インドネシア スマトラ島における天然ゼオライト資源探査とその利用開発
Contents
1. uugppnuupuupugpuugpBaugpggugdgpudbubtsdu oof ooo oog gono OoOS3x2o oopan 3 3 rpg 9 2 4805 3 E RSS 3 3 3 ongo DODR E E E E EJ aaao EN ooogoo ooN gogo 53 3 E BG EJ r r3 Eit i E San b O 1 nod Fig2 Scanning Electron Microscope image of samples 000 000 O0 07071307 8 0 0 DO 70 U DO 0 C C OOo 940 c0 000000 o E Ei 1 m L3 LEE p L3 Lc rr E EP 53 53 1 5 ET RIguugg o o El E DS Ej E seg E 3820975005200 00258050 sooga ggo 24 5 ot o r LJ l Ln mu gt gOS OOS O aa ROOOR DOBROE5 O e gt 2 al Z o os A ERE TE 3 1 ooooooo ogo AA 1 O 53 11111 1111 111 EJ TE L1 7000 c 1 L3 L3 C3 E3 C2. 070 07071306 7071303 12591 1111 1 1 1 111 111 po0000 DO 000 Uu 07071301 07071302 07071305 07071307 07071402 07071403 07071405 07071406 OD0000000000000000000000000000000000 14000 0000 To ED EET EISE Odo BIG 6 1110 Table 1 Mineral compositions of samples Mineral composition of sample 07071201 anorthite montmorillonite quartz 07071301 07071302 07071303 07071304 07071305 07071306 07071307 07071308 07071309 07071401 07071402 07071403 07071404 07071405 07071406 07071601 montmorillonite anorthite
3. 5 r3 CE 002500 pgo FSSA Ec a mem H7 E a e E EE 5 54 43 Ej ca ES a ea c HE 5 63 6 5 5450900058 EYE EdXTEIE o0 55 559225049 Ere a E 4i cu Ju 52 o JA oo 018 on ee oes 00 eya n 3 2 a L3 E3 E3 E3 E3 p E32 C3 o 55 o cs 1 228 222 2 2 2 223 nuo a co 0750 o 00000000 o gg 63 63 03 52 03 3 mnm 2 222 y 63 03 53 03 03 2 2 2 3 Qa up SE Sens ga OD OOOO ODO DDD no 8 y 20000000 E gt 90 ees a 206 OOOO OH DE _ 3 goononnpa a e r3 63 02 03 53 362 3 3 93229 8 6 Ej 2 E rcjcmmpmpgmmpopagnoougogeuoegyg uouocug D CASO OE DO o a a a Y e 00 ADD ooooo0ogoO LJ poco o o rmn 3 3 O0 oOo oO A O r rmn c3 c3 El ES 1 L1 3 2 Eg eed En A 05956 5121 El 5 c3 E El L3 Son Ea
4. 3 gt to mm Ej 111101 ES lt 4 o pj o e On 5 oan 5 BRO DoOS5w ELS 3 53 3 2 4 2 5 2 2 298209205 r3 1 oog 20 FJ EFEPENM 5 o oonoton_ Son 20 2 32 oS Roar 3 DEA gt a BEI Sg a on 2 2 0 C3 r3 E L3 rn SSO Gg DORR Bas ia L3 r3 rn rm 5 53 28 0 7 3 EXE a e T 2 o p E D 3 2222 ED 3 202 2 2 p 2 2 EXEPERETENCJS a a 65 03 9 p L3 pc pc r3 Ad cocoa pun de o a us a EESTI g gt c ED 11 11 1111 O9 2 o L3 000 3 El L3 L3 L3 Lr L3 L3 L3 Oo L3 L3 L3 Lr L3 L3 E OOOO p4 2 so DES ELE w 5 E3 r3 E3 p A Oo 1 OH 2o00 G Lo L3 L3 E3 E3 c C3
5. quartz clinoptilolite anorthite montmorillonite quartz clinoptilolite anorthite mordenite cristobalite quartz clinoptilolite anorthite montmorillonite quartz anorthite clinoptilolite montmorillonite mordenite quartz clinoptilolite anorthite quartz cristobalite clinoptilolite anorthite montmorillonite quartz clinoptilolite anorthite mordenite quartz clinoptilolite cristobalite anorthite quartz clinoptilolite quartz anorthite mordenite clinoptilolite anorthite mordenite quartz montmorillonite clinoptilolite mordenite anorthite montmorillonite quartz clinoptilolite quartz anorthite mordenite montmorillonite clinoptilolite anorthite quartz clinoptilolite montmorillonite anorthite quartz clinoptilolite anorthite mordenite 2500 6 5 O O L1 2000 JAnorthite sd gt Aysus e e 1 Montmorillonite 20 deg Fig 1 The XRD pattern of sample 07071304 E35 rr C3 r3 rrr 3 36 23 EE EE 3 3 1412112111 L3 r3 rrr uf L3 rrr EJjp3 EET L3 3 5 01 01 L3 53 OO O L3 ooog ET E EK ESL ES oooO TO EE DON 5 o ouge 6 ctr C3 r3 ELE E ajo 03 7 Ele 2o00 g Oooeo o oam 353 637
6. r9 ggo Jama A miai oea El redd Eos a gles BEA 6 L3 O H 5 LA L3 LI rim Pon um eto On Ou o d lt ol oocH0no a ml E ou gt uy mm St r3 EAM A v eg Cor 1 82 1 a a OR O Ro 0225 5208 BA S ODO ro gt 2200 poo 17 F3 5 2 2 a 2005000 2 2 2 3 o a wom 1 Ere e mE E EO CE oy m l 23 3 2 2 o Su ESTEE ESICESL oao pre dE ESL ET O ESSET ESTE 1 EAE FE E21 Saele 1 1 4191 Ed 53d ER 2o00 Eg E E 38 o 3 3 2 2 ooo 5 2 3 un AH 25590980 e gt EE ERR AO E SS y bed IOS Rss g5 H2000 032 05 i ric M Ela 302325 203222 E EDES FE E vc as oO SER 02 17 5 gt oo
7. 33 11 94 6 85 5 16 0 26 0 32 0 6 5 09 0 07 0 10 39 100 8 43 10 83 07071304 60 44 12 42 7 39 3 78 0 22 0 15 0 41 3 48 0 05 0 11 11 56 100 8 26 7 63 07071305 67 32 8 36 1 68 3 73 0 48 0 4 0 22 4 32 0 0 13 49 100 13 67 8 93 07071306 64 13 9 96 4 77 4 47 0 59 0 44 0 3 3 64 0 04 0 07 11 59 100 10 93 9 14 07071307 63 67 11 11 4 12 4 04 0 68 0 59 0 31 4 24 0 05 0 14 11 04 100 9 73 9 55 07071308 62 67 12 09 2 58 5 31 0 68 0 71 0 37 4 23 0 05 0 06 11 27 100 8 8 10 93 07071309 63 38 10 24 3 17 5 42 0 41 0 7 0 5 74 0 03 0 11 10 79 100 10 5 12 27 07071401 61 73 11 22 4 26 5 38 0 45 1 03 0 63 3 89 0 04 0 11 36 100 9 34 10 75 07071402 63 86 10 4 3 16 5 47 0 62 0 22 0 33 4 54 0 0 11 41 100 10 42 10 85 07071403 63 88 10 57 3 85 5 61 0 69 0 53 0 48 2 05 0 04 0 12 31 100 10 26 8 88 07071404 65 24 11 35 3 25 3 78 0 77 0 29 0 59 3 62 0 02 0 11 09 100 9 75 8 46 07071405 65 38 13 43 1 59 2 58 1 54 0 37 0 16 0 29 0 0 09 14 57 100 8 26 4 78 07071406 64 41 10 42 3 58 4 56 0 77 0 78 0 43 2 74 0 0 18 12 13 100 10 49 8 85 07071601 60 08 11 93 3 18 5 24 0 82 0 3 0 63 3 93 0 0 05 13 86 100 8 55 10 29 0000000000000000 siozaeosug 100000000000000 O O 5102 203 800000000000000 51 03 2030 00000000 0000000000000000000 00 0 07071330500000000000 00 0000000000000000000000 000000000 ooo 000000000000 0000000000000000000000000 Do00000000000000000000000000 0 2030 230 0 00 0 0 510 203 0 0000000000000000 00000000 5
8. E3 EJ E3 EJ EJ E3 r3 EJ E3 L3 EJ r3 EJ EJ o 3 E3 E3 E3 E3 E3 E3 ooo coooooaooooogo Ed EJ E3 E3 EJ E3 EJ E3 r3 EJ E3 EJ EJ Ed EJ L3 EJ EJ EJ E3 C3 E3 EJ E3 E3 gt 0 5002505000 ELE r9 L3 E3 E3 E3 E3 E3 EJ E3 L3 Cd 4 4 EJ E3 E3 EJ E3 EJ 00504 EST EZ ES ETT A TEST ET L3 L3 L3 7071308 07071309 00000000000 Tammgamus 0 0 0 O O Batu Balai 07071401 07071402 07071403 07071304 07071405 07071406 Teluk Tengr 0 0 0000 070716010 000000000000000 17000 ammgamus 0 0 2000000000000 000 000000000 Dodo 0 00000000 ODO Dd 0000000000000 O 0 T 0 LT JE Y a 1 1 1 LLL uuu 0000 9 1111111101 1111111111 1 111111108 0000 0000 Uu 7130 po00000000 07071601
9. 000 19940 11000 0000000000 20066 11 0 60 000 111 popo0000000000
10. 102 2030 0 0 0 0 0 0 0 510 2030 00000000000000000 DD 000 00000000 D00000 00000000000000 17 0000000000000 Table 3 The result of CEC measurement 56 6 A 000000000000 000000 Sample number nnnnnnnunnonn non TD 155 DO000000000 00000000 2 2 n 0 000000000000000 i 0000000000000 0 07071302 26 2 23 0 000000000000000 07071303 43 9 18 8 00000000000000000 07071304 37 6 27 1 000000000000000000 07071305 34 2 38 9 070716010 000000000 07071306 47 4 48 1 DO 59 5 meq 1009 0 0 0 7 07071307 25 8 41 9 80 1008 OOOO 07071302 0 000 07071308 44 9 57 0 0000000000 26 2 meq 1009 07071309 48 8 53 8 O O 25 0 meq 100g T 07071401 38 2 41 5 07071402 52 0 60 1 00000000000000000 07071403 51 2 57 2 07071304 07071308 0 07071404 37 5 37 0 0000000000 07071306 07071307 07071405 51 5 52 5 1 4 11 1 ANA AAA NAAA NANA 07071406 40 3 38 0 pad 080 0800000 950 0 07071601 59 5 69 7 74200000000 LO ES 5 jel Ej 63 53 6 c goguuyuosuu 2 g 3522 22 2 5 92 2 9 22 2 2 059095992993 EA Sea Ehe Eg E a OR ORo tel ns Leu E eh de Ma EI
11. 200700 000000000000 0000000000000 Ex ENT a EEN 109 5 er o EX Ela Oo m m n 00 39 um nmn Lj pug dep o N o o oo o0 NE o o O E los a 65 o O E o 525 oo oo 2E o o ps Ego e A a PES r3 E 2 o o_o enden oo 908 o o 8 OO mO E 5 51 E Ma MS Eo ugs Sia OcA A yu o 5085 oo 00 o o a ou cnm au o o Oro DO DO gw n n H cep nao Ey Ep Ar GAS BO 2 ma e S5 Dona a o o rmno ro 289 o o ORG mnmmo r3 n amn m ET 5 n aa cos ME a B E on o ODO mu 544 p B BOODODOO r3 o o op ENG En 2570 o o o ODO 6 O 2 BAO OAA po Tus Ele c3 t mur 5 5 Sua o BES Ea yu 9822508580 3 52 2 53 5 TEE OR ORO numbnanu quu geuuumuqadg 32 ek 0 32 3 go 5368300000 el e Na a ESSERI 9 AO SCH go 25 5 22 033322 3165 s 2225 53 1 otoo goa 29 gt on 68 e a E 52631 2 n um eim poa 22950950 rib 3 22 3 r3 Exe Eo ESI p E os ip gl
12. 3 E3 3 6600 E E Weight loss wt99 10 a 20 2 Q 16 6 5 30 5 E 35 40 50 60 0 100 200 300 400 500 600 700 800 Temperature C Fig 3 TG DTA curve of sample 07071601 0 10 20 Q gt 30 8 c LLI 40 50 60 0 100 200 300 400 500 600 700 800 Temprerature C Fig 4 TG DTA curve of sample 07071403 200 300 400 500 600 700 800 100 Temprerature C Fig 5 TG DTA curve of sample 07071405 oo E3 r3 E3 oO L3 oO o S x o Ej bo O0 E Bo E d Em L3 r3 r3 L3 r3 ona Zr Ou E Es ES Bu L3 H Ou L1 oO pH Ou ua ea Ou l E3 C p L3 r3 H m oO BARS gH ooo pp ooo pr oo20 gH E og p3rHMEB p t p3 rH Lo al 5 Oo o O 3 3 3 LO N L3 A Mm o N o L3 L3 3 5 3 040000 E3 E3 L3 E El E 3 CJ EJ EJ CJ E3 E 0001000 E E oes E3 OOS O02000 0O 3 EJ E3 p p
13. 7 3 53 5 3 2 52 oopyro ny EL 032 5 port ERA aro o H 3 35 Ete pof ps 1 EXE LEE gOS ca E n r DDS EE pr Efi Ep qut L3 rur 2 3 352 3 7 Ed r3 2 oopan paa LT EJ ES ET EI ES 1 qup ESO Day oa Ha a L3 r3 E p 5 mrt coloco ABS 2 e gatean GAT 4191 21 ES EI 3 2 0302 02 o 3g OosoOQ L DODO nmge HOSS Eze ooo c nad 3 23 2 2 o BSS 1 51 1 1 21 o oooooo ovg RDA CE SOS mE oog L3 r3 E3 p ogo or aa a 0 HHH a zii 00000000000 00000000 00080000000 13430 0 11 220 SiO2 Al2Os 8 260 13 67 0 0 0 O Table 2 Chemical conpositions of samples obtained by XRF sample numbe SiO ALO FeO CaO a bu KO P O MnO Ig Loss total 83 ora 07071201 55 35 14 45 14 04 1 97 0 27 0 18 0 82 0 75 0 03 0 06 12 07 100 65 3 17 07071301 56 83 13 39 8 19 2 99 0 17 0 28 0 6 5 48 0 05 0 18 11 85 100 72 8 92 07071302 62 4 11 66 7 6 2 73 0 34 0 17 0 65 1 94 0 04 0 06 12 4 100 9 08 5 18 07071303 59
14. bc E3 E3 O L3 EJ E3 E3 E3 E3 E3 E3 E3 L3 E3 C3 L3 E3 EJ EJ E3 ELE 888580 0o00 xA E3 E3 CJ E3 E3 F3 3 9 9 8 2 ooon L3 r3 c3 E3 pm m rm p EJ L3 C3 EJ Lj ES ED 53 3 0200 agog nooo 09 EJ EJ Ed EJ L3 Ed EJ E3 EJ C3 EJ L3 EJ EJ L3 E3 Ed E3 C3 C3 EJ L3 E3 L3 L3 E3 C3 EJ L3 E3 EJ C3 L3 Ed 61060550000 ESLET 2 2 2 3 2 EJ E3 EJ O EJ E3 L3 EJ EJ E3 L3 EJ E3 EE EI 0000 19941 0 0 1110 OOOO ij 441000 00000000000 00 P232 240 GO vol 4 19900 00 0000p O O 19931 D 5D 1111 1 11 O D O 2000 E 111 1111 DEDI P276 284 0O 000000000000 1110 0 20000 po0000000 0000000 111000 00000000
15. m c E TET E o E 73 3 L3 L3 54 1 01009 0 0 0 58 O O Sumatera 0 0 O South Lampun South Lampung 0 0 D Talang Baru 7071201 07071301 07071302 Talang Baru Kart 000 0D 30 Bandar Dalam DD 0 O O O 07071304 07071305 07071306 Uu OOo 0 13 r3 E3 E3 E3 o r3 r3 EJ E3 E3 E3 E3 C3 r3 EJ o EJ 2 2 E3 E3 E3 E3 E EJ E EJ 2 EJ ERS EXE EP ETE BNC EJ EJ EJ E3 EJ EJ E3 EE 4 EJ E3 EJ E3 EJ E3 4 E3 EJ E3 E3 E3 E3 E3 EJ E3 E3 L3 E E E3 ESIECTEIEFEI EI Ed E33 EJ EJ E3 EJ EJ 4 E3
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