マルチショット・パイロライザー MODEL EGA/PY
Contents
1. Ver 1 242. Fig 5 9 EGA ZONE 0 8 10 15 5 18 20 28 min 40 100 200 300 400 500 600 C Fig 5 10 EGA 5 Ver 1 24 STEP1 STEP2 GC Fig 5 11 1 ITF TEMP Auto 2 Heart Cut EGA Analysis STEP3 1 LS 2
3. 4
4. 3 3 2 3 3 3 3 4 3 4 1 PY1 3018M
5. EGA Fig 5 4 2 5 m 0 15 mm 300C Fig 5 6 He P N UADTM 2 5N Fig 5 4 Vent free GC MS MS
6. 20 PY 2020iD
7. MJT 1030Ex SS 1010E CGS 1050Ex cs frontier lab com 1 Fig 4 5 2 CGS 1050Ex Fig 4 5 a A Air Fig 4 5 b B
8. 7 5 Ver 1 24 7 4 PY 1 Heater POWER Furnace Interface PY SENSOR Sensor cryo Trap PY SENSOR 3 Overheating
9. ITF N 1 GC 1 1 EGA 1 2 GC 1 3 GC He 3 6
10. 4 2 1 4 2 1 1 1 Fig 4 3 F Settings Fig 4 4 2 3 4 2 1 3 4 OK 4 2 1 2 CGS SS MJT AS IAccessorics Settines EE v CGS He TAir RSS He TAir Pressure Stability Time 2U sec Default 20 MJT AS Purge Time 10 sec Default 10 Cancel Fig 4 4 4 4 Ver 1 24 4 2 1 3
11. GC MS Evolved Gas Analysis EGA TG Ultra ALLOY Py GC FS 4 50C Ci Cro No 2742492 Ultra ALLOY
12. 4 A1 A2 A3 A1 A2 5 9 Ver 1 24 P N PY1 7510
13. 1 Fig 5 5A STEP4 START Ready for injection Fig 5 5B Start GC A B Fig 5 5 Fig 5 6 EGA 1 50C 200 C 2 350C 500
14. MS 7 0 min 4 5 Ver 1 24 4 2 2 Auto Manual Fig 4 3 E 4 Auto Manual
15. 1 A1 Single Shot Analysis 2 A2 3 Save 4 1 3 Fig4 23 5 B Ver 1 24 Fig 4 23
16. HCI HBr 6 1 4 4 GC PY1 2216 6 8 Ver 1 24 6 2 3 4 6 2 1 1
17. 100 C 6 1 4 2 A GC ITF N 350 C 2 3 1 2 6 1 4 3
18. 100C 2 P N PY1 2025 3 a 2 3 b
19. 3 2 ITF 3 2 6 3 Ver 1 24 4 ITF N 12 mm ITF ITF ITF N 2 mm ITF N 12 mm ITF N 5
20. 2 5 mg 5 wWwtD 0 5 ml 5 pg ul EGA STEP1 0 15 mm id 2 5 m STEP2 1 GC Fig 5 6 ITF TEMP Auto 2 Direct EGA Analysis 5 3 Ver 1 24 STEP3 1 SF 5ul 2 SF
21. EGAPY 3030D Ver 1 24 1 2 EGA PY 3030D EGA PY 3030D PY 2020iD 1 1050C 2 3 4 5 4 GC MS
22. 3 4 Ver 1 24 3 6 3 1 PY1 7801 2 NO N a Fig 3 2 Fig 3 3 Furnace temp C 600C 40C C 20C 500 KPa 5 bar 10 min 700 600 10 Kpa 0 1 bar 30 min 500 500 KPa 7 L min 400
23. Fig 5 2 ro Fig 3 550C ITF 300C 300C 70C 20C min 320 1min Ultra ALLOY 5 30m 0 25 0 25hm 25ug 5ug ul 5uD He 1 mmin 17100 MS 50 350 m z MS 3 scans sec Styrene Monomer Dimer SS Trimer SSS Me stearate Fig 5 3 Ver 1 24 5 2 EGA FID MS
24. 1 2 mm me 1 6 ITF ITF 7 a ITF EE 6 4 Ver 1 24 8 ITF 12 mm 174 9 10 ITF
25. EGA UV PY GC MS HB 1 a b c 9 2 UV Ver 1 24 1 4 EGA PY 3030D 2 2 ITF ITF N GC Fig 1 1 1 4 Ver 1 24 2
26. 2 3 15 Fig 6 3 6 6 Ver 1 24 6 1 3 ITF N 6 1 3 1 ITF ITF TEMP 250 320 C 6 1 3 2
27. EGA EGA EGA RSD 0 3 Me Ste SSS RSD 2 Fig 8 1 Fig 8 2 8 1 Ver 1 24 IIKKEKKKKIKYUKKKKKIKKKKKIKKKKKKILKKMKKKKKKLKKKKLKKMKKKKIKIKINKILIYAKNKILEKAKKLKKKKIUKKKEKKKKLEKKKLKKIKKKKKIKIKMKKILKXKKKKKKKKKKKKLKKMKKKIKKKKIKILIXIKNKILIKIAKKLKKKKKMIKKEKKKKLKKEKKKKKKKIKKIKMKKIKKKKKKKKLKKKKLKXMKKKKKKKKKKKIIXAIKIKILIKAKNLIYKKIKKKEKKKKLKKEKKKKKEKKKKKKLKKIKXKKKKKKKIIKXAKKKKXLKKKKKKKXKKIKXKKKIKILIXAKNKIXIKIKIO Py Py GC ITF ITF
28. PBDE 6 6 1 1 3 6 1 Ver 1 24 6 1 1 2 1 2 Fig 6 1 1 2 3 Fig 6 1
29. EE 6 2 Ver 1 24 6 1 2 SS 6 1 2 1 1 2 1 3
30. 1 1 1 2 EGA PY 3030D 1 3 1 4 2 3 3 1 3 1 1 3 1 2 _ MS 3 2 3 3 GC 3 3 1 GC 3 3 2 _ 3 3 3 3 4 3 4 1 3 4 2 3 4 3 GC 3 5 3 5 1 3 5 2 PC 3 5 3 3 6 3 6 1 3 6 2 3 6 3 3 7 3 7 1
31. 7 2 Ver 1 24 7 2 OFF ON 5 PY ee POWER SENSOR RR _ PY
32. 6 1 2 2 Fig 6 2 A 6 1 2 3 Fig 6 2 6 5 Ver 1 24 6 1 2 3 7 1 Fig 6 3
33. 3 1 Ver 1 24 3 1 2 MS GC MS MS Vent free GC MS MS Vent free GC MS Ultra ALLOY He 5 MS MS 10 Ultra ALLOY 5 0 25mm 0 25um 30m 3 2
34. GC Fig 5 3 1 ITF TEMP Auto 2 Single Shot Analysis 1 SF 5ul 2 SF 1 Fig 5 2B START Ready for injection Fig 5 2B Start GGC mp A B
35. MS GC MS AIA 700 2 165 358 PY 1111E 141 F Search Ver 3 4 PY 1112E 141 EGA MS 14B MS 700 MS PY 1113E 141 PyGC MS14B Py GC MS 700 MS PY 1114E 131 ADD MS 13B 358 MS 3 400 PY 1115E 131 Pyrolyzate
36. GC e PY1 1060 2 e SS 1010E e UV 1047Xe UV On line UV e MS402180 Vent free GC MS e PY K303D 1 e PY K313D AS 1020E 1 e Ultra ALLOY 0 25 0 53 mm 5 60m 1 Split Splitless GC 2 400 600kPa 178 3 mm
37. 0 1 mm 2 A1 A4
38. Hh dh Appendix 4 Ver 1 24
39. B 1 Re order PY1 7618 C D D1 1 NN ee C1 1 1 Re order PY1 1030 1 PY 30A 1 E 3 Re order PY1 3631 1 E1 1 1 1 Re order UA5 30M 0 25F Re order UADTM 2 5N 1 F _ ESyeYosoppamrs sod ee EGA PY 3030D 1 5m 1 5m 1 Re order PY1 7805 1 1 8Swagelok 1 Re order PY1 7613 1 JSB Re order PY1 7801 1 Re order PY1 3751 1 Ver 1 24 SF 0 Po PYLESIOF 90 2 3mg 1
40. ITF Auto Auto ITF 1009C 100 C 7 3 Ver 1 24 7 3 ITF TIC MS m z 28 32 50 ml min GC
41. PIN PY1 3018M 7 4 Ver 1 24 eo SE a 3 Fig 7 1 2 ITF 100m min 1mlmin SC N GC GC 1 2 1
42. 3 6 Ver 1 24 3 8 1 AS 1020E AS 1020E RS 232C RS 232C PC PC Ht 3 8 2 SS 1010E MJT 1030Ex 35E CGS 1050Ex VALVE 3 7 Ver 1 24 3 9 3 9 1 USB
43. Zone Initial min Zone Final min Zone A Initial 0 0min Initial C Final CC E F G A D E H 4 2 START GC
44. 10 10509C 19C 0 19C 10 min 800 509C ITF 40 4509C 19C 0 19C 10 hL 50uL 80 HL PC PC USB 900 C 900C cs frontier lab com 20 900 C
45. 6 10 Ver 1 24 6 2 5 PY1 3018M M30 N PY1 1274 GC ITF N PY1 3513 EGAPY 3030D a EE YOR PY1 EP55F Ne A PY1 2025 20 452 PY1 1
46. 3 8 3 8 1 AS 1020E 3 8 2 _ 3 9 3 9 1 USB 3 9 2 3 9 3 COM 3 10 3 10 1 3 10 2 A 2 A 2 A 2 A 3 A 6 A 8 1 1 1 1 1 2 1 3 1 4 3 1 3 1 3 1 3 2 3 2 3 3 98 3 3 3 3 3 3 3 3 3 3 3 4 3 4 3 4 3 4 3 4 3 4 3 5 3 6 3 6 3 8 3 9 3 9 3 11 3 11 3 12 Ver 1 24 4 EGAPY 3030D 4 1 4 1 1 4 1 2 4 2 4 2 1 4 2 2 4 3 4 3 1 Single Shot Analysis 4 3 2 Double Shot Analysis 4 3 3 Direct EGA Analysis 4 3 4 Heart Cut EGA Analysis 4 4
47. ITF ET rg Il 800 C 800 1050 C 800 C 1 ml GC 40 C 30 10C min SD
48. 4 1 4 1 4 1 4 2 4 4 4 4 4 6 4 7 4 7 4 9 4 12 4 14 4 17 4 17 4 17 4 20 4 20 5 1 5 1 5 3 5 5 5 7 5 9 5 11 6 1 6 1 6 1 6 3 6 7 6 8 6 9 6 10 6 10 6 10 6 11 6 12 7 1 7 1 7 3 7 4 7 6 8 1 Appendix 1 2 Appendix 3 Appendix 4 Ver 1 24 1 1 1 PY GC
49. 5 2 6 START 7 GC Fig 4 8 Starr PC ENTER Fig 4 8 Single Shot Analysis 4 8 Ver 1 24 4 3 2 Double Shot Analysis Tools Analytical Modes Double Shot Analysis
50. ITF N 45 90 6 Ver 1 24 6 1 4 GC 6 1 4 1 GC GC 50 C 3000C 1
51. 10 msec 1992 100C 300C 500 800C
52. 50 200 550C 50 lt GC 50C 20 C min 600C 300C Auto 300C 300C MS 300C He 1 mmin 100 mMmin 10100 0 15 mm 2 5 m 100 ug 5 ug ul 2 0ul MS 50 350 50 200 300 400 500 600 C MS 0 1 scans sec Fig 5 6 EGA Ver 1 24 5 3 Py GC MS
53. 50 C 1 2 6 2 4 GC
54. Ready for pyrolysis Start Yes GC GC Pyrolysis 9C ff a a 2nd TD Final 9C 7 2 TR 0 9C min 1st TD Final 9C ae 1st TD Rate B 5C min 1st TD Initial CC A a 1st TD Initial min 1st TD Final Kmin 2nd TD Final min py Initial min lt 1stTD gt lt 2nd TD gt RW START END Ready for desorption START GC Fig 4 13 Double Shot Analysis Ver 1 24 4 3 3 Direct EGA Analysis
55. pn 7 7 Ver 1 24
56. 50 C Ver 1 24 CS UU 1009C 900C 900 C 900 C 20 900C cs frontier lab com
57. AUTO 100 C E 3 NV 4 3 Ver 1 24 4 2
58. START 1 Ready for injection Start Fig 5 7 C 2 Prepare for pyrolysis step Yes GC A B C a RR Fig 5 7 5 5 Ver 1 24 STEP5 GC Ready for pyrolysis
59. lt 200 300 C Ver 1 24 fo EGA PY 3030D FRONMTIER LRBH A B A1 B2 B1 AC 1 Re order PY1 7023 1 Re order PY1 2022 CD ROM 1 PDF ih 1 Re order PY1 6034 1
60. Agilent 7890 6890 Agilent 7890 6890 3 GC 17A 14A GC 2010 3 MS VF A 50 2 VF 1 2 VF 1 VF D 10 A 1 1 VF A 70 2 VF 1 2 VF 1 VF D 10 A 1 1 VF A 70PE 2 VF 1 2 VF 1 VF D 10 A 1 1 VF 0 15 mm id 50 cm 1 VF D 1 VF B 1 VF 0 15 mm id 70 cm 1 1 1 16
61. 4 3 1 Single Shot Analysis Tools Analytical Modes Single Shot Analysis Single Shot Analysis A Fig 4 7 D 40 1050 C Fig 4 7 Single Shot Analysis 4 7 Ver 1 24 1 Furnace Interface B ON 2 C 3 D 7 Start D Sampling ON 4 E Setting
62. 0 5 ml 1 5 m 1 8 Swagelok 400 600kPa 178 7 3 mm 600kPa MS402180 Vent free GC MS MS402190 J A MS CGC MS 20 cm 35 cm GC 2m 1 FID FID AC100V3W TEXT PUMP 40C Fig 2 1 2
63. YES GC Fig 4 9 J Dauble Shnt Analys Prepare for pyrolysis step Fig 4 11 Double Shot Analysis Desorption Program 10 GC 11 GC GC Ready Fig 4 12 START PC ENTER GC Ver 1 24 Dauhle Shot Analysis Ready for pyrolysis Cancel Fig 4 12 Double Shot Analysis Fig 4 13 Prepare for pyrolysis GC READY
64. 200 300 C Ver 1 24 iii ESAPY3030D 4 2 5 Ao rr A TR i PT WI PD an PP 3 YE a 0 FuApm i 2 mra 1 DL a cs ce 2 Fe m 5 SF x 10 DF x 10 x 1 x k 1 x 1 x5 11 1 1 1 2 5 mg g 2 2 mL L 0 0 5 mL CD Windows 7 Vista XP x 1 1 5 m x 1 1 5 m x 2 USB 2m x 1 gt x 1 x 1 x 1 F x 5
65. a 6 1 2 ITF 0 7 1 Ver 1 24 Ultra ALLOY UA5 NA EGA 50 C NN
66. Double Shot Analysis A Fig 4 9 TD PY E F G H 40 1050 C 0 999 9min A 0 600 C min 40 1050 C 0 999 9min OI EGA PY 3030D Cantral Dshot_DSmtd File View Tools Help B Sl Luans Double Shot Analysis START STIOP Pyrolyzer onitor gt Furnace Not Ready TO Initial Initial Rate Final Final Total N min cinin mi min Run C 1st 200 0 00 20 300 5 00 10 00 am 20 400 5 00 20 00 Actual Set D IPYL 600 020 Fumace 200 0 200 C C J J 40 10509C interface 300 0 9 300 SG fnterface Upper Temp 300 sC Auto Manual Accessories Sampling TD1st Zone K OH SS MIT AS CSS UV Settings ne mIin 0 999 9 DIS Cryo Trap ss EE TE OR EN 1 Sampling Cryo Trap Il TD 2nd _ PY a Elapsed Set EE Time 0 00 1 20 00 ia Elapsed Time
67. 1 USB RTS Kmsec Fig 3 7 COM Ver 1 24 3 10 3 10 1 Fig 3 8 9 le i 2 a ca Ne 1 1 ui 1 TF Ai ON u 3 IDT Sh yy A LP i T lt 2 ITF ITF ITF Fig 3 8 3 1 1 Ver 1 24 1 ll 3 OR QO NN NT 0
68. PY1 1345 4 P 12 P N PY1 7811 6 2 2 GC P N PY1 2216 3 6
69. DF Fig 5 7B STEP4 STEP4 START Ready for injection Start GC GCMS Fig 5 11 GC Dibu
70. Zone A D Zone B Ver 1 24 4 4 4 4 1 File Save As Table 4 1 Single Shot Analysis Test mtd Test SS mtd File Save File Open Table 4 1 Single Shot SS Double Shot DS Direct EGA EG Heart Cut EGA HC 4 4 2 T
71. 2 3 Ver 1 24 3 GC GC OFF 100C GC 3 1 3 1 1 Be GC AC100V 4A PC oewmeea 0 GC GC MS PC CD ROM USB 2 m Sa
72. Fig 4 19 Star PC ENTER Ready for injection Fig 4 19 Heart Cut EGA Analysis Ver 1 24 Fig 4 20 Zone D Final 9C Zone C Final 9 EE EEEEWEWdWdTdudT ud Tr Zone B Final 9C OitOiti ti Os u RMNN x A T q qq q s 0 Zone A Final 9C i oD Zone A Initial C 8 gt Zone A _ ZoneB ZoneC D Initial min START END Ready for injection START GC Fig 4 20 Heart Cut EGA Analysis
73. Fig 4 3 E 3 Auto 100 C E 3 E 4 Auto E 3 300 C 50 C 500 C Fig 4 6 1509C 1009C 300C CC _ 300 C 150 C 50 C Fig 4 6 4 6 Ver 1 24 4 3 Single Shot Analysis Double Shot Analysis Direct EGA Analysis Heart Cut EGA Analysis 4
74. 1 UV UV Py GC MS Ver 1 24 6 GC GC 50 C 6 1 GC GC 6 1 1
75. 4 4 1 4 4 2 4 4 3 4 4 4 PyConditioning Table 5 4 5 1 5 2 EGA 5 3 5 4 EGA 5 5 5 6 6 6 1 6 1 1 F 6 1 2 6 1 3 6 1 4 GC 6 2 6 2 1 6 2 2 GC 6 2 3 6 2 4 6 2 5 6 2 6 7 7 1 7 2 12 7 3 7 4 8
76. 4 4 2 2 C D E F1 F2 Clear 4 4 2 3 PY CGS 1050Ex 1 Maintenance 4 4 2 4 G H
77. Air CGS He Air He Purge Time 1 0 min Default EE SS _ He Air He Purge Time in Column 2 0 mi Air Purge Time in GCIMS 7 0 mi ne 2 0 min Default 2 0 Air Purge Time in GC rU min Default 7 0 MJT AS Purge Time 10 sec Default 10 ee ASI Purge Time 10 sec Default 10 Cancel Cancel a b Fig 4 5 3 C He Purge Time 1 0 min 4 D He Purge Time in Column 2 0 min 5 E Air Purge Time in GC MS
78. USB 1 USB PC 2 EGAPY 3030D control software CD ROM CD CD D 3 4 Fig 3 2 USB 1 CD Windows 0 Windaws Update
79. 4 9 Ver 1 24 6 START 7 GC Fig 4 10 Ready for desorption _ cammcel Fig 4 10 Double Shot Analysis Desorption Program 8 Start PC ENTER 9 GC b Fig 4 11
80. Cooling ON 21 Cryo trap Temperature MJT 250 300kPa _ 7 6 Ver 1 24 8 GC GC EGA
81. 1 VF 0 15 mm id 70 cm 1 VF D 1 VF B 1 VF 3 VF 20 Ultra ALLOY 2 5 m Appendix 1 0 15 mm Ver 1 24 5 M M P 3 PY1 1345 PY1 1342 PY1 3573 PY1 2112 6 S500 S500 L500 L500 L100 L100 SL PY1 MC01S PY1 MC01S K PY1 MC01L PY1 MC01L K PY1 MC02L PY1 MC02L K PY1 MC01SL K PY1 MCP01 1 1 1 1 1 1 1 1 1 1 1 1 6 800
82. EGA GC MS C15 EGA Fig 5 9 8 GC MS EGA Fig 5 10 4 GC MS PF
83. PY 2020iD iS PY1 2018M 3 4 2 PY 2020iD iS PY1 7911 100 PY1 7921 3 4 3 GC ITF GC 2 mm
84. 25 ug 5 ug pl 5 uD LF MS Autotune 200V 300C 5 10 min 29 350 m z 3 scans sec 91 SS 74 Me Stearate 91 SSS 117 104 130 208 194 312 100 200 m z 100 200 300 m z 100 200 300 m z Fig 8 2 Ver 1 24 1 SF PY1 EC50F 1 30 000 LF PY1 EC80F 1 30 000 G PY1 EC50G 1 15 000 GQ PY1 EC50GQ 1 15 000 SHF PY1 EC50HF 1 7 200 LHF PY1 EC80HF 1 7 200 SF PY1 ES10F 1 15 000 DF PY1 ES20F 1 15 000 GS PY1 ES10G 1 15 000 GD PY1 ES20G 1 15 000 M PY1 EP55F 1 9 500 GF PY1 EP55GF 1 9 500
85. GC Fig 3 1 GC GC GC Fig 3 1 3 2 Ver 1 24 3 3 GC 3 3 1 GC GC GC GC
86. USB 0 EGAPY 3030D Select the Com port to the controller Press Work Offline button when stating offline Com1 Com2 Com3 Com4 Com5 Com6 CCom7 Com8 Fig 3 5 COM 5 pe B HH COM LPT ECP OPT USB Serial Port GOM3 4 COM3 COM COM2 0 Fig 3 6 COM 3 9 Ver 1 24 1 Windows
87. 2 m 3 M El 1 Appendix 2 Ver 1 24 Fig A 1 P 6W P 12 P N PY1 2017 20 P N PY1 7811 10 M30 P N PY 3018M 1 EE P N PY1 3551 1 P N PY1 3555 1 a a P N PY1 3552 1 P N PY 7911
88. 3 3 Ver 1 24 3 5 3 5 1 3 5 2 PC PC USB 2 m GC GC MS 3 5 3 GC GC READY GC START
89. 1710 17100 MS FID 550 C He MS eeeeeeeeeeeseeeeeeeeeeeeeseseseeeeeeeeeseeeeeeeenesese neseseee eeee ee ecceeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeese seeese enese se ecoeee ceceeeeeeeeeeeeeeeeeseeeeeeeeeeeeeeeeeeeeeeeeeeeseeeeeeeeeese eenese eneee ee ecoe ceceeeeeeeeeeeceeeeeeeeeeeeeseeeeeeeeeeeer Fig 5 1 Py GC MS 2 5 mg 5 wt wt 0 5 ml 5 ug ul 5 1 Ver 1 24 STEP1 STEP2 STEP3 STEP4
90. 7 3 GC GC GC OTN FRE 1009C 100 C et a 200 3009C jTF GC 350C MS GC MS ITF 0 MN A
91. E Update Web LA 0 USB lt gt Serial 0 CD GJ AA ypLC w et lt C
92. UADTM 2 5N GC lt 250 300 C Tools Analytical Modes Direct EGA Analysis Direct EGA AnalysisS A Fig 4 14 A E F G H D Ox B W START SSR Monitor Not Ready nitial Initial Ratg Final Final otal sC min I C fin 2 mip min Run 0 50 20 500 1 00 21 50 40 700 100 27 50 Actual Set 2o soo 90ool 3250 Fumace 100 0 100 4o tooo 00 Interface 200 0 sC 200 C Interface UpperTemp 300 8C Auto Manual TAccessories SS MJT _ AS TT GGS UY Settings Elapsed Set Time 0 00 37 50 EE 4 gt Elapsed Time Fig 4 14 Direct EGA Analysis 1 Furnace Interface B ON 2 Step1 D H
93. 90 Ver 1 24 f File Print 4 4 4 Py Conditioning Table Tools Py Conditioning Table Fig 4 24 Run Fig 4 24 2012 3 10 21 7000C 3000C 3 11 0 1000C 2000C RUN Py Canditianihg Table Date Time Fumace C Interface C sem Run StOD Close Fig 4 24 Py Conditioning Table 4 20
94. EGA START SSPR Pyrolyzer k Furnace Not Ready 1 ctep Initial Final min 8 CC min Run 1 2nd 0 40 100 Actual Set sl sl nm a i interface 200 0 6 200 sC Sampling Zone 5 Cryo Trap 2 Interface Upper Temp 300 s Auto Manua E rAccessories SS MJT nAS GES WW Sampling zone ia min D 1 Time 0 00 6 00 ia Elapsed Time Fig 4 18 Heart Cut EGA Analysis 4 14 Ver 1 24 Tools Analytical Modes Heart Cut EGA Analysis Heart Cut EGA Analysis A Fig 4 18 1 2 3 Furnace Interface B ON C Direct EGA Analysis Fig 4 17 EGA Zone D MS
95. F 6 1 1 1 F 1 2 6 1 1 2 2 600 C 1 3 5 4 5
96. IE Ver 1 24 5 6 Table 5 1 Ultra ALLOY 0 1 mm Table 5 1 AS 1020E
97. S L 5 2 5 mg 5 wt 2 ml 1g 2 EGA PY 3030D 20 EGA PY 3030D 20 10 EGA PY 3030D ITF N ITF N 2 EGA PY 3030D EGA PY 3030D Agilent7890 6890 GC 2010717A EGA PY 3030D PE Auto system Clarus GC N 3 3 2 6 mm PY1 3513 5 20 Agilent 789076890 5 GC 5 Agilent 7890 6890
98. 200S 03 050S 300S 400S 500S 04 L 8 1 3030D EGA PY 3030D 3030S PY 3030S 9 FMP 0 75S FMP 1 25S FMP 2 00S FMP 03KIT HMP 0 50S HMP 3 00S HMP 4 00S HMP 5 00S HMP 04KIT FCM 6577 PY K303D PY K303S PY1 7510 PY1 7515 1 1 1 1 1 1 1 1 1 1 1 1 1 1 10 000 10 000 10 000 25 000 10 000 10 000 10 000 10 000 25 000 9 500 208 000 208 000 17 900 6 800 0 75 mm 3 L1 1 25 mm 3 L 1 2 00 mm 3 L1 0 75 1 25 2 0 3 L 2 0 50 mm 3 L1
99. Start C Fig 5 8 A 1 A 2 B A 1 A 2 A 1 100C 30C min gt 200 3min ITF 300C 300 70C 20 C min 320 1min Ultra ALLOY 5 30 m 0 25 0 25 um 5 Eco cup He 1 m min 1750 Me stearate Trimer SSS 2 IN A i Styrene Monomer amp a B B 550C A Styrene Monomer Trimer SSS Me stearate Fig 5 8 5 6 Ver 1 24 5 4 EGA
100. Fig 7 1a P 6Wy P N PY1 2017 ITF Fig 7 1b P N PY1 7911 PY1 7921 ITF N Fig 7 1b ITF N P N PY1 1274 Fig 7 1c P 12 P N PY1 7811
101. Start PC ENTER Direct EGA Analysis Ready for injection Cancel Fig 4 16 Direct EGA Analysis Ver 1 24 4 3 4 Heart Cut EGA Analysis Cis Heart Cut EGA Analysis Direct EGA Analysis EGA GC 100 600 C 205C min EGA Fig 4 17 0 10 18 23 30 mi t tg Time Temp Fig 4 17
102. AL PY1 EH10AL 1 12 500 PY1 4908 1 4 200 PY1 5111 1 3 400 2 M30 PY1 3018M 1 14 700 0 8A PY1 7412 1 2 400 M PY1 2025 1 1 100 M P 6W PY1 2017 1 3 700 M P 12 PY1 7811 1 2 100 3 M ITF N PY1 3513 1 19 000 ITF N PY1 3515 1 26 500 M ITF ASN PY1 3533 1 28 000 3030SA PY1 3551 1 16 000 3030PE PY1 3552 1 16 000 PY1 3512 1 2 100 N PY1 1274 1 12 600 PY1 7911 1 14 700 M PY1 2028 1 1 100 4 GC PY1 7301 1 3 500 PY1 7304 1 4 000 PY1 3337 1 5 800 PY1 3361 1 21 000 PY1 2202 1 6 300 17SV PY1 2227 1 15 800 M PY1 2216 1 6 600 GC MS PY1 2210 1 24 200 GC MS
103. c ee w0 8A a Wi CPY1 1032 PY1 7412 PY1 1033 L L PY1 2025 PY1 1021 PY1 1031 P 3 PY1 2112 PEH od PY1 1342 PY1 1345 PY1 3573 6 9 Ver 1 24 d
104. 3 00 mm 3 L 1 4 00 mm 3 L1 5 00 mm 3 L1 3 0 4 0 5 0 3 L 2 L 65x75mm 5 SF 100 LF 100 SF 50 DF 50 AL 5 M30 4 N 8 6 mm 8 F 5 10 SF 100 LF 100 SF 100 AL 5 M30 4 N 8 6 mm 8 F 5 10 Py GC FT IR XRD 3 2 m 1
105. EGA 2 5 m 0 15 mm 1 0 mmin 17100 300C 300C 100 gt 550 C 20C min 300C AUTO RSD 0 3 n 3 Polystyrene 5 wt 125 ug 25 ug ul 5 uD LF Methy Stearate MS FID GC MS ITF 300C 29 350 m z 100 200 300 400 500 0 1 scans sec Fig 8 1 SSS Me Stearate RSD 2 n 3 Ultra ALLOY 5 5 95 St 30 m 0 25 mm 0 25 um VEEN DONO 1 0 ml min 17100 70 320C 20C min 1 min Me Stearate 300C Py 550C Py GC ITF 300C GC MS ITF 5 wt
106. GC ITF N 1 2 ITF N ITF 6 1 3 3 ITF N ITF
107. GC 6 3 6 1 EXT PUMP 100V 3W F 3 6 2
108. AL x 5 PDF 5 AC100 110V 50 60 Hz 4A MAX W X D X H mm kg 76 W x 143 D x 215 H mm 1 6 kg 120W x 310D x 310 H mm 5 4 kg Adilent 7890GC ei 5975 GC MS_ TRACE 130071310GC Trace ISQ GCMS QP2010 GC 2010 GC GC MS JMS Q1000GC Mk II Clarus GC GC MS 436 456 GC SCION SQ 6 e AS 1020E 48 e CGS 1050Ex He SS 1010E e MJT 1030Ex 35E GC C e PY 1110E F Search e PY1 1050 On line
109. LF PY1 EC80F 100 SF 30 C mg SF PY1 EC50F 100 LF LHF PY1 EC80HF C3 10 20 10 mL min GNC 0 OPD ET SF PY1 ES10F 50 EGA EGA 8g 3P25 i 50
110. GC GC 11 EGA GC He ITF 15 30
111. 7 L min 3 AC100V 4A 3P 4 PC GC GC MS PC OS Windows 7 Vista XP USB 1 2 2 Ver 1 24 Fig 2 1 PY1 7801 P a Furnace temp C 600C 40C 170 KPa 15 Lmin 11 mn 100 KPa 7 L min 13 min 50 KPa 3 4 L min 14 min lt 0 1 kPa 0 2 L min 30 min 100 kPa Standard 40C Cooling time min Fig 2 1 20 C Fig 2 2 Air flow rate L min 16 14 0 50 100 150 200 P Air pressure KPa Fig 2 2
112. 7 6 1 1 3 1 2 3 1 4 5 6 3 5 2 3
113. Furnace Interface Sample cup standby position USB PC USB 1 RS 232C 11 Connection NE 2 ON VI i 12 Cup chute a 1 300kPa 500kPa 2 13 Sample cup retrieval 3 ce
114. 300 10 KPa 0 2 L min 200 OO 40C Cooling time min Fig 3 3 3 5 Ver 1 24 3 7 800 C 3 7 1 B 500 kPa 100 mL min B GC
115. gt 3 Step2 Step2 Rate C min 0 Step4 Fig 4 15 Direct EGA Analysis Step1 4 C Settings SS C Ver 1 24 lt STEP1 gt lt STEP2 gt lt STEP3 gt STEP4 gt Fig 4 15 EGA 5 2 6 START 7 GC Fig 4 16
116. FY OE Peokk PY hE TO D ml DF 0 Peo PY EOF 6mm 3 Peo ti PY TH SE P 6W 69 WPT1T131 1 Pe PT EE 6 PO PT EH AL SR AL G9 1 M30 2 FTWT PT 11 Tf t A B 1 6 PT IOCD 1 Foe PT 515 1 Mg Al nt ht hs ie Peo hy sth 3630 Batzp REPY HOGI 1 B TE NR 5 2 0 Pe oR ERY St er Gg F 6 2 10 12mm CN MS TF PTY EPS5F J Em 1 cr JOmim SF 20 8 LF 20 6 Pe oKhk F PY ECSOF KOBE Fe fKWF PTLEC2OF ROR M6 GOA th ma 3 Ver 1 24
117. Fig 3 6 COM LPT USB Serial Port COM COM Fig 3 5 OK 1 8 USB Serial Port Fig 3 7 Fig 3 6 1 8 OK 2 COM3 COM P USB D BM
118. Fig 4 2 Fig 4 2 4 1 Ver 1 24 4 1 2 Fig 4 3 A B E J START SOP Mentor lt l Not Ready J 1 TD Initial Initial Rate Final Final Total I c min cimin C min min Run PP J 2 200 000 20 3oo 500 10 00 2nd 20 4oo soo oo Actual Set 600 020 Furnace 200 0 200 0 E 2 PC Interface 300 0 300 Se RO NI Ci ae Samplin st Zo 1 J 5 S S Settings AA FE mpling Cryo Trap 55 J 6 Sampling Cryo Trap Em FN sg i IPY a oo Elapsed Set Ne ooo leo ElapsedYime G Comment H Status bar J 7 J 8 Fig 4 3 A B C 1 Single Shot Analysis C 2 Double Shot Analysi
119. Fig 4 9 Double Shot Analysis 1 Furnace Interface B ON 2 E 1 G Rate 2 0 3 D J K 4 L 5 1 4 2 GC GC 5 GC
120. a EGAIPY 3030D 1 MS n 3 EGA 2 500 kPa ITF ITF e SF LF 3 _ SGLIDBL Direct EGA Heart cut EGA ITF temp Method Fle Temp Monitor Maintenance e gt 8 25 hg 550 C LF SSS Me Stearate RSD lt 2 LF RSD s 0 3
121. MS402180 1 128 000 50 GC MS MS402190 1 128 000 70 GC MS MS402195 1 128 000 70PE VF A 50 MS402159 1 35 000 VF A 70 MS402191 1 35 000 VF A 70PE MS402196 1 35 000 VF B MS402286 1 15 000 VF D MS402167 1 22 000 MS604234 1 2 100 EGA UADTM 2 5N 1 22 000 2014 12 1 50 ul 3 8 mm 100 80 3 8 mm 100 50 ul 3 mm 100 50 Hl 3 mm 30 50 ml 3 8 mm 20 80 ml 3 8 mm 20 50 50 G GQ 50 G GQ 50 5 G GQ 5
122. PY 1030Ex GC C4 MJT 1030Ex PY 1035E MJT 1030Ex amp MJT 1035E PY 1047Xe UV Xe UV 1047Xe PY 1050Ex CGS 1050Ex PY 1110E 141 F Search Ver 3 4 MS EGA
123. 10 300 3 200 4 400 36 600 15 800 36 600 37 600 36 600 37 600 36 600 22 100 1 1 20 100 500 um 6 mm 10 DF 5 S500 3 LHRF 5 100 500 um 30 mm 5 DF 5 L 500 3 L 2 100 100 um 30 mm 5 DF 5 L 100 3 L 2 S500 L500 L100 2 L 3 7 075S 125S
124. 5 P N PY1 7301 5 ITF N P N PY1 7304 5 P N PY1 3513 1 N P N PY1 1274 3 RNN NT Fig A 1 Appendix 3 Ver 1 24 gt SS 1010E 8 PY 1010E PY 1020E 48 AS 1020E
125. GC MS EGA MS EGA GC MS 59 0 Online Option Option UV Option Ver 1 24 1 3 EGA PY 3030D F Search EGA PY 3030D Table1 Table1 EGAPY 3030D AT HI U2J9S gt MINJV CM7 H MM 4
126. MS13B 165 MS 3 200 PY K303D 3030D 1 PY K313D 3030AS EGA PY 3030D 1 HH o PY1 2210 GC MS Ultra ALLOY MS Q Pole MS MS402180 GC MS 50 MS MS402190 GC MS 70 MS MS EGA MS402195 GC MS 70PE MS Ultra ALLOY
127. OO 0 O O OO O O OO OO O OQ Multi Shot Pyrolyzer EGA PY 3030D a se oOo oO RS 232C OO ee oo HH O HEATER RS 232C POWER AS 1020E USB PC E PS COOLING VALVE GAS EXT PUMP GC 100V 3W REMOTE i QE EN R SN nn 100V 100W HH HH AC100 115 INPUT 100V 400W FRONTIER LAB MADE IN JAPAN Fig 3 9 3 12 Ver 1 24 4 EGA PY 3030D 4 1 4 1 1 EGA PY 3030D Control Fig 4 1
128. Ver 1 24 5 4 5 1 4 lt EGA 4 GC GC MS Py GC MS Fig 5 1 550C GC splitsplitless
129. 345 1 amae zs TTT 9z ms mes lezm ai 4 5 GC GC 6 2 6 11 Ver 1 24 6 2 6 2 6 12 Ver 1 24 7
130. D ROM 4 D Driver_USB_Serial RO V 3 0 0 sw D Driver USB_Serial 3 8 Fig 3 4 USB Ver 1 24 3 9 2 CD ROM Z1 1 EGA PY 3030D control software CD ROM PC CD 2 3 9 3 COM Fig 3 5
131. Fig 5 1 Fig 5 6 EGA STEP1 STEP2 GC Fig 5 8 1 ITF TEMP Auto 2 Double Shot Analysis STEP3 1 LF 5ul 2 DF Fig 5 7 A Fig 5 7B 2 STEP4
132. Ver 1 24 MODEL EGA PY 3030D FRONTIER LAB www frontier lab com 1 2 GC GC MS snn gn
133. ools Maintenance Fig 4 21 3030 OK Fig 4 22 Password Input Password Cancel Fig 4 21 Ver 1 24 IMaintenance TA rTemp Display Monitor Ra SSR D es e 00 co Equilibr fhme Not Read A1 10 sec Save un se Single Shot Input Measured Actual Set B Furnace 595 c Save E ul mm Save Fumacel 599 8 600 Max Furmace Femperature_ eet HAS _save erce 300 3 3oo G MicroJet Cryo Trap Temperature Calibration C c 2 CE sc po Save Sampling Zone 6 Cryo Tral 54 Range 0 196 C Default 1 100 6 Save C Manual Valve Check C1 Furnace Cooling Gas G5 C2 Selective Sampler C6 C3 MicroJet Cryo Trap C7 C4 CGS Valve C8 Number of Accumulated Runs 1000 Maintenance Close F2 Elapsed Time Fig 4 22 4 4 2 1
134. s C 3 Direct EGA Analysis C 4 Heart Cut EGA Analysis D E E 1 2 C 1 C 2 C 3 C 4 C ON OFF ON ON OFF ON 4 2 Ver 1 24 E 3 E 4 F F 1 G H J J 1 J 2 J 3 J 4 J 5 J 6 J 7 J 8 Manual E 3
135. tylphthalate 100C 20C min 600C Zone A 300C Auto NT UU i 40 320C 7 min 10C min iso BMA MS 300 NN mBMA He 1 mlmin 150 Ultra ALLOY 5 30m 0 25 0 25pm Styrene trimer Styrene dimer Fig 5 11 Ver 1 24 5 5 Py GC MS 0 1 mg EGA
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