Sharp MX-M1100 MSDS
Contents
1. Environmental Effects Not toxic to aquatic organisms Estimated from the other product containing similar material Specific Hazards Dust explosion like most finely divided organic powders Directive 1999 45 EC Europe Not classified as dangerous 4 FIRST AID MEASURES Route s of Entry Inhalation Skin Ingestion Yes No Possible but very unusual Inhalation Remove to fresh air If symptoms occur consult medical personnel Skin Contact Wash with soap and water for 15 minutes or until particle is removed If irritation does occur consult medical personnel Eye Contact Flush eyes immediately with water for 15 minutes If irritation does occur consult medical personnel Ingestion Rinse with water and drink several glasses of water If irritation or discomfort does occur consult medical personnel 5 FIRE FIGHTING MEASURES Extinguishing Media Water COs foam and dry chemicals Special Fire Fighting Procedures None Fire and Explosion Hazards Toner material like most finely divided organic powders may form an explosive mixture 6 ACCIDENTAL RELEASE MEASURES Personal Precautions None Environmental Precautions None Methods for Cleaning Up Wipe off with paper or cloth Do not use vacuum cleaner when a large amount is released It like most finely divided organic powders is capable of creating a dust explosion 7 HANDLING AND STORAGE Handling Technical Measures None Precautions None Safe Handl2. No data Density g cm 1 1 bulk density 0 4 Solubility in Water Negligible 10 STABILITY AND REACTIVITY Stability Stable Hazardous Reactions Dust explosion like most finely divided organic powders Conditions to Avoid Materials to Avoid Electric discharge throwing into fire Oxidizing Materials Hazardous Decomposition Products CO CO and NOx Further Information None 11 TOXICOLOGICAL INFORMATION Acute Toxicity Ingestion oral Inhalation Eye irritation Skin irritation Skin sensitizer Mutagenicity Carcinogenicity LD5 gt 2000mg kg Rats gt LC5o gt 5 0mg L Not an irritant Rabbits Not an irritant Rabbits No sensitization Negative Ames Test In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen possible human carcinogen This classification is given to chemicals for which there is inadequate human evidence but sufficient animal evidence on which to base an opinion of carcinogenicity The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung Studies performed in animal models other than rats did not show any association between carbon black and lung tumors Moreover a two year cancer bioassay using a typical toner preparation where carbon black is bound in a resin matrix demonstrated no association between toner exposure and tumor d
3. EU Information 1999 45 EC and 67 548 EEC Symbol amp Indication Not required R Phrase Not required 76 769 EEC All chemical substances in this product comply with all applicable rules or order under 76 769 EEC 16 0THER INFORMATION NFPA Rating USA Health 1 Flammability 1 Reactivity 0 WHMIS Legislation Canada This product is not a controlled product List of R phrases R11 Highly flammable References IARC 1996 IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans Vol 65 Printing Process And Printing Inks Carbon Black and Some Nitro Compounds Lyon pp 149 261 H Muhle B Bellmann O Creutzenberg C Dasenbrock H Ernst R Kilpper J C MacKenzie P Morrow U Mohr S Takenaka and R Mermelstein 1991 Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats Fundamental and Applied Toxicology 17 pp 280 299 The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions However all materials may present unknown hazards and should be used with caution Although certain hazards are described herein we do not guarantee that these are the only hazards which exist
4. SHARP MATERIAL SAFETY DATA SHEET Page 1 4 Date Issued Mar 1 2007 MSDS No F 01491 1 PRODUCT AND COMPANY IDENTIFICATION Product Name MX 850GT MX 850NT MX 850AT MX 850FT MX 850CT Black Toner Supplier Identification Sharp Corporation 22 22 Nagaike cho Abeno ku Osaka Japan Local suppliers are listed below Please contact the nearest supplier for additional information Area Country Name and Telephone Number U S A Sharp Electronics Corporation Sharp Plaza Mahwah NJ North Telephone number for information 1 800 237 4277 Am rica Emergency telephone number 1 800 255 3924 Canada Sharp Electronics of Canada Ltd Telephone number for information 905 890 2100 Emergency telephone number 1 800 255 3924 Australia Sharp Corporation of Australia PTY Ltd Oceania No1 Huntingwood Drive Huntingwood Blacktown N S W Telephone number for information 1300 13 50 22 Germany Sharp Electronics Europe GMBH Sonninstrasse 3 20097 Hamburg Telephone number to access MSDS 040 2376 2185 For more information 040 2376 2613 United Sharp Electronics U K Ltd Kingdom Telephone number for information 08705 274 277 France Sharp Electronics France S A Telephone number for information 01 49 90 34 00 Austria Sharp Electronics GMBH Europe Telephone number for information 01 727 19 0 Italy Sharp Electronics Italy S P A Telephone number for information 02895951 Spa
5. evelopment in rats SHARP MATERIAL SAFETY DATA SHEET Page 4 4 Date Issued Mar 1 2007 MSDS No F 01491 Chronic Effect In a study in rats of chronic inhalation exposure to a typical toner a mild to moderate degree of lung fibrosis was observed in 92 of the rats in the high concentration 16mg m exposure group and a minimal to mild degree of fibrosis was noted in 22 of the animals in the middle 4mg m exposure group but no pulmonary change was reported in the lowest 1mg m exposure group the most relevant level to potential human exposures 12 ECOLOGICAL INFORMATION Ecotoxicity On available data toner is not harmful to aquatic organisms Estimated from the other product containing similar material 13 DISPOSAL CONSIDERATIONS Waste from Residues Waste material may be dumped or incinerated under conditions which meet all federal state and local environmental regulations Contaminated Packaging Waste may be disposed or incinerated under conditions which meet all federal state and local environmental regulations 14 TRANSPORT INFORMATION UN Classification None Not classified as hazardous for transport 15 REGULATORY INFORMATION US Information TSCA Toxic Substances Control Act All chemical substances in this product comply with all applicable rules or order under TSCA SARA Superfund Amendments and Reauthorization Act Title III 302 Extreme Hazardous Substance None 311 312 Hazard Classification None
6. in Sharp Electronics Espana S A Telephone number for information 93 581 97 00 Netherlands Sharp Electronics Benelux B V Telephone number for information 30 6359500 Sweden Sharp Electronics Nordic AB Telephone number for information 08 634 36 00 Switzerland Sharp Electronics Schweiz AG Telephone number for information 01 846 6111 Middle U A E Sharp Middle East FZE l l East P O Box 17115 Jebel Ali Dubai Telephone number for information 04 815311 2 COMPOSITION INFORMATION ON INGREDIENTS Substance Preparation X Ingredient CAS No Proportion OSHA PEL ACGIH TLV MAK TWA NOHSC TWA Polyester resin1 Confidential 45 55 Not listed Not listed Not listed Not listed Polyester resin2 Confidential 30 35 Not listed Not listed Not listed Not listed Carbon black 1333 86 4 5 10 3 5mg m 3 5mg m Not listed 3mg m Iron oxide 1309 38 2 1 5 Not listed Not listed Not listed Not listed Polypropylene Confidential 1 5 Not listed Not listed Not listed Not listed Charge control agent Confidential lt 2 Not listed Not listed Not listed Not listed SHARP MATERIAL SAFETY DATA SHEET Page 2 4 Date Issued Mar 1 2007 MSDS No F 01491 3 HAZARDS IDENTIFICATION Most Important Hazards and Effects of the Products Human Health Effects There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner When used as intended according to instructions studies do not indicate any symptoms of fibrosis will occur
7. ing Advice Use of a dust mask is recommended when handling a large quantity of toner or during long term exposure as with any non toxic dust Try not to disperse the particles Storage Technical Measures None Storage Conditions Keep container closed and Store in a cool and dry place Keep out of the reach of children Incompatible Products None SHARP MATERIAL SAFETY DATA SHEET Page 3 4 Date Issued Mar 1 2007 MSDS No F 01491 8 EXPOSURE CONTROLS PERSONAL PROTECTION Engineering Measures Ventilation Not required under intended use Exposure Limit Values OSHA PEL USA ACGIH TLV USA Personal Protective 15mg m Total Dust 5mg m Respirable Dust i 10mg m Total Dust 3mg m Respirable Dust Equipment Respiratory Protection Not required under intended use Hand Protection Eye Protection Skin Protection Not required under intended use Not required under intended use Not required under intended use Other Protective Equipment Use of a dust mask and goggles are recommended when handling a large quantity of toner or during long term exposure as with any non toxic dust 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Solid Form Powder Color Black Odor odorless Ph Not applicable Boiling Melting Point Not applicable Softening Point C 100 130 Flash Point C Not applicable Ignition Point C gt 350 Explosion Properties
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