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1.     Inhalation    Remove to fresh air  If not breathing  give artificial respiration  If  breathing is difficult  give oxygen  Call a physician    Ingestion    Induce vomiting immediately as directed by medical personnel  Never  give anything by mouth to an unconscious person  Get medical  attention    Skin Contact    Remove any contaminated clothing  Wash skin with soap and water  for    ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    at least 15 minutes  Get medical attention if irritation develops or  persists     Eye Contact    Immediately flush eyes with plenty of water for at least 15 minutes   lifting lower and upper eyelids occasionally  Get medical attention  immediately     Note to Physician    Give sodium bicarbonate intravenously to treat acidosis  Urinalysis  may show low specific gravity  proteinuria  pyuria  cylindruria   hematuria  calcium oxide  and hippuric acid crystals  Ethanol can be  used in antidotal treatment but monitor blood glucose when  administering ethanol because it can cause hypoglycemia  Consider  infusion of a diuretic such as mannitol to help prevent or control  brain edema and hemodialysis to remove ethylene glycol from  circulation     5  Fire Fighting Measures    Fire    Flash point  111C  232F  CC   Auto ignition temperature  398C  748F    Flammable limits in air   by volume    LEL  3 2  UEL  15
2.  3   Slight to moderate fire hazard when exposed to heat or flame   Explosion    Above flash point  vapor air mixtures are explosive within flammable  limits noted above  Containers may explode when involved in a fire   Fire Extinguishing Media    Dry chemical  foam or carbon dioxide  Water or foam may cause  frothing  Water spray may be used to extinguish surrounding fire and  cool exposed containers  Water spray will also reduce fume and  irritant gases    Special I nformation    In the event of a fire  wear full protective clothing and NIOSH   approved self contained breathing apparatus with full face piece  operated in the pressure demand or other positive pressure mode   Toxic gases and vapors may be released if involved in a fire     6  Accidental Release Measures  Ventilate area of leak or spill  Remove all sources of ignition  Wear    ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    appropriate personal protective equipment as specified in Section 8   Isolate hazard area  Keep unnecessary and unprotected personnel  from entering  Contain and recover liquid when possible  Use non   Sparking tools and equipment  Collect liquid in an appropriate  container or absorb with an inert material  e  g   vermiculite  dry  sand  earth   and place in a chemical waste container  Do not use  combustible materials  such as sawdust  Do not flu
3. ElectraCOOL LA550 Chiller July 2003    ElectraCOOL L A 550    ADVANCED THERMOELECTRIC    LA 550 AIRBORNE CHILLER       550 Watt Rack Mountable  Thermoelectric Chiller       ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    MSDS for Coolant  ETHYLENE GLYCOL    MSDS Number  E5125     Effective Date  02  25 99    1  Product I dentification    Synonyms  1 2 Ethanediol  glycol  1 2 Dihydroxyethane  Ethylene  Alcohol  Ethylene Dihydrate   CAS No   107 21 1   Molecular Weight  62 07   Chemical Formula  CH2OHCH2OH   Product Codes    J T  Baker  5387  5845  9140  9298  9300  9346  9349  9356  L715  Mallinckrodt  5001  5037    2  Composition  Information on Ingredients    Ingredient CAS No Percent Hazardous    Ethylene Glycol 107 21 1 99   100  Yes    3  Hazards I dentification  Emergency Overview    WARNING  HARMFUL OR FATAL IF SWALLOWED  HARMFUL IF  INHALED OR ABSORBED THROUGH SKIN  MAY CAUSE ALLERGIC  SKIN REACTION  MAY CAUSE IRRITATION TO SKIN  EYES  AND  RESPIRATORY TRACT  AFFECTS CENTRAL NERVOUS SYSTEM     J T  Baker SAF T DATA     Ratings  Provided here for your  convenience     Health Rating  2   Moderate   Flammability Rating  1   Slight   Reactivity Rating  1   Slight   Contact Rating  2   Moderate   Lab Protective Equip  GOGGLES  LAB COAT  VENT HOOD  PROPER  GLOVES    Storage Color Code  Orange  General Storage     ADVANCED THERMOELEC
4. TRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    Potential Health Effects   Inhalation    Vapor inhalation is generally not a problem unless heated or misted   Exposure to vapors over an extended time period has caused throat  irritation and headache  May cause nausea  vomiting  dizziness and  drowsiness  Pulmonary edema and central nervous system  depression may also develop  When heated or misted  has produced  rapid  involuntary eye movement and coma    Ingestion    Initial symptoms in massive dosage parallel alcohol intoxication   progressing to CNS depression  vomiting  headache  rapid respiratory  and heart rate  lowered blood pressure  stupor  collapse  and  unconsciousness with convulsions  Death from respiratory arrest or  cardiovascular collapse may follow  Lethal dose in humans  100 ml   3 4 ounces     Skin Contact    Minor skin irritation and penetration may occur    Eye Contact    Splashes may cause irritation  pain  eye damage    Chronic Exposure    Repeated small exposures by any route can cause severe kidney  problems  Brain damage may also occur  Skin allergy can develop   May damage the developing fetus    Aggravation of Pre existing Conditions    Persons with pre existing skin disorders  eye problems  or impaired  liver  kidney  or respiratory function may be more susceptible to the  effects of this substance     4  First Aid Measures
5. f  the information required by the CPR     16  Other Information    NFPA Ratings  Health  1 Flammability  1 Reactivity  0   Label Hazard Warning    WARNING  HARMFUL OR FATAL IF SWALLOWED  HARMFUL IF  INHALED OR ABSORBED THROUGH SKIN  MAY CAUSE ALLERGIC SKIN  REACTION  MAY CAUSE IRRITATION TO SKIN  EYES  AND  RESPIRATORY TRACT  AFFECTS CENTRAL NERVOUS SYSTEM    Label Precautions    Do not breathe vapor or mist    Use only with adequate ventilation    Keep container closed    Avoid contact with eyes  skin and clothing    Wash thoroughly after handling    Label First Aid    If inhaled  remove to fresh air  If not breathing  give artificial  respiration  If breathing is difficult  give oxygen  In case of contact   immediately flush skin or eyes with plenty of water for at least 15  minutes  Call a physician if irritation develops or persists  If  swallowed  give water or milk to drink and induce vomiting  Never  give anything by mouth to an unconscious person  In all cases call a  physician    Product Use    Laboratory Reagent    Revision Information    MSDS Section s  changed since last revision of document include  8   Disclaimer    2K 2K OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK OK KK  Mallinckrodt Baker  Inc  provides the information contained  herein in good faith but makes no representation as to its  comprehensiveness or accuracy  This document is intended only  a
6. ral disposal regulations  Dispose of container  and unused contents in accordance with federal  state and local  requirements     14  Transport Information  Not regulated     15  Regulatory Information            Chemical Inventory Status   Part 1                                      Ingredient TSCA EC Japan Australia  Ethylene Glycol  107  21 1  Yes Yes Yes Yes            Chemical Inventory Status   Part 2                                        Canada     Ingredient Korea DSL NDSL Phil   Ethylene Glycol  107  21 1  Yes Yes No Yes            Federal  State  amp  International Regulations   Part 1                     SARA 302         SARA 313        Ingredient RQ  TPQ List Chemical Catg   Ethylene Glycol  107  21 1  No No Yes No              Federal  State  amp  International Regulations   Part 2                    RCRA    TSCA   Ingredient CERCLA 261 33 8 d     Ethylene Glycol  107  21 1  5000 No No    Chemical Weapons Convention  No TSCA 12 b   No CDTA  No  SARA 311 312  Acute  Yes Chronic  Yes Fire  No Pressure  No  Reactivity  No  Pure   Liquid     Australian Hazchem Code  No information found    Poison Schedule  No information found    WHMIS    This MSDS has been prepared according to the hazard criteria of the    33  ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    Controlled Products Regulations  CPR  and the MSDS contains all o
7. ration specified by the appropriate regulatory  agency or respirator supplier  whichever is lowest  A full face piece  respirator with an organic vapor cartridge and particulate filter   NIOSH P100 or R100 filter  may be worn up to 50 times the  exposure limit  or the    maximum use concentration specified by the appropriate regulatory  agency or respirator supplier  whichever is lowest  Please note that N    ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    series filters are not recommended for this material  For emergencies  or instances where the exposure levels are not known  use a full face  piece positive pressure  air supplied respirator  WARNING  Air   purifying respirators do not protect workers in oxygen deficient  atmospheres     Skin Protection    Wear protective gloves and clean body covering clothing    Eye Protection    Use chemical safety goggles  Maintain eye wash fountain and quick   drench facilities in work area     9  Physical and Chemical Properties    Appearance    Clear oily liquid    Odor    Odorless    Solubility    Miscible in water    Specific Gravity    1 1  20C 4C   pH    No information found      Volatiles by volume   21C  70F    100   Boiling Point    197 6C  388F    Melting Point     13C  9F    Vapor Density  Air 1    2 14   Vapor Pressure  mm Hg    0 06   20C  68F   Evaporation Rate  BuAc 1    No info
8. rmation found     10  Stability and Reactivity    Stability   Stable under ordinary conditions of use and storage     Hazardous Decomposition Products    Carbon dioxide and carbon monoxide may form when heated to  decomposition  May produce acrid smoke and irritating fumes when  heated to decomposition    Hazardous Polymerization       gt  31  ADVANGED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    Will not occur    Incompatibilities    Strong oxidizing agents  Reacts violently with chlorosulfonic acid   oleum  sulfuric acid  and perchloric acid  Causes ignition at room  temperature with chromium trioxide  potassium permanganate and  sodium peroxide  causes ignition at 212F 100C  with ammonium  dichromate  silver chlorate  sodium chloride and uranyl nitrate   Conditions to Avoid    Heat  flames  ignition sources  water  absorbs readily  and  incompatibles     11  Toxicological I nformation    Toxicological Data    Oral rat LD50  4700 mg kg  skin rabbit LD50  9530 mg kg   Irritation   skin rabbit  555mg open   mild  eye rabbit  500mg 24H   mild    Investigated as a tumorigen  mutagen  and reproductive effector   Reproductive Toxicity    Has shown teratogenic effects in laboratory animals        NTP Carcinogen       Ingredient Known Anticipated IARC Category    Ethylene Glycol  107  21 1  No No None    12  Ecological   nformation    Environmen
9. s a guide to the appropriate precautionary handling of the  material by a properly trained person using this product   Individuals receiving the information must exercise their  independent judgment in determining its appropriateness for a  particular purpose  MALLINCKRODT BAKER  INC  MAKES NO  REPRESENTATIONS OR WARRANTIES  EI THER EXPRESS OR    IMPLIED  INCLUDING WITHOUT LIMITATION ANY WARRANTIES  OF MERCHANTABILITY  FITNESS FOR A PARTICULAR PURPOSE  WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR  THE PRODUCT TO WHICH THE INFORMATION REFERS   ACCORDINGLY  MALLINCKRODT BAKER  INC  WILL NOT BE    ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    RESPONSI BLE FOR DAMAGES RESULTING FROM USE OF OR  RELI ANCE UPON THIS INFORMATION     ADVANCED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    
10. sh to sewer  US  Regulations  CERCLA  require reporting spills and releases to soil   water and air in excess of reportable quantities  The toll free number  for the US Coast Guard National Response Center is  800  424 8802     7  Handling and Storage    Keep in a tightly closed container  stored in a cool  dry  ventilated  area  Protect against physical damage  Separate from acids and  oxidizing materials  Containers of this material may be hazardous  when empty since they retain product residues  vapors  liquid    observe all warnings and precautions listed for the product     8  Exposure Controls  Personal Protection    Airborne Exposure Limits     OSHA Permissible Exposure Limit  PEL     50 ppm Ceiling    ACGIH Threshold Limit Value  TLV     50 ppm Ceiling  vapor    Ventilation System    A system of local and or general exhaust Is recommended to keep  employee exposures below the Airborne Exposure Limits  Local  exhaust ventilation is generally preferred because it can control the  emissions of the contaminant at its source  preventing dispersion of  it into the general work area  Please refer to the ACGIH document   Industrial Ventilation  A Manual of Recommended Practices  most  recent edition  for details    Personal Respirators  NIOSH Approved     If the exposure limit is exceeded  a half face respirator with an  organic vapor cartridge and particulate filter  NIOSH type P95 or R95  filter  may be worn for up to ten times the exposure limit or the  maximum use concent
11. tal Fate    When released into the soil  this material is expected to readily  biodegrade  When released into the soil  this material is expected to  leach into groundwater  When released into the soil  this material is  not expected to evaporate significantly  When released into water   this material is expected to readily biodegrade  When released into  the water  this material is expected to have a half life between 1  and 10 days  This material is not expected to significantly  bioaccumulate  This material has a log octanol water partition  coefficient of less than 3 0  When released into water  this material  is not expected to evaporate    Significantly  When released into the air  this material is expected to  be readily degraded by reaction with photochemically produced  hydroxyl radicals  When released into the air  this material is  expected to have a half life between 1 and 10 days       gt  32  ADVANGED THERMOELECTRIC For Information Call    1 800 250 2920 electracool com    Nashua  NH 03062 USA international Inquiries  603  888 2467 rev 7 03    ElectraCOOL LA550 Chiller July 2003    Environmental Toxicity   The LC50 96 hour values for fish are over 100 mo l     13  Disposal Considerations    Whatever cannot be saved for recovery or recycling should be  managed in an appropriate and approved waste disposal facility   Processing  use or contamination of this product may change the  waste management options  State and local disposal regulations  may differ from fede
    
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