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        Sharp FO-4400 MSDS
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1.    Preparation community provisions   Waste may be disposed or incinerated under conditions which meet all federal  state and    local environmental regulations     Contaminated Packaging  Waste may be disposed or incinerated under conditions which meet all federal  state and local    SHARP    Date Revised  Apr  8  2008  Date Issued  May  28 1998  MATERIAL SAFETY DATA SHEET  4 4     MSDS       No  B 1020    environmental regulations   Precautions  Do not throw the toner cartridge or toner into an open flame  The hot toner may scatter and cause burns or  other damage   Section 14  Transport Information  Special Precautions  None  Information on Code and Classifications According to International Regulations  UN Classification  None             Section 15  Regulatory Information  US Information  Information on the label  Not required  TSCA Toxic Substances Control Act    All chemical substances in this product comply with all applicable rules or order under TSCA   SARA Superfund Amendments and Reauthorization Act  Title III  302 Extreme Hazardous Substance  None  311 312 Hazard Categories  None  313 Reportable Ingredients  None  California Proposition 65   This product contains no chemical substances subject to California Proposition 65   EU Information  Information on the label  1999 45 EC and 67 548 EEC     Symbol  amp  Indication   Not required  R phrase   Not required  S phrase   Not required  76 769 EEC   All chemical substances in this product comply with all applicable r
2. Entry  Eye contact  inhalation  ingestion  Information    Inhalation  If symptoms are experienced  remove source of contamination or move victim to fresh air and obtain medical advice     SHARP    Date Revised  Apr  8  2008  Date Issued  May  28 1998   MATERIAL SAFETY DATA SHEET  2 4   MSDS       No  B 1020    Skin Contact  Flush with gently flowing water  preferably lukewarm  and soap for 15 minutes or until particle is removed   If irritation does occur  obtain medical advice    Eye Contact  Do not allow victim to rub eye s   Flush with gently flowing water  preferably lukewarm  for 15 minutes or until  particle is removed  Have victim look right and left  and  then up and down  If irritation does occur  obtain medical  attention  DO NOT attempt to manually remove anything stuck to the eye s     Ingestion  If irritation or discomfort occurs  obtain medical attention immediately    Note to Physician  None       Section 5  Fire Fighting Measures       Suitable Extinguishing Media  CO2  water spray  foam and dry chemical   Extinguishing Media to Avoid  Full water jet   Special Firefighting Procedures  None   Fire and Explosion Hazards  If dispersed in air  like most finely divided organic powders  may form an explosive mixture   Protection of Firefighters  Use self contained breathing apparatus  SCBA         Section 6  Accidental Release Measures       Personal Precautions  None   Environmental Precautions  None   Methods for Cleaning Up  Wipe off with paper or cloth  DO NOT u
3. No  215 609 9 for Carbon black  Apr    23   2003 Change   Section 8   DFG MAK  GER    6mg m3 4mg m3    SHARP    Date Revised  Apr  8  2008  Date Issued  May  28 1998    MATERIAL SAFETY DATA SHEET  5 4   MSDS       No  B 1020    Oct    7   2002 Addition   Contact information  Change   Section 15 EU information      88 379   EEC        1999   45   EC     July   22 2002 Addition   Product Name FO 44ND   FO 50ND    
4. SHARP    Date Revised  Apr  8  2008  Date Issued  May  28 1998   MATERIAL SAFETY DATA SHEET  1 4   MSDS       No  B 1020       Section 1  Product and Company Identification       Product Name  Toner Cartridge of FO 47ND   FO 47DC   FO 47DCCN   FO 44ND  FO 50ND   FO 59DC   DUNT 455BSCZZ    Supplier Identification   Sharp Corporation    22 22 Nagaike cho  Abeno     ku  Osaka  Japan    Local suppliers are listed below  Please contact the nearest supplier for additional information                                                                    Area Country Name and Telephone Number  North U S A Sharp Electronics Corporation  America Telephone number for information  1 800 237 4277  Emergency telephone number   1 800 255 3924  Canada Sharp Electronics of Canada Ltd   Telephone number for information   905 890 2100  Emergency telephone number   1 800 424 9300  Oceania Australia AUSTRALIA  SHARP CORPORATION OF AUSTRALIA PTY  LTD     Phone  02 9830 4600  1800 807 820  New Zealand NEW ZEALAND  SHARP CORPORATION OF NEW ZEALAND LTD     Phone  09 634 2059  Europe Germany Sharp Electronics  Europe  GMBH  Sonninstrasse 3  20097 Hamburg  Telephone number to access MSDS   040 2376 2185  For more information   040 2376 2613  United Sharp Electronics  U  K   Ltd   Kingdom Telephone number for information   01923 474013  France Sharp Electronics France S A   Telephone number for information   01 49 90 34 00  Austria Sharp Electronics GMBH  Telephone number for information   01 727 19 0  Ita
5. able    pH  Not applicable    SHARP    MATERIAL SAFETY DATA SHEET  3 4     No  B 1020    Partition Coefficient  n Octanol Water  Not applicable     Based on data for other products with similar ingredients     Date Revised  Apr  8  2008  Date Issued  May  28 1998    MSDS          Section 10  Stability and Reactivity       Stability  Stable X    Unstable      Hazardous Reactions  Dust explosion  like most finely divided organic powders   Conditions to avoid  Electric discharge  throwing into fire    Materials to Avoid  Oxidizing materials    Hazardous Decomposition Products  CO  CO2       Section 11  Toxicological Information       Health Effects from Exposure  No symptoms expected with intended use   Toxicological Data  Acute Toxicity   Inhalation  LC50 mg l    gt 0 74  Rat 4hour     This was the highest attainable concentration    Ingestion oral   LD50 mg kg    gt 5000  Rat     Dermal  LD50 mg kg    gt 2000  Rat     Eye irritation  Non irritant  Rabbit     Skin irritation  Non irritant  Rabbit     Skin sensitizer  No data available  Mutagenicity  Negative    AMES test       Based on data for other products with similar ingredients   Local Effects  see Chronic Toxicity or Long term Toxicity    Chronic Toxicity or Long Term Toxicity  Prolonged inhalation of excessive dust may cause lung damage  It is attributed to     lung overloading     a generic response to excessive amounts of any dust retained in the lungs for a  prolonged interval  Use of this product  as intended  does 
6. ly Sharp Electronics  Italy  S P A   Telephone number for information   02895951  Spain Sharp Electronics  Espana  S A   Telephone number for information   93 581 97 00  Netherlands Sharp Electronics Benelux B V   Telephone number for information   30 6359500  Sweden Sharp Electronics Nordic AB  Telephone number for information   08 634 36 00  Middle U A E  Sharp Middle East FZE  East P O Box 17115 Jebel Ali  Dubai  Telephone number for information   04 815311  Section 2  Ingredients  Ingredients Cas No  Proportion OSHAZ Tables ACGIH TLV IARC DFG MAK GER  Other Limits  Polyester resin Trade Secret  gt 90                Trade secret No  361615  5042 P in New Jersey     Carbon black 1333 86 4 1 5    EEC No  215 609 9    Polyolefin wax 9003 07 0 1 5    Organic pigment Trade Secret 1 5      Trade secret No  361615  5025 P in New Jersey     3 5mg m3 3 5mg m3 2B    Ill 3B    TWA Austl    3 mg m        Section 3  Hazardous Identification       Classification   Not classified as dangerous   1999 45 EC     Most Important Hazards and Effects of the Products    For Human Health  This toner is not classified as a human carcinogen  No symptoms expected with intended use   For the Environment  No data are available on the adverse effects of this product on the environment     For others  None    Specific hazards  Dust explosion  like most finely divided organic powders        Section 4  First Aid Measures       Symptoms of Overexposure  No symptoms expected with intended use     Routes of 
7. not result in inhalation of excessive dust    In a study in rats by chronic inhalation exposure to a typical toner  a mild to moderate degree of lung  fibrosis was observed in 92  of rats in the high concentration 16mg m3  exposure group  and a minimal  to mild degree of fibrosis was noted in 22  of the animals in the middle 4mg m  exposure group  But no  pulmonary change was reported in the lowest 1mg m   exposure group  the most relevant level to    potential human exposures   Carcinogenicity  IARC Monographs  Not listed  NTP USA   Not listed  OSHA Regulated USA   Not listed    In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen  possible human carcinogen   This  evaluation is given to Carbon Black for which there is inadequate human evidence  but sufficient animal  evidence  The latter is based upon the development of lung tumors in rats receiving chronic inhalation    exposures to free carbon black at levels that induce particle overload of the lung     Studies performed in animal models other than rats have not demonstrated an association between carbon  black and lung tumors  Moreover  a two year cancer bioassay using a typical toner preparation containing  carbon black demonstrated no association between toner exposure and tumor development in rats        Section 12  Ecological Information       No data are available on the adverse effects of this material on the environment        Section 13  Disposal Consideration       Appropriate Methods of Disposal 
8. se vacuum cleaner when a large amount is  released  It  like most finely divided organic powders  may create a dust explosion        Section 7  Handling and Storage       Handling  Technical Measures  None  Precautions  None  Safe Handling Advice  Try not to disperse the particles   Storage  Technical Measures  None  Storage Conditions  Keep container closed  Store in a cool and dry place  Keep out of reach of children   Incompatible Products  None       Section 8  Exposure Control Personal Protection       Engineering Measures  Ventilation  None required with intended use   Control Parameters As total dust   OSHA PEL USA   15mg m3  ACGIH TLV USA  10mg m3 DFG MAK GER  4mg m3   Worksafe TWA Austl    10mg m3  Personal Protective Equipment  None required when used as intended in Sharp equipment  For use other than normal customer operating procedures   such as in bulk toner processing facilities   goggles and respirators may be required   Hygiene Measures  Wash hands after handling        Section 9  Physical and Chemical Properties       Appearance   Physical State  Solid Form  Powder Color  Black  Odor  Faint odor Explosion Properties  No data available  Particle Size um   5 15 Density g cms   1 2  bulk density  0 5   Boiling Point  Not applicable Solubility in water  Negligible  Melting Point   C   No data available Oxidizing Properties  No data available  Softening Point   C   120   130   Ignition Temperature   C   450    Flash Point  Not applicable Vapor Pressure  Not applic
9. ules or order under 76 769 EEC   Article 14  2 1  of Directive 1999   45   EC is not applicable to this product   Section 16  Other Information  NFPA Hazard Rating  The National Fire Protection Agency USA   Health  1 Flammability  1 Reactivity  0  HMIS Rating  The National Paint and Coating Association USA   Health  1 Flammability  1 Reactivity  0  Recommended Uses  Toner for Electrophotographic Equipment  Restrictions  This information relates only to the specific material designated as supplied by the manufacturer  This information is  supplied to us by the manufacturer and Sharp offers no warranties as to its accuracy and accepts no responsibilities  for any typographical errors which may appear on these sheets  It is the responsibility of the user to determine the  suitability of this product for each particular use   Literature References   ANSI Z2400 1 1993  ISO 11014 1  Commission Directive 91 155 EEC  IARC 1996   IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans  Vol  65  Printing Process  and Printing Inks  Carbon Black and Some Nitro Compounds  Lyon  pp 149 261  H Muhle  B Bellmann  O Creutzenberg  C Dasenbrock  H Ernst  R Kilpper  J  C  MacKenzie  P Morrow  U Mohr  S Takenaka  and  R Mermelstein 1991  Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats  Fundamental and Applied  Toxicology 17  pp 280 299              Rivision Record    Apr    8   2008 Periodical review      Apr    23   2003 Addition   Section 2   EEC 
    
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