Grace 5003107 Instructions / Assembly
Contents
1. HMIS Rating Health 2 Flammability 1 Reactivity 0 Personal Protective Equipment B Potential Health Effects Inhalation Due to the physical nature of this product inhalation is unlikely If heated inhalation of vapor causes irritation sore throat coughing and breathing difficulty Effects include Nausea headache dizziness and irritation Eye Contact Eye contact with rubberized asphalt residue on hands can cause irritation Skin Contact Skin contact causes irritation Prolonged skin contact can result in dermatitis Contact with petroleum oils in this product may produce serious toxic effects including skin cancer liver damage blood effects and effects on the unborn based on tests with laboratory animals Animal tests indicate that prolonged and repeated skin contact to the oils in this product may produce local skin tumors Individuals with pre existing skin disorders may be at increased risk for worsening their condition from exposure to this product See Section 8 Page 1 of 6 W R GRACE MATERIAL SAFETY DATA SHEET Product Name Waterproofing Membrane MSDS ID Number M 85814 MSDS Date 11 10 08 Skin Absorption Product can be absorbed through the skin upon prolonged contact resulting in systemic effects such as nausea headache and general discomfort Ingestion Due to the physical nature of this product ingestion is unlikely If ingested causes burns to the linings of the mouth esophagus and st2. 64742 04 7 21 New Jersey Hazardous Substance List Identification threshold 0 1 Chemical Name CAS Wt Pennsylvania Hazardous Substance List Identification threshold 0 01 Chemical Name CAS Wt CHEMICAL INVENTORY STATUS All chemicals in this product are listed or exempt from listing in the following countries US CANADA EUROPE AUSTRALIA JAPAN KOREA PHILIPPINES TSCA DSL NDSL EINECS ELINCS AICS ENCS ECL PICCS Yes Yes No Yes Yes Not Determined Yes Yes SECTION 16 OTHER INFORMATION BITUTHENE LOW TEMPERATURE WATERPROOFING MEMBRANE MEMBRANE STRIPS BITUTHENE SYSTEM 4000 WATERPROOFING MEMBRANE MEMBRANE STRIPS PERM A BARRIER WALL FLASHING PERM A BARRIER WALL MEMBRANE PERM A BARRIER LOW TEMPERATURE MEMBRANE PERM A BARRIER DETAIL MEMBRANE GRACE ICE amp WATER SHIELD GRACE ROOF DETAIL MEMBRANE PITTWRAP CW GRACE SELECT VYCOR V40 WEATHER BARRIER STRIPS GRACE VYCOR PLUS TAPES GRACE BASIK GRACE VYCOR DECK PROTECTOR GRACE VYCOR ALL PURPOSE FLASHING GRACE VYCOR ALUMINUM FLASHING PREPRUFE SCS DETAIL TAPE GENERIC 40 MIL FLASHING LOG PERM A BARRIER ALUMINUM FLASHING Non Hazardous Ingredient Disclosure Chemical Name Prepared by Approved by Approved Date Disclaimer The data included herein are presented in accordance with various environment health and safety regulations It is the responsibility of a recipient of the data to remain currentl
3. ECTIVE EQUIPMENT EXPOSURE GUIDELINES US PASTEL Ceiling TWA STEL Ceiling Heavy Paraffinic Distillate erent penaanesaubo goss TLL benzene soluble aerosol apime ne PT copolymer EXPOSURE GUIDELINES CANADA Employers should consult local Provincial regulatory limits for exposure guidelines which may vary locally Engineering Controls Not generally required Personal Protective Equipment Respiratory Protection Respiratory protection is not generally required If exposure limits are exceeded wear approved respiratory protection Skin Protection Use oil impervious gloves to avoid prolonged or repeated contact with rubberized asphalt residue Eye Protection Not required for normal use Work Hygienic Practices Use good personal hygiene practices Avoid rubbing eyes while handling Due to the physical nature of this product ingestion is unlikely Incidental ingestion of residue on hands can be avoided by using good personal hygiene practices This product contains compounds subject to exposure guidelines and or identified as carcinogens See Sections 8 and 11 However due to the physical nature of this product these compounds are unlikely to reach exposure limits unless airborne dust or spray mist is created To avoid skin contact wear recommended gloves see skin protection recommendation and wash with soap and water after handling Intermittent or occasional skin contact with petroleum asphalt is not exp
4. W R GRACE MATERIAL SAFETY DATA SHEET Product Name Waterproofing Membrane MSDS ID Number M 85814 MSDS Date 11 10 08 SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name Waterproofing Membrane MSDS Number M 85814 Cancelled MSDS Number M 85811 MSDS Date 11 10 08 Chemical Family Name Rubberized Asphalt Adhesive Sheet with Film and or Mesh Comprising Various Components Product Use Waterproofing Membrane Chemical Formula Mixture NA CAS Chemical Abstracts Service Number Mixture NA Manufactured by W R Grace amp Co Conn Grace Canada Inc 62 Whittemore Avenue 294 Clements Road West Cambridge MA 02140 Ajax Ontario L1S 3C6 In Case of Emergency Call In USA 617 876 1400 In Canada 905 683 8561 SECTION 2 COMPOSITION INFORMATION ON INGREDIENTS Ingredient CCC Heavy Paraffinic Distillate Solvent Extract 064742 04 7 10 25 Petroleum Asphalt 008052 42 4 50 100 Styrene Butadiene block copolymer 009003 55 8 10 25 SECTION 3 HAZARDS IDENTIFICATION Emergency Overview Warning Eye contact with rubberized asphalt residue on hands can cause irritation Skin contact with rubberized asphalt can cause irritation May be harmful if ingested May be harmful if absorbed through skin May cause teratogenic effects May produce local skin tumors Removal of release liner may generate a static electrical discharge spark Release liners are slippery Remove from work area immediately
5. Waterproofing Membrane MSDS ID Number M 85814 MSDS Date 11 10 08 SECTION 11 TOXICOLOGICAL INFORMATION Ingredient No data unless listed CAS Number LD50 and LC50 Carcinogenicity Ingredient IARC IARC IARC NTP NTP OSHA Group 1 Group 2A No 2B Known Suspect Heavy Paraffinic Distillate Solvent Extract No Petroleum Asphalt m m e e e e Styrene Butadiene block copolymer No No No No No No Animal tests indicate that prolonged and repeated skin contact with the asphalt in this product may produce local skin tumors Mutagenicity Not applicable Teratogenicity Petroleum oils in this product have caused effects on the unborn based on tests with laboratory animals Reproductive Toxicity Not applicable SECTION 12 ECOLOGICAL INFORMATION Environmental Fate No data available for product Ecotoxicity No data available for product SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal Procedures Consult all regulations federal state provincial local or a qualified waste disposal firm when characterizing waste for disposal According to EPA 40 CFR 261 waste of this product is not defined as hazardous Dispose of waste in accordance with all applicable regulations SECTION 14 TRANSPORTATION INFORMATION Proper Shipping Name Not Applicable UN NA Number Not Applicable Domestic Hazard Class Nonhazardous Surface Freight Classification Asphalt Mixture N O 1 B N Label Placard Required Not Applic
6. able SECTION 15 REGULATORY INFORMATION REGULATORY CHEMICAL LISTS CERCLA Comprehensive Response Compensation and Liability Act None present unless listed below Chemical Name CAS Wt CERCLA RQ SARA Title Ill Superfund Amendments and Reauthorization Act SARA Section 312 Tier amp Il Hazard Categories Health Immediate acute Yes Health Delayed chronic Yes Flammable No Reactive No Pressure No 302 Reportable Ingredients Identification Threshold 1 Chemical Name CAS Wt SARA 302 TPQ 313 Reportable Ingredients Chemicals present below reporting threshold are exempt Chemical Name CAS Wt National Volatile Organic Compound Emission Standards For Architectural Coatings Volatile Organic Content gr L Not Applicable WHMIS Classification s D2B Page 5 of 6 W R GRACE MATERIAL SAFETY DATA SHEET Product Name Waterproofing Membrane MSDS ID Number M 85814 MSDS Date 11 10 08 This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations CPR This MSDS contains all the information required by the CPR State Requlatory Information California Proposition 65 This product contains substances known to the state of California to cause cancer birth defects or other reproductive harm Massachusetts Hazardous Substance List Identification threshold 0 001 ippm Chemical Name CAS Wt Heavy Paraffinic Distillate Solvent Extract 0
7. ected to have serious health effects as long as good personal hygiene measures are taken Promptly cleanse with waterless hand cleaner clean fingernails and wash with soap and water after handling All employees working with this product must exercise good and prudent personal hygiene practices SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Physical State Solid sheet Appearance Odor A black rubberized asphalt adhesive layer on a grey black plastic sheet with a paper or plastic release sheet Petroleum odor Odor Threshold ppm Unknown pH Not Applicable Vapor Pressure Mm Hg Not Applicable Vapor Density Air 1 Not Applicable Solubility In Water Negligible Specific Gravity Water 1 1 0 1 1 Evaporation Rate Butyl Acetate 1 Not Applicable Boiling Point Not Applicable Viscosity Not Available Bulk Density Pounds Cubic 70 Foot Pcf Volatiles gr L 70 F 21 C Negligible SECTION 10 STABILITY AND REACTIVITY Chemical Stability Stable Conditions To Avoid Heat Oxidizing materials Strong oxidizers and Water Hazardous Polymerization Will not polymerize Hazardous Decomposition Carbon dioxide Carbon monoxide Sulfur oxides and Low Page 3 of 6 W R GRACE MATERIAL SAFETY DATA SHEET Product Name Waterproofing Membrane MSDS ID Number M 85814 MSDS Date 11 10 08 Products molecular weight hydrocarbons Page 4 of 6 W R GRACE MATERIAL SAFETY DATA SHEET Product Name
8. mbustion exist Avoid breathing hazardous vapors or products of combustion keep upwind Isolate area and keep unnecessary people away Prevent run off from fire control or dilution from entering streams or drinking water supplies Unusual Fire and Explosion Hazards None unless noted below Removal of release paper may create a static electric discharge sparks Do not remove where sparks may ignite flammable vapors SECTION 6 ACCIDENTAL RELEASE MEASURES Spills Leaks Due to the physical nature of this product spills are not possible SECTION 7 HANDLING AND STORAGE Precautionary Measures Avoid contact with eyes skin and clothing Practice good personal hygiene to avoid ingestion Use only with adequate ventilation Wash clothing before reuse Slippery when wet or covered with frost Do not apply where membrane odors may penetrate living areas To avoid skin contact use gloves or barrier creams Promptly cleanse hands with waterless hand cleaner clean fingernails and wash with soap and water after handling Release liners are slippery Remove from work area immediately after membrane application Consistent with good roofing practice always wear fall protection when working on roof decks Page 2 of 6 W R GRACE MATERIAL SAFETY DATA SHEET Product Name Waterproofing Membrane MSDS ID Number M 85814 MSDS Date 11 10 08 FOR PROFESSIONAL USE ONLY KEEP OUT OF CHILDREN S REACH SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROT
9. omach Effects include Nausea vomiting and diarrhea Wash hands before eating SECTION 4 FIRST AID MEASURES Skin Contact In case of skin contact clean fingernails and wash skin with soap and water If residue remains clean with waterless hand cream or abrasive soap Never use solvents If discomfort or irritation persists consult a physician Remove contaminated clothing and wash before reuse Eye Contact Flush eyes with water for at least 15 minutes while holding eyelids open Get immediate medical attention Ingestion If swallowed contact a physician immediately Never give anything by mouth to an unconscious person The decision to induce vomiting should only be made by a physician Inhalation If symptoms develop get fresh air If symptoms persist consult a physician If breathing has stopped give artificial respiration then oxygen if needed Get immediate medical attention SECTION 5 FIRE AND EXPLOSION HAZARD DATA Flash Point gt 210C gt 410F Flash Point Method Open Cup Lower Explosion Limit Not Available Upper Explosion Limit Not Available Auto lIgnition Temperature Not Available NFPA Rating Health 1 Flammability 1 Reactivity 0 Extinguishing Media In case of fire use water spray dry chemical Carbon dioxide or foam Special Fire Fighting Procedures Wear self contained breathing apparatus and complete personal protective equipment when potential for exposure to vapors or products of co
10. y informed on chemical hazard information to design and update its own program and to comply with all national federal state and local laws and regulations applicable to safety occupational health right to know and environmental protection CAS Number EH amp S Department EH amp S Department 11 10 08 Page 6 of 6
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