Kodak 1078419 User's Manual
Contents
1. Zinc Graphite Manganese dioxide Zinc Potassium hydroxide Water Graphite 16 Other information The data below reflects current legislative requirements whereas the product in your possession may carry a different version of the label depending on the date of manufacture US Canadian Label Statements CONTAINS Manganese dioxide 1313 13 9 Zinc 7440 66 6 Potassium hydroxide 1310 58 3 Graphite 7782 42 5 WARNING MAY FLAME OR LEAK IF OPENED SHORT CIRCUITED RECHARGED CONNECTED IMPROPERLY OR EXPOSED TO FIRE OR HIGH TEMPERATURES HARMFUL IF SWALLOWED VAPORS FUMES FROM DAMAGED BATTERIES MAY CAUSE RESPIRATORY TRACT IRRITATION DAMAGED BATTERIES MAY CAUSE SKIN AND EYE BURNS FIRST AID If vapours or fumes from vented or leaking battery are irritating to respiratory tract move to fresh air Get medical attention if symptoms occur In case of contact with battery contents liquid or metal immediately flush with plenty of water for at least 15 minutes Get medical attention immediately In case of contact with battery contents liquid or metal immediately remove metal fragments and flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash contaminated clothing before re use Destroy or thoroughly clean contaminated shoes Get medical attention immediately All batteries may be harmful if swallowed Call a physician or poison control center immediately for any ac2. on skin on clothing Wash thoroughly after handling Prevention of Fire and Explosion DO NOT DISASSEMBLE Keep away from heat and flame Do not short circuit Avoid the use of old and new batteries or batteries of varying sizes and types in the same battery assembly The batteries electrical characteristics and capabilities may vary and damage may Material Safety Data Sheet Revision Date 10 08 2007 000000023093 Version 1 2 Oo Print Date 02 13 2009 Page 3 7 result to the batteries or electrical equipment DO NOT RECHARGE Charging may result in electrolyte leakage explosion and or cause the battery to flame Avoid reversing polarity within a device or a battery assembly To do so may cause leakage explosion and or flame Storage Do not store in a manner that allows terminals to short circuit Keep in a dry cool place Keep away from direct sunlight Storage above 21 C 70 F may affect product quality Do not freeze Keep away from water Short circuiting may reduce battery service life Extended short circuiting creates high temperatures in the battery High temperatures can cause leakage explosion and or flame Keep away from incompatible substances see Incompatibility section 8 Exposure controls personal protection Occupational exposure controls Chemical Name Regulatory List Value Type Value Manganese dioxide OSHA Z1 Ceiling Limit Value 5 mg m3 Expressed as Mn ACGIH time weighted average 0 2 m
3. chewed rinse mouth thoroughly with water Notes to physician Hazards Battery ingestions should not be managed in the same way as other small metallic object ingestions eg coins The position and integrity of the battery in the gastrointestinal tract should be assessed and monitored by x ray Leaking batteries may cause necrosis and tissue damage Larger batteries or batteries that lodge in the gastrointestinal tract may have to be removed endoscopically or surgically 5 Fire fighting measures Extinguishing Media Use appropriate agent for adjacent fire Special Fire Fighting Procedures Wear self contained breathing apparatus and protective clothing Fire or excessive heat may produce hazardous decomposition products Hazardous Combustion Products Carbon oxides oxides of manganese oxides of zinc see also Hazardous Decomposition Products section Unusual Fire and Explosion Hazards Fire or high temperatures may cause battery to flame or leak flammable and hazardous vapours Damaged or opened batteries can result in rapid heating and the release of flammable and hazardous vapours 6 Accidental release measures Dispose of in accordance with local regulations see Section 13 Disposal considerations For Large Spills None should be needed 7 Handling and storage Personal precautions If battery has been damaged do not breathe fumes or vapours Do not get battery contents in eyes
4. than or equal to 0 1 is identified as probable possible or confirmed human carcinogen by IARC No component of this product present at levels greater than or equal to 0 1 is identified as a known or anticipated Material Safety Data Sheet Revision Date 10 08 2007 000000023093 Version 1 2 Print Date 02 13 2009 Page 6 7 Kodak U S Occupational Safety and Health Administration OSHA California Prop 65 US US US US US EPA Emergency Planning and Community Right To Know Act EPCRA SARA Title Ill Section 313 Toxic Chemicals 40 CFR 372 65 Supplier Notification Required EPA Emergency Planning and Community Right To Know Act EPCRA SARA Title Ill Section 302 Extremely Hazardous Substance 40 CFR 355 Appendix A Pennsylvania Worker and Community Right to Know Law 34 Pa Code Chap 301 323 Massachusetts Commonwealth s Right to Know Law Appendix A to 105 Code of Massachusetts Regulations Section 670 000 New Jersey Worker and Community Right to Know Act New Jersey Statute Annotated Section 34 5A 5 carcinogen by NTP No component of this product present at levels greater than or equal to 0 1 is identified as a carcinogen or potential carcinogen by OSHA none Manganese dioxide Zinc SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title III Section 302 Manganese dioxide Zinc Potassium hydroxide Water Graphite
5. Material Safety Data Sheet Revision Date 10 08 2007 000000023093 Version 1 2 Oo Print Date 02 13 2009 Page 1 7 1 Identification of the substance preparation and of the company undertaking Product name KODAK Alkaline Battery KAA KAA P Product code 1078419 Supplier EASTMAN KODAK COMPANY 343 State Street Rochester New York 14650 KODAK CANADA INC 6 Monogram Place Suite 200 Toronto Ontario M9R 0A1 For Emergency Health Safety amp Environmental Information call 585 722 5151 USA For other information or to request an MSDS call 800 242 2424 Synonyms None Product Use Battery For consumer and industrial use 2 Hazards identification CONTAINS Manganese dioxide 1313 13 9 Zinc 7440 66 6 Potassium hydroxide 1310 58 3 Graphite 7782 42 5 WARNING MAY FLAME OR LEAK IF OPENED SHORT CIRCUITED RECHARGED CONNECTED IMPROPERLY OR EXPOSED TO FIRE OR HIGH TEMPERATURES HARMFUL IF SWALLOWED VAPORS FUMES FROM DAMAGED BATTERIES MAY CAUSE RESPIRATORY TRACT IRRITATION DAMAGED BATTERIES MAY CAUSE SKIN AND EYE BURNS 3 Composition information on ingredients Weight Components CAS No 30 40 Manganese dioxide 1313 13 9 10 20 Zinc 7440 66 6 5 10 Potassium hydroxide 1310 58 3 1 5 Graphite 7782 42 5 Weight listed is based on approximate percent of the average weight of the battery 38 grams The components in this section may only represent a haza
6. g m3 Expressed as Mn Potassium hydroxide ACGIH Ceiling Limit Value 2 mg m3 Graphite ACGIH time weighted average 2 mg m3 Form of exposure Respirable fraction Z3 Remarks Listed OSHA Z1 time weighted average 5 mg m3 Form of exposure Respirable fraction OSHA Z1 time weighted average 15 mg m3 Form of exposure Total dust Z3 time weighted average 15 millions of particles per cubic foot of air OSHA Z1A time weighted average 2 5 mg m3 Form of exposure Respirable dust Ventilation Supplemental ventilation may be needed in special circumstances to control fumes vapours to an acceptable level Respiratory protection None should be needed Eye protection When handling a damaged battery wear safety glasses with side shields or goggles Hand protection When handling a damaged battery wear impervious gloves 9 Physical and chemical properties Physical form solid Colour not applicable Odour odourless Specific gravity not applicable Material Safety Data Sheet Revision Date 10 08 2007 000000023093 Version 1 2 Oo Print Date 02 13 2009 Page 4 7 Vapour pressure negligible Vapour density not applicable Volatile fraction by weight not applicable Melting point range not applicable Water solubility insoluble pH not applicable Flash point not applicable 10 Stability and reactivity Stability Stable under normal conditions Incompatibility no data available Hazardous deco
7. mposition products None under normal conditions of use Hazardous Polymerization Hazardous polymerisation does not occur 11 Toxicological information Effects of Exposure General advice Since the materials in this battery are sealed in the battery case the potential for exposure to the components of the battery is negligible when the battery is used as directed However technical or electrical abuse of the battery may result in the release of battery contents Contains Manganese dioxide Can cause nervous system damage Inhalation Intact battery Expected to be a low hazard for recommended handling Damaged battery Harmful if inhaled May cause irritation to the mucous membranes and upper respiratory tract Eyes Intact battery Expected to be a low hazard for recommended handling Damaged battery Contact with electrolyte liquid causes burns Airborne dust mist vapor irritating Contact with metal fragments may cause burns or mechanical injury Skin Intact battery Expected to be a low hazard for recommended handling Damaged battery Contact with electrolyte liquid causes burns Contact with metal fragments may cause burns or mechanical injury Harmful if absorbed through skin Vapors or fumes may cause irritation Ingestion All batteries may be harmful if swallowed May cause burns of the gastrointestinal tract if swallowed Data for Potassium hydroxide CAS 1310 58 3 Material Safety Data Sheet Re
8. rd if the integrity of the battery is compromised 4 First aid measures The routine handling and use of intact non damaged batteries is not expected to result in situations that require first aid measures If battery is damaged due to opening cutting crushing overheating improper installation exposure to fire or high temperatures or recharging battery contents may be released Inhalation If vapours or fumes from vented or leaking battery are irritating to respiratory tract move to fresh air Get medical attention if symptoms occur Material Safety Data Sheet Revision Date 10 08 2007 000000023093 Version 1 2 Oo Print Date 02 13 2009 Page 2 7 Eyes In case of contact with battery contents liquid or metal immediately flush with plenty of water for at least 15 minutes Get medical attention immediately Skin In case of contact with battery contents liquid or metal immediately remove metal fragments and flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash contaminated clothing before re use Destroy or thoroughly clean contaminated shoes Get medical attention immediately Ingestion All batteries may be harmful if swallowed Call a physician or poison control center immediately for any actual or suspected ingestion If swallowed DO NOT induce vomiting Batteries may lodge in the throat or digestive tract and fragment If battery was leaking or was
9. tual or suspected ingestion If swallowed DO NOT induce vomiting Batteries may lodge in the throat or digestive tract and fragment If battery was leaking or was chewed rinse mouth thoroughly with water Material Safety Data Sheet Revision Date 10 08 2007 000000023093 Version 1 2 Oo Print Date 02 13 2009 Page 7 7 Keep out of reach of children Do not handle or use until safety precautions in Material Safety Data Sheet MSDS have been read and understood Since emptied containers retain product residue follow label warnings even after container is emptied IN CASE OF FIRE Use appropriate agent for adjacent fire IN CASE OF SPILL Dispose of in accordance with local regulations see Section 13 Disposal considerations For Large Spills None should be needed The information contained herein is furnished without warranty of any kind Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment The information relating to the working solution is for guidance purposes only and is based on correct mixing and use of the product according to instructions
10. vision Date 10 08 2007 000000023093 Version 1 2 Print Date 02 13 2009 Page 5 7 Kodak Acute Toxicity Data e Oral LD50 rat 273 mg kg e Skin irritation severe 12 Ecological information This material is not expected to be harmful to aquatic life 13 Disposal considerations DO NOT INCINERATE or expose to fire Discharge treatment or disposal may be subject to federal state commonwealth provincial or local laws 14 Transport information For transportation information go to www kodak com go ship 15 Regulatory information Notification status Regulatory List Notification status EINECS y positive listing TSCA y positive listing AICS y positive listing DSL y positive listing ENCS JP n Negative listing KECI KR y positive listing PICCS PH y positive listing INV CN y positive listing AN Negative listing indicates one or more component is either not on the public Inventory or is subject to exemption requirements If additional information is needed contact Kodak Other regulations American Conference of Governmental Industrial Hygienists ACGIH International Agency for Research on Cancer IARC U S National Toxicology Program NTP No component of this product present at levels greater than or equal to 0 1 is identified as a carcinogen or potential carcinogen by ACGIH No component of this product present at levels greater
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