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1. 22980 Page 2 of 8 Issue date 18 Jul 2013 Handling Storage 7 Handling and Storage CAUTION Ensure adequate ventilation Contents under pressure CONTAINER MAY EXPLODE IF HEATED MAY IRRITATE EYES DO NOT get in eyes on skin or clothing Do not ingest DO NOT spray directly on food Prolonged or frequent skin contact may cause an allergic reaction DO NOT spray towards face Do not puncture or incinerate container DO NOT burn Store away from heat DO NOT expose to heat or store at temperatures above 120 F 49 C as the container may burst Keep out of reach of children Keep away from direct sunlight Keep at temperatures below 50 C 122 F Keep away from heat open flames or other sources of ignition NOTE TO PARENTS Intentional misuse by deliberately concentrating and inhaling aerosol products may be harmful or fatal Help stop inhalation abuse for information visit www inhalant org Use only as directed 8 Exposure Controls Personal Protection Exposure limits Ingredient s Ethanol Sodium Tetraborate Engineering controls Personal protective equipment Eye face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations Exposure Limits ACGIH TLV TWA 1000 ppm STEL 1000 ppm OSHA PEL TWA 1000 ppm ACGIH TLV TWA 2 mg m3 STEL 6 mg m3 OSHA PEL Not established General ventilation normally adequate Consult the product label for special pro
2. Freezing point Boiling point Pour point Evaporation rate Flash point Auto ignition temperature Flammability limits in air lower by volume Flammability limits in air upper by volume Vapor pressure Vapor density Specific gravity Octanol water coefficient Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Component analysis LC50 Ingredient s Ethanol Sodium Tetraborate Component analysis Oral LD50 Ingredient s Ethanol Sodium Tetraborate Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects 22980 Not available Not available gt 167 00 F gt 75 C Not available Not available gt 212 00 F gt 100 C Not available Not available Not available Not available Not available Not available Not available 10 Stability and Reactivity This product may react with oxidizing agents Hazardous polymerization does not occur Stable under recommended storage conditions Aerosol containers are unstable at temperatures above 49 C 120 2 F DO NOT MIX WITH BLEACH or use in conjunction with other household products Protect from sunlight and do not expose to temperatures exceeding 50 C 120 F Extremes of temperatures can occur in cars and near ovens and fireplaces Do not place in contact with hot surfaces or near naked flames Do not pie
3. 1 Air Freshener with 100 Natural Propellant Rain Garden 8 oz 0299218v2 0 AIR WICK 4 In 1 Air Freshener with 100 Natural Propellant Vanilla Indulgence 8 oz 180z 0299270v2 0 0384783v1 0 AIR WICK Air Freshener with 100 Natural Propellant Tropical Sunset National Parks 8 oz 0299268v2 0 AIR WICK Air Freshener with 100 Natural Propellant 18 oz 0384783v1 0 201 15 Aug 2012 Reckitt Benckiser Regulatory Department 800 333 3899 For an updated MSDS please contact the supplier manufacturer listed on the first page of the document Page 8 of 8 Issue date 201
4. Safety and Health Administration OSHA 29 CFR 1910 1200 hazardous chemical US Federal regulations Yes This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard 29 CFR 1910 1200 Product Registration Product is compliant with CPSC regulatory guidelines a specific registration is not required for this product CERCLA Superfund reportable quantity Sodium hydroxide 1000 0000 22980 Page6 of 8 Issue date 18 Jul 2013 Superfund Amendments and Reauthorization Act of 1986 SARA Hazard categories Section 302 extremely hazardous substance Section 311 hazardous chemical Clean Air Act CAA Clean Water Act CWA State regulations U S California 8 CCR Section 339 Director s List of Hazardous Substances Present refers to solutions gt 25 which are not beverage alcohols Present exempt except when present as free crystal powder listed under Borates Ethanol Sodium Tetraborate 64 17 5 1303 96 4 Immediate Hazard Yes Delayed Hazard No Fire Hazard No Pressure Hazard Yes Reactivity Hazard No No No Not available Not available This product to regulation tetra sodium salts U S Illinois Toxic Air Contaminants Sodium Tetraborate 1303 96 4 U S Massachusetts Right To Know List Ethanol Sodium Tetraborate U S Minnesota Hazardous Substance List Ethanol Sodium Tetraborate U S New Jersey Right to Know Hazardous Subst
5. Specific hazards arising from Contents under pressure Pressurized container may explode when exposed to heat or the chemical flame Cool containers with flooding quantities of water until well after fire is out Protective equipment for Firefighters should wear full protective clothing including self contained breathing firefighters apparatus Hazardous combustion products May include and are not limited to Oxides of carbon Explosion data Sensitivity to mechanical impact Not available Sensitivity to static discharge Not available 6 Accidental Release Measures Personal precautions Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill leak Environmental precautions Prevent further leakage or spillage if safe to do so Do not contaminate water Methods for containment Eliminate all ignition sources no smoking flares sparks or flames in immediate area Stop leak if you can do so without risk Prevent entry into waterways sewers basements or confined areas Methods for cleaning up Before attempting clean up refer to hazard data given above Remove sources of ignition Although the chance of a significant spill or leak is unlikely in aerosol containers in the event of such an occurrence absorb spilled material with a non flammable absorbent such as sand or vermiculite
6. 2 0 16 0 mL L static 96 Hr LC50 Pimephales promelas gt 100 mg L static 96 Hr LC50 Pimephales promelas 13400 15100 mg L flow through Ecotoxicity Water Flea Acute Toxicity Data Ethanol Persistence degradability Bioaccumulation accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Disposal instructions Waste from residues unused products Contaminated packaging 64 17 5 48 Hr LC50 Daphnia magna 9268 14221 mg L 24 Hr EC50 Daphnia magna 10800 mg L 48 Hr EC50 Daphnia magna 2 mg L Static Not available Not available Not available Not available Not available Not available Not available 13 Disposal Considerations Dispose in accordance with all applicable regulations Empty container can be disposed of as household trash or rinsed and recycled where appropriate Not available Not available 14 Transport Information U S Department of Transportation DOT 22980 UN 1950 Aerosols Non Flammable 2 2 Limited Quantity Page5 of 8 Issue date 1818 Jul 2013 Transportation of Dangerous Goods TDG Canada UN 1950 Aerosols Non Flammable 2 2 Limited Quantity IMDG Marine Transport Aerosols Non Flammable Class 2 2 UN 1950 Limited Quantity IATA ICAO Air UN1950 Aerosols non flammable 2 2 or ConsumerCommodity ID8000 if acceptable to airline 15 Regulatory Information Occupational
7. ER MAY EXPLODE IF HEATED MAY IRRITATE EYES DO NOT get in eyes on skin or clothing DO NOT ingest DO NOT spray directly on food Prolonged or frequent skin contact may cause an allergic reaction DO NOT spray towards face Do not puncture or incinerate container DO NOT burn Store away from heat DO NOT expose to heat or store at temperatures above 120 F 49 C as the container may burst KEEP OUT OF REACH OF CHILDREN Eye Skin contact Inhalation None expected during normal conditions of use May cause eye irritation upon direct contact with eyes None expected during normal conditions of use Prolonged or frequent skin contact may cause an allergic reaction None expected during normal conditions of use Health injuries are not known or expected under normal use Skin Eyes Prolonged or repeated exposure can cause drying defatting and dermatitis Symptoms may include redness edema drying defatting and cracking of the skin Symptoms of overexposure may be headache dizziness tiredness nausea and vomiting This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard 29 CFR 1910 1200 This product has not been tested Page 1 of 8 Issue date 18 Jul 2013 3 Composition Information on Ingredients Ingredient s CAS Percent Ethanol 64 17 5 2 5 10 Sodium Tetraborate 1303 96 4 0 1 1 4 First Aid Measures First aid procedures Eye contact If in eyes rinse eyes with water Remov
8. ance List Ethanol Sodium Tetraborate 1303 96 4 U S Pennsylvania RTK Right to Know List Ethanol Sodium Tetraborate U S Rhode Island Hazardous Substance List Ethanol Sodium Tetraborate Inventory status Couniry s or region United States amp Puerto Rico 64 17 5 Teratogen 1303 96 4 Present 64 17 5 Present 1303 96 4 Present 64 17 5 sn 0844 64 17 5 Present 1303 96 4 Present 64 17 5 Toxic Flammable 1303 96 4 Toxic Inventory name Toxic Substances Control Act TSCA Inventory Present listed under Sodium borate Sn 0241 listed under Sodium borates California On inventory yes no Yes A Yes indicates that all components of this product comply with the inventory requirements administered by the governing country s Disclaimer 22980 16 Other Information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge the information contained herein is accurate However neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein we cannot guarantee that these are the only hazards that exist Page7 of 8 Issue dat
9. e 201 Further information Issue date Effective date Prepared by Other information 22980 AIR WICK Air Freshener with 100 Natural Propellant Apple Cinnamon Medley 8 oz 180z 0340663v1 0 0384786v1 0 AIR WICK Air Freshener with 100 Natural Propellant Cool Linen amp White Lilac 8 oz 0299269v2 0 AIR WICK Air Freshener with 100 Natural Propellant Fresh Waters 8 02 18 oz 0299265v2 0 0384784v1 0 AIR WICK Air Freshener with 100 Natural Propellant Lavender amp Chamomile 8 02 18 oz 0299234v2 0 0384781v1 0 AIR WICK Air Freshener with 100 Natural Propellant Magnolia amp Cherry Blossom 8 oz 0299264v2 0 AIR WICK Air Freshener with 100 Natural Propellant Rain Garden 8 oz 0299218v2 0 AIR WICK Air Freshener with 100 Natural Propellant Vanilla Indulgence 8 oz 180z 0299270v2 0 0384783v1 0 AIR WICK 4 In 1 Air Freshener with 100 Natural Propellant Apple Cinnamon Medley 8 oz 180z 0340663v1 0 0384786v1 0 AIR WICK 4 In 1 Air Freshener with 100 Natural Propellant Cool Linen amp White Lilac 8 oz 0299269v2 0 AIR WICK 4 In 1 Air Freshener with 100 Natural Propellant Fresh Waters 8 0z 18 oz 0299265v2 0 0384784v1 0 AIR WICK 4 In 1 Air Freshener with 100 Natural Propellant Lavender amp Chamomile 8 02 18 oz 0299234v2 0 0384781v1 0 AIR WICK 4 In 1 Air Freshener with 100 Natural Propellant Magnolia amp Cherry Blossom 8 oz 0299264v2 0 AIR WICK 4 In
10. e any contact lenses and continue to rinse eyes for at least 15 minutes If irritation occurs get medical attention Skin contact If on skin wash area with soap and water If irritation occurs get medical attention Discontinue use IMMEDIATELY and get medical attention if a reaction develops Wash hands after handling Inhalation Move to fresh air Ingestion If swallowed call a Poison Control Center or doctor immediately DO NOT induce vomiting Wash out mouth with water Notes to physician Treat patient symptomatically General advice Do not puncture or incinerate container Keep away from sources of ignition No smoking If you feel unwell seek medical advice show the label where possible Ensure that medical personnel are aware of the material s involved and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children NOTE TO PARENTS Intentional misuse by deliberately concentrating and inhaling aerosol products may be harmful or fatal Help stop inhalation abuse for information visit www inhalant org Use only as directed 5 Fire Fighting Measures Flammable properties Aerosol flame extension less than 18 inches 45 cm NFPA AEROSOL LEVEL Flammability Rating 1 per NFPA 30B Extinguishing media Suitable extinguishing media Treat for surrounding material Unsuitable extinguishing media Not available Protection of firefighters
11. hd J Reckitt Benckiser MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name CAS Product Use Distributed by LEGEND HMIS NFPA Severe Serious Moderate Slight Minimal Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Potential environmental effects 22980 AIR WICK Air Freshener with 100 Natural Propellant Aerosols All Scents Mixture This MSDS is designed for workplace employees emergency personnel and for other conditions and situations where there is a greater potential for large scale or prolonged exposure in accordance with requirements of the U S Government s Occupational Safety and Health Administration OSHA This MSDS is not applicable for consumer use of our products For consumer use all precautionary and first aid language is provided on the product label in accordance with the applicable government regulation Air freshener Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway P O Box 225 Parsippany NJ 07054 0225 In Case of Emergency 1 800 338 6167 Transportation Emergencies 24 Hour Number North America CHEMTREC 1 800 424 9300 Outside North America 1 703 527 3887 KE Health Flammability Personal Protection 2 Hazards Identification CAUTION CONTENTS UNDER PRESSURE CONTAIN
12. rce or burn after use Do not spray on a naked flame onto or near a fire or any incandescent material such as an electric fire Oxidizers Acids Caustics May include and are not limited to Oxides of carbon 11 Toxicological Information LC50 31623 ppm rat Not available LD50 3450 mg kg mouse 7060 mg kg rat 2660 mg kg rat 5330 mg kg guinea pig None expected during normal conditions of use May cause eye irritation upon direct contact with eyes None expected during normal conditions of use Prolonged or frequent skin contact may cause an allergic reaction None expected during normal conditions of use Health injuries are not known or expected under normal use The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects Page 4 of 8 Issue date 18 Jul 2013 Carcinogenicity Mutagenicity Reproductive effects Teratogenicity The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Not available Products Ecotoxicity 12 Ecological Information This product has not been tested Ecotoxicity Freshwater Fish Acute Toxicity Data Ethanol 64 17 5 96 Hr LC50 Oncorhynchus mykiss 1
13. tection or precautions that have been identified for using this product under directed consumer use conditions The following recommendations are given for workplace employees emergency personnel and for other conditions and situations where there is a greater potential for large scale or prolonged exposure Not required under normal use conditions Safety glasses with side shields or full eye amp face protection should be worn if risk assessment indicates this is necessary for the workplace or emergency responders Not required under normal use conditions Chemical resistant impervious gloves should be worn if risk assessment indicates this is necessary for the workplace or emergency responders Usual safety precautions while handling the product will provide adequate protection against injury or irritation Not normally required under normal use conditions Where exposure guideline levels may be exceeded use an approved NIOSH respirator Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact Avoid contact with eyes skin and clothing 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state 22980 Aerosol Colorless Misty spray Characteristic Not available Gas Page3 of 8 Issue date 18 Jul 2013 pH

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