First Alert 1-A:10-B:C MSDS
Contents
1. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE None known FOR ENVIRONMENT _ No data available 4 FIRST AID MEASURES Eye Contact Flush with water for a minimum of 15 minutes while holding lids open If irritation persists seek medical attention Skin Contact Wash affected area with soap and water If irritation persists seek medical attention Inhalation Remove from exposure If irritation persists seek medical attention Ingestion If patient is conscious give large amounts of water and induce vomiting Seek medical help FORAY Continued Page 3 5 7 2 7 3 8 2 9 2 FIRE FIGHTING MEASURES This preparation is an extinguishing media There are NO extinguishing media which must not be used for safety reasons NO special protective equipment is needed for fire fighters Wear protective equipment appropriate for the fire conditions ACCIDENTAL RELEASE MEASURES For personal protection Prevent skin and eye contact see Heading 8 Clean up Sweep up and recover for use or place in closed container for disposal see Heading 13 NO harm to the environment is expected from an accidental release of this preparation HANDLING AND STORAGE Handling Care should be taken in handling all chemical substances and preparations See incompatibility information in Heading 10 Storage NO special conditions are needed for safe storage See incompatibility information in Heading 10 Store in original container or Ans2. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS This product is rated D2B Product may irritate skin eyes or mucous membranes Format is from directive 2001 58 EC EINECS data is from http ecb jrc it existing chemicals Data used to compile the data sheet is from Ansul Material Safety Data Sheet March 2003 Toxicological information added from the EINECS ESIS Existing Substances Information System A rating under WHMIS has been added following the Canadian guidelines DISCLAIMER THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE ANSUL SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT MSDS available at http Avww ansul com ANSUL and FORAY are trademarks of Tyco International Ltd or its affiliates TYCO FIRE SUPPRESSION amp BUILDING PRODUCTS MARINETTE WI 54143 2542 715 735 7411 Form No F 9751 6 Copyright 2009 Tyco International Ltd
3. rinse immediately with plenty of water and seek medical advice 36 Wear suitable protective clothing Components Monoammonium Phosphate EU Classification Xn Harmful R Phrases 22 Harmful if swallowed 36 37 38 Irritating to eyes respiratory system and skin S Phrases 26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 36 Wear suitable protective clothing Ammonium sulfate EU Classification Xi Irritant R Phrases 36 37 38 Irritating to eyes respiratory system and skin S Phrases 26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 36 Wear suitable protective clothing Limit Values for Exposure Nuisance dust limit OSHA TWA 15 mg m3 ACGIH TLV TWA 10 mg m8 Neither this preparation nor the substances contained in it have been listed as carcinogenic by National Toxicology Program IARC or OSHA AS PART OF GOOD INDUSTRIAL AND PERSONAL HYGIENE AND SAFETY PROCEDURE avoid all unnecessary exposure to the chemical components and ensure prompt removal from skin eyes and clothing SIGNS AND SYMPTOMS Acute Exposure Eye Contact Mildly irritating for short periods of time Skin Contact May be mildly irritating Inhalation Treat as a mineral dust Irritant to the respiratory tract Transient cough shortness of breath Ingestion Not an expected route of entry Chronic Overexposure Inhalation Chronic fibrosis of the lung pneumoconiosis
4. AN S U L ANSUL INCORPORATED MARINETTE WI 54143 2542 1 1 1 2 1 3 1 4 FORAY MATERIAL SAFETY DATA SHEET CONFORMS TO DIRECTIVE 2001 58 EC IDENTIFICATION OF THE SUBSTANCE PREPARATION AND OF THE COMPANY UNDERTAKING Identification of the preparation Product Name Chemical Name CAS No Chemical Formula EINECS Number Use of the preparation FORAYe N A This is a mixture preparation N A This is a mixture preparation N A This is a mixture preparation N A This is a mixture preparation The intended or recommended use of this preparation is as a FIRE EXTINGUISHING AGENT Company identification Manufacturer Supplier ANSUL INCORPORATED Address Prepared by Phone Internet Home Page Date of Issue Emergency telephone One Stanton Street Marinette WI 54143 2542 Safety and Health Department 715 735 7411 http www ansul com September 2009 CHEMTREC 800 424 9300 or 703 527 3887 COMPOSITION INFORMATION ON INGREDIENTS Ingredient Name Chemical Formula CAS No EINECS Number Concentration Wt Hazard Identification Ingredient Name Chemical Formula CAS No EINECS Number Concentration Wt Hazard Identification Ingredient Name Chemical Formula CAS No EINECS Number Concentration Wt Hazard Identification Ingredient Name Chemical Formula CAS No EINECS Number Concentration Wt Hazard Identification Ingredient Name Chemical
5. Formula CAS No EINECS Number Concentration Wt Hazard Identification Monoammonium Phosphate NH4H2PO4 7722 76 1 231 764 5 65 82 See Heading 3 Ammonium sulfate NH4 2504 7783 20 2 231 984 1 12 25 See Heading 3 Magnesium Aluminum Silicate Attapulgite Clay or Fuller s Earth Mg Al SiO4 7 8031 18 3 b 5 7 See Heading 3 Calcium Carbonate CaCO 471 34 1 207 439 9 lt 2 See Heading 3 Methyl Hydrogen Polysiloxane Mixture preparation 63148 57 2 a lt 1 See Heading 3 FORAY Continued Page 2 Ingredient Name Yellow Pigment Chemical Formula C34H30Cl2N604 CAS No 5468 75 7 EINECS Number 226 789 3 Concentration Wt lt 0 05 Hazard Identification See Heading 3 a EINECS does not include synthetic polymers these are registered in EINECS under their building blocks monomers See 67 548 EEC article 13 79 831 EC and 81 437 EC b EINECS does not include most naturally occurring raw materials See 67 548 EEC article 13 79 831 EC and 81 437 EC NOTE Unless a component presents a severe hazard it does not need to be considered in the MSDS if the concentration is less than 1 According to Directive 1999 45 EC 3 HAZARDS IDENTIFICATION FOR HUMANS Product EU Classification Xn Harmful R Phrases 22 Harmful if swallowed 36 37 38 Irritating to eyes respiratory system and skin S Phrases 26 In case of contact with eyes
6. ation 13 Dispose of in compliance with national regional and local provisions that may be in force FORAY Continued Page 5 14 15 16 17 TRANSPORT INFORMATION Hazard Class or Division Not a hazardous substance For additional transport information contact Ansul Incorporated No harm to the environment is expected from this preparation REGULATORY INFORMATION Product EU Classification Xn Harmful R Phrases 22 Harmful if swallowed 36 37 38 Irritating to eyes respiratory system and skin S Phrases 26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 36 Wear suitable protective clothing Limit Values for Exposure Nuisance dust limit OSHA TWA 15 mg m3 ACGIH TLV TWA 10 mg m8 EINECS Status All components are included in EINECS inventories or are exempt from listing EPA TSCA Status All components are included in TSCA inventories or are exempt from listing Canadian DSL Domestic Substances List All components are included in the DSL or are exempt from listing Environmental restrictions None are known Restrictions on Marketing and Use None are known Refer to any other national measures that may be relevant OTHER INFORMATION HMIS HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS HEALTH 1 4 Severe Hazard FLAMMABILITY Serious Hazard REACTIVITY Moderate Hazard Slight Hazard Minimal Hazard o o WHMIS CANADIAN WORKPLACE
7. tition coefficient n octanol water Not determined Viscosity Not applicable Vapor density Air 1 Not applicable Evaporation rate Not applicable Other information Auto ignition temperature Does not ignite STABILITY AND REACTIVITY Conditions to avoid There are NO known conditions such as temperature pressure light shock etc which may cause a dangerous reaction Materials to avoid Strong alkalis magnesium oxidizers that can release chlorine or produce Nce3 explosive per NFPA 10 Annex A 2 1 Hazardous decomposition products Normally stable Hazardous polymerization will NOT occur Ammonia and or phosphorous oxides can be evolved at very high temperatures TOXICOLOGICAL INFORMATION This product has not been tested for toxicological effects Product is treated as a nuisance dust 12 12 1 12 2 12 3 12 4 12 5 Components Monoammonium Phosphate Material is irritating Harmful if swallowed Ammonium sulfate Toxicity Data Oral rat LDso 2840 mg kg Target Organs Lungs and gastrointestinal ECOLOGICAL INFORMATION Ecotoxicity Not determined Mobility Not determined Persistence and degradability Not determined Bioaccumulative potential Not determined Other adverse effects Ozone depletion potential None Photochemical ozone creation potential None Global warming potential None DISPOSAL CONSIDERATIONS NO harm to the environment is expected from this prepar
8. ul fire extinguisher Keep tightly closed until used There is minimal danger to the environment from a storage release Specific use The intended or recommended use of this preparation is as a FIRE EXTINGUISHING AGENT EXPOSURE CONTROLS PERSONAL PROTECTION Exposure limit values Nuisance dust limit OSHA TWA 15 mg m3 ACGIH TLV TWA 10 mg m8 Exposure controls 8 2 1 Occupational exposure controls 8 2 1 1 Respiratory protection Dust mask where dustiness is prevalent or TLV is exceeded Use mechanical filter respirator if exposure is prolonged 8 2 1 2 Hand protection None normally needed Use chemical resistant gloves when handling the preparation 8 2 1 3 Eye protection Use safety glasses with side shields or safety goggles 8 2 1 4 Skin protection No special equipment is needed 8 2 2 Environmental exposure controls No special controls are needed PHYSICAL AND CHEMICAL PROPERTIES General information Appearance Yellow powder Odor No odor Important health safety and environmental information pH Not determined Boiling point boiling range Not applicable Flash point None Flammability solid gas Not flammable Explosive properties Not explosive Oxidizing properties Not an oxidizer FORAY Continued Page 4 9 3 10 10 1 10 2 10 3 11 Vapor Pressure Not applicable Relative Density Not applicable Solubility Water solubility Slight Fat solubility Not soluble Par
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