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danger/peligro - poison restricted use pesticide

1. Other nonfood commodities SECTION 6 EXPOSURE CONDITIONS The QUICKPHLO R Phosphine Generator produces phosphine gas very rapidly from the QUICKPHLO R Granules Unlike metallic phosphides it is not dependent upon external condi tions like the temperature and humidity to generate phosphine Therefore QUICKPHLO R Phosphine Generator can be used under low humidity and or low temperature The minimum expo sure periods for phosphine gas is 2 to 5 days under favorable weather and other fumigation conditions Exposure periods may be lengthened to obtain better control of infestation even under conditions of poor sealing and penetration of gas throughout the commodity and lower temperatures The following table may be used as a guide in determining the minimum length of the expo sure period at the indicated temperatures Exposure Periods for Phosphine generated from QUICKPHLO R Temperature Phosphine Generator Below 40 F 5 C 6 to 15 days 40 53 F 6 12 C 4 to 10 days 54 59 F 12 15 C 3 to 5 days 60 68 F 16 20 C 2 to 4 days above 68 F 20 C 2 days The fumigation must be long enough so as to provide for ade quate control of the pests that infest the commodity being treat ed The proper length of the fumigation period will vary with exposure conditions since in general insects are more difficult to control at lower temperatures However with the rapid pro duction of
2. gas QUICKPHLO R Granules contain aluminum phosphide as the active ingredient and will liberate phosphine via the following chemical reaction AIP 3H O gt AI OH PH Phosphine gas is highly toxic to insects vertebrate pests humans and other forms of animal life The phosphine gas will corrode certain metals and may ignite spontaneously in air at concentrations above its lower flammable limit of 1 8 v v These hazards are described in greater detail in the Precautionary Statements section of this Manual QUICKPHLO R Granules are greenish yellow in color and are up to 1 4 mm in size QUICKPHLO R Granules are packed in sealed aluminum foil pouches containing 0 125 kg 0 275 lb 0 550 kg 1 21 Ib 2 200 kg 4 85 Ib or 4 400 kg 9 69 Ib of product Each aluminum foil pouch will generate upon contact with water 56 gm 250 gm 1 000 gm or 2 000 gm of phosphine respectively which equates to almost 1 gram of phosphine for each 2 2 gm of QUICKPHLO R Granules The aluminum foil pouches are packed in card board corrugated boxes and shipped in 3 5 ply corrugated fiberboard cartons The chart below shows the recommended number of pouches to generate the desired amount of phosphine Grams Phosphine to be generated 125g 56g 1 500 g 2 1 0 kg 1 25 kg 1 1 5 kg 2 2 0 kg 2 5 kg 2 3 0 kg 3 0 kg 3 5 kg 2 4 0 kg 5 0 kg 1 6 0 kg 7 0 kg 1 8 0 kg 9 0 kg 1 10 0 kg Example 2 2 1 For 5 62 kg phosphine Note Packa
3. other materials collect the spillage and place it back into the original pouch and tightly seal with aluminum tape If possible use immediately CAUTION AN IGNITION MAY OCCUR WHEN THESE CONTAINERS ARE REOPENED Since the QUICKPHLO R Granules are placed in small alu minum foil pouches a spill will be a small quantity of powder spilled from a punctured pouch Consequently spills are not like ly to constitute a frequent problem but the material must not be collected and stored as this might result in a dangerous build up of phosphine which is not only highly toxic but can also cause a fire and explosion Collect the spillage properly and deactivate it in the QUICKPHLO R Phosphine Generator or by using the Wet Method for Deactivation Remember to wear NIOSH MSHA approved or other suitable respiratory protection when handling spills and during deactivation NOTE Never place granules or the dust water slurry in a confined container such as a closed drum or plastic bags Any phosphine generated will be confined and may decompose explosively 23 4 DIRECTIONS FOR DEACTIVATION OF GRANULES BY WET METHOD Caution Wear a NIOSH MSHA approved full face gas mask phosphine canister combination if exposed to levels between 0 3 ppm and 15 ppm or a Self Contained Breathing Apparatus SCBA if exposure is unknown or above 15 ppm during wet deactivation of partially spent material Do not cover the contain er being used for wet deactivation Do
4. R dust and dispose of it with or without further deactivation Refer to Disposal Instructions in the Disposal Instructions section of this Manual 20 4 FUMIGATION OF RAILCARS CONTAINERS TRUCKS VANS OTHER TRANSPORT VEHICLES AND SMALL STORAGES Transport vehicles including railcars containers trucks vans and other small storages loaded with bulk commodities may be treated with phosphine gas generated using QUICKPHLO R Granules and the QUICKPHLO R Phosphine Generator 1 Establish a plan for application of phosphine gas depending upon the characteristics of the vehicle or small storage to be treated 2 Using the Applicator s Manual determine the length of the fumigation and calculate the dosage of granules to be used in the generator based upon volume of the vehicle or trailer 3 Inspect all sidewalls roof floor and doors for cracks holes or defects Seal all openings with tape or caulk Particular atten tion should be paid to any drain holes in the floor 4 Warning placards must be placed on every possible entrance to the fumigation site 5 Connect the distribution lines from the generator to the vehi cle or structure to be fumigated Inject and re circulate phos phine gas from QUICKPHLO R Phosphine Generator through the distribution ducts Following the introduction of phosphine gas from QUICKPHLO R Phosphine Generator the distribution lines should be capped or sealed Disconnect the QUICKPHLO R Phosphin
5. aerated structure SECTION 20 APPLICATION PROCEDURES An FMP must be devised to cover application and exposure period aeration and disposal of the fumigant so as to keep to a minimum any human exposures to phosphine and to help assure adequate control of the insect pests The follow ing instructions are intended to provide general guidelines for typical fumigation sites 20 1 FUMIGATION OF FLAT STORAGES BUNKERS AND OTHER TARPED STRUCTURES Establish a plan for application of phosphine gas depending upon the characteristics of the structure to be treated For example it is difficult to treat a flat storage containing grain at depths greater than 20 feet and having no aeration ducts or distribution ducts unless the storage is sealed very carefully If the structure has no distribution ducts the surface of the commodity must be carefully tarped and the remainder of the building sealed as tightly as possible Using the Applicator s Manual determine the length of the fumigation and calculate the dosage of granules to be used in the generator based upon volume of the building air and or commodity temperature and the general tightness of the structure Warning placards must be placed on every possible entrance to the fumigation site Connect the distribution lines from the generator to the struc ture to be fumigated Inject and re circulate phosphine gas from QUICKPHLO R Phosphine Generator through the distribution ducts De
6. authorities Where per missible this slurry may be poured into a storm sewer or out onto the ground FOR CHEMICAL EMERGENCY SPILL LEAK FIRE EXPOSURE OR ACCIDENT CALL CHEMTREC 1 800 424 9300 IMPORTANT INFORMATION READ BEFORE USING PRODUCT CONDITIONS OF SALE AND LIMITATION OF WARRANTY AND LIABILITY NOTICE Read the entire Directions for Use and Conditions of Sale and Limitation of Warranty and Liability before buy ing or using this product If the terms are not acceptable return the product at once unopened and the purchase price will be refunded The Directions for Use of this product should be followed care fully It is impossible to eliminate all risks inherently associated with the use of this product Crop injury ineffectiveness or other unintended consequences may result because of such factors as manner of use or application weather or crop conditions presence of other materials or other influencing factors in the use of the product which are beyond the control of United Phosphorus Inc or Seller All such risks shall be assumed by Buyer and User and Buyer and User agree to hold United Phosphorus Inc and Seller harmless for any claims relating to such factors United Phosphorus Inc warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated in the Directions for Use subject to the inherent risks referred to above when used in accordance with
7. determined that the design and configuration of the vessel does not allow for safe occupancy by the ship s crew through out the duration of the fumigation then the vessel will not be fumigated unless all crew members are removed from the ves sel The crew members will not be allowed to reoccupy the vessel until the vessel has been properly aerated and the mas ter of the vessel and the certified applicator has made a deter mination that the vessel is safe for occupancy 2 The certified applicator must notify the master of the vessel or his representative of the requirements relating to personal protection equipment detection equipment and that a per son qualified in the use of this equipment must accompany the vessel with cargo under fumigation Emergency procedures cargo ventilation periodic monitoring and inspections and first aid measures must be discussed with and understood by the master of the vessel or his representative Note Personal protection equipment means a NIOSH MSHA approved respirator or gas mask fitted with an approved can ister for phosphine The canister is approved for use up to 15 ppm SCBA or its equivalent must be used above 15 ppm or at unknown concentrations 3 Seal all openings to the cargo hold or tank and lock or other wise secure all openings man ways etc which might be used to enter the hold The over space pressure relief system of each tank aboard tankers must be sealed by closing the appropr
8. directions under normal use conditions This warranty does not extend to the use of this product contrary to label instructions or under abnormal conditions or under conditions not reasonably fore seeable to or beyond the control of Seller or United Phosphorus Inc and Buyer and User assume the risk of any such use UNITED PHOSPHORUS INC MAKES NEITHER WARRANTIES OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED WARRAN TY EXCEPT AS STATED ABOVE To the extent allowed by law United Phosphorus Inc or Seller be not liable for any incidental consequential or special dam ages resulting from the use or handling of this product THE EXCLUSIVE REMEDY OF THE USER OR BUYER AND THE EXCLUSIVE LIABILITY OF UNITED PHOSPHORUS INC AND SELLER FOR ANY AND ALL CLAIMS LOSSES INJURIES OR DAMAGES INCLUDING CLAIMS BASED ON BREACH OF WARRANTY CONTRACT NEGLIGENCE TORT STRICT LIA BILITY OR OTHERWISE RESULTING FROM THE USE OR HAN DLING OF THIS PRODUCT SHALL BE AT THE ELECTION OF UNITED PHOSPHORUS INC OR SELLER THE REPLACE MENT OF THE PRODUCT OR COMPENSATION LIMITED TO DAMAGES NOT EXCEEDING THE FAIR MARKET PURCHASE PRICE AND SHALL NOT INCLUDE INCIDENTAL OR CONSE QUENTIAL DAMAGES United Phosphorus Inc and Seller offer this product and Buyer and User accept it subject to the foregoing conditions of sale and limitations of warranty and of liability which may not be modified except by written agreeme
9. in accordance with the label requirements When entering into the area under fumigation always work with two or more people under the direct supervision of a cer tified applicator wearing appropriate respirators Apply fumigant from the outside where appropriate Provide watchmen when entry into the fumigation site by unauthorized persons cannot otherwise be assured When entering structures always follow OSHA rules for con fined spaces Document that the receiver of in transit vehicles containers under fumigation has been notified Turn off any electric lights in the fumigated area of the struc ture as well as all nonessential electrical motors G POST APPLICATION OPERATIONS ap oO 5 6 Provide watchmen when you cannot secure the fumigation site from entry by unauthorized persons during the aeration process Ventilate and aerate in accordance with structural limitations Turn on ventilating or aerating fans where appropriate Use a suitable gas detector before reentry into a fumigated structure to determine fumigant concentration Keep written records of monitoring to document completion of aeration Consider temperature when aerating Ensure aeration is complete before moving a treated vehicle onto public roads Remove warning placards when aeration is complete Inform business client that employees other persons may return to work or otherwise be allowed to reenter the
10. not dispose of QUICKPHLO R Granules dust in a toilet 19 If the contaminated material is not to be held until completely reacted by exposure to atmospheric moisture deactivate the granules by the Wet Method as follows 1 Deactivating solution is prepared by adding low sudsing detergent or surface active agent to water in a drum or other suitable container A 2 solution or 4 cups in 30 gallons is suggested The container should be filled with deactivating solution to within a few inches of the top 2 The granules should be poured slowly into the deactivating solution and stirred so as to thoroughly wet all of the granules This should be done in the open air Do not cover the contain er being used for wet deactivation Granules may react very vigorously with water and only a small amount of unexposed or partially exposed granules should be deactivated at one time Fresh additions may be added as soon as the vigorous reaction of the granules has subsided QUICKPHLO R Granules should be mixed into no less than about 15 gallons of water detergent solution for each case of material Allow the mixture to stand with occasional stirring for about 6 hours to ensure total hydrolysis Removal of the granules from water before they are largely deactivated may result in a fire The resultant slurry will then be safe for disposal Dispose of the slurry of deactivated material at a sanitary lanafill or other suitable site approved by local
11. oboe al i 15 D Notifica a a A wala A A AA we ee 15 E Sealing Procedures sici n ot ode Pid od A is fi 15 F Application Procedures and Fumigation Period ooooooooocoorrorr ee 15 G Post Application Operaatio Shis 4 sico acetate as autre eA dads edad ae aE a eo Dae a 15 20 APPLICATION PROCEDURES i cece ees eee pa eae eee eee A ee ee 16 20 1 Fumigation of Flat Storages Bunkers and Other Tarped Structures 0 0 00 c eee eee eee 16 20 2 Fumigation of Vertical Storages 0 0 eee 16 20 3 Fumigation of Mills Food Processing Plants and Warehouses 0 0 cee eee eee eee 16 20 4 Fumigation of Railcars Containers Trucks Vans Other Transport Vehicles and Small Storages Tess IYn es aa ea a al a ie 16 20 5 Fumigation of Storage to Control Rodents and Other Non Insect Pests 00 0 eee eee 17 20 6 Fumigation of SRIPphOldAS ws ici tepid travado nan Dae Pade eade ede a peewwaa ea wee eka 17 20 7 Barges ced tine tk ad E id ad ats Site a ee Peed weaker bee 18 21 ENVIRONMENTAL HAZARDS 0 0000 o 18 22 DISPOSAL OF SPENT OR PARTIALLY REACTED GRANULES 0 0 20 e eee eee eee 18 22 1 General eeose aoa cae aig ae aide aa wtuna ae R wal and ae E ea doa ee eea Paes RG ek fanaa ele dane dda 18 22 2 Disposal of Aluminum POUCHES 18 22 3 Directions for Disposal of Unreacted or Partially Reacted QUICKPHLO R Granules ESA Sacre a na ade bt aac dg Bo laure Rokr E E andesite Bod anc B
12. phosphine by the QUICKPHLO R Granules regard less of ambient temperature and the quick distribution of gas in the fumigation structure commodity it is possible to achieve sat isfactory control even at relatively cooler conditions To achieve a faster turn around during fumigation under tight sealing condi tions higher concentration of phosphine may be used but not exceeding the maximum application rate It should be noted that there is little to be gained by extending the exposure period if the structure to be fumigated has not been carefully sealed thereby insects are not subjected to lethal concentrations of phosphine Careful sealing is required to maintain adequate gas levels and proper application procedures must be followed to provide sat isfactory distribution of phosphine gas Some structures can only be treated when completely tarped while others cannot be properly sealed by any means and should not be fumigated SECTION 7 DOSAGE RATE GUIDELINES Phosphine is a mobile gas and will penetrate to all parts of the storage structure if given enough time even if the area is filled with commodity Therefore dosage must be based upon the total volume of the space being treated and not on the amount of commodity it contains The same amount of QUICKPHLO R Granules is required to treat a 30 000 bushel silo whether it is empty or full of grain unless of course a tarpaulin seals off the surface of the commodity Higher dosages are recom
13. the cargo is aerated the certified applicator shall ensure that a qualified person using phosphine gas detection equipment tests spaces adjacent to areas containing fumigated cargo as well as all regularly occupied spaces for fumigant leakage If leakage of the fumigant is detected the person in charge of the fumigation shall take action to correct the leakage or shall inform the master of the vessel or his representative of the leakage so that corrective action can be taken 1 20 6 4 Precautions and Procedures During Voyage 1 Using appropriate gas detection equipment monitor spaces adjacent to areas containing fumigated cargo and all regular ly occupied areas for fumigant leakage If leakage is detected the area should be evacuated of all personnel ventilated and action taken to correct the leakage before allowing the area to be occupied Do not enter areas fumigated with QUICKPHLO R Granules except under emergency conditions If necessary to enter a fumigated area appropriate personal protection equipment must be used see Section 21 6 5 Precautions and Procedures During Discharge Never enter fumigated areas alone At least one other person wearing personal protection equipment should be available to assist in case of an emergency 20 6 5 Precautions and Procedures During Discharge If necessary to enter holds prior to aeration test spaces directly above grain surface for phosphine concentrations using appro priate ga
14. the case with the metal lic phosphides Lower doses of Phosphine can be used for fumigation with QUICKPHLO R Phosphine Generator since the gas addition and distribution inside the fumigating chamber is quick and con tinuous unlike the aluminum and magnesium phosphine tablets pellets and rope formulations SECTION 8 PROTECTIVE CLOTHING 8 1 GLOVES Wear dry gloves of cotton or other material if contact with gran ules is likely Gloves should remain dry during use Wash hands thoroughly after handling QUICKPHLO R Granules Prior to laundering aerate used gloves and other clothing that may be contaminated in a well ventilated area SECTION 9 RESPIRATORY PROTECTION 9 1 WHEN RESPIRATORY PROTECTION MUST BE WORN National Institute for Occupational Safety and Health Mine Safety and Health Administration NIOSH MSHA approved respiratory protection must be worn during exposure to concentrations in excess of permitted limits or when concentrations are unknown Self contained breathing apparatus SCBA must be worn during entry into sites that are under fumigation if the concentration of phosphine is unknown or known to exceed the short term expo sure limit STEL for phosphine 1 ppm for 15 minutes 9 2 PERMISSIBLE GAS CONCENTRATION RANGES FOR RESPIRATORY PROTECTION DEVICES A NIOSH MSHA approved full face gas mask phosphine can ister combination may be used at levels up to 15 ppm or follow ing manufacturer s use conditions i
15. the nearest EPA Regional Office for guid ance For specific instructions see the Spill and Leak Procedures in the Spill and Leak Procedures section of this Manual Some local and state waste disposal regulations may vary from these general recommendations Disposal procedures should be reviewed with appropriate authorities to ensure compliance with local regulations Contact your state Pesticide or Environmental Control Agency or Hazardous Waste Specialist at the nearest EPA Regional Office for guidance 22 2 DISPOSAL OF ALUMINUM POUCHES Dispose empty aluminum foil pouches in a sanitary landfill or by other procedures approved by state and local authorities If properly exposed during the fumigation period spent QUICKPHLO R Granules will contain virtually no unreacted aluminum phosphide This will be a non hazardous waste However incompletely exposed granules will require special care before disposal 22 3 DIRECTIONS FOR DISPOSAL OF UNREACTED OR PARTIALLY REACTED QUICKPHLO R GRANULES IN THE GENERATOR The residual slurry remaining in the reaction chamber of the gen erator after fumigation with QUICKPHLO R Granules is a gray ish liquid This will be a non hazardous waste and contain only a small amount of unreacted aluminum phosphide However residual slurry from incompletely reacted QUICKPHLO R Granules must be further deactivated within the QUICKPHLO R Phosphine Generator see below before disposal at a landfill Confin
16. water into a deactivation unit which is a part of the generator and is automatically sealed off from the rest of the generator to prevent phosphine exposure to the operator Phosphine gas which is being generated during this deactivation process is passed through a scrubber containing a special grade activated carbon No phosphine is released from the deactivation unit or scrubber only clean air is let off into atmosphere from the scrubber All these operations take place automatically through a control panel The phosphine in the slur ry after deactivation drops to less than 0 1 After deactivation the spent material is disposed of as described in Disposal Instructions section of the Applicator s Manual As soon as the residue is flushed with water into the deactivation unit it is safe to open the generator chamber dry it completely and then start another fumigation with additional QUICKPHLO R Granules if needed The required amount of water is placed into the holding tank unit of the generator only after the predetermined quantity of gran ules is placed in a separate section of the reaction unit The sys tem is sealed and phosphine generation starts instantly after the operator initiates the controls of the generator 13 3 LEAKAGE FROM FUMIGATED SITES Phosphine is highly mobile and given enough time may pene trate seemingly gas tight materials such as concrete and cinder block Therefore adjacent enclosed areas likely to be occu
17. with all fumiga tion workers during the initial opening of the fumigation struc ture for aeration Once the aeration process is secured and monitoring has established that aeration can be completed safely the certified applicator does not need to be physically present and trained person s can complete the process and remove the placards Persons with documented training in the handling of phos phine fumigated products must be responsible for receiving aerating and removal of placards from vehicles which have been fumigated in transit Refer to the Requirements for Certified Applicator s Presence and Training for Receipt of In Transit Vehicles Under Fumigation section of this manual for training requirements A Certified Applicator must be present on site with at least one trained worker when entering a area under fumigation for ini tiating aeration gas level measurements repairing leaks or other trouble shooting A Certified Applicator must be present on site when a trained worker is operating the generator lt is the responsibility of the certified applicator that at the end of fumigation the genera tor is disconnected from the fumigation chamber and the spent granules and waste slurry is processed and disposed of safely and properly 10 2 THE REQUIREMENTS FOR AUTHORIZED TRAINING OF WORKERS Prior to receiving in transit fumigated vehicles the trained per son s must be trained by a Certified Applicator following the EP
18. A accepted product applicator s manual that must precede or be attached to the outside of a transport vehicle or by other training which is accepted by local and or state authorities When training has been completed and the employee demonstrates 11 safety knowledge proficiency the training date must be logged and maintained in the employee s safety training record for a minimum of three years Refresher training must be done on an annual basis This training must cover the following items each of which may be found in this manual a How to aerate the vehicle and verify that it contains no more than 0 3 ppm phosphine OR b How to transfer the commodity to another storage area with out prior aeration and ensure that worker safety limits are not being exceeded during the transfer c How to determine when respiratory protection must be worn d How to protect workers and nearby persons from exposure to levels above the 8 hour time weighted average TWA of 0 3 ppm or the 15 minute TWA short term exposure limit STEL of 1 0 ppm phosphine e Proper removal of placards and release of the fumigated commodity SECTION 11 GAS DETECTION EQUIPMENT There are a number of devices on the market for the measure ment of phosphine gas at both industrial hygiene and fumigation levels Glass detection tubes used in conjunction with the appro priate hand operated air sampling pumps are widely used These devices are portable simple to
19. APPLICATOR S MANUAL FOR QUICKPHLO R Granules THIS PRODUCT IS ACCOMPANIED BY AN APPROVED APPLICATOR S MANUAL READ AND UNDERSTAND THE CON TAINER LABEL AND APPLICATOR S MANUAL ALL PARTS OF THE LABELING AND APPLICATOR S MANUAL ARE EQUALLY IMPORTANT FOR SAFE AND EFFECTIVE USE OF THE PRODUCT CONSULT WITH YOUR STATE LEAD PESTI CIDE REGULATORY AGENCY TO DETERMINE REGULATORY STATUS REQUIREMENTS AND RESTRICTIONS FOR USE OF THIS FUMIGANT PRODUCT IN YOUR STATE CALL 1 800 438 6071 IF YOU HAVE ANY QUESTIONS OR DO NOT UNDERSTAND ANY PART OF THIS LABELING RESTRICTED USE PESTICIDE DUE TO ACUTE INHALATION TOXICITY OF PHOSPHINE GAS For retail sale to Dealers and Certified Applicators only For use by Certified Applicators or persons under their direct supervision and only for those uses covered by the Certified Applicator s certification Refer to the directions in the Applicator s Manual for requirements of the physical presence of a Certified Applicator GRANULES uickPHlo R Aluminum Phosphide Fumigant FOR USE ONLY WITH UPI S QuickPHlo R PHOSPHINE GENERATOR FOR CONTROL OF PESTS OF STORED PRODUCTS ACTIVE INGREDIENT ALUMINUM PHOSPHIDE oocoocccccccococo 77 5 OTHER INGREDIENTS coers darea tienaa maai E A a a a 22 5 TOTAL secreet tei ads E eat E Ses State eas 100 0 PRECAUCION AL USUARIO Si usted no le ingles no use este producto hasta que la etiqueta se le haya sido explicado ampliamente TO THE USER If
20. ON OF SHIPHOLDS 20 6 1 General Information Important Shiphold fumigation prior to transit is also governed by U S Coast Guard Regulation 46 CFR 147A Interim Regulations for Shipboard Fumigation Refer to this regulation prior to fumigation For further information contact Commandant U S Coast Guard Hazardous Materials Standards Division GMSO 3 Washington DC 20593 0001 In transit fumigation of transport vehicles and freight containers on ships is also governed by U S Department of Transportation DOT RSPA 49 CFR 176 76 h regulations along with portable tanks containing hazardous materials and International Maritime Dangerous Goods Code P9025 1 Amat 30 00 Notify the con signee if the commodity is to be shipped under fumigation If the consignee is unfamiliar with proper handling of fumigated ves sels fumigated in transit it is recommended that they be provid ed with the necessary information See Sections 10 14 and 16 of this manual for recommendations on training of persons authorized to remove placarding placarding and commodity aeration 20 6 2 Pre Voyage Fumigation Procedures for In Transit Fumigation 1 Prior to fumigating a vessel before the vessel leaves the port the master of the vessel or his representative and the certi fied applicator must determine whether the vessel is suitably designed and configured so as to allow for safe occupancy by the ship s crew throughout the duration of the fumigation If it is
21. PHLO R Granules in the QUICKPHLO R Phosphine Generator b All phosphine readings should be documented D NOTIFICATION i e Confirm that the appropriate local authorities fire depart ments police departments etc have been notified as per label instructions local ordinances or instructions of the client Prepare written procedure Emergency Response Plan which contains explicit instructions names and telephone numbers so as to be able to notify local authorities if phos phine levels are exceeded in an area that could be dangerous to bystanders and or domestic animals Confirm that the receivers of in transit vehicles under fumiga tion have been notified and are trained according to the Requirements for Certified Applicator s Presence and Training for Receipt of In Transit Vehicles Under Fumigation section of this manual SEALING PROCEDURES Sealing must be adequate to control the pests Care should be taken to insure that sealing materials will remain intact until the fumigation is complete If the site has been fumigated before review the previous FMP for previous sealing information Make sure that construction remodeling has not changed the building in a manner that will affect the fumigation Warning placards must be placed on every possible entrance to the fumigation site F APPLICATION PROCEDURES AND FUMIGATION PERIOD la 2 Plan carefully and apply the product
22. age e Vessels ship or barge In addition to the Applicator s Manual read the US Coast Guard Regulations 46 CFR 147A Fully acquaint yourself with the site and commodity to be fumigated including a The general structure layout construction materials design age maintenance of the structure fire or com bustibility hazards connecting structures and escape routes above and below ground and other unique hazards or structure characteristics Prepare with the owner operator person in charge Draw or have a drawing or sketch of structure to be fumigated delineating features hazards and other structural issues The number and identification of persons who routinely enter the area to be fumigated i e employees visitors customers etc The specific commodity to be fumigated its mode of stor age and its condition The previous treatment history of the commodity if available Accessibility of utility service connections Nearest telephone or other means of communication and mark the location of these items on the drawing sketch e f g Emergency shut off stations for electricity water and gas Mark the location of these items on the drawing sketch h Current emergency telephone numbers of local Health Fire Police Hospital and Physician responders i Name and phone number both day and night of appropri ate company officials j Check mark and prepare the points of fumigation applica
23. akage If leakage of the fumigant is detected the person in charge of the fumigation shall take action to correct the leakage or shall inform the master of the vessel or his representative of the leakage so that corrective action can be taken 9 The person in charge of the fumigation shall review with the master or his representative the precautions and procedures to follow during the voyage 20 6 3 Application Procedures for Bulk Dry Cargo Vessels and Tankers Carefully seal and place fumigation warning placards on the vessel or tanker Add granules to the QUICKPHLO R Phosphine Generator The generated phosphine is introduced into the vessel or tanker After the fumigation is complete the generator is disconnected from the fumigated structure and removed from the vessel before it leaves port Immediately after application of the fumigant close and secure all hatch covers tank tops Butterworth valves man ways etc The gas can be continuously re circulated within the vessel or tanker using the vessel s or tanker s circulation fan If the fumigation is not completed and the vessel aerated before the manned vessel leaves port the person in charge of the vessel shall ensure that at least two units of personal pro tection equipment and one gas or vapor detection device and a person qualified in their operation be on board the vessel during the voyage During the fumigation or until a manned vessel leaves port or
24. arges 6 Shipholds Commodity Fumigation a Bulk stored commodi 30 80 66 176 ties in bunkers and commodities stored on ground loosely piled under gas tight covering b Bulk stored commodi 50 145 110 319 ties in flat storage and commodities stored on ground loosely piled under gas tight covering c Packaged commodi 30 60 66 132 ties bagged grain process foods etc in sealable enclosures d Nuts dates or dried fruit in storage boxes 20 40 44 88 20 145 44 319 20 40 44 88 Do not apply more than the recommended maximum rate depending upon the commodity or site being fumigated e All other commodities f Stored Tobacco 7 2 ALLOWABLE DOSAGE RANGE FOR FUMIGATION WITH QUICKPHLO R GRANULES After determining the quantity of stored commodity or area to be treated calculate the quantity of QUICKPHLO R Granules required using the application rate table under Section 7 1 Use an adequate number of pouches use an entire pouch as required for the fumigation Section 3 1 The amount of phos phine to be used and generated is predetermined based on area to be fumigated type of storage and other variables After calculating the amount in grams of granules needed for the size of the structure to be fumigated determine the package size best suitable for use in the generator If multiple packages are used and the phosphine concentration level in
25. ation Number 6 Name address and telephone number of the fumigation com pany and or applicator 7 A 24 hour emergency response telephone number All entrances to a fumigated structure must be placarded Where possible placards should be placed in advance of the fumiga tion to keep unauthorized persons away For in transit fumigat ed railroad hopper cars and trucks placards must be placed on both sides of the car near the ladders and next to the top hatch es into which the fumigant is introduced Do not remove placards until the treated commodity is aerated down to 0 3 ppm phosphine or less To determine whether aer ation is complete each fumigated structure or vehicle must be monitored and shown to contain 0 3 ppm or less phosphine gas in the air space around and if feasible in the mass of the commodity SECTION 15 SEALING OF STRUCTURES The structure to be fumigated must first be inspected to deter mine if it can be made sufficiently gas tight Careful sealing is required so that adequate gas levels are retained Turn off all ven tilation supply air air conditioning and any other air moving sys tems which could negatively affect the fumigation Thoroughly inspect the structure to be fumigated and seal cracks holes and openings These areas could include but are not limited to win dows doors vents chimneys open pipes and structural flaws Sealing techniques can vary but most often include polyethyl ene sheeting ad
26. d ed in the QUICKPHLO R Phosphine Generator User s Operating Instructions Manual The generator is designed to ensure that the 7 phosphine generated is dispensed into the structure without any accumulation of gas in the reaction chamber The residue left behind in the reaction unit consists of a slurry of aluminum hydroxide water and any remaining aluminum phos phide That residue is flushed with water into a deactivation unit which is a part of the generator and is automatically sealed off from the rest of the generator to prevent phosphine exposure to the operator Phosphine gas generated during this deactivation process is passed through a scrubber containing a special grade activated carbon No phosphine is released from the deactiva tion unit or scrubber only clean air is let off into atmosphere from the scrubber All these operations are controlled automatically by a control panel The phosphine in the slurry after deactivation drops to less than 0 1 After deactivation the spent material is disposed of as described in Disposal Instructions section of the Applicator s Manual As soon as the residue is flushed with water into the deactivation unit it is safe to open the generator chamber Ensure that the reaction chamber is dry before starting another fumigation with additional QUICKPHLO R Granules SECTION 4 PESTS CONTROLLED QUICKPHLO R Granules can be used to control the following insects and their pre adult stag
27. de oe a a ee dared e 9 7 1 Recommended Dosage Rates for Various Sites and Commodities 0 00 e eee ee ee 10 7 2 Allowable Dosage Range for Fumigation with QUICKPHLO R Granules n nsss 0000 c eee 10 8 PROTECTIVE CLOTHING comio or ees Dade Ba epee a Faw ee Woe eee 10 SA GIOVES 24 4 5 cu hee sd ed Senedd beth tee ciate ead ned dio ose da 10 9 RESPIRATORY PROTECTION cise cccee core saw ng ae drey parr Swe cd 10 9 1 When Respiratory Protection Must Be Worn o oooccccocc eneren 10 9 2 Permissible Gas Concentration Ranges for Respiratory Protection DevicesS 0ooooooommomooo 11 9 3 Requirements for Availability of Respiratory Protection oooooooooororonrrr ee 11 10 REQUIREMENTS FOR CERTIFIED APPLICATOR S PRESENCE AND TRAINING DURING FUMIGATION ccocoo teens 11 10 1 Requirements for the Presence of a Certified Applicator oooocooocconooocn ro 11 10 2 Requirements for Authorized Training of WorkerS oooocccococcneoo 11 11 GAS DETECTION EQUIPMENT 11 12 NOTIFICATION REQUIREMENTS 0 0 e eee te eee 11 12 1 Authorities and On Site Workers 0 0 0 0 ec eee eee eee 11 12 2 Incidents Involving These Products 00 00 cece ee tet 11 12 3 Theft of ProdUcts voor a a A dee bebe des 11 13 APPLICATOR AND WORKER EXPOSURE 0 0 00 cece eee tte tte eee 11 AS MEX DOS URS LIMITS cata A A A AA a 11 13 2 Generation of Phosphine Using the QUICKPHLO R Phosphine Gen
28. dosage of granules to be used in the generator based upon volume of the building air and or commodity temperature and the general tightness of the structure Turn off all lights within the area to be treated and shut off all electrical motors not essential to operation of storage Carefully seal and place warning placards on the space to be fumigated Doors leading to the fumigated space must be closed sealed and placarded with warning signs Attach the inlet and outlet tubing from the QUICKPHLO R Phosphine Generator fan to the structure to be fumigated Add the QUICKPHLO R Granules to the QUICKPHLO R Phosphine Generator Ensure the generator reaction unit is dry Inject and re circulate phosphine gas through the aeration ducts or at points below the surface of the grain if possible Depending upon the size of the storage it may be necessary to make injections of gas at several points if necessary to achieve more uniform distribution of the gas Upon completion of the exposure period windows doors vents etc should be opened and the fumigated structure allowed to aerate The structure should not be entered with out proper Personal Protective Equipment PPE unless gas readings have been taken and the concentration is below the allowable limits Gas concentration readings may be taken using low level detector tubes or similar devices to ensure safety of personnel who reenter the treated area Collect the spent QUICKPHLO
29. ds Dried fish Dried milk dried powdered milk nondairy creamers and non fat dried milk Dried or dehydrated fruits such as apples dates figs peach es pears prunes raisins citrus and sultanas Processed herbs spices seasonings and condiments Malt Processed nuts Such as almonds apricot kernels Brazil nuts cashews filberts macadamia nuts peanuts pecans pista chio nuts walnuts and other processed nuts Processed oats including oatmeal Rice brewer s rice grits enriched and polished Soybean flour and milled fractions Processed tea Dried and dehydrated vegetables such as beans carrots lentils peas potato flour potato products and spinach Yeast including primary yeast Wild rice Other processed foods 5 3 NONFOOD COMMODITIES INCLUDING TOBACCO The listed nonfood items may be fumigated with QUICKPHLO R Granules Granules should not come into direct contact with tobacco and other nonfood commodities Nonfood Commodities Which May Be Fumigated With QUICKPHLO R Granules Processed or unprocessed cotton wool and other natural fibers or cloth clothing Straw and hay Feathers Human hair rubberized hair vulcanized hair mohair Leather products animal hides and furs Tires for mosquito control Tobacco Wood cut trees wood chips wood and bamboo products Paper and paper products Dried plants and flowers Seeds such as grass seed ornamental herbaceous plant seed and vegetable seed
30. e Generator before the vehicles are transported 6 Phosphine concentrations should be measured at places within the treatment area to verify the lethal concentration throughout the commodity 7 Notify the consignee if the commodity is to be shipped under fumigation If the consignee is unfamiliar with proper handling of fumigated rail cars and containers fumigated in transit it is recommended that they be provided with the necessary infor mation See Sections 10 14 and 16 of this manual for recom mendations on training of persons authorized to remove placarding and commodity aeration 8 Aeration of railcars railroad boxcars containers and other vehicles is prohibited en route 9 Moving in transit fumigated containers or vehicles over public roads is prohibited 20 5 FUMIGATION OF STORAGES TO CONTROL RODENTS AND OTHER NON INSECT PESTS Rodents and other non insect pests in storages may be con trolled with short term fumigations using QUICKPHLO R Granules and the generator In contrast to insects which gener ally require 3 or more days of fumigation to obtain adequate con trol rodents and other vertebrate pests may be controlled within 1 to 4 hours after achieving distribution of phosphine throughout the structure A concentration of 220 ppm phosphine will control these pests in about one hour Control will be achieved by expo sure to 440 ppm phosphine for one half hour 110 ppm phos phine for two hours etc 20 6 FUMIGATI
31. ed Phosphorus Inc for further assistance The FMP and related documentation including monitoring records must be maintained for a minimum of 2 years GUIDANCE FOR PREPARATION OF A FUMIGATION MANAGEMENT PLAN 9 19 1 PURPOSE A Fumigation Management Plan FMP is an organized written description of the required steps involved to help ensure a safe legal and effective fumigation It will also assist you and others in complying with pesticide product label requirements The guidance that follows is designed to help assist you in address ing all the necessary factors involved in preparing for and fumi gating a site 14 This guidance is intended to help you organize any fumigation that you might perform PRIOR TO ACTUAL TREATMENT It is meant to be somewhat prescriptive yet flexible enough to allow the experience and expertise of the fumigator to make changes based on circumstances which may exist in the field By follow ing a step by step procedure yet allowing for flexibility safe and effective fumigation can be performed Before any fumigation begins carefully read and review the label and the Applicator s Manual This information must also be given to the appropriate company officials Supervisors foreman safe ty officer etc in charge of the site Preparation is the key to any successful fumigation If you do not find specific instructions for the type of fumigation that you are to perform listed in this Guidance Docum
32. ee Aaya a data a 18 22 4 Deactivation of QUICKPHLO R GranuleS 0 06 cette eee tne eens 18 23 SPILL AND LEAK PROCEDURES 0 cece tenn eee 19 23 1 General Precautions and Directions deresan eas piihia eee eee ee 19 23 2 Leaking Product Container Procedures 0 ccc eee eee 19 23 3 Spill PrOCeQures asociar a A ind anager A a 19 23 4 Direction for Deactivation of Granules by the Wet Meth0d oo ooocooccococr eee 19 SECTION 1 FIRST AID Symptoms of exposure to this product are headaches dizzi ness nausea difficult breathing vomiting and diarrhea In all cases of overexposure get medical attention immediately Take victim to a doctor or emergency treatment facility IF INHALED e Move person to fresh air e lf person is not breathing call 911 or an ambulance then give artificial respiration immediately preferably by mouth to mouth e Keep warm and make sure person can breathe freely e Contact a poison control center or doctor for treatment advice IF SWALLOWED e Call a poison control center or doctor immediately for treatment advice e Have person drink one or two glasses of water and induce vomiting by touching back of throat with finger or if available administer syrup of ipecac e Do not give anything by mouth to an unconscious person IF ON SKIN OR e Brush or shake material off clothes and CLOTHING shoes in a well ventilated area Allow clothes to a
33. ement of partially spent QUICKPHLO R Granules may result in a fire hazard Small amounts of phosphine gas may be given off from unreacted granules and confinement of the gas may result in a flash 22 4 DEACTIVATION OF QUICKPHLO R GRANULES Any leftover unreacted granules remaining inside the reaction chamber of the generator are deactivated in a separate chamber situated within the generator assembly The QUICKPHLO R Phosphine Generator is equipped with a deactivation chamber to deactivate the residue left after application of QUICKPHLO R Granules The spent slurry left over from the application of QUICKPHLO R Granules is flushed with water in the deactiva tion chamber and the liberated phosphine is scrubbed in the scrubber The spent slurry remaining after the deactivation process is a non hazardous waste and may be disposed of at a sanitary landfill or other approved sites or other means without prior decanting Where permissible the slurry or the decanted water from the slurry may be disposed of by on site burial SECTION 23 SPILL AND LEAK PROCEDURES 23 1 GENERAL PRECAUTIONS AND DIRECTIONS A spill may produce high levels of phosphine gas and therefore attending personnel must wear self contained breathing appara tus SCBA or its equivalent when the concentration of gas is unknown Other NIOSH MSHA approved respiratory protection may be worn if the concentration is known Do not use water at any time to clean up a spill
34. ent you will want to construct a similar set of procedures using this document as your guide or contact United Phosphorus Inc for assistance Finally before any fumigation begins you must be familiar with and comply with all applicable federal state and local laws The success and future of fumiga tion are not only dependent on your ability to do your job but also by carefully following all rules regulations and procedures required by governmental agencies 19 2 A CHECKLIST GUIDE FOR A FUMIGATION MANAGEMENT PLAN This checklist is provided to help you take into account factors that must be addressed prior to performing all fumigations It emphasizes safety steps to protect people and property The checklist is general in nature and cannot be expected to apply to all types of fumigation situations It is to be used as a guide to prepare the required plan Each item must be considered However it is understood that each fumigation is different and not all items will be necessary for each fumigation site A PRELIMINARY PLANNING AND PREPARATION 1 Determine the purpose of the fumigation a Elimination of insect infestation b Elimination of vertebrate pest infestation c Plant pest quarantine Determine the type of fumigation for example a Space tarp mill warehouse food plant b Vehicle railcar truck van container c Commodity raw agricultural or processed foods d Type of Storage vertical silo farm storage flat stor
35. erate in a ventilated area prior to laundering e Do not leave contaminated clothing in occupied and or confined areas such as automobiles vans motel rooms etc e Wash contaminated skin thoroughly with soap and water IF IN EYES e Hold eye open and rinse slowly and gently with water for 15 20 minutes e Remove contact lenses if present after the first 5 minutes then continue rinsing eye e Call a poison control center or doctor for treatment advice Have the product container or label with you when calling a poison control center or doctor or going for treatment For emergency medical treatment contact the Rocky Mountain Poison Center 1 866 673 6671 Note to Physician QUICKPHLO R Granules reacts with mois ture from the air water acids and many other liquids to release phosphine hydrogen phosphide gas Mild inhalation exposure causes malaise indefinite feeling of sickness ringing of ears fatigue nausea and pressure in the chest which is relieved by removal to fresh air Moderate poisoning causes weakness vomiting pain just above the stomach chest pain diarrhea and dyspnea difficulty in breathing Symptoms of severe poisoning may occur within a few hours to several days resulting in pul monary edema fluid in lungs and may lead to dizziness cyanosis blue or purple skin color unconsciousness and death In sufficient quantity phosphine affects the liver kidneys lungs nervous syste
36. erator o oooooocooooo 11 13 3 Leakage from Fumigated SiteS ooooooooocrccrorre eee 12 13 4 Aeration and Reta ci a tia ape kd bw a A E i ee deed add aad 12 13 5 Handling Unaerated Commodities praterie bane Wide a dee ica 12 13 6 Industrial Hygiene Montong ooo decade ne A Pea ed ak a Baked ate 12 13 7 Engineering Controls and Work Practices 0 0c eect eens 12 14 PLACARDING OF FUMIGATED AREAS 0 cece een eee 12 15 SEALING OF STRUCTURES loben rr i ood than Dead vee Pha do RR bee ede a 13 16 AERATION OF FUMIGATED COMMODITIES 0 cee tees 13 16 1 Foods andi ESSAS bas techies ial id a eee donated gay A A Medan aan ott 13 16 2 NOn FOOd COMMOGIIES scooter da ee aaa a ae Puan ene a Pata 13 16 3 TODACCO nn cca cdi e dread reteset a edie ie EE a Hebe ats 13 17 STORAGE INSTRUCTIONS ocio eee ede eek eed Rha malas ak ee Oa ede Ae ia 13 17 1 Labeling of Storage iiss iei tice a Pee A Danae are Road Cae aed eee eee ee 13 TABLE OF CONTENTS continued PAGE 18 TRANSPORT INSTRUCTIONS o 13 18 1 Transportation Designations gamissyari TA ee eed AS id as 13 19 FUMIGATION MANAGEMENT PLAN GUIDANCE FOR PREPARATION OF A FUMIGATION PLAN 14 19 1 PUPOSO vivido ot eked a rd da aa a a de ia a da 14 19 2 A Checklist Guide for a Fumigation Management Plan ooocooccoccrcc 14 A Preliminary Planning and Preparati0N o ooocooooorrr eee 14 Be Personnel dd cia 15 CUMONIONNG sii A A
37. es that is eggs larvae and pupae and certain vertebrate pests almond moth Angoumois grain moth bean weevil bees Cadelle cereal leaf beetle cigarette beetle confused flour beetle dermestid beetles dried fruit beetle dried fruit moth European grain moth flat grain beetle fruit flies granary weevil greater wax moth hairy fungus beetle Hessian fly Indian meal moth Khapra beetle lesser grain borer maize weevil Mediterranean flour moth pink bollworm raisin moth red flour beetle rice weevil rodents rusty grain beetle saw toothed grain beetle spider beetle tobacco moth yellow meal worm Although it is possible to achieve total control of the listed insect pests this is frequently not realized in actual practice Factors contributing to less than 100 control include leaks poor gas distribution unfavorable exposure conditions etc In addition some insects and or their life stages are less susceptible to phosphine than others If maximum control of the pests is to be attained temperature and humidity conditions must be favor able extreme care must be taken in sealing the structure high er dosages must be used exposure periods lengthened and proper application procedures must be followed The use of QUICKPHLO R Granules to control vertebrate pests has also proved to be effective Pests such as mice pigeons squirrels ground hogs etc which are frequent sources of prob lems in storage
38. ge size of granules and amount of phosphine gas generated 125 g granules generates 56 g of phosphine 550 g granules generates 250 g of phosphine 2 2 kg granules generates 1 kg of phosphine 4 4 kg granules generates 2 kg of phosphine or 1 0 g of granules generates 0 45 g of phosphine equivalent to 11 3 ppm of phosphine 1 000 cu ft QUICKPHLO R Granules are packed in sealed aluminum foil pouches and their shelf life is unlimited as long as the pack aging remains intact The aluminum pouches containing QUICKPHLO R Granules cannot be resealed for future use Storage and Handling instructions are given in detail in the Storage Instructions and Disposal Instructions sections of the Applicator s Manual Precautions for and instructions for use of the generator equipment with QUICKPHLO R Granules are explained in the User s Operating Instruction Manual supplied with the generator equipment Number of Pouches to Use Total Number of Pouches 550g 2 2kg 4 4kg wi k oo Pp rm a ala NO oP BWW DM AM OO AINIIN A MP NIO hh 00 NN N 3 2 QUICKPHLO R PHOSPHINE GENERATOR QUICKPHLO R Phosphine Generator is an automatic equipment assembly for generation of phosphine gas from QUICKPHLO R Granules The equipment is portable and it can be used in any location The generator is placed outside the struc ture to be fumigated United Phosphorus Inc will provide de
39. have been established at 0 1 ppm for raw agricultural commodities and animal feeds and 0 01 ppm for processed foods fresh fruits and vegetables To guarantee compliance with these tolerances it is necessary to aerate these commodities for a minimum of 48 hours prior to offering them to the end consumer 16 2 NON FOOD COMMODITIES Aerate all non food commodities to 0 3 ppm or less of phos phine Monitor densely packed commodities to ensure that aer ation is complete 13 16 3 TOBACCO Tobacco must be aerated for at least three days 72 hours when fumigated in hogsheads and for at least two days 48 hours when fumigated in other containers or until the concentration is below 0 3 ppm When plastic liners are used longer aeration periods will probably be required to aerate the commodity down to 0 3 ppm SECTION 17 STORAGE INSTRUCTIONS QUICKPHLO R Granules must be stored in a dry well ventilated area away from heat under lock and key Post as a pesticide storage area Do not contaminate food water or feed by storing pesticides in the same areas used to store these com modities Do not store in buildings where humans or domestic animals may frequent or reside Keep out of reach of children QUICKPHLO R Granules are supplied in aluminum foil pouch es Do not expose the granules to atmospheric moisture any longer than necessary QUICKPHLO R Granules should not be stored at sub zero temperatures because this will increase the
40. hesive tapes and adhesive sprays Expandable foam or caulking material can work well on structural flaws Proper sealing will insure sufficient gas levels within the fumigat ed structure and will decrease the chance of unwanted expo sures outside of the fumigated area As with all fumigations it is required that sealing be inspected for leaks If phosphine above 0 3 ppm is found in an area where exposure to workers or bystanders may occur the applicator using proper respiratory protection equipment must attempt to seal the leak from the exterior of the structure Failing this the applicator following proper procedures to prevent accidental poisoning may enter the structure and seal the leaks from the inside For entering a structure under fumigation at least two trained persons wearing proper respiratory protection may enter the structure A certified applicator must be physically present during the entry into the structure If the concentration inside the structure has decreased below the target level as a result of the leakage additional fumigant may be added following the sealing repairs DO NOT FUMIGATE A STRUCTURE THAT CANNOT BE SEALED SUFFICIENTLY GAS TIGHT SECTION 16 AERATION OF FUMIGATED COMMODITIES As an alternative to the minimum aeration time of 48 hours list ed below each treated commodity may be analyzed for residues of phosphine using accepted analytical methods 16 1 FOODS AND FEEDS Tolerances for phosphine residues
41. iate valves and sealing the openings into the over space with gas tight materials 4 Using the application manual determine the length of the fumigation and calculate the dosage of granules to be used based upon volume of the vessel air and or commodity tem perature and the general tightness of the vessel 5 Placard all entrances to the treated spaces with fumigation warning signs 6 Connect the distribution lines from the generator to the vessel Inject and re circulate phosphine gas from QUICKPHLO R Phosphine Generator through the distribution ducts Following the introduction of phosphine gas from QUICKPHLO R Phosphine Generator the distribution lines should be capped or sealed Seal up all openings The QUICKPHLO R Phosphine Generator must be disconnected and removed from the vessel before it leaves port 7 If the fumigation is not completed and the vessel aerated before the manned vessel leaves port the person in charge of the vessel shall ensure that at least two units of personal pro tection equipment and one gas or vapor detection device and a person qualified in their operation be on board the vessel during the voyage 8 During the fumigation or until a manned vessel leaves port or the cargo is aerated the certified applicator shall ensure that a qualified person using phosphine gas detection equipment tests spaces adjacent to areas containing fumigated cargo as well as all regularly occupied spaces for fumigant le
42. igation seal the vents near the bin top which connect to adjacent bins 1 16 Using the Applicator s Manual determine the length of the fumigation and calculate the dosage of granules to be used in the generator based upon volume of the building air and or commodity temperature and the general tightness of the structure Warning placards must be placed on every possible entrance to the fumigation site Connect the distribution lines from the generator to the stor age to be fumigated Inject and re circulate phosphine from the QUICKPHLO R Phosphine Generator through the distri bution ducts or at points below the surface of the commodity if possible Depending upon the size of the storage it may be necessary to make injections of gas at several points if neces sary to achieve more uniform distribution of the gas Phosphine concentrations should be measured at several times during the fumigation and at places within the treatment area to verify that lethal concentrations are attained through out the commodity When the fumigation is complete aerate as appropriate using precautions to prevent exposure to workers see Section 13 4 on Aeration and Reentry Adequate monitoring and aeration must be performed to reduce any residual phosphine levels to below 0 3 ppm 20 3 FUMIGATION OF MILLS FOOD PROCESSING PLANTS AND WAREHOUSES 1 Using the Applicator s Manual determine the length of the fumigation and calculate the
43. in weather conditions opening the pouches of QUICKPHLO R Granules in open air may produce a flash due to the phosphine build up Containers may also be opened near a fan or other appropriate ventilation that will rapidly exhaust contaminated air When opening point the aluminum foil pouch away from the face and body and slowly cut open the pouch with a pair of scissors Although the chances for a flash are very remote never open these pouches in a flammable atmosphere These precautions will also reduce the fumigator s exposure to phosphine gas Pure phosphine gas is practically insoluble in water fats and oils and is stable at normal fumigation temperatures However it may react with certain metals and cause corrosion especially at high er temperatures and relative humidities Metals such as copper brass and other copper alloys and precious metals such as gold and silver are susceptible to corrosion by phosphine Thus small electric motors smoke detectors brass sprinkler heads batter ies and battery chargers fork lifts temperature monitoring sys tems switching gears communication devices computers calculators and other electrical equipment should be protected or removed before fumigation Phosphine will also react with cer tain metallic salts and therefore sensitive items such as photo graphic film some inorganic pigments etc should not be exposed Immediately after addition of phosphine to the struc ture turn off an
44. l Hygiene Monitoring in the Applicator s Manual Section 13 6 for appropriate monitoring and safety procedures Pure phosphine gas is odorless the garlic odor is due to a contaminant in the formulation Since a garlic odor may not be detected under certain circumstances the absence of an odor does not mean that phosphine gas is absent Observe proper application aeration re entry and dis posal procedures specified elsewhere in the labeling to prevent overexposure PHYSICAL AND CHEMICAL HAZARDS QUICKPHLO R Granules and partially spent slurry will release phosphine gas if exposed to moisture from the air or if it comes into contact with water acids and many other liquids Since phosphine may ignite spontaneously at levels above its lower flammable limit of 1 8 v v it is important not to exceed this concentration Ignition of high concentrations of phosphine can produce a very energetic reaction Explosions can occur under these conditions and may cause severe personal injury Never allow the buildup of phosphine to exceed explosive concen trations Do not confine spent or partially spent granules as the slow release of phosphine may result in formation of an explo sive atmosphere QUICKPHLO R Granules outside its storage containers should not be stacked or piled up or contacted with liquid water This may cause a temperature increase increase the rate of gas production and confine the gas so that ignition could occur Under certa
45. m and circulatory system Inhalation can cause lung edema fluid in lungs and hyperemia excess of blood in a body part small perivascular brain hemorrhage and brain edema fluid in brain Ingestion can cause lung and brain symptoms but damage to the viscera body cavity organs is more common Phosphine poisoning may result in 1 pulmonary edema 2 liver elevated serum GOT LDH and alkaline phos phatase reduced prothrombin hemorrhage and jaundice yel low skin color and 3 kidney hematuria blood in urine and anauria abnormal lack of urination Pathology is characterized by hypoxia oxygen deficiency in blood tissue Frequent expo sure to subacute concentrations over a period of days or weeks may cause poisoning Treatment is symptomatic The following measures are suggested for use by the physi cians in accordance with their own judgment In its milder forms symptoms of poisoning may take some time up to 24 hours to make their appearance and the following is suggested 1 Give complete rest for 1 2 days during which time the patient must be kept quiet and warm 2 Should the patient suffer from vomiting or increased blood sugar appropriate solutions should be administered Treatment with oxygen breathing equipment is recommend ed as is the administration of cardiac and circulatory stimulants In case of severe poisoning intensive care unit recommended 1 Where pulmonary edema is observed steroid therapy sho
46. mended for structures that are of loose construction and for the fumigation of bulk stored commodities in which diffusion of the gas is slow resulting in poor distribution of phosphine gas The quantity of phosphine produced by each of the package sizes of QUICKPHLO R Granules are as follows Phosphine QUICKPHLO R Phosphine equivalent per Granules generated 1 000 cu ft 125 g pouch 56 g 1 400 ppm 550 g pouch 250 g 6 250 ppm 2 2 kg pouch 1 000 g 25 000 ppm 4 4 kg pouch 2 000 g 50 000 ppm 1 g of phosphine is equivalent to 25 ppm 1 000 cu ft area 7 1 RECOMMENDED DOSAGE RATES FOR VARIOUS SITES AND COMMODITIES When a dosage range is recommended use the higher rate under conditions of severe infestation lower temperature and other applicable variables The following dosage ranges are based on bulk storage per 1 000 bushels or space fumigations per 1 000 cu ft Dosage Range 1 000 cu ft QUICKPHLO R Granules g Type of Fumigation Site Fumigation 1 Vertical Storages such as silos concrete bins steel bins tanks etc Phosphine g 30 60 66 132 70 145 30 65 154 319 66 143 2 Farm Bins Butler Type 3 Railcars containers trucks vans and other transport vehicles 4 Space fumigation 20 60 44 132 cereal mills feed mills food processing plants amp warehouses 30 80 30 65 66 176 66 143 5 B
47. mpletely aerated commodity via bulk handling equipment such as augers drag conveyors and conveyor belts to a nearby storage structure is permissible A Certified Applicator is responsible for training workers who handle the transfer of incompletely aerated listed commodities and appro priate measures must be taken i e ventilation or respiratory protection to prevent exposures from exceeding the exposure limits for phosphine The new storage structure must be placard ed if it contains more than 0 3 ppm phosphine If the fumigation structure must be entered to complete the transfer at least two trained persons wearing proper respiratory protection may enter the structure A certified applicator must be physically present during the entry into the structure REMEMBER transporting containers or vehicles under fumiga tion over public roads is prohibited 13 6 INDUSTRIAL HYGIENE MONITORING Phosphine exposures must be documented in an operations log or manual at each fumigation site and operation where expo sures may occur Monitor airborne phosphine concentrations in all indoor areas to which fumigators and other workers have had access during fumigation and aeration Perform such monitoring in workers breathing zones This monitoring is mandatory and is performed to determine when and where respiratory protection is required Once exposures have been adequately character ized spot checks must be made especially if conditions change sig
48. nificantly or if an unexpected garlic odor is detected or a change in phosphine level is suspected 13 7 ENGINEERING CONTROLS AND WORK PRACTICES If monitoring shows that workers may be exposed to concentra tions in excess of the permitted limits then engineering controls such as forced air ventilation and or appropriate work practices must be used to reduce exposure to within permitted limits In any case appropriate respiratory protection must be worn if phosphine exposure limits are exceeded SECTION 14 PLACARDING OF FUMIGATED AREAS All entrances to the fumigated structure must be placarded Placards must be made of substantial material that can be expected to withstand adverse weather conditions and must bear the wording as follows 1 The signal word DANGER PELIGRO and the SKULL AND CROSSBONES symbol in red 2 The statement Area Structure and or commodity under fumi gation DO NOT ENTER NO ENTRE 3 The Statement This sign may only be removed by a certified applicator or a person with documented training after the commodity is completely aerated and checked to contain 0 3 ppm or less of phosphine gas If incompletely aerated commodity is transferred to a new structure the new structure must also be placarded if it contains more than 0 3 ppm phos phine Worker exposure during this transfer must not exceed allowable limits 4 The date the fumigation begins 5 Trade name of the fumigant used and EPA Registr
49. nstructions for escape Above 15 ppm or in situations where the phosphine concentra tion is unknown a NIOSH MSHA approved self contained breathing apparatus SCBA must be worn The NIOSH OSHA Pocket Guide DHHS NIOSH 97 140 or the NIOSH ALERT Preventing Phosphine Poisoning and Explosions During Fumigation lists these and other types of approved respirators and the concentration limits at which they may be used 9 3 REQUIREMENTS FOR AVAILABILITY OF RESPIRATORY PROTECTION Respiratory protection is not required for applications from out side the area to be fumigated such as addition of granules to the generator in outdoor situations etc if exposures above the per mitted exposure limits will not be encountered The generator may never be placed inside the structure to be fumigated SECTION 10 REQUIREMENTS FOR CERTIFIED APPLICATOR S PRESENCE AND TRAINING DURING FUMIGATION 10 1 THE REQUIREMENTS FOR THE PRESENCE OF A CERTIFIED APPLICATOR AND THEIR RESPONSIBILITY FOR ALL WORKERS ARE AS FOLLOWS A Certified Applicator must be physically present responsible for and maintain visual and or voice contact with all fumiga tion workers during the application of the fumigant Once the application is complete and the structure has been made secure the certified applicator does not need to be physically present at the site A Certified Applicator must be physically present responsible for and maintain visual and or voice contact
50. nt and Partially Reacted Granules Section 22 5 Do not leave individual pouches outside its original storage box for extended period of time 6 Do not handle the pouches with wet hands To undertake safe and effective fumigations a Fumigation Management Plan FMP is to be developed by the certified applicator who is responsible for the entire fumigation process For further details on FMP refer to Section 19 SECTION 3 INTRODUCTION 3 1 QUICKPHLO R GRANULES QUICKPHLO R Granules must only be used with the QUICKPHLO R Phosphine Generator and not for use in the manner conventionally employed by aluminum and magnesium phosphide tablets pellets and rope fumigants The granules must not be added directly to raw or any other type of agricul tural commodity QUICKPHLO R Granules are for the exclusive use in a QUICKPHLO R Phosphine Generator for generating phosphine gas for fumigation of stored products to control insect and vertebrate pests QUICKPHLO R Granules in combination with QUICKPHLO R Phosphine Generator are used to protect stored commodities from damage by insects and for control of rodents and other vertebrate pests Fumigation of stored products with QUICKPHLO R Granules in the manner prescribed in the labeling does not contaminate the stored commodity because the granules do not come in direct contact with the stored commodity QUICKPHLO R Granules are acted upon by liquid water to produce phosphine PH
51. nt signed by the duly author ized representative of United Phosphorus Inc QUICKPHLO R is a registered trademark of United Phosphorus Inc 2008 United Phosphorus Inc All rights reserved Made in U S A 70506 69 100308 3315 20
52. of QUICKPHLO R Granules Water in contact with unreacted QUICKPHLO R Granules will greatly accelerate the production of phosphine gas which could result in a toxic and or fire hazard Wear dry gloves of cotton or other material when handling QUICKPHLO R Granules Check corrugated cartons and aluminum foil pouches If they are damaged handle as described below Return the pouches in good condition to the cardboard cartons or other suitable pack aging which complies with DOT regulations and storage and handling safety parameters 23 2 LEAKING PRODUCT CONTAINER PROCEDURES Transport the damaged QUICKPHLO R Granules aluminum foil pouches to an open area away from humidity and moisture suit able for pesticide inspection If QUICKPHLO R Granules alu minum foil pouches have been punctured or damaged causing a leak 1 the product in the pouches may be immediately used 2 the pouches may be temporarily repaired and closed with alu minum tape OR 3 the granules may be deactivated either in the QUICKPHLO R Phosphine Generator or by the Wet Method described below and then dispose of the residue 23 3 SPILL PROCEDURES DO NOT flush spillage down drain with water DO NOT use water at any time to clean up a spill Water in contact with unreacted QUICKPHLO R Granules will rapidly accelerate the production of phosphine and could cause spontaneous ignition of the gas If the spill is only a few minutes old and is not contaminated by
53. on Instruct all personnel on how to report any accident and or incidents related to fumigant exposure Provide a telephone number for emergency response reporting Instruct all personnel to report to proper authorities any theft of fumigant and or equipment related to fumigation Establish a meeting area for all personnel in case of emergency C MONITORING 1 Safety a Monitoring of phosphine conditions must be conducted in areas to prevent excessive exposure and to determine where exposure may occur Document where monitoring will occur Keep a log or manual of monitoring records for each fumi gation site This log must at a minimum contain the timing number of readings taken and level of concentrations found in each location When monitoring document even if there is no phosphine present In such cases subsequent monitoring is not rou tinely required However spot checks must be made occa sionally especially if conditions significantly change 15 2 d Monitoring must be conducted during aeration and correc tive action taken if gas levels exceed the allowed levels in an area where bystanders and or nearby residents or domestic animals may be exposed Efficacy a Phosphine readings should be taken from within the fumi gated structure to insure proper gas concentrations If the phosphine levels have fallen below the targeted level the fumigators may generate additional phosphine using QUICK
54. on Most of the required phosphine gas is generated in approximately 90 to 120 minutes depending on the size of the generator The generation of gas does not depend on outside tem perature or relative humidity Never place the generator inside the structure to be fumigated Before starting the fumigation the operator is required to complete a pre startup check of the generator assembly and delivery sys tems as explained in the generator User s Manual Doing these prechecks will ensure that there is no accumulation of gas in the generator Ensure that the QUICKPHLO R Phosphine Generator reaction unit is dry before addition of the QUICKPHLO R Granules QUICKPHLO R Granules must not be exposed to outside sources of water during addition to the QUICKPHLO R Phosphine Generator reaction unit Do not operate the generator if it is likely to get wet in the rain Do not apply granules to the generator reac tion unit in situations where rain condensate or outside sources of water can come in contact with the granules Depending upon the volume of structure to be fumigated the required quantity of granular formulation full packets only is added to the reaction unit of the generator After the generator is sealed the operator adds a predetermined quantity of water to the reac tion unit from a water tank mounted on the generator The operator must check the flow rates of phosphine gas to ensure that the desired system pressure is maintained as recommen
55. onsult company officials in the development of procedures and appropriate safety measures for nearby workers that will be in and around the area during application and aeration Consult with company officials to develop an appropriate monitoring plan that will confirm that nearby workers and bystanders are not exposed to levels above the allowed limits during application fumigation and aeration This plan must also demonstrate that nearby residents will not be exposed to concentrations above the allowable limits Consult with company officials to develop procedures for local authorities to notify nearby residents in the event of an emergency Confirm the placement of placards to secure entrance into any structure under fumigation Confirm the required safety equipment is in place and the nec essary manpower is available to complete a safe effective fumigation Written notification must be provided to the receiver of a vehi cle that is fumigated in transit These factors must be considered in putting together an FMP It is important to note that some plans will be more comprehensive than others All plans should reflect the experience and expert ise of the applicator and circumstances at and around the site In addition to the plan the applicator must read the entire label and the Applicator s Manual and must follow its directions care fully If the applicator has any questions about the development of a FMP contact Unit
56. ould be consulted for guidance on the selection and placement of such signs SECTION 18 TRANSPORTATION INSTRUCTIONS The United States Department of Transportation DOT classifies aluminum phosphide as Dangerous When Wet material and it must be transported in accordance with DOT regulations 18 1 TRANSPORT DESIGNATIONS The following transport designations apply to aluminum phosphide Proper Shipping Name Aluminum phosphide Hazard Class 4 3 Identification No UN 1397 Packing Group PG Shipping Label Shipping Placard Dangerous When Wet Poison Dangerous When Wet SECTION 19 FUMIGATION MANAGEMENT PLAN A Fumigation Management Plan FMP is a set of guidelines to ensure a safe and effective fumigation The certified applicator is responsible for working with the owners and or responsible employees of the site to be fumigated to develop and follow the FMP The FMP must address characterization of the site and include appropriate monitoring and notification requirements consistent with but not limited to the following 1 Inspect the site to determine its suitability for fumigation 2 When sealing is required consult previous records for any changes to the structure seal leaks and monitor any occu pied adjacent buildings to ensure safety Prior to each fumigation review any existing FMP MSDS Applicator s Manual and other relevant safety procedures with company officials and appropriate employees C
57. pending upon the size of the storage it may be necessary to make injections of gas at several points if necessary to achieve more uniform distribution of the gas Following the introduction of phosphine gas from QUICKPHLO R Phosphine Generator the distribution lines should be capped or sealed Phosphine concentrations should be measured at several times throughout the term of the fumigation and at places within the treatment area to verify the lethal concentration throughout the commodity When the fumigation is complete aerate as appropriate using precautions to prevent exposure to workers see Section 13 4 on Aeration and Reentry Adequate monitoring and aeration must be performed to reduce any residual phosphine levels to below 0 3 ppm 20 2 FUMIGATION OF VERTICAL STORAGES concrete upright bins farm bins and other silos in which grain can be rapidly transferred Carefully seal and place fumigation warning placards on the storage Smaller bins and silos may be fumigated by circulation of phosphine gas produced by the generator in a manner simi lar to that employed for warehouses For fumigation of larger vertical storages leave an opening of 2 sq ft or more at the top of the structure This will prevent a build up of pressure from gas pumped into the storage Consult previous records for any changes to the structure Close openings and seal cracks to make the structure as air tight as possible Prior to the fum
58. pied should be examined to ensure that significant leakage has not occurred Sealing of the fumigated site and or airflow in the occupied areas must be sufficient to bring down the phosphine concentration to a safe level of 0 3 ppm or below 13 4 AERATION AND REENTRY If the structure is to be entered after fumigation a NIOSH MSHA approved full face gas mask phosphine canister combination may be used at levels up to 15 ppm or following manufacturer s use conditions instructions for escape Above 15 ppm or in situ ations where the phosphine concentration is unknown a NIOSH MSHA approved self contained breathing apparatus SCBA must be worn The NIOSH OSHA Pocket Guide DHHS NIOSH 97 140 or the NIOSH ALERT Preventing Phosphine Poisoning and Explosions During Fumigation lists these and other types of approved respirators and the concentration limits at which they may be used The areas neighboring the fumigation site must be monitored to ensure that escape of gas from the treated commodity does not 12 result in the development of unacceptable levels i e over indus trial hygiene levels of phosphine Do not allow reentry into treat ed structures by any person before the level of phosphine reaches 0 3 ppm or below unless protected by an approved res pirator For reentry into an area under fumigation a certified applicator plus a minimum of one trained worker must be present 13 5 HANDLING UNAERATED COMMODITIES Transfer of inco
59. possibility of an ignition flash when opened The shelf life of QUICKPHLO R Granules is virtually unlimited as long as the aluminum foil pouches are sealed 17 1 LABELING OF STORAGE The labeling of the storage area should take into account the needs of a variety of regulatory organizations These should include but not be limited to corporate policy insurance carri er Occupational Safety and Health Administration OSHA Emergency Planning and Community Right To Know ACT and local emergency response professionals At a minimum the stor age must be marked with the following signs and should be locked 1 Danger Poison with skull and cross bones 2 Authorized Personnel Only 3 Pesticide Storage NFPA Hazard Identification Symbols The National Fire Protection Association NFPA has developed Hazard Identification Symbols for hazardous chemicals This standardized system is designed to provide at a glance the information regarding the health fire and reactivity hazards asso ciated with hazardous materials The following are the hazard categories and degree of hazard for aluminum phosphide Category Degree of Hazard Health 4 Severe Hazard Flammability 4 Severe Hazard Reactivity 2 Moderate Special Notice Key WwW NOTE When using the NFPA Hazard Identification System the characteristics of all hazardous materials stored in a particular area must be considered The local fire protection district sh
60. r Environmental Control Agency or Hazardous Waste Specialist at the nearest EPA Regional Office for guidance Container Spent Granules Disposal Dispose empty aluminum foil pouches in a sanitary landfill or by other procedures approved by state and local authorities If properly exposed during the fumigation period spent QUICKPHLO R Granules will contain virtually no unreacted aluminum phosphide This will be a non hazardous waste However incompletely exposed granules will require special care before disposal For specific instructions see the Disposal Instructions and Spill and Leak Procedures sections of the Applicator s Manual Spill and Leak Procedures General Precautions and Directions A spill may produce high levels of phosphine gas and therefore attending personnel must wear self contained breathing appa ratus SCBA or its equivalent when the concentration of gas is unknown Other NIOSH MSHA approved respiratory protection may be worn if the concentration is known Do not use water at any time to clean up a spill of QUICKPHLO R Granules Water in contact with unreacted QUICKPHLO R Granules will greatly accelerate the production of phosphine gas which could result in a toxic and or fire hazard Wear dry gloves of cotton or other material when handling QUICKPHLO R Granules Return all intact aluminum foil pouches to the original card board box Notify consignee and shipper of damaged cases If aluminum foil pouches ha
61. s detection and personal safety equipment Do not allow entry to fumigated areas without personal safety equip ment unless phosphine concentrations are at safe levels as indicated by a suitable detector Also see Section 13 5 for re entry procedures 20 7 Barges Barge fumigation is also regulated by U S Coast Guard Regulation 46 CFR 147A as modified by U S Coast Guard Special Permit 2 75 This permit which must be obtained prior to the fumigation is available from Commandant U S Coast Guard Hazardous Materials Standards Div GMSO 3 Washington DC 20593 0001 Leaks are a common cause of failures in the treatment of com modities aboard barges Carefully inspect all hatch covers prior to application of QUICKPHLO R Granules and seal if neces sary Placard the barge The barges must not be fumigated in transit 18 SECTION 21 ENVIRONMENTAL HAZARDS This product is highly toxic to wildlife Do not contaminate water by cleaning of equipment or disposal of wastes SECTION 22 DISPOSAL OF SPENT OR PARTIALLY REACTED GRANULES 22 1 GENERAL Do not contaminate water food or feed by storage or disposal Unreacted or partially reacted QUICKPHLO R Granules is acutely hazardous Improper disposal of excess pesticide is a violation of Federal Law If these wastes cannot be disposed of by use according to the Applicator s Manual contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at
62. s may be controlled SECTION 5 COMMODITIES WHICH MAY BE FUMIGATED WITH QUICKPHLO R GRANULES 5 1 RAW AGRICULTURAL COMMODITIES ANIMAL FEED AND FEED INGREDIENTS QUICKPHLO R Granules may be used for the fumigation of listed raw agricultural commodities animal feed and feed ingre dients processed foods tobacco and certain other nonfood items Raw Agricultural Commodities and Animal Feed and Feed Ingredients Which May Be Fumigated with QUICKPHLO R Granules almonds animal feed amp feed ingredients barley Brazil nuts cashews cocoa beans coffee beans corn cottonseed dates filberts flower seed grass seed millet oats peanuts pecans pistachio nuts popcorn rice rye safflower seed seed amp pod vegetables sesame seed sorghum soybeans sunflower seeds triticale vegetable seeds walnuts wheat 5 2 PROCESSED FOODS Processed Foods Which May Be Fumigated With QUICKPHLO R Granules Processed candy and sugar Cereal flours and bakery mixes Cereal foods including cookies crackers macaroni noodles pasta pretzels snack foods and spaghetti Processed cereals including milled fractions and packaged cereals Cheese and cheese byproducts Chocolate and chocolate products such as assorted choco late chocolate liquor cocoa cocoa powder dark chocolate coating and milk chocolate products Processed coffee Corn grits Cured dried and processed meat products Dates and figs Dried eggs and egg yolk soli
63. tailed training of all operators of the QUICKPHLO R Phosphine Generator including detailed written instructions in a User s Operating Instructions Manual QUICKPHLO R Phosphine Generator can use only the QUICKPHLO R Granules to produce phosphine at the fumigation site The generator may only be operated by a certified applicator or by a person trained in handling and using fumigants under his direct supervision and who has been further trained and certified by United Phosphorus Inc or its approved representatives Refer to the Applicator s Manual for detailed lists of commodities pests application rates and sites before using this generator and granules Follow all instructions for operation of the QUICKPHLO R Phosphine Generator User s Manual before adding the QUICKPHLO R Granules to the generator A diagram of the generator is shown in Figure 1 below FIGURE 1 GENERAL BLOCK DIAGRAM FOR QUICKPHLO R PHOSPHINE GENERATOR QUICKPHLO R Air Granules Water to Reaction Unit to 2 Holding Tanks GENERATOR DEACTIVATION CHAMBER CHAMBER y Clean Air STRUCTURE TO BE FUMIGATED After the structure is prepared and secured for fumigation the generator is connected to the structure to be fumigated with inlet and outlet tubings The generator has a fan The phosphine gas produced by the generator is delivered to the structure being fumigat ed and the gas is circulated by the fan back into the generator for recirculati
64. the structure has reached adequate levels for control of insect pests then any excess phosphine or unused granules in the generator can be deactivated inside the generator Any excess phosphine gas which is generated during this deactivation step is passed through a scrubber containing a special grade activated carbon No phosphine is released from the unit only clean air is let off into atmosphere The above dosages are not to be exceeded It is important to be aware that a shortened exposure period can not be fully compensated for with an increased dosage of phosphine Somewhat higher dosages but not exceeding the maximum dosage are usually recommended under cooler or where expo sure periods are relatively short However the major factor in selection of dosage is the ability of the structure to hold phos phine gas during the fumigation A good illustration of this point is comparison of the low dosages required to treat modern well sealed warehouses with the higher doses used for structures that cannot be sealed adequately In certain fumigations proper distribution of lethal concentra tions of gas to reach all parts of the structure becomes a very important factor in dosage selection Use of QUICKPHLO R Granules can eliminate the problem of non uniform gas concen trations Another advantage for using the granules is the ease of use and not having to reenter the treated structure by applica tors to apply additional fumigant as is
65. tion locations if the job involves entry into the structure for fumigation k Review labeling and Applicator s Manual In addition review the Operator s Manual for the QUICKPHLO R Phosphine Generator Exposure time considerations 1 Product granules to be used 2 Minimum fumigation period as defined and described in the use directions of the Applicator s Manual Down time required to be available Aeration requirements Cleanup requirements equipment and personnel needs if necessary Measured and recorded commodity temperature and moisture m Determination of dosage 1 Cubic footage or other appropriate space location calculations Structure sealing capability and methods Label recommendations Temperature humidity wind Commodity space volume Past history of fumigation of structure 7 Exposure time 3 4 5 6 oa W PY B PERSONNEL 1 Confirm in writing that all personnel in and around the struc ture to be fumigated have been notified prior to application of the fumigant Consider using a checklist that each employee initials indicating they have been notified Instruct all fumigation personnel to read the Applicator s Manual and about the hazards that may be encountered and about the selection of personal protection devices including detection equipment Confirm that all personnel are aware of and know how to pro ceed in case of an emergency situati
66. tructure is required to apply the fumigant only a certified applicator or trained person under the direct supervision of the certified applicator may operate the QUICKPHLO R Phosphine Generator The certified applicator is also responsible for disconnecting the generator at the end of generation and disposing of the spent granules safely and properly The QUICKPHLO R Phosphine Generator eliminates expo sures of phosphine to the applicator since the gas is generated internally in the equipment assembly and pumped into the struc ture through pipes Sealed aluminum foil pouches containing QUICKPHLO R Granules are opened one at a time to add the granules to the QUICKPHLO R Phosphine Generator The QUICKPHLO R Phosphine Generator is always positioned out side the storage structure to be treated Ensure that the QUICKPHLO R Phosphine Generator reaction unit is dry before addition of the QUICKPHLO R Granules QUICKPHLO R Granules must not be exposed to outside sources of water during addition to the QUICKPHLO R Phosphine Generator reaction unit Do not operate if the gener ator is likely to get wet in the rain and do not apply granules to the generator reaction unit in situations where rain condensate or outside sources of water can come in contact with the granules The residue left behind in the reaction unit consists of a slurry of aluminum hydroxide water and any remaining aluminum phos phide That residue is flushed with
67. uld be considered and close medical supervision is recommend ed Blood transfusions may be necessary 2 In case of manifest pulmonary edema venesection should be performed under vein pressure control Heart Glycosides I V in case of hemoconcentration venesection may result in shock On progressive edema of lungs immediate intuba tion is recommended with a constant removal of edema fluid and oxygen over pressure respiration as well as any meas ures required for shock treatment In case of kidney failure extra corporeal hemodialysis is necessary There is no spe cific antidote known for this poisoning 3 Mention should be made here of suicidal attempts by taking solid phosphide pesticides by the mouth After swallowing emptying of the stomach by vomiting flushing of the stomach with diluted potassium permanganate solution or a solution of magnesium peroxide is recommended until flushing liquid ceases to smell of carbide Thereafter apply carbomedicanalis PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER QUICKPHLO R Granules or dust can be fatal if swal lowed Do not get in eyes on skin or on clothing Do not eat drink or smoke while handling QUICKPHLO R Granules When a sealed container is opened allowing material to come in con tact with moisture water or acids toxic phosphine gas will be released If a garlic odor is detected under certain conditions refer to the section on Industria
68. use do not require exten sive training and are relatively rapid inexpensive and accurate Electronic devices are also available for both low level and high phosphine gas readings Such devices should be used in full compliance with manufacturers recommendations SECTION 12 NOTIFICATION REQUIREMENTS 12 1 AUTHORITIES AND ON SITE WORKERS As required by local regulations notify the appropriate local offi cials fire department police department etc of the impending fumigation Provide to the officials an Material Safety Data Sheet MSDS and an Applicator s Manual for the product and any other technical information deemed useful Offer to review this information with the local official s 12 2 INCIDENTS INVOLVING THESE PRODUCTS Registrants must be informed of any incident involving the use of this product Please call 1 800 438 6071 so United Phosphorus Inc can report the incident as per requirements of OSHA CFR 29 12 3 THEFT OF PRODUCTS Immediately report to the local police department about theft of QUICKPHLO R Granules SECTION 13 APPLICATOR AND WORKER EXPOSURE 13 1 EXPOSURE LIMITS Exposure to phosphine must not exceed the 8 hour Time Weighted Average TWA of 0 3 ppm or the 15 minute TWA short term exposure limit STEL of 1 0 ppm phosphine All persons are covered by these exposure standards 13 2 GENERATION OF PHOSPHINE USING THE QUICKPHLO R PHOSPHINE GENERATOR Since no entry into the fumigated s
69. ve been punctured or damaged so as to leak the container may be temporarily repaired with aluminum tape or the QUICKPHLO R Granules may be transferred from the damaged pouch to a sound metal container which should be sealed and properly labeled as QUICKPHLO R Granules Transport the damaged containers to an open area suitable for pesticide inspection and storage Caution The punctured pouches may flash upon opening at some later time FOR CHEMICAL EMERGENCY SPILL LEAK FIRE EXPOSURE OR ACCIDENT CALL CHEMTREC 1 800 424 9300 SECTION 2 DIRECTIONS FOR USE It is a violation of Federal Law to use this product in a manner inconsistent with its labeling General Information QUICKPHLO R Granules may only be used with the QUICKPHLO R Phosphine Generator to produce phosphine at the fumigation site The generator may only be operated by a certified applicator or by a person trained in han dling and using fumigants under his direct supervision and who has been further trained and certified by United Phosphorus Inc or its approved representatives RESTRICTIONS 1 Do not sell individual pouches 2 Do not remove pouches from the storage box until ready for fumigation 3 Use the entire contents of a pouch Do not leave any granules inside the pouch after opening 4 Unreacted and partially spent granules remaining in the gen erator may be disposed of according to the instructions in this Manual Disposal of Spe
70. y lights and unessential electric equipment STORAGE AND DISPOSAL Storage Instructions 1 Store QUICKPHLO R Granules in its original cardboard box Store only in cool dry locked and ventilated room Protect from moisture open flames or heat Post as a pesti cide storage area Do not contaminate water food or feed by storing pesticides in the same areas used to store these commodities 2 Do not store in buildings where humans or domestic animals reside Keep out of reach of children 3 QUICKPHLO R Granules are supplied in sealed aluminum foil pouches After opening do not expose the product to atmospheric moisture any longer than is necessary Pesticide Disposal Do not contaminate water food or feed by storage or disposal Unreacted or partially reacted QUICKPHLO R is acutely haz ardous Improper disposal of excess pesticide is a violation of Federal Law If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency or the Hazardous Waste repre sentative at the nearest EPA Regional Office for guidance For specific instructions see the Disposal Instructions and Spill and Leak Procedures sections of the Applicator s Manual Some local and state waste disposal regulations may vary therefore disposal procedures must be reviewed with appropri ate authorities to ensure compliance with these regulations Contact your state Pesticide o
71. you cannot read English do not use this product until the label has been fully explained to you e KEEP OUT OF REACH OF CHILDREN e DANGER PELIGRO POISON FOR CHEMICAL EMERGENCY SPILL LEAK FIRE EXPOSURE OR ACCIDENT CALL CHEMTREC 1 800 424 9300 EPA Reg No 70506 69 EPA Est No 41876 IND 001 Manufactured for U UPI UPI United Phosphorus Inc 630 Freedom Business Center Suite 402 King of Prussia PA 19406 1 800 438 6071 e www upi usa com Net Contents TABLE OF CONTENTS PAGE 1 FIRST AID PRECAUTIONARY STATEMENTS AND STORAGE AND DISPOSAL 4 2 DIRECTIONS FOR USE aio A eae he OE dda e cogent aisle da Bente ciate dalled 6 Se INTRODUCTION tis oc 8 dood wicca ii aia tad aoe be yo anda wih Mien cd A A Bae A ace ae 6 3 1 QUICKPHLO R Granules socera ida oia Pha iaa aa eld 6 3 2 QUICKPHLO R Phosphine Generator 0000 e EEE AE ene tenes 7 4 PESTS CONTROLLED cuco tow So toate the avatar tended a ee eee oak ee a de ted dey Aa dc 8 5 COMMODITIES WHICH MAY BE FUMIGATED WITH QUICKPHLO R GRANULES 8 5 1 Raw Agricultural Commodities Animal Feed and Feed Ingredients 2 0 00 e eee ee eee 8 5 2 Processed FdE srar csi os Geren A ees Ghee aE ede eo ewe ede bea A dees 9 5 3 Nonfood Commodities Including TOBACCO steane ete 9 6 EXPOSURE CONDITIONS 6 206456 eceierd rica ia ian pede iiie ia A Pee Lee ave ie 9 7 DOSAGE RATE GUIDELINES 50 5040 dies tat oc ee A ee da

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