24906-02 Instruction Manual PDF - Cole
Contents
1. 107 9 Storage and IransDOTtallOTis caida cuc eraot iiis doles isole uoi oia i boa ics neue 108 TORecycing arid DISDOSAL EE 108 niei EE 109 Declaration of conformity last page of the document SI Analytics Version 110901 US Chapter 1 Specifications Piston burette TITRONIC 500 59 1 Technical Specifications of the TITRONIC 500 Piston Burette 1 1 Summary The TITRONIC 500 is suitable for the following applications Manual titration with or without calculation of the result Dosage Preparation of solutions t can be used as a dosing burette with the TitroLine 7000 Titrator t can be used as a dosing or titrating burette in combination with the TitriSoft control software from version 3 0 A variety of dosing and filling speeds can be set for each method Up to 15 user methods can be memorised in the device Solutions to be used Virtually any liquids and solutions with a viscosity of lt 10 mm s such as concentrated sulphuric acid may be used However one has to avoid the use of chemicals that may attack glass PTFE or FEP or that are explosive such as hydrofluoric acid sodium azide or bromine Suspensions containing high solids percentages may clog or even damage the dosing system General provisions The safety guidelines that are applicable to the handling of chemicals have to be observed under all circumstances This applies in particular to inflammable an2. and calculation formula method contents Documentation in a PDF file stored on a connected USB stick will soon be available with a new update Please contact your dealer or SI Analytics directly Chapter 5 System Settings 95 5 System Settings Main menu 0 000 ml 0 000 ml Methode 01 ISTART Method parameter EDIT Select method system MODE Fig 71 20 ml HaOH 0 1 mol L 01 01 06 13 00 From the main menu Fig 71 lt SYS gt lt F7 gt or the lt MODE gt front keys followed by System settings you get to the system settings System settings Language settings Reagents WA RS232 Settings Printer HP PCL Date time F Selection Enter Back Fig 72 20 ml HaOH 0 1 mol L 01 01 06 13 00 Setting the national language was already described in Chapter 2 5 5 1 Interchangeable Reagents Unit Each interchangeable unit is equipped with an RFID transponder This transponder can be used to store the following information Unit size the default setting cannot be changed Unit ID default setting cannot be changed Reagent name default blank Concentration default 1 000000 Concentration determined on Date To be used until Date Opened Produced on Date Test according to ISO 8655 Date Charge description default no charge Last modification Date 96 Chapter 5 System Settings System settings Reagents vVA Unit size 20 m
3. Fig 57 20 ml HaOH 0 1 mol L 01 01 06 12 08 The following calculation formulae are available for manual titration Titration formula Additional information EP1 B T M F1 W F2 Formula for calculating the concentration of a sample taking into account a blank value in terms of ml B EP1 T M F1 W F2 Formula for calculating the concentration of a sample taking into account a blank value in terms of ml Reverse titration examples CSB saponification number B FS EP1 F1 T M W F2 Formula for calculating the concentration of a sample taking into account a blank value including a multiplicative factor Reverse titration W F2 EP1 B M F1 Formula for calculating a titer T of a titration solution EP1 Used to calculate the consumption in ml Legend of the abbreviations used Titration solution consumption in ml Blank value in ml in most cases determined by titration Titer of the titration solution e g 0 09986 Mol Mol or equivalent weight of the sample e g NaCl 58 44 Factor 1 Conversion factor 2 Factor 2 Conversion factor W Weight sample weight in grams or sample volume in ml gam Chapter 4 Method Parameters 89 After selecting a formula please confirm your selection with lt OK gt lt ENTER gt Formula parameter EQ 1 BYFT MP F L DAPKE 2 B Blank value Q 0000ml T Titre 1 00000000 M mol 1 00000 F1 Factor 1 1 0000 Selection Enter Bac
4. IS For a sample description of the manual a prompt for the sample description will always be displayed at the start of the method Cp also chapter 3 6 Main menu For an automatic sample description there will be selected a master description in the current case this is water cp Fig 68 which will then automatically be numbered Starting on 01 sample ID Methode 01 Position Continue Back Fig 68 20 ml HaOH 0 1 mol L 01 01 06 12 58 After a new power up numbering will resume with 01 94 Chapter 4 Method Parameters 4 5 5 Documentation Methodenparameter andern HEI Dosierparameter Vorlage Einwaage man Probenbezeichnung man Auswahl Enter Zur ck Fig 69 Zo HE no Two different format settings are available for documentation on a printer short and GLP Documentation Methode O1 short GLP Only Display Selection AN Enter Back Fig 70 20 ml HaOH 0 1 mol L 01 01 06 12 53 Note The standard with curve format is only applicable to automatic titrators Manual titration Method name date time sample oame as Short description sample weight sample documentation volume results and calculation plus method contents formula Dosing Method name date time N A Same as Short documentation method contents Prepare solutions Method name date time sample N A Same as Short designation weight sample results documentation
5. Method parameter Select method system MODE Fig 37 10 ml HaOH 0 1 mol L OF 08 11 16 52 82 Fig 38 Chapter 3 Working with the burette TITRONIC 500 Dose dosing NaOH 1 0 239 ml 2 000 ml 10 rl HacH 0 1 mol L 07 02 11 16 53 The dosed volume will be briefly displayed before the display returns to the main menu Fig 39 Fig 40 Dose dosing NaOH 1 2 000 ml 2 000 ml STOP 10 ml MaOH 0 1 mal L OF M0811 16 55 Main menu 2 000 ml 2 000 ml dosing NaOH 1 START Method parameter EDIT Select method system 10 ml NaOH 0 1 mol L 07 02 11 16 52 The next dosage operation can be started immediately Filling of the unit following dosage will not occur automatically unless the maximum cylinder volume has been reached or the automatic filling option was activated The unit can be filled at any time using lt FILL gt A dosing operation can also be performed without any dosing method with the lt DOS gt lt F10 gt key of the external keyboard Fig 41 Dosing volume 000 000mli Value AN Position Continue Back 10 rl NaOH 0 1 mol L 07 08 11 16 55 Chapter 3 Working with the burette TITRONIC 500 83 This is the point to input the volume which will be dosed following the confirmation with lt ENTER gt lt OK gt 0 816 ml 4 500 ml STOP Fig 42 10 ml NaOH 0 1 mol L OF 08 11 16 59 Further dosages can be performed usi
6. 500mA power supply for stirrer TM 235 TM 135 Polypropylene polyester coated 15 3 x 45 x 29 6 cm W x H x D height incl interchangeable unit ca 2 3 kg for basic unit ca 3 5 kg for complete device incl interchangeable unit with empty reagent bottle Ambient temperature 10 40 C for operation and storage Humidity according to EN 61 010 Part 1 Max relative humidity 80 96 for temperatures up to 31 linear decrease down to 50 relative humidity at a temperature of 40 C Chapter 1 Specifications Piston burette TITRONIC 500 61 Interchangeable units Compatibility Recognition Valve Cylinder Hoses Bracket for supply bottle Materials Dimensions Weight Dosing accuracy Accuracy Precision Status Aug 9 2011 units are compatible to the titrators TitroLine 6000 TitroLine 7000 and Piston Burette TITRONIC 500 automatically through RFID Recognition of unit size and characteristics of the Titration or dosing solution volume neutral cone valve made from fluorocarbon polymers PTFE TZ 3000 borosilicate glass 3 3 DURAN FEP hose set blue suitable for square glass bottle and misc reagent bottles borosilicate glass DURANP fluorocarbon polymers PTFE stainless steel polypropylene 15 x 34 x 22 8 cm W x H x D incl reagent bottle approx 1 2 kg for interchangeable unit WA incl empty reagent bottle after DIN EN ISO 8655 part 3 0 1 0 15 96 0 05 0 07 96 de
7. Methode O1 HP PCL A4 DPU 5445 print PDF serial output Selection Enter Back Fig 93 10 ml empty 01 01 06 12 21 Only one printer at a time can be connected because automatic printer recognition is not supported The use of other Hewlett Packard printer models is possible as long they comply with the PCL 3 5e standards and can be connected via USB cable The DPU S445 from Seiko Instruments is the only thermal printer being supported by this system Chapter 10 Recycling and Disposal 107 8 Maintenance and Care of the TITRONIC 500 Piston Burette The preservation of the proper functioning of the piston burette requires testing and maintenance work to be performed on a regular basis Regular inspections are essential prerequisites for the correctness of the volume and the proper functioning of the piston burette The accuracy of the volume is determined by all chemicals carrying components piston cylinder valve titration tip and hoses These parts are subject to wear and tear i e zthey are or wearing parts respectively The piston and cylinder are subject to particular strain hence they require special attention Heavy strain Use of e g concentrated solutions reagents and chemicals 0 5 mol L chemicals attacking glass such as fluorides phosphates alkali solutions solutions with a tendency to crystallising out Fe III chloride solutions oxidising and corroding
8. Selection Enter Back Fig 6 no exchange unit OS 04 11 16 23 alls BER Use ENTER OK to call the menu Select the national language using the 1 arrow keys confirm it with lt ENTER gt lt OK gt System settings Language settings Deutsch English Frangais Selection Enter Cox Back Fig 7 no exchange unit 05 04711 16 26 The selected language will appear immediately Pressing the lt ESC gt key twice will return the user to the main menu Chapter 2 Unpacking and first Operation 67 2 6 Interchangeable unit WA ON oo EE Fig 8 TZ 3871 suction hose TZ 3872 connection hose TZ 3873 dosing hose without dosing tip and holding bracket TZ 3874 dosing hose with dosing tip and holding bracket TZ 3801 valve cover lid TZ 3000 3 2 way valve TZ 2003 drying tube TZ 3802 threaded cap with borehole GL 45 incl adapter with 2 openings for drying tube and suction hose TZ 3803 1 litre reagent bottle brown TZ 3900 UV protection blue transparent 10 TZ 3875 shaft for titration tip and TZ 3656 titration tip unit blue 11 TZ 1507 plastic drip down tubule 2 6 1 Installing the interchangeable unit Fig 8 shows a completely assembled interchangeable unit Remove the valve with the attached hoses from the pack then push it on the valve support until it snaps in position Slip on the valve cover lid on the valve a
9. USB Hub 65 USB stick 65 Viscosity 60 Warning 62 SI Analytics EG KONFORMITATSERKLARUNG EC DECLARATION OF CONFORMITY CE D CLARATION DE CONFORMIT CEE DECLARATI N DE CONFORMIDAD Wir erkl ren in alleiniger We declare under our sole Nous d clarons sous notre Declaramos bajo nuestra Verantwortung dass das responsibility that the seule responsabilit que nica responsabilidad que los folgende Produkt following product les produit ci dessous produit listados a continuaci n Kolbenb rette Piston burett Burette Piston Bureta de mbolo TITRONIC 500 auf das sich diese to which this declaration auquel se r f re cette todo lo relative a esta Erkl rung bezieht relates are in conformity with d claration est conforme declaraci n est en bereinstimmt mit den the following EC directives directives CE soul vantes conformidad con las directivas folgenden EG Richtlinien CEE siguientes EMV EMC CEM CEM EG Richtlinie 2004 108 EG EC Directrive 2004 108 EG CE Directive 2004 108 EG CEE siguientes 2004 108 EG Sicherheit Safety S curit Seguridad EG Richllinie 2006 95 EC Directrive 2006 95 CE Directive 2006 95 CEE siguientes 2006 95 Angewandte harmonisierte Applied harmonized Normes harmonis es ou Estandares armonizados Normen oder normative standards or normative documents normative aplicados o documentos Dokumente documents appliqu es normativos EMV EMC CEM CEM EN 61326 1 200
10. g 14 and end of command lt CR gt lt LF gt Every command must be completed with the ASCII sign lt CR gt and lt LF gt Carriage Return and Line Feed Only if the respective action has ended the answers will be returned to the computer Example The command to dose 12 5 ml shall be sent to the burette TITRONIC 500 with the address 2 The command consists of the characters 02DA12 5 CR LF gt In detail 02 Device address DA Dosage command with filling and zero points of the display 12 5 Volume in ml to be dosed lt CRLF gt Control character as command end Command Description Reply aaAA automatic allocation of device address aaY aaMC1 XX choosing a method aaY aaBF filling burette Aufsatz wird gef llt aaY aaBV output of dosed volume in ml aa0 200 aaDA dose volume without filling with adding the volume aaY aaDB dose volume without filling reset of the volume aaY aaDO dose volume with filling without adding the volume aaY aaGDM dosing speed in ml min aaY aaGF filling time in seconds min is 20 default 30 aaY aaES ESC function one step backwards aaY aaEX EXIT function back to main menu aaY aaGDM dosing speed in ml min 0 01 100 ml min aaY aaGF filling time in sec adjustable 20 999 seconds aaY aaGS output serial no Of device aaGS08154711 aaLR output report short report aaY aaLl output method content aaLO output documentation as configured aaRH request of identification aaldent TL500 aaRC
11. in case of an erroneous operation The keys of the front keyboard produce a clicking sound if the key was used successfully System settings Sound volume System Keypad Setting Selection OK Back Fig 86 20 ml HaOH 0 1 mol JL DLLME 13 14 Note No sounds will occur when the external keyboard is used Chapter 5 System Settings 101 5 8 Software Update System settings Date time Reset Device informations System tone Software Update Selection Enter Back 20 ml HaOH 0 1 mol L 01 01 06 12 12 d Fig 87 An update of the device software requires a USB stick containing a new version For this operation the two files that are needed have to be located in the root directory of the USB stick Wechseldatentrager F Datei Bearbeiten Ansicht Favoriten Extras CH Se d E Suchen K Ordner T ba do Name Gr be Typ Ge Datab Dateiordner 12 3 DataB LiviLine 9400 090820071 Dateiordner 18 Andere Orte Y Exchange Method Prafile Dateiordner 18 amp TL6000 Update 16 1i def 1KB Export Definition File 19 Ed TLXXXX Application 16 11 bin 921KB BIN Datei 19 Details Plug the USB stick into a free USB A port wait for some seconds and then select the Software Update function The valid software updates will be shown on the display In the present case this is Version 16 11 from 19 April 2011 Software Update Software version RCSO 11 Wie Softwareup
12. more details please refer to chapter 5 1 press lt ESC gt to leave the reagents menu fig 13 oystem settings Reagents WA Unit size 10 ml Unit ID 179664904 Concentration 0 10000 Selection Enter OK Back Fig 1 3 10 ml OF 8 11 16 35 You will be prompted for a confirmation of the values fig 14 oystem settings accept values es Ho Selection Enter Back Fig 14 10 ral OF 08 11 16 36 RE PIS If you selected Yes the values will be written into the interchangeable unit You can see this from a message in red colour displayed at the bottom Upon completion the left bottom corner of the display will show the new name of the reagent fig 15 In the present case this is NaOH 0 1 mol L Chapter 2 Unpacking and first Operation 71 Main menu 0 000 ml Methode 01 START Method parameter Select method system Fig 15 10 ml NaOH 0 1 mol L OF 0811 15 35 2 8 Initial Filling or Rinsing of the Entire Interchangeable Unit Initial filling of the interchangeable unit is done using the lt rinsing gt rinsing programme On the main menu fig 16 Main menu 0 000 ml Methode 01 START EDIT Method parameter Select method system Fig 16 10 ml NaOH 0 1 maljL 07 18 11 16 36 press lt MODE gt key to navigate to the methods system fig 17 Select method system Methode 01 System settings Ba
13. send last command aa last command aaRS report status aaStatus text possible answers are STATUS READY for ready oTATUS dosing dosing oTATUS tfilling filling ERROR busy if no interchangeable unit has been attached aaSM start selected method aaY aaSEEPROM EEPROM reset to factory defaults aaY aaSR stop the actual function aaY aaSYS5 adjust language to German aaY aaSYS1 adjust language to English aaY aaSYS2 adjust language to French aaY aaSYS3 adjust language to Spanish aaY aaVE Version number of the software aaVersion Chapter 7 Connection of Analytical Balances and Printers 105 D Connection of Analytical Balances and Printers 7 1 Connection of Analytical Balances As it often happens that the sample is weighed in on an analytical balance it makes sense to connect this balance to the TITRONIC 500 To connect the balance to the TITRONIC 500 the balance must have a RS 232 C interface and the connection cable must be configured accordingly For the following types of balances there are already assembled connection cables 7 1 1 Balance TZ Number Sartorius all types partially Kern Denver TZ 3092 Mettler AT PR PM TZ 3093 Mettler AB S AG PG TZ 3099 Precisa XT Series TZ 3183 Kern with 9 pole RS232 TZ 3180 For all other types of balances it is possible to obtain an already assembled connection cable on demand For this we need detailed information about the RS 232 C interface of the balance u
14. solutions such as iodine potassium permanganate Cer Ill Karl Fischer titration agent HCl solutions with a viscosity of gt 5 mm s frequent or even daily use Normal strain Use of solutions reagents and chemicals up to 0 5 mol l which do not attack glass crystallise out or corrode Interrupted use If the dosing system is not in use for more than two weeks we recommend emptying and cleaning the glass cylinder and all hoses 6 This applies in particular under the operating conditions referred to in the Heavy strain section If this recommendation is not adhered to the piston of the valve may become leaking this may result in damage to the piston burette If the liquid is left within the system you will also have to reckon with corrosion and an alteration of the solutions used over time which includes e g crystallisation Considering that as of the state of the art there are no plastic hoses available for the use in titration equipment which would be perfectly free of diffusion phenomena particular attention is to be paid to the range of the hose lines We recommend the following inspection and maintenance work Heavy strain Normal strain Simple cleaning Whenever required in Whenever required in O Wiping off splashed chemicals from the outer surface 1 operation operation Sight check Weekly when putting Monthly when putting o Check for leakage in the area of the dosing system 2 back into operation bac
15. 6 EN 61326 1 2006 EN 61326 1 2006 EN 61326 1 2006 Sicherheit Safety Securit Seguridad EN 61010 1 2001 EN 61010 1 2001 EN 61010 1 2001 EN 61010 1 2001 Mainz den 01 06 2011 A Dat Koni No Titrat 011 SI Analytics GmbH Hattenbergstral3e 10 55122 Mainz Deutschland Germany Allemagne Notes Notes Notes Typ type type tipo TITRONIC 500 Bescheinigung des Herstellers Wir best tigen dass das oben genannte Ger t gem DIN EN ISO 9001 Absatz 8 2 4 Uberwachung und Messung des Produkts gepr ft wurde und dass die festgelegten Qualit tsanforderungen an das Produkt erf llt werden Supplier s Certificate We certify that the above equipment has been tested in accordance with DIN EN ISO 9001 Part 8 2 4 Monitoring and measurement of product and that the specified quality requirements for the product have been met Certificat du fournisseur Nous certifions que le produit a t v rifi selon DIN EN ISO 9001 partie 8 2 4 Surveillance et mesure du produit et que les exigences sp cifi es pour le produit sont respect es Certificado del fabricante Certificamos que el aparato arriba mencionado ha sido controlado de acuerdo con la norma DIN EN ISO 9001 secci n 8 2 4 Seguimiento y medici n del producto y que cumple con los requisitos de calidad fijados para el mismo SI Analytics GmbH Telefon 49 0 6131 66 5111 Postfach 24 43 Telefax 49 0 6131 66 5001 55014 Mainz www si analytics co
16. A 10 0 002 ml WA 20 and 0 005 ml WA 50 If one keeps the black key depressed on the first level titration will be continued at a low rate If you press the black key fully down 27 level titration will proceed at a higher rate The rate of the second level can be set in five stages using the lt t gt arrow keys These stages can also be changed during manual titration Chapter 3 Working with the burette TITRONIC 500 81 Titration is running 1 545 ml AV Fig 35 10 ml HaOH 0 1 mol L 07 08 11 16 50 Stage 5 corresponds to maximum titration soeed Speed is reduced by 50 each time Example WA 20 interchangeable unit Stage 5 40 00 ml min Stage 4 20 00 ml min Stage 3 10 00 ml min otage 2 5 ml min otage 1 2 5 ml min As soon as manual titration is completed press the lt STOP F2 gt key or approx for 1 sec the grey key of the mouse The titration result will be calculated and displayed and optionally printed on the connected printer Device is filling titration 02 Consumption 1 545 ml Result 0 31 96 Fig 36 10 ml NaOH 0 1 mol L OF 8 11 16 51 lt ESC gt will take you back to the start menu way to start the next titration immediately Filling of the interchangeable unit occurs automatically 3 6 2 Dosage To start a dosage method please use the lt START gt lt F1 gt key or the black key of the mouse mouse Main menu 0 000 ml 0 000 ml dosing NaOH 1 START
17. Confirm the sample designation Then the display asks you a To press the print button at the balance gt Parameters to weighted sample automatically b To enter the weighted sample gt then the parameters are still set to weighted sample manually Put an object onto the balance and press the print button After the standstill of the balance display there will be beep at the TITRONIC 500 and the transmitted balance data appear a After approx 5 sec in the display and the display changes automatically into the measuring display b The weighted sample must again be confirmed with Enter or lt F1 gt 106 Chapter 7 Connection of Analytical Balances and Printers 7 2 Connection of Printers The new TITRONIC 500 supports two different printer systems These are HP PCL 3 5e USB printers e g HP Officejet 6000 and the thermal printer systems of Seiko Instruments e g model DPU S445 To connect the printers to the burette please use the USB socket When printing please check whether the correct printer is connected It is not possible to print HP printer layouts on a Seiko thermal printer or vice versa The printer settings should always be checked and adjusted after changing the printer System settings Language settings Calibration settings Reagents WA RS232 Settings Printer HP PCL amp 4 Selection Enter Back Fig 92 10 ml empty 01 01 06 12 21 Measuring speed drift
18. Gebrauchsanleitung Kolbenburette TITRONIC 500 Operating Instructions Piston burette TITRONIC 500 Mode d emploi Burette piston TITRONIC 500 Manual de instrucciones Bureta de mbolo TITRONIC 500 S Analytics Gebrauchsanleitung sse eren a tnnt nnne nnns Seite D 56 Wichtige Hinweise Die Gebrauchsanleitung vor der ersten Inbetriebnahme der Kolbenb rette TITRONIC 500 bitte sorgf ltig lesen und beachten Aus Sicherheitsgr nden darf die Kolbenburette TITRONIC 500 ausschlieBlich nur f r die in dieser Gebrauchsanleitung beschriebenen Zwecke eingesetzt werden Bitte beachten Sie auch die Gebrauchsanleitungen f r die anzuschlieBenden Ger te Alle in dieser Gebrauchsanleitung enthaltenen Angaben sind zum Zeitpunkt der Drucklegung g ltige Daten Es k nnen jedoch von SI Analytics sowohl aus technischen und kaufm nnischen Gr nden als auch aus der Notwendigkeit heraus gesetzliche Bestimmungen der verschiedenen Lander zu ber cksichtigen Erg nzungen an der Kolbenb rette TITRONIC 500 vorgenommen werden ohne dass die beschriebenen Eigenschaften beeinflusst werden ObDeratig Insmuell fiS sco moist oia ord aid actae iO es mesa abd Page 57 110 Important notes Before initial operation of the Piston Burette TITRONIC 500 please read and observe the operating instructions carefully For safety reasons the Piston Burette TITRONIC 500 may only be used for the purposes described in these present
19. N RS1 for connection to the PC RS2 for connection of a weighing balance and other devices from von SI Analytics burettes sample changers Connecting a printer Printers with a USB interface are to be connected to one of the two USB A interfaces These printers have to feature HP PCL emulation 3 3GUI 3 enhanced 5 5e So called GDI printers cannot be used 2 4 4 Connecting a USB device manual controller keyboard memory device hub The following USB devices can be connected to the USB A interfaces 2 4 5 PC keyboard TZ 3880 manual controller in the following mouse Printer USB storage devices e g USB sticks USB hub USB barcode scanners Connection of analytical balances Analytical balances are to be connected to the RS232 2 using an appropriate cable 66 Chapter 2 Unpacking and first Operation 2 5 Setting the Language of the Country The ex factory default language setting is English When the piston burette is switched on the main menu will appear once the boot sequence is completed Main menu 0 000 ml Methode 01 START Method parameter Select method system Fig 5 10 ml 07 08 11 16 31 Using SYS F7 or lt MODEs followed by System settings you navigate to the system settings The very first menu is to be used for setting the language of the country System settings Language settings Calibration settings RS232 Settings Date time
20. SYS gt F7 key you can also navigate there through the method selection menu oystem settings Language settings Reagents WA RS232 Settings Date time Reset Y Selection Enter OK Back Fig 27 10 ml HacH 0 1 mol L OF 08 11 16 45 System settings Date time Reset Device informations System tone Software Update j Selection AM Enter Back Fig 28 10 ml MaOH 0 1 molt 07 08 11 15 45 Chapter 3 Working with the burette TITRONIC 500 79 3 6 Main Menu After power up the main menu is always the first menu to appear The method displayed will always be the last method that was used Fig 29 In the present case it was a titration method Main menu 0 000 ml titration 02 START Method parameter Select method system Fig 29 10 ml MaOH 0 1 mol L 07 08 11 16 46 3 6 1 Manual Titration Manual titration is always performed using the mouse Manual titration is impossible without the mouse Main menu 0 000 ml titration 02 ISTART Method parameter Select method system MODE Fig 30 10 ml MaOH 0 1 mol L 07 08 11 16 46 Using lt START gt lt F1 gt or pressing the Black key on the mouse will start the manual titration method Depending on the settings of the method the system will prompt you for the sample description Fig 31 and the sample weight Fig 32 You can use an external PC keyboard to enter a 20 digit alphanum
21. and thus penetrate into the zone underneath the piston and if non admitted liquids are being used the materials of the TITRONIC universal Piston Burette may be dissolved or corroded please refer also to chapter 8 Maintenance and Care of the Piston Burette TITRONIC 500 Chapter 2 Unpacking and first Operation 63 2 Unpacking and First Operation 2 1 Unpacking and First Operation of the Piston Burette The piston burette itself as well as all related accessory and peripheral parts have been carefully checked at the factory to ensure their correct function and size Please ensure that the small accessories are also removed in full from the packaging For the scope of delivery please refer to the enclosed parts list The TITRONIC 500 piston burette may be placed on any flat surface 2 2 Installing the Z 300 Rod Foot Plate Optional If the TM 235 magnetic stirrer is not in use it is recommended to use the Z 300 rod foot plate The Z 300 rod foot plate is made of solid metal fig 1 The bottom of the device contains a recess which Is precisely worked to accommodate the metal foot plate The metal foot plate itself features one thread on both sides top and bottom to hold the stand rod coming with the basic device This means that the metal foot plate can be used both to the left and to the right of the device depending on the specific needs The basic device is to be placed on the metal foot plate subsequently the stand rod is screwe
22. as used Fig 24 Main menu 0 000 ml Methode 01 START Method parameter Select method system Fig 24 10 ml NaOH 0 1 mol L 07 08 11 15 35 Pressing START will result in the immediate execution of the method shown lt EDIT gt F3 will take you to the method parameters Fig 25 Method parameter Methode 01 Mew method Copy method Selection Enter Back Fig 25 10 rl NaOH 0 1 mol L 07 08 11 16 42 RE At this point you can e modify the current method e create a new method e call and memorise standard methods e copy or delete an existing method Use the und 1 keys to select the submenus confirm your selection with lt OK gt lt ENTER gt ESC will take you back to the main menu 78 Chapter 3 Working with the burette TITRONIC 500 lt MODE gt F6 will take you to the method selection menu Fig 26 Select method system Method 0 Methode 01 man System settings Balance data Rinsing Selection Enter Back Fig 26 10 ml NaOH 0 1 mol L OF 08 11 15 44 Existing methods can be selected by pressing the und f keys and confirming the selection with lt OK gt lt ENTER gt Once the selection made you will return to the main menu with the newly selected method If no method is selected lt ESC gt will also take you back to the main menu To navigate directly to the system settings Fig 27 and Fig 28 you can use the lt
23. ctions of the hoses at the sealing lips of the piston inside the dosing cylinder or at the valve 3 If any liquid becomes visible below the first sealing lip it has to be checked at short timely intervals whether any liquid will build up under the second sealing lip too In this case both the piston and the glass cylinder have to be replaced immediately It is easily possible that in operation small liquid droplets build up under the first sealing lip but they may also disappear again This phenomenon alone is no reason for replacement 4 The valve has to be removed from its housing for inspection In this process the hoses remain connected to the valve Please check for moisture underneath the valve When reinserting the valve please make sure that the small cam at the rotating axis is fitted into the corresponding groove again 5 The titration tip must be free of sedimentation or crystals which might obstruct the dosing process or falsify the results 6 Hemove the cylinder take the valve out of the valve housing unscrew the hoses and then rinse all parts carefully with distilled water For the assembly of the cylinder hoses and other parts of the interchangeable unit please refer to the operating instructions 7 Dose one burette volume then refill Air bubbles will gather at the tip of the cylinder and in the titration hose where they can be detected easily If bubbles become visible please re tighten all connections finger t
24. d into the thread Now it is possible to install the Z 305 titration clamp included with the basic device on the stand rod fig 2 Fig 1 Fig 2 64 Chapter 2 Unpacking and first Operation 2 3 Installation and Connection of the TM 235 Magnetic Stirrer As arule the TM 235 magnetic stirrer is arranged to the right of the piston burette The magnetic stirrer is connected to the 12V out socket in the rear panel of the piston burette using the TZ 1577 connection cable scope of delivery of the basic device cp Back panel illustration chapter 2 4 The stand rod scope of delivery of the basic device is screwed into the thread subsequently the Z 305 titration clamp scope of delivery of the basic device is installed fig 3 Fig 3 Chapter 2 Unpacking and first Operation 65 2 4 Connecting the Piston Burette Combination with Accessories and Additional Devices 2 4 1 Fig 4 2 4 2 Back panel of the TITRONIC 500 piston burette Connection ports of the TITRONIC 500 piston burette The TITRONIC 500 is equipped with the following connections 1 2 3 4 5 6 2 4 3 USB B interface for connection to a PC On Off switch Two USB A Master interfaces for connecting USB devices such as a keyboard printer manual control unit USB memory stick etc in Connection of the external power pack out Connection of the TM 235 magnetic stirrer Two RS232 interfaces 4 channel Mini DI
25. d or etching liquids Guarantee We provide guarantee for the device described for two years from the date of purchase This guarantee covers manufacturing faults being discovered within the mentioned period of two years Claim under guarantee covers only the restoration of functionality not any further claim for damages or financial loss Improper handling use or illegitimate opening of the device results in loss of the guarantee rights The guarantee does not cover wear parts as lobes cylinders valves and pipes including the thread connections and the titration tips The breach of glass parts is also excluded To ascertain the guarantee liability please return the instrument and proof of purchase together with the date of purchase freight paid or prepaid 60 Chapter 1 Specifications Piston burette TITRONIC 500 1 2 Specifications Piston burette TITRONIC 500 CE sign CE Country of origin Status Aug 9 2011 EMC compatibility according to the Council Directive 2004 108 EG applied harmonized standards EN 61326 1 2006 Low voltage directive according to the Council Directive 2006 95 EG Testing basis EN 61 010 Part 1 Germany Made in Germany The following dissolvents titration reagents are allowed to be used All common titration solutions As reagent water and all non aggressive non organic and organic fluids are allowed If using combustible fluids fire please adhere to the Guidelines for Explosio
26. date 110701 26 11 4 Softwareupdate 110706 27 11 Softwareupdate 110725 279 11 Selection Enter Back Esc 20 ml NaOH 0 1 mol L 01 01 06 12 03 Fig 88 102 Chapter 5 System Settings After starting the update using lt OK ENTER gt next thing to appear is the following graphic nic Sooo OOOO Waiting for system readiness Fig 89 Wers 1 5 0 1 20 which will change after a few seconds to the following display nic 5000 0000 System is updating Please wait Fig 90 Vers 1 5 0 1 20 Upon completion of the update approx 1 2 minutes the device will shut down the software completely and proceed to a new start Please note During the update the device must not be switched off Important In the course of an update the methods will not be deleted You can continue to use them If no valid update file is stored on the USB stick the following message will appear Software Update Software version RC30 11 Wie No Update S Selection Enter Back Fig 91 20 ml HaOH 0 1 mol L D1 01 6 12 04 Chapter 6 Data Communication via RS 232 and USB B interface 103 6 Data Communication via RS 232 and USB B interface 6 1 General Information The burette TITRONIC 500 has two serial RS 232 C interfaces to communicate data with other devices By means of these two interfaces it is possible to operate several devices on one computer PC interface In addi
27. de la primera puesta en marcha de la Bureta de mbolo TITRONIC 500 Por razones de seguridad laBureta de mbolo TITRONIC 500 s lo debe ser empleada para los objetivos descritos en este manual de instrucciones Por favor respeten las indicaciones descritas en los manuales de instrucciones de los equipos antes de conectarlos Todos los datos contenidos en este manual de instrucciones son datos orientativos que est n en vigor en el momento de la impresi n Por motivos t cnicos y o comerciales as como por la necesidad de respetar normas legales existentes en los diferentes pa ses SI Analytics puede efectuar modificaciones concernientes a la Bureta de mbolo TITRONIC 500 sin cambiar las caracter sticas descritas SI Analytics TABLE OF CONTENT PAGE 1 Technical Specifications of the TITRONIC 500 Piston Burette 59 1 1 UTA me n 59 1 2 Specifications Piston burette TITRONIC pop 60 1 3 Warning and Satety An elt LEE 62 2 Unpacking and First Operation ccccssseecesseecesseecenseeeenseecensesenseseeseesenneesooaes 63 2 1 Unpacking and First Operation of the Piston Dureite 63 2 2 Installing the Z 300 Rod Foot Plate Optional cc ccceeccceeeeseeeeeeeeseeeeeeeeeeeeseeeeeseeeseeeeeenas 63 2 3 Installation and Connection of the TM 235 Magnetic G mrer 64 2 4 Connecting the Piston Burette Combination with Accessories a
28. dress 1 is the default setting Fig 78 Fig 79 System settings Device address Value Continue Back 20 ml HaOH 0 1 mol L System settings RS232 Settings Baud rate Parity Data bit stop bits Selection Enter Back 20 ml HaOH 0 1 mol L The baud rate is preset to 4800 It may be set to 1200 19200 01 01 06 13 05 01 01 06 13 07 98 Fig 80 The parity setting can be selected amongst lt No gt lt Even gt and lt Odd gt lt No gt is the standard setting Fig 81 Chapter 5 System Settings Systemeinstellungen Baudrate 1200 2400 9600 10 ml MaOH 1moljl System settings Parity Even Odd Selection Enter Back 20 ml HaOH 0 1 mol JL 4800 Standard Auswahl Enter Zur ck No Default 05 05 11 15 23 S lt 01 01 06 13 09 You may select between 7 and 8 data bits 8 bits is the standard setting Fig 82 Selecting lt Reset RS Parameters gt will reset the RS232 parameters to the factory settings System settings Data bit Data bit Selection Enter Back 20 ml HaOH 0 1 mol L 8 Data bit Default 01 01 06 13 11 5 3 Date and Time The factory time setting is Central European Time This setting may be changed where necessary Fig 83 5 4 Password The password function is currently not yet activated Please ask your dealer for an update 5 5 RESET Chapt
29. e step and Filling continuous titration please refer to Stop of titration including evaluation chapter 3 6 1 manual titration Start dosage Start dosage 3 4 External PC Keyboard Function E S C gt gt wi il ta ke th e u se r to th ep rev i o u s leve o n the e m menu Start of a selected method Stop of the current method d Change of the current method new method copy method Fill the interchangeable unit BIN Display and modification of the balance data Selection c of method rinsing system settings MEN System settings language selection time date Change of sign MEN Call dosing menu E Without function Selection of the method selection menu from the main menu Elders lt ESC gt will take you back to the previous level in _the menu lt T gt lt gt lt gt lt gt gt Selection of individual menus and numeric values 0 9 Input of numeric values _ e lt ENTER gt Confirmation of input parameters lt Backspace gt Deletion of one input digit an input character to the left of _ the blinking cursor Go D M eer ee _ possible Chapter 3 Working with the burette TITRONIC 500 77 3 5 Menu Structure There are 4 selection menus e Start or main menu e Method parameters e Method selection e System settings After power up the main menu is always the first menu to appear The method displayed will always be the last method that w
30. er 5 System Settings System settings Date and time Date 01 01 06 Time Selection Enter Back 20 ml HaOH 0 1 mol L HESET will reset all settings to the factory setting 13 11 40 BEL 01 01 06 13 11 99 Please note All methods will also be deleted So please print the methods or export copy them to a connected USB storage medium this will be possible with a higher update The RESET has to be confirmed separately once again Fig 84 System settings Reset to factory settings Yes Selection Enter Back 20 ml HaOH 0 1 mol L 01 01 06 13 12 100 Chapter 5 System Settings 5 6 Device Information lt Device Information gt contains information about e the current software version e the serial number of the device e printer driver and update version e device address set e number of measurements Starts of a method e anumber of strokes filing cycles Device informations system settings Software version 30 11 Wie Serial number Printer driver version 1 2 5 0 Update version 1530 1 Device address EN Number of readings 125 Number of strokes Back Fig 85 20 ml NaOH 0 1 mol L 01 01 06 13 13 Please hold this device information ready for service purposes 5 7 System Sounds This is the point to set the volume of the system sounds and the front keyboard of the device The system sounds become audible e g at the end of the titration or
31. eric sample description sample ID titration Oz sample123456abcd123 96 Position Continue Back Fig 31 10 mol MaOH 0 1 mol L 07 08 11 15 43 80 Chapter 3 Working with the burette TITRONIC 500 Edit weight 003 23810g Value Position Continue Back Fig 32 10 ml NaOH 0 1 mol L OF 08 11 15 43 The balance data can be input using the front keyboard or the external keyboard Please confirm your selection using lt OK gt lt ENTER gt In the case of automatic takeover of the weighing balance data the sample weights will be read out of the balance data memory If the memory does not contain any balance data a message informing you of the absence of balance data will be displayed Fig 33 Titration is running titration 02 Lo balance data available Wait for automatic sample weight Fig 33 10 rnl NaOH 0 1 mol L 0708 11 16 51 Even at this moment pressing the Print key on the balance will still cause the transfer of the balance data After the input of the sample description and or the sample weight sample volume the following display will appear Titration is running 0 000 ml AV Fig 34 10 mol MaOH 0 1 mol L 07 8 11 16 50 You can control the metering rate with the black key of the mouse A single depression of the key will cause a step up to the first level Depending on the size of the interchangeable unit this corresponds to 0 0005 ml WA 05 0 001 ml W
32. ervention in the Piston Burette TITRONIC 500 as well as in the case of negligently or deliberately caused damage the warranty will become void Prior to switching the device on it has to be ensured that the operating voltage of the Piston Burette TITRONIC 500 matches the mains voltage The operating voltage is indicated on the specification plate Nonobservance of this provision may result in damage to the Piston Burette TITRONIC 500 or in personal injury or damage to property If it has to be assumed that safe operation is impossible the Piston Burette TITRONIC 500 has to be put out of operation and secured against inadvertent putting to operation In this case please switch the Piston Burette TITRONIC 500 off pull plug of the mains cable out of the mains socket and remove the Piston Burette TITRONIC 500 from the place of work Examples for the assumption that a safe operation is no longer possible 2 the package is damaged 2 the Piston Burette TITRONIC 500 shows visible damages 2 the Piston Burette TITRONIC 500 does not function properly 2 liquid has penetrated into the casing The Piston Burette TITRONIC 500 must not be stored or operated in humid rooms For reasons of safety the Piston Burette TITRONIC 500 must only be used for the range of application described in the present operating instructions In the case of deviations from the intended proper use of the device it is up to the user to evaluate the occurring
33. ight and then repeat dosing If air bubbles still remain within the system 6 please check the valve and replace the hose connections The air bubbles may also occur at the interface between the sealing lip of the piston and the cylinder If a reduction of the filling speed will not do the dosing unit has to be replaced 8 Check the electrical plug contacts for corrosion and mechanical damage Defective parts have to be repaired or replaced by new parts 9 Please refer to the application Burette inspection according to ISO 8655 Part 6 9 Storage and transportation If the TITRONIC 500 Piston Burette or the interchangeable units have to be stored over some time or to be dislocated the use of the original packing will be the best protection of the devices However in many cases this packing will not be available any more so that one will have to compose an equivalent packaging system Sealing the lower section in a foil is hereby recommended The devices should be stored in a room with a temperature between 10 and 40 C and the relative humidity of the air should not exceed 70 96 If the interchangeable have to be stored over some time or to be dislocated the fluids inside the system especially aggressive solution have to be removed please refer also to chapter 8 Maintenance and Care of the TITRONIC 500 Piston Burette 10 Recycling and Disposal The present piston burette and it s packaging are manufactured as far a
34. ing the software The address always consists of two characters e g address 1 of the two ASCII characters 0 and 1 The addresses can be set from 00 to 15 i e 16 possibilities It must be ensured that the devices in a chain have different addresses If a device is addressed with its address this device will process this command without sending it to another device The reply to the computer has also an own address The addresses are allocated as described in LL Chapter 5 2 The burette TITRONIC 500 receives commands from a PC at the interface 1 USB B if the computer knows the address It also sends the answer via this interface If the address of the incoming command does not match the device address the complete command will be forwarded to interface 2 Interface 2 is connected to interface 1 of another device This device checks the address as well and reacts to the command as the first TITRONIC 500 did before All information data strings which arrive at interface 2 of the burette TITRONIC 500 will immediately be send to the computer via interface 1 or USB B interface Thus the computer receives the data of all devices In practice itis possible to connect up to 16 devices to one computer PC interface 104 Chapter 6 Data Communication via RS 232 and USB B interface 6 3 Instruction Set for RS Communication The commands consist of three parts Address two digit aa e g 01 Command e g DA Variable if necessary e
35. is input in g This weight will then automatically be used for each start of the method without any sample weight being enquired by a prompt e Manual sample volume The sample volume in ml is prompted at the start of the method and manually input e Fixed sample volume A fixed sample volume is input in ml this volume will then automatically be used for each test of the method without any sample volume enquired by a prompt Note Manual and firm sample volumes are orally available of for manual titration 4 5 2 4 Formula unit The formula unit can be selected in the Unit submenu Unit Methode 01 none mil go ppm Selection Enter Back Fig 63 20 ml HaOH 0 1 mol L 01 01 06 12 52 Once the selection made e g the unit will also be displayed as piece of information on the display Result Methode Q1 Result text Formula Unit Decimal places Selection Enter Back Fig 64 20 ml HaOH 0 1 mol L D1 01 6 12 54 4 5 2 5 Decimal digits To conclude it is possible to determine the number of decimal digits from 2 6 The standard setting is 2 92 Chapter 4 Method Parameters 4 5 3 Dosing parameters Edit method parameter Methode 01 Method name Method type man Result Dosing parameter Selection AN Enter Back Fig 65 20 ml NaOH 0 1 mol L D1 01 06 12 54 The dosing parameters dosing speed filling speed and max dosing titration volume are determined for each method This applies
36. k Fig 58 20 ml HaOH 0 1 mol L 01 01 06 12 08 The values of the individual parameters of the selected calculation formula can now be input one by one Formula parameter M mol 00058 44 700 AV Value Position Continue Back Fig 59 20 ml HaOH 0 1 mol L 01 01 06 12 03 4 5 2 2 Formulae for the Preparation of Solutions A selection of special calculation formulae is available for the Prepare Solutions mode The appropriate calculation formula is selected on the Formula Selection submenu Formula selection Methode O1 no formula W 100 Fa Fb Fc Fd W 10 W 100 Fa Fb Fd Fg W 1 W 100 Fa Fb Fc 100 Fd e Selection Enter Back Fig 60 20 ml HaOH 0 1 mol L 01 0106 12 08 A selection of 3 different calculation formulae is available W 100 Fa Fb Fc Fd W 100 Fb 100 Fe Ff W 100 Fa Fb Fd Fg W 100 Fb 100 Fg Ff W 100 Fa Fb Fc 100 Fd 90 Chapter 4 Method Parameters Meaning of the individual factors W Weight of the sample in g Fa Soluble foreign matters portion in Fb insoluble foreign matter portion in FC Conversion factor for it unit g l 10 mg l und ppm 10000 g 100 ml KC Fd Target concentration of the solution to be prepared in g l mg l ppm g 100 ml or 96 Fe Specific weight of the weighted in sample in g cm Ff Volume correction in ml this volume correction is the required surplus dosage for compensating
37. k into operation O Is the piston tight 3 L Is the valve tight 4 L1 Titration to clear 5 Basic cleaning of the dosing system Every three months Whenever necessary L1 All parts of the dosing system to be cleaned separately 6 Technical inspection Semi annually when Semi annually when L Check for air bubbles in the dosing system 7 putting back into putting back into L Visual inspection operation operation L Check of the electrical connections 8 Verification of the volume according to ISO 8655 Semi annually Annually L Perform basic cleaning d Inspection according to ISO 8655 Part 6 or Part 7 9 Please note Depending on the respective application there may be different specifications for the entirety of the inspection and maintenance work to be performed The individual intervals may be extended if no complaints occur but they will have to be shortened again as soon as any problem has arisen 108 Chapter 10 Recycling and Disposal The inspection of the metrological reliability including maintenance work is offered as a service by SI Analytics GmbH including a manufacturer s certificate if so ordered For this purpose the titration device is to be sent in to SI Analytics GmbH Detailed description of the inspection and maintenance work 1 Wipe off using a soft cloth and some water with a normal household detergent 2 Leaking connections can be identified by moisture or crystals at the threaded conne
38. l Unit ID 1048576 Reagent NaOH 0 1 Concentration 1 00000 Selection AM Enter Back Fig 73 20 ml HaOH 0 1 mol L 01 01 06 13 01 oystem settings Reagents vA Concentration 1 00000 A Conc determine 04 19 11 Expire date 08 24 11 Opened compou 05 71 11 Y Selection ANY Enter OK Back ESC Fig 74 20 ml NaOH 0 1 molt 01 01 06 12 03 System settings Reagents vVA Opened compou 05 21 11 Inspection accor e Batch ID no Charge Last modification 01 01 06 Selection Enter Back Fig 75 20 ml HaOH 0 1 mol L D1 01 6 13 04 dale If you leave the Reagents WA gt menu using lt ESC gt you will always be prompted to know whether you wish to adopt the values System settings accept values No Selection Enter Back Fig 76 20 ml HaOH 0 1 mol L D1 01 6 13 04 If Yes is selected the updated values will be written into the RFID transponder of the interchangeable unit 5 2 RS232 Settings Chapter 5 System Settings 97 The lt RS232 settings gt item can be used to determine the device address of the TITRONIC 500 and set the parameters of the two RS232 interfaces separately Fig 77 System settings HS232 setings Device address RS232 1 Printer PC RS232 2 Balance Reset RS settings Selection Enter Back 20 ml HaOH 0 1 mol L 01 01 06 13 04 The device address can be set from 0 15 Ad
39. lance data Rinsing Selection Enter OK Back Fig 17 10 rl HacH 0 1 mol L 07 02 11 16 38 Pressing 1 once will take you to the Rinsing selection immediately fig 18 72 Chapter 2 Unpacking and first Operation Select method system Methode 01 System settings Balance data Selection Enter Back Fig 18 10 rl NaOH 0 1 mol L 07 08 11 16 39 BER Confirm the selection by pressing ENTER Rinsing Rinse 2 x Continueous test Selection Enter Back Fig 19 10 rl HacH 0 1 mol L 07 02 11 16 39 At this point you can select the number of rinsing cycles Fig 19 Initial filling requires a minimum of two rinsing cycles You can stop the rinsing operation Fig 20 at any time by pressing STOP and then resume rinsing with START Rinsing Rinse 1x 1 548 ml 10 000 ml an LESE Fig 20 10 rl HacH 0 1 mol L 07 08 11 16 40 While the initial filling or rinsing programme is being run please place a sufficiently dimensioned waste vessel under the titration tip Chapter 2 Unpacking and first Operation 73 2 9 Replacing the Glass Cylinder and the PTFE Piston Replacing the glass cylinder and the piston does not require any additional tools In certain cases the piston extractor has to be used Remove the interchangeable unit from the base unit Unscrew the hose between the glass cylinder and the valve from the glass cylinder Rotate the bl
40. lies in particular to glass breakage since broken glass may damage the sealing rings of the PTFE piston Please note As a rule the hoses and cylinders will contain chemicals which may spill or be splashed around in the course of disassembly The relevant safety precaution measures applicable to the handling of the chemicals concerned have to be observed Chapter 3 Working with the burette TITRONIC 500 75 3 Working with the TITRONIC 500 3 1 Front Keyboard Apart from alphanumeric input a z A Z 0 9 and a few other functions almost all functions can be performed using the front keyboard Mode Methods selection rinsing system settings lt EDIT gt Changing the current method new method copy and delete method lt ESC gt lt ESC gt will take you back to the previous menu level lt START gt Start and Stop of a current method lt FILL gt Filling the unit The individual functions are described in detail in Chapter 3 4 External PC Keyboard 3 2 Display The display consists of a graphical LCD display with a resolution of 320 x 240 pixels lilration is running 0 022 ml Speed 6 Shop MODE TITRONIC 500 76 Chapter 3 Working with the burette TITRONIC 500 3 3 Manual controller mouse The mouse Fig 23 is needed for manual titration It can also be used for starting dosage or other methods Fig 23 Black key Manual titration otart of titration singl
41. m HattenbergstraBe 10 E Mail support si analytics com 55122 Mainz Deutschland Germany Allemagne Alemania SI Analytics Version 110901 US EDV Printed in Germany
42. n Protection and Prevention of the chemical industry For fluids with higher viscosity 2 5 mm s lower boiling point or affinity to outgas the filling and dosage speed can be adjusted Fluids with viscosity over 20mm s cannot be dosed Display Power supply RS 232 C Interface Data bits otop bit Start bit Parity Baud rate Address RS 232 1 RS 232 2 USB Interface USB Typ B slave USB Typ A master Stirrer connection Housing material Front keyboard Housing dimensions Weight Ambient conditions 3 5 inches 1 4 VGA TFT display with 320x240 pixels power supply 90 240 V 50 60 Hz power input 30 VA HS 232 C interface separated galvanically through photocoupler Daisy Chain function available adjustable 7 or 8 Bit default 8 Bit adjustable 1 or 2 Bit default 1 Bit static 1 Bit adjustable even odd none adjustable 1200 2400 4800 9600 19200 Default 4800 baud adjustable 0 to 15 default 01 for computer input Daisy Chain devices of SI Analytics titrator TitroLine 7000 Burettes TITRONIC 500 TITRONIC 110 plus TITRONIC universal Balances of the types Mettler Sartorius Kern Ohaus for more please contact SI Analytics Exit Daisy Chain 2 x USB type A and 1 x USB type B for connecting a PC for connecting USB keyboard USB printer USB mouse mouse USB data media e g USB stick USB Hub 12V DC out
43. n on the left and then pull the interchangeable unit forward as is shown in fig 9 c 9 a A Please note Removing the interchangeable unit is only possible as long as the piston is in the lower position zero position Possibly it may be necessary to press the lt FILL gt key first 2 7 3 Programming the titration unit The data from the RFID transponder of the interchangeable unit will be read immediately fig 10 Device is filling 0 000 ml START Method parameter Select method system Fig 10 Reading exchange unit oF 8 11 16 34 Following the reading operation the input menu for the input of the reagents will be shown for approx 10 seconds fig 11 The size of the interchangeable unit is displayed on the left side of the display here 10 ml oystem settings Reagents VV A Unit size 10 ml Unit ID 1296649042 Concentration 0 10000 Selection Enter Back Fig 11 10 ral 07 8 11 16 34 70 Chapter 2 Unpacking and first Operation When used for the first time it is recommended to enter here at least the name of the reagent being used To do so confirm the Reagent selection with ENTER then type the name and possibly the concentration fig 12 System settings Reagent NaOH 0 1 mol L _ Position lt gt Continue Back Fig 12 10 ml 07 08 11 16 35 Press OK ENTER to confirm fig 12 Following the optional input of additional parameters for
44. nd Additional Devices 65 2 4 1 Back panel of the TITRONIC 500 piston Si 65 2 4 2 Connection ports of the TITRONIC 500 piston burette 2 0 0 ceceeceeeeeceeeeeeeeeeeeeeeeeesaaaneeeees 65 2 4 3 Connecting Heal PINE eT m Med 65 2 4 4 Connecting a USB device manual controller keyboard memory device hub 65 2 4 5 Connection of analytical balarices eer aerea eee Mec a ec eee 65 2 5 Setting the Language of the COUN EE 66 2 6 Interehanige able init EE 67 2 6 1 Installing the interchangeable D EEN 67 2 7 Positioning and Replacing an Interchangeable Un 68 2 7 1 Placing andnterehangeable tibilts etu ieecce rio scrape deseco ia ec Eo vae EB veas bees Miele ele 68 2 7 2 Removing an interchangeable unt 69 2 7 3 Programming tbe Miraton E ln EE 69 2 8 Initial Filling or Rinsing of the Entire Interchangeable Unit essssseesssssse 71 2 9 Replacing the Glass Cylinder and the PTFE Piston cccccceceeceeeeeeeeeeeeeeeeeeeeeeeeaeeeeeeeeeas 73 3 Working with the TITRONIC 500 eere nnne tnn tns tn annt 75 3 1 mo ee E 75 3 2 RI e 75 3 3 Manual CONMONEGE MOUSE E 76 3 4 External FO Key DO ai BEE 76 3 5 KEE Ruder 77 3 6 Man VIG EE 79 3 6 1 Manual TI Ol EEN 79 3 6 2 Bono wire seater cvs EE 81 3 6 3 Preparing Solutions ccccccccsseeccceceeeeceecceaeeceeesseseceeseeeeaeeeeesseaeeeeessaaeeeesessegseeeessaanseeeeeenas 83 A Meihod Parameters cie
45. ng lt ENTER gt lt OK gt Filling of the unit following dosage will not occur automatically here unless the maximum cylinder volume has been reached The unit can be filled at any time using lt FILL gt lt ESC gt will take you back to the main menu 3 6 3 Preparing Solutions The so called Preparing solutions method is a special dosing method In this process a solvent e g sulphuric acid is dosed to a sample weight of a substance until the desired target concentration is reached Main menu Polyamid Method parameter Select method system Fig 43 10 ml NaOH 0 1 mol L 07 08 11 17 02 Device is dosing 1 973 ml 2 940 ml STOP Fig 44 10 ml MaOH 0 1 mol L 07 02 11 17 04 84 Chapter 3 Working with the burette TITRONIC 500 Result Polyamid Weight 0 020 g W 100 Fa Fb Fc Fd Formula result 2 94020 ml Dosed volume 2 940 ml Fig 45 10 rl NaOH 0 1 mol L oF 08 11 17 05 If the calculated volume is greater than the maximum volume an error message will be displayed and dosage will be suppressed for safety reasons Device is dosing Polyamid Calculated volume is too large Weight 0 1000g Formula WS 100 Fa Fb Fc Fd W 100 Fby 100 Fe Ff calculated volume 10 701 ml maximum dosing volume 10 000 ml Back ESC Fig 46 10 ml HaOH 0 1 mol L OF A811 17 05 4 From the main menu shown in Fig 43 Fig 24 lt EDIT gt lt F3 gt will take you to the method pa
46. ode 01 Method type man Result Dosing parameter Selection Enter Back 20 ml NaOH 0 1 mol L 0101 06 12 05 87 On the lt Method type gt you can select whether you wish to perform a manual titration or a dosage or whether you wish to prepare a solution Fig 54 Fig 54 Method type Methode Oo manuel titration Solution preparation Selection Enter Back 20 ml NaOH 0 1 mol L 01 01 06 12 05 The selection of the Method type will have an influence of the further parameterisation of the method For instance if you select the dosing mode no selection of a formula will be available 4 5 2 Result The Result menu offers the following possible settings Fig 55 The Result text may contain up to 21 alphanumeric characters including special characters Result Methode Q1 Result text Formula Unit Decimal places Selection Enter Back 20 ml NaOH 0 1 mol L 01 01 06 12 06 88 Chapter 4 Method Parameters Result text Methode Q1 Meth 1234567896 abc AB Position Continue Back Fig 56 20 ml HaOH 0 1 mol L 01 01 06 12 07 Please confirm your input with lt OK lt lt ENTER gt 4 5 2 1 Formulae for manual titration On the Formula Selection submenu you can select the appropriate calculation formula Formula selection Methode O1 EQ1 B T M F1 W F2 B EQ19 T M F1 W F2 B F3 EQ1 F1 T M W F2 YW Selection Enter Back
47. on made you are directly prompted for the input of the method name Fig 50 Method name Method O4 HEI Position Continue Back Fig 50 10 ml NaOH 0 1 mol L 07 08 11 17 08 The standard name may be adopted or modified Subsequently you will be taken to the Change method parameters item Please continue at this point with Chapter 4 5 4 3 Copy Methods Methods can be copied or stored with a new name If you select this function the current method will be copied and you can include a new name Fig 51 Mew method Method name LOD Position Continue Back Fig 51 10 ml NaOH 0 1 mol L 07 08 11 17 08 A new name with the suffix 1 will be assigned automatically so as to avoid the existence of 2 methods having the same name Subsequently you will be taken to Change method parameters Please continue at this point with Chapter 4 5 4 4 Delete Methods If this function is selected you will be prompted to know whether the current method is actually to be deleted You have to reply Yes in explicit terms and also confirm this reply with lt OK gt lt ENTER gt Delete method HCI 1 Yes Selection Enter Back Fig 52 10 ml Ha OH 0 1 mol L 07 08 11 17 10 Chapter 4 Method Parameters 4 5 Change Method Parameters The input or modification of the method name was already described in Chapters 4 1 and 4 3 Fig 53 4 5 1 Edit method parameter Meth
48. operating instructions Please also observe the operating instructions for the units to be connected All specifications in this instruction manual are guidance values which are valid at the time of printing However for technical or commercial reasons or in the necessity to comply with the Statuary Stipulations of various countries SI Analytics may perform additions to the Piston Burette TITRONIC 500 without changing the described properties Ville ak e e EE Page 111 164 Instructions importantes Pri re de lire et d observer attentivement le mode d emploi avant la premi re mise en marche de la Burette piston TITRONIC 500 Pour des raisons de s curit la Burette piston TITRONIC 500 pourra tre utilis e exclusivement pour les usages d crits dans ce pr sent mode d emploi Nous vous prions de respecter galement les modes d emploi pour les appareils connecter Toutes les indications comprises dans ce mode d emploi sont donn es titre indicatif au moment de l impression Pour des raisons techniques et ou commerciales ainsi qu en raison des dispositions l gales existantes dans les diff rents pays SI Analytics se r serve le droit d effectuer des suppl ments concernant la Burette piston TITRONIC 500 qui n influencent pas les caract ristiques d crits Manu l dednslrHcclOFleS eege Eege P gina 165 218 Instrucciones importantes Primeramente lean y observen atentamente el manual de instrucciones antes
49. pending on the used interchangeable unit Dosing accuracy of the Piston Burette TITRONIC 500 with WA interchangeable units Interchangeable unit 20 00 0 005 t 0 15 0 05 Volume 5 00 0 005 0 15 Tolerances of the Dosage error Reproducibility of the glass cylinder according to 96 mm 100 96 volume 76 0 07 10 00 0 005 t 0 15 0 05 90 00 0 005 0 15 0 05 62 Chapter 1 Specifications Piston burette TITRONIC 500 1 3 Warning and safety information The Piston Burette TITRONIC 500 corresponds to protection class l It was manufactured and tested according to DIN EN 61 010 Part 1 Protective Measures for Electronic Measurement Devices and has left the factory in an impeccable condition as concerns safety technology In order to maintain this condition and to ensure safe operation the user should observe the notes and warning information contained in the present operating instructions Development and production is done within a system which meets the requirements laid down in the DIN EN ISO 9001 standard For reasons of safety the Piston Burette TITRONIC 500 must be opened by authorised persons only this means for instance that work on electrical equipment must only be performed by qualified specialists A In the case of nonobservance of these provisions the Piston Burette TITRONIC 500 may constitute a danger electrical accidents of persons or fire hazard Moreover in the case of unauthorised int
50. rameters Fig 47 Chapter 4 Method Parameters Method Parameters Method parameter Polyamid New method 10 ml MaOH 0 1 mol L 4 1 Method editing and new method Copy method Y Selection ANN Enter OK Back Esc 07 02 11 17 06 85 If you select edit method or new method you will be taken to the modification or new creation of a method selecting new method will always lead to the prompt for the input of a method name Fig 48 This prompt will not appear in the case of the modification of an already created method Fig 48 New method Method name Method 04 Position Continue Back 10 ml NaOH 0 1 mol L 07 02 11 17 07 The method name can contain up to 21 characters Special characters are also possible If no keyboard is connected the method name being displayed has to be adopted in the present case Method 04 Numbering of methods will occur automatically Press OK ENTER to confirm the input The method name can be changed at any time Please continue at this point with Chapter 4 5 4 2 Standard Methods The Standard methods item of the TITRONIC 500 contains a series of ready made standard methods which can be conveniently selected Fig 49 Fig 49 HCI NaOH Auswahl Enter Zuruck 50 ml MaOH 0 1 mol L Standardmethoden dae ef 04 11 14 57 86 Chapter 4 Method Parameters Once the selecti
51. re tect a aae a aaa aaa 85 4 1 Method editing and new metbod nennen nnn nennen nnn nnne nnns nsns 85 4 2 lana Methods MR E E DES 85 4 3 CODY MENOS EPOR EL T 86 4 4 Race T R 86 4 5 Change Method WE TEE 87 4 5 1 Method TVG ries RH 87 4 5 2 ali ge c M 87 4 5 3 Dosing Dafatlielels ucro hti pito ph ee a Uem ueri a cd du dde 92 4 5 4 Sample le dad Te c c 93 4 5 5 Reie fly za lei eset cc wed nneed 94 5 System E due E 95 5 1 Interchangeable Reagents e eot deae e cene ed aste eek eed io Drei v ee eae riori edes 95 5 2 A ele uisi lut REED ITE 97 5 9 ate ANG TIM RT E m E TNT UTRUM 99 5 4 Se e c RN 99 5 5 EI E Mee P 99 5 6 Device TOMA OM ec rc T 100 SI Analytics 5 7 System SOUNS E 100 5 8 Software WPA m 101 6 Data Communication via RS 232 and USB B interface 103 6 1 General IntermalQbiss EE 103 6 2 Chaining multiple devices Daisy Chain Concept 103 6 3 Instruction Set for HS Communication 104 7 Connection of Analytical Balances and Printers 105 7 1 Connection of Analytical Balances AAA 105 7 1 1 Balance EK Eine EEN 105 7 2 EENHEETEN 106 8 Maintenance and Care of the TITRONIC 500 Piston Burette
52. risks A The relevant regulations regarding the handling of the substances used have to be observed The Decree on Hazardous Matters the Chemicals Act and the rules and information of the chemicals trade It has to be ensured on the side of the user that the persons entrusted with the use of the Piston Burette TITRONIC 500 are experts in the handling of substances used in the environment and in the Piston Burette TITRONIC 500 or that they are supervised by specialised persons respectively During all work with titration solutions A Please wear protective glasses A The TITRONIC 500 Piston Burette is equipped with integrated circuits EPROMs X rays or other high energy radiation may penetrate through the device s casing and delete the program For working with liquids not beeing common titration solvents especially the chemical resistance of the construction materials of the TITRONIC 500 have to be considered please also refer to chapter 1 1 For the use of liquids with high vapor pressure or mixture of substances not being mentioned in chapter 1 1 as allowed substances the safe and proper operation of the Piston Burette TITRONIC 500 has to be guaranteed by the user When the piston moves upwards within the cylinder a microfilm of dosing liquid or titration solution will always remain adhered to the inner wall of the cylinder but this has no influence on the dosing accuracy This small residue of liquid however may evaporate
53. s is shown in the illustration Insert the TZ 3872 connection hose in the threaded hole provided in the burette cylinder then tighten it by hand Insert the TZ 3871 suction hose into the threaded opening of the GL 45 or S 40 adapters then tighten it manually All the other hoses are already preassembled 68 Chapter 2 Unpacking and first Operation 2 Positioning and Replacing an Interchangeable Unit The base unit comes with an RFID reader and all the interchangeable units are equipped with an RFID transponder This transponder can be used to store the following information Unit size cannot be changed Unit ID cannot be changed Reagent name default blank Concentration default 1 000000 Concentration determined on Date To be used until Date Opened Produced on Date Test according to ISO 8655 Date Charge description default no charge Last modification Date Each time an interchangeable unit is pushed onto the base unit the data is automatically read out of the transponder 2 7 1 Placing an interchangeable unit The interchangeable unit is to be placed on the device unit as is shown in fig 9 a c subsequently it is to be pushed downwards until the black button latches on the left side Fig 9 a Fig 9 b Chapter 2 Unpacking and first Operation 69 Fig 9 c 2 7 2 Removing an interchangeable unit Removing the interchangeable unit is done in reverse order e Depress the black butto
54. s possible from materials which can be disposed of environmental friendly and recycled in a technically appropriate manner Please note The main printed board carries a lithium battery Batteries should not to be disposed of with the normal domestic waste They will be taken back and recycled or disposed of properly by the manufacturer at no cost Should you have any questions regarding disposal please contact SI Analytics Kapitel 11 Index 109 11 Index analytical balance 65 change method parameters 87 copy methods 86 delete methods 86 device address 97 Device Information 100 Display 75 Disposal 108 Documentation 94 Dosing accuracy 61 Dosing parameters 92 dosing speed 93 edit method 85 external PC Keyboard 76 Formula Selection 88 89 Formula unit 91 Formulae for manual titration 88 Formulae for the Preparation of Solutions 89 Front Keyboard 75 interchangeable units 108 Interchangeable units 61 Interrupted use 107 Main Menu 79 manual controller 76 manual controller TZ 3880 Mouse 65 Manual Titration 79 max dosing titration volume 92 Method name 85 method parameters 85 new method 85 Password 99 printer 65 RESET 99 RS232 Settings 97 safety information 62 Sample description 93 Sample weight and volume sample quantity Software Update 101 standard methods 85 storage 108 system Settings 95 System sounds 100 transportation 108 Unpacking and First Operation 63 USB Barcode scanner 65
55. sed The connection cable is to be connected to the RS 232 C interface 2 of the TITRONIC 500 This side of the connection cables always consists of a 4 pole mini plug The other side of the cable can depending on the type of balance be a 25 pole plug Sartorius a 9 pole plug Mettler AB S or a 15 pole specialised plug Mettler AT etc In order to allow the balance data to be sent to the TITRONIC 500 the data transmission parameters of the titrator and the balance must correspond to each other Additionally it is necessary to carry out some more standard settings on the side of the balances gt The balance is to send the balance data via RS 232 C only by means of a print command The balance is to send the balance data only after the display standstill The balance should never be set to automatic sending and or send continuously Handshake on the balance must be set to off or even Software Handshake or Pause VW ON WV No special characters such as S or St are allowed to be used as prefix in the balance data of the balance data string In such a case it might be possible that the TITRONIC 500 cannot process the balance data correctly After you have connected the balance with the appropriate cable to the TITRONIC 500 and have adjusted all settings in the balance software and possibly in the TITRONIC 500 you can now test the data transfer of the balance very easily Start the one method
56. the volume contraction and the specific weight difference between the sample weight and the solvent please observe the note on volume correction Fg opecific weight of the solvent used in g cm Note on volume correction The user has to decide on a case by case basis whether a volume correction is necessary and according to which procedure this correction is to be performed As a rule this volume correction may be omitted in the case of solutions with very low percentages of diluted substance 4 5 2 3 Sample weight and volume sample quantity Formula parameter EQ 1 BYFT MP F LOVE 2 B Blank value O 0000ml T Titre 1 00000000 M mol 28 44000 F1 Factor 1 1 0000 Selection AY E Enter Back Fig 61 20 ml HaOH 0 1 mol L 01 01 06 12 51 Formula parameter Amount Weight manual Weight automatic fixed weighed manuel volume Y Selection Enter Back Fig 62 20 ml HaOH 0 1 mol L 01 01 06 12 52 Chapter 4 Method Parameters 91 The Sample Quantity W item is used to select whether one is wishing to use a sample weight or a sample volume for titration or solution preparation You have the following options Fig 62 e Manual sample weight The sample weight is enquired by a prompt at the start of the method and manually input e Automatic sample weight The sample weight is automatically transferred by a connected balance e Fixed sample weight A fixed sample weight
57. tion to that the TITRONIC 500 also has an alternatively USB B interface which can only be used to connect a PC RS 232 C 1 establishes the connection to a connected computer or to the previous device of the Daisy Chain At the RS 232 C 2 it is possible to connect additional devices Daisy Chain Concept PIN assignment of the RS 232 C interfaces PIN No Meaning Description 1 T xD Data output 2 R xD Data input 3 Digital mass 6 2 Chaining multiple devices Daisy Chain Concept In order to activate several devices in a chain individually each device must have an own device address For this it is at first necessary to establish a connection from the computer to the RS 232 C interface 1 of the first devise in the chain by means of a RS 232 C data cable e g Type No TZ 3097 With the additional RS 232 C data cable Type No TZ 3094 the RS 232 C interface 2 of the first device is connected with the RS 232 C interface 1 of the second device At interface 2 of the second device it is possible to connect an additional device The TITRONIC 500 can also be connected via USB cable TZ 3480 type A M type B M 1 8m It is also possible to connect the TITRONIC 500 via USB cable TZ 3480 type A M USB type B M 1 8 m to a USB interface of a PC To accomplish this connection a driver has to be installed on the PC Then the USB B interface takes over the function of the RS232 1 interface Please contact SI Analytics for acquir
58. to all types of methods such as manual titration dosing and Solution Preparation Edit dosing parameter Methode 01 Dosing speed 40 00 ml min Filling speed 30 s max titration volu 10 000 ml Selection ANS Enter Back Fig 66 20 ml HaOH 0 1 mol L 01 01 05 12 55 Chapter 4 Method Parameters 93 The dosing speed can be set as a function of the interchangeable unit in terms of ml min from 0 1 to 100 ml min Interchangeable unit Max dosing speed ml min o 0 WA 05 10 WA 10 WA 20 WA 50 The filling speed can be set in terms of seconds from 20 to 999 The standard setting of this value is 30 seconds For diluted aqueous solutions the filling speed can be six to 20 seconds For non aqueous solutions the filling speed should be set to the 30 seconds In the case of highly viscous solutions such as concentrated sulphuric acid the filling speed should be further reduced down to 40 60 seconds Depending on the method type the maximum the living volume or titration volume can be set to 999 999 or even 9999 999 4 5 4 Sample description In the manual titration and in the preparation of solutions it is possible to input a sample description The possible input includes manual automatic or no sample description at all sample ID Methode 01 without sample ID automatic sample ID manual sample ID Selection Enter Back _Esc Fig 67 20 ml HaOH 0 1 mol L 01 01 06 12 56 BE
59. ue UV protection 5 to 6 times to the left to loosen it You can remove the UV protection and pull out of the glass cylinder together with the piston inside it Insert a new glass cylinder and piston Fig 21 into the interchangeable unit and then slip on the blue UV protection again Tighten the blue UV protection again by rotating it 5 to 6 times to the right e The piston rod should project 1 2 cm out of the interchangeable unit Fig 22 a At this point tilt the unit forward until the slanted bottom side is in flat contact with the lab table Fig 22 b This forces the piston into its correct position Should the piston be forced somewhat too far into the glass cylinder simply pull it out and place it in the correct position according to the procedure described above A 20 mi TZ 3920 Nr 000010 Glass cylinder Mahtis Piston rod Fig 21 Piston rod Fig 22a 74 Chapter 2 Unpacking and first Operation Fig 22 b Basically it should be noted that within one and the same interchangeable unit only the specified cylinder size may be installed since otherwise the coding which is memorised within the interchangeable unit will no longer match the cylinder size This will entail incorrect dosage And for the sake of dosing and analytical accuracy it is also recommended to replace the PTFE pistons each time a defective glass cylinder is replaced This app
Download Pdf Manuals
Related Search