Lexmark 1382620
Contents
1. Personal Protection Engineering Controls None required Use in a well ventilated area Respiratory Protection None required for intended use in printer Gloves None required for intended use in printer 1382620 Revision Date 09 12 2003 Page 2 of 4 Skin Protection Eyes None required for intended use in printer None required for intended use in printer Section 9 Physical and Chemical Properties Physical State Solid powder Freezing Point Range C Not applicable Color Black Melting Point Not determined Odor Faint plastic like odor Vapor Density Air 1 Not applicable Specific Gravity Not determined Volatility Not determined Solubility in Water Insoluble Evaporation Rate Not applicable Section 10 Stability and Reactivity Chemical Stability Hazardous Polymerization Conditions to Avoid Materials to Avoid Hazardous Decomposition Products Additional Guidelines Stable Will not occur High temperatures and flame Strong oxidizers Carbon dioxide carbon monoxide and unidentified organics None Section 11 Toxicological Information Primary Routes of Exposure Ingestion Acute Toxicity Oral Rat LD50 mg kg Inhalation Aggravated Conditions Carcinogenicity Comment Inhalation of dust skin contact Low acute oral toxicity Exposure not probable with intended use gt 5000 Low acute inhalation toxicity As with exposure to high concentrations of any2. M ial Safety D Sh LEXMARK aterial Sa m i a Optra S Print Cartridge Lexmark has determined that Material Safety Data Sheets are not required for print cartridges For customer convenience Lexmark provides product information in this familiar format Section 1 Product and Company Identification Product Name Opira S Print Cartridge Manufacturer Lexmark International Inc Product ID 1382620 740 West New Circle Road Chemical Toner Cartridge Lexington KY 40550 Family Application Laser Printer Information 1 859 232 3000 Prepared By Product Environmental Programs Emergency 1 859 232 3333 Section 2 Composition Information on Ingredients Ingredients Percent wt CAS No OSHA PELS ACGIH TLV Styrene Acrylate Copolymer 85 95 25767 47 9 None None Carbon Black 3 8 1333 86 4 3 5 mg m TWA 3 5 mg m TWA Amorphous Silica modified 1 5 Trade Secret None None NJTSRN 80100451 5015 Particle Control Agent 1 5 Trade Secret 15 mg m TWA total 10 mg m TWA NJTSRN 80100451 5000 dust 5 mg m TWA respirable fraction Charge Control Agent 1 5 Trade Secret None None NJTSRN 80100451 5002 Section 3 Hazards Identification The following information is based on testing of the product as a whole and or characteristics of components Hazard Information Primary Routes of Exposure Dust inhalation skin contact Inhalation Low acute inhalation toxicity As with exposure to high concentrations of any dust minimal irritatio
3. dust minimal irritation of the respiratory tract may occur Pure carbon black a minor component of this product has been listed by IARC as a group 2B possible carcinogen This classification is based on rat lung particulate overload studies performed with airborne particulate carbon black Toner is not listed by IARC NTP or OSHA Exposure to high airborne dust concentrations including toner may aggravate existing respiratory conditions Neither this product nor any of its components present above 0 1 are listed by IARC NTP or OSHA as known carcinogens Section 12 Ecological Information Mobility Persistence Bioaccumulative Other Information Not determined Not determined Not determined None 1382620 Revision Date 09 12 2003 Page 3 of 4 Section 13 Disposal Considerations Waste Disposal This product is not a listed hazardous waste in accordance with Federal Regulation 40 CFR Part 261 If discarded in its purchased form this product would not be a hazardous waste either by listing or by characteristic However under RCRA it is the responsibility of the product user to determine at the time of disposal whether a material has been contaminated and should be classified as a hazardous waste Disposal is subject to local state and federal regulations Section 14 Transport Information DOT Status Not classified as a hazardous material or substance under US DOT DOT Shipping Name Not applicab
4. le DOT Reportable Quantity Not applicable Hazard Class Not applicable DOT Packing Group Not applicable Section 15 Regulatory Information TSCA USA All ingredients are listed on the Toxic Substances Control Act TSCA inventory have been registered or are exempt SARA EPCRA USA None of the ingredients in this product has a final reportable quantity RQ under Emergency Planning and Community Right to Know Act EPCRA Section 302 Extremely Hazardous Substances EHS or notification requirements for EHS under Section 304 EPCRA Section 313 Supplier Notification This product contains lt 5 percent of a zinc compound California Proposition 65 This product contains no known materials at levels which the State of California has found to cause cancer birth defects or other reproductive harm California Proposition 65 DSL Canada All ingredients are listed on the Canadian Domestic Substances List DSL have been registered on the Non Domestic Substances List NDSL or are exempt EINECS Europe All ingredients are listed on the European Inventory of Existing Commercial Substances EINECS list have been registered on the European List of New Chemical Substances ELINCS or are exempt ECL Korea All ingredients are listed on the Korean Existing Chemicals List ECL have been registered or are exempt WHMIS Hazard Class Canada Not a WHMIS controlled product Section 16 Other Information The follo
5. n of the respiratory tract may occur Exposure not probable with intended use Skin Contact Not an irritant Low dermal toxicity Not a dermal sensitizer Eye Contact Toner may act as a mechanical irritant Ingestion Low acute oral toxicity Exposure not probable with intended use Section 4 First Aid Measures Inhalation If symptoms such as shortness of breath or persistent coughing are experienced remove source of contamination and move individual to fresh air If symptoms persist seek medical attention Skin Contact Wash with soap and water Should irritation occur seek medical attention 1382620 Revision Date 09 12 2003 Page 1 of 4 Eye Contact Do not rub eyes Flush immediately with plenty of water Remove contact lenses and continue flushing for at least 15 minutes If irritation develops and persists seek medical attention Ingestion Do not induce vomiting Slowly dilute with 1 2 glasses of water or milk and seek medical attention Never give anything by mouth to an unconscious person Aggravated Conditions Exposure to high airborne dust concentrations including toner may aggravate existing respiratory conditions Notes to Physician No specific antidote Section 5 Fire Fighting Measures Flash Point Range C Solid not applicable Autoignition Temperature C Not applicable Flammable Limits in Air UEL Not determined Flammable Limits in Air LEL Not determined Extinguishing Media Carbon di
6. oxide water spray or fog dry chemical or foam Hazardous Combustion Products Carbon monoxide carbon dioxide unidentified organics Special Exposure Hazards Like many finely divided materials toner dust in high concentrations can form an explosive mixture in air which if ignited could result in a dust explosion Special Protective Equipment Fire fighters should wear full protective clothing including self contained breathing apparatus if a large number of cartridges are involved NFPA Rating Health 1 Flammability 1 Reactivity 0 HMIS Classification Health 1 Flammability 1 Reactivity 0 Section 6 Accidental Release Measures Personal Precautionary None required for intended use in printer Measures Environmental Precautionary Disposal is subject to national state regional or provincial regulations Procedure for Cleaning If a dust cloud is possible due to a spill remove all sources of ignition such as Absorption open sparks flames or static discharge to prevent the ignition of the dust Minimize dust generation during clean up Sweep up spill with non metallic broom and dustpan Contain for disposal Oil permeated sweeping compound may be useful in cleaning up spills Section 7 Handling and Storage Handling To avoid damage to cartridge and accidental contact with toner KEEP OUT OF REACH OF CHILDREN Storage Store in a cool dry place Store away from oxidizing material Section 8 Exposure Controls
7. wing has been revised since the last issue of this MSDS No significant revisions to health and safety information Additional Information None Data are most current known to Lexmark at the time of preparation and are believed to be accurate No warranty as to their accuracy or completeness is expressed or implied END OF MSDS 1382620 Revision Date 09 12 2003 Page 4 of 4
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