Lanier 4800021
Contents
1. Inhalation should be avoided May cause temporary eye discomfort Health Hazards of Long Term exposure Chronic A manufacturer sponsored chronic inhalation study in rats using a special test toner revealed there were no lung changes at all in the lowest exposure level 1mg m the most relevant level to potential human exposures A very slight degree of fibrosis was noted in 25 of the animals at the middle exposure level 4mg m while a slight degree of fibrosis was observed at the highest exposure level 16mg m in all animals These findings are attributed to Lung Overloading a generic response to excessive amount of any dust retained in the lungs for a prolonged interval The special test toner was ten times more respirable than commercially available toner to comply with EPA testing protocol and would not function properly in Xerographic equipment Carbon Black is listed on the IARC Monograph and the Massachusetts Substance List The IARC has evaluated the evidence for the carcinogenicity of Carbon Black as inadequate to determine a carcinogenic risk for humans This product contains no known hazardous materials as defined by the OSHA Hazard Communication Standard 29 CFR 1910 1200 Section 4 First Aid Measures Remove to fresh air if effects occur Gargle with In case of contact immediately flush eyes with Inhalation water Get medical attention if needed Eye Contact water for 15 minutes Get medical attention if needed Dilute s2. LANIER Lanier Worldwide Inc 2300 Parklake Dr N E Atlanta GA 30345 2979 Emergency Telephone 800 526 4371 MATERIAL SAFETY DATA SHEET Section 1 Chemical Product and Company Information Identity Black Toner for 5365 MSDS No CP 332 Product ID 480 0021 Issued 05 22 2003 Supersedes 04 30 2001 Synonyms Date 05 22 03 amp Common Black Toner for Prepared by EH amp S Department 770 496 9500 Names Lanier 5365 5355 5555 5565 5580 5480 Approved by Larry Choskey Manager CEH amp S European Contact Walter Fricke Manager Safety amp Environment Uses Lanier 5365 5355 5555 5565 5580 5480 Lanier Worldwide Inc Digital Copier Im Taubental D 41468 Neuss Germany Chemical 49 2131 387 177 Formula Mixture Section 2 Composition Information on Ingredients PERCENT CAS No EXPOSURE LIMITS SOURCE Styrene acrylate copolymer gt 90 25036 16 2 N a N a 9010 79 1 Carbon black 5 7 1333 86 4 3 5mg m 3 5mg m OSHA PEL ACGIH TWA Inorganic pigment 1 2 25869 00 5 N a N a Organic pigment 1 2 104815 18 1 N a N a PEL as the product 15mg m total dust 5mg m respirable dust TLV as the product 10mg m total dust 5mg m respirable dust Section 3 Hazards Identification HMIS Rating FLAMMABILITY 1 HEALTH 0 REACTIVITY 0 SPECIAL none Health Hazards Acute Chronic Immediate and Potential Minimum irritation to respiratory tract may occur as with exposure to any non toxic dust May cause gasping if inhaled
3. andling of this product under normal conditions On the basis of the data available to us this product is not a dangerous substance One should however observe the usual precautionary measures for dealing with chemicals MATERIAL SAFETY DATA SHEET Page 3 of CP 332 Judgment as to the suitability of information contained herein for user s purposes is the responsibility of the purchaser Therefore although reasonable care has been taken in the preparation of this information Lanier Worldwide Inc extends no warranties makes no representations and assumes no responsibility as to the accuracy or suitability of such information for application to user s intended purposes or for consequences of its use All materials may present unknown hazards and should be used with caution Although certain hazards are described herein we do not guarantee that these are the only hazards that exist Information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions On the basis of the data available to us this product is not a dangerous substance One should however observe the usual precautionary measures for dealing with chemicals
4. ified as irritant according to OSHA Haz Com Standard and EU Directive 67 548 EEC based on test data of rabbits Sensitizer No sensitizer according to Annex of EU Directive 67 548 EEC and strong sensitizer list of FHSA Mutagenicity Ames test negative Reproductive Toxicity No reproductive toxic substances according to Annex of EU Directive 67 548 EEC California Proposition 65 and DFG Carcinogenicity Carbon Black IARC 2B Possible human carcinogen based on animal testing Not listed in NTP OSHA USA regulation California Proposition 65 and Annex of EU Directive 67 548 EEC Section 12 Environmental Ecological Information No information indicating any adverse ecological effects Section 13 Disposal Consideration Used Toner should be disposed of under conditions that meet all federal state and local environmental regulations Disposal regulations vary from locality to locality therefore consult your local Lanier office or the EPA to determine the proper method for disposal Do not incinerate loose or spilled Toner Empty plastic container may be recycled Section 14 Transportation Information None This is not a hazardous product Section 15 Regulatory Information SARA Title Ill 313 none TSCA All chemical substances in this product comply with all applicable rules or orders under TSCA Section 16 Miscellaneous Information Information on this data sheet represents our current data and best opinion as to the proper use in h
5. ter eyes Minimize inhalation of dust Cleanse skin thoroughly after contact before breaks and meals and at end of work periods Section 8 Exposure Control and Personal Protection Information Respiratory Protection none required under normal use Hand Protection none required under normal use Eye Protection none required under normal use Ventilation Local exhaust equipment is needed Skin Protection none required under normal use Exposure Guidelines USA OSHA TWA PEL 15mg m Total Dust 5mg m Respirable fraction ACGIH TWA TLY 10mg m Total dust 3mg m Respirable fraction DFG MAK 6mg m Total dust Section 9 Physical and Chemical Properties CHARACTERISTICS Appearance Black Melting point 110 150 C softening point Form Powder Vapor pressure n a Odor Odorless Vapor density n a Solubility in Water Negligible Evaporation rate n a Density 1 1 1 5 Boiling point n a Flammability N a Fat solubility N a Section 10 Stability and Reactivity Conditions to avoid none Materials to avoid none Stability Stable Hazardous decomposition products CO and CO2 and other decomposition products when burned Section 11 Toxicological Information Acute Toxicity Inhalation Data from similar material without ferrite LC50 gt 5 19mg L 4hr rats Mean maximum attainable concentration Ingestion Data from ingredients of toner LD50 gt 5000mg kg rats Eye Data from ingredients of toner Not class
6. tomach contents with several glasses of water Get medical attention if needed Section 5 Fire Fighting Measures Suitable extinguishing media COs dry chemical foam or water Unusual Fire and Explosion Hazards Toner material like most Extinguishing media which may not be used for safety reasons none organic material in powcered form is capable of creating a dust explosion Flammability Product will burn in case of fire The decomposition products are CO COz and No Avoid inhalation of smoke Special protective equipment for fire fighters none UEL n a LEL n a Section 6 Accidental Release Measures Skin Contact Wash with soap and water Ingestion MATERIAL SAFETY DATA SHEET Page 2 of CP 332 Spill leak Procedures If spilled sweep up using an approved toner vacuum with a 0 5 micron filter or smaller such as the Atrix AAA Toner Vacuum or 3M Toner Vacuum Use of a vacuum cleaner not rated for toner particles could result in a fire or personal injury Remove residue with soap and cold water Miscellaneous Keep product out of sewers and watercourses Personal protection Avoid inhalation of dust Section 7 Handling and Storage Special Handling Cleanse skin after contact before breaks or meals and end of workday Special Storage Store in a cool dry place Avoid direct sunlight Keep out of reach of children Keep from contact with oxidizing materials Miscellaneous Do not handle in windy areas Flying powder may en
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