Lincoln Electric NICK61POP Use and Care Manual
Contents
1. MATERIAL SAFETY DATA SHEET Prepared to U S OSHA CMA ANSI and Canadian WHMIS Standards This Material Safety Data Sheet is offered pursuant to OSHA s Hazard Communication Standard 29 CFR 1910 1200 Other government regulations must be reviewed for applicability to these products WARNING PRODUCT COMPONENTS PRESENT HEALTH AND SAFETY HAZARDS READ AND UNDERSTAND THIS MATERIAL SAFETY DATA SHEET M S DS ALSO FOLLOW YOUR EMPLOYER S SAFETY PRACTICES This product may contain Chromium and or Nickel which are listed by OSHA NTP or IARC as being a carcinogen or potential carcinogen Use of this product may expose you or others to fumes and gases at levels exceeding those established by the American Conference of Governmental Industrial Hygienists ACGIH or the Occupational Safety and Health Administration OSHA The information contained herein relates only to the specific product If the product is combined with other materials all component properties must be considered BE SURE TO CONSULT THE LATEST VERSION OF THE MSDS MATERIAL SAFETY DATA SHEETS ARE AVAILABLE FROM HARRIS PRODUCTS GROUP salesinfo jwharris com 513 754 2000 www harrisproductsgroup com STATEMENT OF LIABILITY DISCLAIMER To the best of the Harris Products Group knowledge the information and recommendations contained in this publication are reliable and accurate as of the date prepared However accuracy suitability or completeness are not guaranteed and no warranty guarantee2. EFFECTIVE DATE June 21 2002 PAGE 10 OF 10
3. June 21 2002 PAGE 1 OF 10 ROSIN CORE COMPOSITION ELEMENT WEIGHT of Core Weight WEIGHT of Total Solder Weight 2 NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS Continued WIRE COMPOSITION CHEMICAL NAME EXPOSURE LIMITS IN AIR ACGIH TLV OSHA PEL IDLH mg m TWA STEL TWA STEL mg m mg m mg m mg m NE Antimony amp exposure 7440 36 0 NIOSH REL compounds as Sb TWA 0 5 DFG MAKS TWA 0 5 Antimony elemental measured as the Inhalable fraction of the aerosol PEAK 10 MAK 30 min average value Copper 7440 50 8 NIOSH RELs exposure limits are for TWA 1 dust 0 1 fume copper fume as Copper DFG MAKs TWA 0 1 fume Respirable fraction 1 dusts amp mists inhalable fraction PEAK 2 MAK 30 min average value Carcinogen EPA D dusts amp mists Nickel Elemental metal 7440 02 0 1 5 A5 NIOSH REL Inhalable TWA 0 015 Fraction Carcinogen IARC 2B MAK 1 Not NIOSH X NTP R TLV A5 Suspected as a Human Carcinogen Silver 7440 22 4 F NIOSH REL The following exposure TWA 0 01 dust limits are for Silver Metal DFG MAKs TWA 0 01 Inhalable Fraction PEAK 2eMAK 5 min momentary value Inhalable Fraction Carcinogen EPA D Tin 7440 31 5 NIOSH REL The following exposure TWA 2 limits are for Tin Metal Zinc 7440 66 6 5 fume NIOSH RELs Exposure limits given are 10 dust Vacated TWA 5 dust amp fume for Zinc oxide Fume amp Du
4. PAGE 8 OF 10 15 REGULATORY INFORMATION Continued ADDITIONAL U S REGULATIONS continued CALIFORNIA PROPOSITION 65 Nickel is a component of some of these products Nickel is on the California Proposition 65 lists WARNING Some of these products contain chemical s known to the State of California to cause cancer LABELING Precautionary Statements CAUTION FUMES MAY BE HARMFUL IF INHALED FUMES CAN CAUSE SKIN AND EYE IRRITATION FUMES OR CONTACT WITH PLASTIC CORE MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS MOLTEN SOLDER CAN CAUSE THERMAL BURNS CANCER HAZARD CONTAINS MATERIAL WHICH CAN CAUSE CANCER Avoid inhalation of fumes Avoid contact with skin eyes and clothing Wash thoroughly after handling Use in well ventilated area Wear gloves safety glasses or colored absorptive lens body protection and respiratory protection as appropriate for welding or soldering operations FIRST AID In case of skin or eye contact with fumes flush skin with copious amounts of water In case of thermal burn flush area with water for 15 minutes Remove contaminated clothing and shoes If inhaled remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen If ingested do not induce vomiting Seek medical attention if adverse reaction occurs or in the event of a thermal burn INCASE OF FIRE Use water spray foam dry chemical or COs INCASE OF SPILL Sweep up or vacuum spilled material absorb spil
5. leather apron 9 PHYSICAL and CHEMICAL PROPERTIES The following information is for Tin the main component of these products RELATIVE VAPOR DENSITY air 1 Not applicable EVAPORATION RATE nBuAc 1 Not applicable SPECIFIC GRAVITY water 1 7 28 FREEZING MELTING POINT 232 C 450 F SOLUBILITY IN WATER Insoluble BOILING POINT 2270 C 4118 F VAPOR PRESSURE mm Hg 20 C Approximately 0 pH Not applicable ODOR THRESHOLD Not applicable COEFFICIENT OF OIL WATER DISTRIBUTION PARTITION COEFFICIENT Not applicable The following information is for the product APPEARANCE ODOR AND COLOR These products are a gray to silver odorless metal wires which may have a plastic core running through the middle HOW TO DETECT THIS SUBSTANCE warning properties The appearance is a distinctive characteristic of these products 10 STABILITY and REACTIVITY STABILITY Stable DECOMPOSITION PRODUCTS A tin and zinc compounds and a variety of metal oxides MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE These products are not compatible with strong acids i e nitric acid strong bases i e sodium hydroxide sulfur and strong oxidizers i e hydrogen peroxide HAZARDOUS POLYMERIZATION Will not occur CONDITIONS TO AVOID Avoid uncontrolled exposure to extreme temperatures and incompatible chemicals PART IV is there any other useful information about this material 11 TOXICOLOGICAL INFORMATION TOXICITY DATA The foll
6. Exposure Indices represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV Ecological Information EC is the effect concentration in water BCF Bioconcentration Factor which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter Coefficient of Oil Water Distribution is represented by log Kow or log Koc and is used to assess a substance s behavior in the environment REGULATORY INFORMATION This section explains the impact of various laws and regulations on the material U S EPA is the U S Environmental Protection Agency DOT is the U S Department of Transportation SARA is the Superfund Amendments and Reauthorization Act TSCA is the U S Toxic Substance Control Act CERCLA or Superfund refers to the Comprehensive Environmental Response Compensation and Liability Act Labeling is per the American National Standards Institute ANSI Z129 1 CANADA CEPA is the Canadian Environmental Protection Act WHMIS is the Canadian Workplace Hazardous Materials Information System TC is Transport Canada DSL NDSL are the Canadian Domestic Non Domestic Substances Lists The CPR is the Canadian Product Regulations This section also includes information on the precautionary warnings which appear on the materials package label
7. concentration from which one can escape within 30 minutes without suffering escape preventing or permanent injury The DFG MAK is the Republic of Germany s Maximum Exposure Level similar to the U S PEL NIOSH is the National Institute of Occupational Safety and Health which is the research arm of the U S Occupational Safety and Health Administration OSHA NIOSH issues exposure guidelines called Recommended Exposure Levels RELs When no exposure guidelines are established an entry of NE is made for reference NTP National Toxicology Program HAZARD RATINGS HAZARDOUS MATERIALS IDENTIFICATION SYSTEM Health Hazard 0 minimal acute or chronic exposure hazard 1 slight acute or chronic exposure hazard 2 moderate acute or significant chronic exposure hazard 3 Severe acute exposure hazard onetime overexposure can result in permanent injury and may be fatal 4 extreme acute exposure hazard onetime overexposure can be fatal Flammability Hazard 0 minimal hazard 1 materials that require substantial pre heating before burning 2 combustible liquid or solids liquids with a flash point of 38 93 C 100 200 F 3 Class IB and IC flammable liquids with flash points below 38 C 100 F 4 Class IA flammable liquids with flash points below 23 C 73 F and boiling points below 38 C 100 F Reactivity Hazard 0 normally stable 1 material that can become unstable at elevated temperatures or which can react slightly
8. consult the latest edition DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS Some of these which are commonly used include the following CAS This is the Chemical Abstract Service Number which uniquely identifies each constituent EXPOSURE LIMITS IN AIR ACGIH American Conference of Governmental Industrial Hygienists a professional association which establishes exposure limits IARC International Agency for Research on Cancer TLV Threshold Limit Value an airborne concentration of a substance which represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect The duration must be considered including the 8 hour Time Weighted Average TWA the 15 minute Short Term Exposure Limit and the instantaneous Ceiling Level C Skin absorption effects must also be considered OSHA U S Occupational Safety and Health Administration PEL Permissible Exposure Limit This exposure value means exactly the same as a TLV except that it is enforceable by OSHA The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June 1993 Air Contaminants Rule Federal Register 58 35338 35351 and 58 40191 Both the current PELs and the vacated PELs are indicated The phrase Vacated 1989 PEL is placed next to the PEL which was vacated by Court Order IDLH Immediately Dangerous to Life and Health This level represents a
9. information is included in appropriate sections based on the ANSI Z400 1 1998 format This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEW These products consist of gray to silver colored odorless wires which may have a plastic core through the center There is no immediate health hazard associated with the wire product The plastic core of these products contains a sensitizer prolonged or repeated exposure to this plastic can cause respiratory and skin allergy like reactions Nickel a component of the Bridgit and Nick wires is a suspect carcinogen Though the wire is not flammable if involved in a fire and exposed to extremely high temperatures harmful fumes containing Tin Silver Antimony and Copper and a variety of metal oxides may be generated These products are not reactive under normal circumstances of use Emergency responders must wear the proper personal protective equipment suitable for the situation to which they are responding SYMPTOMS OF OVER EXPOSURE BY ROUTE OF EXPOSURE During soldering operations the most significant routes of exposure are inhalation and contact of the skin and eyes INHALATION If any exposure to these fumes does occur however the main health effect will be irritation of the nose throat and other tissues of the respiratory system Inhalation of copper oxide
10. respirator except single use and quarter mask respirator or Supplied Air Respirator SAR continued on following page LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 5 OF 10 8 EXPOSURE CONTROLS PERSONAL PROTECTION Continued RESPIRATORY PROTECTION continued CONCENTRATION RESPIRATORY EQUIPMENT Up to 50 mg m SAR operated in a continuous flow mode or powered air purifying respirator with dust and mist filter s Up to 100 mg m Full facepiece respirator with high efficiency particulate filter s or full facepiece Self Contained Breathing Apparatus SCBA or full facepiece SAR Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions Positive pressure full facepiece SCBA or positive pressure full facepiece SAR with an auxiliary positive pressure SCBA Escape Full facepiece respirator with high efficiency particulate filter s or escape type SCBA EYE PROTECTION Safety glasses When these products are used in conjunction with soldering wear safety glasses goggles or face shield with filter lens of appropriate shade number per ANSI Z49 1 1988 Safety in Welding and Cutting as necessary HAND PROTECTION Wear gloves for routine industrial use When these products are used in conjunction with soldering wear gloves that protect from sparks and flame per ANSI Z249 1 1988 Safety in Welding and Cutting as necessary BODY PROTECTION Use body protection appropriate for task i e
11. the presence of an ignition source UEL the highest percent of vapor in air by volume that will explode or ignite in the presence of an ignition source TOXICOLOGICAL INFORMATION Human and Animal Toxicology Possible health hazards as derived from human data animal studies or from the results of studies with similar compounds are presented Definitions of some terms used in this section are LDsp Lethal Dose solids amp liquids which kills 50 of the exposed animals LCs Lethal Concentration gases which kills 50 of the exposed animals ppm concentration expressed in parts of material per million parts of air or water mg m concentration expressed in weight of substance per volume of air mg kg quantity of material by weight administered to a test subject based on their body weight in kg Other measures of toxicity include TDLo the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom TDo LDLo and LDo or TC TCo LCLo and LCo the lowest dose or concentration to cause lethal or toxic effects Cancer Information The sources are IARC the International Agency for Research on Cancer NTP the National Toxicology Program RTECS the Registry of Toxic Effects of Chemical Substances OSHA and CAL OSHA IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4 Subrankings 2A 2B etc are also used Other Information BEI ACGIH Biological
12. Not applicable CANADIAN ENVIRONMENTAL PROTECTION ACT CEPA PRIORITIES SUBSTANCES LISTS The components of these products are not on the CEPA Priorities Substances Lists CANADIAN WHMIS SYMBOLS For plastic core D2B Poisonous and Infectious Material Other Toxic Effects LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 9 OF 10 16 OTHER INFORMATION DATE OF PRINTING August 26 2010 This Material Safety Data Sheet is offered pursuant to OSHA s Hazard Communication Standard 29 CFR 1910 1200 Other government regulations must be reviewed for applicability to these products The information contained herein relates only to the specific product If the product is combined with other materials all component properties must be considered To the best of the Harris Products Group knowledge the information and recommendations contained in this publication are reliable and accurate as of the date of issue However accuracy suitability or completeness are not guaranteed and no warranty guarantee or representation expressed or implied is made by Harris Products Group as to the absolute correctness or sufficiency of any representation contained in this and other publications Harris Products Group assumes no responsibility in connection therewith nor can it be assumed that all acceptable safety measures may not be required under particular or exceptional conditions or circumstances Data may be changed from time to time Be sure to
13. Y INFORMATION ADDITIONAL U S REGULATIONS U S SARA REPORTING REQUIREMENTS The components of these products are subject to the reporting requirements of Sections 302 304 and 313 of Title Ill of the Superfund Amendments and Reauthorization Act as follows CHEMICAL NAME SARA 302 SARA 304 SARA 313 40 CFR 355 Appendix A 40 CFR Table 302 4 40 CFR 372 65 Not applicable Not applicable Not applicable Yes fume or dust Yes Yes No Yes Yes U S SARA THRESHOLD PLANNING QUANTITY There are no specific Threshold Planning Quantities for the components of this product The default Federal MSDS submission and inventory requirement filing threshold of 10 000 Ibs 4 540 kg therefore applies per 40 CFR 370 20 U S TSCA INVENTORY STATUS The components of these products are listed on the TSCA Inventory U S CERCLA REPORTABLE QUANTITY RQ Silver 1 000 lbs 454 kg Copper 5000 Ibs 2270 kg Nickel 100 lbs 45 4 kg Zinc 1000 lbs 454 kg Antimony 5000 Ibs 2270 kg Note No reporting is required if the diameter of the metal equals or exceeds 100 micrometers U S STATE REGULATORY INFORMATION The components of these products are covered under specific State regulations as denoted below Alaska Designated Toxic and Hazardous Substances Copper Fume Dust amp Mist Nickel Tin Antimony compounds Silver Massachusetts Substance List Copper Nickel Tin Zinc Antimony and Silver Michigan Critical Material
14. and zinc oxide components of this product fumes can cause metal fume fever Initial symptoms of metal fume fever can include a metallic or sweet taste in the mouth dryness or irritation of the throat and coughing Later symptoms after 4 48 hours can include sweating shivering headache fever chills thirstiness muscle aches nausea vomiting weakness and tiredness Repeated over exposures via inhalation to the dusts or fumes generated by these products during soldering operations may have adverse effects on the lungs with possible pulmonary edema and emphysema life threatening lung injuries Exposure to large quantities of the plastic core component of these products may cause irritation of the nose and respiratory system Repeated or prolonged inhalation of Rosin a component of some of the plastic core of these products can cause allergy like reactions i e wheezing and asthma CONTACT WITH SKIN or EYES Contact of the wire form of these products with skin is not anticipated to be irritating Symptoms of skin over exposures to the fumes or rosin core of these products may include irritation and redness prolonged or repeated skin over exposures may lead to dermatitis Contact of the liquid core of these products with the skin can cause allergic reactions i e rashes and inflammation of the skin Contact with the wire form of these products can be physically damaging to the eye Fumes generated during soldering operations can be irritating
15. copper compounds and a variety of metal oxides When the plastic core is heated the solvent will OTHER evaporate and the rosin core may be degraded to produce aliphatic aldehydes k acids and terpines The molten material can present a significant thermal See Section 16 for hazard to fire fighters Definition of Ratings Explosion Sensitivity to Mechanical Impact Not sensitive Explosion Sensitivity to Static Discharge Not sensitive SPECIAL FIRE FIGHTING PROCEDURES Not applicable 6 ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE Not applicable PART Ill Howcan prevent hazardous situations from occurring 7 HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES As with all chemicals avoid getting these products ON YOU or IN YOU Wash hands after handling these products Do not eat or drink while handling this material Use ventilation and other engineering controls to minimize potential exposure to these products STORAGE AND HANDLING PRACTICES All employees who handle this material should be trained to handle it safely Avoid breathing fumes of these products during soldering operations Packages of these products must be properly labeled If these products are used during soldering operations it is recommended that the requirements of the Federal Occupational Safety and Health Welding and Cutting Standard 29 CFR 1910 Subpart Q and the safety standards of the American National Standards Institute for welding and cu
16. ic levels by marine life COPPER Copper may concentrate to toxic level in the food chain SILVER Solubility Insoluble in water Many silver salts are only slightly soluble and so silver cations will rapidly be reduced to lower levels The Biological Half Life for silver is a few days for animals and up to 50 days for humans TIN Solubility Insoluble in water ZINC Solubility Insoluble in water Biological Half Life for normal humans 162 500 days Bioconcentration The Bioconcentration Factor in edible portions of Crassostrea virgina adult oyster is 16 700 total zinc EFFECT OF MATERIAL ON PLANTS or ANIMALS Heavy metal toxicity effects on plants may result in poor plant growth poor appearance and loss of plant vitality This material may be harmful to animal life Specific data on test animals are available but are not presented in this Material Safety Data Sheet EFFECT OF CHEMICAL ON AQUATIC LIFE Discharge of these products into water may cause local heavy metal contamination and may cause permanent contamination of the bottom of the affected body of water All work practices must minimize potential or actual releases to the environment The following aquatic toxicity data are available for the components of these products COPPER ZINC Odorless zinc poisoning causes inflamed gills in fish Laboratory Copper is concentrated by plankton by 1000 or more Copper may studies of Atlantic salmon rainbow trout carp and goldfish have show
17. led liquid with inert materials If molten material is released allow it to cool before clean up Place in a suitable container Consult Material Safety Data Sheet before use WARNING PROTECT yourself and others Read and understand this information FUMES AND GASES can be hazardous to your health ARC RAYS can injure your eyes and burn skin ELECTRIC SHOCK can kill HEAT RAYS INFRARED RADIATION from flame or hot metal can injure eyes e Before use read and understand the manufacturer s instructions Material Safety Data Sheets MSDSs and your employer s safety policies e Keep your head out of the fumes e Use enough ventilation exhaust at the arc or both to keep fumes and gases from your breathing zone and the general area e FOR MAXIMUM SAFETY BE CERTIFIED FOR AND WEAR A RESPIRATOR AT ALL TIMES WHEN WELDING OR BRAZING e Wear correct eye ear and body protection e Do not touch live electrical parts e See American National Standard 249 1 Safety in Welding Cutting and Allied Processes published by the American Welding Society 550 N W LeJeune Road Miami Florida 33126 OSHA Safety and Health Standards 29 CFR 1910 available from the U S Government Printing Office Superintendent office P O Box 371954 Pittsburgh PA 15250 7954 DO NOT REMOVE THIS INFORMATION ADDITIONAL CANADIAN REGULATIONS CANADIAN DSL NDSL INVENTORY STATUS The components of these products are on the DSL Inventory OTHER CANADIAN REGULATIONS
18. llergen and can cause respiratory and skin reactions i e asthma rashes and welts Rare cases of allergic contact dermatitis have been reported in people working with copper dust Nickel is also in some of these product and has been reported to cause sensitization effects in sensitive individuals however due to the low concentration in the product this is not anticipated to be a significant hazard REPRODUCTIVE TOXICITY INFORMATION Listed below is information concerning the effects of these products and their components on the human reproductive system Mutagenicity These products are not reported to produce mutagenic effects in humans Animal mutation data are available for Nickel a component of these products these data were obtained during clinical studies on specific animal tissues exposed to high doses of this compound Embryotoxicity These products are not reported to produce embryotoxic effects in humans Teratogenicity These products are not reported to cause teratogenic effects in humans Clinical studies on test animals exposed to relatively high doses of Copper and Nickel a component of these products indicate teratogenic effects Reproductive Toxicity These products are not reported to cause reproductive effects in humans Clinical studies on test animals exposed to relatively high doses of Copper a component of these products indicate adverse reproductive effects A mutagen is a chemical which causes permanent changes to gene
19. n concentrate to toxic level in the food chain avoidance reactions by these fish to zinc in water SILVER 0 1 ppm is toxic to bacteria and aquatic life Discharge into marine waters should not exceed 1 20 of 96 hour LC50 0 25 0 025 mg kg day LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 7 OF 10 13 DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL Waste disposal must be in accordance with appropriate Federal State and local regulations These products if unaltered by use may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority EPA WASTE NUMBER Wastes of these products should be analyzed for Toxicity Characteristic Leach Procedure chemicals as follows Silver D011 Regulated Level 5 0 mg L 14 TRANSPORTATION INFORMATION THIS MATERIAL IS NOT HAZARDOUS Per 49 CFR 172 101 BY THE U S DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME HAZARD CLASS NUMBER and DESCRIPTION UN IDENTIFICATION NUMBER PACKING GROUP Not applicable DOT LABEL S REQUIRED Not applicable NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER 2000 Not applicable MARINE POLLUTANT No component of this product is designated as a marine pollutant by the Department of Transportation 49 CFR 172 101 Appendix B TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS This material is not considered as dangerous goods per regulations of Transport Canada 15 REGULATOR
20. or representation expressed or implied is made by Harris Products Group as to the absolute correctness or sufficiency of any representation contained in this and other publications Harris Products Group assumes no responsibility in connection therewith nor can it be assumed that all acceptable safety measures are contained in this and other publications or that other or additional measures may not be required under particular or exceptional conditions or circumstances Data may be changed from time to time PART What is the material and what do need to know in an emergency 1 PRODUCT IDENTIFICATION TRADE NAME AS LABELED LEAD FREE SOLDERS STAY BRITE STAY BRITE ROSIN CORE STAY BRITE 8 STAY SAFE 50 BRIDGIT SPEEDY NICK 85 15 95 5 amp 95 5 ROSIN CORE CHEMICAL NAME CLASS Solder Alloy SYNONYMS Not Applicable PRODUCT USE Metal Soldering DOCUMENT NUMBER 0125 SUPPLIER MANUFACTURER S NAME HARRIS PRODUCTS GROUP ADDRESS 4501 Quality Place Mason Ohio 45040 EMERGENCY PHONE CHEMTREC 1 800 424 9300 BUSINESS PHONE 513 154 2000 FAX 513 754 8778 DATE OF PREPARATION August 13 2010 2 NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS prooucrnane ag sd Sd SS dS SY moar o f oos ames l a OOO oa C a A E a C Bee E E a A A E nee PCS swere soso OOOO OOO l e CS savemmerrosncone sass OO f e oO o E A E A a e E a pees 0s fess amsenoswcone so 50 __ LEAD FREE SOLDERS MSDS EFFECTIVE DATE
21. owing human toxicological data are available for the components of these products Other data for animals are available but are not presented in this Material Safety Data Sheet SILVER COPPER TCLo inhalation human 1 mg m TDLo oral human 120 pg kg gastrointestinal tract effects SUSPECTED CANCER AGENT The components of these products are listed as follows COPPER EPA D Not Classifiable as to Human Carcinogenicity NICKEL ELEMENTAL METAL IARC 2B Possibly Carcinogenic to Humans MAK 1 Substances which Cause Cancer in Man NIOSH X Carcinogen Defined with no Further Categorization NTP R Reasonably Anticipated to be a Human Carcinogen ACGIH TLV A5 Not Suspected as a Human Carcinogen SILVER EPA D Not Classifiable as to Human Carcinogenicity ZINC EPA D Not Classifiable as to Human Carcinogenicity inadequate human and animal evidence of carcinogenicity or no data available The other components of these products are not found on the following lists FEDERAL OSHA Z LIST NTP CAL OSHA IARC and therefore are not considered to be nor suspected to be cancer causing agents by these agencies LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 6 OF 10 11 TOXICOLOGICAL INFORMATION Continued IRRITANCY OF PRODUCT The fumes of these products generated during soldering operations can be irritating to contaminated skin and eyes SENSITIZATION TO THE PRODUCT Some of these products contain Rosin which is an a
22. running water Use sufficient force to open eyelids Have victim roll eyes Minimum flushing is for 15 minutes If molten solder contaminates the eyes immediately begin decontamination with running water Minimum flushing is for 15 minutes Victim must seek immediate medical attention INHALATION If fumes of these products are inhaled remove victim to fresh air If necessary use artificial respiration to support vital functions INGESTION If swallowed call physician immediately Do not induce vomiting unless directed by medical personnel Rinse mouth with water if person is conscious Never give fluids or induce vomiting if person is unconscious having convulsions or not breathing MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Skin disorders may be aggravated by prolonged over exposures to these products RECOMMENDATIONS TO PHYSICIANS Treat symptoms and eliminate over exposure LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 4 OF 10 5 FIRE FIGHTING MEASURES FLASH POINT Not flammable AUTOIGNITION TEMPERATURE Not flammable NFPA RATING FLAMMABLE LIMITS in air by volume FLAMMABILITY Lower LEL Not applicable Upper UEL Not applicable FIRE EXTINGUISHING MATERIALS Water Spray YES Carbon Dioxide YES HEATH REACTIVITY Halon YES Foam YES Dry Chemical YES Other Any ABC Class UNUSUAL FIRE AND EXPLOSION HAZARDS When involved in a fire this material may melt and produce fumes containing tin zinc
23. s Register Copper Pennsylvania Hazardous Substance List Copper Nickel Tin Zinc Antimony and Silver Rhode Island Hazardous Substance List metal soluble compounds California Permissible Exposure Limits for Chemical Contaminants Copper Nickel Tin Antimony and Silver Florida Substance List Copper Fume Dust amp Mist Nickel Tin Zinc Antimony Silver Illinois Toxic Substance List Copper Nickel Zinc Antimony and Silver Kansas Section 302 313 List Copper Nickel Zinc Antimony and compounds LEAD FREE SOLDERS MSDS Nickel Antimony Silver and Zinc Minnesota List of Hazardous Substances Copper Dust amp Mists Nickel Tin Antimony and compounds Silver Missouri Employer Substance List Antimony and Silver New Jersey Right to Know Hazardous Substance List Copper Nickel Tin Zinc Antimony and Silver North Dakota List of Hazardous Chemicals Reportable Quantities Copper Nickel Zinc Antimony and Silver Information Toxic Copper Nickel Tin Copper Fume Dust amp Mist Nickel Tin Zinc Antimony and compounds Silver Texas Hazardous Substance List Copper Fume Nickel and Antimony Silver metal and soluble compounds West Virginia Hazardous Substance List Copper Fume Nickel and Antimony Silver metal and soluble compounds Wisconsin Toxic and Hazardous Substances Copper Fume Nickel and Antimony Silver metal and soluble compounds EFFECTIVE DATE June 21 2002
24. st 1989 STEL 10 fume 15 ceiling 15 PEL min dust DFG MAK Rene TWA 1 5 Respirable Fraction 5 dust Carcinogen EPA D respirable dust Vacated 1989 PEL NE Not Established See Section 16 for Definitions of Terms Used NOTE 1 The ACGIH has an established exposure limit for Brazing Fumes Not Otherwise Classified The Threshold Limit Value is 5 mg m NIOSH classifies brazing fumes as carcinogens NOTE 2 ALL WHMIS required information is included in appropriate sections based on the ANSI Z400 1 1998 format This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 2 OF 10 2 NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS Continued ROSIN CORE COMPOSITION CHEMICAL NAME CAS EXPOSURE LIMITS IN AIR OTHER Cee oe te ES mg m mg m mg m ngn mg mg m WW Rosin 8050 09 7 Sensitizer DFG MAK The following exposure reduce Danger of sensitization of limits are for Rosin Core exposure as the skin Solder decomposition low as products as resin acids possible colophony NE Not Established See Section 16 for Definitions of Terms Used NOTE 1 The ACGIH has an established exposure limit for Brazing Fumes Not Otherwise Classified The Threshold Limit Value is 5 mg m NIOSH classifies brazing fumes as carcinogens NOTE 2 ALL WHMIS required
25. tic material DNA such that the changes will propagate through generational lines An embryotoxin is a chemical which causes damage to a developing embryo i e within the first eight weeks of pregnancy in humans but the damage does not propagate across generational lines A teratogen is a chemical which causes damage to a developing fetus but the damage does not propagate across generational lines A reproductive toxin is any substance which interferes in any way with the reproductive process BIOLOGICAL EXPOSURE INDICES Currently Biological Exposure Indices BEls have not been determined for the components of these products 12 ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION ENVIRONMENTAL STABILITY These products if released into the environment may cause local heavy metal contamination with potential impact on plant animal and aquatic life The metal is not biodegradable and will persist in the environment for an extended period of time The following environmental data are available for the components of these products ANTIMONY Solubility Insoluble in water Antimony tends to hydrolyze and precipitate out as an oxide In experiments the approximate half life for antimony initial phase was 40 hour for antimony trioxide and 30 hour for antimony dust for the second phase half lives of 20 40 days for antimony trioxide and antimony dust were observed Antimony can be accumulated to tox
26. to the skin and eyes Symptoms of eye over exposure include pain redness irritation and tearing Contact with the molten core solder will burn contaminated skin or eyes SKIN ABSORPTION No component of these products can be absorbed through the skin INGESTION Not applicable LEAD FREE SOLDERS MSDS EFFECTIVE DATE June 21 2002 PAGE 3 OF 10 3 HAZARD IDENTIFICATION Continued INJECTION Though not a likely route of occupational exposure for these products injection of these products via punctures or HAZARDOUS MATERIAL IDENTIFICATION SYSTEM lacerations in the skin may cause local reddening tissue swelling and discomfort HEALTH EFFECTS OR RISKS FROM EXPOSURE An HEALTH Explanation in Lay Terms Symptoms associated with over exposure to these products and the fumes generated during soldering operations are as follows ACUTE Inhalation of copper oxide and zinc oxide fumes can FLAMMABILITY cause metal fume fever Inhalation of large amounts of particulates generated by these products during metal processing operations can result in pneumoconiosis a disease of the lungs Contact with the molten solder will burn contaminated skin or eyes REACTIVITY eer CHRONIC Chronic skin over exposure to the fumes of these products generated during soldering operations may produce dermatitis red inflamed skin Chronic skin contact or ingestion of dusts salts or fumes of Silver a component of some these PROTECTIVE EQUIPMENT
27. tting ANSI 249 1 be followed 8 EXPOSURE CONTROLS PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS Use with adequate ventilation to ensure exposure limits are below those provided in Section 2 Composition and Information on Ingredients Use a mechanical fan or vent area to outside Prudent practice is to ensure eyewash safety shower stations are available near areas where these products are used RESPIRATORY PROTECTION Maintain airborne contaminant concentrations below exposure limits listed in Section 2 Composition and Information on Ingredients If respiratory protection is needed i e a Weld Fume Respirator or Air Line Respirator for welding in confined spaces U S Federal OSHA Standard 29 CFR 1910 134 applicable U S State regulations or the Canadian CSA Standard Z94 4 93 and applicable standards of Canadian Provinces Respiratory Protection is recommended to be worn during welding operations Oxygen levels below 19 5 are considered IDLH by OSHA In such atmospheres use of a full facepiece pressure demand SCBA or a full facepiece supplied air respirator with auxiliary self contained air supply is required under OSHA s Respiratory Protection Standard 1910 134 1998 For additional information the following respirator selection guidelines from NIOSH for Tin the main component of these products are provided CONCENTRATION RESPIRATORY EQUIPMENT Up to 10 mg m Dust and mist respirator Up to 20 mg m Dust and mist
28. with water 2 materials that are unstable but do not detonate or which can react violently with water 3 materials that can detonate when initiated or which can react explosively with water 4 materials that can detonate at normal temperatures or pressures NATIONAL FIRE PROTECTION ASSOCIATION Health Hazard 0 material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials 1 materials that on exposure under fire conditions could cause irritation or minor residual injury 2 materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury 3 materials that can on short exposure could cause serious temporary or residual injury 4 materials that under very short exposure causes death or major residual injury Flammability Hazard and Reactivity Hazard Refer to definitions for Hazardous Materials Identification System LEAD FREE SOLDERS MSDS FLAMMABILITY LIMITS IN AIR Much of the information related to fire and explosion is derived from the National Fire Protection Association NFPA Flash Point Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air Autoignition Temperature The minimum temperature required to initiate combustion in air with no other source of ignition LEL the lowest percent of vapor in air by volume that will explode or ignite in
29. x products can result in a condition known as Argyria This condition is marked by a bluish appearance of the skin and eyes The liquid er RESPIRATORY HANDS BODY core of these products contains a sensitizer prolonged or repeated jes pesmom Hos f eoor EYES exposure to this plastic can cause respiratory and skin allergy like reactions Nickel a component of some of these products is a suspect carcinogen Refer to Section 11 Toxicological Information Section 8 Section 8 for further information TARGET ORGANS For Fumes ACUTE Skin and eyes For routine industrial applications for rods respiratory system CHRONIC Skin respiratory system See Section 16 for Definition of Ratings PART li What should I do if a hazardous situation occurs 4 FIRST AID MEASURES Victims of chemical exposure must be taken for medical attention Rescuers should be taken for medical attention if necessary Take copy of label and MSDS to health professional with victim SKIN EXPOSURE If the fumes or plastic core of the product irritates the skin begin decontamination with running water Victim must seek medical attention if any adverse reaction occurs If molten solder contaminates the skin immediately begin decontamination with cold running water Minimum flushing is for 15 minutes Victim must seek immediate medical attention EYE EXPOSURE If the product s fumes or plastic core enters the eyes open victim s eyes while under gentle
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