Duracell 7k 67 User's Manual
Contents
1. covered by this MSDS in their original form are considered dry cell batteries and are not regulated for transportation as DANGEROUS GOODS The batteries must be packaged in a manner that prevents the generation of a dangerous quantity of heat and short circuits For finished packaged product transported by ground US DOT not regulated For finished packaged product transported by sea IMDG not regulated For finished packaged product transported by air IATA not regulated GMEL 2002 9 Page 4 of 6 Special provisions apply and shippers should consult the most current versions of the transportation regulations SECTION 15 REGULATORY INFORMATION United States OSHA Status While the finished product s is considered an article and not covered by the OSHA Hazard Communication Standard 29 CFR 1910 1200 this MSDS contains valuable information critical to the safe handling and proper use of the product EPA TSCA Status All intentionally added components of this product are listed on the US TSCA Inventory SARA 313 302 304 311 312 chemicals Manganese compounds 35 40 Zinc 10 25 California This product has been evaluated and does not require warning labeling under California Proposition 65 State Right to Know and CERCLA The following ingredients present in the finished product are listed on state right to know lists or state worker exposure lists Ingredient CA2. I puRACELL Material Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Product Name DURACELL ALKALINE BATTERIES Product Identification Alkaline Manganese Dioxide Cells Duracell Designations 7K67 MN1203 MN1300 MN1400 MN1500 MN2400 MN1604 MN908 MN918 MN9100 MX1604 MX2500 MX1300 MX1400 MX1500 MX2400 Product Use Energy Source MSDS Date of Preparation July 1 2008 Company Identification US Office Canadian Office Duracell a division of P amp G Duracell a division of P amp G Berkshire Corporate Park 4711 Yonge Street 14 Research Drive Toronto Ontario Bethel CT USA 06401 Canada M2N 6K8 203 796 4000 416 730 4711 Emergency Phone Number INFOTRAC Emergency Response Hotline 1 800 535 5053 US amp Canada SECTION 2 HAZARDS IDENTIFICATION Physical Appearance Copper top battery EMERGENCY OVERVIEW CAUTION May explode or leak and cause burn injury if recharged disposed of in fire mixed with a different battery type inserted backwards or disassembled Replace all used batteries at the same time Do not carry batteries loose in your pocket or purse Do not remove the battery label Potential Health Effects The chemicals and metals in this product are contained in a sealed can Exposure to the contents will not occur unless the battery leaks is exposed to high temperatures or is mechanically physically or electrically abused Damaged battery will release concentrated pot
3. S Level CERCLA State RQ IL MA NJ PA RI Manganese Dioxide 1313 13 9 35 40 None Y Y N Y Y Zinc 7440 66 6 10 25 1000 lb Y Y Y Y N Potassium Hydroxide 1310 58 3 5 10 1000 Ib Y Y Y Y Y Graphite 7182 42 5 1 5 None Y Y N Y Y 7440 44 0 Canada All intentionally added components of this product are listed on the Canadian DSL This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations CPR and this MSDS contains all information required by the Controlled Products Regulations SECTION 16 OTHER INFORMATION P amp G Hazard Rating Health 0 Fire 0 Reactivity 0 Data supplied is for use only in connection with occupational safety and health DISCLAIMER This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material The information contained here has been compiled from sources considered by Procter amp Gamble to be dependable and is accurate to the best of the Company s knowledge It is not meant to be an all inclusive document on worldwide hazard communication regulations This information is offered in good faith Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures property damage GMEL 2002 9 Page 5 of 6 or release to the environment Procter amp Gamble assumed no respons
4. assium hydroxide which is caustic Anticipated potential leakage of potassium hydroxide is 2 to 20 mL depending on battery size Eye Contact Contact with battery contents may cause severe irritation and burns Eye damage is possible Skin Contact Contact with battery contents may cause severe irritation and burns Inhalation Inhalation of vapors or fumes released due to heat or a large number of leaking batteries may cause respiratory and eye irritation Ingestion Swallowing is not anticipated due to battery size Choking may occur if smaller AAA batteries are swallowed Ingestion of battery contents from a leaking battery may cause mouth throat and intestinal burns and damage GMEL 2002 9 Page 1 of 6 SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS Chemical Name CAS Number Amount Manganese Dioxide 1313 13 9 35 40 Zinc 7440 66 6 10 25 Potassium Hydroxide 35 1310 58 3 5 10 Graphite natural or synthetic 7782 42 5 7440 44 0 1 5 SECTION 4 FIRST AID MEASURES Eye Contact If battery is leaking and material contacts the eye flush thoroughly with copious amounts of running water for 30 minutes Seek immediate medical attention Skin Contact If battery is leaking and material contacts the skin remove any contaminated clothing and flush exposed skin with copious amounts of running water for at least 15 minutes If irritation injury or pain persists seek medical a
5. espirable dust 15 mg m3 TWA total dust OSHA PEL 2 mg m3 TWA respirable dust ACGIH TLV Ventilation No special ventilation is needed for normal use Respiratory Protection None required for normal use Skin Protection None required for normal use Use neoprene rubber or latex gloves when handling leaking batteries Eye Protection None required for normal use Wear safety goggles when handling leaking batteries SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor Copper top battery Specific Gravity Not applicable Boiling Point Not applicable Water Solubility Insoluble Melting Point Not applicable Vapor Pressure Not applicable Flash Point Not applicable Vapor Density Not applicable Autoignition Point Not applicable SECTION 10 STABILITY AND REACTIVITY Stability This product is stable Incompatibility Conditions to Avoid Contents are incompatible with strong oxidizing agents Do not heat crush disassemble short circuit or recharge GMEL 2002 9 Page 3 of 6 Hazardous Decomposition Products Thermal decomposition may produce hazardous fumes of zinc and manganese caustic vapors of potassium hydroxide and other toxic by products Hazardous Polymerization Will not occur SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity Data Manganese Dioxide LD50 oral rat gt 3478 mg kg Potassium Hydroxide LDS0 oral rat 273 mg kg Chronic Effects The chemica
6. ibility for injury to the recipient or third persons or for any damage to any property resulting from misuse of the product GMEL 2002 9 Page 6 of 6
7. ls in this product are contained in a sealed can and exposure does not occur during normal handling and use No chronic effects would be expected from handling a leaking battery Target Organs Skin eyes and respiratory system Carcinogenicity None of the components of this product are listed as carcinogens by ACGIH IARC NTP or OSHA SECTION 12 ECOLOGICAL INFORMATION No ecotoxicity data is available This product is not expected to present an environmental hazard SECTION 13 DISPOSAL INFORMATION Disposal should be in accordance with Federal state provincial and local regulations Products covered by this MSDS in their original form when disposed as waste are considered non hazardous waste according to Federal RCRA regulations 40 CFR 261 Alkaline batteries can be safely disposed of with normal household waste Due to concerns about mercury in the municipal solid waste stream Duracell has voluntarily eliminated all of the added mercury from its alkaline batteries since 1993 Individual consumers may dispose of spent used batteries with household trash Duracell does not recommend that spent batteries be accumulated and disposed of in large quantities Do not incinerate except for disposal in a controlled incinerator Some communities offer recycling or collection of alkaline batteries contact your local government for disposal practices in your area SECTION 14 TRANSPORT INFORMATION Products
8. r appropriate protective clothing to avoid eye and skin contact and inhalation of vapors or fumes Increase ventilation Carefully collect batteries and place in an appropriate container for disposal GMEL 2002 9 Page 2 of 6 SECTION 7 HANDLING AND STORAGE Avoid mechanical or electrical abuse DO NOT short circuit or install incorrectly Batteries may explode pyrolize or vent if disassembled crushed recharged or exposed to high temperatures Install batteries in accordance with equipment instructions Do not mix battery systems such as alkaline and zinc carbon in the same equipment Replace all batteries in equipment at the same time Do not carry batteries loose in a pocket or bag Do not remove battery tester or battery label Storage Store batteries in a dry place at normal room temperature Do not refrigerate this will not make them last longer SECTION 8 EXPOSURE CONTROLS PERSONAL PROTECTION The following occupational exposure limits are provided for informational purposes No exposure to the battery components should occur during normal consumer use Chemical Name Exposure Limits Manganese Dioxide 5 mg m3 Ceiling OSHA PEL 0 2 mg m3 TWA ACGIH TLV Zinc None established for zinc metal Potassium Hydroxide 2 mg m3 Ceiling ACGIH TLV Graphite natural non fibrous 15 mppef TWA OSHA PEL 2 mg m3 TWA respirable dust ACGIH TLV Graphite synthetic non fibrous 5 mg m3 TWA r
9. ttention Inhaled If battery is leaking contents may be irritating to respiratory passages Move to fresh air If irritation persists seek medical attention Swallowed If battery contents are swallowed do not induce vomiting If the victim is alert have them rinse their mouth are the surrounding skin with water for at least 15 minutes Seek immediate medical attention Note This MSDS does not include or address the small button cell batteries which can be ingested SECTION 5 FIRE FIGHTING MEASURES Fire and Explosion Hazards Batteries may burst and release hazardous decomposition products when exposed to a fire situation Extinguishing Media Use any extinguishing media that is appropriate for the surrounding fire Special Fire Fighting Procedures Firefighters should wear positive pressure self contained breathing apparatus and full protective clothing Fight fire from a distance or protected area Cool fire exposed batteries to prevent rupture Use caution when handling fire exposed containers containers may rocket or explode in heat of fire Hazardous Combustion Products Thermal degradation may produce hazardous fumes of zinc and manganese hydrogen gas caustic vapors of potassium hydroxide and other toxic by products SECTION 6 ACCIDENTAL RELEASE MEASURES Notify safety personnel of large spills Caustic potasstum hydroxide may be released from leaking or ruptured batteries Clean up personnel should wea
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