BATTERY INFORMATION SHEET
Contents
1. Battery Information Sheet Dry silver zinc oxide cells battery kits and battery systems According to REACH regulation EC 1907 2006 Art 31 and to OSHA regulation 29 CFR 1910 1200 batteries are ARTICLES with no intended release As such they are not covered by legal requirements to generate and supply an SDS or an MSDS This Battery Information Sheet is provided solely as an information document for the purpose of assisting our customers 1 IDENTIFICATION 1 1 Product Dry secondary silver zinc oxide cells battery kits systems and battery systems composed of these cells N B This document refers to dry silver zinc oxide cells as Ag ZnO gt For electrolyte risks please refer to the electrolyte security data sheet gt For wet cells please refer to specific recommendations from the supplier 1 2 Supplier Headquarters Saft S A S Address 12 rue Sadi Carnot 93170 BAGNOLET France Phone Fax Phone Fax 33 0 1 49 93 19 18 33 0 1 49 93 19 50 Factory Saft Poitiers Address Rue Geoges Leclanch BP n 1039 86060 POITIERS Cedex 9 France Phone Fax 33 0 5 49 55 48 48 33 0 5 49 55 48 50 1 3 Emergency contact Chemtrec US Service within the USA 1 800 424 93 00 outside 1 703 527 3887 2 HAZARD IDENTIFICATION 2 1 At cell level Not chemically dangerous with normal use in accordance with Saft recommendations as stated in the user manual or other similar documentation In particular the2. and water Seek immediate medical attention INHALATION Remove to fresh air and seek immediate medical attention INGESTION Clear mouth with water Do not induce vomiting Seek immediate medical attention 13 FIRE FIGHTING MEASURES not anticipated under normal use ESTINGUISHING MEDIA Use appropriate extinguishing media according to the type of fire In case of water use contaminated water had to be contained and avoid sewage surface water and underground water contamination SPECIAL FIRE FIGHTING PROCEDURES Fire fighters should wear self contained breathing apparatus Use approved certified vapour respirator to avoid breathing toxic fumes Wear protective clothing and equipment to prevent potential body contact with dust and fumes It is permissible to use any class of extinguishing medium specified above on these batteries or their packing material Cool exterior of batteries if exposed to fire to prevent rupture PARTICULAR HAZARDS RESULTING FROM EXPOSURE TO THE SUBSTANCE PREPARATION TO COMBUSTION AND GAS PRODUCTS Cells material combustion will produce fumes and dust containing toxic metal or metal oxide substances 14 EXPOSURE CONTROLS AND PERSONAL PROTECTION not necessary under normal use In case of incident fumes or dust formation use gas mask which covers the whole face and equipped with N100 or P3 type filters or escape mask type Self Contained Breathing Apparatus Fire fighters should wear self contained brea
3. battery should not be opened or burned Exposure to the ingredients contained within or their combustion products could be harmful EYE CONTACT Dust can cause inflammation of eyelids SKIN CONTACT Dust may cause irritation to skin Contains mercury oxide that can be lethal in case of skin absorption INHALATION Contents of an opened cell can cause respiratory tract and mucus membrane irritation nose and throat Contains mercury oxide that can be lethal by inhalation INGESTION Contains mercury oxide that can be lethal in case of ingestion ENVIRONMENTAL IMPACT Very toxic to aquatic life January 2014 Version 1 2 Dry silver zinc oxide cells battery kits systems and battery systems Page 1 GY Bis sart ass TEMPERATURE Do not place the batteries on or near fires or other high temperature locations gt 70 C 2 2 At module and battery system level For batteries issues see specific documentation provided by SAFT 3 COMPOSITION INFORMATION OR INGREDIENTS 3 1 At cell level Component CAS Number EINECS ELINCS Content wt Silver 7440 22 4 231 131 3 25 35 Negative active material N A N A 25 30 Comprising mercury oxide lt 0 5 Metallic and inert material N A N A 15 20 Non metallic material N A N A 15 30 Quantities may vary a little with cell model 3 2 At module and battery system level Depending on the type of battery system 4 HANDLING AND STORAGE IMPORTANT NOTICE The battery should n
4. in accordance with local regulations 16 OTHER INFORMATION This information has been compiled from sources considered to be dependable and is to the best of our knowledge and belief accurate and reliable as of the date compiled However neither exhaustively nor perfect reliability can be granted Information does not imply implicit or specific warranty of it This information relates to the specific products designated and may not be valid for such products used in combination with any other materials or in any process It is the user s responsibility to satisfy himself as to the suitability and completeness of this information for his particular use Saft does not accept liability for any loss or damage that may occur whether direct indirect incidental or consequential from the use of this battery information sheet provided as a service to our customers Saft does not offer warranty against patent infringement Sart Doc N BIS 02 10 12 Edition January 2014 12 rue Sadi Carnot Version 1 2 93170 Bagnolet France Tel 33 0 1 49 93 19 18 Data in this document is subject to Fax 33 0 1 49 93 19 69 change without notice and www saftbatteries com becomes contractual only after written confirmation January 2014 Version 1 2 Dry silver zinc oxide cells battery kits systems and battery systems Page 5
5. ot be opened without Saft approval destroyed or incinerated since the ingredients contained in the cells could be harmful under some circumstances if exposed STORAGE Store in a cool dry and ventilated area Elevated temperatures can result in shortened battery life Keep batteries in original packaging until use and do not jumble them HANDLING e Do not short or terminal with conductors conductive materials e Do not open the battery system or modules e Do not submit to excessive mechanical stress e Do not expose the unit to water or condensation e Do not directly heat solder or throw into fire Such unsuitable use can cause toxic fumes and dust 5 PHYSICAL AND CHEMICAL PROPERTIES The dry silver zinc oxide cell or battery described by this Battery Information Sheet is a sealed unit when offered for sale It is a manufactured article and does not expose the user to hazardous chemicals when used in accordance with manufacturer specifications Boiling Point Not applicable Melting Point Not applicable Vapor Pressure Not applicable Vapor Density Not applicable Specific Gravity Not applicable January 2014 Version 1 2 Dry silver zinc oxide cells battery kits systems and battery systems Page 2 Q a sart Saat 6 STABILITY AND REACTIVITY the battery system is stable when handled and stored according to section 4 MATERIALS TO AVOID Materials contained in these cells can reac
6. rs on the ground or into any body of water Disposal considerations See the section on Sustainability amp Environment on http www saftbatteries com 10 TRANSPORTATION INFORMATION Important Dry silver zinc cells are not classified under transportation regulation gt All information in this paragraph concerns the alkaline electrolyte For specific information concerning wet cells or batteries see SAFT transportation documentation 10 1 United Nations Class Transportation information for alkaline electrolyte only Class UN N UN2797 battery fluid alkali Hazard Classification 8 Packaging Group Il 10 2 International agreements Transportation information for alkaline electrolyte only By Air International IATA By Sea International IMDG European road transportation ADR road European rail transportation RID January 2014 Version 1 2 Dry silver zinc oxide cells battery kits systems and battery systems Page 3 SarT a 11 REGULATORY INFORMATION Marking Consideration European Union According to directive 2006 66 EC the batteries have to be marked with the crossed wheel bin symbol 12 FIRST AID MEASURES not anticipated under normal use EYE CONTACT Immediately flush with copious amount of water for more than 15 minutes Seek immediate medical attention SKIN CONTACT Remove contaminated clothing and flush affected areas with plenty of water for at least 15 minutes Wash skin with soap
7. t with various types of chemicals for example oxidizing agents acids bases reducing agents As a consequence active material contained in these cells will not be mixed or put in contact with any type of chemicals CONDITIONS TO AVOID Avoid exposing battery to fire or temperature gt 70 C Do not disassemble crush or short Avoid mechanical or electrical abuse HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition of the cell produces harmful and toxic fumes metals metal oxide and dusts 7 TOXICOLOGICAL INFORMATION Risk of irritation occurs only if the cell is mechanically thermally or electrically abused to the point of compromising the enclosure If this occurs irritation to the skin eyes and respiratory tract may occur Contains mercury oxide that can be lethal in case of inhalation ingestion or skin contact 8 ECOLOGICAL INFORMATION There is no ecological harm when cells are used correctly and recycled after use has ended In case of mechanical abuse of the cell container active material is very toxic to aquatic life acute and chronic toxicity Any contact with aquatic life must be avoided 9 DISPOSAL CONSIDERATIONS Battery recycling is either mandatory European Directive 2006 66 EC or recommended Batteries should be fully discharged prior to disposal and terminals protected Dispose in accordance with local laws and regulations Store material for disposal as indicated in Section 4 Do NOT dump into any sewe
8. thing apparatus Respiratory protection Hand Use polypropylene polyethylene rubber or Viton gloves when handling ruptured cells Take off gloves without being in contact with the polluted side Dispose all contaminated protections according to applicable regulation protection Wash hands after any handling Eye In case of incident or after an abusive use in case of a cell opening wear safety glasses with protected side protection shields or a mask covering the whole face when handling ruptured cells Other In the event of leakage or ruptured cells wear a rubber apron and protective clothes S030 AFNOR pictograms 15 ACCIDENTAL RELEASE MEASURES not anticipated under normal use INDIVIDUAL PRECAUTIONS Evacuate the employees from the contaminated area until fumes or dust dispersal Do not inhale fumes or dust without adequate respiratory protection In case of skin or eye contact inhalation or ingestion follow the measured described in section 12 January 2014 Version 1 2 Dry silver zinc oxide cells battery kits systems and battery systems Page 4 ENVIRONMENTAL PRECAUTION Avoid sewage surface water and underground water contamination Avoid ground and atmosphere contamination In case of water contamination alert competent authorities WAYS OF CLEANING Collect all material dispersed using appropriate personal protection store in appropriate waste packaging and dispose of as special waste
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