Home

Revised Site Investigation Work Plan

1. sss eene enne nennen 8 3 2 7 Surface Water Sampling ecese ei E E nennen tenen nennen nenne 8 3 3 Equipment Decontamination eese eene nne nnne nennen enne enne teen 8 3 4 Sample Preservation see ete te e EE IR Deere teer thes 9 3 5 Sample Identification eee ette e er Re Deer tese E Pets 9 3 6 Investigation Derived Waste enne nennen nne 10 3 7 Chain of Custody Procedures l tnnt ente ennnnns 10 ANALYTICAL TESTING PLAN erred E REI ERE ERE Se RS 11 4 1 Laboratory Testing Methodologies essere ener ener 11 4 2 Laboratory Reporting uu o P rrr RA REPORTER 11 FIELD DOCUMENTA TION there entem temen 12 DATA EVALUATIONS e utei tmt temet 12 6 1 XRF Screening Level Data u n teen rennen entente 12 6 2 Soil and Groundwater Data ene eterne retener nre 13 REPORT PREPARATION rtr RO Demi ene 13 REFERENCES SSS saam SSS oes eee ees ee 14 List of Figures Figure 1 Site Location Map Figure 2 Site Features and Anticipated Shot Fall Deposition Zones Current Configuration Figure 3 Historic Anticipated Shot Fall Deposition Zones Historic Configuration Figure 4 Combined Anticipated Shot Fall Zones Figure 5 Proposed Sample Location Plan List of Tables Table 1 Proposed Sample Location and Analytical
2. qaj co a 9 3 v a eaj Shaw shaw Environmental Inc DAILY FIELD REPORT Project Naperville Sportsman s Park Project No Client Date Weather Conditions Time Log Total Hours Completed By Page Personnel Company Hours On Site Equipment Vehicles On Site Supplies and Materials Used Work Description 80 6 AIA 0011 3780 Ag poalacoy OUILL ae Aq poysinburyay 011 g PARIA 11 Aq pousmbui os suononnsul er2edg pue s20N 2 emjejeduio 1928914 lost Ni 069 1 499W 0 peeN ON S8A u9204j 159 ON S94 juesejg 99 Os eInieJedue 101019BujoH uonoe oo Jo SJU ului peAreoeHg ON j s 988 683 peAle eg SiSuleluoO on SOA pereeBujeu ejdures 2s TON S A Os9 t 0 exnyeeduje 18 009 sas qeuy Ag pejdureg mure Xea tA 1100877 pues 800 9 Xe euoud drz eS Wu ISS IDDV SS Tauren 000500 sd jo ard 081000181 AGOLSND AO NIVHO AINO 3810 8 803 uae 1 0 WO O WASA IOS S9poo Od rq poid 6001 00018307100 1 U102 A19 S IIT 010917 BUH CLTT SLL 0 9 XEA Q0CT 8LL 9 0 ououq 9509 souy ojrardeN q ating peoy 310118 0091 SI
3. alierations or additions lo he pecmtted tb Anucipated noncomphance The permittee shall give advance nouce lo Ine Agency of any planned changes in ihe permired facility ar activity which riy result in noncomplianca wiih parmil requirements icl Compliance schedules Reports n compliance or noncomphance with or any progress reporis On intenm and requirements contained in any courmplinee schedute Si this permit shall b submitted no imiar than 14 days lollowmg scn schedule data tdi Monitoring reports Monitonng resulls shall be reporied at ha 4 alsawhera n thii permit 1 Monttoong tasults must De reported on z Orseharge Monionng Report OMA 2 If perenes momtors any pollutant more frequently than required by the permit using te31 proceduri approved under 40 CFR 136 or as specibed in the pemn tha rwaults of his moniionng shall ba meluded in tha calculation amd reporting of ihe data submulted in tha DMR ai Calculations jor all hmitauons which require averaging al massurements shall utile an anita mann undess otherwise by the Agency in ihe permit Twanty lour hour reporting The permites shall report any noncomphance when may endanger naallh or tha environment Any information shail be provided orally wihin 24 hours from the ume the Drerrruttoq becomes aware of the circumstances A ventien submrasion shall also ba provided within 5 days of the
4. tha permites becomes aware Di Ihe Greumsatances Th wnnen submission shall conten a dascnption of the noncompliance anc ns cause tha penod of noncompliance inciuding susci dares and ume and sf ihe noncomphance nas not been correcisad tha antcipated tone pecied ip continue and sisps taken or planned to reduce elimingte and prevent teoceurrenca of tha noncomplisnce The lollowing snail ba mcludad as information which must be reported writin 24 hours ni Any unan cipsled bypass which axceeds any affluent nmitaign in tha permit i21 Vicisuen ol a maximum daily discharge lmitabon for any al the poHutants bated by the Agency in tha perma i0 be raported 24 hours The Agancy mey waiva tha wnten report an a case by case Oasis l Ihe Oral report has been fecened within 24 hours 0 Other noncomphance The permites shall report all instances of Aencomplance not reported under paragraphs 12 c dl or le at ine uma rmamipnog reports are submirisd Tha reports shall conia the informauen heted in parsgrsph 11 2 Other information Where Ihe permiriee becomes aware thal Jaded 10 submi any reievant lacta in a perm pplicgstion or submilterd incprracit information m a permit applicatron or an any report io the Agency 1 shall prompily submit such lactis or information Transfer of permis A perm m y be automatically trans arred lo new partes l lal The currant parmirtee nonis ihe
5. 5 1 5 2 PURPOSE This procedure is intended to provide guidelines for the compositing of samples collected in the course of environmental program activities Composites represent the average distribution of properties and can be used to reduce analytical costs or represent well defined decision boundaries SCOPE This procedure applies to the compositing of solid and liquid samples where no project specific process is in place Field composite methods are not appropriate for Volatile Organic Compounds VOC analysis of solids Composites for these methods must be laboratory derived using either individual grab extracts or other laboratory methods REFERENCES U S Environmental Protection Agency 1987 Compendium of Superfund Field Operations Methods EPA 540 P 87 001a OSWER 9355 0 14 Washington DC Shaw E amp Standard Operating Procedure FS010 Sample Mixing Homogenization DEFINITIONS Composite Sample A sample that is comprised of roughly equal amounts of discrete grabs from a set of sample locations or time flow increments known as a sample group Sample Group A predetermined number or time area span of discrete samples which is composited into one sample for analytical purposes RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP sh
6. REFERENCES U S Environmental Protection Agency 1998 EPA Guidance for Quality Assurance Project Plans EPA 600 R 98 018 Washington D C U S Army Corps of Engineers 2001 Requirements for the Preparation of Sampling and Analysis Plans EM200 1 3 Washington D C DEFINITIONS None RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without exp
7. 7439 89 6 Manganese Mn 7439 96 5 Molybdenum Mo 7439 93 7 Potassium K 7440 09 7 Rubidium Rb 7440 17 7 Strontium Sr 7440 24 6 Thorium Th 7440 29 1 Titanium Ti 7440 32 6 Zirconium Zr 7440 67 7 1 2 This method is a screening method to be used with confirmatory analysis using other techniques e g flame atomic absorption spectrometry FLAA graphite furnance atomic absorption spectrometry GFAA inductively coupled plasma atomic emission spectrometry ICP AES or inductively coupled plasma mass spectrometry ICP MS This method s main strength is that it is a rapid field screening procedure The method s lower limits of detection are typically above the toxicity characteristic regulatory level for most RCRA analytes However when the obtainable values for precision accuracy and laboratory established sensitivity of this method meet project specific data quality objectives DQOs FPXRF is a fast powerful cost effective technology for site characterization 1 3 The method sensitivity or lower limit of detection depends on several factors including the analyte of interest the type of detector used the type of excitation source the strength of the excitation source count times used to irradiate the sample physical matrix effects chemical matrix effects and interelement spectral interferences Example lower limits of detection for analytes of interest in environmental applications are shown in Table 1 These limits app
8. PROPOSED SAMPLE LOCATION PLAN DIN REV NO DATE DESCRIP TION Tables TABLE 1 PROPOSED SAMPLING LOCATIONS AND ANALYTICAL SUITE Revised December 2011 C13 C15 C7 c 19 J m ER N N N N o 9 w 5 amp o UU c N U U U TT U Footnotes Small Arms Range Berm Sample Sediment Sample Location Sample Located in Anticipated Primary Shotfall Deposition Zone Present amp Historic Configuation Combined No sample collected from this interval XRF Screening for Total Lead no laboratory analysis XRF Screening Laboratory Analysis of Total Lead pH and moisture content and select TCLP metals based on total results XRF Screening Laboratory Analysis of RCRA 8 Total Metals Antimony Copper and Zinc select TCLP metals based on total results pH PNAs and moisture j i i f i il Laboratory Analysis of RCRA 8 Total Metals Antimony Copper and Zinc select TCLP metals based on total results pH PNAs and moisture Shaw shaw Environmental Inc Appendix A Regulator Documentation LAW OFFICES BROOKS TARULIS SCHAFFER amp TIBBLE LLC RICHARD J TARULIS 101 NORTH WASHINGTON STREET GERALD J BROOKS DAVID N SCHAFFER NAPERVILLE ILLINOIS 60540 4511 1937 2007 DOUGLAS C TIBBLE 630 355 2101 DAVID G WENTZ BRIAN D MOORE 630 355 7843 FAX OF COUNSEL September 20 2010 Mr Eric Shutes Naperville Park District
9. Page 2 of 2 5 2 Project Responsibility Shaw E amp employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw E amp employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records 6 PROCEDURE 6 1 Completing the Custody Seal Information All Custody Seals must be completed in indelible ink All corrections must be made using standard single line cross out methods and the initials of the individual making the change must be included beside the corrected entry Each Custody Seal attached must be completed by writing the Date at a minimum and signing with full signature by the person responsible for the sealing of the sample If a space is provided the Time should also be added 6 2 Attaching the Custody Seals Whenever possible custody seals should be attached over the sample container lids during actual sampling and not whe
10. The IEPA s approval of this Work Plan is requested No fieldwork will be performed until written confirmation of the IEPA s approval is received 1 14 Background Information The Site is managed by the NPD and owned by the City of Naperville The NPD leased the property in 1988 for a 99 year term Since 1948 Sportsman s Park utilization has included gun club activities which are conducted by the Naperville Sportsman s Club The Site is inclusive of approximately 27 acres of land and irregular in shape The Site is improved with three structures These include a club house for the Naperville Sportsman s Club a storage facility for Sportsman s Park and a seasonal storage facility for the NPD The balance of the Site includes a pond forested land a nature trail an access road and a parking lot Trap shooting activities are restricted to within the fenced area The site currently contains three trap stations Figure 2 illustrates the Site features A review of historic aerial photographs and the site reconnaissance indicate that a small arms i e rifle and pistol shooting area was located against an earthen berm on the northern side of the property Also the site historically hosted two additional trap stations The earthen berm and historic trap stations are depicted on Figure 3 The combined shot fall trajectories of the present and historical configurations are illustrated in Figure 4 The Site was previously enrolled in the SRP The por
11. a Further investigation or remedial action has been conducted that documents the attainment of objectives appropriate for the new land use and b A new Letter is obtained and recorded in accordance with Title XVII of the Act and regulations adopted thereunder OTHER TERMS 4 Further information regarding this remediation site can be obtained through a written request under the Freedom of Information Act 5 ILCS 140 to Illinois Environmental Protection Agency Attn Freedom of Information Act Officer Bureau of Land 224 1021 North Grand Avenue East P O Box 19276 Springfield IL 62794 9276 5 Pursuant to Section 58 10 f of the Act 415 ILCS 5 58 10 f should the Illinois EPA Page 3 seek to void this Letter the Illinois EPA shall provide notice to the current title holder and to the Remediation Applicant at the last known address The notice shall specify the cause for the voidance explain the provisions for appeal and describe the facts in support of this cause Specific acts or omissions that may result in the voidance of this Letter under Sections 58 10 e 1 7 of the Act 415 11005 5 58 10 e 1 7 include but shall not be limited to a b c d g h Any violation of institutional controls or the designated land use restrictions The failure to operate and maintain preventive or engineering controls or to comply with any applicable groundwater monitoring plan If applicable the disturba
12. are generally used for initial screening and hot spot delineation and longer measurement times up to 300 seconds are typically used to meet higher precision and accuracy requirements FPXRF instruments can be calibrated using the following methods internally using fundamental parameters determined by the manufacturer empirically based on site specific calibration standards SSCS or based on Compton peak ratios The Compton peak is produced by backscattering of the source radiation Some FPXRF instruments can be calibrated using multiple methods 3 0 DEFINITIONS 3 1 FPXHF Field portable x ray fluorescence 3 2 MCA Multichannel analyzer for measuring pulse amplitude 3 3 SSCS Site specific calibration standards 3 4 FP Fundamental parameter 3 5 ROI Region of interest 6200 4 Revision 0 February 2007 3 6 SRM Standard reference material a standard containing certified amounts of metals in soil or sediment 3 7 eV Electron volt a unit of energy equivalent to the amount of energy gained by an electron passing through a potential difference of one volt 3 8 Refer to Chapter One Chapter Three and the manufacturer s instructions for other definitions that may be relevant to this procedure 4 0 INTERFERENCES 4 1 The total method error for FPXRF analysis is defined as the square root of the sum of squares of both instrument precision and user or application related error Generally instrument precision is
13. concern at a given time and location Analytical results for representative samples reflect variations in the presence and concentration ranges of contaminants throughout a site Variables affecting sample representativeness include differences in soil type contaminant concentration variability sample collection and preparation variability and analytical variability all of which should be minimized as much as possible 4 9 Soil physical and chemical effects may be corrected using SSCS that have been analyzed by inductively coupled plasma ICP or atomic absorption AA methods However a major source of error can be introduced if these samples are not representative of the site or if the analytical error is large Another concern is the type of digestion procedure used to prepare the soil samples for the reference analysis Analytical results for the confirmatory method will vary depending on whether a partial digestion procedure such as Method 3050 or a total digestion procedure such as Method 3052 is used It is known that depending on the nature of the soil or sediment Method 3050 will achieve differing extraction efficiencies for different analytes of interest The confirmatory method should meet the project specific data quality objectives DQOs XRF measures the total concentration of an element therefore to achieve the greatest comparability of this method with the reference method reduced bias a total digestion procedure should b
14. has been homogenized it is examined under an ultraviolet light to assess the distribution of sodium fluorescein throughout the sample If the fluorescent dye is evenly distributed in the sample homogenization is considered complete if the dye is not evenly distributed mixing should continue until the sample has been thoroughly homogenized During the study conducted to provide data for this method the time necessary for homogenization procedure using the fluorescein dye ranged from 3 to 5 min per sample As demonstrated in Secs 13 5 and 13 7 homogenization has the greatest impact on the reduction of sampling variability It produces little or no contamination Often the direct analysis through the plastic bag is possible without the more labor intensive steps of drying grinding and sieving given in Secs 11 5 and 11 6 Of course to achieve the best data quality possible all four steps should be followed 11 5 Once the soil or sediment sample has been homogenized it should be dried This can be accomplished with a toaster oven or convection oven A small aliquot of the sample 20 to 50 g is placed in a suitable container for drying The sample should be dried for 2 to 4 hr in the convection or toaster oven at a temperature not greater than 150 C Samples may also be air dried under ambient temperature conditions using a 10 to 20 0 portion Regardless of what drying mechanism is used the drying process is considered complete when a constant s
15. or Teflon Certain types of solid matrices may not be amenable to mixing using conventional techniques For example certain solids may require grinding and thorough mixing to ensure that the analytes of interest within the sample are homogeneously distributed It is extremely important that soil and sediment samples be homogenized to ensure that the entire sample is as representative as possible of the media being sampled 6 1 Solid Samples The following two methods are examples for homogenizing solid samples Other homogenization techniques may be employed using approved standard methods such as ASTM C702 Reducing Samples of Aggregate to Testing Size 6 1 1 Quartering Place the sample on a hard clean level surface such as a pan If such a surface is too small for the desired quantity a clean sheet of plastic may be used Mix the solid material by turning the entire quantity over three times with a trowel or shovel For the third time shovel the material into a cone shaped pile Carefully press down on the apex of the pile to create a soil layer of uniform thickness and diameter Divide the material in the sample pan or on the plastic into quarters Option 1 Mix each quarter individually Then mix two quarters to form halves Mix each formed half and then fill the appropriate sample jars containers Option 2 Remove two diagonally opposite quarters including any fine material Mix the remaining material build it into a
16. 1 If confined to one Surrogate ina fraction Data is acceptable 2 If surrogate R values are at least 80 of acceptance lirrits Data is acceptable If any Surrogate 94a is greater than 110 of acceptance limt Data is unacceptable Procedure No EI FS020 Attachment No 1 Result Within 10 0f or Above Result Greater than 1076 Above Actiondevd 1 If confined to one Surrogate in a fraction Data is acceptable 2 If surrogate YR values are at least 80 of acceptance limits Data is acceptable 1 If confined to one Surrogate in a fraction Data is acceptable 2 If surrogate YR values are within 20 of acceptance lirrits Data is acceptable Procedure No EI FS101 Revision No 1 Date of Revision 9 11 06 Shaw shaw Page 10f3 STANDARD OPERATI NG PROCEDURE Subject Trowel Spoon Surface Soil Sampling 5 1 5 2 PURPOSE The purpose of this document is to provide the methods and procedure for sampling of surface Soils using trowels or spoons Trowels or spoons can be used when matrices are composed of relatively soft and non cemented formations and to depths of up to 12 inches into the ground surface dependent on site conditions Samples for Volatile Organic Compound VOC analysis should not be collected via trowel or spoon method However a trowel or spoon may be utilized to penetrate to and expose the undisturbed material at the desired depth for sampling by more applicable methods SCOPE This procedure
17. 16052 as Amended DI E ei me Agency means the lllingis Envir nmental Protection Agency Board means Ine nois Po utrari Control Board Crean Water Act lormesty relercad 10 as ihe Federal Water Pollution Control Act means Pub L 92 500 as amended 33 USC 1251 seq NPDES Navona Pollutent Discharge Eurrinatron System maans the national program for ISSUING modifying 6 and ressumng terrmanating monronng and enforcing permits and mposirg and enforcing pretrealmant requirements under Sections 307 402 J18 and 405 af the Clan Water Act USEPA means the United States Environmental Protection Agency Daily Diacharge means the discharges of a pollutant measured dunng a calandar day or any 24 hour panod ihal ressanabiy represents ine calendar day lor purposes Of sampling For Pollutants with fimtevons enpressed in units of mass the daily discharge ig calculated as ihe tofali mass of the polluiant discharged over the day For pollutants with limitanona ezpressed n other units of measurements the dey discharge is calculated as the average of ibe pollutant over ha day Maximum Daily Discharge Limitation tdady maximum masns Ihe highest sl owatia asy discharpa Average Monthly Discharge Limitation 20 day aversgal means he highest allowable average of daily discharges over a calendar month calculsied as the sum of al gaily rcharges measured dunng a calendar month divided by tho number of
18. 294 40 Cu 627 4 81 98 6 114 2950 lt 45 Cd Y 1944 NY NJ Sediment 424 50 Zn 656 350 352 438 6952 35 Cd Y 2782 Ind Sludge 34 70 Zn 1254 350 352 438 6952 35 Cd Y 2781 Dom Sludge 294 40 Zn 1273 350 352 438 6952 35 Cd Y 2780 Hard Rock 315 50 Zn 2570 350 352 438 6952 35 Cd X 2587 Tr Elem in SoillLBP 266 55 Pb 3242 15 6 161 432 1162 5532 15 Cd Y 1648 Urban PM 218 2 Zn 4760 350 352 438 6952 35 Cd Y 2709 San J Soil 27 50 As 17 7 22 23 4 105 626 1550 20 Cd 0 2709 San J Soil 27 50 Pb 18 9 15 6 161 432 1162 5532 15 Cd O 1944 NY NJ Sediment 424 50 As 18 9 22 23 4 105 626 1550 20 Cd O 2780 Hard Rock 35 50 Ag 27 J 35 3 2710 9 Am O 1648 Urban PM 218 2 Sb 45 J 38 4 2710 45 Am O 1944 NY NJ Sediment 424 50 Ni 76 1 75 2586 lt 65 Cd O 1648 Urban PM 218 2 As 115 22 23 4 105 626 1550 20 Cd O 2702 Marine Sediment 318 50 Cu 117 7 81 98 6 114 2950 lt 45 Cd O 2702 Marine Sediment 318 50 Pb 132 8 15 6 161 432 1162 5532 lt 15 Cd O 2782 Ind Sludge 34 70 As 166 22 23 4 105 626 1550 20 Cd O 1944 NY NJ Sediment 424 50 Cr 266 301 2586 lt 300 Cd O 1944 NY NJ Sediment 424 50 Pb 330 15 6 161 432 1162 5532 15 Cd O 2587 Tr Elem in Soil LBP 266 55 Zn 335 8 350 352 438 6952 lt 35 Cd O 2702 Marine Sediment 318 50 Cr 352 301 2586 lt 300 Cd O 2702 Marine Sediment 318
19. 320 West Jackson Avenue Naperville Illinois 60540 Re Sportsman s Park Dear Eric Enclosed is correspondence received at our office regarding the above referenced matter Very truly yours BROOKS TARULIS SCHAFFER amp TIBBLE LLC DCT lgh Enc lt ILLINOIS ENVIRONMENTAL PROTECTION AGENCY 1021 North Grand Avenue Fast P O Box 19276 Springfield Illinois 62794 9276 s 217 782 2820 James R Thompson Center 100 West Randolph Suite 11 400 Chicago IL 60601 312 814 6026 PAT QUINN GOVERNOR Douctas P SCOTT DIRECTOR 217 782 0610 September 16 2010 Naperville Park District 320 West Jackson Avenue Naperville Illinois 60540 Re Naperville Park District Sportsman s Park NPDES Permit No 110073253 Final Permit Gentlemen Attached is the final NPDES Permit for your discharge The Permit as issued covers discharge limitations monitoring and reporting requirements Failure to meet any portion of the Permit could result in civil and or criminal penalties The Illinois Environmental Protection Agency is ready and willing to assist you in interpreting any of the conditions of the Permit as they relate specifically to your discharge The following changes have been made since the public notice of your permit The permittee address has been changed to the address indicated in your August 19 letter The statement in Special Condition 4 pertaining to how to fill out the DMR form when there is no discharge has been
20. 50 Zn 485 3 350 352 438 6952 lt 35 Cd O 2782 Ind Sludge 34 70 Cu 2594 81 98 6 114 2950 45 Cd O 2780 Hard Rock 35 50 Pb 5770 15 6 161 432 1162 5532 15 Cd 0 1648 Urban PM 218 2 Pb 6550 15 6 161 432 1162 5532 15 Cd O 2780 Hard Rock 35 50 Hg 1U 32 6 140 lt 30 Cd N 2587 Tr Elem in Soil LBP 266 55 Hg 1U 32 6 140 lt 30 Cd N 2702 Marine Sediment 318 50 Cd 1U 41 7 2711 lt 50 Am N 2702 Marine Sediment 318 50 Hg 1U 32 6 140 lt 30 Cd N 2702 Marine Sediment 318 50 Ag 1 35 3 2710 lt 9 Am N 2709 San J Soil 2 1 50 Cd 1U 41 7 2711 50 Am N 2709 San J Soil 27 50 Ag 1U 35 3 2710 9 Am N 2782 Ind Sludge 34 70 Hg 14 32 6 140 30 Cd N 2709 San J Soil 271 50 Hg 1 4 32 6 140 30 Cd N 2587 Tr Elem in Soil LBP 266 55 Cd 1 92 41 7 2711 50 Am N 1944 NY NJ Sediment 424 50 Hg 3 4 32 6 140 30 Cd N 2781 Dom Sludge 294 40 Hg 3 64 32 6 140 30 Cd N 2782 Ind Sludge 341 70 Cd 4 17 41 7 2711 lt 50 Am N 1944 NY NJ Sediment 424 50 Sb 5J 38 4 2710 lt 45 Am N 2702 Marine Sediment 318 50 Sb 5 6 38 4 2710 45 Am N Page 1 of 1 EI FS200 2 1 Shaw shaw XRF Calibration Form Project No Add Number 1 Initial Calibration Data Is XRF warm up gt 15 min Yes No Internal calibration complete Record energy resolution 2 Start of Day Calibration Sources Used check allthat apply FS200 1
21. Attachment B Figure 5 shows the proposed soil sampling locations field screening locations sediment surface water and groundwater sampling locations 3 2 1 Surface Near Surface Soil Sampling Previous investigations have indicated that the impact from historic shooting activities is located in the upper soil horizon Accordingly this Site Investigation will emphasize characterization of this interval Surface and near surface soil samples will be obtained at the trapshooting range area on both sides of the existing site channel at the former small arms shooting range impact berm face and floor areas and the remaining areas on the Sportsman s Park property within the facility s fenced boundary Grid methodology will be utilized to determine sample location Approximately 267 soil samples will be collected from within the existing and former shooting range areas N 3 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois e Surface and near surface soil samples will typically be collected on 100 foot spacing across a proposed grid sampling system Proposed sample IDs locations and analytical suites are summarized on Table 1 and are also depicted on Figure 5 e Surface near surface soil samples will be obtained at depths representative of 0 6 inches 6 12 inches and 12 18 inches below the existing ground surface elevations utilizing either a stainless steel sampling trowel hand spade and or hand auger m
22. EPA rules and guidelines pene n me eme AX Clubhouse POSIT nm i es m 9 p arase ee EAE n ll Sportsman s Fenc Naperville Park District g l Api dee r 17777 s O D v gt 2 DP A TT TLL ima QE UN NF ehh fed Mv da z weil Park District Structures Vater Sportsman s Park and Surrounding Scale 1 400 Area without Aerial Photo Naperville Park District Planning Team 400 0 400 800 Feet August 28 1998 a Appendix B Example Shaw Field Data Collection Forms AN Soil Sediment Field Logsheet Shaw shaw Site Name Project Sample Location Sketch SED Sediment SUR Surface soil SUB Subsurface Soil OTH Other grab Grab comp Composite Depth ft bgs Physical description Analyses requested Photograph Log O2 LEL Calibration Date Equipment Decontamination Technique QC Samples Analytical Laboratory Field Technician Print Date Jeu siu eyeorpur ey qeue jeujoue Jo ilU uBiu e s eJeui J 75070 91e ejduues ui ejqisi eje s1 Bue1 e o sie ing J eave dn ying u pejdures J 1919e1euo ajdwes ayeoipul 8 MOJ JU8UJUJOZ TSOJON PI Id Jeuornippyv o e
23. P CBs P esticides Organic Bases 196 nitric acid Hexane followed by Isopropyl Alcohol Isopropyl Alcohol Organic Acids Trace Metals and Radio Isotopes 196 nitric acid 1096 Nitric acid Trace metals grade Isopropyl Alcohol Cations Anions Acidic Compounds Basic Compounds caustic 196 nitric acid 1 All organic solvents must be Pesticide Grade or better The selection of appropriate solvent rinses should first consider if a known or suspected contaminant requires removal from sampling equipment Secondly identify whether the subsequent analytical protocol would be impacted by the proposed solvent or an impurity thereof e g residual acetone present in isopropyl alcohol would be measured with certain volatile organics analysis 2 Organic bases include amines hydrazines 3 Organic acids include phenols thiols nitro and sulfonic compounds 4 Usea grade of water appropriate to the application For trace level analysis this must be Analyte Free Water For non trace applications store bought distilled water is sufficient Adapted from Appendix E Requirements for the Preparation of Sampling and Analysis Plans EM 200 1 3 February 2001 US Army Corp of Engineers Washington D C Page 1 of 1 Revision 1 3 2006 Procedure No EI FS020 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 1of4 STANDARD OPERATI NG PROCEDURE Subject Data U
24. Revision 0 February 2007 11 2 Each FPXRF instrument should be operated according to the manufacturer s recommendations There are two modes in which FPXRF instruments can be operated in situ and intrusive The in situ mode involves analysis of an undisturbed soil sediment or sample Intrusive analysis involves collection and preparation of a soil or sediment sample before analysis Some FPXRF instruments can operate in both modes of analysis while others are designed to operate in only one mode The two modes of analysis are discussed below 11 3 For in situ analysis remove any large or nonrepresentative debris from the soil surface before analysis This debris includes rocks pebbles leaves vegetation roots and concrete Also the soil surface must be as smooth as possible so that the probe window will have good contact with the surface This may require some leveling of the surface with a stainless steel trowel During the study conducted to provide example performance data for this method this modest amount of sample preparation was found to take less than 5 min per sample location The last requirement is that the soil or sediment not be saturated with water Manufacturers state that their FPXRF instruments will perform adequately for soils with moisture contents of 5 to 20 percent but will not perform well for saturated soils especially if ponded water exists on the surface Another recommended technique for in situ analysis is to tamp the
25. Shaw Shaw Page 2 of 4 5 1 5 2 Standard Reference Material SRM An environmental matrix material containing a known and traceable concentration of analyte s usually traceable to the National Institute of Standards and Testing NIST It is used to verify analytical accuracy of the system Site Specific Calibration A calibration process which uses samples from the site itself to develop a calibration curve Each sample is analyzed by a Definitive method SW 846 to establish the true value Site specific calibrations factor in the effect of the site matrix on results and provide better comparison to Definitive data At least one of the standards should be at a concentration near the site action level s Sample Cup A small plastic or PFE container designed to hold a prepared soil sample and introduce it to the instrument Sample cups are usually covered with a clear film Mylar which is secured using a plastic ring RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also
26. Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS001 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 3of5 6 4 Operation The following requirements must be met when using a field logbook Record significant details and or events work observations material quantities calculations drawings and related information directly in the field logbook If data collection forms are in use the information on the form need not be duplicated in the field logbook However any forms used to record site information must be referenced in the field logbook Information must be factual and unbiased Do not start a new page until the previous one is full or has been marked with a single diagonal line so that additional entries cannot be made Use both sides of each page Write in black or dark blue indelible ink Do not erase scribble over or blot out any entry Do not use White Out or like correction items Before an entry has been signed and dated changes may be made however care must be taken not to obliterate what was written originally Indicate any deletion by a single line through the material to be deleted Any change shall be initialed and dated Error codes Attachment 1 should be added to the end of the deleted entry All error code
27. Shiffler s Subdivision to the point of beginning in the City of Naperville DuPage County Illinois 7 88 acres 2 Common Address N A 3 Remediation Site Owner City of Naperville 4 Land Use Limitation Residential 5 Site Investigation Focused See NFR letter for other terms PROPERTY OWNER CERTIFICATION OF NFR LETTER UNDER THE SITE REMEDIATION PROGRAM If the Remediation Applicant is not the sole owner of the remediation site include the full legal name title the company the street address the city the state the ZIP code and the telephone number of all other property owners Include the site name street address city ZIP code county Illinois Inventory I D number and real estate tax index parcel index number The property owner s or the duly authorized agent of the owner s must certify by original signature the statement appearing below A duly authorized agent means a person who is authorized by written consent or by law to act on behalf of a property owner including but not limited to l For corporations a principal executive officer of at least the level of vice president 2 For a sole proprietorship or partnership the proprietor or a general partner respectively and 3 For a municipality state or other public agency the head of the agency or ranking elected official For multiple property owners attach additional sheets containing the information described above along with a signed dated certification
28. Site 2 0 SCOPE OF WORK 2 1 Site Investigation Objectives Shaw proposes to perform Site investigations to evaluate and characterize the Site in accordance with the requirements of the IEPA SRP with a goal of obtaining a Focused NFR letter for the balance of the Site areas not previously covered by the IEPA issued Focused NFR letter s It is noted that the 1998 issued IEPA NFR letters only cover portions of the adjoining property parcels and the Sportsman s Park property beyond the existing fence line boundaries therefore this investigation will be focused to the interior areas bounded by the existing Site fencing not currently covered by the 1998 NFR determination The objective of this Work Plan is to convey the methods and rationale associated with performing the proposed data collection activities In general this Site Investigation will consist of the following tasks Data Collection soil sediment surface water and groundwater sampling Analytical Testing Data Evaluation and Report Preparation 2 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois Detailed discussions of these tasks are presented in the following sections of this Work Plan 3 0 FIELD INVESTIGATIONS 3 1 Data Collection Data collection activities will be performed by Shaw professionals who are trained in accordance with Occupational Safety and Health Administration OSHA standard 29 CFR 1910 120 Hazardo
29. The 18 SRMs included 9 soil SRMs 4 stream or river sediment SRMs 2 sludge SRMs and 3 ash SRMs Each of the SRMs contained known concentrations of certain target analytes A percent recovery was calculated for each analyte in each SRM for each FPXRF instrument Table 6 presents a summary of this data With the exception of cadmium chromium and nickel the values presented in Table 6 were generated from the 13 soil and sediment SRMs only The 2 sludge and 3 ash SRMs were included for cadmium chromium and nickel because of the low or nondetectable concentrations of these three analytes in the soil and sediment SRMs Only 12 analytes are presented in Table 6 These are the analytes that are of environmental concern and provided a significant number of detections in the SRMs for an accuracy assessment No data is presented for the X MET 920 with the gas filled proportional detector This FPXRF instrument was calibrated empirically using site specific soil samples The percent recovery values from this instrument were very sporadic and the data did not lend itself to presentation in Table 6 Table 7 provides a more detailed summary of accuracy data for one particular FPXRF instrument TN 9000 for the 9 soil SRMs and 4 sediment SRMs These data are provided for guidance purposes only Table 7 shows the certified value measured value and percent recovery for five analytes These analytes were chosen because they are of environmental concern and were m
30. WP Wipe Samples LIQ Other Liquid SOL Other Solid AS Air Sample SED Sediment Shaw Shaw E amp FS003 1 0 Shaw E amp I COC Continuation Page COC Ref Document Page of Project Number Shipment Date Project Name Location Collection Information Sample ID Number Sample Description Dae Time GC 2 Turn Around Time Requested Container Page 2 of 2 Procedure No EI FS005 Revision No 1 Date of Revision 9 8 06 Shaw Shaw Page 10f2 STANDARD OPERATI NG PROCEDURE Subject Custody Seals 5 1 PURPOSE The purpose of this procedure is to provide the requirements for completion and attachment of Custody Seals on environmental samples and shipping containers SCOPE This procedure is applicable to all Shaw E amp efforts where sample legal defensibility and custody integrity is desired Adherence to this procedure is not required whenever the same individual team is performing the sampling and testing within the same workday and transfer to the testing process is being documented by other means i e sampling and then field screening in a mobile laboratory REFERENCES U S Environmental Protection Agency 1986 Test Methods for Evaluating Solid Waste Physical Chemical Methods SW 846 Third Edition U S Army Corps of Engineers Requirements for the Preparation of Sampling and Analysis Plans EM200 1 3 Shaw E amp l 2002 Sampler s Tr
31. XRF clock Agree Yes Source Strength Blank SiO2 Count Moderate Lead NIST 2711 Count sec Conc m Element Certified Detected Element RPD Accept Conc ppm Certified Detected Low Lead NIST 2586 Count H igh Lead NIST 2710 Count Conc ppm Element Certified Detected Element Conc ppm Certified Detected Pb 432 Ho c35 Cr 301 Comments Not a NIST certified valu 290328 Form Completed by Cre 300 Signature Page 1 of 1 Y Shaw shaw XRF Laboratory Sample Results Form FS200 2_0 Site Name City State Project No Add Number Contract Title Client Name Cost Code Add Number 1 General Sample Location and Identification circleone Floor Sidewall Other it other describe Sample Loc Description to location itype excavation depth tt Location comments Sample Associated QC Number 2 Sample Preparation Check all that apply pan prep Temp Cfor 10 2 rn Sample Prep Comments Tat Observed 3 Analytical Results all units are ppm Source s Cd 109 count Measurement Date Fe 55 count NA sec Time Am 241 count NIA sec Original Analysis Dup Analysis RPD Comm
32. amp 7470A e PNAs USEPA Methods 3510 8270C Surface Water Analytical e Total Metals RCRA 8 List plus Antimony Copper and Zinc via USEPA Method 6010B 3010A 4 2 Laboratory Reporting All laboratory analytical results will be reported according to EPA method protocols Copies of the laboratory reports will be appended to the final report for the project 11 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois 5 0 FIELD DOCUMENTATION Summaries of the daily field activities will be recorded by the Shaw field scientist in a bound waterproof field logbook or on Daily Field Report forms All daily field activities will be documented in indelible ink in the logbook or on the forms and no erasures will be made All corrections will consist of a single line out deletion followed by the sampler s initials and the date Detailed information to be recorded in the logbook or on the forms will include Date of Field Activity Weather Conditions Project Name and Location Name of Shaw Field Scientist Name of Contractor Personnel e g Drillers Sample number as previously described Location of sample including station name GPS and or grid coordinates Sample type i e surface soil subsurface soil composite etc Sample material description Description of the sample moisture content of soil dry moist or wet Unique sample tag number Written Summary of Daily Activities listed
33. analytical system Surrogate Compound n several organic methods a compound similar in structure and chemical behavior to the target analytes which is added to each Sample and QC Sample at a known concentration before the analysis begins The surrogate recovery is used to approximate the recovery of the target compounds based upon the behavior of chemically similar analytes Post digest Spike in metals analyses used to determine the possibility of chemical interferences and digestion deficiencies If the normal QC results are unacceptable a known concentration of the target analyte is added to the sample digestate The recovery is then used to determine if reanalysis or data qualification is warranted QC Acceptance Range The limits that define QC results demonstrating compliant accuracy and precision Qualified Person An individual capable through knowledge education formal training and or experience in the establishment and verification of analytical Data Quality Objectives The This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS020 Revision No 1 Date of Revision 9 8 06 Shaw shaw E amp I Page 3 of 4 5 1 5 2 6 1 6 2 Qualified Person is usually a chemist or environmenta
34. and aniry pursuant to Section 308 of ihe Clean Water Aci If an sbphicable standard of hmilat on 3 premulgeted under Section 301 IIDC and DI 304 bii2 or 307 2 and that affluent standard or is mora strngent then any affluent raton in ihe permit or contro a poliutant noi brute in ihe parri the permu shall be prompuy 5 or revoked and resad lO conlorm to that effluent standard or Any muthonzsmon ta construct ieued to tha permitea pursuant to 35 tll Adm Code 303 154 s heraby incorponied Dy reference am m Condition of 15 8 permit The perrmiries shbll noi maka any lalsa staternent representanon or cermficabon in ary upobcation recor report Pian or oher document submitted ID Ihe Agency or Ihe USEPA or required to ba marntained under ius permet The Clason Waler Act provides that any person who violate a permit 5 irpiernantig Sections 301 302 305 307 308 318 or 405 of the Clean Water Act im subpect TO a civil panaity nat to exceed 310 000 per day of such violanan Amy person who or neghganthy violates permit candrians mplamaning Sections 301 302 306 307 or 308 of iha Clean Veter Aci is subraci lo a f na af not less Ihan 2 500 nor more than 25 000 par day of violauon of by urgpnaonment for nol mora ihan one year of bolh The Claan Water Act provides that any parson who falsilies tampers with or knowmQgly renders inaccurate
35. any moniionng Oevice Gr meihod required 10 bs rnmntained under permit shall upon coreiciion be punished by a fine of not more than 10 000 per violapon of by imprisonment for nol mors han 6 months per v la ton or by both The Clas Water Act provides thet any person who knovemgry makes any faise slemeni rapresenis ion Or certhcation wt gny tuCOf or other documeni submitied or required to be mentgoed under this permit shail including rnorutorrm iepoms or reports ol compliance oF non compl arnce shall upon comnciion ba pumshed by s fine of not more than 10 000 per violation or by umpraonment lor not mora than B months per violation or by both Collected screereng suxipes and other solidis shall be Guspossd o in such a mermer as to prevent entry of those wastes ior runoff trom the wastes into waters of the Stata The proper suthonzstion for such disposal shall ba obtained from the Agency and ia incorporated as part hereat by reference In case of confhcl between these atandard condirions and ary other condiponis inpiaded m tha permit the other condrionis shall govern The permite shall compy wilh in addon to ihe requirens ol ihe perm ali appbcabie provisions of 35 Ill Adm Code Subote C Subite D 5 E anc all apphcabis orders of ihe Board The provipons of this parmi ara severable and i any pyrervrsson of this pemn or Iw Bpphcaneon of any proven of the permi is heid reshd ihe remaning provivone
36. appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records 6 PROCEDURE The sampling procedure is as follows 1 Assemble the sampler by inserting the appropriate sample tube and close the ends If using extension rods attach the sampler by its top to the bottom rod Attach the T handle either to the extension rod or directly to the sampler head 2 If desired place plastic sheeting around the targeted location to keep sampled material in place Use a knife to cut an access hole for the sample location 3 Don a pair of clean sample gloves 4 Remove any surficial debris e g vegetation rocks twigs from the sample location and surrounding area 5 If the sample will be collected from a depth beyond the surface use a hand auger to remove the overburden and expose the target sample depth Measure the depth of the hole with a rule or stiff tape to confirm that the target depth has been reached 6 If the sampling depth is below where the sampling device can be seen while sampling measure the distance from the tip to top of the sampler and mark the extension rod at this distance plus the depth of the hole with tape as a reference 7 Change sample gloves just prior to collecting the sample especially i
37. calculated for samples with Pb As ratios of 10 1 or more This high ratio of Pb to As may result in reporting of a nondetect or a less than value e g 300 ppm for As regardless of the actual concentration present No instrument can fully compensate for this interference It is important for an operator to understand this limitation of FPXRF instruments and consult with the manufacturer of the FPXRF instrument to evaluate options to minimize this limitation The operator s decision will be based on action levels for metals in soil established for the site matrix effects capabilities of the instrument data quality objectives and the ratio of lead to arsenic known to be present at the site If a site is encountered that contains lead at concentrations greater than ten times the concentration of arsenic it is advisable that all critical soil samples be sent off site for confirmatory analysis using other techniques e g flame atomic absorption spectrometry FLAA graphite furnance atomic absorption spectrometry GFAA inductively coupled plasma 6200 6 Revision 0 February 2007 atomic emission spectrometry ICP AES or inductively coupled plasma mass spectrometry ICP MS 4 8 If SSCS are used to calibrate an FPXRF instrument the samples collected must be representative of the site under investigation Representative soil sampling ensures that a sample or group of samples accurately reflects the concentrations of the contaminants of
38. cone and press down to flatten as before Divide the flattened material into quarters discard two diagonally opposing sections and repeat Repeat the process until only enough sample remains to fill the required containers and proceed to fill the sample jars 6 1 2 Mixing in a Bowl Placethe sample in a bowl Samples for organic constituent compound analysis should be mixed using bowls and stirrers made of glass or stainless steel while samples for metals analysis should be mixed using equipment made of glass stainless steel or hard plastic Make sure the bowl is large enough to accommodate the sample with extra volume to allow for mixing the sample This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS010 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 3of3 Mix the sample with the stirrer If round bowls are used for sample mixing adequate mixing is achieved by stirring the material in a circular fashion reversing direction and occasionally turning the material over High moisture samples are more difficult to homogenize Use an adequate mixing motion for as long as needed to determine by visual observation that the sample media has taken on a uniform appea
39. core sampler 12 Decontaminate the sampler 7 ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS124 Revision No 1 Date of Revision 9 21 06 Shaw shaw E amp I Page 10f3 STANDARD OPERATI NG PROCEDURE Subject Sediment Sampling using Ponar Ekman Type Systems 5 1 PURPOSE The purpose of this document is to provide the methods and procedures for sampling of sediments using clamshell type sampling devices such as the Ponar and Ekman systems These sampling systems can be utilized to collect non core sediment samples If core samples are desired alternative methods should be used SCOPE This procedure is applicable to all Shaw E amp I projects where non core sediment samples will be collected via clamshell sampling device methods and no project program specific procedure is in place REFERENCES U S Army Corps of Engineers Requirements for the Preparation of Sampling and Analysis Plans Appendix C Section C 6 EM200 1 3 Washington D C Wildlife Supply Company WILDCO web site at http www wildco com DEFINITIONS Clamshell Device A sampling device consisting of spring loaded jaws that activate either by contact
40. daly discharges measured dunng that month Averege Weekly Discharge Limitation 7 dey average meens iha highest allowable average of daly discharges overs calendar week caiculated as he sum of all daily discharges mamir during a calendar week dived by the numbar of daily discharges measured dunng Ihat weri Beat Management Practicas BMPs means schedules of actribes prohibiiuns of practices maintenance procedures and ather management practicas l prevent oc reduce the polaron of waters of the State BMPs also include Ireatmeni requirements oparating procedures and preciices to control plant sie runoff spillege or leaks sludge or wasta disposal or dramage from raw matenal sloregs Aliquot maang amp sample of specilied volume used to make up a total compote sample Grah Sample means an individuel sample of at Hast 100 mulliitera collected at a randomly sebected Ume Ovet parod not asceeding 15 munuiss 24 Hour Composite Sampie moans a combmanon of at last B sample of a1 least 100 m kkters collected at panga intervals dunng the operaung hours of n lac lity over a 26 hour penad 8 Hour Composite Sampie means a c minnehon of st oust 3 sample aliquot a at laast 100 mulhtery collected at penodic intervals dunng rhe operaung hours of a Facility over an Brhour penod Flow Proportional Composite Sarnpin means a combination of sample shquots of al ieasl 100 milers collacied 1 penodic intervals such that eithe
41. data 6200 29 Revision 0 February 2007 TABLE 7 EXAMPLE ACCURACY FOR TN 9000 Standard Arsenic Barium Copper Reference Material Cert Meas Rec Cert Cert Conc Conc Conc Conc RTC CRM 021 24 8 193 5 4792 RTC CRM 020 397 753 BCR CRM 143R 131 BCR CRM 141 32 6 USGS GXR 2 131 5 76 0 USGS GXR 6 198 5 NIST 2711 110 3 114 NIST 2710 110 6 2950 NIST 2709 950 98 1 34 6 NIST 2704 443 107 0 98 6 CNRC PACS 1 N 452 SARM 51 466 139 1 268 SARM 52 1285 219 Source Ref 4 These data are provided for guidance purposes only 7 All concentrations in milligrams per kilogram Rec Percent recovery ND Not detected NA Not applicable os No data 6200 30 Revision 0 February 2007 TABLE 8 EXAMPLE REGRESSION PARAMETERS FOR COMPARABILITY Arsene Barium Cope _ 2 69 0 64 3 89 1 38 067 646 052 246 096 204 145 081 589 055 246 O96 199 led Zinc C Chomium _ 2 2 n e m See n m See n m 1205 1 66 1103 1 86 280 64 6 300 096 138 271 1 41 49 Source Ref 4 These data are provided for guidance purposes only Log transformed data n Number of data points r Coefficient of determination Int Y intercept No applicable data 6200 31 Revision 0 February 2007 METHOD 6200 FIELD PORTABLE X RAY FLUORESCENCE SPECTROMETRY FOR THE DETERMINATION OF ELEMENTAL CONCENTRATIONS IN SOIL AND SEDIMENT 11 1
42. employment 3 REFERENCES U S Army Corps of Engineers 2001 Requirements for the Preparation of Sampling and Analysis Plans EM200 1 3 Washington D C U S Department of Transportation Regulations 49 CFR Part 107 178 Dangerous Goods Regulations current edition International Air Transport Association IATA 4 DEFINITIONS Dangerous Goods Airbill Form required when offering Dangerous Goods as defined in IATA regulations for air transport The Dangerous Goods Airbill must be completed and signed by a responsible and qualified person Some carriers require a typed or computer generated form Inner packaging Packaging in immediate contact with the hazardous materials to be shipped such as a sample jar or vial Limited Quantity In the IATA Tables the maximum total amount of a Dangerous Good that can be transported without using UN specification containers such as a non UN tested cooler This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS013 Revision No 1 Date of Revision 9 5 06 Shaw Shaw Page 2 of 4 5 1 5 2 Outer packaging Packaging into which one or more inner packages can be placed such as a sturdy plastic cooler meeting general pac
43. especially willful misrepresentation and shipment as non hazardous materials is a violation of federal law and is punishable by fines and possible imprisonment of the guilty parties It is also a violation of Shaw E amp I policy and can result in disciplinary action up to and including termination of employment 3 REFERENCES U S Army Corps of Engineers 2001 Requirements for the Preparation of Sampling and Analysis Plans EM200 1 3 Washington D C U S Department of Transportation Regulations 49 CFR Parts 108 178 International Air Transport Association IATA Dangerous Goods Regulations current edition 4 DEFINITIONS Cooler Shipping Container Any hard sided insulated container meeting DOT s or IATA s general packaging requirements Bubble Wrap Plastic sheeting with entrained air bubbles for protective packaging purposes This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS012 Revision No 1 Date of Revision 9 8 06 Shaw Shaw E amp Page 2 of 3 5 1 5 2 6 1 RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regardin
44. feasible laboratory personnel should use pollution prevention techniques to address their waste generation When wastes cannot be feasibly reduced at the source the Agency recommends recycling as the next best option 14 2 For information about pollution prevention that may be applicable to laboratories and research institutions consult Less is Better Laboratory Chemical Management for Waste Reduction available from the American Chemical Society s Department of Government Relations and Science Policy 1155 16th St N W Washington D C 20036 http www acs org 15 0 WASTE MANAGEMENT The Environmental Protection Agency requires that laboratory waste management practices be conducted consistent with all applicable rules and regulations The Agency urges laboratories to protect the air water and land by minimizing and controlling all releases from hoods and bench operations complying with the letter and spirit of any sewer discharge permits and regulations and by complying with all solid and hazardous waste regulations particularly the hazardous waste identification rules and land disposal restrictions For further information on waste management consult The Waste Management Manual for Laboratory Personnel available from the American Chemical Society at the address listed in Sec 14 2 16 0 REFERENCES 1 Metorex X MET 920 User s Manual 2 Spectrace Instruments Energy Dispersive X ray Fluorescence Spectrometry An Introduction 19
45. for each All property owner certifications must be recorded along with the attached NFR letter Property Owner Information Owner s Name Title Company Street Address City State Zip Code Site Information Site Name Site Address City State Zip Code Illinois Inventory ID Number Real Estate Tax Index Parcel Index No I hereby certify that I have reviewed the attached No Further Remediation Letter and that I accept the terms and conditions and any land use limitations set forth in the letter Owner s Signature Date SUBSCRIBED AND SWORN TO BEFORE ME this day of 19 Notary Public The Illinois EPA is authorized to require this information under Sections 415 ILCS 5 58 58 12 of the Environmental Protection Act and regulations promulgated thereunder If the Remediation Applicant is not also the sole owner of the remediation site this form must be completed by all owners of the remediation site and recorded with the NFR Letter Failure to do so may void the NFR Letter This form has been approved by the Forms Management Center All information submitted to the Site Remediation Program is available to the public except when specifically designated by the Remediation Applicant to be treated confidentially as a trade secret or secret process in accordance with the Illinois Compiled Statutes Section 7 a of the Environmental Protection Act applicable Rules and Regulations of the Illinois Pollution Control Board and applicable Hlinois
46. is applicable to all Shaw E amp projects where surface soil samples will be collected via trowel or spoon methods REFERENCES U S Army Corps of Engineers 2001 Requirements for the Preparation of Sampling and Analysis Plans Appendix C SectionC 6 EM200 1 3 Washington D C DEFINITIONS Trowel A sample collection device with a curved and pointed metal blade attached to a handle All trace environmental samples should be collected using stainless steel blades Spoon A sample collection device with a round metal blade attached to a handle Surface Soil Soil that is removed from the surface no greater than 6 inches below grade after removing vegetation rocks twigs etc Weathered Soil The top to inch of soil impacted by heat from sun rain or foot traffic that could evaporate dilute or otherwise deposit contaminants from an adjacent location thereby misrepresenting the actual soil characteristic RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for the maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsibl
47. its location on the sampling grid A suffix of A B or C will be added to identify the representative vertical high interval that the sample originated from i e A 0 to 3 feet above range floor B 3 to 6 feet above range floor and C 6 to 9 feet above range floor etc e Asample identified as BS 1 BS 2 BS 3 will identify composite bulk samples obtained from various shooting range soils A sample identified as SED A1 SED A2 SED A3 will identify a sediment samples collected from a corresponding grid sample location A suffix N 9 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois designation of 0 6 inch or 6 12 inch will be added to identify the representative depth interval that the sediment originated from Sample containers will also be labeled with information identifying the date and time of sample collection and the initials of the Shaw field scientist responsible for the collection 3 6 Investigation Derived Waste Wastes generated during the sampling program are expected to be non hazardous Investigation derived waste IDW generated during sampling is expected to include sampling bags decontamination water containing residual solid materials and used personal protective equipment e g gloves paper towels Liquid IDW generated from decontamination and or monitoring well developments and sampling activities will be disposed of on the surface of the site where gen
48. leval gt reject is gt the difference between result and action level Result Within 10 0f or Above Result Greater than 1076 Above Actiordevd LCS LowRecovery If MS MSD are acceptable or If MS MISD are acceptable or Surrogates are acceptable and the RL Surrogates are acceptable Data is at most 20 of action level Data accepted accepted If MS MSD are acceptable or No effect on cata Surrogates are acceptable and LCS is within 10 of acceptance lirrit and result is above action leval gt Data Otherwise flag and qualify that results may in fact be greater than action level accepted Otherwise flag and qualify result as suspected to be above actior level LCS High Recovery No effect on data No effect on cata If MS MSD are acceptable or No effect on cata Surrogates are acceptable evaluate potential bias in QC and accept data Matrix Spike Low R If MSD and LCS acceptable and If MSD and LCS ac No effect on data No effect on data Surrogates or Post spike within range ceptable and Surrogates or Post spike within range Datta is accepted with precision qualifier Data is accepted vith precision qualifier MS MSD RPD High No effect on data No effect on data No effect on data No effect on data If surrogate Y R values are at least If surrogate YR values are at least No effect on cata 70 of acceptance limit Data is 70 of acceptance limit Data is acceptable acceptable Surrogate YR High If surrogate YR values are
49. of the FSIR for the investigation outlined within this Revised Site Investigation Work Plan additional sampling and or laboratory analysis may be required to fully delineate the extent of potential contamination in both the horizontal and vertical directions 13 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois 8 0 REFERENCES U S EPA 1998 SW 846 Test Methods for Evaluating Solid Waste Physical Chemical Methods U S EPA 1997 Environmental investigations standard operating procedure and quality assurance manual U S EPA 2005 Best Management Practices for Lead at Outdoor Shooting Ranges IEPA 1997 Project Summary for Naperville Sportsman s Park JMS Environmental Associates Ltd 2008 Lead Project Report Lead Survey Naperville Sportsman Club Interstate Technology and Regulatory Council ITRC 2003 Characterization and Remediation of Soils at Closed Small Arms Firing Ranges Shaw Standard Operating Procedures SOPs 2006 EI FS 001 Field Log Book EI FS 002 Field Logsheet EI FS 003 Chain of Custody Documentation EI FS 005 Custody Seals EI FS 006 Sample Labeling EI FS 010 Sample Homogenization EI FS 011 Compositing EI FS 012 Shipping and Packaging of Non Hazardous Samples EI FS 013 Packaging and Shipping of DOT IATA Hazardous Samples EI FS 014 Decontamination of Contact Sampling Equipment EI FS 020 Data Usability Review EI FS 101 Trowel Spoon Surface Soil Sampl
50. of the tract of land recorded as West Street according to the plat thereof recorded January 18 1962 as document number R62 1737 for a point of beginning thence Westerly along a line which forms an angle of 91 degrees 37 minutes 30 seconds measured North to West with the West line of West Street a distance of 1106 00 feet to a point on the Southerly extension of a easterly line of Charles Shuffler s Sons Green Acres thence Northerly along said Easterly line of Green Acres and the Southerly extension thereof a distance of 94 92 feet to the Northeast corner of Lot 14 in said Green Acres thence Northeasterly along the Southeasterly line of Lot 13 in said Green Acres and said line extended a distance of 1260 16 feet to a point on the West line of West Street aforesaid thence Southerly along said West line of West Street a distance of 1488 0 feet to the point beginning in DuPage County Illinois Garden Plots 33 8 acres VON OVEN PROPERTY That part of Section 24 Township 38 North Range 9 East of the Third Principal Meridian Described as follows Beginning at the point of intersection of the southerly line of Oswego Road and the east line of Shiffler s Subdivision Green Acres thence in an Easterly direction along the Southerly line of Oswego Road 570 feet thence South 100 feet thence in a Northeasterly direction 198 feet thence South 543 18 feet thence in a Southwesterly direction 801 9 feet thence North 577 5 feet along east line of
51. of thia permit shall contine in Tull force and affect 12 1 88 ILLINOIS ENVIRONMENTAL PROTECTION AGENCY 1021 North Grand Avenue East P O Box 19276 Springfield Illinois 62794 9276 Mary A Gade Director 217 782 6761 October 29 1998 Mr Peter Burchard City Manager City of Naperville 400 S Eagle St Naperville IL 60566 Mr Joe Schultz Executive Director Naperville Park District 320 W Jackson Avenue Naperville IL 60540 5275 Re 0434675330 DuPage County Naperville City of Naperville Site Remediation Technical Reports Dear Mr Burchard The Soil and Groundwater Analysis of Naperville Sportsman s Club and Adjacent Properties 05 08 97 97 566 as prepared by Packer Engineering for the Sportsman s Park property and adjacent properties has been reviewed by the Illinois Environmental Protection Agency Illinois EPA The approved remediation objectives at the remediation sites are equal to or above the existing levels of regulated substances and the Packer report shall serve as the approved Remedial Action Completion Report The remediation sites consisting of approximately 41 68 acre s in total for the parcels investigated outside of the Sportsman s Park are located in the City of Naperville Illinois see attached legal descriptions Pursuant to Section 58 10 of the Illinois Environment Protection Act Act 415 ILCS 5 58 10 your request for a no further remediation determination is granted under th
52. on the data usability Data Quality Objectives The empirical statements and quantitative measures necessary for a given set of measurements to be usable in the planned decision Data Quality Indicators Field and laboratory measures for which compliance with specified requirements or limits can be construed to support attainment of the Data Quality Objectives in a given data set Analytical Data Package The manner in which analytical results are provided from subcontractor laboratories Analytical Data Packages can be received via fax e mail or postal mail QC Summary A summary table of laboratory QC sample results Laboratory Control Blank LCB Reagent Water or Clean Solid Matrix analyzed in the same manner as a sample to determine the Target Analyte concentration contribution due to contamination in the entire analytical system Laboratory Control Spike LCS Reagent Water or Clean Solid Matrix spiked with a known concentration of target analytes and analyzed as a sample to determine the method accuracy of the analytical system Matrix Spike A sample spiked with a known concentration of target analyte and analyzed along with the rest of the analytical batch The percent recovery of the target analytes is used to determine the effect on accuracy due to the sample matrix Matrix Spike Duplicate A duplicate of the Matrix Spike used to determine the analytical precision expressed as Relative Percent Difference RPD of the
53. responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE Safety Notes XRF instruments contain radioactive source s and the ionizing radiation is hazardous Do not remove shielding or disassemble instruments beyond the user maintenance dictated in the instrument manual Never place a hand or other body part in the path of the source and always operate it with its shield closed with its safety shutter if applicable locked or with the sensor window held tight against a surface do not look directly at the beam Some systems utilize cryogenic cooling systems and appropriate precautions should be taken during operation These instruments contain regulated radioactive sources and require licensing and specific radioactive licensee procedures for use In several states XRF units are considered controlled sources and are subject to state radioactive regulations including specific training for all persons using the instrument posting of radioacti
54. samplers provide an intact depth specific sample for geotechnical chemical radiological or biological analysis 2 SCOPE This procedure is applicable to all Shaw E amp projects where soil samples will be collected via hand operated soil probe corer methods and no project specific procedure exists This procedure is not applicable to drilling or direct push methods 3 REFERENCES U S Army Corps of Engineers 2001 Requirements for the Preparation of Sampling and Analysis Plans EM 200 1 3 American Society for Testing and Materials Standard Practice for Soil Investigation and Sampling by Auger Borings D1452 80 re approved 2000 U S Environmental Protection Agency 1994 Soil Sampling EPA ERT SOP 2012 November 4 DEFINITIONS Soil Corer A sample collection device consisting of extension rods a T handle and a sampling head The sampling head is a thin walled two piece metal tube split lengthwise into which a metal or plastic sleeve is placed The tube halves are held together with screw locked ends the bottom one having a point The sleeve fills with material as the sampler is forced downward allowing for an undisturbed core to be collected Soil Probe A core sample collection device consisting of a thin walled metal tube with a cutting edge on the bottom The tube is cut away from its tip to approximately one third of the way to its top to allow material to enter The top of a soil probe is
55. sheet or QC Summary page If any QC is non compliant review its impact to use as project data by referencing the QC Results Impact Table attached to this SOP and consult with the Qualified Person to determine final acceptability Note on the Data Report itself or checklist all discrepancies and the reasons for data acceptance qualification or rejection If a Qualified Person has made the decision this should also be noted If any of the data is determined to be unusable immediately notify the Project Manager and project site personnel Reporting of Usability Review Results Project personnel must be provided either a spreadsheet summary of the results with an attached signed and dated Statement of Usability or the complete Data Package with the project specific Data Usability Review documentation At no time are results to be communicated verbally ATTACHMENTS Attachment 1 Project QC Impact Table FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS020 Attachment No 1 Shaw shaw E amp Attachment 1 Project QC Impact Table a LCB Contaninated No effect on data No effect on data No effect unless contamination is 1O No effect unless contarrination of actior
56. soil to increase soil density and compactness for better repeatability and representativeness This condition is especially important for heavy element analysis such as barium Source count times for in situ analysis usually range from 30 to 120 seconds but source count times will vary among instruments and depending on the desired method sensitivity Due to the heterogeneous nature of the soil sample in situ analysis can provide only screening type data 11 4 Forintrusive analysis of surface or sediment it is recommended that a sample be collected from a 4 by 4 inch square that is 1 inch deep This will produce a soil sample of approximately 375 g or 250 cm which is enough soil to fill an 8 ounce jar However the exact dimensions and sample depth should take into consideration the heterogeneous deposition of contaminants and will ultimately depend on the desired project specific data quality objectives The sample should be homogenized dried and ground before analysis The sample can be homogenized before or after drying The homogenization technique to be used after drying is discussed in Sec 4 2 If the sample is homogenized before drying it should be thoroughly mixed in a beaker or similar container or if the sample is moist and has a high clay content it can be kneaded in a plastic bag One way to monitor homogenization when the sample is kneaded in a plastic bag is to add sodium fluorescein dye to the sample After the moist sample
57. the presence of large concentrations of Fe when attempting to measure cobalt Co The V K and K energies are 4 95 and 5 43 keV respectively and the Cr K energy is 5 41 keV The Fe K and K energies are 6 40 and 7 06 keV respectively and the Co K energy is 6 92 keV The difference between the V K and Cr K energies is 20 eV and the difference between the Fe K and the Co K energies is 140 eV The resolution of the highest resolution detectors in FPXRF instruments is 170 eV Therefore large amounts of V and Fe will interfere with quantitation of Cr or Co respectively The presence of Fe is a frequent problem because it is often found in soils at tens of thousands of parts per million ppm 4 7 Other interferences can arise from K L K M and L M line overlaps although these overlaps are less common Examples of such overlap involve arsenic As K lead Pb L and sulfur S K Pb M In the As Pb case Pb can be measured from the Pb L line and As can be measured from either the As K or the As K line in this way the interference can be corrected If the As K line is used sensitivity will be decreased by a factor of two to five times because it is a less intense line than the As K line If the As K line is used in the presence of Pb mathematical corrections within the instrument software can be used to subtract out the Pb interference However because of the limits of mathematical corrections As concentrations cannot be efficiently
58. the containers to avoid breakage from bumping Double bag the ice chips or cubes in gallon or quart sized resealable plastic freezer bags and wedge the ice bags between the sample bottles Add bagged ice across the top of the samples When sufficiently full seal the inner protective plastic bag and place additional packing material on top of the bag to minimize shifting of containers during shipment Tape a gallon sized resealable plastic bag to the inside of the cooler lid place the completed chain of custody document inside and seal the bag shut Tape the shipping container cooler shut using packing tape duct tape or other tear resistant adhesive strips Taping should be performed to ensure the lid cannot open during transport Place a custody seal on two separate portions of the cooler to provide evidence that the lid has not been opened prior to receipt by the intended recipient This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS012 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 3of3 6 2 Labeling A This Side Up arrow should be adhered to all sides of the cooler especially ones without obvious handles The name and addr
59. they differ by less than 25 If they differ by more than 25 sample preparation methods should be reviewed This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS200 Revision No 1 Date of Revision 9 22 2006 Shaw shaw Page 4014 6 3 Analyze a calibration check after every ten sample analyses following any extended down period and at the end of the analysis day shift or as specified in the project plans Download data if required turn off the analyzer clean the window and properly store the instrument when finished Systems that use batteries should be left on their chargers overnight Those equipped with safety shutters should always be stored with the shutter in the locked position Quality Control Quality Control requirements vary depending upon data use and the DQOs necessary and should be defined in a project specific plan At a minimum QC should include analysis of blanks calibration checks SRMs or known value samples and replicate samples Confirmatory use requires more extensive QC efforts site specific calibration should be performed by split analyzing prepared samples in duplicate by XRF and off site definitive methods The results are used to develop a si
60. to manually conduct a gain check because of increasing or decreasing ambient temperature it is standard to perform a gain check after every 10 to 20 sample measurements or once an hour whichever is more frequent It is also suggested that a gain check be performed if the temperature fluctuates more than 10 F The operator should follow the manufacturer s recommendations for gain check frequency 6200 7 Revision 0 February 2007 5 0 SAFETY 5 1 This method does not address all safety issues associated with its use The user is responsible for maintaining a safe work environment and a current awareness file of OSHA regulations regarding the safe handling of the chemicals listed in this method A reference file of material safety data sheets MSDSs should be available to all personnel involved in these analyses NOTE No MSDS applies directly to the radiation producing instrument because that is covered under the Nuclear Regulatory Commission NRC or applicable state regulations 5 2 Proper training for the safe operation of the instrument and radiation training should be completed by the analyst prior to analysis Radiation safety for each specific instrument can be found in the operator s manual Protective shielding should never be removed by the analyst or any personnel other than the manufacturer The analyst should be aware of the local state and national regulations that pertain to the use of radiation producing equipment and radioacti
61. unless otherwise specified by the permitting authority Permiltees not using eDMRs shall mail Discharge Monitoring Reports with an original signature to the IEPA at the following address Illinois Environmental Protection Agency Division of Water Pollution Controi 1021 North Grand Avenue East Post Office Box 19276 Springfield lllinois 62794 9276 SPECIAL CONDITION 5 For the purpose of this permit this effluent is limited to storm water free from process and other wastewater discharges SPECIAL CONDITION 6 The Agency may request more frequent monitoring by Letter and Without Public Notice for finite periods in the event of operational maintenance or other problems resulting in possible effluent deterioration SPECIAL CONDITION 7 The water quality standards for lead at this location are 0 51 mg l daily maximum and 0 107 mg l monthly average Based on these standards the Agency has developed Action Levels of 0 25 mg l daily maximum and 0 05 mg l monthly average In the event either of these Action Levels is exceeded on any two consecutive monthly Discharge Monitoring Reports which report an effluent the Permittee shall initiate the development and implementation of a Preventative Action Plan in accordance with the compliance schedule outlined below The Plan shall be aimed at preventing any further increase in the lead concentrations present in the effluent An alternative means of compliance with this requirement may includ
62. with the bottom or by other means and entrap the collected materials for retrieval These devices can be operated via hand line or with a winch for deep water operations Ekman Sampler A type of clamshell device designed for use in soft bottoms The Ekman sampler rests on the bottom and uses a messenger system to activate the closure spring The sampler scoops up the material caught between the jaws upon closure Ponar Sampler A type of clamshell device designed for hard and gravelly bottoms Unlike the Ekman a Ponar sampler self activates its closure mechanism after it penetrates into the bottom material Ponar samplers are heavy 45 lbs and require a winch to operate Messenger A metal weight usually lead with a hole through its core that is used to activate the spring closure on clamshell devices The messenger is dropped onto the closure activation mechanism by sliding it down a line It activates the closure by the force of its weight upon impact RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which m
63. within 30 No effect on data of acceptance lirrit gt Data is acceptable Page 1 of 4 Shaw Shaw E amp QC Data Discrepancy Result Non delect Result gt 10 Bdow Actiondevel Duplicate Precision outside lirrits Matrix Spike High YR MS MSD RPD High Procedure No EI FS020 Attachment No 1 Result Within 10 0f or Above Actiordevel REMEDIATION or TREATMENT MONITORING No effect unless Duplicate is either above or within 50 of action level in this case qualify sarrple data and report with Duplicate result as highest probable value If MS MSD are acceptable or Surrogates are acceptable Data accepted If 9dA250 and LCS acceptable Deta accepted No effect on data unless perceived native concentration in MS or MSD result would be above action level this case reject cata as highly suspect and advise review of sarrpling and lab sub sarrpling procedures In No effect unless Duplicate is either above or within 30 of action level inthis case qualify result as assumed above action level If MS MISD are acceptable or Surrogates are acceptable Data accepted If 9daA250 and LCS acceptable Data accepted No effect on data unless perceived MS or MSD native concentration would be above actiorHevel In this case qualify results as potentially above actiorlevel If TB is greater than 10 of actior level or resuit gt reject data If Duplicate is either above o
64. 0 Site Name City State Contract Title Client Name Cost Code Add Number Check XRF clock Source Strength Note Cd 103 ell be used for Pb Cu calibration Amrc241 willbe used for Sb x Jca1o9 Na Am 241 Fe 55 Blank SiO2 Count Moderate Lead NIST 2711 Count sec Conc ppm Element Certified Detected Element 2 RPD Accept Conc ppm Certified Detected Pb 25 50 1 162 114 lt 70 Other metals Zn lt 40 3 Cr lt 300 As lt 30 i Low Lead NIST 2586 Count High Lead NIST 2710 Count Conc ppm Certified Detected Conc ppm Certified Detected 143 As 189 Comments Not a NIST certified value 3a Continuing Calibration Data Is XRF warm up gt 15 min Yes No Internal calibration complete Record energy resolution 3b Continuing Calibration Data Is XRF warm up gt 15 min Yes No Internal calibration complete Record energy resolution 4 End of Day Calibration Is XRF warm up gt 15 min Yes No Internal calibration complete Record energy resolution Zn 6 952 As 626 Check XRF clock Agree Yes Source Strength Check XRF clock Agree Yes Check
65. 2 10 Don a pair of clean gloves If desired place plastic sheeting around the targeted location to keep sampled material in place Use a knife to cut an access hole for the sample location Remove any surficial debris e g vegetation rocks twigs from the sample location and surrounding area until the soil is exposed Once exposed the soil surface is designated as at grade or 0 inches Use a trowel to scrape and remove the top 1 8 to 1 4 inch of weathered soil A spoon can be interchanged with trowel If collecting a sample that includes VOC analysis collect the VOC sample aliquot first following more applicable methods With a new trowel place the point of the blade on the ground While holding the handle of the trowel partially rotate the blade in a clockwise counter clockwise motion while pushing at a downward angle until the blade is inserted to the required depth or the blade is nearly covered Be certain that the trowel is not inserted to a depth where the soil will touch the handle or other non stainless steel portion of the trowel or the sampler s hand With a prying motion lift up the trowel with soil on the blade and place soil into the stainless steel mixing bowl Repeat steps 6 and 7 until the required depth of soil is placed into the mixing bowl Measure the depth of the sample location with a rule or tape to verify the sampling depth and record in the field logbook Homogenize the non VOC sample an
66. 55 and Am 241 sources respectively The TN Lead analyzer was operated using a 60 second count time for the Cd 109 source The X MET 920 with the Si Li detector was calibrated using fundamental parameters and one well characterized site specific soil standard as a calibration check It used 140 and 100 second count times for the Cd 109 and Am 241 sources respectively The X MET 920 with the gas filled proportional detector was calibrated empirically using between 10 and 20 well characterized site specific soil standards It used 120 second times for the Cd 109 source The XL Spectrum Analyzer utilized NIST SRM 2710 for calibration and the Compton peak normalization procedure for quantitation based on 60 second count times for the Cd 109 source The MAP Spectrum Analyzer was internally calibrated by the manufacturer The calibration was checked using a well characterized site specific soil standard It used 240 second times for the Cd 109 source 13 5 Precision measurements The example precision data are presented in Table 4 These data are provided for guidance purposes only Each of the six FPXRF instruments performed 10 replicate measurements on 12 soil samples that had analyte concentrations ranging from nondetects to thousands of mg kg Each of the 12 soil samples underwent 4 different preparation techniques from in situ no preparation to dried and ground in a sample cup Therefore there were 48 precision data points for five of the instrumen
67. 60 Des Plaines e 5113 Harrison St Des Planes 60016 lt 847 294 4000 Elgin 53955 State fign IL 6012 3 9 E371 186 71 1 Peoria e 5415 N University St Peona IL 616148 109 693 5463 Bureau of Land Peoria amp 620 S Linwersity SC Peona id 616149 1109 0915302 Champaign 7125 5 Fest St Champaign IL 61620 217 278 5800 Collinsville s 200 sall Str et Coliasville 62234 e 618 136 5120 Marion e s Vv Man st Suite 116 Manon 62959 e 618 993 7200 Promed en Recycled Pape NPDES Permit No IL0073253 Illinois Environmental Protection Agency Division of Water Pollution Control 1021 North Grand Avenue East Post Office Box 19276 Springfield Illinois 62794 9276 NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM Expiration Date September 30 2015 Name and Address of Permittee Naperville Park District 320 West Jackson Avenue Naperville Illinois 60540 Discharge Number and Name 001 Shooting Stations and Shot Fall Area Reissued NPDES Permit Issue Date September 16 2010 Effective Date October 1 2010 Facility Name and Address Sportsman s Park 743 South West Street Naperville Illinois 60540 DuPage County Receiving Waters Unnamed Connecting Channel Tributary to South Pond Tributary to Unnamed Ditch Tributary to the West Branch of the DuPage River In compliance with the provisions of the Illinois Environmental Protection Act Title 35 of Ill Adm Code Subtitle C and or Subtitle D Ch
68. 94 3 TN Spectrace Spectrace 9000 Field Portable Benchtop XRF Training and Applications Manual 4 Unpublished SITE data received from PRC Environment Management Inc 17 0 TABLES DIAGRAMS FLOWCHARTS AND VALIDATION DATA The following pages contain the tables referenced by this method A flow diagram of the procedure follows the tables 6200 24 Revision 0 February 2007 Analyte Antimony Sb Arsenic As Barium Ba Cadmium Cd Calcium Ca Chromium Cr Cobalt Co Copper Cu Iron Fe Lead Pb Manganese Mn Mercury Hg Molybdenum Mo Nickel Ni Potassium K Rubidium Rb Selenium Se Silver Ag Strontium Sr Thallium TI Thorium Th Tin Sn Titanium Ti Vanadium V Zinc Zn Zirconium Zr Source Refs 1 2 and 3 TABLE 1 Chemical Abstract Series Number 7440 36 0 7440 38 0 7440 39 3 7440 43 9 7440 70 2 7440 47 3 7440 48 4 7440 50 8 7439 89 6 7439 92 1 7439 96 5 7439 97 6 7439 93 7 7440 02 0 7440 09 7 7440 17 7 7782 49 2 7440 22 4 7440 24 6 7440 28 0 7440 29 1 7440 31 5 7440 32 6 7440 62 2 7440 66 6 7440 67 7 EXAMPLE INTERFERENCE FREE LOWER LIMITS OF DETECTION Lower Limit of Detection in Quartz Sand milligrams per kilogram 40 40 20 100 70 150 60 50 60 20 70 30 10 50 200 10 40 70 10 20 10 60 50 50 50 10 These data are provided for guidance purposes only 6200 25 Revision 0 February 2007 TABLE 2 SUMMARY
69. Agency nt tenst JO deys in advance of the proposed 18 Cale tb Thu notice includes amp writlnn agreement bolween ihe existing Shd new perrruttess cantaming a specific data for transfer of permit responsibility coverage and lainhty Coleen the current and nee psrmitiees and le The Agancy doss nol nouly the smsung parmiriaqs and iha proposed new petrrratiee of its miem lo modify er ravoks and rmaaue the permit If Ihia Notice is not recerved Ihe transier rs effective on the date specihed in the All manufsciuneg commercial frunng and sibeicultural dichargars must noliy ihe Agency as soon ss they know of have reason 10 Thal any activity has occurred or will occur which would rasull n the discharge of any tox Dollutant dented under Section 307 of iha Clean Water Ac which r not limited m the pemr if thal discharge wil sacred Hryete the highest of the following on One hundred micrograms per bier 100 ug l 115 161 n7 18 159 20 2117 22 123 iz 251 24 ia Two hundred micrograms pee iter L200 ug l for acromm and pcryloritriie ive hundred micrograms par her ISOQ ug l for 24 geutraphenolt and for Z metnyl 4 B dinrraphenol and one milligram per hiter 1 mori for antimony Five 5 tires ihe meumum contentahon value reported Jor that poluant n ha NPDES pemi appicaspon or 4 The level established b
70. Analyzer SiLi Gas Filled Spectrum Spectrum Detector Detector Analyzer Analyzer Analyte Antimony 6 54 NR Arsenic 5 33 4 11 3 23 1 91 12 47 6 68 Barium 4 02 NR 3 31 5 91 NR NR Cadmium 29 84 NR 24 80 NR NR NR Calcium 2 16 NR NR NR NR NR Chromium 22 25 25 78 22 72 3 91 30 25 NR Cobalt 33 90 NR NR NR NR NR Copper 7 03 9 11 8 49 9 12 12 77 14 86 Iron 1 78 1 67 1 55 NR 2 30 NR Lead 6 45 5 93 5 05 7 56 6 97 12 16 Manganese 27 04 24 75 NR NR NR NR Molybdenum 6 95 NR NR NR 12 60 NR Nickel 30 85 NR 24 92 20 92 NA NR Potassium 3 90 NR NR NR NR NR Rubidium 13 06 NR NR NR 32 69 NR Strontium 4 28 NR NR NR 8 86 NR Tin 24 32 NR NR NR NR NR Titanium 4 87 NR NR NR NR NR Zinc 7 27 7 48 4 26 2 28 10 95 0 83 Zirconium 3 58 NR NR NR 6 49 NR These data are provided for guidance purposes only Source Ref 4 a These values are biased high because the concentration of these analytes in the soil samples was near the lower limit of detection for that particular FPXRF instrument NR Not reported NA Not applicable analyte was reported but was below the established lower limit detection 6200 27 Revision 0 February 2007 TABLE 5 EXAMPLES OF PRECISION AS AFFECTED BY SAMPLE PREPARATION Average Relative Standard Deviation for Each Preparation Method Intrusive In Situ Field Undried and Unground Analyte Intrusive Dried and Ground Antimony 30 1 15 0 14 4 Arsenic 22 5 5 36 3 76 Barium 17 3 3 38 2 90
71. Cadmium 41 2 30 8 28 3 Calcium 17 5 1 68 1 24 Chromium 17 6 28 5 21 9 Cobalt 28 4 31 1 28 4 Copper 26 4 10 2 7 90 Iron 10 3 1 67 1 57 Lead 25 1 8 55 6 03 Manganese 40 5 12 3 13 0 Mercury ND ND ND Molybdenum 21 6 20 1 19 2 Nickel 29 8 20 4 18 2 Potassium 18 6 3 04 2 57 Rubidium 29 8 16 2 18 9 Selenium ND 20 2 19 5 Silver 31 9 31 0 29 2 Strontium 15 2 3 38 3 98 Thallium 39 0 16 0 19 5 Thorium NR NR NR Tin ND 14 1 15 3 Titanium 13 3 4 15 3 74 Vanadium NR NR NR Zinc 26 6 13 3 11 1 Zirconium 20 2 5 63 5 18 These data are provided for guidance purposes only Source Ref 4 2 These values may be biased high because the concentration of these analytes in the soil samples was near the lower limit of detection ND Not detected NR Not reported 6200 28 Revision 0 February 2007 TABLE 6 EXAMPLE ACCURACY VALUES Instrument TN 9000 TN Lead Analyzer X MET 920 SiLi Detector XL Spectrum Analyzer p sp neo nt ox p nos n L I RE TUE RES 123 286 s 4804 so4 62 6 26 187 1086 529 s s nex 2 BEES ees es mes E RR nn Source Ref 4 These data are provided for guidance purposes purposes only n Number of samples that contained a certified value for the analyte and produced a detectable concentration from the FPXRF instrument SD Standard deviation NA Not applicable only two data points therefore a SD was not calculated Rec Percent recovery No
72. E amp I Attachment 1 Common Data Error Codes COMMON DATA ERROR CODES RE CE TE SE CL DC WO NI OB Recording Error Calculation Error Transcription Error Spelling Error Changed for Clarity Original Sample Description Changed After Further Evaluation Write Over Not Initialed and Dated at Time of Entry Not Recorded at the Time of Initial Observation All Error Codes should be circled Page 1 of 1 EI FS001 1 Procedure No EI FS002 Revision No 1 Date of Revision 9 8 06 Shaw Shaw Page 10f2 STANDARD OPERATI NG PROCEDURE Subject Field Logsheet 5 1 5 2 PURPOSE This procedure is intended to communicate the requirements for proper use and completion of Field Logsheets to document sample collection and data gathering activities Field Logsheets are often utilized to document single location event information Examples include boring logs and drum container logs This procedure also provides several templates that may be utilized or modified to a particular need SCOPE This procedure is applicable to all Shaw E amp projects where Field Logsheets are utilized to document data and or sample collection information This procedure does not mandate the use of Field Logsheets on all Shaw E amp I data sample collection efforts and projects programs are free to utilize other means Field Logbooks direct data entry etc to document sample collection and other pertinent data gathering activities
73. EETS GRAPHIC SCALE 80 0 80 w o SS 10 CONTOUR DATA OBTAINED FROM THE ILLINOIS NATURAL RESOURCES GEOSPATIAL DATA CLEARINGHOUSE SPORTSMANS PARK di NAPERVILLE ILLINOIS 070 FIGURE 3 3 T AutoCAD AUTOCAD 2008 PROJECTS 141835 JUNE 2011 FIGURE 3 HISTORICAL CONFIGURATION dwg 6 27 2011 10 18 30 AM PEL Sh W Shaw Environmental Inc HISTORIC ANTICIPATED SHOT FALL DESPOSITIONS a a HISTORIC CONFIGURATION 3 OF 5 SHEETS GRAPHIC SCALE 80 0 80 em ISISSM DEAE 02 E I E M PP JU CONTOUR DATA OBTAINED FROM THE ILLINOIS NATURAL RESOURCES GEOSPATIAL DATA CLEARINGHOUSE SPORTSMANS PARK e NAPERVILLE ILLINOIS DESIGNED BY JJC DRAWING NO DRAWN BY PEL 4 FIGURE 4 CHECKED BY Shaw Shaw Environmental Inc COMBINED ANTICIPATED SHOT FALL ZONES DESCRIPTION APPROVED BY 4 OF 5 SHEETS T AutoCAD AUTOCAD 2008 PROJECTS 141835 JUNE 2011 FIGURE 4 COMBINED SHOT FALL ZONES dwg 6 27 2011 10 28 39 AM GRAPHIC SCALE 80 0 80 PD 11 12 13 14 E ca S Cd Ex Du 2 t se xa da M LAS eT x gt LJ y 1 a P mE A KL See 1 CONTOUR DATA OBTAINED FROM THE ILLINOIS NATURAL RESOURCES GEOSPATIAL DATA CLEARINGHOUSE 2 REMISED DECEMBER 2011 SPORTSMANS PARK NAPERVILLE ILLINOIS DRAWING NO 5 7 diii Shaw shaw Environmental Inc
74. Follow manufacturers manual for operation of FPXRF insturmentation In situ Intrusive 11 3 Remove debris from soil surface and level surface if necessary Tap 11 4 Collect sample from a 4 x 4 inch square of soil soil to increase density and compactness 11 3 Perform analysis Sample homogenization before drying No Follow preparation procedure to achieve your DQOs Yes 11 4 Thoroughly mix sample in a beaker or plastic bag Monitor homogenization with sodium fluorescein dye 11 5 Dry 20 50 grams of sample for 2 4 hours at a temp no greater than 150 C 11 6 Ground sample until 9096 of original sample passes through a 60 mesh sieve 11 6 Place sample in polyethylene sample cup and perform analysis 6200 32 Revision 0 February 2007 Shaw Shaw Environmental Inc St Charles Illinois 630 762 1400
75. For this reason the sensitivity should be established as the lowest point of detection based on acceptable target analyte recovery in the desired sample matrix 9 7 Confirmatory samples The comparability of the FPXRF analysis is determined by submitting FPXRF analyzed samples for analysis at a laboratory The method of confirmatory analysis must meet the project and XRF measurement data quality objectives The confirmatory samples must be splits of the well homogenized sample material In some cases the prepared sample cups can be submitted A minimum of 1 sample for each 20 FPXRF analyzed samples should be submitted for confirmatory analysis This frequency will depend on project specific data quality objectives The confirmatory analyses can also be used to verify the quality of the FPXRF data The confirmatory samples should be selected from the lower middle and upper range of concentrations measured by the FPXRF They should also include samples with analyte concentrations at or near the site action levels The results of the confirmatory analysis and FPXRF analyses should be evaluated with a least squares linear regression analysis If the measured concentrations span more than one order of magnitude the data should be log transformed to standardize variance which is proportional to the magnitude of measurement The correlation coefficient r for the results should be 0 7 or greater for the FPXRF data to be considered screening level data If t
76. Groundwater Data Soil and groundwater sample chemical analytical results will be evaluated by the Shaw project manager to determine if residual environmental impacts are present at the Site The analytical results will be summarized in tabular formats and compared directly to the Tier 1 Residential Soil Remediation Objectives SROs the Tier 1 Construction Worker SROs and Groundwater Remediation Objectives GROs as listed in Title 35 of the Illinois Administrative Act Part 742 Tiered Approach to Corrective Action Objectives TACO Results that exceed the TACO objectives if any will be clearly identified in the tables Shaw s evaluation of the data will form the basis for determining the need for additional investigations and or remedial actions Recommendations for additional investigations and or remedial actions will be provided in the final report 7 0 REPORT PREPARATION At the conclusion of the Site investigations and laboratory analyses Shaw will prepare a Focused Site Investigation Report FSIR to document the methodologies used and the results of the investigations The FS R will provide discussions of the following Project Background Investigation Methodologies Data Evaluation and Endangerment Assessment Findings and Opinions Scaled Site Maps and tabulated analytical summaries will be included in the report Copies of the Laboratory Analytical Reports will be appended to the FS R Following IEPA submittal and review
77. IAL CONDITION 1 Flow shall be reported as a daily maximum and monthly average In the event that no discharge occurs during a given month a statement of No Discharge shall be reported on the DMR form for that month SPECIAL CONDITION 2 Samples taken in compliance with the effluent monitoring requirements shall be taken at a point representative of the discharge but prior to entry into the unnamed ditch tributary to the West Branch of the DuPage River SPECIAL CONDITION 3 If an applicable effluent standard or limitation is promulgated under Sections 301 bX2XC and D 304 b 2 and 307 a 2 of the Clean Water Act and that effluent standard or limitation is more stringent than any effluent limitation in the permit or controls a pollutant not limited in the NPDES Permit the Agency shall revise or modify the permit in accordance with the more stringent standard or prohibition and shall so notify the permittee SPECIAL CONDITION 4 The Permittee shall record monitoring results on Discharge Monitoring Report DMR Forms using one such form for each outfall each month The Permittee may choose to submit electronic DMRs eDMRs instead of mailing paper DMRs to the IEPA More information including registration information for the eDMR program can be obtained on the IEPA website http Avww epa state il us water edmr index html The completed Discharae Monitoring Report forms shall be submitted to IEPA no later than the 25th day of the following month
78. ION 11 In the event trap shooting activities at this facility permanently cease the Permiltee shall notify the Agency s Bureau of Land Site Remediation Section at the address listed under Special Condition 4 SPECIAL CONDITION 12 The permittee shall implement a Best Management Practices BMP program to limit and control the deposition of shotgun shell wadding either directly or indirectly into the waters of the State In developing the BMP the permittee shall evaluate the shooting activities and effluent to determine if the shell wadding is being contributed to any surface waters If so the BMP program shall include measures designed to control the discharge of this material into the waters of the State SPECIAL CONDITION 13 Issuance of this permit expressly prohibits the deposition of toxic containing target material into waters of the State SPECIAL CONDITION 14 Permittee shall analyze the effluent for the following polynuclear aromatic hydrocarbons PNA s Acenaphthene Acenaphthylene Anthracene Benzo a anthracene Benzo a pyrene 3 4 Benzofiuoranthene Benzo ghi perylene Benzo k fluoranthene Chrysene Dibenzo a h anthracene Fluoranthene Fluorene Indeno 1 2 3 cd pyrene Naphthalene Phenanthrene Pyrene Priority Pollutant PNA monitoring refers to the sum of these polynuclear aromatic hydrocarbons Pase 5 ATTACHMENT H Standard Conditions Detinitiana At means the inas Environmental Prowenon Act h 131 0 2 Rev Star Sec 1001
79. LIOJBIOGL EUSUTUO ITAU ISIA UY 39 1077 1007 EJUIUUOIAUH j Appendix C Shaw Standard Operation Procedures SOP Procedure No EI FS001 Revision No 1 Date of Revision 9 8 06 Shaw shaw E81 Page 1015 STANDARD OPERATING PROCEDURE Subject Field Logbook 5 1 5 2 PURPOSE This procedure is intended to communicate the requirements for selection use and maintenance of all field logbooks Field logbooks are often used to document observations sampling information and other pertinent information on project sites They are considered legal documents and should be maintained and documented accordingly as part of the project file SCOPE This procedure is applicable to all Shaw E amp site operations where field logbooks are utilized to document all site activities and pertinent information REFERENCES Nielsen Environmental Field School 1997 Field Notebook Guidelines DEFINITIONS Significant detail Any piece and or pieces of information or an observation that can be considered pertinent to the legal reconstruction of events description of conditions or documentation of samples and or sampling procedures Significant event Any event or events that could influence or be considered pertinent to a specific task or function and therefore require documentation in the Field Logbook Field Logbook Logbooks used at field sites that contain detailed informatio
80. N IS THERE ADEQUATE SPACING OF SAMPLES SO THAT THEY WILL NOT TOUCH DURING SHIPMENT HAVE AN ADEQUATE NUMBER OF BLUE ICE PACKS OR WATER ICE BEEN PLACED AROUND AND ON TOP OF THE SAMPLE HAS FRESH BLUE ICE OR WATER ICE BEEN ADDED TO THE COOLER THE DAY OF THE SHIPMENT HAS THE COOLER BEEN FILLED WITH ADDITIONAL CUSHIONING MATERIAL HAS THE COC BEEN PLACE IN A ZIPLOCK BAG AND TAPED TO THE INSIDE OF THE LID OF THE COOLER HAVE CUSTODY SEALS BEEN PLACED ONTO THE LID HAS THE COOLER BEEN LABELED THIS SIDE UP IF REQUIRED HAS THE COOLER BEEN LABELED WITH THE DOT PROPER SHIPPING NAME UN NUMBER AND LABEL HAS THE LABORATORY PERFORMING THE ANALYSES BEEN NOTIFIED OF THE SHIPMENT OF SAMPLES PROBLEMS RESOLUTIONS O0 O 200 Ua O0 O0 aad PREPARED BY SIGNATURE Page 1 of 1 Procedure No EI FS014 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 1 of 2 STANDARD OPERATING PROCEDURE Subject Decontamination of Contact Sampling Equipment 1 PURPOSE This procedure is intended to provide minimal guidelines for the decontamination of contact sampling equipment Contact sampling equipment is equipment that comes in direct contact with the sample or the portion of a sample that will undergo chemical analyses or physic
81. OF RADIOISOTOPE SOURCE CHARACTERISTICS Source Activity Half Life Excitation Energy Elemental Analysis Range mCi Years keV Fe 55 20 50 2 7 5 9 Sulfur to Chromium K Lines Molybdenum to Barium L Lines Cd 109 5 30 1 3 22 1 and 87 9 Calcium to Rhodium K Lines Tantalum to Lead K Lines Barium to Uranium L Lines Am 241 5 30 432 26 4 and 59 6 Copper to Thulium K Lines Tungsten to Uranium L Lines Cm 244 60 100 17 8 14 2 Titanium to Selenium K Lines Lanthanum to Lead L Lines Source Refs 1 2 and 3 TABLE 3 SUMMARY OF X RAY TUBE SOURCE CHARACTERISTICS Anode Recommended K alpha Elemental Analysis Range Material Voltage Range Emission KV KeV Cu 18 22 8 04 Potassium to Cobalt K Lines Silver to Gadolinium L Lines Mo 40 50 17 4 Cobalt to Yttrium K Lines Europium to Radon L Lines Ag 50 65 22 1 Zinc to Technicium K Lines Ytterbium to Neptunium L Lines Source Ref 4 Notes The sample elements excited are chosen by taking as the lower limit the same ratio of excitation line energy to element absorption edge as in Table 2 approximately 0 45 and the requirement that the excitation line energy be above the element absorption edge as the upper limit L2 edges used for L lines K beta excitation lines were ignored 6200 26 Revision 0 February 2007 TABLE 4 EXAMPLE PRECISION VALUES Average Relative Standard Deviation for Each Instrument at 5 to 10 Times the Lower Limit of Detection TN Lead X MET 920 X MET 920 XL MAP
82. OPERLY SIGNED IN THE TRANSFER SECTION PACKAGING CHECKLIST HAS EACH SAMPLE BEEN PLACED INTO AN INDIVIDUAL PLASTIC BAG HAS THE DRAIN PLUG OF THE COOLER BEEN TAPED CLOSED WITH WATER PROFF TAPE FROM THE INSIDE HAVE ALL THE SAMPLES BEEN PLACED INTO THE COOLER IN AN UPRIGHT POSITION IS THERE ADEQUATE SPACING OF SAMPLES SO THAT THEY WILL NOT TOUCH DURING SHIPMENT HAVE AN ADEQUATE NUMBER OF BLUE ICE PACKS OR WATER ICE BEEN PLACED AROUND AND ON TOP OF THE SAMPLE HAS FRESH BLUE ICE OR WATER ICE BEEN ADDED TO THE COOLER THE DAY OF THE SHIPMENT HAS THE COOLER BEEN FILLED WITH ADDITIONAL CUSHIONING MATERIAL HAS THE COC BEEN PLACE IN A ZIPLOCK BAG AND TAPED TO THE INSIDE OF THE LID OF THE COOLER HAVE CUSTODY SEALS BEEN PLACED ONTO THE LID HAS THE COOLER BEEN LABELED THIS SIDE UP IF REQUIRED HAS THE COOLER BEEN LABELED WITH THE DOT PROPER SHIPPING NAME UN NUMBER AND LABEL HAS THE LABORATORY PERFORMING THE ANALYSES BEEN NOTIFIED OF THE SHIPMENT OF SAMPLES PROBLEMS RESOLUTIONS YES NO COMMENTS YES NO COMMENTS 200 200 PREPARED BY SIGNATURE Page 1 of 1 Procedure No EI FS013 Revision No 1 Date of Revision 9 5 06 Shaw Shaw Page 10f4 STANDARD OPERATI NG PROCEDURE Subject Packaging and Shipping of DOT IA
83. Peltier effect Instruments with a Si Li detector have an internal liquid nitrogen dewar with a capacity of 0 5 to 1 0 L Proportional counter detectors are rugged and lightweight which are important features of a field portable detector However the resolution of a proportional counter detector is not as good as that of a solid state detector The energy resolution of a detector for characteristic x rays is usually expressed in terms of full width at half maximum FWHM height of the manganese K peak at 5 89 keV The typical resolutions of the above mentioned detectors are as follows Hgl 270 eV silicon pin diode 250 eV Si Li 170 eV and gas filled proportional counter 750 eV During operation of a solid state detector an x ray photon strikes a biased solid state crystal and loses energy in the crystal by producing electron hole pairs The electric charge produced is collected and provides a current pulse that is directly proportional to the energy of the x ray photon absorbed by the crystal of the detector A gas filled proportional counter detector is an ionization chamber filled with a mixture of noble and other gases An x ray photon entering the chamber ionizes the gas atoms The electric charge produced is collected and provides an electric signal that is directly proportional to the energy of the x ray photon absorbed by the gas in the detector 6 1 4 Data processing units The key component in the data processing unit of an FPXRF
84. RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS123 Revision No 1 Date of Revision 9 21 06 Shaw shaw Page 2 of 3 6 PROCEDURE Always tie off to rails or hooks
85. Shaw shaw Environmental Inc Project No 144531 Revised Site Investigation Work Plan Sportsman s Park 735 South West Street Naperville Illinois Prepared for Naperville Park District 320 West Jackson Avenue Naperville Illinois January 2012 Revised Site Investigation Work Plan Sportsman s Park 735 South West Street Naperville Illinois 60540 Shaw Project No 144531 January 2012 Prepared for Naperville Park District 320 West Jackson Avenue Naperville Illinois 60540 Prepared by Shaw shaw Environmental Inc 1607 E Main St Suite E St Charles Illinois 60174 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 Table of Contents INTRODUCTION eR RR RE RU Ee 1 1 1 Background Information esses eene aS Rum nun Saa 2 s 1 SGOPE OF WORK S s e de UB EN E e I SSS S 2 2 1 Site Investigation Objectives oo eee u un L Susu a hua usa a 2 FIELD INVESTIGATIONS nana nunus REA eR EN e e 3 3 1 Bata Gollection dct ederet OU ERE RR NH t UE 3 3 2 Sample Collection amp Field Screening Procedures l nn 3 3 21 Surface Near Surface Soil Sampling sse 3 3 22 XRF Field Screening set S eh ARR Nena RR e 5 3 2 3 Sediment Sampling x s eese ee deni d 6 3 2 4 Bulk Soil Samples sd dee eL RR REED eee 6 3 2 5 Soil Borings amp Monitoring Well Installation sse 7 3 2 6 Groundwater Sampling
86. Suite Appendices Appendix A Regulatory Documentation Appendix B Example Field Data Forms Appendix C Shaw Standard Operation Procedures Appendix D USEPA Method 6200 1 0 INTRODUCTION The purpose of this Revised Site Investigation Work Plan Work Plan is to convey the strategies and methodologies that will be used to collect and analyze soil sediment and groundwater samples from Sportsman s Park located at 735 South West Street Naperville Illinois hereinafter referred to as the Site The Site location is shown on Figure 1 The objective of this work plan is to convey the methods and rationale associated with performing the proposed data collection activities Soil sediment surface water and groundwater sampling methodology will be performed in a manner consistent with lllinois Environmental Protection Agency IEPA Site Remediation Program SRP regulations and supplemental guidance as applicable This Work Plan is being submitted to the IEPA SRP Shaw Environmental Inc Shaw and the Naperville Park District NPD desire this investigation and future investigations and or remediation that may be warranted be performed in consultation with the IEPA SRP It is the NPD s intent to ultimately receive a Focused No Further Remediation NFR determination for the Site for the following constituents Polynuclear Aromatics PNAs Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver Antimony Copper and Zinc
87. TA Hazardous Samples 1 PURPOSE The purpose of this procedure is to provide general instructions for packaging and shipping of hazardous samples as defined by DOT and or IATA including Class 9 Environmentally hazardous substances The primary use of this procedure is for the transportation of samples collected on site to be sent off site for physical chemical biological infectious substance and or radiological analysis in accordance with applicable laws and regulations and without destroying sample integrity 2 SCOPE This procedure applies to the packaging and shipping of all DOT IATA hazardous samples Samples must be packaged and shipped as hazardous materials if they meet any of the hazard class definitions in 49 CFR 107 178 including Reportable Quantities and or if they can be classified as a Dangerous Good under IATA All IATA classified materials designated for air transport even in Limited Quantities must be declared packaged and shipped as Dangerous Goods Examples include methanolic VOC soil samples and any samples from a project facility known to be impacted by an infectious substance Improper shipment of hazardous materials especially willful misrepresentation and shipment as non hazardous materials is a violation of federal law and is punishable by fines and possible imprisonment of guilty parties It is also a violation of Shaw E amp I policy and can result in disciplinary action up to and including termination of
88. absorption and enhancement effects iron Fe tends to absorb copper Cu x rays reducing the intensity of the Cu measured by the detector while chromium Cr will be enhanced at the expense of Fe because the absorption edge of Cr is slightly lower in energy than the fluorescent peak of iron The effects can be corrected mathematically through the use of fundamental parameter FP coefficients The effects also can be compensated for using SSCS which contain all the elements present on site that can interfere with one another 4 6 When present in a sample certain x ray lines from different elements can be very close in energy and therefore can cause interference by producing a severely overlapped spectrum The degree to which a detector can resolve the two different peaks depends on the energy resolution of the detector If the energy difference between the two peaks in electron volts is less than the resolution of the detector in electron volts then the detector will not be able to fully resolve the peaks The most common spectrum overlaps involve the K line of element Z 1 with the K line of element Z This is called the K K interference Because the K K intensity ratio for a given element usually is about 7 1 the interfering element Z 1 must be present at large concentrations to cause a problem Two examples of this type of spectral interference involve the presence of large concentrations of vanadium V when attempting to measure Cr or
89. aining Course Handout DEFINITIONS Custody The legal term used to define the control and evidence traceability of an environmental sample A sample is considered to be in one s custody if it is in actual physical possession of the person is in view of the person has been locked in a container controlled by the person or has been placed into a designated secure area by the person Custody Seal Commercially available thin strips of adhesive paper with write in lines for the date time and identification of the using party Custody seals are placed over the caps of sample containers and along the cover seals of shipping containers as a means to detect tampering before arrival at the testing facility All Shaw E amp strategic alliance laboratories provide Custody Seals in their sample container supply kits RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS005 Revision No 1 Date of Revision 9 8 06 Shaw shaw
90. al description Analyses requested Photograph Log Calibration Date Sampling Equipment Equipment Decontamination Technique Analytical Laboratory Field Technician Print Page 1 of 1 Shaw shaw E Surface Water Field Logsheet FS002 3_0 Site Name Project Sample ID Sample Location Sketch Date Sampled Time Sampled Depth ft below surface 1 gt Field Technician Print Page 1 of 1 Shaw shaw Air Field Logsheet FS002 4_0 Site Name Project Sample Location Sketch Sample ID Date Sampled Time Sampled Sampling Technique Photograph Log Temperature Sampling Equipment Equipment Decon Technique QC Samples Analytical Laboratory Field Technician Print Page 1 of 1 Procedure No EI FS003 Revision No 1 Date of Revision 9 8 06 Shaw Shaw Page 10f4 STANDARD OPERATI NG PROCEDURE Subject Chain of Custody Documentation Paper 5 1 PURPOSE The purpose of this procedure is to provide the requirements for completion of written Chain of Custody COC documentation and to provide a suggested Chain of Custody Form for project use SCOPE This procedure is applicable to all Shaw E amp efforts where samples are transferred among parties including to off site testing facilities Adherence to this procedure is not required whenever the same individual team is performing th
91. al testing 2 SCOPE This procedure applies to all instances where non disposable direct contact sampling equipment is utilized for sample collection and no project specific procedure is in place This procedure is not intended to address decontamination of peristaltic or other sampling pumps and tubing The steps outlined in this procedure must be executed between each distinct sample data point 3 REFERENCES U S Environmental Protection Agency Region 4 2001 Environmental Investigations Standard Operating Procedures and Quality Assurance Manual 980 College Station Road Athens Georgia November US Army Corp of Engineers Washington D C 2001 Requirements for the Preparation of Sampling and Analysis Plans EM 200 1 3 February 4 DEFINITIONS Soap A standard brand of phosphate free laboratory detergent such as Liquinox Organic Desorbing Agent A solvent used for removing organic compounds The specific solvent would depend upon the type of organic compound to be removed See Attachment 1 for recommendations Inorganic Desorbing Agent An acid solution for use in removing trace metal compounds The specific acid solution would depend upon the type of inorganic compound to be removed See Attachment 1 for recommendations Tap water Water obtained from any municipal water treatment system An untreated potable water supply can be used as a substitute for tap water if the water does not contain the
92. alibration is necessary then SSCSs must be collected prepared and analyzed 7 3 1 The SSCS must be representative of the matrix to be analyzed by FPXRF These samples must be well homogenized A minimum of 10 samples spanning the concentration ranges of the analytes of interest and of the interfering elements must be obtained from the site A sample size of 4 to 8 ounces is recommended and standard glass sampling jars should be used 6200 11 Revision 0 February 2007 7 3 2 Each sample should be oven dried for 2 to 4 hr at a temperature of less than 150 C If mercury is to be analyzed a separate sample portion should be dried at ambient temperature as heating may volatilize the mercury When the sample is dry all large organic debris and nonrepresentative material such as twigs leaves roots insects asphalt and rock should be removed The sample should be homogenized see Sec 7 3 3 and then a representative portion ground with a mortar and pestle or other mechanical means prior to passing through a 60 mesh sieve Only the coarse rock fraction should remain on the screen 7 3 3 The sample should be homogenized by using a riffle splitter or by placing 150 to 200 g of the dried sieved sample on a piece of kraft or butcher paper about 1 5 by 1 5 feet in size Each corner of the paper should be lifted alternately rolling the soil over on itself and toward the opposite corner The soil should be rolled on itself 20 times Approximatel
93. alifier 1 If confined to one Surrogate in a fraction Data is acceptable 2 If surrogate YR values are at least 80 of acceptance limits Datta is acceptable VERIFICATION or CLOSURE ANALYSIS No effect on data Corrrrent LCB cortarrination If MS MISD are acceptable or Surrogates are acceptable Data accepted If MSD and LCS acceptable and Surrogates or Post spike within range Datta is accepted with precision qualifier Procedure No EI FS020 Attachment No 1 Result Within 10 0f or Above Actiondevel If Surrogate R is greater than 120 of acceptance lirrit Data is unacceptable If LCB is greater than 10 of action level or sarrple result Data is unacceptable If MS MSD are acceptable or Surrogates are acceptable Data accepted If MS MSD are acceptable or Surrogates are acceptable gt Data accepted evaluate potential bias in reported result If MSD and LCS acceptable and Surrogates or Post spike within range Datta is accepted with precision qualifier Result Greater than 1076 Above Actiondevd No effect on data No effect on data If LCB is greater than 10 of actior level or sarrple result Data is unacceptable If MS MSD are acceptable or Surrogates are acceptable Data accepted If MS MSD are acceptable or Surrogates are acceptable Data accepted If MSD and LCS acceptable and Surrogates or Post spike within range Datta is accepted with precision qualifier Matrix Spik
94. ample weight can be obtained Care should be taken to avoid sample cross contamination and these measures can be evaluated by including an appropriate method blank sample along with any sample preparation process 6200 19 Revision 0 February 2007 CAUTION Microwave drying is not a recommended procedure Field studies have shown that microwave drying can increase variability between the FPXRF data and confirmatory analysis High levels of metals in a sample can cause arcing in the microwave oven and sometimes slag forms in the sample Microwave oven drying can also melt plastic containers used to hold the sample 11 6 The homogenized dried sample material should be ground with a mortar and pestle and passed through a 60 mesh sieve to achieve a uniform particle size Sample grinding should continue until at least 90 percent of the original sample passes through the sieve The grinding step normally takes an average of 10 min per sample An aliquot of the sieved sample should then be placed in a 31 0 mm polyethylene sample cup or equivalent for analysis The sample cup should be one half to three quarters full at a minimum The sample cup should be covered with a 2 5 uim Mylar or equivalent film for analysis The rest of the soil sample should be placed in a jar labeled and archived for possible confirmation analysis All equipment including the mortar pestle and sieves must be thoroughly cleaned so that any cross contamination is below the
95. ampling each sample must be entered on the COC form at the time of collection in order to document possession The sampler must not wait until sampling is completed before entering samples on the COC Complete the Sample ID Number for each line If there are multiple container types for a sample use additional lines to indicate the needed information Ensure that the Sample Description matches the description on the sample label the laboratory will use this information for cross referencing Provide the Collection Date and Time These must match those on the sample label and Field Logbook Logsheets Indicate whether the sample is a Grab or Composite sample Indicate the Matrix of the sample Use the Matrix Codes listed on the Chain of Custody form Indicate the Number of Containers and the Container Type f a sample has multiple container types use multiple lines and cross out the information spaces to the left of the container blocks Failure to do this may cause the laboratory to log in each container type as a separate sample lab ID resulting in a confused report and invoice Alternatively if each sample has the same number type container types use various in the Container Type block and provide detail in the Special Instructions section e g Each sample consists of one 16 oz jar two pre weighed VOC w DI water and one pre weighed VOC w Methanol Check the appropriate Preservative box for each line container type Writ
96. analysis begins on each working day after every 20 samples are analyzed and at the end of sampling This verification is performed by analyzing either an NIST SRM or an SSCS that is representative of the site specific samples This SRM or SSCS serves as a calibration check A manufacturer recommended count time per source should be used for the calibration check The analyst must then adjust the y intercept and slope of the calibration curve to best fit the known concentrations of target analytes in the SRM or SSCS A percent difference 96D is then calculated for each target analyte The 96D should be within 20 percent of the certified value for each analyte If the D falls outside this acceptance range then the calibration curve should be adjusted by varying the slope of the line or the y intercept value for the analyte The SRM or SSCS is reanalyzed until the D falls within 20 percent The group of 20 samples analyzed before an out of control calibration check should be reanalyzed The equation to calibrate D is as follows 96D C C C x 100 where D Percent difference C Certified concentration of standard sample C Measured concentration of standard sample 10 2 2 BFP calibration BFP calibration relies on the ability of the liquid nitrogen cooled Si Li solid state detector to separate the coherent Compton and incoherent Rayleigh backscatter peaks of primary radiation These peak intensities are known to be a
97. anual may be employed provided that method performance appropriate for the intended application has been demonstrated and documented 6 1 FPXRF spectrometer An FPXRF spectrometer consists of four major components 1 a source that provides x rays 2 a sample presentation device 3 a detector that converts x ray generated photons emitted from the sample into measurable electronic signals and 4 a data processing unit that contains an emission or fluorescence energy analyzer such as an MCA that processes the signals into an x ray energy spectrum from which elemental concentrations in the sample may be calculated and a data display and storage system These components and additional optional items are discussed below 6 1 1 Excitation sources FPXHF instruments use either a sealed radioisotope source or an x ray tube to provide the excitation source Many FPXRF instruments use sealed radioisotope sources to produce x rays in order to irradiate samples The FPXRF instrument may contain between one and three radioisotope sources Common radioisotope sources used for analysis for metals in soils are iron Fe 55 Fe cadmium Cd 109 Cd americium Am 241 4 Am and curium Cm 244 Cm These sources may be contained in a probe along with a window and the detector the probe may be connected to a data reduction and handling system by means of a flexible cable Alternatively the sources window and detector may be included in the same unit
98. apter 1 and the Clean Water Act CWA the above named permittee is hereby authorized to discharge at the above location to the above named receiving stream in accordance with the standard conditions and attachments herein Permittee is not authorized to discharge after the above expiration date In order to receive authorization to discharge beyond Ihe expiration date the permittee shall submit the proper application as required by the Illinois Environmental Protection Agency IEPA not later than 180 days prior to the expiration date SAK MEL 10061603 bah Alan Keller P E Manager Permit Section Division of Water Pollution Control Page 2 at ail limes as follows PARAMETER Outfalls 001 Shooting Stations and Shot Fall Area Intermittent Discharge of Stormwater Flow pH Lead Priority Pollutant PNA s See Special Condition 7 See Special Condition 14 NPDES Permit No 1L0073253 Effluent Limitations and Monitoring 1 From the effective date of this permit until the expiration date the effluent of the following discharge s shall be monitored and limited LOAD LIMITS Ibs day DAF DMF 30 DAY DAILY AVERAGE See Special Condition 1 MAXIMUM AVERAGE CONCENTRATION LIMITS mg l DAILY MAXIMUM Monitor Only Monitor Only Monitor Only SAMPLE SAMPLE FREQUENCY TYPE Measure When Monitoring 1 Month Grab 1 Month Grab 1 Month Grab Page 3 NPDES Permit No IL0073253 Special Conditions SPEC
99. as the data reduction and handling system The relative strength of the radioisotope sources is measured in units of millicuries mCi All other components of the FPXRF system being equal the stronger the source the greater the sensitivity and precision of a given instrument Radioisotope sources undergo constant decay In fact it is this decay process that emits the primary x rays used to excite samples for FPXRF analysis The decay of radioisotopes is measured in half lives The half life of a radioisotope is defined as the length of time required to reduce the radioisotopes strength or activity by half Developers of FPXRF technologies recommend source replacement at regular intervals based on the source s half life This is due to the ever increasing time required for the analysis rather than a decrease in instrument performance The characteristic x rays emitted from each of the different sources have energies capable of exciting a certain range of analytes in a sample Table 2 summarizes the characteristics of four common radioisotope sources X ray tubes have higher radiation output no intrinsic lifetime limit produce constant output over their lifetime and do not have the disposal problems of radioactive sources but are just now appearing in FPXRF instruments An electrically excited x ray tube operates by bombarding an anode with electrons accelerated by a high voltage The electrons gain an energy in electron volts equal to the acceler
100. at least two decimal places is necessary Concentrated ICP or AA standard solutions can also be used to make standards These solutions are available in concentrations of 10 000 parts per million thus only small volumes have to be added to the soil An empirical calibration using SSCS involves analysis of SSCS by the FPXRF instrument and by a conventional analytical method such as ICP or AA A total acid digestion procedure should be used by the laboratory for sample preparation Generally a minimum of 10 and a maximum of 30 well characterized SSCS site typical standards or prepared metal oxide standards are necessary to perform an adequate empirical calibration The exact number of standards depends on the number of analytes of interest and interfering elements Theoretically an empirical calibration with SSCS should provide the most accurate data for a site because the calibration compensates for site specific matrix effects The first step in an empirical calibration is to analyze the pure element standards for the elements of interest This enables the instrument to set channel limits for each element for spectral deconvolution Next the SSCS site typical standards or prepared metal oxide standards are analyzed using a count time of 200 seconds per source or a count time recommended by the manufacturer This will produce a spectrum and net intensity of each analyte in each standard The analyte concentrations for each standard are then entered
101. ating voltage and can excite atomic transitions in the anode which then produces characteristic x rays These characteristic x rays are emitted through a window which contains the vacuum necessary for the electron acceleration An important difference between x ray tubes and radioactive sources is that the electrons which bombard the anode also produce a continuum of x rays across a broad range of energies in addition to the characteristic x rays This continuum is weak compared to the characteristic x rays but can provide substantial excitation since it covers a broad energy range It has the undesired property of producing background in the spectrum near the analyte x ray lines when it is scattered by the sample For this reason a filter is often used between the x ray tube and the sample to suppress the continuum radiation while passing the characteristic x rays from the anode This filter is sometimes incorporated into the window of the x ray tube The choice of 6200 9 Revision 0 February 2007 accelerating voltage is governed both by the anode material since the electrons must have sufficient energy to excite the anode which requires a voltage greater than the absorption edge of the anode material and by the instrument s ability to cool the x ray tube The anode is most efficiently excited by voltages 2 to 2 5 times the edge energy most x rays per unit power to the tube although voltages as low as 1 5 times the absorption edge energy will wo
102. ay and at any other time when the instrument operator believes that drift is occurring during analysis A pure element such as iron manganese copper or lead is often used for the energy calibration check A manufacturer recommended count time per source should be used for the check 9 2 2 The instrument manufacturer s manual specifies the channel or kiloelectron volt level at which a pure element peak should appear and the expected intensity of the peak The intensity and channel number of the pure element as measured using the source should be checked and compared to the manufacturer s recommendation If the energy calibration check does not meet the manufacturer s criteria then the pure element sample should be repositioned and reanalyzed If the criteria are still not met then an energy calibration should be performed as described in the manufacturer s manual With some FPXHRF instruments once a spectrum is acquired from the energy calibration check the peak can be optimized and realigned to the manufacturer s specifications using their software 9 3 Blank samples Two types of blank samples should be analyzed for FPXRF analysis specifically instrument blanks and method blanks 9 3 1 An instrument blank is used to verify that no contamination exists in the spectrometer or on the probe window The instrument blank can be silicon dioxide a polytetraflurorethylene PTFE block a quartz block clean sand or lithium carbonate This inst
103. ay not be reproduced without express written permission of the company Procedure No EI FS124 Revision No 1 Date of Revision 9 21 06 Shaw shaw Page 2 of 3 5 2 Project Responsibility Shaw E amp employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw E amp employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records 6 PROCEDURE Safety Notes These sampling devices are spring activated they close with great force and are capable of causing injury Care should be used when opening and securing these devices in the ready position Do not handle by the trip line and always transport in the closed position Always use proper life saving equipment and personnel numbers when sampling from a boat or barge Consult the project Health and Safety Plan for requirements 6 1 Equipment The following equipment should be used when sampl
104. brated and the batch of samples analyzed before the unacceptable calibration verification check must be reanalyzed 9 5 Precision measurements The precision of the method is monitored by analyzing a sample with low moderate or high concentrations of target analytes The frequency of precision measurements will depend on the data quality objectives for the data A minimum of one precision sample should be run per day Each precision sample should be analyzed 7 times in replicate It is recommended that precision measurements be obtained for samples with varying concentration ranges to assess the effect of concentration on method precision Determining method precision for analytes at concentrations near the site action levels can be extremely important if the FPXRF results are to be used in an enforcement action therefore selection of at least one sample with target analyte concentrations at or near the site action levels or levels of concern is recommended A precision sample is analyzed by the instrument for the same field analysis time as used for other project samples The relative standard deviation RSD of the sample mean is used to assess method precision For FPXRF data to be considered adequately precise the RSD should not be greater than 20 percent with the exception of chromium RSD values for chromium should not be greater than 30 percent If both in situ and intrusive analytical techniques are used during the course of one day it is
105. ce are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS010 Revision No 1 Date of Revision 9 8 06 Shaw shaw E amp 1 Page 2 of 3 6 PROCEDURE Sampling equipment materials shall be selected so as to minimize contamination of samples Sampling equipment shall be either new never used previously documented to have been decontaminated or dedicated to each specific sampling point Samples for organic constituent compound analysis should be collected and mixed using non reactive material such as glass or stainless steel bowls trowels and or spoons Samples for metals analysis should be collected and mixed using equipment made of stainless steel glass
106. cedures used in FPXRF analyses should follow the guidelines in Chapter Three Inorganic Analytes 9 0 QUALITY CONTROL 9 1 Follow the manufacturer s instructions for the quality control procedures specific to use of the testing product Refer to Chapter One for additional guidance on quality assurance QA and quality control QC protocols Any effort involving the collection of analytical data should include development of a structured and systematic planning document such as a Quality Assurance Project Plan QAPP or a Sampling and Analysis Plan SAP which translates project objectives and specifications into directions for those that will implement the project and assess the results 9 2 Energy calibration check To determine whether an FPXRF instrument is operating within resolution and stability tolerances an energy calibration check should be run The energy calibration check determines whether the characteristic x ray lines are shifting 6200 12 Revision 0 February 2007 which would indicate drift within the instrument As discussed in Sec 4 10 this check also serves as a gain check in the event that ambient temperatures are fluctuating greatly more than 10 F 9 2 1 The energy calibration check should be run at a frequency consistent with manufacturer s recommendations Generally this would be at the beginning of each working day after the batteries are changed or the instrument is shut off at the end of each working d
107. ch analyst must demonstrate the ability to generate acceptable results with this method 2 0 SUMMARY OF METHOD 2 1 The FPXRF technologies described in this method use either sealed radioisotope sources or x ray tubes to irradiate samples with x rays When a sample is irradiated with x rays the source x rays may undergo either scattering or absorption by sample atoms This latter process is known as the photoelectric effect When an atom absorbs the source x rays the incident radiation dislodges electrons from the innermost shells of the atom creating vacancies The electron vacancies are filled by electrons cascading in from outer electron shells Electrons in outer shells have higher energy states than inner shell electrons and the outer shell electrons give off energy as they cascade down into the inner shell vacancies This rearrangement of electrons results in emission of x rays characteristic of the given atom The emission of x rays in this manner is termed x ray fluorescence Three electron shells are generally involved in emission of x rays during FPXRF analysis of environmental samples The three electron shells include the K L and M shells A typical emission pattern also called an emission spectrum for a given metal has multiple intensity peaks generated from the emission of K L or M shell electrons The most commonly measured x ray emissions are from the K and L shells only metals with an atomic number greater than 57 have meas
108. constituents of concern Distilled Water Water that has been purified via distillation Distilled water can be purchased in most stores and is acceptable as a final rinse in non trace analytical decontamination processes Examples would include disposal profiling HazCat and other gross screening applications Analyte free water Water that has been treated by passing through a standard deionizing resin column and for organics either distillation or activated carbon units At a minimum the finished water should contain no detectable heavy metals or other inorganic compounds and or no detectable organic compounds i e at or above analytical detection limits Type and Type Il Reagent Grade Water meet this definition as does most laboratory supplied blank water This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS014 Revision No 1 Date of Revision 9 8 06 Shaw Shaw E amp Page 2 of 2 5 1 5 2 RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be sent to the Field Sampling Discipline Lead Project Responsib
109. cost of requiring an extra person on site to prepare samples must be balanced with the gain in data quality and sample throughput 13 8 The following documents may provide additional guidance and insight on this method and technique 13 8 1 A D Hewitt Screening for Metals by X ray Fluorescence Spectrometry Response Factor Compton K Peak Normalization Analysis American Environmental Laboratory pp 24 32 1994 13 8 2 S Piorek and J R Pasmore Standardless In Situ Analysis of Metallic Contaminants in the Natural Environment With a PC Based High Resolution Portable X Ray Analyzer Third International Symposium on Field Screening Methods for Hazardous Waste and Toxic Chemicals Las Vegas Nevada February 24 26 1993 Vol 2 pp 1135 1151 1993 13 8 8 S Shefsky Sample Handling Strategies for Accurate Lead in soil Measurements in the Field and Laboratory International Symposium of Field Screening Methods for Hazardous Waste and Toxic Chemicals Las Vegas NV January 29 31 1997 6200 23 Revision 0 February 2007 14 0 POLLUTION PREVENTION 14 1 Pollution prevention encompasses any technique that reduces or eliminates the quantity and or toxicity of waste at the point of generation Numerous opportunities for pollution prevention exist in laboratory operation The EPA has established a preferred hierarchy of environmental management techniques that places pollution prevention as the management option of first choice Whenever
110. cribed in Sec 7 3 The two FP calibration processes discussed below are based on an effective energy FP routine and a back scatter with FP BFP routine Each FPXRF FP calibration process is based on a different iterative algorithmic method The calibration procedure for each routine is explained in detail in the manufacturer s user manual for each FPXHRF instrument in addition training courses are offered for each instrument 6200 15 Revision 0 February 2007 10 2 1 Effective energy FP calibration The effective energy FP calibration is performed by the manufacturer before an instrument is sent to the analyst Although SSCS can be used the calibration relies on pure element standards or SRMs such as those obtained from NIST for the FP calibration The effective energy routine relies on the spectrometer response to pure elements and FP iterative algorithms to compensate for various matrix effects Alpha coefficients are calculated using a variation of the Sherman equation which calculates theoretical intensities from the measurement of pure element samples These coefficients indicate the quantitative effect of each matrix element on an analyte s measured x ray intensity Next the Lachance Traill algorithm is solved as a set of simultaneous equations based on the theoretical intensities The alpha coefficients are then downloaded into the specific instrument The working effective energy FP calibration curve must be verified before sample
111. d field logbook shall be submitted to the project records file Restrictions Limitations Field logbooks constitute the official record of on site technical work investigations and data collection activities Their use control and ownership are restricted to activities pertaining to specific field operations carried out by Shaw personnel and their subcontractors They are documents that may be used in court to indicate and defend dates personnel procedures and techniques employed This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS001 Revision No 1 Date of Revision 9 8 06 Shaw Shaw Page 5of5 during site activities Entries made in these notebooks should be factual clear precise and as non subjective as possible Field logbooks and entries within are not to be utilized for personal use 7 ATTACHMENTS Attachment 1 Common Data Error Codes 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No Attachment No Shaw Shaw
112. d allows field personnel to adapt the sampling strategy in reaction to XRF readings Prior to use at the Site a Site specific Radiation Protection Plan RPP will be developed and prepared by Shaw for the XRF Spectrometer screening activities Only certified and trained XRF operators shall be allowed to use the XRF screening instrumentation General Procedures for XHF Screening Analysis e The field portable XRF detector will be operated and maintained in accordance with procedures outlined in the operator s manual accompanying the instrument in accordance with the Shaw Standard Operating Procedures and requirements of the Site Specific RPP e Calibration and standardization of the XRF detector will be performed according to the instrument manufacturer s instructions and at a frequency consistent with the manufacturer s recommendations e Field personnel will follow quality assurance and quality control protocols defined in EPA Method 6200 refer to Appendix C including energy calibration checks blank samples analysis calibration verification checks precision sample analysis calculation of site specific method detection and quantitation limits e Applicable Total Metals concentration data will be collected for 60 seconds by the XRF operator At 60 seconds concentration and standard deviation measurements will be recorded in the field logbook and in instrument memory for later downloading e At each sampling location a soil sample w
113. d transfer the sample directly into the sample container s Cap the sample container s label the containers complete the documentation and place the containers into the sample cooler This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS101 Revision No 1 Date of Revision 9 11 06 Shaw shaw E amp Page 3 of 3 T ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS103 Revision No 1 Date of Revision 9 11 06 Shaw shaw Page 10f3 STANDARD OPERATI NG PROCEDURE Subject Soil Sampling using a Soil Probe or Core Type Sampler 1 PURPOSE The purpose of this document is to provide the methods and procedure for sampling of soils and other solids using soil probes and core type devices These samplers can be used when matrices are composed of relatively soft and non cemented formations They are utilized to collect near surface core samples and can also be placed into boreholes at specified depths Soil probe corer
114. dge L absorption edge or M absorption edge energy The absorption edge energy is somewhat greater than the corresponding line energy Actually the K absorption edge energy is approximately the sum of the K L and M line energies of the particular element and the L absorption edge energy is approximately the sum of the L and M line energies FPXHF is more sensitive to an element with an absorption edge energy close to but less than 6200 3 Revision 0 February 2007 the excitation energy of the source For example when using a cadmium 109 source which has an excitation energy of 22 1 kiloelectron volts keV FPXRF would exhibit better sensitivity for zirconium which has a K line energy of 15 77 keV than to chromium which has a K line energy of 5 41 keV 2 2 Under this method inorganic analytes of interest are identified and quantitated using a field portable energy dispersive x ray fluorescence spectrometer Radiation from one or more radioisotope sources or an electrically excited x ray tube is used to generate characteristic x ray emissions from elements in a sample Up to three sources may be used to irradiate a sample Each source emits a specific set of primary x rays that excite a corresponding range of elements in a sample When more than one source can excite the element of interest the source is selected according to its excitation efficiency for the element of interest For measurement the sample is positioned in front of the prob
115. e conditions and terms specified in this letter Issuance of this focused No Further Remediation Letter Letter signifies a release from further responsibilities under the Act in performing remedial actions The Letter shall be considered prima facic evidence that the remediation sites described in the attached Site Remediation Program SRP Environmental Notice and shown in the attached Site Base Map do not constitute a threat to human health and the environment for the specified recognized environmental conditions so long as the site is utilized in accordance with the terms of this Letter Printed on Recycled Paper Page 2 CONDITIONS AND TERMS OF APPROVAL LEVEL OF REMEDIATION AND LAND LIMITATION 1 The recognized environmental conditions as characterized by the investigation consist of the following a Regulated Substances of Concern that have been successfully addressed are detailed in the Soil and Groundwater Analysis of Naperville Sportsman s Club and Adjacent Properties 05 08 07 97 566 b Regulated Substances of Concern are the following CAS No Chemica e 7439 92 1 Lead 2 In accordance with Section 58 8 c and 58 10 b 3 of the Act 415 ILCS 5 58 8 c and 415 ILCS 5 58 10 b 3 respectively the remediation sites described in the attached SRP Environmental Notice and shown on the attached Site Base Map of this Letter is limited to residential uses 3 The land use specified in this Letter may be revised if
116. e 2 of 5 6 1 6 2 6 3 detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE General Each site or operation as applicable will have one current Logbook which will serve as an index of all activities performed at the site or in the task performance The Logbook is initiated at the start of the first applicable activity Summary entries are made for every day that covered activities take place Multiple field logbooks may be used depending upon the number of different types of field personnel conducting work and the various activities at the site These field logbooks and the site logbooks shall be made part of the project files Information recorded in field logbooks includes observations significant events and details data calculations time weather and descriptions of the data collection activity methods instruments and results Additionally the field logbook may contain descriptions of wastes biota geologic material and site features including sketches maps or drawings as appropriate Equipment and Materials Logbook s bound with numbered pages hard covered waterproof preferred One per project or separate significant task example treatment residual composite collection Indelible black or dark blue ink pen Other items needed to perform required tasks c
117. e High YR If MSD and LCS acceptable and If MSD and LCS acceptable and If MSD and LCS acceptable and If MSD and LCS acceptable and Surrogates or Post spike within range Surrogates or Post spike within Surrogates or Post spike within range Surrogates or Post spike within Data is accepted with precision range Datta is accepted with Datta is accepted with precision qualifier range Datta is accepted with qualifier precision qualifier precision qualifier MS MSD RPD High No effect on data If sarrple result is greater then 90 If RPD is greater than 110 of If RPD is greater than 110 60f of actior level Data is unacceptable acceptance lirrit Data is unacceptable acceptance lirrit Data is unacceptable Page 3 of 4 Shaw shaw E amp I Surrogate S High 1 If confined to one Surrogate ina fraction Data is acceptable 2 If surrogate R values are at least 80 of acceptance lirrits Data is acceptable 1 If confined to one Surrogate ina fraction Data is acceptable 2 If surrogate YR values are within 20 of acceptance lirrits Data is acceptable 1 If confined to one Surrogate ina fraction Data is acceptable 2 If surrogate R values are at least 80 of acceptance limits Data is acceptable 1 If confined to one Surrogate ina fraction Data is acceptable 2 If surrogate R values are within 20 of acceptance lirrits and other QC is within acceptance linits Data is acceptable Page 4 of 4 Actionleve
118. e for following appropriate portions of this SOP This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS101 Revision No 1 Date of Revision 9 11 06 Shaw shaw E amp I Page 2 of 3 For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records 6 PROCEDURE 6 1 Equipment Decontaminated trowel or spoon stainless steel construction for trace environmental sampling If samples will be collected at depth 0 6 inches the trowel or spoon will require decontamination prior to collection of the targeted depth sample Alternatively a different trowel or spoon can be used to remove the material to the targeted depth and the sample collected using a clean dedicated trowel or spoon Engineers rule or stiff measuring tape Decontaminated stainless steel mixing bowl 6 2 Sampling 1
119. e in and check the Analyses Hequested boxes for each line container type The appropriate method number e g EPA Method 8260C must be written as well as the method name Indicate the Turn around Time Requested for each sample Use the Special Instructions section to provide important information to the laboratory e g samples that may require dilution or samples that will need to be composited by the laboratory This section may also be used to inform the laboratory of additional information contained in attachments to the Chain of Custody package Circle the appropriate QC Data Package Level requested Custody Transfer Section The first Relinquished By space must be completed by the individual who will either transfer the samples or seal the shipping container This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS003 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 404 f the samples will be transferred to a courier write the courier carrier company in the Received By box and enter the Date and Time that the shipping container was closed All other transfers must be performed in person and the Relinquisher must witness the signing by the Receiver A copy of the Chain o
120. e placed into a cooler on ice for the duration of the daily field activities The samples will then be transported to the Shaw offices in St Charles Illinois for temporary refrigerated storage If feasible the samples will be delivered to the contract environmental laboratory the same day they are collected Otherwise Shaw will arrange to have the samples picked up and delivered to the laboratory at the next earliest opportunity 3 5 Sample Identification Shaw will implement a Site specific sample identification scheme to track the project sampling activities Each sample will be assigned a unique sample number Soil samples will be named based on their grid and or other selected sampling location as illustrated in Figure 5 Samples will be identified using the following nomenclature e A sample identified as B 1 10 12 will identify a soil sample from Boring 1 obtained from 10 12 feet e Asample identified as MW 1 will identify a groundwater sample recovered from Monitoring Well 1 e A sample identified as TR A1 TR A2 TR A3 will identify a soil sample from the trap shooting range area based on its location on the sampling grid A suffix designation of 0 6 inch 6 12 inch or 12 18 inch etc will be added to identify the representative depth interval that the sample originated from e Asample identified as SAB 1 SAB 2 SAB 3 will identify a soil sample from the former small arms backstop berm area based on
121. e providing documentation to the Agency that the Action Level exceedances were not representative of the actual levels of lead in the effluent COMPLIANCE SCHEDULE Item Compliance Date 1 Submit preliminary plan 6 months 2 Submit final plan amp apply for necessary permits 12 months 3 Initiate necessary action 15 months 4 Submit an interim status report 18 months 5 Complete plan objective 24 months Monthly DMR forms must be submitted to the Agency no later than the 15th of the following month Therefore the Compliance Date shall be calculated from the 25th day of the month in which the DMR reporting the second Action Level exceedance was due SPECIAL CONDITION 8 Grab samples shall be collected within the first thirty minutes of effluent from the storm event SPECIAL CONDITION 9 The effluent alone or in combination with other sources shall not cause a violation of any applicable water quality standard outlined in 35 Ill Adm Code 302 SPECIAL CONDITION 10 Issuance of this permit expressly prohibits the use of lead shot at this facility Use of lead shot would require modification of this permit subject to the public notice requirements outlined in 35 Ill Admin Code 309 If a barrier is proposed to prevent lead shot from entering the waters of the state design criteria must be submitted to the Agency proving that the barrier will meet Page 4 NPDES Permit No 1L0073253 Special Conditions this objective SPECIAL CONDIT
122. e sample the sleeve will most likely be submitted intact Wipe the outside of the sleeve and use a knife to cut off any material sticking from the end so that the ends are even Place Teflon tape over the ends and cap both ends Be sure to label the top and bottom of the sample interval 15 A Soil Corer sample may be submitted intact especially for geotechnical parameters If this is the case wipe the outside of the sleeve and use a knife to cut off any material sticking from the end so that the ends are even Place Teflon tape over the ends and cap labeling the sleeve and marking the top and bottom of the sample interval 16 If the Soil Corer sample will be aliquotted into other containers use a knife to split the sleeve lengthwise and remove the top section to expose the sample 17 If sampling for Volatile Organic Compounds VOCs collect sample aliquots from the intact core first using an EnCore or other syringe type device 18 Place the remaining material directly into sample jars or into a mixing bowl for homogenization and containerization Cap the sample container s label it them complete the documentation and place the sample container s into the sample cooler 19 Decontaminate the sampler 7 ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses mate
123. e sampling and testing within the same workday and transfer to the testing process is being documented by other means e g sampling and then field screening in a mobile laboratory REFERENCES U S Environmental Protection Agency 1986 Test Methods for Evaluating Solid Waste Physical Chemical Methods SW 846 Third Edition U S Army Corps of Engineers Requirements for the Preparation of Sampling and Analysis Plans EM200 1 3 Shaw E amp l 2002 Sampler s Training Course Handout DEFINITIONS Custody The legal term used to define the control and evidence traceability of an environmental sample A sample is considered to be in an individual s custody when it is in actual physical possession of the person is in view of the person is locked in a container controlled by the person or has been placed into a designated secure area by the person Chain of Custody Form A form used to document and track the custody and transfers of a sample from collection to analysis or placement in a designated secure area within the testing facility COC Continuation Page Additional page s that may be included with a Chain of Custody form The continuation page s contain the information on additional samples contained within the same cooler shipping container associated with the cooler shipping container Chain of Custody form RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is respons
124. e sediment sampling points may require the use of a field portable boat and or other sampling support platform e Each sediment sample will be properly labeled with a unique sample identification number refer to Section 3 5 Sample Identification and submitted to the offsite analytical laboratory for analysis Chain of custody forms will be completed and signed by the field representative and submitted with the samples to the analytical laboratory e Sediment samples will be submitted for laboratory analysis for RCRA 8 Total Metals Antimony Copper and Zinc select TCLP metals based on total results pH PNAs and moisture content at an offsite laboratory 3 2 4 Bulk Soil Samples Following evaluation of the initial XRF screening level data representative soil bulk samples will be collected from the trapshooting range areas and former small arms shooting range areas Samples will be taken by hand with a shovel or other similar sampling tool Each hand excavation will be completed to an approximate depth of 1 foot Two 2 composite bulk samples will be collected from the trapshooting range areas exhibiting the highest XRF indicated lead impacts and two 2 from the former small arms shooting range areas Each composite bulk sample will be placed in a clean 5 gallon plastic container and reserved for further laboratory treatability assessment testing if recommended e During the bulk sample collection activities the field investigator will
125. e used for sample preparation However in the study used to generate the performance data for this method see Table 8 the confirmatory method used was Method 3050 and the FPXRF data compared very well with regression correlation coefficients r often exceeding 0 95 except for barium and chromium The critical factor is that the digestion procedure and analytical reference method used should meet the DQOs of the project and match the method used for confirmation analysis 4 10 Ambient temperature changes can affect the gain of the amplifiers producing instrument drift Gain or drift is primarily a function of the electronics amplifier or preamplifier and not the detector as most instrument detectors are cooled to a constant temperature Most FPXHF instruments have a built in automatic gain control If the automatic gain control is allowed to make periodic adjustments the instrument will compensate for the influence of temperature changes on its energy scale If the FPXRF instrument has an automatic gain control function the operator will not have to adjust the instrument s gain unless an error message appears If an error message appears the operator should follow the manufacturer s procedures for troubleshooting the problem Often this involves performing a new energy calibration The performance of an energy calibration check to assess drift is a quality control measure discussed in Sec 9 2 If the operator is instructed by the manufacturer
126. e window This can be done in two manners using FPXRF instruments specifically in situ or intrusive If operated in the in situ mode the probe window is placed in direct contact with the soil surface to be analyzed When an FPXRF instrument is operated in the intrusive mode a soil or sediment sample must be collected prepared and placed in a sample cup The sample cup is then placed on top of the window inside a protective cover for analysis Sample analysis is then initiated by exposing the sample to primary radiation from the source Fluorescent and backscattered x rays from the sample enter through the detector window and are converted into electric pulses in the detector The detector in FPXRF instruments is usually either a solid state detector or a gas filled proportional counter Within the detector energies of the characteristic x rays are converted into a train of electric pulses the amplitudes of which are linearly proportional to the energy of the x rays An electronic multichannel analyzer MCA measures the pulse amplitudes which is the basis of qualitative x ray analysis The number of counts at a given energy per unit of time is representative of the element concentration in a sample and is the basis for quantitative analysis Most FPXRF instruments are menu driven from software built into the units or from personal computers PC The measurement time of each source is user selectable Shorter source measurement times 30 seconds
127. ed double bag the ice chips or cubes in gallon or quart size freezer Ziploc type resealable plastic bags and wedge the ice bags between the inner packages and or primary receptacles Also add bagged ice across the top of the samples receptacles This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS013 Revision No 1 Date of Revision 9 5 06 Shaw shaw Page aot 4 When sufficiently full seal the plastic bag that lines the outer packaging and place additional cushioning material on top of the bag to minimize shifting of contents during shipment Tape a gallon Ziploc type bag to the inside of the container lid place the completed chain of custody document inside and seal the bag shut Tape the outer packaging closed using packing tape duct tape or other tear resistant adhesive strips Place a custody seal on two separate portions of the outer packaging to provide evidence that the lid remains sealed during transit 6 3 Marking and Labeling If the package contains any liquids orientation arrows must be applied to two opposite faces of the package front and back or both ends The proper shipping name UN number and all other required markings as well as the appropriate hazard class
128. ent If performed Other Metals Ni Hg Cr Comments Form Completed by Signature Page 1 of 1 Shaw shaw Location ID Location Sampling Data XRF Summary of Results FS200 3_0 Site Name City State XRF Data Count sec Page 1 of 1 Conc ppm Other Metals Split to Lab Other Comments Appendix D USEPA Method 6200 Field Portable XRF Spectrometry for the Determination of Elemental Concentrations in Soil and Sediment METHOD 6200 FIELD PORTABLE X RAY FLUORESCENCE SPECTROMETRY FOR THE DETERMINATION OF ELEMENTAL CONCENTRATIONS IN SOIL AND SEDIMENT SW 846 is not intended to be an analytical training manual Therefore method procedures are written based on the assumption that they will be performed by analysts who are formally trained in at least the basic principles of chemical analysis and in the use of the subject technology In addition SW 846 methods with the exception of required method use for the analysis of method defined parameters are intended to be guidance methods which contain general information on how to perform an analytical procedure or technique which a laboratory can use as a basic starting point for generating its own detailed Standard Operating Procedure SOP either for its own general use or for a specific project application The performance data included in this method are for guidance purposes only and are not intended to be and must not be used a
129. er conducted five replicate measurements of the in situ field samples by taking measurements at five different points within the 4 inch by 4 inch sample square Ten replicate measurements were collected for both the intrusive undried and unground and intrusive dried and ground samples contained in cups The cups were shaken between each replicate measurement Table 5 shows that the precision dramatically improved from the in situ to the intrusive measurements In general there was a slight improvement in precision when the sample was dried and ground Two factors caused the precision for the in situ measurements to be poorer The major factor is soil heterogeneity By moving the probe within the 4 inch by 4 inch square 6200 21 Revision 0 February 2007 measurements of different soil samples were actually taking place within the square Table 5 illustrates the dominant effect of soil heterogeneity It overwhelmed instrument precision when the FPXRF analyzer was used in this mode The second factor that caused the RSD values to be higher for the in situ measurements is the fact that only five instead of ten replicates were taken A lesser number of measurements caused the standard deviation to be larger which in turn elevated the RSD values 13 6 Accuracy measurements Five of the FPXRF instruments not including the MAP Spectrum Analyzer analyzed 18 SRMs using the source count times and calibration methods given at the beginning of this section
130. erated Solid IDW e g used personal protective equipment will be placed in plastic garbage bags and disposed of at the Site s solid waste collection facilities 3 7 Chain of Custody Procedures Every sample obtained for laboratory analysis during this project will be logged on a Chain of Custody form The purpose of the Chain of Custody is to document the disposition of the samples from the point of collection to the point of delivery to the contract environmental laboratory The Chain of Custody form will accompany every shipment of samples to the contract environmental laboratory and will be reproduced with each laboratory analytical report As a minimum the following information will be included on the Chain of Custody form Project Name and Location Date Time of Sample Collection and Delivery to Laboratory Sample Description Sample Matrix e g soil Laboratory Analytical Suite Contact Information for Shaw Contact Information for Laboratory Signatures of Sampling Technician s and Laboratory Representative s When a Chain of Custody form is completed one page of the three page carbon form is retained and placed in the Shaw project file The other two pages of the form accompany the samples to the contract environmental laboratory The laboratory retains one page and returns the last page with the analytical report Upon receipt of the laboratory analytical report the Shaw project manager will cross check the laborator
131. ere the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS006 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 2of2 6 PROCEDURE All sample labels must be completed in indelible ink All corrections must be performed using standard single line cross out methods and the initials of the individual making the change must be included beside the corrected entry Sample labels should be completed and attached as samples are collected Do not wait until final packaging to attach and or complete the sample labels Sample labels must be attached to the non sealing portion of the container Do not place labels on or across sample container caps lf the laboratory has provided pre labeled containers make sure to fill one for each pa
132. ering effort this must be indicated on the form by either a single line cross out or the letters NA being written in the data line block ATTACHMENTS None FORMS Container Field Logsheet Soil Sediment Field Logsheet Surface Water Field Logsheet Air Field Logsheet This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Shaw shaw E amp I Container Field Logsheet FS002 1_0 Date Time Site Container Number Project Container Size Weather Container Location Photograph Container material of construction plastic glass metal fiberboard Container condition intact bulging 0 Lid type screw bung ring Lid material of construction plastic glass metal fiberboard Labels manufacturer address content name chemical name chemical formula other flammability reactivity PID Calibration Date Contents Description Sample Number Preservative QC Samples Page 1 of 1 Shaw shaw Soil Sediment Field Logsheet FS002 2_0 Site Name Project Sample ID Sample Location Sketch Sample Type SED Sediment SUR Surface soil SUB Subsurface Soil OTH Other grab Grab comp Composite Date Sampled Time Sampled Depth ft bgs Physic
133. ers for the corporgion i2 Fer m partnership or sole propristoratop by a genere partner or the propnator respectively or For municipality Sute Federal or other public agency by ver a pracipal executive officer of raniong elected official b Reporta Allreporis rwquirwd by permis Dr other information requested by the Agancy shall be sgned by a person destnbed m paragraph a or by a daly authonzed 5 of thal person A person a duly authonzed recresantstve omy il I The suthorzavon is made in wnhmg by s parson dascnbed in paragraph al and 2 The zulhonzation species ethar an individual or a position responsible for ine Overall operation of tha facdiry from which ihe discharge onginales such ss a piani manager amp upanntan dent Or Person of equresient responsibility and 3 The wnttan suthonzeuon is submitted tp the Agency DN RECYCLED PAPER wa tal tel Changes of Authorization an sutnonration under b i nc longer accurate beacause a different individual or posmon nas ponsiksury or the Overall gpearspan of the imclty s new suthonish n sehsiying tha requirements of Ib cust be submitted 0 the Agency phor to of togather with any saporis information or applications tD be signed by an surhpnred x 2 Reporung requirements la Planned changes The permittere shall grve nonca Io the Agancy as soon as passible of any planned physica
134. ess of the receiver and the shipper must be on the top of the cooler The airbill must be attached to the top of the cooler 6 3 Shipping Documentation A Cooler Shipment Checklist Attachment 1 should be completed and kept in the project file 7 ATTACHMENTS Attachment 1 Shaw E amp I Cooler Shipment Checklist 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Shaw Shaw Attachment 1 Procedure No Attachment No Shaw E amp I Cooler Shipment Checklist Project Name Project Number Address EI FS012 1 Date Time Fax No Sh aw bui ite Contac oO Shaw E amp I Inc SAMPLE CHECKLIST SAMPLE LIDS ARE TIGHT AND CUSTODY SEALS IN PLACE ARE ALL SAMPLE NUMBERS DATES TIMES AND OTHER LABEL INFORMATION LEGIBLE AND COMPLETE HAVE ALL SAMPLE NUMBERS DATES TIMES AND OTHER SAMPLING DATA BEEN LOGGED INTO THE SAMPLE LOG BOOK DO SAMPLE NUMBERS AND SAMPLE DESCRIPTIONS ON THE LABELS MATCH THOSE ON THE COC HAVE THE SAMPLES BEEN PROPERLY PRESERVED HAVE THE CHAIN OF CUSTODIES BEEN FILLED OUT COMPLETELY AND CORRECTLY DOES THE ANALYTICAL SPECIFIED ON THE COC MATCH THE ANALYTICAL SPECIFIED IN THE SCOPE OF WORK HAVE THE COC S BEEN PR
135. established lower limit of detection of the procedure or DQOs of the analysis If all recommended sample preparation steps are followed there is a high probability the desired laboratory data quality may be obtained 12 0 DATA ANALYSIS AND CALCULATIONS Most FPXRF instruments have software capable of storing all analytical results and spectra The results are displayed in ppm and can be downloaded to a personal computer which can be used to provide a hard copy printout Individual measurements that are smaller than three times their associated SD should not be used for quantitation See the manufacturer s instructions regarding data analysis and calculations 13 0 METHOD PERFORMANCE 13 1 Performance data and related information are provided in SW 846 methods only as examples and guidance The data do not represent required performance criteria for users of the methods Instead performance criteria should be developed on a project specific basis and the laboratory should establish in house QC performance criteria for the application of this method These performance data are not intended to be and must not be used as absolute QC acceptance criteria for purposes of laboratory accreditation 13 2 The sections to follow discuss three performance evaluation factors namely precision accuracy and comparability The example data presented in Tables 4 through 8 were generated from results obtained from six FPXRF instruments see Sec 13 3 The soi
136. etals Antimony Copper and Zinc PNAs pH and moisture content e Following XRF field screening data evaluations 46 select soil samples collected from the former small arms shooting range berm will be transferred into pre cleaned 8 oz sample containers and submitted for laboratory analysis for Total Lead pH and moisture content at an offsite laboratory An additional 10 soil samples will be transferred into pre cleaned 8 oz sample containers and submitted for laboratory analysis for RCRA 8 Total Metals Antimony Copper and Zinc PNAs pH and moisture content e Chain of custody forms will be completed and signed by the field representative and submitted with the samples to the analytical laboratory refer to Section 3 7 Chain of Custody Procedures 4 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois e Based upon Total Metals results approximately 32 select samples from various intervals will also be analyzed for various TCLP metals 3 2 8 XHF Field Screening XRF measurements of various metals concentrations within the former shooting range areas will be measured primarily ex situ using a field portable XRF detector according to USEPA Method 6200 Field Portable XRF Spectrometry for the Determination of Elemental Concentrations in Soil and Sediment Ex situ XRF analysis is a rapid testing method that can generate a large quantity of screening level quality data over a short time period an
137. ethods refer to Table 1 A GeoProbe or other IEPA approved technology may be utilized to collect soil samples underneath existing pavement e Information on the condition of the soil in the investigation areas moisture content dry moist or wet indications of lead and or steel shot bullet fragments target debris etc will be recorded in the field logbook for each sampling location Field data reporting is discussed in Section 6 0 Field Documentation section of this Work Plan e Sampling location coordinates will be recorded using a handheld GPS receiver All positional data will be recorded in the Illinois State Plane Coordinate system e Upon collection soil samples will be directly transferred into a sterile 16 ounce plastic sample bag for subsequent X Ray Fluorescence XRF field screening of Total Metals concentrations within the sample refer to Section 3 2 2 XRF Field Screening e Each bag sample will be properly labeled with a unique sample identification number refer to Section 3 5 Sample Identification e Following XRF field screening data evaluations 58 select soil samples collected from the trap shooting range areas will be transferred into pre cleaned 8 oz sample containers and submitted for laboratory analysis for Total Lead pH and moisture content at an offsite laboratory An additional 29 soil samples will be transferred into pre cleaned 8 oz sample containers and submitted for laboratory analysis for RCRA 8 Total M
138. examine the berm and or range floor excavation areas for indications of bullet pockets and record the observed conditions in the field logbook A 6 Revised Site Investigation Work Plan Sportsman s Park Shaw P Naperville Illinois e Each composite bulk sample will be passed through a number 10 sieve to initially quantify the presents of any physical lead shot bullet fragments and or shooting target debris within the impact berms Upon bulk sample screening any materials retained by the number 10 screen will be returned to the bulk sample e Each composite bulk sample will be properly labeled with a unique sample identification number refer to Section 3 5 Sample Identification Field data reporting is discussed in Section 6 0 Field Documentation 3 2 5 Soil Borings amp Monitoring Well Installation Shaw proposes to advance 7 soil borings PMW 1 through PMW 7 as illustrated on the attached Figure 5 The soil borings will be converted into 2 inch diameter monitoring wells PMW 1 through PMW 7 The purpose of the soil borings will be to vertically profile the Site subsurface geologic conditions and allow the installation of groundwater monitoring wells to assess the local groundwater conditions at the Site At the proposed well point locations soil sampling will be performed at 24 inch intervals until contact with the underlying shallow groundwater and or a saturated condition is encountered Upon contact with the water table and o
139. f Custody form and all associated Continuation Pages should be maintained in the project files T ATTACHMENTS None 8 FORMS Shaw E amp l Chain of Custody Form ShawE amp l COC Continuation Page This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Shaw shaw E amp I Project Contact Name amp phone 3 Send Report To Phone Fax Number Address City Sampler s Name s Lab Contact Name ph Collection Information Sample ID Number Sample Description Special Instructions Relinquished By Relinquished By Relinquished By Shaw E amp I Chain of Custody Form Project Number Project Name Location Purchase Order Shipment Date Waybill Airbill Number Lab Destination 5 Time G C 2 containers Container type Preservative FS003 1 0 Ref Document Page of Analyses Requested Turn Around Time Requested G C Codes QC Data Package Level Required C Composite G Grab II Ill IV Project Specific Matrix Codes Received By Received By Received By Page 1 of 2 DW Drinking Water SO Soil GW Ground Water SL Sludge WW Waste Water CP Chip Samples SW Surface Water
140. f a beneficial interest of a land trust or inter vivos trust whether revocable or irrevocable involving the remediation site Any mortgagee or trustee of a deed of trust of the owner of the remediation site or any assignee transferee or any successor in interest of the owner of the remediation site Any successor in interest of the owner of the remediation site Any transferee of the owner of the remediation site whether the transfer was by sale bankruptcy proceeding partition dissolution of marriage settlement or adjudication of any civil action charitable gift or bequest Any heir or devisee of the owner of the remediation site Any financial institution as that term is defined in Section 2 of the Illinois Banking Act and to include the Illinois Housing Development Authority that has acquired the ownership operation management or control of the remediation site through foreclosure or under the terms of a security interest held by the financial institution under the terms of an extension of credit made by the financial institution or any successor in interest thereto or In the case of a fiduciary other than a land trustee the estate trust estate or other interest in property held in a fiduciary capacity and a trustee executor administrator guardian receiver conservator or other person who holds the remediated site in a fiduciary capacity or a transferee of such party This Letter including all attachments mus
141. f all reports required by this permiL and records of all daim used to complate the appbcauion for hia parrruL for a penod of at laast 3 years from the data of ius parmi messurement report or apphcauon This penod may ba extended by rsquest o tha Agency any ime kc Records af momionng iniormauon shall includa nn Thu dais exact pisce and ums of sampling or masauraments iZ The indresduat s who performed tha sampling or measurements Tha date s amp nalyses were performed 31 14 Tha individuatls who performed the analyses 5 The snahyucni techniques or methods used and 16 The results of such anniysas la Momtonng musi ba conducted according to Les procedures approved under 40 CFR Part 136 unless othar lest proceduras have been specitiad n tha Darr Where no test procedura under 40 CFA Part 126 has bean approved ihe permittes must submit to tha Agency a lest msibed for approval The parmuttea shail calibrate snd perform mamtenance Procedures on maruto nng and analytical i ratpurnaentation at mtervala 10 erusure accuracy of measurement Signatory raquiremant All spplicahons reports ar infarmatron submitted lo tha Agency shall ba signed ang a Applicaton Af permit appiications shall be signed as follows nh For a corporation by a principal axecutiva officer of al least the laval of vica president Or person of poston having Overall responsibility for environmental matt
142. f an auger was used to expose the target depth 8 To collect the sample using a Soil Corer place the point of the assembled corer directly on the ground or in the auger hole and while holding it vertical push straight down into the soil Do not twist A slide hammer may be required for hard or stiff materials 9 A Soil Probe should be placed into the location and pushed downward with a twisting motion to allow the cutting edge to work Do not drive or hammer the sampler as this will damage the cutting tip This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS103 Revision No 1 Date of Revision 9 11 06 Shaw shw Page 3 of 3 10 Continue to force the sampler downward until either the top joint is touching the ground or the reference mark is even with the top of the auger hole This will ensure that the entire sleeve is filled with material 11 Extract the sampler by pulling upward with a slight rocking or twisting motion until the head is fully out of the hole 12 Wipe the sampler head with a cloth or towel and remove it from the T handle or extension rod 13 Disassemble the sampler and remove the sleeve Also perform any field screening desired e g PID screen 14 For a Soil Prob
143. f the company Procedure No EI FS001 Revision No 1 Date of Revision 9 8 06 Shaw shaw E81 Page 4of5 6 5 6 6 i Health and Safety issues such as PPE upgrades monitoring results near misses and incidents associated with the logbook areas j Instrumentation calibration details Entries into the field logbook shall be preceded with the time of the observation The time should be recorded frequently and at the point of events or measurements that are critical to the activity being logged All measurements made and samples collected must be recorded unless they are documented by automatic methods e g data logger or on a separate form required by an operating procedure In such cases the field logbook must reference the automatic data record or form While sampling make sure to record observations such as color and odor Indicate the locations from which samples are being taken sample identification numbers the order of filling bottles sample volumes and parameters to be analyzed If field duplicate samples are being collected note the duplicate pair sample identification numbers If samples are collected that will be used for matrix spike and or matrix spike matrix spike duplicate analysis record that information in the field logbook A sketch of the station location may be warranted All maps or sketches made in the field logbook should have descriptions of the features shown and a direction indicator There must be at lea
144. formauon which the Agency may requesl to determine whelher causa axists for modifying revoking aod camsu ng or terminating this penrit or lo elarrmena compliance with the perma Tha permittee shall also furnish 10 the Agency upon requast copies of records required 10 be kenl by this permat Inspacuon and entry The permitice shell allow an auihonzed representative of the Agency upon the presantavon of credentials and other documents as may be mequared by law 10 Enter upon tne perrnittee 3 premises where a regulated sc lity or located of conduciad or whara records must be kept under the condirons al ines permi tol Have access to and copy al reasonable umes any records hat must be kept under the conditions of ihs parmur 2 ici Inspect at reasonable tones any Inzilitias equipment including mamtonng Qr Operations regulated er required and control equipment pracuc under this parit and td Sample or monitor at rassonable umes for the purpose ol assunng permi eomphanca or as otihenwisa authonzed by tha Act any substances or parameters at any location Monitoring end records sl Samples and measurements token for tha purpose of monitonng shall ba repreaeniatve of tha momiored sclivity ibi The permuttee shall retain records of ali monitoring informanon including all calibration and maintenance records snd all original snp chan reconduygs for continuous momtanng mstrurenlauen copes o
145. function of sample composition and the ratio of the Compton to Rayleigh peak is a function of the mass absorption of the sample The calibration procedure is explained in detail in the instrument manufacturer s manual Following is a general description of the BFP calibration procedure The concentrations of all detected and quantified elements are entered into the computer software system Certified element results for an NIST SRM or confirmed and validated results for an SSCS can be used In addition the concentrations of oxygen and silicon must be entered these two concentrations are not found in standard metals analyses The manufacturer provides silicon and oxygen concentrations for typical soil types Pure element standards are then analyzed using a manufacturer recommended 6200 16 Revision 0 February 2007 count time per source The results are used to calculate correction factors in order to adjust for spectrum overlap of elements The working BFP calibration curve must be verified before sample analysis begins on each working day after every 20 samples are analyzed and at the end of the analysis This verification is performed by analyzing either an NIST SRM or an SSCS that is representative of the site specific samples This SRM or SSCS serves as a calibration check The standard sample is analyzed using a manufacturer recommended count time per source to check the calibration curve The analyst must then adjust the y intercept and
146. g this technical SOP should be sent to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE Packaging Use tape and seal off the cooler drain on the inside and outside to prevent leakage Place packing material on the bottom on the shipping container cooler to provide a soft impact surface Place a large 30 55 gallon or equivalent plastic bag into the cooler to minimize possibility of leakage during transit Starting with the largest glass containers wrap each container with sufficient bubble wrap to ensure the best chance to prevent breakage of the container Pack the largest glass containers in the bottom of the cooler placing packing material between each of
147. h of the corer tube and nose piece above the bottom of the corer Slowly lower the sampler until the bottom is felt Make sure that the handle extension is straight up and push down in a straight direction to force the sampler into the bottom sediment If using a drive hammer be sure that the system is straight during each drive Continue to push drive the sampler until the mark of the extension is at water level indicating that the entire sampler has been driven into the sediment Withdraw the sampler by pulling straight up It may be necessary to twist slightly while pulling Retrieve the sampler from the water and place the corer body into the shallow pan Disassemble the sampler and retrieve the sleeve Place Teflon tape over each end and cap Label the ends Top and Bottom T B This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS123 Revision No 1 Date of Revision 9 21 06 Shaw shaw Page 3 of 3 11 Clean and dry the sleeve then attach a completed sample label document the sample and place it into an appropriate container Alternatively a plastic sleeve can be split lengthwise and then the sample retrieved Always collect volatile fractions first using a syringe type or VOC
148. h theses materials which may not be reproduced without express written permission of the company Procedure No EI FS020 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 4 of 4 6 3 6 4 6 5 Compare the reported analytes methods and detection limits to those in the project plan for the specific analyses Be sure to account for indicated and reasonable increased reporting limits due to dilutions or sample effects Address any discrepancies with the laboratory directly Compare the results to project action levels and circle or otherwise mark all results above the limits QC Level Review Consult the project Data Usability Review Checklists and or the project Chemical Quality Plan and evaluate all provided QC results against project acceptance limits Mark or flag any results that are outside of the project limits and note on the applicable checklist if using one Also evaluate any Field QC results such as Duplicates and Trip Blanks against requirements and note any issues Usability Review If all QC results for all samples are within the acceptance ranges complete the appropriate section of the checklist and then date and sign the completed checklist If all QC is acceptable and you are not using a checklist you must indicate data usability directly on the data package itself or on a separate cover sheet To do this date and initial the QC Summary pages and write QC acceptable data OK for use on the cover
149. haw shaw Page 3of3 Using clean glass pipets deliver equal volumes from each grab container to the composite sample container that is to be shipped to the lab For example if there are five grab samples and the composite sample requires 100 mL for the parameter of interest pipet 20 mL from each of the grab samples into the composite sample container Alternatively measured volumes can be determined via a graduated cylinder beaker and combined The measuring container should be decontaminated between composites Cap sealthe composite container and swirl to agitate Stirring should be avoided as it increases the risk of introducing contamination to the sample Label the sample s document the event and package ship the sample s as required T ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS012 Revision No 1 Date of Revision 9 8 06 Shaw shaw E81 Page pos STANDARD OPERATI NG PROCEDURE Subject Shipping and Packaging of Non Hazardous Samples 1 PURPOSE The purpose of this procedure is to provide general instructions in the packaging and shipping of non hazardous samples The primary use of this procedure is for the transportatio
150. he line to the sampler and if applicable the messenger line If the messenger has a separate line make sure it is at least as long as the tag line Do not place the messenger on the line at this time 5 Carefully open and lock the sampler From this point on handle it only by the tag line and take care not to strike it on the release mechanism 6 Attach the free end of the tag line to a secure holding place to keep from losing the sampler 7 Being careful not to contact the sampler slowly lower it into the water until the 1 meter to bottom mark is reached Make sure that the rope line does not become entangled 8 Slow the descent further and continue until the bottom is contacted Contact with the bottom will be evidenced when the descent stops and slack appears in the line 9 If sampling with a Ponar the slack in the line should have activated the closure mechanism If using a messenger type system thread the messenger onto the tag or trip line and allow it to fall and trip the device 10 Free the device from the bottom by pulling straight up on the tag line and slowly raise it until it is about 1 to 2 feet from the surface while being careful not to allow the rope line coils to entangle on anything 11 Prepare and clear the sample receiving area and then slowly raise the sampler out of the water 12 Allow clear water to drain and swing the sampler onto the pan in the receiving area once the clear liquids have drained Do n
151. he r is 0 9 or greater and inferential statistics indicate the FPXRF data and the confirmatory data are statistically equivalent at a 99 percent confidence level the data could potentially meet definitive level data criteria 10 0 CALIBRATION AND STANDARDIZATION 10 1 Instrument calibration Instrument calibration procedures vary among FPXRF instruments Users of this method should follow the calibration procedures outlined in the operator s manual for each specific FPXRF instrument Generally however three types of calibration procedures exist for FPXRF instruments namely FP calibration empirical calibration and the Compton peak ratio or normalization method These three types of calibration are discussed below 10 2 Fundamental parameters calibration FP calibration procedures are extremely variable An FP calibration provides the analyst with a standardless calibration The advantages of FP calibrations over empirical calibrations include the following No previously collected site specific samples are necessary although site specific samples with confirmed and validated analytical results for all elements present could be used Cost is reduced because fewer confirmatory laboratory results or calibration standards are necessary However the analyst should be aware of the limitations imposed on FP calibration by particle size and matrix effects These limitations can be minimized by adhering to the preparation procedure des
152. he use of internal standards in organics analysis The Compton normalization method may not be effective when analyte concentrations exceed a few percent The certified standard used for this type of calibration could be an NIST SRM such as 2710 or 2711 The SRM must be a matrix similar to the samples and must contain the analytes of interests at concentrations near those expected in the samples First a response factor has to be determined for each analyte This factor is calculated by dividing the net peak intensity by the analyte concentration The net peak intensity is gross intensity corrected for baseline reading Concentrations of analytes in samples are then determined by multiplying the baseline corrected analyte signal intensity by the normalization factor and by the response factor The normalization factor is the quotient of the baseline corrected Compton K peak intensity of the SRM divided by that of the samples Depending on the FPXRF instrument used these calculations may be done manually or by the instrument software 11 0 PROCEDURE 11 1 X Operation of the various FPXRF instruments will vary according to the manufacturers protocols Before operating any FPXRF instrument one should consult the manufacturer s manual Most manufacturers recommend that their instruments be allowed to warm up for 15 to 30 minutes before analysis of samples This will help alleviate drift or energy calibration problems later during analysis 6200 18
153. ible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS003 Revision No 1 Date of Revision 9 8 06 Shaw shaw E amp Page 2 of 4 5 2 Project Responsibility Shaw E amp employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records 6 PROCEDURE 6 1 Documentation All Chain of Custody documentation must be completed in indelible ink All corrections mus
154. icable to all Shaw E amp projects proposals where samples will be collected REFERENCES U S Environmental Protection Agency 1986 Test Methods for Evaluating Solid Waste Physical Chemical Methods SW 846 Third Edition U S Army Corps of Engineers Requirements for the Preparation of Sampling and Analysis Plans EM200 1 3 Shaw E amp l 2002 Sampler s Training Course Handout DEFINITIONS Sample Label Any writing surface with an adhesive backing that can be used to document sample identification information The sample label is attached to the sample container as a means of identification and in some commercially available or laboratory supplied containers may be pre attached All Shaw E amp I strategic alliance laboratories provide sample labels or pre labeled containers in their sample container supply kits RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw E amp employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw E amp employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects wh
155. igrams per kilogram Page 1 of 1 Shaw shaw E amp Attachment 2 List of Available SRMs and Properties Procedure No Attachment No Available SRMs Shaw Owned Comparisons Helps SRM ID Cost Quan Metal Conc Shaw Current XRF RL Source Yes OK No 2782 Ind Sludge 34 70 Ag 30 6 35 3 2710 9 Am Y 2702 Marine Sediment 318 50 As 45 3 22 23 4 105 626 1550 lt 20 Cd Y 2780 Hard Rock 315 50 As 48 8 22 23 4 105 626 1550 lt 20 Cd Y 1648 Urban PM 218 2 Cd 75 41 7 2711 lt 50 Am Y 2702 Marine Sediment 318 50 Ni 75 4 75 2586 lt 65 Cd Y 2781 Dom Sludge 294 40 Ni 80 2 75 2586 lt 65 Cd Y 1648 Urban PM 218 2 Ni 82 75 2586 lt 65 Cd Y 2709 San J Soil 271 50 Ni 88 75 2586 lt 65 Cd Y 2781 Dom Sludge 294 40 Ag 98 35 3 2710 lt 9 Am Y 2709 San J Soil 271 50 Zn 106 350 352 438 6952 lt 35 Cd Y 2782 Ind Sludge 341 70 Ni 154 1 75 2586 lt 65 Cd Y 2780 Hard Rock 315 50 Sb 160 J 38 4 2710 lt 45 Am Y 2781 Dom Sludge 294 40 Pb 202 1 15 6 161 432 1162 5532 lt 15 Cd Y 2780 Hard Rock 315 50 Cu 215 5 81 98 6 114 2950 45 Cd Y 1944 NY NJ Sediment 424 50 Cu 380 81 98 6 114 2950 lt 45 Cd Y 1648 Urban PM 218 2 Cr 403 301 2586 lt 300 Cd Y 2782 Ind Sludge 341 70 Pb 574 15 6 161 432 1162 5532 15 Cd Y 1648 Urban PM 218 2 Cu 609 81 98 6 114 2950 45 Cd Y 2781 Dom Sludge
156. ile allowing for sample throughput efficiency Typical count times are 60 to 180 seconds XRF instruments can be used to screen for metals in filters and filter papers by placing the filter or a portion thereof in the detector and analyzing it On some systems a filter holder is used The filter position with regards to the detector should be altered at least three times and the average of the three readings used to determine the result Solid surfaces such as painted walls are analyzed by holding the unit against the surface and collecting readings or by placing chips into the detector Again the average of three readings should be calculated for each result Soils can be analyzed by either in situ or ex situ methods depending upon the Data Quality Objectives and data use In situ analysis can be performed by simply placing the detector onto or over the ground surface and collecting data However since XRF is a surface detection technique it is advisable to at least remove mix and sieve a small pile of soil to provide a more consistent matrix Ex situ analysis involves thorough drying grinding mixing and sieving of the sample and placing it into a sample cup for introduction to the instrument XRF instruments are quantitative screening instruments and in most instances provide non definitive screening data that must be confirmed by definitive methods They can however be utilized for confirmation in well defined remedial actions gover
157. ility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE Wear appropriate eye protection including safety goggles when working with corrosive liquids especially when diluting concentrated materials to create low percentage solutions and follow all project Health and Safety requirements Decontamination wastes are to be recovered and handled as impacted project waste materials and must be disposed of in accordance with regulatory requirements A decontamination area should be established Implements can either be immersed in a 5 gallon bucket containing each solution rinse or the solutions can be contained in hand held units made of an inert and compatible material such as a Teflon wash bottle The analyte free water needs to be placed in a containe
158. ill be placed into a bag and labeled according to sample station location and depth of sample Ideally soil moisture content should be between 5 and 20 percent If sample is wet the samples will be retained dried and XRF analyzed back at the Shaw office and note on the field forms e The XRF reading will be taken directly through the plastic sample bag N 5 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois e Information on the condition of the sample location i e built up area visible shot and or clay target debris etc and the moisture content dry moist or wet will be recorded in the field logbook for each sampling e Selected soil samples will be submitted for various analyses at an offsite NELAP certified laboratory refer to Section 5 0 3 2 8 Sediment Sampling Sediment sampling is necessary because parts of the ponds channel and wetlands areas located on the Site are within the projected shot fall and clay target break zones refer to Figures 2 through 4 e Approximately 12 sediment samples will be collected from the Site at select locations corresponding to the established 50 foot grid system Sediment Sample IDs and their locations are included on Figure 5 and summarized within Table 1 e Sediment grab samples will be collected using either an Ekman Dredge clam type sediment sampler and or a core type sediment sampler below any standing surface water areas Access to th
159. in chronological order including field observations measurements and comments pertinent to the Site investigation goals e Description of any deviation from the Work Plan as applicable and e Any other pertinent data or observations identified during sampling Copies of Chain of Custody documentation will be appended to the Daily Field Reports and maintained by the Shaw project manager in the project files Examples of the standard Shaw field reporting forms are included in Attachment A 6 0 DATA EVALUATIONS 6 1 XRF Screening Level Data Soil XRF screening data will be evaluated by the Shaw project manager to initially define the aerial extents both vertical and horizontal for the primary shooting range contaminants of concern i e Lead and Arsenic etc The XRF screening results will be summarized in a tabular format along with the GPS positioning coordinates Initial XRF screening data will be uploaded to SURFER Version 10 a data visualization software program to develop iso concentration maps of both Lead and Arsenic Site impacts Shaw s evaluation of the XRF screening level data will form the basis in part for the selection of representative soil samples to be submitted for Total Metals laboratory confirmation analyses and to assess the need for additional soil sampling to delineate potential soil impacts at the Site NY 12 Revised Site Investigation Work Plan Sportsman s Park Shaw P Naperville Illinois 6 2 Soil and
160. ing EI FS 103 Soil Sampling Using a Soil Probe or Core Type Sampler EI FS 123 Sediment Sampling Using a Core Sampler EI FS 124 Sediment Sampling Using Ponar Ekman Type Systems EI FS 200 Screening For Metals via XRF Spectrometry T Projects 2011 144531 Naperville Park District04 SIWP Revised 01_Text DRAFT REVISED Site Investigation Work Plan_Sportsmans Park_Naperville docx 14 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois Figures PROJECT LOCATION APPROXIMATE SITE BOUNDARY vs fi M av 6 2011 Google 6 004 41 45 43 64 N 88 09 40 44 W elev 701 ft Eye alte 6543 ft GRAPHICAL SCALE FT Note Figure Adapted from 2010 Google Aerial Imagery 0 510 1 020 Sportsman s Park Naperville Illinois FIGURE 1 Shaw Shaw Environmental Inc SITE LOCATION MAP GRAPHIC SCALE 80 0 80 w di CONTOUR DATA OBTAINED FROM THE ILLINOIS NATURAL RESOURCES GEOSPATIAL DATA CLEARINGHOUSE SPORTSMANS PARK NAPERVILLE ILLINOIS DRAWING NO J DRAWN BY P 2 T AutoCAD AUTOCAD 2008 PROJECTS 141835 JUNE 2011 FIGURE 2 CURRENT CONFIGURATION dwg 6 27 2011 10 11 28 AM EL DATED SH Shaw Shaw EDviFenmehltal Ino PWEEFERTORESAND 0 2 OF 5 SH
161. ing sediments using clamshell type sampling devices Decontaminated commercial clamshell sampling device stainless steel construction for trace environmental sampling Rope or line with graduations on winch if required Weighted line with graduations to determine depth to bottom or depth finder if available Separate line for messenger if applicable Carpenter s chalk Plastic sheeting to keep emptying area clean Plastic or metal shallow pan to empty sampler into decontaminated or dedicated Stainless steel spoons or scoops decontaminated or dedicated Decontaminated or dedicated stainless steel bowl 6 2 Sampling The following procedure should be used when sampling sediments using clamshell type sampling devices 1 Dona pair of clean gloves 2 Place plastic sheeting around the area where the sampler will be emptied to keep sampled material in place 3 Determine the depth to the bottom using the weighted line or depth finder and then mark the sampler s line at the distance representative of approximately 1m from the bottom with chalk This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS124 Revision No 1 Date of Revision 9 21 06 Shaw shaw Page 3 of 3 4 Attach t
162. instrument is the MCA The MCA receives pulses from the detector and sorts them by their amplitudes energy level The MCA counts pulses per second to determine the height of the peak in a spectrum which is indicative of the target analyte s concentration The spectrum of element peaks are built on the MCA The MCAs in FPXHF instruments have from 256 to 2 048 channels The concentrations of target analytes are usually shown in ppm on a liquid crystal display LCD in the instrument FPXHF instruments can store both spectra and from 3 000 to 5 000 sets of numerical analytical results Most FPXRF instruments are menu driven from software built into the 6200 10 Revision 0 February 2007 units or from PCs Once the data storage memory of an FPXRF unit is full or at any other time data can be downloaded by means of an RS 232 port and cable to a PC 6 2 Spare battery and battery charger 6 3 Polyethylene sample cups 31 to 40 mm in diameter with collar or equivalent appropriate for FPXRF instrument 6 4 X ray window film Mylar Kapton Spectrolene polypropylene or equivalent 2 5 to 6 0 um thick 6 5 Mortar and pestle Glass agate or aluminum oxide for grinding soil and sediment samples 6 6 Containers Glass or plastic to store samples 6 7 Sieves 60 mesh 0 25 mm stainless steel Nylon or equivalent for preparing soil and sediment samples 6 8 Trowels For smoothing soil surfaces and collecting soil sam
163. into the instrument software these concentrations are those obtained from the laboratory the certified results or the gravimetrically determined concentrations of the prepared standards This gives the instrument analyte values to regress against corresponding intensities during the modeling stage The regression equation correlates the concentrations of an analyte with its net intensity 6200 17 Revision 0 February 2007 The calibration equation is developed using a least squares fit regression analysis After the regression terms to be used in the equation are defined a mathematical equation can be developed to calculate the analyte concentration in an unknown sample In some FPXRF instruments the software of the instrument calculates the regression equation The software uses calculated intercept and slope values to form a multiterm equation In conjunction with the software in the instrument the operator can adjust the multiterm equation to minimize interelement interferences and optimize the intensity calibration curve It is possible to define up to six linear or nonlinear terms in the regression equation Terms can be added and deleted to optimize the equation The goal is to produce an equation with the smallest regression error and the highest correlation coefficient These values are automatically computed by the software as the regression terms are added deleted or modified It is also possible to delete data points from the regres
164. kaging requirements or a 5 gallon UN specification plastic pail Performance Oriented Packaging Packaging designed for and tested to be used for shipment of DOT hazardous materials Also known as UN specification packaging Qualified person An individual with appropriate DOT IATA Hazardous Materials training including General Awareness Function Specific and Safety training necessary to properly classify samples as hazardous materials and to complete all subsequent shipping steps RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for the maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw E amp employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw E amp employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for recording information in sufficient detail to provide objective documentation i e checkprints calculations reports e
165. l samples analyzed by the six FPXRF instruments were collected from two sites in the United States The soil samples contained several of the target analytes at concentrations ranging from nondetect to tens of thousands of mg kg These data are provided for guidance purposes only 13 3 The six FPXHF instruments included the TN 9000 and TN Lead Analyzer manufactured by TN Spectrace the X MET 920 with a SiLi detector and X MET 920 with a gas filled proportional detector manufactured by Metorex Inc the XL Spectrum Analyzer manufactured by Niton and the MAP Spectrum Analyzer manufactured by Scitec The TN 9000 and TN Lead Analyzer both have a Hgl detector The TN 9000 utilized an Fe 55 Cd 109 and Am 241 source The TN Lead Analyzer had only a Cd 109 source The X Met 920 with the SiLi detector had a Cd 109 and Am 241 source The X MET 920 with the gas filled proportional detector had only a Cd 109 source The XL Spectrum Analyzer utilized a silicon pin diode 6200 20 Revision 0 February 2007 detector and a Cd 109 source The MAP Spectrum Analyzer utilized a solid state silicon detector and a Cd 109 source 13 4 All example data presented in Tables 4 through 8 were generated using the following calibrations and source count times The TN 9000 and TN Lead Analyzer were calibrated using fundamental parameters using NIST SRM 2710 as a calibration check sample The TN 9000 was operated using 100 60 and 60 second count times for the Cd 109 Fe
166. l professional with several years of environmental analytical experience Trip Blank In VOC analysis a container of Reagent Grade Water that is included in the sample cooler and analyzed by the laboratory to determine if cross contamination may have occurred in shipping Ambient or Field Blank Reagent Grade Water containerized during sample collection activities and analyzed at the laboratory The results are used to determine if sample results may be biased by site environmental factors Equipment Blank Final rinseate collected during sample equipment decontamination and analyzed by the laboratory The results indicate the effectiveness of the decontamination procedure Field Duplicate An additional sample aliquot or in some cases a collocated sample that is collected and analyzed The results are compared with the original samples as an indication of the overall precision of the entire sampling and analytical process RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsib
167. l type and by preparation method These data are provided for guidance purposes only The soil types are as follows soil 1 sand soil 2 loam and soil 3 silty clay The preparation methods are as follows preparation 1 in situ in the field preparation 2 intrusive sample collected and homogenized preparation 3 intrusive with sample in a sample cup but sample still wet and not 6200 22 Revision 0 February 2007 ground and preparation 4 intrusive with sample dried ground passed through a 40 mesh sieve and placed in sample cup For arsenic copper lead and zinc the comparability to the confirmatory laboratory was excellent with r values ranging from 0 80 to 0 99 for all six FPXRF instruments The slopes of the regression lines for arsenic copper lead and zinc were generally between 0 90 and 1 00 indicating the data would need to be corrected very little or not at all to match the confirmatory laboratory data The r values and slopes of the regression lines for barium and chromium were not as good as for the other for analytes indicating the data would have to be corrected to match the confirmatory laboratory Table 8 demonstrates that there was little effect of soil type on the regression parameters for any of the six analytes The only exceptions were for barium in soil 1 and copper in soil 3 In both of these cases however it is actually a concentration effect and not a soil effect causing the poorer comparability All ba
168. label must be placed on the same face of the package in close proximity to each other Consignor and consignee information should appear on some face of the package in addition to appearing on the shipping papers that are enclosed in a pouch attached to the package 6 4 Shipping Documentation If a sturdy cooler is used whether UN specification or not complete a Cooler Shipment Checklist see Attachment 1 and keep it in the project file A Dangerous Goods Airbill must be completed inserted into an adhesive pouch and attached to the package in close proximity to the proper shipping name and hazard class label Many carriers require a typed or computer generated Dangerous Goods Airbill If the Dangerous Goods Airbill has an area specifically designated for a 24 Hour Emergency Response telephone number insert 800 424 9300 into that space If it does not write 24 Hour Emergency Response Telephone Number 800 424 9300 in the Additional Handling Information section of the airbill Immediately following the telephone number write ERG xxx where xxx is the 3 digit Emergency Response Guidebook page number that corresponds to the hazardous material being shipped The shipper must sign the certification on the airbill Prior to carrier pickup a copy of the Dangerous Goods Airbill must be faxed to CHEMTREC at 703 741 6037 with a Shaw coversheet addressed to ITCR 7 ATTACHMENTS Attachment 1 Shaw E amp I C
169. lations for guidance on This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS013 Revision No 1 Date of Revision 9 5 06 Shaw shaw E amp I Page 3 of 4 packaging and prepare as an over pack with individual marking and labeling on the outer packaging If shipping multiple inner packages that meet the same hazard class es but represent both solid and liquid matrices prepare as an over pack with individual marking and labeling on the outer packaging If shipping hazardous material that meets more than one hazard class definition check the hazard precedence table in the appropriate regulations to determine primary and subsidiary classes 6 1 Additional Inner Packaging Requirements Place each sample container into a resealable plastic baggie Fold over and tape the bag seal onto the sample jar to prevent the closure from unsealing Several IATA packing instructions require containerizing of glass plastic sample jars into a sealed primary receptacle such as a metal can before placing them into outer packaging i e the cooler Wrap the bagged sample container with bubble wrap or other packing material to prevent breakage against the sides of the primary receptacle and place it into the primar
170. le for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that the activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE First Level Review of the Data Package Verify that the package contains all of the required elements listed in Section 2 If any items are missing contact the laboratory immediately and correct the situation Compare the reported results to the Chain of Custody request and verify that all expected samples and analyses results were reported If results are missing contact the laboratory and correct the situation If the missing data is not available yet perform partial review of the data provided and hold the package for follow up once the non reported results are provided Second Level Review Consult the project Chemical Quality Plan SAP QAPP etc for information concerning sample types and analysis requirements This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated wit
171. ly to a clean spiked matrix of quartz sand silicon dioxide free of interelement spectral interferences using long 100 600 second count times These sensitivity values are given for guidance only and may not always be achievable since they will vary depending on the sample matrix which instrument is used and operating conditions A discussion of performance based sensitivity is presented in Sec 9 6 1 4 Analysts should consult the disclaimer statement at the front of the manual and the information in Chapter Two for guidance on the intended flexibility in the choice of methods apparatus materials reagents and supplies and on the responsibilities of the analyst for demonstrating that the techniques employed are appropriate for the analytes of interest in the matrix of interest and at the levels of concern 6200 2 Revision 0 February 2007 In addition analysts and data users are advised that except where explicitly specified in a regulation the use of SW 846 methods is not mandatory in response to Federal testing requirements The information contained in this method is provided by EPA as guidance to be used by the analyst and the regulated community in making judgments necessary to generate results that meet the data quality objectives for the intended application 1 5 Use of this method is restricted to use by or under supervision of personnel appropriately experienced and trained in the use and operation of an XRF instrument Ea
172. m the high voltage supply however if the tube is properly positioned within the instrument this is only a negligible risk Any instrument x ray tube or radioisotope based is capable of delivering an electric shock from the basic circuitry when the system is inappropriately opened 5 3 Radiation monitoring equipment should be used with the handling and operation of the instrument The operator and the surrounding environment should be monitored continually for analyst exposure to radiation Thermal luminescent detectors TLD in the form of badges and rings are used to monitor operator radiation exposure The TLDs or badges should be worn in the area of maximum exposure The maximum permissible whole body dose from occupational exposure is 5 Roentgen Equivalent Man REM per year Possible exposure pathways for radiation to enter the body are ingestion inhaling and absorption The best precaution to prevent radiation exposure is distance and shielding 6 0 EQUIPMENT AND SUPPLIES The mention of trade names or commercial products in this manual is for illustrative purposes only and does not constitute an EPA endorsement or exclusive recommendation for 6200 8 Revision 0 February 2007 use The products and instrument settings cited in SW 846 methods represent those products and settings used during method development or subsequently evaluated by the Agency Glassware reagents supplies equipment and settings other than those listed in this m
173. n of samples collected on site to be sent off site for physical chemical and or radiological analysis 2 SCOPE This procedure applies to the shipping and packaging of all non hazardous samples Non hazardous samples are those that do not meet any hazard class definitions found in 49 CFR 107 178 including materials designated as Class 9 materials and materials that represent Reportable Quantities hazardous substances and or materials that are not classified as Dangerous Goods under current IATA regulations In general most soil air and aqueous samples including those that are acid or caustic preserved do not qualify as hazardous materials or dangerous goods An exception is methanolic soil VOC vials these containers are flammable in any quantity and must be packaged shipped and declared as Dangerous Goods whenever transported by air The Class 9 Environmentally Hazardous designation should only be applied to samples if they are known or suspected via screening to contain a sufficient concentration of contaminant to pose a health and or environmental risk if spilled in transport Samples for which screening has shown a potential hazard i e flammability or those that are derived from a known hazard including a site facility with confirmed contamination by an infectious substance must also be shipped in accordance with the applicable DOT IATA requirements Refer to Shaw E amp I SOP FS013 Improper shipment of hazardous materials
174. n regarding site activities that must include dates times personnel names activities conducted equipment used weather conditions etc Field logbooks can be used by a variety of different field personnel and are part of the project file RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS001 Revision No 1 Date of Revision 9 8 06 Shaw shaw E81 Pag
175. n the samples are packaged for shipment This will provide confidence in legal custody and will demonstrate non tampering during the sample collection process Do not attach custody seals to VOC sample containers as contamination may occur For these samples the custody seal should be used to seal the folded plastic zip bag that holds the sample containers For sample jars the completed Custody Seal should be placed across the top of the lid with the edges below the lid jar interface and attached to the jar material This will require the visible breaking of the seal in order to open the container Sample coolers and shipping containers should have Custody Seals attached in such a manner that the seal extends lengthwise from the top edge of the lid to the side of the cooler container 7 ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS006 Revision No 1 Date of Revision 9 8 06 Shaw Shaw Page 10f2 STANDARD OPERATI NG PROCEDURE Subject Sample Labeling 5 1 5 2 PURPOSE The purpose of this procedure is to provide the requirements for completion and attachment of sample labels on environmental sample containers SCOPE This procedure is appl
176. nce or removal of contamination that has been left in place in accordance with the Remedial Action Plan Access to soil contamination may be allowed if during and after any access public health and the environment are protected consistent with the Remedial Action Plan The failure to comply with the recording requirements for this Letter Obtaining the Letter by fraud or misrepresentation Subsequent discovery of contaminants not identified as part of the investigative or remedial activities upon which the issuance of the Letter was based that pose a threat to human health or the environment The failure to pay the No Further Remediation Assessment Fee within 45 days after receiving a request for payment from the Illinois EPA The failure to pay in full the applicable fees under the Review and Evaluation Services Agreement within 45 days after receiving a request for payment from the Illinois EPA Pursuant to Section 58 10 d of the Act the No Further Remediation Letter shall apply in favor of the following persons a b c d The City of Naperville The owner City of Naperville and operator Naperville Park District of the remediation site Any parent corporation or subsidiary of the owner of the remediation site Any co owner either by joint tenancy right of survivorship or any other party Page 4 e g h J k sharing a relationship with the owner of the remediation site Any holder o
177. ncluded the Project Contact should be a responsible individual that the laboratory may access to address analytical issues This person is usually the analytical lead for the project The Shipment Date should be provided on the applicable lines f shipping by carrier the Waybill Airbill Number must be included Note couriers will not sign custody documents Therefore inclusion of the waybill airbill number on the Chain of Custody is the only means of documenting the transfer to the carrier Laboratory Destination and Contact information should be provided This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS003 Revision No 1 Date of Revision 9 8 06 Shaw shaw E amp I Page 3 of 4 6 4 6 5 The Sampler s names should be provided on the appropriate line This line should include all persons whose initials appear on any of the sample containers to provide the laboratory a means of cross referencing containers The Send Report To information should be completed If multiple reports locations are needed the information should be provided on a separate page included with the Chain of Custody documents Sample Information Section Including on Continuation Page s During actual s
178. nd will also be submitted for analysis of PNAs total of three samples The samples will be immediately preserved in laboratory provided containers 3 3 Equipment Decontamination Prior to use at the Site and between sampling locations all down hole drilling and sampling equipment including hand trowels augers driling rods and split spoon samplers will be decontaminated The purpose of decontamination is to prevent potential cross contamination between sampling locations and sample intervals Decontamination will consist of using a steam generating pressure washer and potable water to remove soil and other debris from the drilling equipment In addition the split 8 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois spoon sampler the field scientist s logging tools hand trowels hand augers and any other sampling equipment will be washed using a scrub brush in a solution of potable water and a non phosphate detergent Washed equipment will be double rinsed with distilled water and allowed to air dry between uses 3 4 Sample Preservation All representative soil sediment surface water and groundwater samples selected for laboratory analysis will be preserved in the field in appropriate sized sterile glass containers with twist on Teflon lined lids as supplied by the contract environmental laboratory Immediately after filling labeling and sealing the sample containers the containers will b
179. ned by detailed approved plans and applicable quality objectives Use of the method for confirmatory purposes requires enhancements such as site specific calibration over multiple points regular QC checks adjustments of the site specific curve Definitive method relationship via split sample analysis and defined confidence windows for grey area data All of these elements should be detailed and defined in a project specific plan General Operation Record all data onto a log sheet or log book Allow the instrument to warm up for 15 to 30 minutes before use Perform any manufacturer specified background scatter and internal calibration checks using the supplied materials If the system fails the background check clean the window and repeat If the internal calibration check fails consult the manual to determine how to perform an Energy Calibration Do not use an instrument that fails either the background check or internal calibration criteria Prior to analyzing any samples analyze all of the required QC samples and compare to the project criteria Do not proceed to project samples until QC meets criteria QC samples in sample cups should be tilted to remix the contents before analysis Proceed with sample analysis Higher confidence data from soils in sample cups is achieved if each cup is analyzed in duplicate Tilt the cup to remix the material between each analysis Report the result as the average of the two values provided
180. nization is very important because it helps ensure that sample aliquots are representative of the whole collected sample and helps minimize sampling error so that other errors included in the measurement process such as laboratory sample preparation and test measurement can be better assessed SCOPE This procedure applies to Shaw Environmental amp Infrastructure Shaw E amp l personnel responsible for the collection of environmental samples The sample matrix must be amenable to mixing This SOP applies to the collection of samples that are to be tested for all analytes except volatile analytes REFERENCES American Society for Testing and Materials ASTM 1998 Reducing Samples of Aggregate to Testing Size C702 U S Army Corps of Engineers Requirements for the Preparation of Sampling and Analysis Plans EM 200 1 3 Section E 2 Homogenizing Techniques DEFINITIONS MHomogenize The use of physical mixing motions to make a uniform sample matrix RESPONSIBILITIES Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be sent to the Field Sampling Discipline Lead Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performan
181. ntended to provide general guidance for the analysis of samples using X ray Fluorescence XRF methods XRF can be used to screen for a variety of metals Attachment 1 in environmental sample matrices that include soils air filters and solid surfaces and materials including dried filter papers and to screen for lead based paint LBP The XRF technique has been accepted by the U S Environmental Protection Agency EPA for screening of samples during investigative and remediation actions and is published in SW 846 as Method 6200 2 SCOPE This procedure is applicable to all Shaw E amp efforts where metals are to be determined using XRF methods It is intended to act primarily as a guideline for the use and applicable Quality Control requirements of this technique This procedure is not intended to replace the applicable manufacturer s information procedures or those in SW 846 and it also does not present expanded detail on sample preparation XRF is a surface analysis technique and as such higher confidence data is achieved when solid samples especially soil samples are homogenized and reduced to consistent particle size mixtures by drying grinding and sieving Shaw E amp I owns a NITON Model XL 703 XRF system with three sources expanded analyte capabilities and the filter holder assembly Contact the Electronics Department in Findlay Ohio for availability 3 REFERENCES Field Portable X ray Fluorescence Spectrometry for the De
182. of properly qualified individuals Oversight may be accomplished through provision of a project specific and well defined checklist training in its use regular QA checks and real time availability for issue resolution 3 REFERENCES U S Environmental Protection Agency National Functional Guidelines for Inorganic Data Review EPA 540 R 94 013 U S Environmental Protection Agency National Functional Guidelines for Organic Data Review EPA 540 R 94 012 This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS020 Revision No 1 Date of Revision 9 8 06 Shaw shaw Page 2of4 U S Department of Defense 2002 Department of Defense Quality Systems Manual for Environmental Laboratories Final June U S Army Corps of Engineers Requirements for the Preparation of Sampling and Analysis Plans EM 200 1 3 4 DEFINITIONS Data Usability Review DUR The cursory review of an analytical data package for completeness and compliance with the ordered analysis specified quality and method project specific protocols before the data is used as input to a particular project decision making process The DUR process identifies any potential data quality issues and informs the data users of the effect
183. olume Soils and sediments can be used to create vertical composites Solid Composites To ensure the integrity of the composite all discrete grab samples must be collected in an identical manner Composite samples can be created by combining discrete grab samples into the same mixing holding container as they are collected or by combining and mixing equal aliquots of containerized and homogenized discrete grab samples Remove coarse fragments and organic material from the mixing bowl Homogenize the sample as specified in SOP FS010 Sample Mixing Homogenization Remove sample aliquots and place into the appropriate sample containers for shipment to the laboratory Label the sample and document the sampling event according to the project procedures Package ship the composite sample as required Liquid Composites Liquid composite samples should be created by combining equal aliquots of discrete samples Assemble the containers that will comprise a given composite Swirl or stir the individual containers to homogenize the contents just prior to removing the measured aliquots This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS011 Revision No 1 Date of Revision 9 8 06 S
184. ompass ruler calculator etc Preparation Site personnel responsible for maintaining field logbooks must be familiar with the SOPs for all tasks to be performed Field logbooks are project files and should remain with project documentation when not in use Personnel should not keep Field logbooks in their possession when not in use Field logbooks should only leave the project site for limited periods and they should always be returned to the site files or the designated on site location Sampler s Trailer etc Field logbooks shall be bound with lined consecutively numbered pages All pages must be numbered prior to initial use of the field logbook The front cover shall include the following information Project Number Project Name and Task s included in logbook Dates covered by logbook the starting date must be entered on the first day of use Logbook number if more than one logbook will be needed to cover project task s The inside front cover shall contain a listing and sign off of each person authorized to make entries and or review the logbook All persons who make entries or review approve such entries must signify their authority to enter into the logbook via their signature and the date of their signing on the inside front cover If initials are used for entries instead of full names the initials must be entered beside the full name on the inside cover This document contains proprietary information of
185. on boats wear life jackets when appropriate and abide by all water body safety rules in the project HASP Sampling that requires either a boat or conveyance across a walkway or other system that exposes personnel to potential of falling in including sampling for proposal purposes must be performed under an approved HASP and with proper personnel numbers including a dedicated and unoccupied spotter 6 1 Equipment The following equipment is used for collecting sediment samples with a core sampler Decontaminated commercial sediment gravity corer with extension handle s stainless steel construction for trace environmental sampling Brass or plastic sleeves consult project plan Drive hammer if required Plastic sheeting to keep emptying area clean Carpenter s chalk or duct electrical tape Plastic or metal shallow pan to empty sampler into 6 2 Sampling Procedure The procedure for collecting sediment samples with a core sampler is as follows 1 2 10 Don a pair of clean gloves Place plastic sheeting around the area where the sampler will be emptied to keep sampled material in place Assemble the sampler by placing an insert sleeve into the tube and attaching the nose piece and top collar usually done with screw threads Attach to an extension or drive hammer system with sufficient length to reach the bottom plus 2 to 3 times the sampler length Mark the extension at the point equal to the water depth plus the lengt
186. ooler Shipment Checklist 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS013 Attachment No 1 Shaw Shaw Attachment 1 Shaw E amp I Cooler Shipment Checklist Project Name Project Number Address Date Time City State Zi Fax No Shaw 7 ite Contact No Shaw E amp Inc SAMPLE CHECKLIST YES NO COMMENTS SAMPLE LIDS ARE TIGHT AND CUSTODY SEALS IN PLACE ARE ALL SAMPLE NUMBERS DATES TIMES AND OTHER LABEL INFORMATION LEGIBLE AND COMPLETE HAVE ALL SAMPLE NUMBERS DATES TIMES AND OTHER SAMPLING DATA BEEN LOGGED INTO THE SAMPLE LOG BOOK DO SAMPLE NUMBERS AND SAMPLE DESCRIPTIONS ON THE LABELS MATCH THOSE ON THE COC HAVE THE SAMPLES BEEN PROPERLY PRESERVED HAVE THE CHAIN OF CUSTODIES BEEN FILLED OUT COMPLETELY AND CORRECTLY DOES THE ANALYTICAL SPECIFIED ON THE COC MATCH THE ANALYTICAL SPECIFIED IN THE SCOPE OF WORK HAVE THE 00 5 BEEN PROPERLY SIGNED IN THE TRANSFER SECTION PACKAGING CHECKLIST YES NO COMMENTS HAS EACH SAMPLE BEEN PLACED INTO AN INDIVIDUAL PLASTIC BAG HAS THE DRAIN PLUG OF THE COOLER BEEN TAPED CLOSED WITH WATER PROFF TAPE FROM THE INSIDE HAVE ALL THE SAMPLES BEEN PLACED INTO THE COOLER IN AN UPRIGHT POSITIO
187. or a composite logsheet There are several types of composite samples Flow proportioned composite Flow proportioned composite samples are collected proportional to the flow rate during the sampling period by either a time varying constant volume or time constant varying volume method Flow proportioned composite samples are typically collected using automatic samplers paced by a flow meter This sampling method is commonly used for wastewaters Time composite A time composite sample is composed of a discrete number of grab samples collected at equal time intervals during the sampling period Time composite sampling is often used to sample wastewater discharges or streams Volume mass composite A volume mass composite is composed of a discrete number of grab samples collected at defined volume or mass intervals Volume mass composite sampling is often used to sample the output of a process system such as a Thermal Destruction Unit or pug mill Area composite Area composite samples are samples collected from individual grab samples located on a regularly spaced grid or along a pile at defined locations and depths Each of the grab samples must be collected in an identical fashion and must be of equal volume Vertical or Depth composite Vertical composites are composed of individual grab samples collected across a vertical cross section Like area composites the grab samples must be collected in an identical fashion and must be of equal v
188. ost prevalently certified for in the SRM and detected by the FPXRF instrument The first nine SRMs are soil and the last 4 SRMs are sediment Percent recoveries for the four NIST SRMs were often between 90 and 110 percent for all analytes 13 7 Comparability Comparability refers to the confidence with which one data set can be compared to another In this case FPXRF data generated from a large study of six FPXRF instruments was compared to SW 846 Methods 3050 and 6010 which are the standard soil extraction for metals and analysis by inductively coupled plasma An evaluation of comparability was conducted by using linear regression analysis Three factors were determined using the linear regression These factors were the y intercept the slope of the line and the coefficient of determination r As part of the comparability assessment the effects of soil type and preparation methods were studied Three soil types textures and four preparation methods were examined during the study The preparation methods evaluated the cumulative effect of particle size moisture and homogenization on comparability Due to the large volume of data produced during this study linear regression data for six analytes from only one FPXHRF instrument is presented in Table 8 Similar trends in the data were seen for all instruments These data are provided for guidance purposes only Table 8 shows the regression parameters for the whole data set broken out by soi
189. ot allow the fine particles to exit the sampler also 13 If a messenger was used remove it from the line to keep from accidentally tripping the device when retrieving the sample Carefully open and lock the sampler and allow the sample to fill the pan Put the sampler aside for cleaning and decontamination 14 If collecting samples for VOC analysis these samples should be taken first from the material in the pan using corer or syringe type methods 15 The remainder of the sample material should be mixed in the pan and placed into labeled sample containers or other plan required receptacles using a spoon or scoop 16 Complete all required documentation and place the sample into a cooler or other plan specified container 17 Decontaminate the sampler on the inside and outside while open and closed to remove all particles Dry the sampler and return it to its closed position when completed 7 ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS200 Revision No 1 Date of Revision 9 22 2006 Shaw Shaw Page 10f4 STANDARD OPERATI NG PROCEDURE Subject Screening for Metals via X Ray Fluorescence XRF Spectrometry 1 PURPOSE This procedure is i
190. ould be sent to the Field Sampling Discipline Lead Project Responsibility Shaw E amp employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw E amp employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other appropriate procedures Project participants are responsible for documenting information in sufficient detail to provide objective documentation i e checkprints calculations reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS011 Revision No 1 Date of Revision 9 8 06 Shaw Shaw E amp Page 2 of 3 6 1 6 2 PROCEDURE The discrete samples that are used to prepare a composite sample must be of equal volume and must each be collected in an identical manner Field documentation must clearly indicate the composite elements on either a map
191. p to surge and purge the well screen interval A minimum of ten 10 well volumes will be purged from the monitoring well until the purge water is clear to the unaided eye Following the well development activities the monitoring wells will be surveyed to obtain accurate hydraulic head measurements Field hydraulic conductivity tests slug tests shall also be performed at each well point location 7 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois 3 2 6 Groundwater Sampling Within one week but not sooner than one day after completing the monitoring well development operations Shaw personnel will return to the Site to obtain representative groundwater samples from the 7 newly installed monitoring wells and from the 2 existing on site monitoring wells installed by others total of 9 samples Prior to sampling at each location Shaw field scientists will use an electronic water level indicator to measure the static water level A disposable polyethylene bailer will then be used to purge three 3 well volumes from the well After purging the groundwater samples will be obtained using disposable polyethylene bailers or a low flow peristaltic pump New sampling equipment will be used at each monitoring well location to prevent potential cross contamination between locations Appropriate sized sample containers as supplied by the contract environmental laboratory will be filled directly from the sampling e
192. permet T4 Dury to mitigate The pecruttes shai taka s reasonable steps o munimira or preveni any discharge in violabon of this permit which hag a ransonabta likelihood of adversely affecting human health or the envepDnrriest i53 Proper operation amd rainterumece The permitea shall si all umas property Opetate and maritain all acit and systems of 5 and conmol land realad pppurtenences which are installed or used by the permiriee 10 achieve comphance with ihe canalons of rus permit Proper opersuon and maintenance includes affective performance adequate funding adequate operator stating and trairung and adequate laboratory and procesa controls including appropnate Quality assurance procedures This provision requires ihe oparaton of back up ar Burlary facita of afila systema oniy when nocosanry to achieve compliance with the conditions of the permil PRINTED 16 m 181 hol n Permit schons This panmi may be modified revoked and reiasued Or tarrunaled or cause ny the Agency pursuant to AO CFR 122 62 The bing of a quasi by tha permitime for 2 parmit modilication ravocati n and eeissuanca of emmnalion ora not ication of planned changes or anticipated noncomplisnca dows not stay any pormit Property rights This permit doas not convey any propery nglis ol any son or any exclusive privilage Duty to provida inlarmauon The parmiltaa shall fuenish to the Agency wilhin a feasoanable ime any in
193. ples 6 9 Plastic bags Used for collection and homogenization of soil samples 6 10 Drying oven Standard convection or toaster oven for soil and sediment samples that require drying 7 0 REAGENTS AND STANDARDS 7 1 Reagent grade chemicals must be used in all tests Unless otherwise indicated it is intended that all reagents conform to the specifications of the Committee on Analytical Reagents of the American Chemical Society where such specifications are available Other grades may be used provided it is first ascertained that the reagent is of sufficiently high purity to permit its use without lessening the accuracy of the determination 7 2 Pure element standards Each pure single element standard is intended to produce strong characteristic x ray peaks of the element of interest only Other elements present must not contribute to the fluorescence spectrum A set of pure element standards for commonly sought analytes is supplied by the instrument manufacturer if designated for the instrument not all instruments require the pure element standards The standards are used to set the region of interest ROI for each element They also can be used as energy calibration and resolution check samples 7 3 Site specific calibration standards Instruments that employ fundamental parameters FP or similar mathematical models in minimizing matrix effects may not require SSCS If the FP calibration model is to be optimized or if empirical c
194. quipment 3 2 7 Surface Water Sampling The NPD has performed monthly sampling of the pond in accordance with the NPDES Permit since 2000 The permit requires sampling of any discharge within the first 30 minutes of a storm event for analysis of Lead and Priority Pollutant PNAs In general discharge events are infrequent a total of 14 events during the 10 year reporting history and sampling results have not indicated the presence of a permit exceedances during the ten year reporting history with the exception of the Total Lead value concentration during the March 2010 sampling event 0 413 mg L It should be noted that this sample was later noted to contain solid wood fragments which the laboratory determined had biased the sample PNA analytical results have not exceeded method detection limits during the reporting period Two surface water samples will be obtained from the North Pond channel and South Pond total of six samples and analyzed for the inorganic contaminants of concern Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver Antimony Copper and Zinc The surface water sample will be collected in a laboratory provided glass container and suspended solids will be allowed sufficient time to settle The surface water sample will be decanted into a second laboratory provided container and submitted for laboratory analysis One surface water sample from each of the sampling locations North Pond channel and South Po
195. r ihe ume interval between each shquel pr ihe voluma of aach abquot i proportional Id eihar the stream flow at iha tune of Surnpung or the toual sLresm ilow since the collection of tha previous aliquot m Duty to comely The permines must comply with all conditrona ol this parmit Any pent noncompliance constitules 3 wolahon of the Act and is grounds Tor enforcement schon parmit lermunal on revocation and rewsuance modilicalion or for demai of a permit ronewal application The permitiese shall comply wilh sHluent standards or prohibitrons established under Secuon JO a of tha Clean Water Act for toxic pollutants within iha ome provided in tha rsulabans that esisbhsh hase standards or peohiburons even 0 the permil hag nol yet bean modified to incarporata ihe requeaement 2 Duty to respply lf the permittee wishes 10 conbnus an activity regulated by this Permit altar the azprauon date of this permit the perrruttee must apply for and naw peril If the permetes submits a proper application as required by tha Agency no later than 180 days pror 1 Ihe expirstion date this permit shell contrive in uD force and eflect unti the fina Agency decision on tha application has bean mace 13 Need 10 hait of reduce activity not a defense It shell not be a dalense lor permettee in an enforcement action hat Il would hava been necessary Io hall or reduce The permitied activity imn order IO mentam complunce with the condone ol this
196. r is greater then the method blank would be considered acceptable If the method blank cannot be considered acceptable the cause of the problem must be identified and all samples analyzed with the method blank must be reanalyzed 6200 13 Revision 0 February 2007 9 4 Calibration verification checks A calibration verification check sample is used to check the accuracy of the instrument and to assess the stability and consistency of the analysis for the analytes of interest A check sample should be analyzed at the beginning of each working day during active sample analyses and at the end of each working day The frequency of calibration checks during active analysis will depend on the data quality objectives of the project The check sample should be a well characterized soil sample from the site that is representative of site samples in terms of particle size and degree of homogeneity and that contains contaminants at concentrations near the action levels If a site specific sample is not available then an NIST or other SRM that contains the analytes of interest can be used to verify the accuracy of the instrument The measured value for each target analyte should be within 20 percent 96D of the true value for the calibration verification check to be acceptable If a measured value falls outside this range then the check sample should be reanalyzed If the value continues to fall outside the acceptance range the instrument should be recali
197. r saturated zone drilling will continue approximately 5 feet below the water table to allow the installation of a 5 foot well screen interval and riser piping well strings Up to 3 soil samples per soil boring location will be collected and submitted for laboratory analysis for RCRA 8 Total Metals Antimony Copper and Zinc select TCLP metals based on total results pH PNAs and moisture content at an offsite laboratory The proposed monitoring wells will be constructed of two inch diameter Schedule 40 PVC with a 0 01 slot screen and a stick up riser casing Riser sections will be added as necessary to extend the well casing to approximately 3 feet above the ground surface A sand pack will be installed in the borehole annulus to approximately 2 feet above the elevation of the top of screen A granular bentonite seal will be placed and hydrated above the sand pack to approximately 2 feet below the ground surface steel aboveground protector with a lockable hinged lid will then be installed in concrete over the top of casing The Shaw field scientist will complete a Well Construction Report for each well Approximately two days after installing the monitoring wells Shaw personnel will return to the Site to develop the monitoring wells The purpose of development is to ensure the monitoring well screens are not clogged and the wells function as intended Development will consist of using a disposable polyethylene bailer or a submersible pum
198. r that will be free of any compounds of concern Consult Attachment 1 for the decontamination solutions solvents appropriate to the task The minimum steps for decontamination are as follows 1 Remove particulate matter and other surface debris by brushing and or dipping in the soap solution 2 Rinse thoroughly with tap water 3 If necessary rinse with other applicable solutions solvents If hexane is used be sure to follow it with isopropyl alcohol to allow for the final water rinses to properly mix and contact the surface 4 Final rinse three times to make sure all residual solutions solvents are removed 5 Place decontaminated equipment on a clean surface appropriate for the compounds of concern and allow to air dry ATTACHMENTS Attachment 1 Recommended Decontamination Procedures FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Shaw Shaw Compound Attachment 1 Procedure No Attachment No Recommended Decontamination Procedures Detergent Wash Inorganic Desorbing Agent Organic Desorbing Agent Final Water Rinset EI FS014 1 Organic Constituents Volatile Organic Compounds Methanol Purge amp Trap grade Base Neutrals Acid Extractables
199. r within 20 of action level qualify result as assumed above actior level If LCB is greater than 10 of action level or sample result Data is unacceptable If MS MSD are acceptable or Surrogates are acceptable Data accepted If MS MSD are acceptable or Surrogates are acceptable evaluate for bias Data accepted If R 5O LCS acceptable Data accepted evaluate potential low bias in results below actior level If MSD and LCS acceptable and Surrogates or Post spike within range Data is accepted with precision qualifier If the perceived native result of either the MS or MSD is greater than 110 of action level qualify data as being above actior level Page 2 of 4 Result Greater than 1076 Above Actionrdevd No effect report result even if Duplicate is below actior level No effect on cata No effect on cata No effect on cata No effect on cata No effect on cata Shaw shaw E amp I QC Data Discrepancy Surrogate R Low Surrogate S High LCB Cortarrinated LCS LowRecovery LCS High Recovery Matrix Spike Low YR 1 If confined to one Surrogate in a fraction Deta is acceptable 2 If surrogate R values are at least 80 of acceptance lirrits Data is No effect on data Corrrrert LCB contamination If MS MSD are acceptable or Surrogates are acceptable Data accepted If MSD and LCS acceptable and Surrogates or Post spike within range Data is accepted with precision qu
200. rameter set needed Laboratory pre labeled containers are often bar coded and it is important to provide a complete container set for each sample The following information must be recorded on the Sample Label Sample Identification Number Date and Time collected nitials of person s responsible for collection lf a space is provided the Analysis Requested should also be added lf a Description is provided remember it must match that on the Chain of Custody form for cross referencing purposes Cover the completed and attached label with clear plastic tape to prevent bleeding of the ink if it becomes wetted Do not perform this step for pre weighed VOC vials as the final weight values will be influenced by the mass of the tape Protect these containers by enclosing the rack holder in a plastic bag within the cooler 7 ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS010 Revision No 1 Date of Revision 9 8 06 Shaw shaw E81 Page pes 5 1 5 2 STANDARD OPERATI NG PROCEDURE Subject Sample Homogenization PURPOSE The purpose of this procedure is to establish the method for homogenizing samples prior to containerization Proper homoge
201. rance 6 2 Liquid Samples Most aqueous samples do not require homogenization since water is well mixed due to diffusion and bulk convection If the sample matrix is a viscous liquid semi solid or an aqueous one with suspended solids the sample will require mixing Do not shake the sample and do not agitate the sample in any way if collecting for volatile parameters Volatile sample containers should be either filled directly from the sample source or if transferring from a large container such as an automatic sampler reservoir filled first and without agitation For non volatile parameters mix either using an appropriate stirrer or by gentle swirling and then immediately transfer the material into the appropriate containers The sample should be mixed frequently during the container filling step in particular if there are a large number of containers so that the condition of the bulk sampled fluid will be approximately the same when each parameter specific sample container is filled T ATTACHMENTS None 8 FORMS None This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No 1 Revision No 1 Date of Revision 9 8 06 Shaw shaw E81 Page pos STANDARD OPERATI NG PROCEDURE Subject Compositing
202. recommended that separate precision calculations be performed for each analysis type The equation for calculating RSD is as follows RSD SD Mean Concentration x 100 where RSD Relative standard deviation for the precision measurement for the analyte SD Standard deviation of the concentration for the analyte Mean concentration Mean concentration for the analyte The precision or reproducibility of a measurement will improve with increasing count time however increasing the count time by a factor of 4 will provide only 2 times better precision so there is a point of diminishing return Increasing the count time also improves the sensitivity but decreases sample throughput 9 6 The lower limits of detection should be established from actual measured performance based on spike recoveries in the matrix of concern or from acceptable method performance on a certified reference material of the appropriate matrix and within the appropriate calibration range for the application This is considered the best estimate of the true method sensitivity as opposed to a statistical determination based on the standard deviation of 6200 14 Revision 0 February 2007 replicate analyses of a low concentration sample While the statistical approach demonstrates the potential data variability for a given sample matrix at one point in time it does not represent what can be detected or most importantly the lowest concentration that can be calibrated
203. rely Z lt lt Remedial Project Management Section Division of Remediation Management Bureau of Land Enclosures SRP Environmental Notice Site Base Maps cc Bob O Hara Tim Milbrandt PREPARED BY Name Peter Burchard City Manager Address City of Naperville 400 S Eagle St Naperville IL 60566 RETURN TO Name Peter Burchard City Manager Address City of Naperville 400 S Eagle St Naperville IL 60566 THE ABOVE SPACE FOR RECORDER S OFFICE This Environmental No Further Remediation letter must be submitted by the remediation applicant within 45 days of its receipt to the Office of the Recorder of DuPage County Illinois State EPA Number 0434670024 The Naperville Park District the Remediation Applicant whose address is 320 W Jackson Naperville IL has performed investigative activities for the remediation sites depicted on the attached Site Base Map and which can be identified by the following 1 Legal description or Reference to a Plat Showing the Boundaries GARDEN PLOTS Does not include those areas within the fenced portion of the Sportsman s Park Plat of Survey of that part of the Southwest Quarter of Section 24 Township 38 North Range 9 East of the third Principal Meridian described by commencing at the Southeast corner of said Southwest Quarter thence North along the East line of said Southwest quarter a distance of 921 5 feet thence Westerly a distance of 232 85 feet to the Southwest corner
204. removable and a plastic or metal sleeve is inserted through the top and is held in place by the reduced diameter of the tube at the top of the cutout Soil probes can be attached to extension rods and T handles or may be of one length construction Samples collected from a soil probe are almost always submitted to the laboratory intact This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS103 Revision No 1 Date of Revision 9 11 06 Shaw shaw Page 2of3 5 RESPONSIBILITIES 5 1 Procedure Responsibility The Field Sampling Discipline Lead is responsible for maintenance management and revision of this procedure Questions comments or suggestions regarding this technical SOP should be directed to the Field Sampling Discipline Lead 5 2 Project Responsibility Shaw employees performing this task or any portion thereof are responsible for meeting the requirements of this procedure Shaw employees conducting technical review of task performance are also responsible for following appropriate portions of this SOP For those projects where the activities of this SOP are conducted the Project Manager or designee is responsible for ensuring that those activities are conducted in accordance with this and other
205. removed as it is duplicative to that in Special Condition 1 The date to file your DMR has been modified to the 25 of the month The Agency has begun a program allowing the submittal of electronic Discharge Monitoring Reports eDMRs instead of paper Discharge Monitoring Reports DMRS If you are interested in eDMRs more information can be found on the Agency website http epa state il us water edmr index html If your facility is not registered in the eDMR program a supply of preprinted paper DMR Forms for your facility will be sent to you prior to the initiation of DMR reporting under the reissued permit Additional information and instructions will accompany the preprinted DMRs upon their arrival The attached Permit is effective as of the date indicated on the first page of the Permit Until the effective date of any re issued Permit the limitations and conditions of the previously issued Permit remain in full effect You have the right to appeal any condition of the Permit to the Illinois Pollution Control Board within a 35 day period following the issuance date Should you have questions concerning the Permit please contact Mark Liska at the 217 782 0610 li WA Alan Keller P E Manager Permit Section Division of Water Pollution Control SAK SAK MEL 10061603 bah Attachment Final Permit cc Records Compliance Assurance Section Des Plaines Region Billing NL Rochford e i 0 C Man SC Rockford L 61103 815 987 7 7
206. ress written permission of the company Procedure No EI FS002 Revision No 1 Date of Revision 9 8 06 Shaw Shaw Page 2 of 2 6 1 6 2 reports etc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE Field Logsheets can be prepared to address the specific needs of each project and they can even be converted to laptop data entry forms Field Logsheets are considered legally defensible and all appropriate requirements must be observed Required Information All Field Logsheets must contain entry lines for the following in addition to whatever sample data gathering specific information is desired Site Project Name Project Number Date including time if required to properly document Comments or Issues area to record any non specified information pertinent to the sample data collection effort Initial or signature line for person responsible for completion Proper Completion Use Whenever Field Logsheets are utilized the following requirements must be strictly followed and enforced Field Logsheets are to be completed in real time They should not be filled out by transcription from another source All corrections must be single line cross out with the initials of the person making the correction All data information areas must be completed If an entry line block is not applicable to a particular sample data gath
207. rials which may not be reproduced without express written permission of the company Procedure No EI FS123 Revision No 1 Date of Revision 9 21 06 Shaw shaw Page 10f3 STANDARD OPERATI NG PROCEDURE Subject Sediment sampling using a Core Sampler 5 1 5 2 PURPOSE The purpose of this document is to provide the methods and procedures for collecting sediment samples using sediment gravity core samplers These samplers are usually used to collect intact sediment cores in shallow waters However they can be mounted onto deep water drill rigs or similar systems SCOPE This procedure is applicable to all Shaw E amp projects where sediment core samples will be collected and no project specific procedure is in place REFERENCES U S Army Corps of Engineers 2001 Requirements for the Preparation of Sampling and Analysis Plans Appendix C Section C 6 EM200 1 3 Washington D C Wildlife Supply Company WILDCO web site at http www wildco com DEFINITIONS Sediment Gravity Core Sampler A sampling device consisting of a hollow metal tube with a tapered nose piece collar and a check valve system The check valve allows water to flow through the sampler body on descent and prevents wash out of the sample as it is retrieved The tube is divided lengthwise and accepts a brass or plastic insert sleeve that actually holds the sample The sampler can be attached to an extension handle and or drive hammer
208. rium and copper concentrations in soil 1 and 3 respectively were less than 350 mg kg Table 8 shows there was a preparation effect on the regression parameters for all six analytes With the exception of chromium the regression parameters were primarily improved going from preparation 1 to preparation 2 In this step the sample was removed from the soil surface all large debris was removed and the sample was thoroughly homogenized The additional two preparation methods did little to improve the regression parameters This data indicates that homogenization is the most critical factor when comparing the results It is essential that the sample sent to the confirmatory laboratory match the FPXRF sample as closely as possible Sec 11 0 of this method discusses the time necessary for each of the sample preparation techniques Based on the data quality objectives for the project an analyst must decide if it is worth the extra time necessary to dry and grind the sample for small improvements in comparability Homogenization requires 3 to 5 min Drying the sample requires one to two hours Grinding and sieving requires another 10 to 15 min per sample Lastly when grinding and sieving is conducted time has to be allotted to decontaminate the mortars pestles and sieves Drying and grinding the samples and decontamination procedures will often dictate that an extra person be on site so that the analyst can keep up with the sample collection crew The
209. rk The characteristic x rays emitted by the anode are capable of exciting a range of elements in the sample just as with a radioactive source Table 3 gives the recommended operating voltages and the sample elements excited for some common anodes 6 1 2 Sample presentation device FPXRF instruments can be operated in two modes in situ and intrusive If operated in the in situ mode the probe window is placed in direct contact with the soil surface to be analyzed When an FPXRF instrument is operated in the intrusive mode a soil or sediment sample must be collected prepared and placed in a sample cup For FPXRF instruments operated in the intrusive mode the probe may be rotated so that the window faces either upward or downward A protective sample cover is placed over the window and the sample cup is placed on top of the window inside the protective sample cover for analysis 6 1 3 Detectors The detectors in the FPXRF instruments can be either solid state detectors or gas filled proportional counter detectors Common solid state detectors include mercuric iodide Hgl silicon pin diode and lithium drifted silicon Si Li The Hgl detector is operated at a moderately subambient temperature controlled by a low power thermoelectric cooler The silicon pin diode detector also is cooled via the thermoelectric Peltier effect The Si Li detector must be cooled to at least 90 C either with liquid nitrogen or by thermoelectric cooling via the
210. rument blank should be analyzed on each working day before and after analyses are conducted and once per every twenty samples An instrument blank should also be analyzed whenever contamination is suspected by the analyst The frequency of analysis will vary with the data quality objectives of the project A manufacturer recommended count time per source should be used for the blank analysis No element concentrations above the established lower limit of detection should be found in the instrument blank If concentrations exceed these limits then the probe window and the check sample should be checked for contamination If contamination is not a problem then the instrument must be zeroed by following the manufacturer s instructions 9 3 2 A method blank is used to monitor for laboratory induced contaminants or interferences The method blank can be clean silica sand or lithium carbonate that undergoes the same preparation procedure as the samples A method blank must be analyzed at least daily The frequency of analysis will depend on the data quality objectives of the project If the method blank does not contain the target analyte at a level that interferes with the project specific data quality objectives then the method blank would be considered acceptable In the absence of project specific data quality objectives if the blank is less than the lowest level of detection or less than 10 of the lowest sample concentration for the analyte whicheve
211. ry samples 4 3 Moisture content may affect the accuracy of analysis of soil and sediment sample analyses When the moisture content is between 5 and 20 percent the overall error from moisture may be minimal However moisture content may be a major source of error when analyzing samples of surface soil or sediment that are saturated with water This error can be minimized by drying the samples in a convection or toaster oven Microwave drying is not recommended because field studies have shown that microwave drying can increase variability between FPXRF data and confirmatory analysis and because metal fragments in the sample can cause arcing to occur in a microwave 4 4 Inconsistent positioning of samples in front of the probe window is a potential source of error because the x ray signal decreases as the distance from the radioactive source increases This error is minimized by maintaining the same distance between the window and each sample For the best results the window of the probe should be in direct contact with the sample which means that the sample should be flat and smooth to provide a good contact surface 6200 5 Revision 0 February 2007 4 5 Chemical matrix effects result from differences in the concentrations of interfering elements These effects occur as either spectral interferences peak overlaps or as x ray absorption and enhancement phenomena Both effects are common in soils contaminated with heavy metals As examples of
212. s absolute QC acceptance criteria for purposes of laboratory accreditation 1 0 SCOPE AND APPLICATION 1 1 This method is applicable to the in situ and intrusive analysis of the 26 analytes listed below for soil and sediment samples Some common elements are not listed in this method because they are considered light elements that cannot be detected by field portable x ray fluorescence FPXRF These light elements are lithium beryllium sodium magnesium aluminum silicon and phosphorus Most of the analytes listed below are of environmental concern while a few others have interference effects or change the elemental composition of the matrix affecting quantitation of the analytes of interest Generally elements of atomic number 16 or greater can be detected and quantitated by FPXRF The following RCRA analytes have been determined by this method Analytes CAS Registry No Antimony Sb 7440 36 0 Arsenic As 7440 38 0 Barium Ba 7440 39 3 Cadmium Cd 7440 43 9 Chromium Cr 7440 47 3 Cobalt Co 7440 48 4 Copper Cu 7440 50 8 Lead Pb 7439 92 1 Mercury Hg 7439 97 6 Nickel Ni 7440 02 0 Selenium Se 7782 49 2 Silver Ag 7440 22 4 Thallium TI 7440 28 0 Tin Sn 7440 31 5 6200 1 Revision 0 February 2007 Analytes CAS Registry No Vanadium V 7440 62 2 Zinc Zn 7440 66 6 In addition the following non RCRA analytes have been determined by this method Analytes CAS Registry No Calcium Ca 7440 70 2 Iron Fe
213. s should be circled Do not remove any pages from the book Do not use loose paper and copy into the field logbook later Record sufficient information to completely document field activities and all significant details events applicable to the project task s covered by the logbook All entries should be neat and legible Specific requirements for field logbook entries include the following Initial and date each page Sign and date the final page of entries for each day Initial date and if used code all changes properly Draw a diagonal line through the remainder of the final page at the end of the day Record the following information on a daily basis a Date and time b Name of individual making entry c Detailed description of activity being conducted including well boring sampling location number as appropriate d Unusual site conditions e Weather conditions i e temperature cloud cover precipitation wind direction and speed and other pertinent data f Sample pickup chain of custody form numbers carrier time g Sampling activities sample log sheet numbers h Start and completion of borehole trench monitoring well installation or sampling activity This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission o
214. sability Review 1 PURPOSE The purpose of this procedure is to establish the means by which all subcontracted environmental analytical data will be reviewed for completeness and usability based upon comparison to the project action decision levels and Data Quality Objectives before use in the intended decision making processes 2 SCOPE This procedure applies to all subcontracted analytical data including faxed or e mailed preliminary reports By way of its requirements this procedure prohibits verbal communication of analytical results and establishes minimum deliverable standards that must be provided for all subcontracted analytical data reports including faxed or e mailed preliminary reports These minimum standards include the following Sample Results Chain of Custody unless already available to the reviewer Sample Receipt Documentation unless already available to the reviewer QC Summary Laboratory Control Blank Laboratory Control Spike Matrix Spike Matrix Spike Duplicate Post digest Spike Surrogate Summary if applicable Hold time Compliance Summary or signed certification that all requirements were met Initial and Continuing Calibration Information or signed certification that it meets prescribed requirements GC MS Tuning Information if applicable or signed certification that it meets prescribed requirements This procedure should be performed only by or under the oversight
215. sion line if these points are significant outliers or if they are heavily weighing the data Once the regression equation has been selected for an analyte the equation can be entered into the software for quantitation of analytes in subsequent samples For an empirical calibration to be acceptable the regression equation for a specific analyte should have a correlation coefficient of 0 98 or greater or meet the DQOs of the project In an empirical calibration one must apply the DQOs of the project and ascertain critical or action levels for the analytes of interest It is within these concentration ranges or around these action levels that the FPXRF instrument should be calibrated most accurately It may not be possible to develop a good regression equation over several orders of analyte concentration 10 4 Compton normalization method The Compton normalization method is based on analysis of a single certified standard and normalization for the Compton peak The Compton peak is produced from incoherent backscattering of x ray radiation from the excitation source and is present in the spectrum of every sample The Compton peak intensity changes with differing matrices Generally matrices dominated by lighter elements produce a larger Compton peak and those dominated by heavier elements produce a smaller Compton peak Normalizing to the Compton peak can reduce problems with varying matrix effects among samples Compton normalization is similar to t
216. slope of the calibration curve to best fit the known concentrations of target analytes in the SRM or SSCS A 96D is then calculated for each target analyte The 96D should fall within 20 percent of the certified value for each analyte If the D falls outside this acceptance range then the calibration curve should be adjusted by varying the slope of the line the y intercept value for the analyte The standard sample is reanalyzed until the D falls within 20 percent The group of 20 samples analyzed before an out of control calibration check should be reanalyzed 10 3 Empirical calibration An empirical calibration can be performed with SSCS site typical standards or standards prepared from metal oxides A discussion of SSCS is included in Sec 7 3 if no previously characterized samples exist for a specific site site typical standards can be used Site typical standards may be selected from commercially available characterized soils or from SSCS prepared for another site The site typical standards should closely approximate the site s soil matrix with respect to particle size distribution mineralogy and contaminant analytes If neither SSCS nor site typical standards are available it is possible to make gravimetric standards by adding metal oxides to a clean sand or silicon dioxide matrix that simulates soil Metal oxides can be purchased from various chemical vendors If standards are made on site a balance capable of weighing items to
217. st one fixed point with measurements on any map drawn Maps and sketches should be oriented so that north is towards the top of the page Other events and observations that should be recorded include but are not limited to the following Changes in weather that impact field activities Visitors to the site associated with the covered task s Note their time of arrival and departure and provide a brief summary of their purpose on site Subcontractor activities applicable to the covered task s Deviations from procedures outlined in any governing documents including the reason for the deviation Deviations from procedures must be accompanied with the proper authorization Significant events that may influence data such as vehicles in the vicinity of VOC sampling efforts Problems downtime or delays Upgrade or downgrade of personal protective equipment Post Operation To guard against loss of data due to damage or disappearance of field logbooks all original completed logbooks shall be securely stored by the project All field logbooks will be copied at the end of each work shift and attached to the daily reports At the conclusion of each activity or phase of site work the individual responsible for the field logbook will ensure that all entries have been appropriately signed and dated and that corrections were made properly single lines drawn through incorrect information initialed coded and dated The complete
218. t be performed using standard single line cross out methods and the initials of the individual making the change must be included beside the corrected entry 6 2 Continuation Pages Continuation pages may be utilized for shipping containers coolers with sufficient samples sample containers that all of the lines of the Chain of Custody form are used before the documentation of the cooler shipping container is complete The number of pages in total must be filled out All samples entered onto a Continuation Page must be included in the same cooler shipping container as those on the Chain of Custody form itself 6 3 Header Information Each Chain of Custody form must be assigned a unique Reference Document Number use the Project proposal number followed by a unique numeric sequence or current date if only one cooler sent per day Continuation Pages should contain the same Document Reference Number as the Chain of Custody form that they are associated with The project team should maintain a log of Chain of Custody Reference Document Numbers The page identifier and total page count section must be completed Total pages include the Chain of Custody form and any attached Continuation Pages Project number name and location information must be completed for all forms f available the laboratory Purchase Order Number should be included on the appropriate line The name and phone number of the Project Contact should be i
219. t be recorded as a single instrument within 45 days of receipt with the Office of the Recorder of DuPage County For recording purposes the SRP Environmental Notice attached to this Letter should be the first page of the instrument filed This Letter shall not be effective until officially recorded by the Office of the Recorder of DuPage County in accordance with Illinois law so that it forms a permanent part of the chain of title for the properties investigated outside of the Sportsman s Park see attached legal descriptions Within 30 days of this Letter being recorded by the Office of the Recorder of DuPage County a certified copy of this Letter as recorded shall be obtained and submitted to the Illinois EPA to Page 5 Mr Robert E O Hara Illinois Environmental Protection Agency Bureau of Land RPMS Section 1021 North Grand Avenue East P O Box 19276 Springfield IL 62794 9276 8 In accordance with Section 58 10 g of the Act a No Further Remediation Assessment Fee based on the costs incurred for the remediation site by the Illinois EPA for review and evaluation services will be applied in addition to the fees applicable under the Review and Evaluation Services Agreement Request for payment of the No Further Remediation Assessment Fee will be included with the final billing statement If you have any questions regarding this correspondence you may contact the Illinois EPA project manager Stan Komperda at 217 782 5504 Since
220. tc that the requirements of this SOP have been met Such documentation shall be retained as project records PROCEDURE A Qualified Person must perform or oversee the classification packaging and completion of all related declaration and shipping papers t is a violation of federal law to pre complete these documents and provide them to an unqualified person without providing minimal training to that person This training must be documented and may take the form of a verbal discussion hands on demonstration or detailed written instructions including a task specific SOP with review provided by the Qualified Person The basic packaging and shipping procedures are as follows Determine the traits of the material to be shipped and compare them to the specific hazard class definitions in the appropriate regulations If the material falls within one or more hazard class definitions it is deemed hazardous Select the most accurate proper shipping name and packing group combination and prepare the package according to the prescribed requirements for quantity limitations authorized packaging marking labeling and documentation Check the current IATA regulations to make sure the carrier accepts the material s and or does not have its own special requirements for shipment f shipping multiple inner packages that each meet a separate hazard class definition consult the Separation and Segregation table in the appropriate regu
221. te specific XRF Definitive method correlation and calibration curve Daily QC should include the analysis of blanks at least three of the site specific calibration standards bracketing the expected concentration ranges replicates and a check sample or SRM The correlation should be verified and if necessary adjusted on a defined sample analysis or time frequency ATTACHMENTS Attachment 1 List of XRF Analytes and Typical Instrument Detection Limits Attachment 2 List of Available SRMs and Properties FORMS XRF Calibration Form XRF Laboratory Sample Results Form XRF Summary of Results This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS200 Attachment No 1 Shaw shaw Attachment 1 List of XRF Analytes and Typical Instrument Detection Limits Typical Reporting Limits for Each Radioactive Source mg kg Element Cd 109 Am 241 Chlorine 450 Potassium Calcium Titanium Chromium 9 260 Manganese 205 Selenium Rubidium Strontium Zirconium Molybdenum Cadmium 50 Tin 85 Antimony 45 Barium 30 Silver 9 1 Typically achievable in a clean silica sand matrix Actual sample detection limits will be higher due to the sample matrix interferences mg kg Mill
222. termination of Elemental Concentrations in Soil and Sediment Method 6200 Hevision 0 1998 Test Methods for Evaluating Solid Waste Physical Chemical Methods SW 846 Third Edition January Instrument Manual for Spectrace Model 9000 XRF TN Technologies Instrument Manual for Niton 700 Series Systems Niton Inc 4 DEFINITIONS X ray Fluorescence Spectrometry XRF An analytical technique whereby the sample is exposed to high energy radiation from a radioactive source s forcing the ejection of an electron from the target metal specie s The vacant space is quickly filled in by another electron from a higher energy shell with the excess energy released in the form of an X ray measured in kiloelectron volts keV characteristic for a particular metal species System Blank A manufacturer supplied non metal implement such as a Teflon or SiO plug that is placed into the detector and analyzed to evaluate system contamination and scatter Energy Standard A manufacturer supplied solid metal implement that is analyzed to verify system performance and background correction algorithms This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS200 Revision No 1 Date of Revision 9 22 2006
223. the least significant source of error in FPXRF analysis User or application related error is generally more significant and varies with each site and method used Some sources of interference can be minimized or controlled by the instrument operator but others cannot Common sources of user or application related error are discussed below 4 2 Physical matrix effects result from variations in the physical character of the sample These variations may include such parameters as particle size uniformity homogeneity and surface condition For example if any analyte exists in the form of very fine particles in a coarser grained matrix the analyte s concentration measured by the FPXRF will vary depending on how fine particles are distributed within the coarser grained matrix If the fine particles settle to the bottom of the sample cup i e against the cup window the analyte concentration measurement will be higher than if the fine particles are not mixed in well and stay on top of the coarser grained particles in the sample cup One way to reduce such error is to grind and sieve all soil samples to a uniform particle size thus reducing sample to sample particle size variability Homogeneity is always a concern when dealing with soil samples Every effort should be made to thoroughly mix and homogenize soil samples before analysis Field studies have shown heterogeneity of the sample generally has the largest impact on comparability with confirmato
224. tion of the Site located outside of the Shooting Range fence was issued a no further remediation determination of Total Lead 1 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois A copy of the NFR letter is included in Appendix A Additional information regarding the historic investigation is included in the June 2010 Phase Environmental Site Assessment which has been provided to the SRP Discharges from the pond are regulated under National Pollutant Discharge Elimination System NPDES permit 1L0073253 for analysis of Lead A copy of the NPDES permit is included in Appendix A In compliance with the permit preventative measures for the balance of the Sportsman s Park property were implemented including limiting access to the gun range areas posting signage and implementing environmental best management practices at the Park including the required use of environmentally friendly steel shot biodegradable targets and banning Lead shot The Site was subject of US EPA investigation under Comprehensive Environmental Response Compensation and Liability Information System CERCLIS in 1999 The Site is not on the National Priorities List NPL Several possible risks to public health and the environment are associated with the Site A large quantity of lead from the historic use of lead shot bullets and broken clay targets containing Polynuclear Aromatic Hydrocarbons PNAs have been deposited at the
225. ts and 24 precision points for the MAP Spectrum Analyzer The replicate measurements were taken using the source count times discussed at the beginning of this section For each detectable analyte in each precision sample a mean concentration standard deviation and RSD was calculated for each analyte The data presented in Table 4 is an average RSD for the precision samples that had analyte concentrations at 5 to 10 times the lower limit of detection for that analyte for each instrument Some analytes such as mercury selenium silver and thorium were not detected in any of the precision samples so these analytes are not listed in Table 4 Some analytes such as cadmium nickel and tin were only detected at concentrations near the lower limit of detection so that an RSD value calculated at 5 to 10 times this limit was not possible One FPXRF instrument collected replicate measurements on an additional nine soil samples to provide a better assessment of the effect of sample preparation on precision Table 5 shows these results These data are provided for guidance purposes only The additional nine soil samples were comprised of three from each texture and had analyte concentrations ranging from near the lower limit of detection for the FPXRF analyzer to thousands of mg kg The FPXRF analyzer only collected replicate measurements from three of the preparation methods no measurements were collected from the in situ homogenized samples The FPXRF analyz
226. urable M shell emissions Each characteristic x ray line is defined with the letter K L or M which signifies which shell had the original vacancy and by a subscript alpha a beta B or gamma y etc which indicates the higher shell from which electrons fell to fill the vacancy and produce the x ray For example a K line is produced by a vacancy in the K shell filled by an L shell electron whereas a K line is produced by a vacancy in the K shell filled by an M shell electron The K transition is on average 6 to 7 times more probable than the K transition therefore the K line is approximately 7 times more intense than the K line for a given element making the K line the choice for quantitation purposes The K lines for a given element are the most energetic lines and are the preferred lines for analysis For a given atom the x rays emitted from L transitions are always less energetic than those emitted from K transitions Unlike the K lines the main L emission lines L and L for an element are of nearly equal intensity The choice of one or the other depends on what interfering element lines might be present The L emission lines are useful for analyses involving elements of atomic number Z 58 cerium through 92 uranium An x ray source can excite characteristic x rays from an element only if the source energy is greater than the absorption edge energy for the particular line group of the element that is the K absorption e
227. us Operation and Emergency Hesponse Guidelines All individuals involved with these activities will be required to conform to a Site specific Health and Safety Plan prepared by the Shaw Health and Safety Officer Soil sediment surface water and groundwater samples will be collected using a systematic approach that will ensure the data gathered will be representative of the Site environmental conditions All sampling activities and laboratory work will be conducted in general accordance with the U S Environmental Protection Agency s EPA s SW 846 Test Methods for Evaluation Solid Waste and Environmental Investigations Standard Operating Procedure and Quality Assurance Manual Specific methods for performing field tasks are described in subsequent sections 3 2 Sample Collection amp Field Screening Procedures Experienced Shaw environmental scientists will perform all sampling operations The scientists will be responsible for preserving representative samples and maintaining Daily Field Reports Examples of the field forms that will be used during this project are included in Attachment A The sampling procedures for this characterization study will include surface near surface and sub surface soils sediment surface water and groundwater sampling collected for laboratory analysis The protocols for this work are described in detail in the following sections and within the applicable Shaw Standard Operating Procedures SOPs included in
228. ve materials with which compliance is required There should be a person appointed within the organization that is solely responsible for properly instructing all personnel maintaining inspection records and monitoring x ray equipment at regular intervals Licenses for radioactive materials are of two types specifically 1 a general license which is usually initiated by the manufacturer for receiving acquiring owning possessing using and transferring radioactive material incorporated in a device or equipment and 2 a specific license which is issued to named persons for the operation of radioactive instruments as required by local state or federal agencies A copy of the radioactive material license for specific licenses only and leak tests should be present with the instrument at all times and available to local and national authorities upon request X ray tubes do not require radioactive material licenses or leak tests but do require approvals and licenses which vary from state to state In addition fail safe x ray warning lights should be illuminated whenever an x ray tube is energized Provisions listed above concerning radiation safety regulations shielding training and responsible personnel apply to x ray tubes just as to radioactive sources In addition a log of the times and operating conditions should be kept whenever an x ray tube is energized An additional hazard present with x ray tubes is the danger of electric shock fro
229. ve safety procedures isolation of work areas and issuance of state radioactive licenses and permits Several states require persons transporting receiving and or operating the XRF to attend a Safety Training course every two years for properly handling an instrument containing radioactive sources Shaw personnel using this type of instrument for the first time must attend the manufacturer s Safety Training course or be trained by a certified Shaw representative Manufacturers will not send instruments containing regulated radioactive sources to a project site without a competent person as required by their Specific License and General License with an Agreement State where analysis will be performed For This document contains proprietary information of Shaw Environmental amp Infrastructure Inc Shaw Environmental amp Infrastructure Inc retains all rights associated with theses materials which may not be reproduced without express written permission of the company Procedure No EI FS200 Revision No 1 Date of Revision 9 22 2006 Shaw shaw E amp I Page 3 of 4 6 1 6 2 additional information or assistance in dealing with licensing and or shipment issues contact the manufacturer the leasing agent or the Radiation Control Officer at the Shaw Oakridge TN facility General Information Sensitivity is a function of the instrument count time Consult the manual to establish a count time that provides the needed sensitivity wh
230. y receptacle Seal the primary receptacle and label it with the Sample ID and any hazard information and place it into a plastic bag to protect the label 6 2 Additional Outer Packaging Requirements Samples that in total qualify as Excepted Quantities or Limited Quantities do not require the use of UN specification packaging and may be shipped in sturdy coolers pails or any packaging that meets general packaging requirements Samples that do not qualify as Excepted Quantities or Limited Quantities require UN specification packaging For such samples that also require cooling to meet sample preservation requirements UN specification coolers are available from several Haz Mat packaging vendors If using a cooler of any kind seal off the cooler drain on the inside and outside with tape to prevent leakage Place cushioning and or absorbent material on the bottom of the outer packaging to provide a soft impact surface Place a plastic bag into the container to minimize the possibility of leakage during transit Wrap glass inner packagings with sufficient bubble wrap to ensure the best chance to prevent breakage of the container For methanolic soil VOC vials place vials into the supplied rack holder or box and then place it into a tied off plastic bag to keep out moisture Pack the largest inner packagings in the bottom of the container with cushioning material between each to avoid breakage from bumping If cooling is requir
231. y 5 g of the sample should then be removed and placed in a sample cup for FPXRF analysis The rest of the prepared sample should be sent off site for ICP or AA analysis The method use for confirmatory analysis should meet the data quality objectives of the project 7 4 Blank samples The blank samples should be from a clean quartz or silicon dioxide matrix that is free of any analytes at concentrations above the established lower limit of detection These samples are used to monitor for cross contamination and laboratory induced contaminants or interferences 7 5 Standard reference materials Standard reference materials SRMs are standards containing certified amounts of metals in soil or sediment These standards are used for accuracy and performance checks of FPXRF analyses SRMs can be obtained from the National Institute of Standards and Technology NIST the U S Geological Survey USGS the Canadian National Research Council and the national bureau of standards in foreign nations Pertinent NIST SRMs for FPXRF analysis include 2704 Buffalo River Sediment 2709 San Joaquin Soil and 2710 and 2711 Montana Soil These SRMs contain soil or sediment from actual sites that has been analyzed using independent inorganic analytical methods by many different laboratories When these SRMs are unavailable alternate standards may be used e g NIST 2702 8 0 SAMPLE COLLECTION PRESERVATION AND STORAGE Sample handling and preservation pro
232. y Chain of Custody copy with the Shaw file copy An example of the Chain of Custody form that will be used for this project is included in Appendix A N 10 Revised Site Investigation Work Plan Sportsman s Park Shaw Naperville Illinois 4 0 ANALYTICAL TESTING PLAN Shaw proposes to retain First Environmental Laboratories Inc First Environmental Naperville Illinois as the contract environmental laboratory for this project First Environmental Laboratories is an Illinois Environmental Protection Agency Accredited Environmental Laboratory in accordance with Title 35 of the Illinois Administrative Code Part 186 Accreditation of Laboratories for Drinking Water Wastewater and Hazardous Waste Analysis First Environmental s Accreditation Number is 100292 4 4 Laboratory Testing Methodologies Laboratory analysis will be performed at the contract environmental laboratory Selected surface soil samples subsurface samples and groundwater samples from the Site will be laboratory analyzed for the following potential contaminant and physical parameters Soil and Sediment Analytical e Total Metals RCRA 8 List plus Antimony Copper and Zinc via USEPA Method 6010A amp 7470A e TCLP Metals RCRA 8 List plus Antimony Copper and Zinc via USEPA Method 1311 e pH via USEPA Method 4500H B e PNAs via USEPA Method 8270C Groundwater Analytical e Total Metals RCRA 8 List plus Antimony Copper and Zinc via USEPA Method 6010A
233. y Ihe Agency n this permi tb That they have Degun Dr expeti to begin to use or manufsciurme an Inimrrrecdhalm or final produci of byproduct any Oxic pollutant which was nal reported in the NPDES pernil applearion All Publichy Owned Treatment Works POTWs must provea adequate notte 10 the Agency of tha foflawing Any new introduction of pollulants into thai POT W from an madrect dizchergar whith would bs subject ta Sections 301 or 306 of the Ciesn Waler Act il t ware directiy discharging those Dolhutants and Ibi Any subsian al changa m tha volume or character of pollulanis beng introduced into hat POTW by a source introdecmyg pollutants imc the POTW si tha time of issuance of the permit fc For purposes of ihis paragraph adequate notice shel include 1 06 on fil iha quahty and quantity of effluent mroduced into tha POTW snd lul any antecipated impact of ihe change on tha Quantity or quality of effluent to De discharged from ine POTW H iha permit is sued In a publicly owned or publ gty reguiared treatment works the permurtes shall require any induainel user D such 1 works lo comply wih federal requirements concemng a User charges pursuant tc Section 204 bb of tha Clean Water Act and applicapia regulations appeanng im 40 CFR 35 r4 0 pollutant sHluent stondards and pretreatment 519 pursuant ID Section J07 ol ihe Clean Water Act and 131 inspection manitonng

Revised Site Investigation Work Plan

Contents

Download Pdf Manuals

Related Search

Related Contents