Pentosin® Pentofrost A1 Antifreeze Material Safety
Contents
1. Chemicals known to cause developmental toxicity None of the ingredients is listed Carcinogenic Categories EPA Environmental Protection Agency None of the ingredients is listed IARC International Agency for Research on Cancer None of the ingredients is listed TLV Threshold Limit Value established by ACGIH 107 21 1 ethanediol NIOSH Ca National Institute for Occupational Safety and Health None of the ingredients is listed OSHA Ca Occupational Safety amp Health Administration None of the ingredients is listed Canada Canadian Domestic Substances List DSL All ingredients are listed Canadian Ingredient Disclosure list limit 0 1 None of the ingredients is listed Canadian Ingredient Disclosure list limit 1 107 21 1 ethanediol 15 2 Chemical safety assessment A Chemical Safety Assessment has not been carried out 16 Other information This information is based on our present knowledge However this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship Relevant phrases H302 Harmful if swallowed PENTOSIN MOTOR OILS OIL amp FLUIDS2. Labelling according to Regulation EC No 1272 2008 The product is classified and labelled according to the CLP regulation Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 Hazard pictograms GHS07 Signal word Warning Hazard determining components of labelling ethanediol 2 2 oxybisethanol Hazard statements H302 Harmful if swallowed H319 Causes serious eye irritation Precautionary statements P101 If medical advice is needed have product container or label at hand P102 Keep out of reach of children P103 Read label before use P280 Wear protective gloves eye protection P264 Wash thoroughly after handling P305 P351 P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P362 Take off contaminated clothing and wash before reuse P337 P313 If eye irritation persists Get medical advice attention P302 P352 IF ON SKIN Wash with plenty of soap and water Hazard description WHMIS symbols D2B Toxic material causing other toxic effects NFPA ratings scale 0 4 Health 2 Fire 1 Reactivity 0 HMIS ratings scale 0 4 HEALTH Health 2 FIRE Fire 1 L Reactivity 0 HMIS Long Term Health Hazard Substances None of the ingredients is listed 2 3 Other hazards Results of PBT and vPvB assessment PBT Not applicable S
3. and effects both acute and delayed Cramp Thirst Headache Dizziness Nausea Disorientation Hazards No further relevant information available 4 3 Indication of any immediate medical attention and special treatment needed Contains ethylene glycol Consult literature for specific antidotes Monitor circulation possible shock treatment Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 Medical supervision for at least 48 hours 5 Firefighting measures 5 1 Extinguishing media Suitable extinguishing agents Use fire extinguishing methods suitable to surrounding conditions For safety reasons unsuitable extinguishing agents None 5 2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire 5 3 Advice for firefighters Protective equipment Wear self contained respiratory protective device Wear fully protective suit Additional information Cool endangered receptacles with water spray No further relevant information available 6 Accidental release measures 6 1 Personal precautions protective equipment and emergency procedures Wear protective equipment Keep unprotected persons away Ensure adequate ventilation 6 2 Environmental precautions Do not allow to enter sewers surface or ground water 6 3 Methods and material for containment and cleaning up Absorb w
4. Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS 1 Identification of the substance mixture and of the company undertaking 1 1 Product identifier Trade name Pentofrost A1 1 2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available Application of the substance the preparation Coolant Anti freeze Cer AUTOMOTIVE 2 Hazards identification 2 1 Classification of the substance or mixture Classification according to Regulation EC No 1272 2008 GHS07 Acute Tox 4 H302 Harmful if swallowed Eye Irrit 2 H319 Causes serious eye irritation Classification according to Directive 67 548 EEC or Directive 1999 45 EC Xn Harmful R22 Harmful if swallowed x Xi Irritant R36 38 Irritating to eyes and skin Information concerning particular hazards for human and environment The product has to be labelled due to the calculation procedure of the General Classification guideline for preparations of the EU in the latest valid version Classification system The classification is according to the latest editions of the EU lists and extended by company and literature data The classification is in accordance with the latest editions of international substances lists and is supplemented by information from technical literature and by information provided by the company 2 2 Label elements
5. Water if necessary together with cleansing agents 14 Transport information 14 1 UN Number DOT ADR ADN IMDG IATA 14 2 UN proper shipping name DOT ADR ADN IMDG IATA 14 3 Transport hazard class es DOT ADR ADN IMDG IATA Class 14 4 Packing group DOT ADR IMDG IATA 14 5 Environmental hazards Marine pollutant No 14 6 Special precautions for user Not applicable 14 7 Transport in bulk according to Annex II of MARPOL73 78 and the IBC Code Not applicable UN Model Regulation 15 Regulatory information 15 1 Safety health and environmental regulations legislation specific for the substance or mixture United States USA SARA Section 355 extremely hazardous substances None of the ingredients is listed Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 Section 313 Specific toxic chemical listings 107 21 1 ethanediol TSCA Toxic Substances Control Act All ingredients are listed Proposition 65 California Chemicals known to cause cancer None of the ingredients is listed Chemicals known to cause reproductive toxicity for females None of the ingredients is listed Chemicals known to cause reproductive toxicity for males None of the ingredients is listed
6. afety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 vPvB Not applicable 3 Composition information on ingredients 3 2 Mixtures Description Mixture of substances listed below with nonhazardous additions Dangerous components CAS 107 21 1 ethanediol 50 100 EINECS 203 473 3 Index number 603 027 00 1 lt Acute Tox 4 H302 CAS 111 46 6 2 2 oxybisethanol lt 10 EINECS 203 872 2 Index number 603 140 00 6 CAS 1310 73 2 sodium hydroxide lt 0 5 EINECS 215 185 5 Index number 011 002 00 6 lt gt Skin Corr 1A H314 Additional information For the wording of the listed risk phrases refer to section 16 4 First aid measures 4 1 Description of first aid measures General information Symptoms of poisoning may even occur after several hours therefore medical observation for at least 48 hours after the accident After inhalation Supply fresh air consult doctor in case of complaints After skin contact Immediately wash with water and soap and rinse thoroughly If skin irritation continues consult a doctor After eye contact Remove contact lenses if worn Rinse opened eye for several minutes under running water If symptoms persist consult a doctor After swallowing Rinse out mouth and then drink plenty of water Do not induce vomiting call for medical help immediately 4 2 Most important symptoms
7. al Does not accumulate in organisms 12 4 Mobility in soil No further relevant information available Additional ecological information General notes This statement was deduced from products with a similar structure or composition Avoid transfer into the environment Due to available data on eliminability decomposition and bioaccumulation potential a prolonged damage of the environment is unlikely Water hazard class 1 German Regulation Self assessment slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water water course or sewage system 12 5 Results of PBT and vPvB assessment PBT Not applicable vPvB Not applicable 12 6 Other adverse effects No further relevant information available Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 13 Disposal considerations 13 1 Waste treatment methods Recommendation Must not be disposed together with household garbage Do not allow product to reach sewage system Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations Can be reused after reprocessing Contact waste processors for recycling information Uncleaned packaging Recommendation Disposal must be made according to official regulations Recommended cleansing agents
8. d and stored according to specifications 10 3 Possibility of hazardous reactions No dangerous reactions known 10 4 Conditions to avoid No further relevant information available 10 5 Incompatible materials No further relevant information available Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 11 Toxicological information 11 1 Information on toxicological effects Acute toxicity LD LC50 values relevant for classification 107 21 1 ethanediol Oral LD50 5840 mg kg rat Dermal LD50 9530 mg kg rabbit Primary irritant effect on the skin Slight irritant effect on skin and mucous membranes on the eye Irritating effect Sensitization No sensitizing effects known Subacute to chronic toxicity Vapours have narcotic effect Additional toxicological information The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version Harmful Irritant Toxic and or corrosive effects may be delayed up to 24 hours Repeated dose toxicity May cause damage to organs through prolonged or repeated exposure 12 Ecological information 12 1 Toxicity Aquatic toxicity No further relevant information available 12 2 Persistence and degradability Moderately partly biodegradable 12 3 Bioaccumulative potenti
9. diol IOELV EU Short term value 104 mg m 40 ppm Long term value 52 mg m 20 ppm Skin TLV USA Short term value C 100 mg m H EL Canada Short term value C 100 20 mg m C 50 ppm Long term value 10 mg m Aerosol Particulate Vapour 111 46 6 2 2 oxybisethanol WEEL USA Long term value 10 mg m8 1310 73 2 sodium hydroxide PEL USA Long term value 2 mg m REL USA Short term value C 2 mg m TLV USA Short term value C 2 mg m EL Canada Short term value C 2 mg m DNELs No further relevant information available PNECs No further relevant information available Additional information The lists valid during the making were used as basis 8 2 Exposure controls Personal protective equipment General protective and hygienic measures The usual precautionary measures are to be adhered to when handling chemicals Keep away from foodstuffs beverages and feed Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work Avoid contact with the eyes and skin Respiratory protection Not required under normal conditions of use Use suitable respiratory protective device when aerosol or mist is formed For spills respiratory protection may be advisable Protection of hands Protective gloves Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pento
10. frost A1 The glove material has to be impermeable and resistant to the product the substance the preparation Due to missing tests no recommendation to the glove material can be given for the product the preparation the chemical mixture Selection of the glove material on consideration of the penetration times rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material but also on further marks of quality and varies from manufacturer to manufacturer As the product is a preparation of several substances the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed For the permanent contact gloves made of the following materials are suitable Butyl rubber BR Neoprene gloves Nitrile rubber NBR Eye protection Safety glasses Body protection Not required under normal conditions of use Protection may be required for spills Limitation and supervision of exposure into the environment No further relevant information available Risk management measures See Section 7 for additional information No further relevant information available 9 Physical and chemical properties 9 1 Information on basic physical and chemical
11. ith liquid binding material sand diatomite acid binders universal binders sawdust Send for recovery or disposal in suitable receptacles Dispose contaminated material as waste according to item 13 6 4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment See Section 13 for disposal information 7 Handling and storage 7 1 Precautions for safe handling Ensure good ventilation exhaustion at the workplace Prevent formation of aerosols Information about fire and explosion protection No special measures required 7 2 Conditions for safe storage including any incompatibilities Storage Requirements to be met by storerooms and receptacles No special requirements Information about storage in one common storage facility Store away from foodstuffs Store away from oxidizing agents Further information about storage conditions Store in cool dry conditions in well sealed receptacles Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 7 3 Specific end use s No further relevant information available 8 Exposure controls personal protection Additional information about design of technical facilities No further data see item 7 8 1 Control parameters Ingredients with limit values that require monitoring at the workplace 107 21 1 ethane
12. properties General Information Appearance Form Liquid Colour Red Odour Light Odour threshold Not determined pH value at 20 C 7 9 50 solution Change in condition Melting point Melting range Undetermined Boiling point Boiling range 347 F 175 C Safety Data Sheet according to 1907 2006 EC REACH 1272 2008 EC CLP and GHS Trade name Pentofrost A1 Flash point 262 F 128 C Flammability solid gaseous Not applicable Ignition temperature gt 500 F gt 260 C Decomposition temperature Not determined Self igniting Product is not self igniting Danger of explosion Product does not present an explosion hazard Explosion limits Lower 3 2 Vol Upper 53 0 Vol Vapour pressure at 20 C 0 1 hPa Density at 20 C 1 13 g cm Relative density Not determined Vapour density Not determined Evaporation rate Not determined Solubility in Miscibility with water Fully miscible Partition coefficient n octanol water Not determined Viscosity Dynamic Not determined Kinematic Not determined Solvent content Organic solvents Not determined 9 2 Other information No further relevant information available 10 Stability and reactivity 10 1 Reactivity 10 2 Chemical stability Thermal decomposition conditions to be avoided No decomposition if use
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