Lincoln Electric SCPF4POP Use and Care Manual
Contents
1. 4800 mg m 30 minutes pulmonary effects LDLo oral human 786 mg kg TCLo inhalation human 4800 mg m 3 hours LDLo oral human 398 mg kg central nervous system gastrointestinal liver effects TCLo inhalation human 10000 mg m eye and pulmonary effects LDLo unreported man 1637 mg kg SUSPECTED CANCER AGENT Components of this product are listed as follows ETHYLENE GLYCOL Aerosol ACGIH TLV A4 Not Classifiable as to Human Carcinogenicity ZINC CHLORIDE EPA D Not Classifiable as to Human Carcinogenicity inadequate human and animal evidence of carcinogenicity or no data available The other components of this product are not found on the following lists FEDERAL OSHA Z LIST NTP CAL OSHA and therefore are not considered to be nor suspected to be cancer causing agents by these agencies IRRITANCY OF PRODUCT This product may be slightly irritating to contaminated tissue SENSITIZATION TO THE PRODUCT Petrolatum the main component of this product may cause allergic skin reactions in hypersensitive individuals REPRODUCTIVE TOXICITY INFORMATION Listed below is information concerning the effects of this product and its components are on the human reproductive system Mutagenicity This product is not reported to produce mutagenic effects in humans Animal mutation data are available for Ammonium Chloride Ethylene Glycol and Zinc Chloride components of this product and was obtained during clinical studies on s2. MATERIAL SAFETY DATA SHEET Prepared to U S OSHA CMA ANSI and Canadian WHMIS Standards This Material Safety Data Sheet is offered pursuant to OSHA s Hazard Communication Standard 29 CFR 1910 1200 Other government regulations must be reviewed for applicability to these products WARNING PRODUCT COMPONENTS PRESENT HEALTH AND SAFETY HAZARDS READ AND UNDERSTAND THIS MATERIAL SAFETY DATA SHEET M S DS ALSO FOLLOW YOUR EMPLOYER S SAFETY PRACTICES This product may contain Chromium and or Nickel which are listed by OSHA NTP or IARC as being a carcinogen or potential carcinogen Use of this product may expose you or others to fumes and gases at levels exceeding those established by the American Conference of Governmental Industrial Hygienists ACGIH or the Occupational Safety and Health Administration OSHA The information contained herein relates only to the specific product If the product is combined with other materials all component properties must be considered BE SURE TO CONSULT THE LATEST VERSION OF THE MSDS MATERIAL SAFETY DATA SHEETS ARE AVAILABLE FROM HARRIS PRODUCTS GROUP salesinfo jwharris com 513 754 2000 www harrisproductsgroup com STATEMENT OF LIABILITY DISCLAIMER To the best of the Harris Products Group knowledge the information and recommendations contained in this publication are reliable and accurate as of the date prepared However accuracy suitability or completeness are not guaranteed and no warranty guarantee
3. NATIONAL FIRE PROTECTION ASSOCIATION Health Hazard 0 material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials 1 materials that on exposure under fire conditions could cause irritation or minor residual injury 2 materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury 3 materials that can on short exposure could cause serious temporary or residual injury 4 materials that under very short exposure causes death or major residual injury Flammability Hazard and Reactivity Hazard Refer to definitions for Hazardous Materials Identification System STAY CLEAN PASTE SOLDERING FLUX MSDS FLAMMABILITY LIMITS IN AIR Much of the information related to fire and explosion is derived from the National Fire Protection Association NFPA Flash Point Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air Autoignition Temperature The minimum temperature required to initiate combustion in air with no other source of ignition LEL the lowest percent of vapor in air by volume that will explode or ignite in the presence of an ignition source UEL the highest percent of vapor in air by volume that will explode or ignite in the presence of an ignition source TOXICOLOGICAL INFORMATION Human and Animal Toxicology Possible health hazards as derive
4. or representation expressed or implied is made by Harris Products Group as to the absolute correctness or sufficiency of any representation contained in this and other publications Harris Products Group assumes no responsibility in connection therewith nor can it be assumed that all acceptable safety measures are contained in this and other publications or that other or additional measures may not be required under particular or exceptional conditions or circumstances Data may be changed from time to time PART What is the material and what do need to know in an emergency 1 PRODUCT IDENTIFICATION TRADE NAME AS LABELED STAY CLEAN PASTE SOLDERING FLUX CHEMICAL NAME CLASS Petroleum Gel Mixture SYNONYMS Not Applicable PRODUCT USE Metal Soldering Operations DOCUMENT NUMBER 0136 SUPPLIER MANUFACTURER S NAME HARRIS Products Group ADDRESS 4501 Quality Place Mason Ohio 45040 EMERGENCY PHONE CHEMTREC 1 800 424 9300 BUSINESS PHONE 513 754 2000 FAX 513 754 8778 DATE OF PREPARATION August 21 2010 2 COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS W W EXPOSURE LIMITS IN AIR OTHER ma ma ma ma ma ma Zinc Chloride 7646 85 7 lt 40 2 Vacated NIOSH RELs TWA 1 The exposure limits 1989 STEL 2 provided are for Zinc PELs Carcinogen EPA D Chloride Fumes Ethylene Glycol 107 21 1 100 ceiling aerosol A4 Not Classifiable as a Human DFG MAKs TWA 26 Danger of Cutaneous Absorpt
5. determined NFPA RATING FLAMMABLE LIMITS in air by volume Le ee Lower LEL Not applicable Upper UEL Not applicable FIRE EXTINGUISHING MATERIALS Water Spray YES for cooling Carbon Dioxide YES Halon YES Foam YES PEALTH REACTIVITY Dry Chemical YES Other Any B Class gt UNUSUAL FIRE AND EXPLOSION HAZARDS This product must be substantially preheated before ignition can occur This product can float on water and may travel to distant locations During a fire irritating and toxic OTHER gases i e carbon monoxide carbon dioxide and hydrogen chloride may be generated Explosion Sensitivity to Mechanical Impact Not sensitive See Section 16 for Explosion Sensitivity to Static Discharge Not sensitive Definition of Ratings SPECIAL FIRE FIGHTING PROCEDURES Not applicable 6 ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE Uncontrolled releases should be responded to by trained personnel using pre planned procedures Proper protective equipment should be used In case of a large uncontrolled release clear the affected area and protect people In the event of a non incidental release of this product minimum Personal Protective Equipment should be Level D gloves rubber gloves over latex gloves safety goggles and appropriate body protection Level B Protection which includes Self Contained Breathing Apparatus during spill response situations in which the oxygen level is below 19 5 or is unknown Absorb
6. spilled paste flux with polypads or other suitable absorbent Rinse area with soap and water solution If the heated product has been spilled allow the material to cool before clean up procedures begin Decontaminate the area thoroughly Place all spilled residues in a suitable container and seal Dispose of in accordance with U S Federal State and local hazardous waste disposal regulations or the appropriate Standards of Canada and its Provinces see Section 13 Disposal Considerations PART Ill Howcan prevent hazardous situations from occurring 7 HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES As with all chemicals avoid getting this product ON YOU or IN YOU Wash thoroughly after using this product Do not eat drink smoke or apply cosmetics while handling this product STORAGE AND HANDLING PRACTICES All employees who handle this material should be trained to handle it safely Standard safety practices associated with welding brazing and soldering operations should be followed when using this product STAY CLEAN PASTE SOLDERING FLUX MSDS July 1 2004 PAGE 3 OF 8 7 HANDLING and STORAGE Continued STORAGE AND HANDLING PRACTICES continued Open containers slowly on a stable surface Avoid the accidental exposure of this material to open flames hot surfaces or other sources of ignition Store this product in a cool dry location away from direct sunlight sources of intense heat or where freezing is poss
7. AL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION ENVIRONMENTAL STABILITY The components of this product will slowly react with water oxygen and other substances to form a wide variety of inorganic compounds The following environmental data are available for the components of this product ETHYLENE GLYCOL Log Kaw 1 36 The bioconcentration factor of Ethylene Glycol in fish was reported to be 10 after 3 days of exposure this suggests that it will not bioconcentrate in fish Biological Oxygen Demand 0 47 g oxygen g Ethylene Glycol Chemical Oxygen Demand 1 29 g oxygen g Ethylene Glycol ZINC CHLORIDE Water solubility 432 g 100 mL 25 C 614 g 100 mL 100 C Zinc can persist indefinitely as a cation Radioactive zinc Zn has been found to concentrate in plants and milk Acute Hazard Level Threshold For vegetables and other crops 750 ppm Zn STAY CLEAN PASTE SOLDERING FLUX MSDS July 1 2004 PAGE 5 OF 8 12 ECOLOGICAL INFORMATION Continued EFFECT OF MATERIAL ON PLANTS or ANIMALS This product may be harmful to plant and animals depending on the quantity and duration of over exposure Specific data on test animals are available but are not presented in this Material Safety Data Sheet EFFECT OF CHEMICAL ON AQUATIC LIFE Because this product contains a petroleum based material which can float on water thereby depriving oxygen to impacted bodies of water large releases of this produ
8. CAS This is the Chemical Abstract Service Number which uniquely identifies each constituent EXPOSURE LIMITS IN AIR ACGIH American Conference of Governmental Industrial Hygienists a professional association which establishes exposure limits TLV Threshold Limit Value an airborne concentration of a substance which represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect The duration must be considered including the 8 hour Time Weighted Average TWA the 15 minute Short Term Exposure Limit and the instantaneous Ceiling Level C Skin absorption effects must also be considered OSHA U S Occupational Safety and Health Administration PEL Permissible Exposure Limit This exposure value means exactly the same as a TLV except that it is enforceable by OSHA The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June 1993 Air Contaminants Rule Federal Register 58 35338 35351 and 58 40191 Both the current PELs and the vacated PELs are indicated The phrase Vacated 1989 PEL is placed next to the PEL which was vacated by Court Order IDLH Immediately Dangerous to Life and Health This level represents a concentration from which one can escape within 30 minutes without suffering escape preventing or permanent injury The DFG MAK is the Republic of Germany s Maximum Exposure Level similar to the U S PEL NIOSH is the Nati
9. EZING MELTING POINT 37 60 C 100 140 F SOLUBILITY IN WATER Insoluble BOILING POINT Not applicable VAPOR PRESSURE Not applicable pH Not applicable ODOR THRESHOLD Not applicable COEFFICIENT OF OIL WATER DISTRIBUTION PARTITION COEFFICIENT Not applicable The following information is for the product APPEARANCE ODOR AND COLOR This product is an opaque odorless tan gold gel HOW TO DETECT THIS SUBSTANCE warning properties The appearance may act as a distinguishing characteristic of this product 10 STABILITY and REACTIVITY STABILITY Stable DECOMPOSITION PRODUCTS Carbon oxides a variety organic molecules hydrogen chloride zinc oxides nitrogen oxides and ammonia MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE This product is not compatible with strong oxidizing agents HAZARDOUS POLYMERIZATION Will not occur CONDITIONS TO AVOID Avoid exposing this product to incompatible materials STAY CLEAN PASTE SOLDERING FLUX MSDS July 1 2004 PAGE 4 OF 8 PART IV is there any other useful information about this material 11 TOXICOLOGICAL INFORMATION TOXICITY DATA The following human toxicological data are available for the components of this product Other data for animals are available but are not presented in this Material Safety Data Sheet ZINC CHLORIDE ETHYLENE GLYCOL DNA Inhibition System human lymphocyte 0 360 mmol L DNA Inhibition System human lymphocyte 320 mmol L TCLo inhalation man
10. FICATION SYSTEM exposure to this product In the unlikely event this product is inhaled mild irritation of the nose may occur Symptoms of such over exposure may include nasal congestion and sneezing Though not anticipated to occur during use of this paste flux when the proper precautions are taken extreme inhalation over exposure to Zinc Chloride a component of this product can have adverse effects on the lungs i e causing pulmonary edema and pneumonitis life threatening lung conditions Inhalation FLAMMABILITY RED 1 of Zinc Chloride fumes can cause metal fume fever Symptoms of such over exposures include headache fever rapid breathing sweating and pains in legs and chest Severe inhalation of vapors or fumes as may occur if individuals are exposed in poorly ventilated areas such as confined spaces may be harmful CONTACT WITH SKIN or EYES This product may be slightly irritating to the skin Though this paste flux is not classified as a sensitizer Petrolatum the main component of this product may cause allergic skin reactions in hypersensitive individuals If the paste flux enters the eyes mild irritation may occur and result PROTECTIVE EQUIPMENT A in redness and watering Note If the product is heated before use the temperature of the heated product will be above 37 C 100 F skin or eye contact with the heated product can result in thermal burns SKIN ABSORPTION Skin absorption is not a significant route of over exp
11. RY PROTECTION Up to 10 mg m Dust mist and fume respirator or Supplied Air Respirator SAR Up to 25 mg m Powered air purifying respirator with dust mist and fume filter s or SAR operated in a continuous flow mode Up to 50 mg m Full facepiece respirator with high efficiency particulate filter s powered air purifying respirator with tight fitting facepiece and high efficiency particulate filter s full facepiece Self Contained Breathing Apparatus SCBA or full facepiece SAR Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions Positive pressure full facepiece SCBA or positive pressure full facepiece SAR with an auxiliary positive pressure SCBA Escape Full facepiece respirator with high efficiency particulate filter s or escape type SCBA EYE PROTECTION Safety glasses or goggles In the event the heated product is used a face shield is recommended HAND PROTECTION Wear butyl rubber nitrile rubber or polyfluorinated polyethylene gloves for routine industrial use BODY PROTECTION None normally needed for normal circumstances of use Use body protection appropriate for task i e apron coveralls chemically resistant boots 9 PHYSICAL and CHEMICAL PROPERTIES Unless otherwise specified the following information is for Petrolatum the main component of this product RELATIVE VAPOR DENSITY air 1 Not applicable EVAPORATION RATE nBuAc 1 1 5 SPECIFIC GRAVITY water 1 0 815 0 88 FRE
12. TORY INFORMATION Continued U S SARA THRESHOLD PLANNING QUANTITY There are no specific Threshold Planning Quantities for the components of this product The default Federal MSDS submission and inventory requirement filing threshold of 10 000 Ibs 4 540 kg therefore applies per 40 CFR 370 20 U S CERCLA REPORTABLE QUANTITY RQ Ammonium Chloride 5000 Ib 2270 kg Ethylene Glycol 5000 Ib 2270 kg Zinc Chloride 1000 Ib 454 kg U S TSCA INVENTORY STATUS The components of this product are listed on the TSCA Inventory OTHER U S FEDERAL REGULATIONS Not applicable CALIFORNIA PROPOSITION 65 WARNING This product may contain chemical s and when used for welding may produce fumes or gases containing chemicals known to the State of California to cause cancer and or birth defects or other reproductive harm U S STATE REGULATORY INFORMATION Components of this product are covered under specific State regulations as denoted below Alaska Designated Toxic and Hazardous Substances Ammonium Chloride Ethylene Glycol Zinc Chloride fume California Permissible Exposure Limits for Chemical Contaminants Ammonium Chloride Ethylene Glycol Zinc Chloride fume Florida Substance List Ammonium Chloride Ethylene Glycol Zinc Chloride fume Illinois Toxic Substance List Ammonium Chloride Ethylene Glycol Zinc Chloride fume Kansas Section 302 313 List Ethylene Glycol Massachusetts Substance List Ammonium Chlo
13. ct is may be harmful to aquatic plant and animal life Additionally odorless zinc poisoning causes inflamed gills in fish Laboratory studies of Atlantic salmon rainbow trout carp and goldfish have shown avoidance reactions by these fish to zinc in water Additional aquatic toxicity information for the components of this product is as follows ETHYLENE GLYCOL ETHYLENE GLYCOL LDso Carassius auratus goldfish 5000 mg L 24 hour modified ASTM D Toxicity threshold cell multiplication test Pseudomonas pudita bacteria 1345 10 00 mg L LCs Poecilia reticulata guppies 49300 ppm 7 days Toxicity threshold cell multiplication test Entosiphon sulcatum protozoan LCso rainbow trout 18 500 mg L 96 hours 10 00 mg L LCso rainbow trout 41000 mg L 96 hours at 20 EC Toxicity threshold cell multiplication test Uronema parduzi Chatton Lwoff LCs Crangon crangon brown shrimp 100 mg L 48 hours aerated salt protozoan 10 00 mg L water Toxicity threshold cell multiplication test Chorella pyrenoidasa algae LCs Carassius auratus goldfish 5000 mg L 24 hours 20 EC static 180 000 mg L toxic conditions Toxicity threshold cell multiplication test Microcystis aeruginosa algae 2 000 mg L 13 DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL Waste disposal must be in accordance with appropriate U S Federal State and local regulations or with regulations of Canada and its Provinces This product if unaltered by use
14. d from human data animal studies or from the results of studies with similar compounds are presented Definitions of some terms used in this section are LDso Lethal Dose solids amp liquids which kills 50 of the exposed animals LCs Lethal Concentration gases which kills 50 of the exposed animals ppm concentration expressed in parts of material per million parts of air or water mg m concentration expressed in weight of substance per volume of air mg kg quantity of material by weight administered to a test subject based on their body weight in kg Other measures of toxicity include TDLo the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom TDo LDLo and LDo or TC TCo LCLo and LCo the lowest dose or concentration to cause lethal or toxic effects Cancer Information The sources are IARC the International Agency for Research on Cancer NTP the National Toxicology Program RTECS the Registry of Toxic Effects of Chemical Substances OSHA and CAL OSHA IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4 Subrankings 2A 2B etc are also used Other Information BEI ACGIH Biological Exposure Indices represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV Ecologica
15. ible Store away from incompatible chemicals see Section 10 Stability and Reactivity Keep container tightly closed when not in use Inspect all incoming containers before storage to ensure they are properly labeled and not damaged 8 EXPOSURE CONTROLS PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS No special ventilation systems or engineering controls are normally required when using this product Prudent practice is to ensure eyewash safety shower stations are available near areas where this product is used RESPIRATORY PROTECTION No respiratory protection is normally required when using this product Maintain airborne contaminant concentrations below guidelines listed in Section 2 Composition and Information on Ingredients If respiratory protection is needed U S Federal OSHA Standard 29 CFR 1910 134 applicable U S State regulations or the Canadian CSA Standard Z94 4 93 and applicable standards of Canadian Provinces Respiratory Protection is recommended to be worn during welding operations Oxygen levels below 19 5 are considered IDLH by OSHA In such atmospheres use of a full facepiece pressure demand SCBA or a full facepiece supplied air respirator with auxiliary self contained air supply is required under OSHA s Respiratory Protection Standard 1910 134 1998 For additional information the NIOSH recommended respiratory protection guidelines for Zinc Chloride Fumes are provided as follows CONCENTRATION RESPIRATO
16. ion PEAK 2eMAK 5 min momentary value DFG MAK Pregnancy Risk Classification C Carcinogen TLV A4 Ammonium Chloride a 02 10 NIOSH RELs The exposure limits Vacated eee TWA 10 provided are for 1989 1989 STEL 20 Ammonium Chloride PELs PELs Fumes 7782185 Balance ne ne Ne one se jo OE _ k NE Not Established See Section 16 for Definitions of Terms Used NOTE 1 ALL WHMIS required information is included in appropriate sections based on the ANSI Z400 1 1998 format This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR STAY CLEAN PASTE SOLDERING FLUX MSDS July 1 2004 PAGE 1 OF 8 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW This product is an opaque odorless tan gold gel This product can be slightly irritating to contaminated tissue This product must be substantially pre heated before ignition can occur This product is not reactive Emergency responders must wear personal protective equipment suitable for the situation to which they are responding SYMPTOMS OF OVER EXPOSURE BY ROUTE OF EXPOSURE The most significant routes of over exposure for this product are inhalation of fumes and contact with skin and eyes The symptoms of overexposure to this product via route of entry are as follows INHALATION Inhalation is not anticipated to be a significant route of over HAZARDOUS MATERIAL IDENTI
17. l Information EC is the effect concentration in water BCF Bioconcentration Factor which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter Coefficient of Oil Water Distribution is represented by log Kow or log Koc and is used to assess a substance s behavior in the environment REGULATORY INFORMATION This section explains the impact of various laws and regulations on the material U S EPA is the U S Environmental Protection Agency DOT is the U S Department of Transportation SARA is the Superfund Amendments and Reauthorization Act TSCA is the U S Toxic Substance Control Act CERCLA or Superfund refers to the Comprehensive Environmental Response Compensation and Liability Act Labeling is per the American National Standards Institute ANSI Z129 1 CANADA CEPA is the Canadian Environmental Protection Act WHMIS is the Canadian Workplace Hazardous Materials Information System TC is Transport Canada DSL NDSL are the Canadian Domestic Non Domestic Substances Lists The CPR is the Canadian Product Regulations This section also includes information on the precautionary warnings which appear on the materials package label July 1 2004 PAGE 8 OF 8
18. may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority U S EPA WASTE NUMBER Not applicable to wastes consisting only of this product 14 TRANSPORTATION INFORMATION THIS MATERIAL IS NOT HAZARDOUS Per 49 CFR 172 101 BY THE U S DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME Not applicable HAZARD CLASS NUMBER and DESCRIPTION Not applicable UN IDENTIFICATION NUMBER Not applicable PACKING GROUP Not applicable DOT LABEL S REQUIRED Not applicable NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER 2000 Not applicable MARINE POLLUTANT No component of this product is designated as a marine pollutant by the Department of Transportation 49 CFR 172 101 Appendix B TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS This material is not considered as dangerous goods per regulations of Transport Canada 15 REGULATORY INFORMATION ADDITIONAL U S REGULATIONS U S SARA REPORTING REQUIREMENTS The components of this product are subject to the reporting requirements of Sections 302 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act and are listed as follows CHEMICAL NAME SARA 302 SARA 304 SARA 313 40 CFR 355 Appendix A 40 CFR Table 302 4 40 CFR 372 65 Ammonium Chloride Ethylene Glycol Zinc Chloride NO YES as Zinc Compound STAY CLEAN PASTE SOLDERING FLUX MSDS July 1 2004 PAGE 6 OF 8 15 REGULA
19. n if necessary Take copy of label and MSDS to health professional with victim SKIN EXPOSURE In the event of skin over exposure rinse affected area with a soap and water solution If skin contact results in irritation the minimum flushing is for 15 minutes Victim must seek medical attention if adverse health effects occur or if skin contact has resulted in a thermal burn STAY CLEAN PASTE SOLDERING FLUX MSDS July 1 2004 PAGE 2 OF 8 4 FIRST AID MEASURES Continued EYE EXPOSURE If this product enters the eyes open victim s eyes while under gentle running water Use sufficient force to open eyelids Have victim roll eyes Minimum flushing is for 15 minutes Victim must seek medical attention if adverse health effects occur or if eye contact has resulted in a thermal burn INHALATION If this product is inhaled remove victim to fresh air Have victim blow nose INGESTION If swallowed call physician immediately Do not induce vomiting unless directed by medical personnel Rinse mouth with water if person is conscious Never give fluids or induce vomiting if person is unconscious having convulsions or not breathing MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Skin disorders may be aggravated by prolonged over exposures to this product RECOMMENDATIONS TO PHYSICIANS Treat symptoms and eliminate overexposure 5 FIRE FIGHTING MEASURES FLASH POINT ASTM D 92 gt 198 C gt 390 F for Petrolatum AUTOIGNITION TEMPERATURE Not
20. onal Institute of Occupational Safety and Health which is the research arm of the U S Occupational Safety and Health Administration OSHA NIOSH issues exposure guidelines called Recommended Exposure Levels RELs When no exposure guidelines are established an entry of NE is made for reference HAZARD RATINGS HAZARDOUS MATERIALS IDENTIFICATION SYSTEM Health Hazard 0 minimal acute or chronic exposure hazard 1 slight acute or chronic exposure hazard 2 moderate acute or significant chronic exposure hazard 3 severe acute exposure hazard onetime overexposure can result in permanent injury and may be fatal 4 extreme acute exposure hazard onetime overexposure can be fatal Flammability Hazard 0 minimal hazard 1 materials that require substantial pre heating before burning 2 combustible liquid or solids liquids with a flash point of 38 93 C 100 200 F 3 Class IB and IC flammable liquids with flash points below 38 C 100 F 4 Class IA flammable liquids with flash points below 23 C 73 F and boiling points below 38 C 100 F Reactivity Hazard 0 normally stable 1 material that can become unstable at elevated temperatures or which can react slightly with water 2 materials that are unstable but do not detonate or which can react violently with water 3 materials that can detonate when initiated or which can react explosively with water 4 materials that can detonate at normal temperatures or pressures
21. osure to the components of this product HEALTH BLUE 1 REACTIVITY euow l o SEE SECTION8 SEE SECTION 8 INGESTION If this flux is ingested nausea vomiting and diarrhea may occur For routine applications depending on the amount of the product swallowed Severe ingestion an N ri Ppa exposures may result in damage to the tissues of the gastrointestinal system See Section 16 for Definition of Ratings and death INJECTION Though not a likely route of occupational exposure for this product injection of this product via punctures or lacerations in the skin may cause local reddening tissue swelling and discomfort HEALTH EFFECTS OR RISKS FROM EXPOSURE An Explanation in Lay Terms Symptoms associated with over exposure to this product are as follows ACUTE The chief acute health hazards associated with this product would be the potential for mild irritation of contaminated tissue Though unlikely to occur during occupational use ingestion of large quantities may be fatal CHRONIC Dermatitis may result in chronic skin contact to this product Refer to Section 11 Toxicological Information for additional data on this product s components TARGET ORGANS ACUTE Eyes skin CHRONIC Skin PART Il What should do if a hazardous situation occurs 4 FIRST AID MEASURES Victims of chemical exposure must be taken for medical attention if adverse health effects occur Rescuers should be taken for medical attentio
22. pecific animal tissues exposed to high doses of these compounds Embryotoxicity This product is not reported to produce embryotoxic effects in humans Animal embryotoxic data are available for Ethylene Glycol and Zinc Chloride components of this product Teratogenicity This product is not reported to cause teratogenic effects in humans Studies on test animals exposed to relatively high doses of Ethylene Glycol and Zinc Chloride components of this product indicate teratogenic effects Reproductive Toxicity This product is not reported to cause reproductive effects in humans Studies on test animals exposed to relatively high doses of Ethylene Glycol and Zinc Chloride components of this product indicate adverse reproductive effects A mutagen is a chemical which causes permanent changes to genetic material DNA such that the changes will propagate through generational lines An embryotoxin is a chemical which causes damage to a developing embryo i e within the first eight weeks of pregnancy in humans but the damage does not propagate across generational lines A teratogen is a chemical which causes damage to a developing fetus but the damage does not propagate across generational lines A reproductive toxin is any substance which interferes in any way with the reproductive process ACGIH BIOLOGICAL EXPOSURE INDICES Currently there are no ACGIH Biological Exposure Indices BEIs determined for the component of this product 12 ECOLOGIC
23. ride Ethylene Glycol Zinc Chloride fume Michigan Critical Materials Register No Minnesota List of Hazardous Substances Ammonium Chloride Ethylene Glycol Zinc Chloride fume Missouri Employer Information Toxic Substance List Ammonium Chloride Ethylene Glycol Zinc Chloride fume New Jersey Right to Know Hazardous Substance List Ammonium Chloride Ethylene Glycol Zinc Chloride fume North Dakota List of Hazardous Chemicals Reportable Quantities Ammonium Chloride Zinc Chloride Pennsylvania Hazardous Substance List Ammonium Chloride Ethylene Glycol and Zinc Chloride Rhode Island Hazardous Substance List Ammonium Chloride fume Ethylene Glycol Zinc Chloride fume Texas Hazardous Substance List Zinc Chloride fume West Virginia Hazardous Substance List Zinc Chloride fume Wisconsin Toxic and Substances Zinc Chloride fume Hazardous CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT PROPOSITION 65 No component of this product is on the California Proposition 65 lists ADDITIONAL CANADIAN REGULATIONS CANADIAN DSL NDSL INVENTORY STATUS The components of this product are on the DSL Inventories OTHER CANADIAN REGULATIONS Not applicable CANADIAN ENVIRONMENTAL PROTECTION ACT CEPA PRIORITIES SUBSTANCES LISTS Ethylene Glycol is on the CEPA Second Priorities Substances List CANADIAN WHMIS SYMBOLS PREPARED BY DATE OF PRINTING Class D2B Other Toxic Effect
24. s 16 OTHER INFORMATION CHEMICAL SAFETY ASSOCIATES Inc 9163 Chesapeake Drive San Diego CA 92123 1002 858 565 0302 September 21 2010 This Material Safety Data Sheet is offered pursuant to OSHA s Hazard Communication Standard 29 CFR 1910 1200 Other government regulations must be reviewed for applicability to this product The information contained herein relates only to the specific product other materials all component properties must be considered If the product is combined with To the best of the Harris Products Group knowledge the information and recommendations contained in this publication are reliable and accurate as of the date of issue However accuracy suitability or completeness are not guaranteed and no warranty guarantee or representation expressed or implied is made by Harris Products Group as to the absolute correctness or sufficiency of any representation contained in this and other publications Harris Products Group assumes no responsibility in connection therewith nor can it be assumed that all acceptable safety measures may not be required under particular or exceptional conditions or circumstances Data may be changed from time to time Be sure to consult the latest edition STAY CLEAN PASTE SOLDERING FLUX MSDS PAGE 7 OF 8 July 1 2004 DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS Some of these which are commonly used include the following
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