pH測定と電極の選び方 第一版 - 株式会社ティ・アンド・シー・テクニカル
Contents
1. e MINITHODE 49 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical f HE FLATRODE pH2. pH pH pH pH
3. 7 7 2098 T T 1 1 277 112 118 18 HAMILT INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical Group Fenodic able of the Hements liB
4. pH pH9 10 pH12 13 pH 1 2 3 4 5 6 7 8 9 10 11 12 13 14 100 250 300 350 400 44 HA
5. 38 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH 100kPa
6. 1 pH pH 2 pH
7. 16 17 1
8. 7 Cathode 6 7 H HAIMVIILT INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical
9. CALPAK 1 2 28175 S Hamilto nH 56 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 9 sw 09 ow sw sm sw 09 sw 09 m sw ow 9 sw sw 09 3 9 2 pH
10. 1 0 1mol L 0 1molL 0 1mol L NaOH
11. 60 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3922 pH pH V pH pH7
12. 3 8 2 3 4
13. 10 C pH pH pH7 pH7 pH 64 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 10 pH pH
14. pH AmV ApH
15. Na lon CI lon 65 e 1 1 1 1 1 1 1 NaCI
16. pH pH pH pH Theory is necessary Experience is essential By Hamilton pH Electrode system R amp D team 76 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 32N31132X3 4NSVIN HL NOLIIAVH 3GOuAlHSfYIA 4I2INX SSV 19 ON di N L SSV 19 di a L SSV 19 ON d 1 SSV19 SSV 19 SSV I9 ON SSV TS OdT TIH SSV IO 3 I9NIS XH eg LSV IdA lOd dNa
17. HCI HNO CH3COOH HCOOH H2SO4 HsPO4 OH ZR EV UO gs FAXESF NaOH Ca OH e AI OH s KOH Mg OH 2 EA
18. P3 56g 81 BH KCI pH7 pH pH7 KCI
19. HAIMVIILT INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical NaNO SA 990 AI2 SO4 8 Cas PO4 2 3Ca 2 68 mol 0 012Kg 12g gt SI 1971 Oxford Dictionary 12 12g 6 0221367 x 10 1776 1856 1811
20. 112 1911 1837 1937 ics 1913 1885 1962 HAMILT INI THE MEASURE OF EXCELLENCE pH
21. pH 4 1 3 68 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical CU eim S SREURO IUBET RHITARUM TG ELER KCI 4 2 pH
22. 0 1 2kO 1 39 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 4 1 1 E HCI H CI 5
23. H H H H 0mV pH L
24. 1 8 92 1 7 K L Q The Bohr Atom L 8 EE M 18 n 2n 18
25. Acidity solution Alkalinity solution HAIVIHLI INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical OH 1 1 H 100 1 100 1 10 10 1 10 000 000 1 10 000 000 1 10 107 1 1000 000 000 1 1000 000 000 1 10 10 amp OH
26. 1 1 2 3 1 43 7k d HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 65
27. 27 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 8 1 E E E E E Et pH E E pH pH mV
28. 1980 pH 1 KCI 2 3 2 1 2
29. pH pH pH pH HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 1 4 pH pH pH
30. 200kPa KCI 52 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH2 12 25 C 6 POLISOLVE pHO0 130 C
31. pH EVEREF 1 805C 1 100mV
32. 2uS cm pH b pH pH SIP pH 25 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 2 0 pH pH pH NES JA pH 2 pH
33. pH U pH U 46 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 pH pH pH pH pH pH 47 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical p
34. pH pH pH HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical mV pH pH pH 3 9 2 1 1 2 pH 1 pH pH7 1
35. E Es E Ee E Es 3 8 2 0mV 29
36. 36 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical c PTB pH 1997 Tracebility of pH measureme
37. 4 2HOH OH HaO 1 H 1 OH OH HH
38. 2 30 C 135 C 21 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 135 CE C KCI pH 3 2 3 1947 1
39. J KCI Ag AgCI C ut mEprxGekc u pH 22 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 324 KCI pH 3mol L KCI
40. 16 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 17 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 2 11 pH pH pH
41. 19 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 1 2 24 55 O 1um 20 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 222 pH pH pH
42. pH pH 18 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 2 12 7 Mc Innes Corning 015 pH pH pH 0 1um pH
43. 1 1mol H 29 1 189 1molO Cl 719 1molO Hn 2229 1 36 50 1mol 409 69 OH OH OH HAIMVIILT INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical 10 1 1 1 2 2e
44. 6 E pH pH E 28 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical E pH 0mV Es Es
45. b c pH pH pH 1 0 1mol L HCI 69 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical
46. ge ien 3mollL 1 KCI 2 3 pH7 pH 40 Diffusion Potentials which develop between various solutions and a saturated KCl electrolyte 1 0 0 1 0 01 0 1 Buffer pH Buffer pH Buffer pH Buffer pH mole HCI mole HCI mole HCI mole 1 68 4 01 4 65 7 00 Buffer pH 10 01 0 01 0 1 mole NaOH mole NaOH 1 0 mole NaOH 14 1 mV 4 6 mV 3 0 mV 1 8 mV 3 3 mV 2 6 mV 3 1 mV 1 9 mV 1 8 mV 2 3 mV 0 4 mV 8 6 mV HAIMVIILT IN THE MEASURE OF EXCELLENC
47. pH pH pH pH pH pH pH Dr Hannes B hler Andreas Brugger Dirk Tillich and thank to my loving wife HAIMVIILT IN THE MEASURE OF EXCELLENCE amp 2 pH 1 10 1
48. 6 6 3 1 NaCI H CI NaOH HAMILT IN THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical Na OH Electrolytes 1 CI lon
49. pH 3 9 2 1 61 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 9 3 pH pH b c d e gm 3 9 4 pH 547 RII RUI DMEBDRO pH pH 30 0 01pH 0 6mV
50. pH 0 1pH 26 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 1 100 5000MO N a N J 100 3 8 pH pH
51. 20 C 1pH 58 16mV pH pH pH 255C 10MQ 1000MO 25 C 10 pH amp pH
52. 71 5 PH PH i 72 5 a 72 5 2 i 72 5 3 i 73 73 75 1 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH pH pH
53. Ag AgCI KCI pH7 pH 55 3mol L KCI pH pH 23 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 25
54. pH pH
55. pH 9 pH h pH 50 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 3 8 3 8 1 1 2 3
56. 54 pH 10 0 pH
57. 0 02pH 4 pH pH pH 4 1 pH pH 66 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 4 1 1
58. Nucleus In each shell there Shells 2 n electrons maximum 7 shells HAMILTON THE MEASURE OF EXCELLENCE pH 150322_E J 19 The Hydrogen Atom Electron orbit The Oxygen Atom Electron Proton Atomic Atomic number weight Symbol Element name 6 3 1869 1834 1907
59. 22 C 10 molL Ht O H 10 OH 10 pH pH 1 pH log HAMILT INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical pH Erich L Springer 12
60. 3 4 4 1 EVEREF EVEREF DET d 42 3 4 4 2 B HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH
61. pH 1 pH pH pH pH
62. VP SMEK B 3mol L KCI B EVEREF B pH B pH 021875 UL amp 3 43 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 35 3 5 1 pH10
63. pH pH pHO 1mol L pH14 1mol L NaOH 2 NaCI pHO pH14 pH NaCIl pH pH 7 pH 7
64. 62 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH pH 10 C 3molL
65. pH pH 3 1 25C 65 C s 100 50 7 8 9 10 11 12 13 14 _ _ _ mV 50 100 150 200 8 0 2H 8 SR IE 68 300 at i ET 25 pH 657C 67 09mV 3 3 5 pH7 pH
66. pH pH7 0mV 47mV pH0 8 pH 31 HAIVIILT 9N THE MEASURE OF EXCELLENCE by
67. 2 0 2 3 3 2 1 pH 1897 pH
68. UN E 10 R F 1 n T C R Xx T x 2303585 x 273 15 20 293 15 UN 58 16mV 14 HAIMVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 10 mol L HOH 10 molL NaOH pH 10 11 12 13 rs 1mol L HCI 1mol L NaOH 407 12 mV 407 12 ImV mV at 20 58 16mv mV mV 116 32 mV 19 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 2 pH pH m 1 pH
69. 24 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 3 pH2 4 90 C 5 3 2 5 1 POLISOLVE 1 pHO 2 3 4 130 C 600kPa 5 6
70. 50 pH 64pF m 102pF m pH pH 70 E pH 30 C 80 C 130 C 52 72 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 5 3
71. 90 C 130 C 12 53 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 3 9 pH 3 9 1 pH pH pH NIST pH 9
72. pH 8 10 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical pH 10 molL HOH 10 molL NaOH Y Y Y ub 1 2 3 4 5 6 7 Add A 1 1mol L HCI 1mol L NaOH pH 0 2 3 4 5 6 7 8 9 10 11 12 13 14 30 wt 11 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 3 pH 3 1 pH pH 3 1 pH 2 pH 3 pH
73. 48 67 HAIVIILT IN THE MEAS
74. pH HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 50m pH PVC PVC PVC 1 2 USE RR 74 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 55 pH 2
75. 2 pH pH pH mV pH U Us pH pH U pH 25 C 60 E 0 1pH pH 7 8 9 10 11 12 13 14 NN pH SS N 150 N x 200 Slope at 0 C 54 20 mV MN N N 300 Slope at 20 C 58 16 mV E 350 vu 400 Slope at 50 C 64 12 mV 35 HAIV
76. pH 2pH 3 2 3 2pH pH 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 1 5 2 H d 58 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH fi amp FHUVRIXE d 1 60 RET OD m E 2 Vis 5 4 01 7
77. 450 400 350 100 50 7 8 9 10 11 12 13 14 mV 50 prix SN 100 E 150 NN 200 NN Slope at 0 54 20 mV NN 300 Slope at 20 C 58 16 mV 350 400 Slope at 50 64 12 mV A 450 Bo pH pH HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH 450 400 350 300 200 150 pHas 100 50 8 9 10 11 12 13 14 mV 50 pH 100 Ne 150
78. H OH 1 mol HCI gt pH HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH pH
79. 150322_E J T amp C Technical 1932 1891 1974 6 2 1913 Bohr Theory of the Atom
80. 36 3 4 1 40 3 4 2 kl 42 3441 EVEREF 42 3 4 4 2 B 43 4 44 3 5 1 44 3 5 2 45 3 6 ki 46 3 7 kk 48 4 c 51 3 8 1 kk 51 3 82 ki 52 3 9 n 54 3 91 pH 54 3 9 2 ki 57 3 9 2 1 i 58 3 9 2 2 pH 61 62 3 9 4 kk 62 3 95 64 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 10 kk 65 66 66 RENE t TOI ARR 67 4 1 2 68 4 1 3 _ kk 68 EE oe 69 4 3
81. BN 200 _ 0 54 20 mV w N 300 Slope at 20 58 16 mV 3 N 350 NNS m 400 Slope at 50 C 64 12 mV NONO 420 450 89 C 3 8 5 0mV pH7 pH Uis U 34 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH
82. 1 1 2 2 HAMIIET IN THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical NaCI The Ionic Bond of Sodium and Chlorine 1 7 8 Na Atom CI Atom 1 1 The Molecule Nar 1 Pk
83. CO 54 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 5 pH9 21 pH10 01 pH NIST NIST pH A B D F G 55 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical
84. pH NIST pH NIST 0 C 60 C 0 005pH 60 C 95 C 0 008pH NIST 0 02pH 1
85. 12 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical C1 C2 Electrolyte Bridge E x Log C2 E mV R 8 31439Jxmo xK F 96495 7Cxmo JI T n 1 C Ci C2 C gt 13 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical RxT C4 C4 C 10 1 x Log n X F C2 E T fo Un
86. 104 5 CO Electron Configuration of Noble Gases 2 He 8 Ne Ar Xe Rn 8 2 6 8 2 1 1
87. 2 3molL KCI 12 1 lt gt 70 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical
88. PN 238290 A lt 3 500mL B 4 500mL 3molL KCI 500mL 4 3 71 HAIVIILT IN TH
89. pH pH pH b pH c 30 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 3 3
90. 4 60 C 5 6 7 a b c d 9 pH4 pH8 18 o 90 C 2 51 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH13 90 C 2 3 pH
91. 1 1m pH pH EET pH pH pH pH MD SSV 19 07 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH
92. 1 TI1Od V1 1 TI1Od ij UZL Z Wis EE Xt goi 3GoarTil4 3GOHLHS YT SSV I9 3HOd 1DNIS ER 2OIN LSV 1d 1Od dNaAL LSV 1d 1Od 1 ISV IdA lOd ON dI 3L TSV 1d 1Od ISV 1d 1Od LSV 1d 1Od TSV 1d 1Od dNAL V1 1 1I1Od d 1 V1 1 TI1Od dNAL V1 1 1I1Od V1 1 TI1Od HZ AVETE ff HAIVIHLI INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical 6 pH H 1 6 1
93. VB VIIB IVA VA VIIA VIIIA Gas Noble Gases Liquid Solid Synthetically need HAMILTON 26 ao HAMILT INI THE MEASURE OF EXCELLENCE pH 150322_E J T amp C Technical 4 1 1743 1794 Ne 104 5 The Water Molecule H O H2O s 2
94. HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH7 pH 7 0mV Ei u E Es pH 30mV 30mV pH pH6 8 pH 0 02pH 1 16mV
95. pH 0 01pH 63 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 3 9 5 pH 3 1 2 3 3
96. 07 10 molL 0 14 pH pH H concentration OH concentration pH mol L mol L 0 0 1 0 0000000000001 1 0 01 0 000000000001 2 0 001 0 00000000001 3 0 0001 0 0000000001 4 0 00001 0 000000001 5 0 000001 0 00000001 6 0 0000001 0 0000001 7 0 00000001 0 000001 8 0 000000001 0 00001 9 0 0000000001 0 0001 10 0 00000000001 0 001 11 0 000000000001 0 01 12 0 0000000000001 0 1 13 0 00000000000001 1 14 pH pondus hydrogenii 1909 S P L Sgrensen 1868 1939 pH OH pH 9 HAIVII
97. 09 10 19 10 4 00 7 06 10 15 15 4 00 7 04 10 11 18 4 00 7 03 10 08 20 4 00 7 02 10 06 22 4 00 7 01 10 04 30 4 01 6 99 9 97 35 4 02 6 98 9 92 40 4 03 6 97 9 86 45 4 04 6 97 9 83 50 4 05 6 97 9 79 pH7 0mV 1 pH pHas pH 59 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical
98. 100kPa 65 HAIVIILT 9N THE MEASURE OF EXCELLENCE by T amp C Technical 10 O pH 0 03pH 0 05pH
99. AL LSV 1d 1Od LSV 1d 1Od SSV IO 139 1VS IdA lOd diN3 L 8v13 LA Tl TlOd LSV ldA lOd V1 1 TI1Od ON LSV d 1Od ON V1 1 1I1Od TSV 1d 1Od V1 1 TI1Od X TY c C 3aosldlrL MZ RI ETE XL T 3e BL 2g 88 exje1o4d 3aosHsma SSV 19 JOd 319NIS 3HOd a 1anod 3HOd a1anoa XT 3E HZ SPACE dIA3 L V1 1 TI1Od V1 1 TI1Od 1 amp via lAlllod V1 1 TI1Od ONG dia amp SvialAlllod V1 1 TI1Od 3aoalv 4 V1 1ATITOd V1 1 TI1Od gx 00 SSV 19 3QOMHINIdS aqOALININ SSV TO 3HOd IATONIS 3GoaulHsfYl4 V1 1 TI1Od V1 1 TI1Od ON V1 1 1I1Od V1 1 1I1Od ENWE 3GQOMHLNIdS dOd1OI A C 7 3aourTiia SSV19 3HOd 319NIS ONALHSNTA 2OIN 15 1 dWa L LSV 1d 1Od LSV 1d lOd ON LSV IdA lOd ISV IdA lOd ON TSV 1d 1Od TSV ld 1Od dNaAL BV1 1 1 1Od d N3 L BV1 1 TI1Od dNAL V1
100. E by T amp C Technical pH7 pH 41 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 342 pH
101. E MEASURE OF EXCELLENCE by T amp C Technical 5 pH pH 5 1 pH 5x10 YQ pH pH 10 Q 1m 10 Q 10 7O pH 150pF m 200pF m 50m pH
102. H a b FLUSHTRODE mE Cg 48 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical
103. HAMILTON THE MEASURE OF EXCELLENCE pH By Erich L Springer 2013 7 7 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical H x EE o ro 5 S 15 7 2 PH 8 EE oe 12 3 1 kk 12 3 2 kk 16 3 2 1 16 3 2 1 1 18 3 2 1 2 ILU S MEE 19 21 3 2 3 22 3 24 KCI 23 3 2 5 ius 24 3 2 5 1 kk 25 3 2 6 pH 26 3 3 PH 27 3 3 1 28 3 3 2 29 3 3 3 kk 31 9 04 EIE 32 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 3 5 kk 34 CC
104. IILT IN THE MEASURE OF EXCELLENCE by T amp C Technical 3 4 b
105. IVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH 50 HH pH pH pH1 45 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH pH 1 2 3 pH _
106. LT IN THE MEASURE OF EXCELLENCE by T amp C Technical 1 Loo molL H 10 pH 1 0 1 0 01 pH 0S H 0 01 0 01molHCI
107. T amp C Technical 3 34 pH pH 1pH ApH AU pH 58 16mV 0 pH7 pH7 pH14 58 16mV 99 8 pH pH 32 HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH
108. URE OF EXCELLENCE by T amp C Technical 4 1 2 3molL KCI KCI 3mol L gt gt L
109. nt by Petra Spitzer ISBN 3 89429 877 4 ISSN 0947 7063 37 d e HAIVIILT IN THE MEASURE OF EXCELLENCE by T amp C Technical pH
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