NIR FlexIR - PIKE Technologies
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1. two passes through 1 00 mm gap Window Material Borosilicate glass Stainless steel borosilicate glass chemically resistant epoxy Materials in Contact with Liquid Viton O ring Call PIKE Technologies to inquire about perfluoroelastomer O ring Precautions In order to provide the maximum signal in the infrared with the minimum spectral interference the mirrors in this accessory are thin film coated Since the coatings are soft care must be taken to avoid damage Normally these mirrors will not need cleaning since they are contained within the housing of the accessory If they do need cleaning they may be gently swept with a camel hair brush Under no circumstances must the mirrors be rubbed with paper products such as Kleenex since this may scratch the mirror coating Options Part Number Description 045 2001 Liquids Sampling Tip 1 0 mm pathlength 045 2000 Liquids Sampling Tip 1 5 mm pathlength 045 2002 Liquids Sampling Tip 2 0 mm pathlength 045 2010 Diffuse Reflection Tip for FlexIR NIR Probe PN 350 0451000 00 Page 9 PIIKE TECHNOLOGIES Spectroscopic Creatit ity 6125 Cottonwood Drive Madison WI 53719 5120 608 274 2721 TEL 608 274 0103 FAX info piketech com www piketech com2. typically a service function and PIKE Technologies should be contacted before attempting to do this adjustment Fiber Optic Connections Jo mo amp a o E E d oa E E E SpE p ge Detector Gain Adjust Service Only Figure 2 Interior view of FlexIR Electronic Interface Module PN 350 0451000 00 Page 4 Performance Verification With the accessory installed and the appropriate aperture set insert the diffuse reflectance probe into the reference side of the probe stand to contact the diffuse gold reference Figure 3 Source intensities shape of the infrared beam and the beam splitter characteristics vary from bench to bench The single beam spectra may appear slightly different than shown in Figure 4 Using a 1 minute data collect time collect a background followed immediately by a sample spectrum The peak to peak noise around 6000 cm should be equal to or less than 150 Abs RMS Diffuse Gold Reference Position Figure 3 Probe stand with diffuse gold reference ad y tk y Fi 1 f 15 Z 70 65 je J 60 Fi e j i a A ra Lieven tari icv sonality 25 20 15 a M oe ae A Wavenumber cm 1 Arbitrary units Figure 4 Single beam energy of the FlexIR Red ratio of two consecutive 1 min spectra of gold reference Blue Noise level around 6000 cm should be less than 150 Abs RMS PN 350 0451000 00 Page 5 Solid Sampling Sampling with th
3. Installation and User Guide PICE TECHNOLOGIES Spectroscopic Creativity FlexIR NIR Fiber Optic Accessory The information in this publication is provided for reference only All information contained in this publication is believed to be correct and complete PIKE Technologies Inc shall not be liable for errors contained herein nor for incidental or consequential damages in connection with the furnishing performance or use of this material All product specifications as well as the information contained in this publication are subject to change without notice This publication may contain or reference information and products protected by copyrights or patents and does not convey any license under the patent rights of PIKE Technologies Inc nor the rights of others PIKE Technologies Inc does not assume any liability arising out of any infringements of patents or other rights of third parties This document contains confidential or proprietary information of PIKE Technologies Inc Neither this document nor the information herein is to be reproduced distributed used or disclosed either in whole or in part except as specifically authorized by PIKE Technologies Inc PIKE Technologies Inc makes no warranty of any kind with regard to this material including but not limited to the implied warranties of merchantability and fitness for a particular purpose Copyright 1991 2014 by PIKE Technologies Inc Madison WI 53719
4. Printed in the United States of America All world rights reserved No part of this publication may be stored in a retrieval system transmitted or reproduced in any way including but not limited to photocopy photograph magnetic or other record without the prior written permission of PIKE Technologies Inc Address Comments to PIKE Technologies Inc 6125 Cottonwood Drive Madison WI 53719 Phone 608 274 2721 Fax 608 274 0103 E mail info piketech com Web Site www piketech com Jan 1 2014 Contents Introduction Unpacking Your Accessory Packing List Installation Accessory Adjustment Performance Verification Solid Sampling Liquid Sampling Precautions Options NIN ITN S OUR 0 IN IN E Introduction FlexIR Near Infrared Fiber Optic accessory is a compact sample compartment mounted accessory for measuring the composition of a wide variety of solid and paste materials Using near infrared chemometrics qualitative product identification or quantitative analysis may be performed on pharmaceutical nutraceutical chemical polymer textile food agricultural or other samples The FlexIR accessory features a high throughput low OH fiber optic probe with a reflectance tip and a high speed low noise Indium Gallium Arsenide detector with optics and electronics interface The FlexIR fits in the sample compartment of the FTIR spectrometer and connects to the detector port of the spectrometer The window is bonde
5. d and sealed to protect the probe tip from corrosive materials and contamination PN 350 0451000 00 Page 1 Unpacking Your Accessory In order for you to quickly verify receipt of your accessory we have included a packing list Please inspect the package carefully Packing List User Manual FlexIR Optical and Electronic Fiber Optics and Cable PN 350 0451015 Interface Module Quantity 1 Quantity 1 PN 045 10XX Quantity 1 Probe Stand with Gold Reference Quantity 1 PN 350 0451000 00 Page 2 Installation Before installation make sure the spectrometer is working in the near infrared region without the FlexIR Please consult the manufacturer of the FT IR spectrometer regarding the conversion of the bench to near infrared This may involve replacing the beamsplitter and source to optimize for the 10 000 to 4000 cm wavelength region of the IntegratIR It is advisable to perform an alignment of the interferometer before inserting the IntegratIR into the sample compartment Each FlexIR unit is manufactured to interface with a specific model FTIR spectrometer Operation with a different model may require a factory conversion to be performed by PIKE Technologies Place the Interface Module in the sample compartment of the spectrometer The baseplate of the accessory assures the alignment of the accessory relative to the beam coming from the spectrometer Connect the detector cable to the spectrometer CAUTION Make sur
6. e FlexIR is as easy as placing the probe on the sample The probe is designed to be used with powders plastics and other solid materials that have a flat part to contact the window on the probe For solid samples reproducible sample positioning has to be assured The window at the tip of the probe is sealed using epoxy compound thus it is relatively chemically inert and can be cleaned preferably with alcohol or with acetone for samples which are more difficult to clean Samples for near infrared need to be presented to the spectrometer in an optically uniform and reproducible fashion to obtain the same spectrum every time Parameters that have significant effect on the samples are particle size and distribution crystallinity phase for example melted or solidified oils have very different spectra compression temperature especially water containing samples and other physical or chemical differences In all cases the accessory is measuring the reflected light thus transparent materials such as films produce very small signal In certain cases a reflective mirror can aid in returning the near infrared light to the collecting part of the fiber This double transmission called transflectance is a convenient way of measuring transparent or semi transparent samples that have a reproducible thickness or pathlength Figure 5 Sampling with the FlexIR through a thin plastic bag is possible due to the weak near infrared signature of polyethy
7. e power to the spectrometer bench is off before plugging in the detector cable Use the included cable to connect to the external port of the spectrometer and turn the spectrometer back on Attach the two SMA connectors of the Fiber Optic Probe to the Interface Module The FlexIR is ready for measurements SMA Connectors Fiber Optic Probe Optical and Electronic Interface Probe Stand Figure 1 FlexIR NIR assembly PN 350 0451000 00 Page 3 Accessory Adjustment The accessory has been aligned and tested to ensure that it performs to specifications No additional alignment is necessary The gain of the FlexIR is set to allow the best signal to noise Please check that the interferogram signal magnitude does not exceed the A D converter required signal magnitude This is done by placing the reflectance probe against the diffuse reference set into the bottom of the probe holder reference position Figure 3 The interferogram signal can be reduced by using the aperture selection on the spectrometer In the near infrared high resolution is rarely used thus the default aperture may be in the fully open position or any of the smaller apertures that do not significantly reduce the light level Should a gain adjustment be necessary which may be the case if switching between the diffuse probe tip and the liquid tip the housing of the accessory can be removed and the gain adjusted using the potentiometer on the electronic board This is
8. lene PN 350 0451000 00 Page 6 To collect a spectrum background position the probe in the diffuse gold reference slot on the probe holder shown in Figure 3 prior to collecting the sample spectrum Samples may be directly measured in a container using the probe The contact between the sample and the probe should be maintained during the sample spectrum collection Pressure on the sample should be maintained during the measurement and applied reproducibly to achieve repeatable results Glass or plastic containers can also be used for samples but the user must assure that the glass or plastic is uniform reproducible and as thin as possible to position the sample surface as close to the probe tip as possible Solids pastes and powders can be measured The near infrared region is not as sensitive to residual water vapor as the mid infrared If the resolution is higher the sharper water rotational vibrational bands still are exhibited Purging the sample compartment will also reduce this effect for increased spectral reproducibility in the water vapor regions Liquid Sampling The Liquid Probe Tip is transflection tip used with the FlexIR Near Infrared Fiber Optic Probe for liquid measurements The tip is secured by threading it onto the probe end after removal of the standard diffuse tip To install the liquids tip unscrew the diffuse tip first and transferring the O ring seal between the probe body and the liquid tip This O ring seal is importa
9. nt to assure that chemicals cannot migrate into the inside of the probe Prior to securing the liquids tip make sure the O ring is not damaged and that the tip is threaded on properly Finger tightening is enough to assure proper seal Tools are not necessary nor recommended to tighten the tip Liquid Gap O Ring Seal Use of Liquid Probe For measurements probe can be dipped in liquids Please do not submerge too close to the handle because there is no chemically resistant seal around the handle For background it is best to use pure PN 350 0451000 00 Page 7 solvent Otherwise the dry cell can reflect the light differently from when the gap is filled with liquid The small gap can be cleaned between samples with a stream of solvent alcohol acetone etc squirted in the gap from the front and dried with a cloth or absorbent paper Please note that water has higher surface tension and may not fill the gap just by dipping the probe due to the formation of an air bubble To eliminate an air bubble from the gab the probe can be held slanted with the front lip upward and the probe can also be swished in the liquid Absorbance Wavenumber cm 1 Figure 1 Near infrared transmission spectrum of biodiesel sample using the liquid tip PN 350 0451000 00 Page 8 Liquid Tip Specifications 1 0 mm two passes through 0 50 mm gap Nominal Liquid Pathlengths 1 5 mm two passes through 0 75 mm gap 2 0 mm
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