Tender Corporation After Sting Jellyfish
Contents
1. Non Bulk Regulation UN No Proper Shipping Name Class Package Label Additional Group Information U S Department of Transportation DOT E E _ Not regulated Non Bulk U S Department of Transportation DOT 3266 Corrosive liquids n o s 8 Ill C Corrosive Bulk Ammonium Hydroxide Canadian Transportation of Dangerous _ Ammonium Hydroxide 8 m Corrosive Goods TDG Non Bulk International Maritime Dangerous Goods 2 _ Not regulated IMDG Non Bulk International Air Transport Assoc IATA cs _ s _ Not regulated The transportation regulations are cited according to international are not considered regulations and in the form applicable to the United S ates and Canada Possible national deviations in other countries SECTION 15 REGULATORY INFORMATION U S FEDERAL REGULATIONS TSCA TOXIC SUBSTANCE CONTROL ACT CERCLA COMPREHENSIVE RESPONSE COMPENSATION AND LIABILITY ACT CERCLA HAZARDOUS SUBSTANCE Ammonium hydroxide CAS 1336 21 6 CERCLA REPORTABLE QUANITIY RQ 500 bs RCRA 261 RESOURCE CONSERVATION RECOVERY ACT Ammonium hydroxide CAS 1336 21 6 SARA TITLE Ill SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT Section 302 Extremely Hazardous Substances TPQ TPQ 500lbs 311 312 HAZARD CLASS Acute Health and Chronic Health Hazard 313 REPORTABLE INGREDIENTS Ammonium hydroxide CAS 1336 21 6 California Proposition 65 None States Right to Know This pro2. CTION 16 OTHER INFORMATION PHMIS o G T O Health Flammability 0 Reactivity 0 Special Corrosive 4 extreme 3 High 2 Moderate 1 Slight 0 Insignificant REVISED SECTIONS OR REASON FOR REVISION ISSUED DATE OCT 22 2007 1 1 13 2009 NAME ADDITION 2 5 14 2010 NEW WHIMIS amp EU COMPLIANT FORMATTTING 3 6 21 2010 NEW GHS FORMATTING SPEC CHANGE TO SP GR amp PH 4 4 23 12 MEDICAL INFORMATION PHONE amp ADDED E MAIL ADDRESS PRINT DATE PRODUCT CODE INGREDIENT RANGES DISCLAIMER The information provided herein was believed to be accurate to the best knowledge of Tender Corporation at the time of preparation from a compilation of sources believed to be reliable and is furnished without warranty expressed or implied It is the responsibility of the user to investigate and understand other pertinent sources of information to comply with all laws and procedures applicable to the safe handling storage and use of this product and to determine the suitability of the product for its intended use This data sheet relates only to the specific product listed and does not relate to use in combination or in any process with other materials Product Code 0001 1113 Page 6 of 6 Date Printed 31 October 2013
3. RE CONTROLS PERSONAL PROTECTION Read entire label before using Use strictly in accordance with label precautionary statements and Keep product in its original container Keep container tightly closed Store this product in a cool dry ENGINEERING CONTROLS General ventilation is usually adequate When handling large quantities of concentrated product Use local exhaust ventilation if necessary PERSONAL PROTECTIVE EQUIPMENT PPE None required EXPOSURE GUIDELINES INGREDIENT CAS NO Exposure Limits ACGIH TLV TWA ACGIH TLV STEL OSHA PEL TWA Ammonia 7664 41 7 lt 3 5 18 mg m3 TWA 25ppm 40 ppm as STEL SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Opaque gel ODOR Ammonia pH 10 0 to 12 0 BOILING POINT Not determined MELTING POINT RELATIVE DENSITY H20 1 25 C VAPOR PRESSURE mmHg C VAPOR DENSITY AIR 1 FLASH POINT SOLUBILITY IN WATER SOLUBILITY IN SOLVENTS VISCOSITY VOLATILE ORGANIC COMPOUNDS VOC PARTITION COEFFICIENT Not applicable 1 00 gm ml Not applicable Not applicable Not expected for water based product Complete Not determined 30 000 cps 25 C Not determined Not determined SECTION 10 STABILITY AND REACTIVITY STABILITY CONDITIONS TO AVOID INCOMPATIBILITY MATERIAL TO AVOID HAZARDOUS DECOMPOSITION OR BY PRODUCTS HAZARDOUS POLYMERIZATION Product Code 0001 1113 2013 Stable Extreme temperatures Sunlig
4. duct contains Ammonium hydroxide CAS 1336 21 6 CANADIAN REGULATIONS EJ WHMIS CLASSIFCATION Class E Corrosive D This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR DOMESTIC SUBSTANCE LIST DSL NON DOMESTIC SUBSTANCE LIST NDSL A components are listed or exempt Canadian Ingredient Disclosure List Ammonium hydroxide CAS 1336 21 6 Product Code 0001 1113 2013 Page 5 of 6 Date Printed 37 October All components of this product are listed or exempt on the TSCA list t 2 tender CORPORATION MATERIAL SAFETY DATA SHEET SAFETY DATA SHEET Prepared according to 29CFR 1910 1200 Regulation EC No 1272 2008 GHS and Canadian Controlled Products Act CPR EU REGULATIONS Labeling in accordance with EC Directives Hazard symbols P Irritant Corrosive Toxic to Aquatic Organisms Hazardous component s to be indicated on label Contains Ammonium hydroxide EC Number R phrases 22 Harmful if swallowed 36 37 38 Irritating to eyes skin and respiratory system S phrases 1 2 Keep locked and out of the reach of children 26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 45 in case of accident or if you feel unwell seek medical advise immediately 49 Keep only in the original container 61 avoid release to the environment Refer to special instructions safety data sheet SE
5. fied as having sensitizing properties Method Source Literature Not determined Method Source Carcinogenicity Reproductive toxicity No components present in this material at concentrations of 0 1 or greater are listed by IARC NTP OSHA or ACGIH as being carcinogens Source Safety Data Sheets of components Specific Target Organ Toxicity Single exposure GHS no data available Repeated exposure GHS no data available Signs and Symptoms of Exposure Redness rash or blistering POTENTIAL HEALTH EFFECTS INHALATION SKIN CONTACT EYE CONTACT INGESTION General Comments Mobility May cause irritation to lungs Pre existing skin disorders may be aggravated by exposure Prolonged contact may cause irritation with redness pain tearing blurred vision and conjunctivitis Harmful if swallowed SECTION 12 ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product but it is classified on the basis of the known hazards of the components This section is not required by WHMIS The product is water based and expected to be mobile in the aquatic environment Persistence degradability The Ammonium Hydroxide is readily biodegradable in the environment according to Bioaccumulation Toxicity Product Code 0001 1113 2013 ECBI 07 00 Rev 3 29 8 00 The Ammonium Hydroxide has been shown to have a low bioaccumulation Log POW 2 02 The Ammonium Hydroxide has been shown
6. ht Metals and Oxidizing agents Attacks many metals forming explosive gas Reacts violently with acids Strong acids most common metals strong oxidizing agents bromine chlorine aluminum copper brass bronze hypochlorite acids monoammonium phosphate sodium potassium alloy strong alkalis or mineral acids Will not occur Page 3 of 6 Ammonia Carbon dioxide Carbon monoxide Nitrogen oxides Date Printed 31 October t 2 tender CORPORATION MATERIAL SAFETY DATA SHEET SAFETY DATA SHEET Prepared according to 29CFR 1910 1200 Regulation EC No 1272 2008 GHS and Canadian Controlled Products Act CPR SECTION 11 TOXICOLOGICAL INFORMATION The preparation has not been tested for all toxicological effects some are classified on the basis of the known hazards of the components Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Irritant effect on skin Irritant effect on eyes Sensitization Mutagenicity LD50 Greater than 2000 mg kg female rat Method OPPTS 870 1100 OECD 425 Source Product Tested 2005 LC50 Not determined Method Source LD50 Not determined Method Source Moderately irritating slightly irritating at 72hrs PDII 3 4 Method OPPTS 870 2500 OECD 404 Source Product Tested 2005 Severely irritating irritation cleared by 17 days MMTS 34 7 Method OPPTS 870 2400 OECD 405 Source Product Tested 2005 No ingredient has been identi
7. hting water must be disposed of in accordance with local regulations SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS For Large Spills Isolate the hazard area Keep out unnecessary and unprotected personnel Increase ventilation to area or move leaking container to a well ventilated and secure area Use the Personal Protective Equipment recommended in Section 8 of this MSDS Review Section 7 Handling of this MSDS before proceeding with cleanup ENVIRONMENTAL PRECAUTIONS Do not allow into any sewer on to ground or into any waterway METHOD FOR CONTAINMENT AND CLEAN UP Prevent product from entering drains and ventilation systems Contain and soak up spill with absorbent that does not react with spilled product Place used absorbent into suitable covered labeled containers for disposal Large Spills Dike spill product to prevent runoff Recover contaminated water for appropriate disposal Report spills to local health safety and environmental authorities as required Date Printed 31 October 2013 Product Code 0001 1113 Page 2 of 6 ate s gt lender CORPORATION MATERIAL SAFETY DATA SHEET SAFETY DATA SHEET Prepared according to 29CFR 1910 1200 Regulation EC No 1272 2008 GHS and Canadian Controlled Products Act CPR SECTION 7 HANDLING AND STORAGE HANDLING directions Do not contaminate food or feed STORAGE place away from heat or direct sunlight Protect from freezing SECTION 8 EXPOSU
8. respiration if indicated Contact a physician if warranted Take off contaminated clothing Immediately wash gently and thoroughly with luke warm gently flowing water and non abrasive soap for 15 20 mins If skin irritation or rash occurs see a doctor Thoroughly clean clothing before reuse or dispose of safely CONTACT WITH SKIN Immediately flush the contaminated eye s with lukewarm gently flowing water for 15 20 minutes while holding the eyelid s open Remove contact lenses if present and easy to do Take care not to rinse contaminated water into the unaffected eye or onto the face If irritation or pain persists see a doctor CONTACT WITH EYES Have victim rinse mouth with water NEVER give anything by mouth if the victim is rapidly losing consciousness or is unconscious or convulsing DO NOT INDUCE VOMITING Contact a physician if warranted INGESTION SECTION 5 FIRE FIGHTING MEASURES FIRE AND EXPOLSIVE PROPERTIES Non Flammable This product is not flammable combustible or explosive Flash Point Not applicable Flammable Limits Not applicable EXTINGUISHING MEDIA Water spray Carbon dioxide Dry Chemical or foam In case of fire hazardous combustion gases may be formed Carbon monoxide CO Carbon Dioxide CO2 Nitrogen oxides NOx SPECIFIC HAZARDS PROTECT EUIPMENT FOR FIREFIGHTERS Use self contained breathing apparatus and full protective clothing FURTHER INFORMATION Fire residues and contaminated firefig
9. t 2 Tender CORPORATION MATERIAL SAFETY DATA SHEET SAFETY DATA SHEET Prepared according to 29CFR 1910 1200 Regulation EC No 1272 2008 GHS and Canadian Controlled Products Act CPR SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME After Sting Gel After Bite Xtra After Bite Gel HMIS Hazard Rating After Bite Outdoor After Bite Chigger Ant HEALTH 2 Product Code 0001 1113 FLAMMABILITY 0 MSDS Date April 23 2012 REACTIVITY 0 MSDS Revision No 4 PERSONAL PROTECTION X USE Insect bite treatment MANUFACTURER Tender Corporation ADDRESS 106 Burndy Road Littleton NH 03561 INFORMATION CALLS 800 258 4696 E Mail customersrevice tendercorp com FAX PHONE 603 444 6735 EMERGENCY PHONE Spills 800 354 2382 Veolia Medical Information 800 258 4696 Tender Corporation SECTION 2 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Opaque non flammable water soluble gel with a strong ammonia odor HAZARD CLASSIFICATION Warning GHS Label elements including precautionary statements Pictogram Signal word WARNING Hazard statement s H302 Harmtul if swallowed H319 Causes serious eye irritation H315 Causes skin irritation H412 Harmful to aquatic organisms and may cause long term adverse effects in the aquatic environment Precautionary statement s P102 Keep out of the reach of children P234 Keep in original container P305 P351 P338 IF IN EYES Rinse cautiously with water for several minu
10. tes Remove contact lenses if present and easy to do Continue rinsing P301 330 331 315 IF SWALOWED Rinse mouth DO NOT induce vomiting Get immediate medical advice attention P273 Avoid release to the environment ROUTES OF EXPOSURE Dermal oral POTENTIAL HEALTH EFFECTS INHALATION May cause irritation to lungs SKIN CONTACT Do not use over cuts wounds or irritated skin Pre existing skin disorders may be aggravated by exposure EYE CONTACT Prolonged contact may cause irritation with redness pain tearing blurred vision and conjunctivitis INGESTION May be harmful if swallowed Product Code 0001 1113 Page 1 of 6 Date Printed 31 October 2013 t 2 Tender CORPORATION MATERIAL SAFETY DATA SHEET SAFETY DATA SHEET Prepared according to 29CFR 1910 1200 Regulation EC No 1272 2008 GHS and Canadian Controlled Products Act CPR SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS Ingredient Conc CAS NO EINECS NO Classification Ammonia 3 5 7664 41 7 231 635 3 EU X WHMIS Class E Water 84 0 to 88 0 7732 18 5 231 791 2 None Sodium Bicarbonate 1 0 to 3 0 144 55 8 205 633 8 None Carbomer Polyacrylic acid 1 0 to 2 5 9003 01 4 N A None Melaleuca alternifolia 0 3 to 0 5 85085 48 9 285 377 1 EU Xn See Section 8 EXPOSURE CONTROLS PERSONAL PROTECTION for exposure guidelines SECTION 4 FIRST AID MEASURES INHALATION Move victim to fresh air Apply artificial
11. to be toxic to aquatic organisms 10mg lt LC50 lt 100 mg l Page 4 of 6 Date Printed 31 October t 2 Tender CORPORATION MATERIAL SAFETY DATA SHEET SECTION 13 DISPOSAL CONSIDERATIONS SAFETY DATA SHEET Prepared according to 29CFR 1910 1200 Regulation EC No 1272 2008 GHS and Canadian Controlled Products Act CPR WASTE DISPOSAL METHOD Do not reuse any empty containers US This product is not a hazardous solid waste as defined in Resource Conservation Recovery Act Regulations 40 CFR 261 and should be disposed of according to local state and Federal regulations Dispose of partially filled and empty containers by wrapping and discarding in trash International This product should not be disposed of via the drains or by landfill Disposal must be in accordance with current national and local regulations Chemical residues generally count as special waste and their disposal may be regulated in the EC member countries through corresponding laws and regulations We recommend that you contact either the authorities or approved waste disposal companies who will advise you on how to dispose of special waste Packaging may contain residues of the product and should be treated accordingly General EU requirements are given in the Waste Framework Directive 75 442 EEC and the Hazardous Waste Directive 91 689 EEC SECTION 14 TRANSPORT INFORMATION SHIPPING INFORMATION Marine Pollutant No
Download Pdf Manuals
Related Search