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1. OSHA STEL Ceiling ACGIH OSHA SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES MIXTURE the following mixture data are for 5 Hydrogen Peroxide Appearance Clear colorless liquid Odor Odorless pH 7 0 to 8 0 Freezing Point 3 C 27 F Boiling Point 101 C 214 F Flash Point and Method Noncombustible Flammable Limits Noncombustible Fire Explosion Hazards Product is non combustible On decomposition releases oxygen which may intensify fire Vapor Pressure 31 mm Hg 30 C 86 F Vapor Density No data available Solubility in Water 100 Evaporation Rate gt 1 Butyl acetate 1 SpecificGravity 1 01 20 C 68 F H20 1 Volatile 100 Auto ignitionTemperature Noncombustible Hazardous Decomposition Products Oxygen which supports combustion Sensitivity to StaticDischarge No data available Sensitivity tolmpact No data available HYDROGEN PEROXIDE Molecular Formula H2 02 Molecular Weight 34 01 g mole pH Weak acid H202 concentration weight 35 50 70 90 corresponding true pH 4 6 4 3 4 4 5 1 SpecificGravity 1 4425 25 C 77 F Melting Point 0 43 C 31 F Boiling Point 152 C 305 5 F Vapor Pressure 1 97 mm Hg 25 C 77 F Solubility Miscible with water soluble in ether insoluble in petroleum ether soluble in alcohol Viscosity 1 245 cP liquid SECTION 10 STABILITY AND REACTIVITY Thermal decomposition conditions to beavoided TOMI Environmenta2. Your needs may vary depending upon the potential for exposure in your workplace SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS EU Classification EU Risk Phrases Hydrogen peroxide 7722 84 1 231 765 0 Xi R36 Inert Ingredients d d ace trade secret Trade secret lt 4 5 Trade secret i ChemicalName CAS Weight EINECS The Full Text for all EU Classification and EU Risk Phrases is Displayed in Section 16 In accordance with29 CFR 1910 1200 i the specific chemical identity and or percentage of composition of certainingredients are being withheld as a trade secret SECTION 4 FIRST AID MEASURES e Eyes Hold eye open and rinse slowly and gently with water for 15 20 minutes o Remove contact lenses if present after the first 5 minutes then continue rinsing eye Call a Poison Control Center or doctor for treatment advice e Skin o Take off contaminated clothing Rinse skin immediately with plenty of water for 15 20 minutes Call a Poison Control Center or doctor for treatment advice e Ingestion o Rinse mouth with water o Dilute by giving 1 or 2 glasses of water Do not induce vomiting o See a medical doctor immediately e Inhalation TOMI Environmental Solutions Inc East Coast Office 5111 Pegasus Court Suite A Frederick MD 20009 800 525 1698 www tomiesinc com ILO M l ENVIRONMENTAL SOLUTIONS INC INNOVATING FOR A SAFER WorLD o Remove to fresh air o Consult doctor in case of sympto
3. TO M l ENVIRONMENTAL SOLUTIONS INC INNOVATING FOR A SAFER WoRrLD STERAMIST row ey BINARY IONIZATION TECHNOLOGY Safety Data Sheet SECTION 1 IDENTIFICATION Trade Names e BinarylonizationTechnology e BITBinarylonizationTechnology e BIT e BIT Solution Ready To Use Hydrogen peroxide lt 8 e SteraMist BIT Intended Use For use as a Hospital Healthcare Disinfectant and Mold Control and Mold Inhibitor during remediation dry pre cleaned enclosures located in industrial commercial and institutional settings including production operations in pharmaceutical manufacturing including clean rooms laboratories animal research facilities hotel rooms offices cruise ships and recreational facilities Use Binary lonization Technology BIT Solution only with SteraMist Environment System or SteraMist Surface Unit fogging misting equipment following detailed instructions provided in the SteraMist Binary lonization Technology BIT User Manual Details of the Supplier of the Safety Data Sheet This Safety Data Sheet has been updated in accordance with the Globally Harmonized System GHS Manufacturer Supplier TOMI Environmental Solutions Inc 5111 Pegasus Court Suite A Frederick MD 21704 800 525 1698 310 275 2282 Emergency Telephone Numbers CHEMTREC US 800 424 9300 703 527 3887 POISON CONTROL 800 222 1222 SECTION 2 HAZARD S IDENTIFICATION HazardClassification For so
4. l Solutions Inc East Coast Office 5111 Pegasus Court Suite A Frederick MD 20009 800 525 1698 www tomiesinc com TO M l ENVIRONMENTAL SOLUTIONS INC INNOVATING FOR A SAFER WorLb o No decomposition if used and stored according tospecifications e Dangerous products of decomposition Possible intraces SECTION 11 TOXICOLOGICAL INFORMATION MIXTURE the following mixture data are for Binary lonization Technology BIT Solution e Eye Effects Corrosive irritant rabbit e Skin Effects Mild or slightly irritating after 14 days rabbit No perceptible reaction guinea pig e Dermal LD50 gt 2 000 mg kg rabbit e Oral LD50 gt 5 000 mg kg rat e Inhalation LC50 gt 2 77 mg L rat HYDROGENPEROXIDE e Eye Effects 5 hydrogen peroxide Minimally irritating rabbit FMC Study Number 186 0949 e Skin Effects 10 hydrogen peroxide Mildly irritating after 4 hour exposure rabbit FMC Study Number 189 1078 Dermal LD50 35 hydrogen peroxide gt 2 000 mg kg rabbit FMC Study Number 183 746 Oral LD50 10 hydrogen peroxide gt 5 000 mg kg rat FMC Study Number 189 1077 Inhalation LC50 50 hydrogen peroxide gt 0 17 mg L rat FMC Study Number 189 1080 Acute Effects from Overexposure Minimally irritating to the eyes skin nose throat and lungs Chronic Effects from Overexposure The International Agency for Research on Cancer IARC has concluded that there is inadequate evidence for carcinogenici
5. lly valid contractual relationship TOMI Environmental Inc believes that the information contained in this Safety Data Sheet is accurate and while it is provided in good faith it is without a warranty of any kind expressed or implied Disclaimer The contents of this MSDS are believed to be correct but do not purport to be all inclusive and should only be used as a guide TOMI Environmental Solutions Inc disclaims any express or implied warranty as to the accuracy of the above information and shall not be held liable for any direct incidental or consequential damages resulting from the reliance on the above information TOMI Environmental Solutions Inc East Coast Office 5111 Pegasus Court Suite A Frederick MD 20009 800 525 1698 www tomiesinc com
6. lution Class IV Irritant if on skin Class Danger if in eyes Signal Word Warning Danger Hazard Statement Minimally irritating to the skin and mildly irritating to respiratory tract May be harmful if swallowed May cause irreversible eye damage User must wear goggles If mist gets into the eyes flush eyes with fresh water and seek immediate medical treatment Weak oxidizing agent that is stable under normal conditions TOMI Environmental Solutions Inc East Coast Office 5111 Pegasus Court Suite A Frederick MD 20009 800 525 1698 www tomiesinc com TO M l ENVIRONMENTAL SOLUTIONS INC INNOVATING FOR A SAFER WoRLD Precautionary Statement s Hazards to Humans and Domestic Animals DANGER Causes irreversible eye damage Harmful if absorbed through skin Do not get in eyes or on clothing Avoid contact with skin Wear appropriate protective eyewear such as goggles face shield or safety glasses Wash thoroughly with soap and water after handling and before eating drinking and chewing gum using tobacco or using the toilet Remove and wash contaminated clothing before reuse GHS Label Elements Irritant if on skin Danger if in eyes Note This document has been prepared in accordance with standards for workplace safety which require the inclusion of all known hazards of the product or its ingredients regardless of the potential risk The precautionary statements and warnings included may not apply in all cases
7. ms e Notes to Medical Doctor o Direct contact may be minimally irritating o Treatment is by dilution and is symptomatic and supportive SECTION 5 FIRE FIGHTING MEASURES e Suitable Extinguishing Media Noncombustible flood with water or agent suitable toenvironment e Fire Fighting Procedures Any tank or container surrounded by fire should be flooded with water for cooling Wear full protective clothing and self contained breathing apparatus SECTION 6 ACCIDENTAL RELEASE MEASURES e Person related Safety Precautions Wear protective equipment Keep unprotected persons away when applying e Measures for Environmental Protection Do not allow product to reach sewage system or water bodies e Measures for Cleaning Collecting Absorb with liquid binding material sand diatomite acid binders universal binders sawdust or wipe with towel e Additional Information No dangerous materials arereleased SECTION 7 HANDLING AND STORAGE This section provides guidance on the safe handling practices and conditions for safe storage of chemicals The required information consists of e Handling o Information for safe handling No special measuresrequired o Information about protection against explosions and fires No special measures required e Storage o Requirements to be met by storerooms and containers No special requirements o Information about storage in one common storage facility Store away from foodstuffs o Further informati
8. olutions Inc East Coast Office 5111 Pegasus Court Suite A Frederick MD 20009 800 525 1698 www tomiesinc com TO M l ENVIRONMENTAL SOLUTIONS INC INNOVATING FOR A SAFER WoRrLD SECTION 14 TRANSPORT INFORMATION NON MANDATORY The following refers to all modes of transportation unless specified below e Not regulated for transport under USDOT EUADR IATA ICAO or IMDG regulations SECTION 15 REGULATORY INFORMATION NON MANDATORY OSHA Label e Non hazardous in accordance with international standards for workplace safety SECTION 16 OTHER INFORMATION Text of classification and phrases referred to under heading 3 R36 Irritating to eyes R67 Vapors may cause drowsiness and dizziness Xi Irritant HMIS Hazardous MaterialsIdentificationSystem During Application Health 0 Minimal Flammability 0 Minimal Physical Hazard 0 Minimal Personal Protection PPE H Protection H Safety goggles gloves apron the use of a supplied air or SCBA respirator is required in lieu of a vapor cartridgerespirator NFPA National Fire Protection Association During Application Health 0 Insignificant Flammability 0 Insignificant Reactivity 0 Insignificant Special None No specialrequirements Revision Summary This SDS was generated July 2014 The above data are based on our present knowledge However they shall not constitute a guarantee for any specific product features and shall not establish a lega
9. on about storage conditions Do not store in direct sunlight SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION e Personal Protective Equipment general o General protective and hygienic measures The usual precautionary measures for handling chemicals should be adhered to o Breathing equipment See below Protection of hands See below o Penetration time of glove material The exact break through time will vary by manufacturer Please refer to glove manufacturer data o Eye protection Safety glasses recommended during refilling o Handling BIT Solution long sleeved shirt and long pants socks and chemical resistant footwear goggles safety or glasses with side shields or face shield chemical resistant gloves such as barrier laminate butyl rubber nitrile neoprene rubber polyvinyl chloride or Viton o Handheld Unit Application Where airborne hydrogen peroxide concentrations are expectedto exceed 1 ppm air purifying respirator with a full face piece or hood in O TOMI Environmental Solutions Inc East Coast Office 5111 Pegasus Court Suite A Frederick MD 20009 800 525 1698 www tomiesinc com TO M l ENVIRONMENTAL SOLUTIONS INC INNOVATING FOR A SAFER WoRrLD ChemicalName TLV ACGIH combination with an air purifying cartridge recommended by the manufacturer specifically for hydrogen peroxide use Exposure Limits Components with Limit Values that Require Monitoring at the Workplace STEL Ceiling PEL
10. ty of hydrogen peroxide in humans but limited evidence in experimental animals Group 3 not classifiable as to its carcinogenicity to humans The American Conference of Governmental Industrial Hygienists ACGIH has concluded that hydrogen peroxide is a Confirmed Animal Carcinogen with Unknown Relevance to Humans A3 e Carcinogenicity ACGIH Listed A3 Animal carcinogen SECTION 12 ECOLOGICAL INFORMATION NON MANDATORY ECOTOXICOLOGICALINFORMATION Data from toxicity tests 7722 84 1 hydrogen peroxide solution e Channel catfish 96 hour LC50 37 4mg L Fathead minnow 96 hour LC50 16 4 mg L Daphnia magna 24 hour EC50 7 7mg L Daphnia pulex 48 hour LC50 2 4mg L Freshwater snail 96 hour LC50 17 7 mg L For more information refer to ECETOC Joint Assessment of Commodity Chemicals No 22 Hydrogen Peroxide ISSN 0773 6339 January 1993 CHEMICAL FATE INFORMATION Hydrogen peroxide in the aquatic environment is subject to various reduction or oxidation processes and decomposes into water and oxygen Degradesin the atmosphere within the light spectrum with hydroxyl radicals in the gas phase and subsequent photolysis SECTION 13 DISPOSAL CONSIDERATIONS NON MANDATORY Product e Recommendation Smaller quantities can be disposed with household garbage Uncleaned packaging e Recommendation Disposal must be made in accordance with applicable local regulations e Recommended cleaning agent Water TOMI Environmental S
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