Seal-All 380113 Instructions / Assembly
Contents
1. Stop leak if without risk Move containers from spill area Approach release from upwind Prevent entry into sewers water courses basements or confined areas Wash spillages into an effluent treatment plant or proceed as follows Contain and collect spillage with non combustible absorbent material e g sand earth vermiculite or diatomaceous earth and place in container for disposal according to local regulations see section 13 Use spark proof tools and explosion proof equipment Dispose of via a licensed waste disposal contractor Contaminated absorbent material may pose the same hazard as the spilled product Note see section 1 for emergency contact information and section 13 for waste disposal Stop leak if without risk Move containers from spill area Dilute with water and mop up if water soluble or absorb with an inert dry material and place in an appropriate waste disposal container Use spark proof tools and explosion proof equipment Dispose of via a licensed waste disposal contractor Handling and elade Handling Storage 12 20 2011 Put on appropriate personal protective equipment see section 8 Eating drinking and smoking should be prohibited in areas where this material is handled stored and processed Workers should wash hands and face before eating drinking and smoking Do not breathe vapor or mist Do not ingest Avoid contact with eyes skin and clothing Use only with adequate ventilation Wear app2. 3 Label Additional information Limited quantity Yes Remarks lt 3 gal Consumer commodity ORM D Explosive Limit and Limited Quantity Index 5 Passenger Carrying Road or Rail Index 5 7 9 14 Transport information IMDG Class 1133 IATA DGR Class ADHESIVES 3 II Emergency schedules EmS F E S D Remarks Limited quantity Consumer commodity PG Packing group 15 Regulatory information Canada WHMIS Canada Canadian lists Canada inventory United States inventory TSCA 8b All components are listed or exempted SARA 311 312 fire Acute Chronic Class B 2 Flammable liquid Class D 2A Material causing other toxic effects Very toxic Class D 2B Material causing other toxic effects Toxic CEPA Toxic substances The following components are listed Volatile organic compounds Canadian NPRI The following components are listed Methyl ethyl ketone Volatile organic compounds Canada inventory All components are listed or exempted This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR Mexico Classification EU regulations Hazard symbol or symbols Risk phrases Safety phrases International regulations International lists 12 20 2011 Flammability Reactivity Special Health R11 Highly flammable R36 Irritating to eyes
3. I Indicates information that has changed from previously issued version Notice to reader To the best of our knowledge the information contained herein is accurate However neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein we cannot guarantee that these are the only hazards that exist 12 20 2011 9 9
4. Substances for which there is a Biological Exposure Index or Indices STEL 885 mg m 15 minute s STEL 300 ppm 15 minute s TWA 590 mg m 8 hour s TWA 200 ppm 8 hour s NIOSH REL United States 6 2008 STEL 885 mg m 15 minute s STEL 300 ppm 15 minute s TWA 590 mg m 10 hour s TWA 200 ppm 10 hour s OSHA PEL United States 11 2006 TWA 590 mg m 8 hour s TWA 200 ppm 8 hour s OSHA PEL 1989 United States 3 1989 STEL 885 mg m 15 minute s STEL 300 ppm 15 minute s TWA 590 mg m 8 hour s TWA 200 ppm 8 hour s Acetone ACGIH TLV United States 1 2009 STEL 1782 mg m 15 minute s STEL 750 ppm 15 minute s TWA 1188 mg m 8 hour s TWA 500 ppm 8 hour s NIOSH REL United States 6 2008 TWA 590 mg m 10 hour s TWA 250 ppm 10 hour s OSHA PEL United States 11 2006 TWA 2400 mg m 8 hour s TWA 1000 ppm 8 hour s OSHA PEL 1989 United States 3 1989 Notes The acetone STEL does not apply to the cellulose acetate fiber industry It is in effect for all other sectors STEL 2400 mg m 15 minute s STEL 1000 ppm 15 minute s TWA 1800 mg m 8 hour s TWA 750 ppm 8 hour s Recommended monitoring If this product contains ingredients with exposure limits personal workplace atmosphere procedures or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and or the necessity to use respiratory protective equipm
5. R66 Repeated exposure may cause skin dryness or cracking R67 Vapors may cause drowsiness and dizziness S2 Keep out of the reach of children S46 If swallowed seek medical advice immediately and show this container or label Australia inventory AICS All components are listed or exempted China inventory IECSC All components are listed or exempted Korea inventory KECI Not determined Philippines inventory PICCS All components are listed or exempted Japan inventory ENCS Not determined Europe inventory Not determined 8 9 16 Other information Hazardous Material Information System U S A Health Flammability Physical hazards Caution HMIS ratings are based on a 0 4 rating scale with 0 representing minimal hazards or risks and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR 1910 1200 the preparer may choose to provide them HMIS ratings are to be used with a fully implemented HMIS program HMIS is a registered mark of the National Paint amp Coatings Association NPCA HMIS materials may be purchased exclusively from J J Keller 800 327 6868 The customer is responsible for determining the PPE code for this material National Fire Protection Association U S A Flammability Health Instability Special Date of printing 12 20 2011 Date of issue 12 20 2011 Date of previous issue 11 16 2011 Version 1 03
6. combustion products Special protective equipment for fire fighters Do not use water jet Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire No action shall be taken involving any personal risk or without suitable training Move containers from fire area if this can be done without risk Use water spray to keep fire exposed containers cool Decomposition products may include the following materials carbon oxides Fire fighters should wear appropriate protective equipment and self contained breathing apparatus SCBA with a full face piece operated in positive pressure mode 6 Accidental release measures Personal precautions Environmental precautions Large spill Small spill No action shall be taken involving any personal risk or without suitable training Evacuate surrounding areas Keep unnecessary and unprotected personnel from entering Do not touch or walk through spilled material Shut off all ignition sources No flares smoking or flames in hazard area Avoid breathing vapor or mist Provide adequate ventilation Wear appropriate respirator when ventilation is inadequate Put on appropriate personal protective equipment see section 8 Avoid dispersal of spilled material and runoff and contact with soil waterways drains and sewers Inform the relevant authorities if the product has caused environmental pollution sewers waterways soil or air
7. 0000 ug L Fresh water Acute LC50 gt 100000 ug L Fresh water Acute LC50 10000 ug L Fresh water Acute LC50 13300000 ug L Fresh water Acute LC50 12600000 ug L Fresh water Daphnia cucullata Daphnia 48 hours Daphnia cucullata Fish Pimephales promelas Fish Pimephales promelas Fish Pimephales promelas Daphnia 96 hours 96 hours 96 hours 48 hours Daphnia magna Daphnia 48 hours Daphnia magna Daphnia 48 hours Daphnia magna Waste disposal The generation of waste should be avoided or minimized wherever possible Dispose of surplus and non recyclable products via a licensed waste disposal contractor Disposal of this product solutions and any by products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements Avoid dispersal of spilled material and runoff and contact with soil waterways drains and sewers Disposal should be in accordance with applicable regional national and local laws and regulations Refer to Section 7 HANDLING AND STORAGE and Section 8 EXPOSURE CONTROLS PERSONAL PROTECTION for additional handling information and protection of employees 14 Transport information Regulatory information DOT Classification TDG Classification 12 20 2011 UN number Proper shipping name Not available Consumer commodity ADHESIVES Classes
8. ECLECTIC IM THE HOME amp ON THE JOB PRODUCTS Material Safety Data Sheet 1 Product and company identification Trade name gt Supplier Material uses Manufacturer Code Validation date Print date Responsible name In case of emergency Seal All Eclectic Products Inc 1075 Arrowsmith Eugene OR 97402 541 484 9621 Consumer products Adhesive Eclectic Products Inc 1075 Arrowsmith Eugene OR 97402 541 484 9621 1070105 12 20 2011 12 20 2011 Regulatory Compliance CALL INFOTRAC 800 535 5053 001 352 323 3500 2 Hazards identification Physical state Emergency overview Routes of entry Potential acute health effects Inhalation Ingestion Skin Eyes Potential chronic health effects No known significant effects or critical hazards No known significant effects or critical hazards No known significant effects or critical hazards No known significant effects or critical hazards No known significant effects or critical hazards No known significant effects or critical hazards Contains material which may cause damage to the following organs lungs peripheral Chronic effects Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Target organs Over exposure signs symptoms Adverse symptoms may include the following Inhalation Ingestion 12 20 2011 Liquid WARNING FLAMMABLE LIQUID AND VAPOR CAUSES R
9. ESPIRATORY TRACT EYE AND SKIN IRRITATION MAY BE HARMFUL IF SWALLOWED Flammable liquid Harmful if swallowed Irritating to eyes respiratory system and skin Keep away from heat sparks and flame Do not ingest Avoid breathing vapor or mist Avoid contact with eyes skin and clothing Use only with adequate ventilation Keep container tightly closed and sealed until ready for use Wash thoroughly after handling Dermal contact Eye contact Inhalation Irritating to respiratory system Harmful if swallowed Irritating to skin Irritating to eyes nervous system upper respiratory tract skin central nervous system CNS eye lens or cornea respiratory tract irritation coughing No specific data 1 9 2 Hazards identification Skin Adverse symptoms may include the following irritation redness Eyes Adverse symptoms may include the following pain or irritation watering redness Medical conditions Pre existing digestive disorders may be aggravated by over exposure to this product aggravated by over exposure See toxicological information section 11 3 Composition information on ingredients Name CAS number Methyl Ethyl Ketone 78 93 3 30 60 Acetone 67 64 1 10 30 There are no ingredients or additional ingredients present which within the current knowledge of the supplier and in the concentrations applicable are classified as hazardous to health or the environment and hence require report
10. ent Engineering measures Use only with adequate ventilation Use process enclosures local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits The engineering controls also need to keep gas vapor or dust concentrations below any lower explosive limits Use explosion proof ventilation equipment Hygiene measures Wash hands forearms and face thoroughly after handling chemical products before eating smoking and using the lavatory and at the end of the working period Appropriate techniques should be used to remove potentially contaminated clothing Wash contaminated clothing before reusing Ensure that eyewash stations and safety showers are close to the workstation location Personal protection Respiratory Use a properly fitted air purifying or air fed respirator complying with an approved standard if a risk assessment indicates this is necessary Respirator selection must be based on known or anticipated exposure levels the hazards of the product and the safe working limits of the selected respirator Hands Chemical resistant impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary 12 20 2011 4 9 8 Exposure controls personal protection Eyes Safety eyewear complying with an approved standard should be used when a risk as
11. ing in this section 4 First aid measures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes occasionally lifting the upper and lower eyelids Check for and remove any contact lenses Get medical attention Skin contact Flush contaminated skin with plenty of water Remove contaminated clothing and shoes Continue to rinse for at least 10 minutes Get medical attention Wash clothing before reuse Clean shoes thoroughly before reuse Inhalation Move exposed person to fresh air If it is suspected that fumes are still present the rescuer should wear an appropriate mask or self contained breathing apparatus Keep person warm and at rest If not breathing if breathing is irregular or if respiratory arrest occurs provide artificial respiration or oxygen by trained personnel It may be dangerous to the person providing aid to give mouth to mouth resuscitation Get medical attention If unconscious place in recovery position and get medical attention immediately Maintain an open airway Loosen tight clothing such as a collar tie belt or waistband Ingestion Wash out mouth with water Remove dentures if any Move exposed person to fresh air Keep person warm and at rest If material has been swallowed and the exposed person is conscious give small quantities of water to drink Stop if the exposed person feels sick as vomiting may be dangerous Do not induce vomiting unless directed to do so by medical perso
12. nnel If vomiting occurs the head should be kept low so that vomit does not enter the lungs Get medical attention Never give anything by mouth to an unconscious person If unconscious place in recovery position and get medical attention immediately Maintain an open airway Loosen tight clothing such as a collar tie belt or waistband Protection of first aiders No action shall be taken involving any personal risk or without suitable training If it is suspected that fumes are still present the rescuer should wear an appropriate mask or self contained breathing apparatus It may be dangerous to the person providing aid to give mouth to mouth resuscitation Notes to physician No specific treatment Treat symptomatically Contact poison treatment specialist immediately if large quantities have been ingested or inhaled 5 Fire fighting measures Flammability of the product Flammable liquid In a fire or if heated a pressure increase will occur and the container may burst with the risk of a subsequent explosion The vapor gas is heavier than air and will spread along the ground Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back Runoff to sewer may create fire or explosion hazard Extinguishing media Suitable Use dry chemical COz water spray fog or foam 12 20 2011 2 9 5 Fire fighting measures Not suitable Special exposure hazards Hazardous
13. onfined areas Materials to avoid Reactive or incompatible with the following materials oxidizing materials Hazardous decomposition Under normal conditions of storage and use hazardous decomposition products should products not be produced Hazardous polymerization Will not occur 11 Toxicological information Acute toxicity Product ingredient name Result Species Dose Exposure Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg kg LD50 Rat 607 mg kg Intraperitoneal LD50 Oral Rat 2737 mg kg Acetone LD50 Intravenous Rat 5500 mg kg LD50 Oral Rat 5800 mg kg LD50 Oral Rat 5800 mg kg LDLo Dermal Rabbit 20 mL kg LDLo Rat 500 mg kg Intraperitoneal TDLo Oral Rat 5 mL kg Carcinogenicity Conclusion Summary IDLH Not available Synergistic products Not available 12 20 2011 5 9 12 Ecological information Environmental effects Aquatic ecotoxicity Product ingredient name Methyl Ethyl Ketone Acetone 12 20 2011 Test No known significant effects or critical hazards Result Acute EC50 5091000 to 6440000 ug L Fresh water Acute LC50 3220000 to 3320000 ug L Fresh water Acute LC50 gt 520000 ug L Fresh water Acute LC50 5600000 ug L Fresh water Acute LC50 gt 400 ppm Marine water Chronic NOEC lt 70000 ug L Fresh water Acute LC50 6900 mg L Fresh water Acute LC50 5 54 to 6 33 ml L Fresh water Acute LC50 12100000 ug L Fresh water Acute LC50 11000000 to 11300000 ug L Marine wate
14. r Acute LC50 10700000 ug L Fresh water Acute LC50 9218000 to 14400000 ug L Fresh water Acute LC50 9100000 to 9482000 ug L Fresh water Acute LC50 8800000 ug L Fresh water Acute LC50 8300000 ug L Fresh water Acute LC50 8300000 ug L Fresh water Acute LC50 8120000 to 8760000 ug L Fresh water Acute LC50 8098000 to 8640000 ug L Fresh water Acute LC50 Species Daphnia Daphnia magna Fish Pimephales promelas Daphnia Daphnia magna Fish Gambusia affinis Fish Cyprinodon variegatus Daphnia Daphnia magna Daphnia Daphnia magna Fish Oncorhynchus mykiss Daphnia Daphnia magna Fish Alburnus alburnus Fish Pimephales promelas Daphnia Daphnia magna Fish Pimephales promelas Daphnia Daphnia pulex Fish Lepomis macrochirus Fish Lepomis macrochirus Fish Pimephales promelas Daphnia Ceriodaphnia dubia Daphnia Exposure 48 hours 96 hours 48 hours 96 hours 96 hours 48 hours 48 hours 96 hours 48 hours 96 hours 96 hours 48 hours 96 hours 48 hours 96 hours 96 hours 96 hours 48 hours 48 hours 6 9 12 Ecological information Conclusion Summary Biodegradability Conclusion Summary Not available Not available 13 Disposal considerations 7810000 ug L Fresh water Acute LC50 7460000 ug L Fresh water Acute LC50 7280000 to 7880000 ug L Fresh water Acute LC50 6210000 to 703
15. ropriate respirator when ventilation is inadequate Do not enter storage areas and confined spaces unless adequately ventilated Keep in the original container or an approved alternative made from a compatible material kept tightly closed when not in use Store and use away from heat sparks open flame or any other ignition source Use explosion proof electrical ventilating lighting and material handling equipment Use non sparking tools Take precautionary measures against electrostatic discharges To avoid fire or explosion dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material Empty containers retain product residue and can be hazardous Do not reuse container Store in accordance with local regulations Store in a segregated and approved area Store in original container protected from direct sunlight in a dry cool and well ventilated area away from incompatible materials see section 10 and food and drink Eliminate all ignition sources Separate from oxidizing materials Keep container tightly closed and sealed until ready for use Containers that have been opened must be carefully resealed and kept upright to prevent leakage Do not store in unlabeled containers Use appropriate containment to avoid environmental contamination 3 9 8 Exposure controls personal protection Product name Exposure limits Methyl Ethyl Ketone ACGIH TLV United States 1 2009 Notes
16. sessment indicates this is necessary to avoid exposure to liquid splashes mists gases or dusts Skin Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they controls comply with the requirements of environmental protection legislation In some cases fume scrubbers filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels 9 Physical and chemical properties Physical state Liquid Flash point Closed cup 0 55556 C 31 F Setaflash Color Clear Odor Not available Boiling condensation point gt 100 C gt 212 F Specific gravity 0 95 Vapor pressure 24 5 kPa 184 mm Hg Estimated Vapor Density gt 1 Air 1 VOC 3 7517 Evaporation rate Bi Water 1 Solubility Partially soluble in the following materials water 10 Stability and deal Stability The product is stable Under normal conditions of storage and use hazardous polymerization will not occur Conditions to avoid Avoid all possible sources of ignition spark or flame Do not pressurize cut weld braze solder drill grind or expose containers to heat or sources of ignition Do not allow vapor to accumulate in low or c
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