Fluke 9112A User's Manual
Contents
1. RCRA CMS wool as manufactured is not classified as a hazardous waste according to Federal regulations 40 CFR 261 As manufactured CMS wool was tested using EPA s Toxicity Characteristics Leaching Procedure TCLP Results showed there were no detectable contaminants or detectable leachable contaminants that exceeded the regulatory levels Any processing use alteration or chemical additions to the product as purchased may alter the disposal requirements Under Federal regulations it is the waste generator s responsibility to properly characterize a waste material to determine if it is a hazardous waste Check local regional state or provincial regulations to identify all applicable disposal requirements 14 TRANSPORT INFORMATION U S DEPARTMENT OF TRANSPORTATION DOT Hazard Class Not regulated United Nations UN Number Not applicable Labels Not applicable North America NA Number Not applicable Placards Not applicable Bill of Lading Product name INTERNATIONAL Not classified as dangerous goods under ADR road RID train IATA air or IMDG ship 15 REGULATORY INFORMATION UNITED STATES REGULATIONS SARA Title III This product does not contain any substances reportable under Sections 302 304 313 40 CFR 372 Sections 311 and 312 apply OSHA Comply with Hazard Communication Standards 29 CFR 1910 1200 and 29 CFR 1926 59 and Respiratory Protection Standards 29 CFR 1910 134 and 29 CFR 1926 103 T2. PRODUCT STEWARDSHIP PROGRAM Morgan Thermal Ceramics has established a program to provide customers with up to date information regarding the proper use and handling of Superwool If you would like more information about this program please call your local supplier or visit one of the following web sites Thermal Ceramics Global www thermalceramics com Refractory Ceramic Fibers Coalition USA www RCFC net ECFIA Europe www ecfia org LABELING As product information labels may be required on Superwool packages check local destination regulations before shipping HMIS HAZARD RATING HMIS Health 1 HMIS Flammable 0 HMIS Reactivity 0 HMIS Personal Protective To be determined by user DEFINITIONS Page 6 Of 7 MATERIAL SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002 ACGIH American Conference of Governmental Industrial Hygienists ADR Carriage of Dangerous Goods by Road International Regulation CAA Clean Air Act CAS Chemical Abstracts Service Registry Number CERCLA Comprehensive Environmental Response Compensation and Liability Act EPA Environmental Protection Agency EU European Union flec Fibers per cubic centimeter HEPA High Efficiency Particulate Air HMIS Hazardous Materials Identification System IARG International Agency for Research on Cancer IATA International Air Transport Association IMDG International Maritime Dangerous
3. If the mains supply cord becomes damaged replace 1t with a cord with the appropriate gauge wire for the current of the instrument If there are any questions call Hart Scientific Customer Service for more informa tion Before using any cleaning or decontamination method except those rec ommended by Hart users should check with Hart Scientific Customer Service to be sure that the proposed method will not damage the equip ment Tf the instrument is used in a manner not in accordance with the equip ment design the operation of the furnace may be impaired or safety haz ards may arise The over temperature cut out should be checked every 6 months to ensure that it is working properly Set the unit to 300 C and let it stabilize Turn the adjustable cutout knob down until the cutout is activated Turn the knob back up and push the reset button Periodically remove the equilibration block and use emery cloth to re move the oxidation build up on the block 27 9 Appendix A Material Safety Data Sheets MSDS 9 Appendix A Material Safety Data Sheets MSDS 29 Pza MATERIAL SAFETY DATA SHEET MSDS No M0001 Effective Date 06 10 2003 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Group REFRACTORY CERAMIC FIBER PRODUCT Chemical Name VITREOUS ALUMINOSILICATE FIBER Synonym s RCF ceramic fiber synthetic vitreous fiber SVF man made vitreous fiber MMVF man made mineral fiber MMMF Trade Na
4. Hart Scientific 9112A Calibration Furnace User s Guide Rev 5B2901 Fluke Corporation Hart Scientific Division 799 E Utah Valley Drive American Fork UT 84003 9775 USA Phone 1 801 763 1600 Telefax 1 801 763 1010 E mail support hartscientific com www hartscientific com Subject to change without notice e Copyright 2005 Printed in USA Rev 5B2901 Table of Contents 1 Before You Start 1 1 1 Symbols Used o ee os uidit ee 1 1 2 Safety Information 2 1 2 1 WARNINGS 0 0 c bek eu nie ee a RS EAS 2 122 GE ER SEE eee Se eh a Rd ws 4 1 3 Authorized Service Centers 5 2 Introduction 9 3 Specifications and Environmental Conditions 11 3 1 OPECITICAIONS 2 2445 Ba ga be ERAS b t a 11 3 2 Environmental Conditions 11 3 3 Warranty sc ss os Ga eH Pe EO Ee eS 11 4 Installation e se cee 4 we 46 ox du 5 0 ss 13 4 1 Unpacking amp Inspection 13 4 2 LOCAON EE EEE id SENG SS 13 4 3 Drysout Period seas bbe ee eee A s 14 AA PowWeb ae erigir gas FE EGGE sense 14 4 5 Equilibration Block Assembly Installation 14 4 6 Probe Installation 14 5 Parts and Controls 17 Sil Front VIEW lo x reel AEE F bk ek sere AG 17 5 1 1 Temperature Controll
5. Particulates Not Otherwise Regulated Product Stewardship Program Refractory Ceramic Fibers Coalition Resource Conservation and Recovery Act Recommended Exposure Guideline RCFC Recommended Exposure Limit NIOSH Carriage of Dangerous Goods by Rail International Regulations Superfund Amendments and Reauthorization Act Emergency Planning and Community Right to Know Act Extremely Hazardous Substances Emergency Release MSDSIList of Chemicals and Hazardous Inventory Emergency and Hazardous Inventory Toxic Chemicals and Release Reporting Short Term Exposure Limit Synthetic Vitreous Fiber Transportation of Dangerous Goods Threshold Limit Value ACGIH TSCA Toxic Substances Control Act TWA Time Weighted Average WHMIS Workplace Hazardous Materials Information System Canada Revision Summary Section 1 Added new product name Replaces 02 11 02 MSDS MSDS Prepared By UNIFRAX RISK MANAGEMENT DEPARTMENT DISCLAIMER The information presented herein is presented in good faith and believed to be accurate as of the effective date of this Material Safety Data Sheet Employers may use this MSDS to supplement other information gathered by them in their efforts to assure the health and safety of their employees and the proper use of the product This summary of the relevant data reflects professional judgment employers should note that information perceived to be less relevant has not been included in this MSDS Therefore given the su
6. perature limit is not exceeded in the air above the instrument The instrument and any thermometer probes used with it are sensitive instru ments that can be easily damaged Always handle these devices with care Do not allow them to be dropped struck stressed or overheated When calibrating PRTs always follow correct calibration procedure and cali brate from high temperatures to low temperatures with the appropriate triple point of water checks Never immerse a wet or cold PRT into a bath filled with hot medium Severe damage to the PRT may result as well as personal injury to the calibration technician This furnace is not designed to be portable Therefore moving the furnace once it has been installed should be kept to a minimum To safely move the furnace two people are required One person should lift the furnace at each end of the furnace place their hand under the control drawer and lift simultaneously be ing careful not to tip Ensure that the furnace is de energized and cooled to less then 100 C Remove the equilibration block prior to moving The equilibration block can damage the fused silica tube that is extremely fragile The control probe must be inserted properly in the instrument and plugged into the socket at the back of the furnace DO NOT operate the furnace without the control probe properly inserted and attached The furnace will not operate cor rectly without the control probe Injury to operating personnel and p
7. respirable dust OR Calcium Magnesium Zirconium Silicate Mixture 100 15 mg m total dust 10 mg m inhalable dust 308084 09 5 5 mg m respirable dust 3 mg m respirable dust o May contain alumina and titania as minor constituents See Section 8 Exposure Controls Personal Protection for exposure guidelines 3 HAZARDS IDENTIFICATION May cause temporary mild mechanical irritation to the eyes skin nose and or throat Pre existing skin and respiratory conditions may be aggravated by exposure Page 1 of 7 MATERIAL SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002 4 FIRST AID MEASURES RESPIRATORY TRACT nose and throat IRRITATION If respiratory tract irritation develops move the person to a dust free location See Section 8 for additional measures to reduce or eliminate exposure EYE IRRITATION If eyes become irritated flush immediately with large amounts of lukewarm water for at least 15 minutes Eyelids should be held away from the eyeball to ensure thorough rinsing Do not rub eyes SKIN IRRITATION If skin becomes irritated remove soiled clothing Do not rub or scratch exposed skin Wash area of contact thoroughly with soap and water Using a skin cream or lotion after washing may be helpful GASTROINTESTINAL IRRITATION If gastrointestinal tract irritation develops move the person to a dust free environment If symptoms pe
8. Fibers Aluminosilicate There is no specific regulatory standard for RCF in the U S OSHA s Particulate Not Otherwise Regulated PNORY standard 29 CFR 1910 1000 Subpart Z Air Contaminants applies generally Total Dust 15 mg m Respirable Fraction 5 mg m The Refractory Ceramic Fibers Coalition RCFC has sponsored comprehensive toxicology and epidemiology studies to identify potential RCF related health effects see Section 11 for more details consulted experts familiar with fiber and particle science conducted a thorough review of the RCF related scientific literature and further evaluated the data in a state of the art quantitative risk assessment Based on these efforts and in the absence of an OSHA PEL RCFC has adopted a recommended exposure guideline as measured under NIOSH Method 7400 B The manufacturers REG is intended to promote occupational health and safety through prudent exposure control and reduction and it reflects relative technical and economic feasibility as determined by extensive industrial hygiene monitoring efforts undertaken pursuant to an agreement with the U S Environmental Protection Agency OTHER OCCUPATIONAL EXPOSURE LEVELS OEL RCF related occupational exposure limits vary internationally Regulatory OEL examples include Australia 0 5 f cc Austria 0 5 f cc Canada 0 5 to 1 0 f cc Denmark 1 0 f cc France 0 6 f cc Germany 0 5 f cc Netherlands 1
9. Hazard Communication Standards 29 CFR 1910 1200 and 29 CFR 1926 59 and the Respiratory Protection Standards 29 CFR 1910 134 and 29 CFR 1926 103 California Ceramic fibers airborne particles of respirable size is listed in Proposition 65 The Safe Drinking Water and Toxic Enforcement Act of 1986 as a chemical known to the State of California to cause cancer Other RCF products are not known to be regulated by states other than California States however state and local OSHA and EPA regulations may apply to these products If in doubt contact your local regulatory agency INTERNATIONAL REGULATIONS Canada Canadian Workplace Hazardous Materials Information System WHMIS RCF is classified as Class D2A Materials Causing Other Toxic Effects Canadian Environmental Protection Act CEPA All substances in this product are listed as required on the Domestic Substance List DSL European European Directive 97 69 EC classified RCF as a Category 2 carcinogen that is it Union should be regarded as if it is carcinogenic to man 16 OTHER INFORMATION RCF DEVITRIFICATION As produced all RCF fibers are vitreous glassy materials which do not contain crystalline silica Continued exposure to elevated temperatures may cause these fibers to devitrify become crystalline The first crystalline formation mullite begins to occur at approximately 985 C 1805 F Crystalline silica cristobalite formation may begin a
10. PERSONAL PROTECTION MANUFACTURER S RECOMMENDATION It is prudent to reduce exposure to respirable dusts to the lowest attainable level through the use of engineering controls such as ventilation and dust collection devices Industrial hygiene standards and occupational exposure limits may vary between countries state and local jurisdictions Contact your employer to determine which exposure levels apply to your facility If no regulatory dust or other standards apply a qualified industrial hygienist can assist with a specific workplace evaluation including recommendations for respiratory protection In the absence of such guidance the manufacturer generally recommends the control of CMS wool exposures to 1 fiber cc or less ENGINEERING CONTROLS Use feasible engineering controls such as local exhaust ventilation point of generation dust collection down draft work stations emission controlling tool designs and materials handling equipment designed to minimize airborne fiber emissions PERSONAL PROTECTION EQUIPMENT Skin Protection Wear gloves head coverings and full body clothing as necessary to prevent skin irritation Washable or disposable clothing may be used If possible do not take unwashed work clothing home If soiled work clothing must be taken home employers should ensure employees are trained on the best practices to minimize or avoid non work dust exposure e g vacuum clothes before leaving the work area wash work clothing
11. SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002 10 STABILITY AND REACTIVITY CHEMICAL STABILITY Stable under conditions of normal use CHEMICAL INCOMPATIBILITIES Avoid contact with strong acids CONDITIONS TO AVOID None HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION Not applicable 11 TOXICOLOGICAL INFORMATION TOXICOLOGY CMS wools have been tested for their biopersistence using methods devised by the European Union The results from these studies exonerate CMS wools from carcinogen classification under the criteria listed in Nota Q of European Commission Directive 97 69 EU In a lifetime carcinogenicity test rats were exposed by inhalation for two years 5 days a week 6 hours a day to CMS fibers at 200 WHO fibers ml There was neither fibrosis nor carcinogenic response only reversible cellular changes were seen Further subchronic inhalation studies on rats with CMS fibers at concentrations of 150 fibers gt 20 um long per ml for 90 days with follow up to 1 year showed neither inflammation nor cell proliferation All parameters studied returned rapidly to baseline levels on cessation of exposure After service CMS wools may contain crystalline phases including some forms of silica See Section 16 However CMS fibers heated to 1000 C for 2 weeks were not cytotoxic to macrophage like cells at concentrations up to 320 ug cm In the same test s
12. TC847 BAS Set the Baud Rate on the Controller of the 9112A to 9600 Set the address of your furnace to 10 or greater Set the temperature or if needed the furnace parameters A listing of the parameters and their meaning are in the following table Table 2 Command Parameters PV process value temperature SL set point OP output power XP proportional band TI integration time TD derivative time CH Cycle time To set a parameter simply type in the parameter and the value For example to set the control temperature to 800 C type SL 800 26 8 Maintenance Maintenance The calibration instrument has been designed with the utmost care Ease of op eration and simplicity of maintenance have been a central theme in the product development Therefore with proper care the instrument should require very little maintenance Avoid operating the instrument in an oily wet dirty or dusty environment If the outside of the instrument becomes soiled it may be wiped clean with a damp cloth and mild detergent Do not use harsh chemicals on the surface which may damage the paint Be sure that the well of the furnace is kept clean and clear of any foreign matter Do not use fluids to clean out the well If a hazardous material is spilt on or inside the equipment the user is re sponsible for taking the appropriate decontamination steps as outlined by the national safety council with respect to the material
13. a chemical known to the State of California to cause cancer The Canadian Environmental Protection Agency CEPA has classified RCF as probably carcinogenic Group 2 The Canadian Workplace Hazardous Materials Information System WHMIS RCF is classified as Class D2A Materials Causing Other Toxic Effects The Hazardous Materials Identification System HMIS Health 1 Flammability 0 Reactivity 0 Personal Protection Index X Employer Determined denotes potential for chronic effects 4 FIRST AID MEASURES FIRST AID PROCEDURES RESPIRATORY TRACT nose amp throat IRRITATION If respiratory tract irritation develops move the person to a dust free location Get medical attention if the irritation continues See Section 8 for additional measures to reduce or eliminate exposure EYE IRRITATION If eyes become irritated flush immediately with large amounts of lukewarm water for at least 15 minutes Eyelids should be held away from the eyeball to ensure thorough rinsing Do not rub eyes Get medical attention if irritation persists SKIN IRRITATION If skin becomes irritated remove soiled clothing Do not rub or scratch exposed skin Wash area of contact thoroughly with soap and water Using a skin cream or lotion after washing may be helpful GASTROINTESTINAL IRRITATION If gastrointestinal tract irritation develops move the person to a dust free environment NOTES TO PHYSICIANS Skin and respira
14. extend the life of the heaters The cutout controls a relay which is wired in series with the heater circuit The cutout is provided as a safety backup in case the solid state relay driven by the temperature controller fails shorts causing thermal runaway Power and Heater Switches The power switch is located just left of the temperature controller The top is pressed inward to turn the unit on Note The internal fans are wired ahead of the switch so they stay on until the unit is cooled even though the main power may have been turned off This way the outer surfaces of the enclosure are not heated to dangerous levels from stored heat 5 Parts and Controls Heater Assembly 5 2 Front Guide Tubes Heater Assembly The heater is a made of fiber ceramic insulating material with imbedded heat ing The heater is made up with two halves each with a separate heating ele ment The heating elements are wired in parallel The heater is primarily a radiating device and is rated for a maximum furnace operating temperature of 1100 C Realize however that the higher the operat ing temperature the lower the lifetime of the heater Limiting the number of hours at the extreme high end of the temperature range to only the time re quired for calibrations increases the longevity of your furnace heating element Quartz Tube Isothermal Block Back Cutout Probe hm Control Probe Figure 2 Sectional Side View
15. f 4 sus ais Ge Gp tees dde be eg aS 17 5 1 2 Over Temperature Cutout sa sakker a re mes SAP Ga b re Ga 18 5 13 Power and Heater Switches 18 5 2 Heater Assembly 54 3 4044 cil a sun 19 521 Equilibration Block Assembly 19 522 Temperature Control and Cutout Sensor 20 5 3 Back VIEW ic oh aeae Ve eee SE ee SE e SG 21 53 1 The Power Cables Suk s Samsun BA el As die ne 21 532 Nomenclatura as arent ar dose GS leges 21 5 3 3 FUSES au ska BT se Aae AT GLA Ga 21 6 Operatioi EE SN 2 6 1 OVERVIEW EE ia ES A BE ee A 23 6 2 7 Digital Communication Interface Operating the Furnace 8 Maintenance 9 Appendix A Material Safety Data Sheets MSDS Figures Figure 1 Figure 2 Figure 3 Figure 4 Front View 2 55 a e Gr Re Rl sk wk DS ikke 6 seu 17 Sectional Side View Ls 2544 eek aa RUE be harmonie a 19 Back VIEW e r LT ae di o a we ee Oa 20 RS232 Cable Witing sac er sorain SL gars SES eS 25 iii 1 Before You Start Symbols Used 1 1 Before You Start Symbols Used Table 1 lists the International Electrical Symbols Some or all of these symbols may be used on the instrument or in this manual Table 1 International Electrical Symbols Symbol Description NU AC Alternating Current PS AC DC Battery CE Complies with European Union Directives Mm MA DC Double Insulated Electric Shock Fuse PE Ground Hot
16. lung disease interstitial fibrosis from evaluations of chest X rays 2 There is no evidence of an elevated incidence of lung disease among RCF manufacturing employees 3 In early studies an apparent statistical trend was observed in the exposed population between RCF exposure duration and some measures of lung function The observations were clinically insignificant If these observations were made on an individual employee the results would be interpreted as being within the normal predicted respiratory range A more recent longitudinal study of employees with 5 or more pulmonary function tests found that there was no effect on lung function associated with RCF production experience Initial data circa 1987 seemed to indicate an interactive effect between smoking and RCF exposure more recent data however found no interactive effect Nevertheless to promote good health RCF employees are still actively encouraged not to smoke 4 Pleural plaques thickening along the chest wall have been observed in a small number of RCF employees Some studies appear to show a relationship between the occurence of pleural plaques on chest radiographs and the following variables a years since RCF production hire date b duration of RCF production employment and c cumulative RCF exposure The best evidence to date indicates that pleural plaques are a marker of exposure only Pleural plaques are not associated with pulmonary impairment The path
17. power can be switched to HIGH or LOW power positions The object of the temperature control is the equilibration block with test wells containing the ref erence probe and the sensors to be calibrated inside The block provides a ther mal mass which tends to stabilize the temperature and reduce the gradients between the test wells The user settable over temperature cut out can open the heater circuit with a relay if the safe temperature for the test probe or for the furnace is exceeded The enclosure is designed to limit the heat seen by the various components of the furnace as well as the user The control section is in a separate cabinet below the furnace heat preventing damage or accuracy er rors The furnace part of the cabinet contains ventilation holes as well as two fans controlled by the thermostat This cooling capability prevents the surface of the enclosure from getting dangerously hot In the event that the fans should fail a second thermostat is installed in the cabinet which shuts down the fur nace heaters if the cabinet exceeds a safe temperature Operating the Furnace Operating the Model 9112A is straight forward once you have grasped all the important principles When the unit is turned on the cutout reset button must be pushed before the unit will heat Temperature selection is accomplished by using the up and down arrow keys on the front of the temperature controller The lower display indicates the new temperature
18. 0 C for 4 hours or more The instrument is intended for indoor use only BURN HAZARD High temperatures may be present in this equipment Fires and severe burns may result if personnel fail to observe safety precautions The furnace generates extreme temperatures Precautions must be taken to pre vent personal injury or damage to objects Probes may be extremely hot when removed from the furnace Cautiously handle probes to prevent personal injury Carefully place probes on a heat resistant surface rack until they are at room temperature DO NOT lift the back of this instrument with the equilibration block in place The equilibration block will fall out of the instrument DO NOT operate near flammable materials Extreme temperatures could ignite the flammable material Use of this instrument at HIGH TEMPERATURES for extended periods of time requires caution DO NOT touch the well access cover of the instrument it is extremely hot For compliance with IEC 1010 1 it is recommended that the cutout mode al ways be set to the manual mode requiring user intervention to reset the instrument Take extreme care in handling hot probes The extreme temperatures generated in a furnace of this type can cause serious personal injury Do not touch them on external surfaces of the furnace or set them on any other surfaces unable to withstand those temperatures A fire hazard exists Do not touch the access tube end plate or severe burns can res
19. 0 f cc New Zealand 1 0 f cc Norway 2 0 f cc Poland 2 0 f cc Sweden 1 0 f cc United Kingdom 2 0 f cc Non regulatory OEL examples include ACGIH TLV 0 2 f cc RCFC REG 0 5 f cc The objectives and criteria underlying each of these OEL decisions also vary The evaluation of occupational exposure limits and determining their relative applicability to the workplace is best performed on a case by case basis by a qualified Industrial Hygienist ENGINEERING CONTROLS Use engineering controls such as local exhaust ventilation point of generation dust collection down draft work stations emission controlling tool designs and materials handling equipment designed to minimize airborne fiber emissions PERSONAL PROTECTION EQUIPMENT Respiratory Protection RCF When engineering and or administrative controls are insufficient to maintain workplace concentrations within the 0 5 f cc REG the use of appropriate respiratory protection pursuant to the requirements of OSHA Standards 29 CFR 1910 134 and 29 CFR 1926 103 is recommended The following information is provided as an example of appropriate respiratory protection for aluminosilicate fibers The evaluation of workplace hazards and the identification of appropriate respiratory protection is best performed on a case by case basis by a qualified Industrial Hygienist MANUFACTURER S RESPIRATORY PROTECTION RECOMMENDATIONS WHEN HANDLING RCF PRODUCTS Respirable A
20. 5 2 1 Equilibration Block Assembly The Equilibration Block Assembly consists of 1 the test well 2 access tubes and end plate 3 the front and rear guard blocks 4 insulation on each end and 5 the center block The center block is intended to stabilize the temperature fluctuations and to conduct heat between the test wells in order to equalize them The guard blocks shunt heat to the various probes to reduce heat loss out the ends The whole assembly is supported by a fused silica tube All heated materials are fused silica ceramic fiber or Inconel alloy 600 19 9112A Calibration Furnace User s Guide 20 5 2 2 Figure 3 Back View Temperature Control and Cutout Sensor The temperature control sensor is a Type K Thermocouple as indicated This sensor is 3 16 inch in diameter and 12 inches long Its location in the block is important and can cause the gradient in the block to move back and forth The probe is normally inserted as shown in Figures 2 and 3 The cutout sensor is the same as the control sensor 12 inches long This sensor is inserted through a tube in the back of the block Its location here helps pre vent the heater elements from overheating thus prolonging their life 5 Parts and Controls Back View 5 3 5 3 1 5 3 2 5 3 3 The sensor connectors are provided on the rear panel of the furnace for con necting the control and cutout thermocouples They are Ty
21. Goods Code mg m Milligrams per cubic meter of air mppcf Million particles per cubic meter MSHA Mine Safety and Health Administration NFPA National Fire Protection Association NIOSH National Institute for Occupational Safety and Health OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit PNOC Particulates Not Otherwise Classified PNOR Particulates Not Otherwise Regulated RCRA Resource Conservation and Recovery Act RID Carriage of Dangerous Goods by Rail International Regulation SARA Superfund Amendments and Reauthorization Act Title III Emergency Planning and Community Right to Know Act Section 302 Extremely Hazardous Substances Section 304 Emergency Release Section 311 MSDS List of Chemicals Section 312 Emergency and Hazardous Inventory Section 313 Toxic Chemicals Release Reporting STEL Short Term Exposure Limit TCLP Toxicity Characteristics Leaching Procedures EPA TLV Threshold Limit Values ACGIH TSCA Toxic Substance Control Act WHMIS Workplace Hazardous Materials Information System Canada 29 CFR 1910 134 amp 1926 103 OSHA Respiratory Protection Standards 29 CFR 1910 1200 amp 1926 59 OSHA Hazard Communication Standards Revision Summary MSDS re formatted in its entity Minor changes applied MSDS Prepared By THERMAL CERAMICS ENVIRONMENTAL HEALTH amp SAFETY DEPARTMENT DISCLAIMER Reasonable care has been taken in the preparation of the information contain
22. SCA CMS wools have been assigned two CAS numbers however they are not required to be listed on the TSCA inventory CERCLA CMS wool contains fibers with an average diameter greater than one micron and thus is not considered a CERCLA hazardous substance CAA CMS wool contains fibers with an average diameter greater than one micron and thus is not considered a hazardous air pollutant States CMS wools are not known to be regulated by any State If in doubt contact your local regulatory agency INTERNATIONAL REGULATIONS Canada WHMIS No Canadian Workplace Hazardous Materials Information System categories apply to this product Canadian EPA All substances in this product are listed as required on the Domestic Substance List DSL European Union These products are exonerated from any carcinogenic classification in the countries of the European Union under the provisions of Nota Q of the European Commission Directive 97 69 EC Page 5 Of 7 MATERIAL SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002 16 OTHER INFORMATION SUPERWOOL DEVITRIFICATION As produced Superwools are vitreous glassy AES Wools that do not contain crystalline silica Continued exposure to elevated temperatures gt 900 C may cause these materials to form crystalline phases including crystalline silica The occurrence and extent of crystalline silica formation is dependent on the dura
23. Surface Burn Hazard Read the User s Manual Important Information Off On O Oi gt o 9112A Calibration Furnace User s Guide 1 2 1 2 1 Symbol Description Canadian Standards Association US OVERVOLTAGE Installation CATEGORY II Pollution Degree 2 per IEC1010 1 re CATI fers to the level of Impulse Withstand Voltage protection provided Equipment of OVERVOLTAGE CATEGORY II is energy consuming equipment to be supplied from the fixed installation Examples include household office and laboratory appliances C TIC Australian EMC Mark The European Waste Electrical and Electronic Equipment WEEE Directive 2002 96 EC mark Safety Information Use this instrument only as specified in this manual Otherwise the protection provided by the instrument may be impaired The following definitions apply to the terms Warning and Caution e WARNING identifies conditions and actions that may pose hazards to the user e CAUTION identifies conditions and actions that may damage the in strument being used WARNINGS To avoid personal injury follow these guidelines DISCLAIMER Hart Scientific manufactures instruments for the purpose of temperature calibration Instruments used for applications other than calibration are used at the discretion and sole responsibility of the cus tomer Hart Scientific cannot accept any responsibility for the use of in struments for any a
24. amples of pure crystalline quartz were significantly active at 20 ug cm EPIDEMIOLOGY This material has not been the subject of an epidemiology study NOTE Neither the International Agency for Research on Cancer IARC nor the National Toxicology Program nor any other U S regulatory or classification entity has evaluated CMS wool Superwool products are members of a family of materials whose properties are distinct in several ways from other man made mineral fibers In October 2001 IARC re reviewed Man Made Vitreous Fibers and elected not to make an overall evaluation of the newly developed fibers such as CMS wool but recognized that those that have been tested appear to have low carcinogenic potential in experimental animals While CMS wool is an inert material that does not react with the skin exposures may cause temporary mild mechanical irritation to the eyes skin nose and or throat for First Aid Measurers see Section 4 Proper handling practices and the use of protective clothing see Section 8 can minimize irritation 12 ECOLOGICAL INFORMATION No adverse effects of this material on the environment are anticipated 13 DISPOSAL INFORMATION WASTE MANAGEMENT To prevent waste materials becoming airborne a covered container or plastic bagging is recommended Page 4 Of 7 MATERIAL SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002
25. ay shows tem perature to the nearest degree in C or F shipped in C The temperature is set with convenient up and down buttons on the front panel Sensors being calibrated as well as the furnace itself are protected from exces sive temperature with an over temperature cutout The cutout is easily adjusted from the front panel This device is relay operated and protects against the pos sibility of thermal runaway due to a shorted solid state relay which controls the heaters 3 Specifications and Environmental Conditions Specifications 3 Specifications and Environmental Conditions 3 1 Specifications Operating Range 300 C to 1100 C Stability 300 C 0 05 C 500 C 0 05 C 700 C 0 1 C 1000 C 0 1 C 1100 C 0 1 C Uniformity 300 C 0 05 C 500 C 0 08 C 700 C 0 2 C 1000 C 0 25 C 1100 C 0 3 C Stabilization Time Typically 2 hours midrange slower at the low temperature end 4 hours faster at the high temperature end Heater Power 3700 Watts High Power Requirements 230 VAC 10 50 60 Hz 20 A Outside Dimensions 18 H x 14 25 W x 26 D 457mm x 362mm x 660mm Weight 72 5 lbs 3 2 Environmental Conditions Although the instrument has been designed for optimum durability and trou ble free operation it must be handled with care The instrument should not be operated in an excessively dusty or dirty environment Maintenance and clean ing recommendations can be found in the Ma
26. ding dermatitis asthma or chronic lung disease may be aggravated by exposure individuals who have a history of allergies may experience greater amounts of skin and respiratory irritation HAZARD CLASSIFICATION Although studies involving occupationally exposed workers have not identified any increased incidence of respiratory disease results from animal testing have been used as the basis for hazard classification In each of the following cases the conclusions are qualitative only and do not rest upon any quantitative analysis suggesting that the hazard actually may occur at current occupational exposure levels In October 2001 the International Agency for Research on Cancer IARC confirmed that Group 2b possible human carcinogen remains the appropriate IARC classification for RCF The Seventh Annual Report on Carcinogens 1994 prepared by the National Toxicology Program NTP classified respirable RCF and glasswool as substances reasonably anticipated to be carcinogens The American Conference of Governmental Industrial Hygienists ACGIH has classified RCF as A2 Suspected Human Carcinogen The Commission of The European Communities DG XI has classified RCF as a substance that should be regarded as if it is carcinogenic to man The State of California pursuant to Proposition 65 The Safe Drinking Water and Toxic Enforcement Act of 1986 has listed ceramic fibers airborne fibers of respirable size as
27. e temperatures A fire hazard exists Do not touch the access tube end plate or severe burns can result Some kind of metal and or ceramic fiber surface or container should be used to set the hot probes on to prevent injury damage and fire For best results all reference or sample probes should be inserted into the full depth of the well At this position the stability is the highest and the gradient the lowest Each user should satisfy themselves as to what the uncertainties are in terms of stability and gradients between the test wells Variations in equip ment probe size configuration etc affect these important factors A solid unstirred mass such as in a furnace is subject to heat losses from the probe stem which varies from probe to probe and temperature to temperature Typi cally stabilities are less than 0 1 C and can be as little as 0 015 C at 500 C Similarly gradients between the measuring cells can range from 0 2 C to well under 0 1 C For calibrations that must be less than full insertion into the test well make your own comparisons between the reference and test cell at that depth to establish the uncertainties The furnace can be used throughout the temperature range of 300 to 1100 C Lower temperatures are sluggish however High integrating values are required to maintain controller stability 1200 sec at the lower temperatures Expect some offset from the indicated temperature and the actual temperature Stabil
28. e weighted average TWA as determined by air samples collected and analyzed pursuant to NIOSH method 7400 B for airborne fibers e The manufacturer recommends the use of a full facepiece air purifying respirator equipped with an appropriate particulate filter cartridge during furnace tear out events and the removal of used RCF to control exposures to airborne fiber and the potential presence of crystalline silica If exposure levels are known the respiratory protection chart provided above may be applied e Potential exposure to other airborne contaminants should be evaluated by a qualified Industrial Hygienist for the selection of appropriate respiratory protection and air monitoring Skin Protection Wear gloves head coverings and full body clothing as necessary to prevent skin irritation Washable or disposable clothing may be used If possible do not take unwashed clothing home If soiled work clothing must be taken home employers should ensure employees are thoroughly trained on the best practices to minimize or avoid non work dust exposure e g vacuum clothes before leaving the work area wash work clothing separately rinse washer before washing other household clothes etc Eye Protection Wear safety glasses with side shields or other forms of eye protection in compliance with appropriate OSHA standards to prevent eye irritation The use of contact lenses is not recommended unless used in conjunction with appropriate eye pro
29. eaters shut off The up and down Temperature Adjustment arrow keys are the only temperature controls normally used A quick single stroke increments or decrements the temperature setting Holding the buttons down causes a gradual acceleration of the temperature setting These same buttons are used to adjust other parameters in conjunction with the PAR button Further information about the controller operation can be obtained from the temperature controller installation and operation manual included with the instrument Over Temperature Cutout The over temperature cutout is located at the left side of the control panel The controls include a temperature limit adjustment control knob calibrated in Cel sius and limit exceeded indicator light The cutout is adjustable by the user within the temperature range of the furnace with divisions shown every 25 C The indicator light turns on when the set limit is reached The cutout can be set to Manual Reset or Auto Reset The button on front panel allows the user to re set the cutout The unit leaves the factory with the unit set in the Manual Reset Mode In the Auto Reset Mode the temperature resets when it has dropped about 20 degrees The cutout is provided to allow the user to set the maximum furnace tempera ture to a point within the safe range of the sensor s being calibrated and to pro tect the furnace from exceeding its own safe operating range Limiting the top end also helps
30. ed in this Material Safety Data Sheet and the information provided is given in good faith However Thermal Ceramics Inc assumes no responsibility as to the accuracy or suitability of such information and no warranty expressed or implied is made Page 7 Of 7
31. ermanent damage to the furnace could occur Components and heater lifetimes can be shortened by continuous high tempera ture operation If a mains supply power fluctuation occurs immediately turn off the furnace Power bumps from brown outs and black outs can damage the instrument Wait until the power has stabilized before re energizing the furnace The probe and the block may expand at different rates Allow for probe expan sion inside the well as the block heats Otherwise the probe may become stuck in the well Be aware that the equilibration block expands as the furnace heats It will ex tend beyond the front of the furnace at high temperatures anywhere from 4 to approximately 1 2 inch This is normal and is due to thermal expansion Take care that all sensors used as references or being calibrated in the furnace are capable of withstanding the desired temperature range to be used Authorized Service Centers Please contact one of the following Authorized Service Centers to coordinate service on your Hart product 9112A Calibration Furnace User s Guide Hart Scientific Inc 799 E Utah Valley Drive American Fork UT 84003 9775 USA Phone 1 801 763 1600 Telefax 1 801 763 1010 E mail support O hartscientific com Fluke Nederland B V Customer Support Services Science Park Eindhoven 5108 5692 EC Son NETHERLANDS Phone 31 402 675300 Telefax 31 402 675321 E mail ServiceDesk fluke nl Fluke Int l C
32. intenance Section of this manual The instrument operates safely under the following conditions e temperature range 5 40 C 41 104 F e ambient relative humidity 15 50 e pressure 75kPa 106kPa e mains voltage within 10 of nominal e vibrations in the calibration environment should be minimized e altitude less than 2000 meters e indoor use only 3 3 Warranty Fluke Corporation Hart Scientific Division Hart warrants this product to be free from defects in material and workmanship under normal use and service 11 9112A Calibration Furnace User s Guide for a period as stated in our current product catalog from the date of shipment This warranty extends only to the original purchaser and shall not apply to any product which in Hart s sole opinion has been subject to misuse alteration abuse or abnormal conditions of operation or handling Software is warranted to operate in accordance with its programmed instruc tions on appropriate Hart products It is not warranted to be error free Hart s obligation under this warranty is limited to repair or replacement of a product which is returned to Hart within the warranty period and is determined upon examination by Hart to be defective If Hart determines that the defect or malfunction has been caused by misuse alteration abuse or abnormal condi tions or operation or handling Hart will repair the product and bill the pur chaser for the reasonable cost of repa
33. ir To exercise this warranty the purchaser must forward the product after calling or writing Hart for authorization Hart assumes NO risk for in transit damage For service or assistance please contact an Authorized Service Center see Sec tion 1 3 THE FOREGOING WARRANTY IS PURCHASER S SOLE AND EXCLU SIVE REMEDY AND IS IN LIEU OF ALL OTHER WARRANTIES EX PRESS OR IMPLIED INCLUDING BUT NOT LIMITED TO ANY IMPLIED WARRANTY OR MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE OR USE HART SHALL NOT BE LIABLE FOR ANY SPECIAL INDIRECT INCIDENTAL OR CONSEQUENTIAL DAM AGES OR LOSS WHETHER IN CONTRACT TORT OR OTHERWISE 4 Installation Unpacking amp Inspection 4 1 4 2 Installation Unpacking amp Inspection The furnace has been carefully packed for safe shipment by traditional means Unpacking should be done carefully Check carefully for all parts If any dam age has occurred you should notify the shipper immediately and make the ap propriate claim The equilibration block assembly has been packed separately in order to protect the fused silica tube from breakage during shipment The block assembly should not be installed into the furnace until it has been placed in its final location Verify that the following components are present e Furnace e 2 Thermocouples e Equilibration Block Assembly 2 pieces e Block Assembly Instruction Sheet e Diskette e Controller Manual e User s Guide e Se
34. irborne Fiber Concentration levels are 8 hr time weighted averages Not yet determined but expected to be below 5 0 f cc Half face air purifying respirator equipped with a based on operation NIOSH certified P100 particulate filter cartridge Reliably less than 0 5 f cc Optional 0 5 f cc to 5 0 f cc Half face air purifying respirator equipped with a NIOSH certified P100 particulate filter cartridge 5 0 f cc to 25 f cc Full facepiece air purifying respirator equipped with a NIOSH certified P100 particulate filter cartridge or PAPR Ressistor Reromnendaiont Respirator Recommendation Greater than 25 f cc PAPR with tight fitting full facepiece or a supplied air respirator in continuous flow mode When individual workers request respiratory protection A NIOSH certified respirator such as a disposable as a matter of personal comfort or choice where exposures are reliably below 0 5 f cc particulate respirator or respirators with filter cartridges rated N95 or better tthe P100 recommendation is a conservative default choice in some case solid arguments can be made that other respirator types e g N95 R99 etc may be suitable for some tasks or work environments The P100 recommendation is not designed to limit informed choices provided that respiratory protection decisions comply with 29 CFR 1910 134 Other Information e Concentrations based upon an eight hour tim
35. ity and gradients between test wells are similar at higher temperatures but time to stability is much longer 7 Digital Communication Interface Digital Communication Interface To control the furnace through a computer follow the instructions listed below The program supplied is a demo program and may be altered by you for your specific needs First make the appropriate cable assembly for your computer system The serial communications cable attaches to the calibrator through the DB 9 connector at the back of the instrument Figure 4 shows the pin out of this connector and suggested cable wiring To eliminate noise the serial cable should be shielded with low resistance between the connector DB 9 and the shield RS 232 Cable Wiring for IBM PC and Compatibles Instrument Computer DTE Connector Connector DB 9 Pin DB 9 Pin 1NC 1DCD 2 RxD 2 RxD 3TxD 3TxD ANC 4 DTR 5 GND 5 GND 6NC 6 DSR 7RTS 7RTS 8 CTS 8 CTS 9NC e 9NC Instrument Computer DTE Connector Connector DB 9 Pin DB 25 Pin 1NC e 2 RxD e e 2TxD 3TxD e 3RxD 4NC e 4 RTS 5 NE 5 CTS 6 NC DK E 6 DSR 7RTS I Jr GND 8 CTS 8DCD 9NC e 20 DTR Figure 4 RS 232 Cable Wiring Connect the appropriate connectors to your computer and to the furnace To communicate with the furnace 25 9112A Calibration Furnace User s Guide Load GWBASIC Load and then run the program
36. l probe should be inserted through the guard cover first so that the cover can be properly installed afterward Position the rear guard block as 4 Installation Probe Installation shown and then insert the insulation ceramic fiber see MSDS in the Appen dix being careful no to bend the probe sheath The insulation should generally block air movement in and out of the back of the fused silica tube Install the Guard Cover to prevent physical contact with parts that become dangerously hot when in use Be sure to connect the probes properly on the rear panel 15 5 Parts and Controls Front View 5 5 1 Parts and Controls Front View Figure 1 Front View Temperature Controller The temperature controller is a full PID micro processor based instrument as indicated The controller is set to cover the range of 0 to 1100 C and features 9112A Calibration Furnace User s Guide 18 5 1 2 5 1 3 two LED type displays The upper display normally indicates the actual tem perature while the lower display indicates the set temperature The displays are also utilized in setup and alarm functions Other indicators include the OP1 and OP2 indicator lights The OP1 indicator lights when the heater is on The OP2 1s not functional on the unit The R indicator lights during programmed ramping The M indicator flashes if the sensor fails If the sensor opens the h
37. m RCF AFTER SERVICE REMOVAL Respiratory protection should be provided in compliance with OSHA standards During removal operations a full face respirator is recommended to reduce inhalation exposure along with eye and respiratory tract irritation A specific evaluation of workplace hazards and the identification of appropriate respiratory protection is best performed on a case by case basis by a qualified industrial hygiene professional PRODUCT STEWARDSHIP PROGRAM The Unifrax Corporation has established a program to provide customers with up to date information regarding the proper use and handling of refractory ceramic fiber In addition Unifrax Corporation has also established a program to monitor airborne fiber concentrations at customer facilities If you would like more information about this program please call the Unifrax Corporation Product Stewardship Information Hotline at 1 800 322 2293 On February 11 2002 the Refractory Ceramic Fibers Coalition RCFC and the U S Occupational Safety and Health Administration OSHA introduced a voluntary worker protection program entitled PSP 2002 a comprehensive multi faceted risk management program designed to control and reduce workplace exposures to refractory ceramic fiber RCF Unifrax Corporation as a member of RCFC is participating in this highly acclaimed product stewardship program For more information regarding PSP 2002 please call the Unifrax Corporation s Product S
38. mes FIBERFRAX CERAMIC FIBER PRODUCTS INCLUDES FIBERS FIBERFRAX HIGH PURITY FIBERS HP ODB Module Trim MT HP HP Chopped H Bulk Regular Bulk Spun Bulk Fiberfrax FPP Fiber FIBERFRAX 6000 SERIES FIBERS All bulk fibers from 6000 AAA to 6100 ZZZ 6900 70A to 6900 99Z FIBERFRAX 7000 SERIES FIBERS 7000 AA to 7100 ZZ FIBERFRAX MILLED FIBERS EF 119 HP Ball Milled A HP Ball Milled B HP Ball Milled C D FIBERFRAX HIGH INDEX FIBERS W 657 W 707 W 758 HS 95C MX 135 CW MX 400 CW HS 70 HS 70C FIBERFRAX HSA FIBERS HSA K HSA HP FIBERFRAX KAOLIN FIBERS K Chopped KMTX MT MTX MT T MX 150 BLANKETS Durablanket AC Durablanket HP Durablanket HP S Durablanket S Durablanket Strip Duraback Duraback S Tank Car Insulation TCB SMB QSB600 QSB800 FIBERMAT LO CON BLANKET PAPERS FIBERFRAX BINDERLESS PAPERS 972 AH 972 FH 972 JH 882 FH 882 JH HSA F without binder HSA J without binder Manufacturer Supplier Unifrax Corporation 2351 Whirlpool St Niagara Falls NY 14305 2413 Product Stewardship Information Hotline 1 800 322 2293 Monday Friday 8 00 a m 4 30 p m EST For additional MSDSs visit our web page http www unifrax com or call Unifrax Customer Service at 716 278 3872 CHEMTREC Assist CHEMTREC will provide assistance for chemical emergencies Call 1 800 424 9300 2 COMPOSITION INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER BY WEIGHT Refrac
39. mmary nature of this document Unifrax Corporation does not extend any warranty expressed or implied assume any responsibility or make any representation regarding the completeness of this information or its suitability for the purposes envisioned by the user gt Thermal Ceramics MATERIAL SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002 1 PRODUCT AND COMPANY IDENTIFICATION Product Group ALKALINE EARTH SILICATE AES WOOL PRODUCT Chemical Name Calcium Magnesium Silicate Wool or Calcium Magnesium Zirconium Silicate Wool Synonyms CMS Synthetic Vitreous Fiber SVF Man made Vitreous Fiber MMVF Man made Mineral Fiber MMMF Trade Names Superwool Bulks Blankets Mats and Modules ALL GRADES Manufacturer Supplier Thermal Ceramics Inc P O Box 923 Dept 300 Augusta GA 30903 0923 For Product Stewardship and Emergency Information Hotline 1 800 722 5681 Fax 706 560 4054 For additional MSDSs and to confirm this is the most current MSDS for the product visit our web page www thermalceramics com or call our automated FaxBack 1 800 329 7444 Superwool is a trademark of The Morgan Crucible Company plc 2 COMPOSITION INFORMATION ON INGREDIENTS INGREDIENT amp CAS NUMBER BY WEIGHT OSHA PEL ACGIH TLV Calcium Magnesium Silicate Mixture 100 15 mg m total dust 10 mg m inhalable dust 329211 92 9 5 mg m respirable dust 3 mg m
40. nd one mesothelioma were observed in the 9 mg m group No acute respiratory effects were seen in the rats in the 3 mg m exposure group which suggests that there may be a dose response threshold below which irreversible respiratory impacts do not occur Other toxicological studies have been conducted which utilized non physiological exposure methods such as intrapleural intraperitoneal and intratracheal implantation or injection Some of these studies have found that RCF is a potential carcinogen Some experts however suggest that these tests have limited relevance because they bypass many of the biological mechanisms that prevent fiber deposition or facilitate fiber clearance To obtain more epidemiology or toxicology information please call the toll free telephone number for the Unifrax Corporation Product Stewardship Program found in Section 16 Other Information 12 ECOLOGICAL INFORMATION No ecological concerns have been identified 13 DISPOSAL CONSIDERATIONS WASTE MANAGEMENT To prevent waste materials from becoming airborne during waste storage transportation and disposal a covered container or plastic bagging is recommended DISPOSAL RCF as manufactured is not classified as a hazardous waste according to Federal regulations 40 CFR 261 Any processing use alteration or chemical additions to the product as purchased may alter the disposal requirements Under Federal regulations it is the waste generato
41. nt A Cautions Always operate this instrument at room temperature between 41 F and 104 F 5 C to 40 C Allow sufficient air circulation by leaving at least 18 inches 45 cm of clearance around the instrument DO NOT place instrument in a corner or block the back of the instrument Extreme temperatures are emitted from the back and front of the furnace Allow sufficient space in front of the furnace to work and to insert and remove the probes Read Section 4 Installation before placing the instrument into service DO NOT use fluids to clean out the well Fluids could leak into and damage the instrument Never introduce any foreign material into the probe hole of the insert Fluids etc can leak into the instrument causing damage DO NOT change the values of the calibration constants from the factory set values The correct setting of these parameters is important to the safety and proper operation of the unit Read and understand the controller operation prior to operating the instrument The controller manufacturer s manual is included with the instrument DO NOT operate this instrument in an excessively wet oily dusty or dirty environment 1 Before You Start Authorized Service Centers 1 3 The unit is a precision instrument Although it has been designed for optimum durability and trouble free operation it must be handled with care Most probes have handle temperature limits Be sure that the probe handle tem
42. ogenesis of pleural plaques remains incompletely understood however the mechanism appears to be an inflammatory response caused by inhaled fibers TOXICOLOGY A number of toxicological studies designed to identify any potential health effects from RCF exposure have been completed In one study conducted by the Research and Consulting Company Geneva Switzerland rats and hamsters were exposed to 30 mg m about 200 fibers cc of specially prepared RCF for 6 hours day 5 days week for up to 24 months In rats a statistically significant increase in lung tumors was observed two mesotheliomas cancer of the pleural lining between the chest wall and lung were also identified Hamsters did not develop lung tumors however interstitial fibrosis and mesothelioma was found Some in the scientific community have concluded that the maximum tolerated dose was exceeded and that significant particle contamination was a confounding issue therefore these study findings may not represent an accurate assessment of the potential for RCF to produce adverse health effects In a related multi dose study with a similar protocol other rats were exposed to doses of 16 mg m 9 mg m 3 mg m which corresponds to about 115 75 and 25 fibers per cubic centimeter respectively This study found no statistically significant increase in lung cancer Some cases of pleural and parenchymal fibrosis were seen in the 16 mg m dose group Some cases of mild fibrosis a
43. orporation Service Center Instrimpex Room 2301 Sciteck Tower 22 Jianguomenwai Dajie Chao Yang District Beijing 100004 PRC CHINA Phone 86 10 6 5 12 3436 Telefax 86 10 6 5 12 3437 E mail xingye han fluke com cn Fluke South East Asia Pte Ltd Fluke ASEAN Regional Office Service Center 60 Alexandra Terrace 03 16 The Comtech Lobby D 118502 SINGAPORE 1 Before You Start Authorized Service Centers Phone 65 6799 5588 Telefax 65 6799 5588 E mail antngOsinga fluke com When contacting these Service Centers for support please have the following information available e Model Number e Serial Number e Voltage e Complete description of the problem 2 Introduction Introduction The 9112A Calibration Furnace was designed specifically for calibrating PRTs fiber optic sensors and thermocouples at higher temperature ranges up to 1100 C The furnace utilizes an equilibration block capable of making compar ison measurements on multiple probes The standard equilibration block is sized for 1 4 inch probes however custom options are possible Temperature stability is better than 0 1 C throughout the range and the gradient between wells at full insertion is less than 0 5 C 0 25 C The temperature control system utilizes a digital controller with a Type K ther mocouple control sensor and RS 232 interface The controller displays the set temperature and the actual temperature simultaneously The displ
44. pe K miniature con nectors and allow for ease of system assembly and sensor replacement Back View See Figure 3 The Power Cable The furnace is provided with a 12 gauge two conductor with ground power ca ble The user must provide a connector to meet the needs of the installation Be sure to follow electrical codes A separate permanent earth ground is provided with this instrument This is required to be installed correctly for safe operation of the instrument Nomenclature The nomenclature on the rear of the furnace provides information to the user in case service is required The nomenclature includes the manufacturer manufac turer location model number and serial number specific to this unit Refer to the model number and serial number whenever service is required Fuses Two 20 A F 250 V fuses are used to protect the system one for each leg of the 230 VAC power The fuses are located inside the control cabinet If the furnace fails to operate check the fuses first Two 1 AF 250 V fuses are located inside the control cabinet for the controller 21 6 Operation Overview 6 1 6 2 Operation Overview The Model 9112A is basically a temperature controlled furnace utilizing a full PID micro processor based temperature controller with a Type K thermocouple temperature sensor The temperature controller sends a time proportional signal to the solid state relay which regulates the current to the heater The heater
45. pplication other than temperature calibration GENERAL Appropriate personal safety protection should be worn by the operator at all times while using the furnace DO NOT use the instrument for any application other than calibration work The instrument was designed for temperature calibration Any other use of the unit may cause unknown hazards to the user DO NOT use the unit in environments other than those listed in the user s guide Completely unattended operation is not recommended 1 Before You Start Safety Information Follow all safety guidelines listed in the user s manual Calibration Equipment should only be used by Trained Personnel Tf this equipment is used in a manner not specified by the manufacturer the protection provided by the equipment may be impaired or safety hazards may arise Inspect the instrument for damage before each use DO NOT use the instrument if it appears damaged or operates abnormally Before initial use or after transport or after storage in humid or semi humid environments or anytime the instrument has not been energized for more than 10 days the instrument needs to be energized for a dry out period of 2 hours before it can be assumed to meet all of the safety requirements of the IEC 1010 1 If the product is wet or has been in a wet environment take necessary measures to remove moisture prior to applying power such as storage in a low humidity temperature chamber operating at 5
46. r s responsibility to properly characterize a waste material to determine if it is a hazardous waste Check local regional state or provincial regulations to identify all applicable disposal requirements 14 TRANSPORT INFORMATION U S DEPARTMENT OF TRANSPORTATION DOT Hazard Class Not Regulated United Nations UN Number Not Applicable Labels Not Applicable North America NA Number Not Applicable Placards Not Applicable Bill of Lading Product Name INTERNATIONAL Canadian TDG Hazard Class 8 PIN Not regulated Not classified as dangerous goods under ADR road RID train or IMDG ship 15 REGULATORY INFORMATION UNITED STATES REGULATIONS EPA Superfund Amendments and Reauthorization Act SARA Title III This product does not contain any substances reportable under Sections 302 304 313 40 CFR 372 Sections 311 and 312 40 CFR 370 apply delayed hazard Toxic Substances Control Act TSCA All substances in this product are listed as required on the TSCA inventory RCF has been assigned a CAS number however it is a simple mixture and therefore not required to be listed on the TSCA inventory The components of RCF are listed on the inventory Comprehensive Environmental Response Compensation and Liability Act CERCLA and the Clean Air Act CAA RCF contains fibers with an average diameter greater than one micron and thus is not considered a hazardous air pollutant OSHA Comply with
47. rial Cable Location The furnace is intended to be installed into any typical calibration facility envi ronment The best results from the furnace are realized if the temperature fluc tuations in the room are not excessive A minimum of 18 inches free air space around the furnace must be allowed This air space allows exchange to occur and safely remove heat from the furnace WARNING This furnace is intended for high temperature use and conse quently a fire danger exists DO NOT mount the furnace on a flammable surface and keep fire extinguishing equipment near by Extremely humid environments may require startup on low heat after long peri ods of disuse 13 9112A Calibration Furnace User s Guide 4 3 4 4 4 5 4 6 A A Dry out Period WARNING Before initial use after transport and any time the instru ment has not been energized for more than 10 days the instrument needs to be energized for a dry out period of 1 2 hours before it can be as sumed to meet all of the safety requirements of the IEC 1010 1 If the product is wet or has been in a wet environment take necessary measures to remove moisture prior to applying power such as storage in a low hu midity temperature chamber operating at 50 C for 4 hours or more Power The furnace utilizes a grounded AC supply of 230 VAC 10 20 amps sin gle phase 50 60 HZ An eight foot 2 conductor with ground power cord is pro vided A separate g
48. round connection is provided and required to permanently connect the instrument to earth ground for added operator safety WARNING Ensure accessability to the mains plug for disconnection from supply source Equilibration Block Assembly Installation After the furnace has been installed and the permanent earth ground appropri ately attached the equilibration block assembly may be inserted Carefully in sert the block assembly into the tube with its insulation packing per Figure 1 Extreme care should be taken installing the Equilibration Block since it is very heavy and the fused silica tube is very fragile A 1 8 to inch air gap between the front access plate and the front panel of the furnace is required in order to prevent the front panel from getting too hot Care must be taken to prevent dirt insulation or anything else from getting between the block and the fused silica tube or it might break during heat up due to thermal expansion differences The fit between the block and the tube is typically loose in order to accommodate this expansion CAUTION If the furnace must be moved for any reason remove the block assembly to prevent breakage of the fused silica tube Probe Installation Install the temperature control and over temperature cutout probes from the as shown in Figure 1 and Figure 3 Insert the probes carefully to the depth shown in order to insure that the sensor is properly located in the equilibration block The contro
49. rsist seek medical attention NOTE TO PHYSICIANS Skin and respiratory effects are the result of temporary mild mechanical irritation fiber exposure does not result in allergic manifestations 5 FIRE FIGHTING MEASURES NFPA Codes Flammability 0 Health 1 Reactivity 0 Special _0_ NFPA Unusual Hazards None Flammable Properties None Flash Point None Hazardous Decomposition Products None Unusual Fire and Explosion Hazard None Extinguishing Media Use extinguishing media suitable for type of surrounding fire 6 ACCIDENTAL RELEASE MEASURES SPILL PROCEDURES Avoid creating airborne dust Dust suppressing cleaning methods such as wet sweeping or vacuuming should be used to clean the work area If vacuuming the vacuum should be equipped with a HEPA filter Compressed air or dry sweeping should not be used for cleaning 7 HANDLING AND STORAGE STORAGE Store in original factory container in a dry area Keep container closed when not in use HANDLING Limit use of power tools unless in conjunction with local exhaust Use hand tools whenever possible Frequently clean the work area with HEPA filtered vacuum or wet sweeping to minimize the accumulation of debris Do not use compressed air for clean up EMPTY CONTAINERS Do not reuse the container Page 2 Of 7 MATERIAL SAFETY DATA SHEET MSDS No 350 Date Prepared 03 24 1992 Current Date 7 26 2002 Last Revised 03 20 2002 8 EXPOSURE CONTROLS
50. separately rinse washer before washing other household clothes etc Eye Protection Wear safety glasses with side shields or other forms of eye protection in compliance with appropriate OSHA standards to prevent eye irritation The use of contact lenses is not recommended unless used in conjunction with appropriate eye protection Do not touch eyes with soiled body parts or materials If possible have eye washing facilities readily available where eye irritation can occur Respiratory Protection When it is not possible or feasible to reduce respirable dust exposures through engineering controls employees are encouraged to use good work practices together with respiratory protection Comply with OSHA Respiratory Protection Standards 29 CFR 1910 134 and 29 CFR 1926 103 for the particular hazard or airborne concentrations to be encountered in the work environment For the most current information on respirator selection contact your supplier 9 PHYSICAL AND CHEMICAL PROPERTIES ODOR AND APPEARANCE White odorless material with a wool type appearance CHEMICAL FAMILY Calcium Magnesium Silicate Mixture BOILING POINT Not Applicable WATER SOLUBILITY Slight MELTING POINT 1275 1300 C 2327 2372 F SPECIFIC GRAVITY RANGE 2 5 3 0 VAPOR PRESSURE Not Applicable pH Not Applicable VAPOR DENSITY Air 1 Not Applicable VOLATILE Not Applicable MOLECULAR FORMULA Not Applicable Page 3 Of 7 MATERIAL
51. setting while the upper display shows the actual temperature When scanning from one temperature to another notice that the temperature controller seems to be ahead of the equilibration block temperature This differ ence is because the temperature control sensor is near the outside of the block and it takes some time for the heat to conduct into the center Depend on an ex ternal temperature monitor to establish when the equilibration block has reached the desired temperature and achieved stability The actual temperature indication made by the temperature controller is not in tended to be a calibration reference but to merely provide a general indication of the furnace temperature NIST traceable standard thermometers are available and should be used in making comparison measurements For less stringent measurements you may make a calibration of the controller and control probe at particular temperature points and use that with reasonable accuracy for a time 23 9112A Calibration Furnace User s Guide 24 A A CAUTION Take care that all sensors used as references or being cali brated in the furnace are capable of withstanding the desired temperature range to be used WARNING A Take extreme care in handling hot probes The ex treme temperatures generated in a furnace of this type can cause serious personal injury Do not touch them on external surfaces of the furnace or set them on any other surfaces unable to withstand thos
52. t temperatures of approximately 1200 C 2192 F The occurrence and extent of crystalline phase formation is dependent on the duration and temperature of exposure fiber chemistry and or the presence of fluxing agents The presence of crystalline phases can be confirmed only through laboratory analysis of the hot face fiber IARC s evaluation of crystalline silica states Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans Group 1 and additionally notes carcinogenicity in humans was not detected in all industrial circumstances studied IARC Monograph Vol 68 1997 NTP lists all polymorphs of crystalline silica amongst substances which may reasonably be anticipated to be carcinogens IARC and NTP did not evaluate after service RCF which may contain various crystalline phases However an analysis of after service RCF samples obtained pursuant to an exposure monitoring agreement with the USEPA found that in the furnace conditions sampled most did not contain detectable levels of crystalline silica Other relevant RCF studies found that 1 simulated after service RCF showed little or no activity where exposure was by inhalation or by intraperitoneal injection and 2 after service RCF was not cytotoxic to macrophage like cells at concentrations up to 320 g cm by comparison pure quartz or cristobalite were significantly active at much lower levels circa 20 g c
53. tection Do not touch eyes with soiled body parts or materials If possible have eye washing facilities readily available where eye irritation can occur 9 PHYSICAL AND CHEMICAL PROPERTIES ODOR AND APPEARANCE White odorless fibrous material CHEMICAL FAMILY Vitreous Aluminosilicate Fibers BOILING POINT Not Applicable WATER SOLUBILITY Not Soluble in Water MELTING POINT 1760 C 3200 F SPECIFIC GRAVITY 2 50 2 75 VAPOR PRESSURE Not Applicable pH Not Applicable VAPOR DENSITY Air 1 Not Applicable VOLATILE Not Applicable MOLECULAR FORMULA Not Applicable 10 STABILITY AND REACTIVITY CHEMICAL STABILITY Stable under conditions of normal use INCOMPATIBILITY Soluble in hydrofluoric acid phosphoric acid and concentrated alkali CONDITIONS TO AVOID None HAZARDOUS DECOMPOSITION None PRODUCTS HAZARDOUS POLYMERIZATION Not Applicable 11 TOXICOLOGICAL INFORMATION HEALTH DATA SUMMARY Epidemiological studies of RCF production workers have indicated no increased incidence of respiratory disease nor other significant health effects In animal studies long term high dose inhalation exposure resulted in the development of respiratory disease in rats and hamsters EPIDEMIOLOGY The University of Cincinnati is conducting an ongoing epidemiologic investigation The evidence obtained from employees in U S RCF manufacturing facilities is as follows 1 There is no evidence of any fibrotic
54. tewardship Information Hotline at 1 800 322 2293 or refer to the RCFC web site http www rcfc net DEFINITIONS ACGIH ADR CAA CAS CERCLA DSL EPA EU fice HEPA HMIS IARC IATA IMDG mg m mmpcf NFPA NIOSH OSHA 29 CFR 1910 134 8 1926 103 29 CFR 1910 1200 amp 1926 59 PEL PIN PNOC PNOR PSP RCFC RCRA REG REL RID SARA SARA Title III SARA Section 302 SARA Section 304 SARA Section 311 SARA Section 312 SARA Section 313 STEL SVF TDG TLV American Conference of Governmental Industrial Hygienists Carriage of Dangerous Goods by Road International Regulation Clean Air Act Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Domestic Substances List Environmental Protection Agency European Union Fibers per cubic centimeter High Efficiency Particulate Air Hazardous Materials Identification System International Agency for Research on Cancer International Air Transport Association International Maritime Dangerous Goods Code Milligrams per cubic meter of air Million particles per cubic meter National Fire Protection Association National Institute for Occupational Safety and Health Occupational Safety and Health Administration OSHA Respiratory Protection Standards OSHA Hazard Communication Standards Permissible Exposure Limit OSHA Product Identification Number Particulates Not Otherwise Classified
55. tion and temperature of exposure CMS Wool chemistry and or the presence of fluxing agents The presence of crystalline silica can be confirmed only through laboratory analysis of the hot face fiber If crystalline silica is present follow appropriate hygiene standards and national regulations Devitrified after service Superwool containing crystalline silica has shown no adverse reactions in toxicity assays See Section 11 These findings are consistent with IARC s evaluation which states Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans Group 1 and additionally notes carcinogenicity in humans was not detected in all industrial circumstances studied Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs IARC Monograph Vol 68 1997 Respirable dust from devitrified Superwool products can be controlled with ventilation dust collectors or respiratory protection as detailed in Section 8 above Ventilation and respiratory protection should be provided in compliance with OSHA standards The evaluation of workplace hazards and if necessary the identification of appropriate respiratory protection is best performed by qualified Industrial Hygienists For more information call the Thermal Ceramics Product Stewardship Hotline 800 722 5681
56. tories Fibers Aluminosilicate 142844 00 6 100 See Section 8 Exposure Controls Personal Protection for exposure guidelines 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING POSSIBLE CANCER HAZARD BY INHALATION See Section 11 for more information CHRONIC EFFECT There has been no increased incidence of respiratory disease in studies examining occupationally exposed workers In animal studies long term laboratory exposure to doses hundreds of times higher than normal occupational exposures has produced fibrosis lung cancer and mesothelioma in rats or hamsters The fibers used in those studies were specially sized to maximize rodent respirability OTHER POTENTIAL EFFECTS TARGET ORGANS Respiratory Tract nose amp throat Eyes Skin RESPIRATORY TRACT nose amp throat IRRITATION If inhaled in sufficient quantity may cause temporary mild mechanical irritation to respiratory tract Symptoms may include scratchiness of the nose or throat cough or chest discomfort EYE IRRITATION May cause temporary mild mechanical irritation Fibers may be abrasive prolonged contact may cause damage to the outer surface of the eye SKIN IRRITATION May cause temporary mild mechanical irritation Exposure may also result in inflammation rash or itching GASTROINTESTINAL IRRITATION Unlikely route of exposure MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Pre existing medical conditions inclu
57. tory effects are the result of temporary mild mechanical irritation fiber exposure does not result in allergic manifestations 5 FIRE FIGHTING MEASURES NFPA Codes Flammability 0 Health 1 Reactivity 0 Special 0 NFPA Unusual Hazards None Flammable Properties None Flash Point None Hazardous Decomposition Products None Unusual Fire and Explosion Hazard None Extinguishing Media Use extinguishing media suitable for type of surrounding fire 6 ACCIDENTAL RELEASE MEASURES SPILL PROCEDURES Avoid creating airborne dust Dust suppressing cleaning methods such as wet sweeping or vacuuming should be used to clean the work area If vacuuming the vacuum must be equipped with a HEPA filter Compressed air or dry sweeping should not be used for cleaning 7 HANDLING AND STORAGE STORAGE Store in original container in a dry area Keep container closed when not in use HANDLING Handle ceramic fiber carefully Limit use of power tools unless in conjunction with local exhaust Use hand tools whenever possible Frequently clean the work area with HEPA filtered vacuum or wet sweeping to minimize the accumulation of debris Do not use compressed air for clean up EMPTY CONTAINERS Product packaging may contain residue Do not reuse 8 EXPOSURE CONTROLS PERSONAL PROTECTION EXPOSURE GUIDELINES COMPONENTS OSHA PEL MANUFACTURER REG None Established Pe f cc 8 hr TWA Refractories
58. ult 9112A Calibration Furnace User s Guide 1 2 2 ELECTRICAL HAZARD These guidelines must be followed to ensure that the safety mechanisms in this instrument will operate properly This instrument must be plugged into a 230 VAC 10 50 60 Hz only electric outlet The power cord of the instrument 1s equipped with a three pronged grounding plug for your protection against electrical shock hazards It must be plugged directly into a properly grounded three prong receptacle The receptacle must be installed in accordance with lo cal codes and ordinances or adapter plug Additionally the instrument has a Permanent Earth Ground that must be connected during use DO NOT use an extension cord Consult a qualified electrician Always replace the power cord with an approved cord of the correct rating and type If you have questions contact a Hart Scientific Authorized Service Center see Section 1 3 The instrument is not equipped with easily accessible fuses The fuses are lo cated inside the control drawer We do not recommend replacing the fuses with out calling a Hart Scientific Authorized Service Center first High voltage is used in the operation of this equipment Severe injury or death may result if personnel fail to observe the safety precautions Before working inside the equipment turn off the power and disconnect the power cord Always ensure that the equilibration block ground is connection prior to use of the instrume
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