g 100mm 100mm 105g 30mm 3 75 15 1 6 1 SN ee 3 4 a 10 10 10 1 20
192. 1 3 TRA 1 11
193. 5 0 018 1 15 0 016 0 088 0 39 0 387 0 002 0 33 0 0054 1 85 0 0049 0 435 0 001 2 2 LDs LDs LD50 LC5o LCso mg kg mg kg mg kg mg m3 ppm 1030 1040 850 1200 gt 2210 4 32 124 70 107 75 650 gt 40 3733 3597 gt 4827 4 0 a A Ss bs a 424 405 1410 1500 5000 gt 1330 12 0 68 62 99 94 1282 564 gt 3300 6h 5 9 890 640 5000 6 2 1266 1361 1837 1734 a 8 0 11 NT
194. 1 2 AY A NETL A 2 lol uo Rel 1 I 70 3
195. I 1 2 3 1 2 3 1 2 3 40 1
196. 21 32 366 10 3 351 20 DDT 22 BHC 30 1 10001 es me
197. 2 Fa bs a sss 7 7 gt
198. 2
199. 1 12 6 dlld T80 12 6 OD dld T80 d dd T80 d T800 d d T80 CE 1 2 2 LDs5o 5000mg kg 5000mg kg 5000mg kg 5000mg kg 2 12 140 3
200. 465 13 56 7 51 16 I jp 2 s 9 i lomwswl g sg wa mw 24 3623 1341 987 572 570 446 3 Moe 13kg cm2 RON 100ml 4 1989 LPG
201. ppm 50 lethal dose 50 1kg mg ml parts per billion 10 1 10 100 1g 20mX 50m X 1m 1ml parts permillion 100 1 1 1g 1m 1ml Ultra Low Volume micro gram 100 1 8 3 31 06 11
202. 4 Ta 0 A A CT 2
203. 7 1 3 Na 200mL 20 MA nl 2 1 20 2 8 1
204. 14 25 50 14 25 10 20 1 2 3 12 12 9 20 20 27 1 20 50 1 2 3 12 8 13 4 5 17 20 28 EN 4 J Sa mon imurium 1 S SDD _ 5 a Escherichia coli 7 5 Staphylococcus spp Salmonella typhosa Shigella alkalescens Pasteurella pestis
205. 3 1 1 100m EPA 4
206. 5 3 N 4 10 2 1 50 150 200 500 illl 5 5 10 5 10 1 2 3 3 1 1 2 3 12 4 12 9 10 3 6 3 20
207. 9 10 2 70C 1 2 3 4 5 6 7 8 9 2 1
208. 7 10 ed a H Ny i Oi ER AA 1m2 8 1m2 30 50mL i 3 5mL 15 20 _ 1 20 50mL 20 30 1 gt
209. i 7 ed P F ll 1 EF Pr ji J a IM Ly 1 em i har FF FA Ei Pr Fr 1 1 a 1 1 Wi 3 i F 1 i fl po ay 1 8 82 3 lll 3 0D 1990 3 11 1996 1 2000 2 6
210. 6 0 Elliott 1965 0 Ya 0 Elliott 1965 Resmethrin O Itaya 1977 Katsuda 1965 Katsuda 1967 Imiprothrin O Benathrin Prallethrin hs Fujimoto 1968 O Katsuda 1966 Phenothrin Katsuda 1967 Furamethrin Ea Bs 4 CN 9 CI O O 0 gt 2 Nakanishi 1967 Cl COO Proparthrin Hirano 1973 Matsuo 1971 Elliott 1974 Empenthrin Cyphenothrin Permehrin XG AX COO COO F 0 F F Hammann amp Fuchs 1981 Naumann 1985 Cyfluthrin Iransfluthrin Y F F A Ujihara 1998 Metofluthrin CH20CH3 6 6
211. 1 LDso kg 146 150 350 221 500 500 0 500 500 LDso 2 8 100 3
212. 100000 sooo Mi ln lt 30000 30 35 40 45 50 55 60 2 1 4 25 1951 26 1958 33 1956 31 1955 30 1956 31 1950 32 1962 37 1957 ME 37 1964 39 1962 37 1963 38 1972 47 1975 50 1976 51 1974 49 1973 48 1981 56 1982 57 1954 29 1965 40 1971 46 1972 47 1974 49 1974 49 1975 50 1976 51 1962 d1 d T80 UL d T80 i 52 1983 58 1988 63 1986 61 1999 11 1988 63 1977 1993 5 d T80 EE d T80 d d T 1993
213. 27 2 9 1 2 27 3 9 1 2 3 4 27 4 9 1 St 2 3
214. 3 5 6 40 TRA I 1 ICI gt B
215. 5 1996 8 2001 13 2005 17 1968 43 1979 54 1978 53 1982 57 1 1988 63 2000 12 2004 16 1989 yy 7 C 20 30 4 40 40 46
216. NNW 3 WE EC gt 2 2 Ea a buy
217. YI bY 0 21 dd a FS 0 10 TT 1 51 0 815 0 544 1990 9 1 CMP GMP
218. HC Gammexane ICI 3cm 5mm crack and crevice
219. HzCHzCHs 7 CH3OCH3 CO2 4 4 24 0 af 2 5 1 0 1 0 5 40 50 40 50 10 20 2 77 40 60 40 60 2
220. o XA 450 680 gt 10 000 gt 1 560 4h 0 d T80 D 10 000 gt 5 000 x By mw zem DX D ru gt 10 000 gt 3 500 gt 2 000 2h 0 d T80 0 gt 5 000 gt 5 000 gt 2 100 4h CA Lo O Cl OL OL 430 470 gt 2 500 gt 685 3h so O i pn pe 2 250 2 640 gt 5 000 gt 1 850 3h 3h es O S 1 080 1 250 gt 2 000 gt 1 850 ed NS ddT80 460 640 gt 5 000 658 855 4h Y QO B34 a BZ TI gt 3 500 gt 2 000 gt 4 610 4h O 2 400 4500 gt 2 000 gt 1 200 4h 3 NN O 0 2 4 1 HN F Hd gt 5 000 5 000 gt 513 4h KX F O F 1 080 1960 co x 2 000 gt 2 000 4b Oo con F O 1 2 T 3
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