Manuel utilisation chimie_ Version 4 ENG
Contents
1. Y E L pes n 4 SYNCHROTRON _ Updated on 9th October 2008 Chemistry Laboratory Users Manual Users Laboratory Chemistry Laboratory Users Manual n 1 1 Summary 1 SIME 2 ZEB um EL S 3 3 Presenting the LaDoratoty o oir tr cte ihe ee re D De iv ERE ee e SEXE eda EUER eer vragen e DV ER CR EN HUY 4 3 1 To Wwhomdoes MIS AY ossa pnta eri E Nd NO D ena EEEE apamsanousanabencbsanincsnesavinuuteaeatanactabs 4 3 2 BNL VCS MP 4 zx MS ou eu S a 4 4 Salety TUleS coconut ud enu A E 6 4 1 General 1 RUE CONS ces bc as chat ED DT EET 6 LEE GIO Rari c ss stnce cate asda wsicasecsny dona pvacusensccucannslcded EEE E EEE EE E EEEE 7 4 2 General remarks ee eo Cee rae eer eee Sep TQ 7 4 2 2 Acids bases and solvents sionn E R E NA TA EEE 7 4 2 3 CMR CARCINOGENIC MUTAGENIC REPROTOXIC products eee 7 4 3 Measures to take in case of incidents i iccss icccnscidadaceaecdivovaeenneatessyaey sartencisavvanceayoonsavoanssusdesiveasaeasgonevebedebundeses 8 4 3 1 In ease of an accident to th pers n ssiciiessiisoinsror oiiire sisis eane TR OM Oed UR 8 4 3 2 MCAS of a fire alarm ccrosusisiinoesicisiiiiciseenn isi a EEEE EES Ea 8 4 3 3 In case of an environmental incident ssessssesseeeesssesssessresrttstesssrsseetstessttsstesstesreesesssrssreeseesssessres 9 5 Experim2. and follow instructions concerning their use maintenance and safety Every day after handling all chemical samples the laboratory should be returned to its original state all chemicals and samples should be put away all work surfaces should be cleaned etc Work premises IT IS STRICTLY FORBIDDEN TO EAT DRINK OR SMOKE in the laboratory Do not place food in the laboratory refrigerator Do not wash dishes used for food in the laboratory sink Clean your work area before leaving Chemical storage areas are marked Chemical waste must be placed in the designated bins Chemistry Laboratory Users Manual n 1 6 4 2 Needles must be systematically thrown away in the special containers provided NEVER put the top back on a needle throw tops away in ordinary waste bin Chemical risks 4 2 1 General remarks All dangerous chemicals must be handled in the fume cupboard All caustic irritant and CMR carcinogenic mutagenic reprotoxic products must be handled inside the fume cupboard with gloves suitable for the product concerned and with the lab coat buttoned up for maximum protection Work carried out away from the fume cupboard can only involve substances without risk without hazard signs In this case it is still recommended that protective glasses be worn against splashes and a FFP3 mask to protect against dust particles When a new flask or bottle is opened for the first time mark with the date of opening All flasks a
3. ental follow up procedures ii cscccceceseeseneeccscesssatsoccesceeehenteosseesucaesecceesusenaueecencocindasecessanssdibenseecnosnaacccoeenees 9 5 1 E log or computerized log book of experiments sssssesseeressssessrrsessrestesresteseesrestentesesterseetessesreesreeeesrssees 9 32 MSIE E ON 9 6 nud c 10 6 1 Simplified glove compatibility table Leno oen dco ds iaidnedsdieekshanteaNeesteadavgonddtdeachvbasledaei Lp NND aee 10 62 Hazard G11 REL uUum 11 Chemistry Laboratory Users Manual n 1 2 2 Foreword The aim of this document compiled for laboratory users is to present all the preventative measures that must be applied when working in the chemistry laboratory It contains all the elements required to understand and take the necessary precautions when using the laboratory and has user autonomy as its objective The laboratory staff consists of Head of department St phanie Blanchandin Health and safety officer Tel 33 0 1 69 35 96 85 Fax 33 0 1 69 35 94 56 E mail stephanie blanchandin G synchrotron soleil fr Assistant Engineer Karine Chaouchi Tel 33 0 1 69 35 97 40 Fax 33 0 1 69 35 94 56 E mail karine chaouchi synchrotron soleil fr The Users Chemistry Laboratory is located in Synchrotron building O3 0 02 Chemistry Laboratory Users Manual n 1 3 3 Presenting the Laboratory 3 1 To whom does this apply Th
4. horities by using the red telephones or by dialling 18 on a landline phone 4 3 3 In case of an environmental incident Spillage of a chemical In case of a chemical spill use the absorbent material available in the laboratory and limit access to the area of the spill 5 Experimental follow up procedures 5 E log or computerized log book of experiments All users of the laboratory are required to enter a minimum of information on the E Log still being installed even if there just to store away products 5 2 Data storage At present the laboratory is not in a position to store data We only have the computer hard disks that are wiped clean on a regular basis so it is preferable if each user takes responsibility for saving his her own data Chemistry Laboratory Users Manual n 1 9 6 Appendices 6 1 Simplified glove compatibility table Natural latex Nitrile Neoprene Solvents Ketones x n Caustic products Acids Hydrocarbons Oils Grease Organic solvents ra Excellent Good Moderate Not recommended Chemistry Laboratory Users Manual n 1 6 2 Hazard signs flammable F Corrosive C Explosive E Toxic T Chemistry Laboratory Users Manual n 1 Dangerous to the environment N Oxidizing agent O Irritant or Harmful Xi and Xn This symbol is for flammable products so these s
5. hould be used well away from flames or heat This symbol is for corrosive products that attack living tissues and materials This symbol is for products capable of exploding on impact or when exposed to a heat source This symbol is for products harmful to the environment so they should be salvaged after use for treatment e g organic solvents This symbol is for oxidizing agents they help combustion so must be used far from flames or heat source This symbol is for toxic products they can cause death in small doses and must be handled using the appropriate protection This symbol is for irritant or harmful products that can affect the health They must be handled with the appropriate protection 11 I the undersigned acknowledge having read the present document and confirm that I am aware of the rules and regulations on the running of the chemistry laborator y ies and shall follow the procedures described in the user s manual Signature Date Chemistry Laboratory Users Manual n 1 12
6. is applies to all laboratory users 3 2 Services The laboratory provides the infrastructure equipment and products normally found in a chemistry laboratory and its technical staff offer scientific support advice expertise and technical support feasibility setting up of experiments The following Individual Protection Equipment IPE is provided for use in the laboratory lab coats gloves glasses and masks During normal office hours external internal users are invited to contact laboratory staff for any requests chemicals small materials sample and or material storage etc and the local beamline contact for declared projects outside normal hours 3 3 Equipment Simplified Operating Methods for all equipment are available on the OM link A paper version is also available in the laboratory and the original manuals can be consulted on request Equipment present in the laboratory is listed in alphabetical order 1 Stirrers 17 Ventilated cabinet for solvents 2 Thermostated bath 18 Ventilated cabinet for acids bases 3 Balances 1 10 mg 19 pH meter 4 Basic glove box N2 gas system 20 Hot plate 5 Centrifuge 21 Vacuum pump 6 Conductimeter 22 Pellet equipment press 7 Ultrasonic washer 23 Fridge freezer 8 Desiccators 24 Fume cupboard 9 Turbidimeter 25 Sieve 10 Ultrapure water 26 Vacuum filtration device 11 Oven 27 Glassware 12 Glassware washer 28 Vortex mixer 13 Mixers 29 DSC in collaborati
7. labelled and identified as CMR with Toxic Harmful hazard signs Chemistry Laboratory Users Manual n 1 7 Handling e INHALING ANY PRODUCT IN POWDER FORM MUST BE AVOIDED AT ALL COSTS ESPECIALLY IF IT IS VERY DUSTY IT IS OBLIGATORY TO WEAR A SPECIALLY ADAPTED FPP3 MASK e The handling of this type of product is limited to people who have had formal training on the risks involved e Pregnant women are forbidden from handling these products or from access to the handling areas e In the case of a very dusty powder stop the fume cupboard extractor Do not weigh out the product but use the double weighing system the weight of the empty container is subtracted from the weight of the product in the container or use pre weighed products e tis preferable to use single use glassware and other utensils When this is not practicable it is possible to obtain material required for use just with these products The experimenter must then wash this equipment him herself which will have been labelled CMR with Toxic Harmful signs The first rinsing water of this equipment is disposed of as chemical waste Waste disposal e A special procedure is necessary for the disposal of these products Please ask a member of the chemical laboratory staff 4 3 Measures to take in case of incidents All incidents must be reported to the Safety Team 4 3 1 In case of an accident to the person In all cases e First contact one of the emerge
8. ncy staff listed on the walls of buildings next to the red telephones in the corridor e Otherwise use the red telephones or dial 18 on a landline phone The call will connect to the Safety PC in the control room where it will be treated For accidents involving mainly chemicals e If there are burns over a large area of the body rinse yourself under the safety shower e For chemical burns remove contaminated clothes and spray the area thoroughly with water until the arrival of emergency staff e For thermal type burns run cold water over the affected area preferably for at least 5 minutes e If the eyes are affected use the eye bath If contact lenses were being worn do not remove them e In all cases consult a doctor 4 3 2 In case of a fire alarm e When a fire alarm has been set off o Leave the premises after making the laboratory safe e g switch off the emergency electricity switch close hoods doors and windows o Leave by the nearest exit following the emergency evacuation plan displayed in the corridors and make your way to the nearest assembly point then wait for instructions from the safety officers or competent authorities firemen Chemistry Laboratory Users Manual n 1 8 o The Head of department is at the disposal of the emergency services for any further information If you witness the start of a fire first try to put out the fire with a fire extinguisher without taking any risks then alert the aut
9. nd bottles must be labelled Avoid moving these products around unnecessarily Clean the balance with the paintbrush and leave the bench clean 4 2 2 Acids bases and solvents Storage None of these products must be stored in the freezer The storage of these products is reduced to a minimum in relation to laboratory needs Products in use are placed in the fume cupboard and in the permanently ventilated chemicals cabinet After use in the fume cupboard they must be returned to their place in these cabinets Handling Always handle these products in the fume cupboard Never handle these products near a heat source Waste disposal Do not mix products when their interactions or incompatibility are unknown Follow the waste disposal procedure and separate each type of chemical waste Chemical waste must be thrown out in the respective ACID BASE or SOLVENT bins under or near the fume cupboard These containers must be closed Before closing the bins check for the absence of chemical reactions If an exothermic reaction starts or gas is given off place the open bin in the fume cupboard and pull down the glass protective screen 4 2 3 CMR CARCINOGENIC MUTAGENIC REPROTOXIC products Storage Only limited quantities must be ordered Flasks must be either double packaged or placed on a retention tray The storage area must be kept to the minimum There must be limited access to areas containing these products which should be
10. on with SAMBA 14 Micropipettes 30 Raman microscope 15 Binocular microscope 31 Raman spectrometer in collaboration with SAMBA 16 Mortars 32 UV Vis spectrometer in collaboration with SAMBA The following plan shows where the equipment is distributed in the laboratory as well as the product storage areas and the areas designated for sorting the different kinds of waste resulting from the experiments Chemistry Laboratory Users Manual n 1 4 aS EN yt I di Pos oO 7 NI N l l l l Plastic box needles 5 L plastic container solvent waste 5 L plastic container base waste 5 L plastic container acid waste O L E O 60 L plastic container glass waste 30 L plastic container contaminated waste gloves paper etc Chemistry Laboratory Users Manual n 1 5 4 Safety rules 4 1 Access General instructions Access to the laboratory is only permitted after authorization from a member of the laboratory staff A badge system with controlled access is in place The laboratory is open 24 hours on request for all users with green classified projects For yellow or red classified projects specific procedures will be set up on an individual basis Individual protection Lab coats must be worn in the laboratory Minimum safety protection o Gloves suitable for the product being used See Ap
11. pendix 6 1 For handling ketone type solvents latex gloves When using acids or bases in concentrated solutions or CMR products carcinogenic mutagenic or reprotoxic nitrile gloves When wearing gloves they must be removed before using the phone when going anywhere requiring the opening of doors and before using computer keyboards handling books or papers etc o Protective glasses against splashes when using liquid nitrogen or irritants toxic or carcinogenic products Special glasses for use with lasers o Wearing a type FFP3 mask when handling aerosols with liquid or toxic particles Masks with filter cartridges are available on request for use when handling gases and toxic vapours Those carrying out experiments must wash their hands before and after handling all chemicals Recommendations on how to handle materials It is forbidden to handle dangerous chemicals when alone in the laboratory Pipetting using the mouth is strictly forbidden Manual pipetting devices are provided Single use materials are preferable whenever possible All samples and chemical products must be labelled The label must contain the following information name of the product and date of preparation and how dangerous it is The name of the project and a contact name should also be included Except in specific cases all users must leave with all their samples securely packaged Please refer to user manuals for all equipment required for the experiment
Download Pdf Manuals
Related Search