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Fumigation Study Guide for Hawaii

1. ND Di Cooperative Extension Service PESTICIDE SAFETY EDUCATION PROGRAM College of Tropica Agriculture and Human Resources University of Hawai i at M noa Fumigation Study Guide for Hawaii March 2009 FOR PERSONS SEEKING CERTIFICATION BY THE STATE OF HAWAII DEPARTMENT OF AGRICULTURE TO BUY USE OR SUPERVISE THE USE OF RESTRICTED USE PESTICIDES FOR FUMIGATION This booklet is the March 2009 version It replaces the January 2009 version This version has two additions on page 20 Subsection Fumigation Management Plan for Phosphine Fumigants summarizes the requirement for a fumigation management plan FMP for applications of phosphine fu migant products and the major features of FMPs Subsection Fumigation Management Plan for Soil Fumigants alerts soil fumigators to new requirements expected to appear on soil fumigant labeling in 2010 x ok Ok DEVELOPMENT OF THIS GUIDE WAS SUPPORTED IN PART BY THE STATE OF HAWAII DEPARTMENT OF AGRICULTURE Acknowledgement Disclaimer This study guide is based on the Utah Depart Where trade names are used no endorsement is ment of Agriculture s Study Guide for Fumiga intended nor is criticism implied of similar tion which was downloaded in January 2007 suitable products not named from this web page lt www ag state ut us plantind pest_app html study gt and on the electronic version of E J Bond s Manual of fumigation for insect con trol 1984 54 in the
2. Air pump failure or a constriction of the air line can shut off the air supply The air pump must also be located in a fumigant free area In combination with an SCBA an air supplied respirator does offer an unlimited work period with backup respiratory protection provided by the SCBA if for any rea son the outside air supply is cut off One final respiratory protection topic concerns the fit of a face mask If a face mask doesn t seal tightly against the face it cannot provide protec 24 tion from a fumigant gas Air could leak into the mask by passing between the edges of the mask the face The wearer must first undergo a fit test to aid in selecting a mask that will form a complete seal against his or her face Facial hair must be cleanly shaved before the test and whenever wearing the mask The tester assists by releasing puffs of irritant smoke near the edges of the mask Any irritant smoke passing through between the mask and face will alert the wearer to a poor fit Before wearing a properly fitted respirator in a fumigation site the wearer should do a fit check immediately after putting on the respirator This done by completely blocking the mask s breathing holes while trying to breathe the inlet holes while breathing in and then the outlet holes while breathing out If air gets in the wearer should ad just the mask to form a good seal None of the respiratory protection equipment provides protection f
3. calized areas of a building unless it s possible to completely seal and control access to the treated area throughout the fumigation and aeration pe riod Fumigants should never be used in any areas that can t be fully secured to prevent entry or con tact by people or animals The fumigation site also must have the proper environmental conditions to allow successful use of the fumigants This includes correct tempera ture humidity and air circulation conditions re quired for effective pest control Sites should also be thoroughly surveyed to identify and protect items that may react with or be damaged by the fumigant This may include such items as furnishings floor coverings food stuffs wall hangings finishes plumbing and elec trical devices and moisture sources Structural Fumigation Fumigation may be used to control certain pests within existing buildings such as grain stor age bins and homes Since typical construction isn t sufficiently airtight these require sealing In relatively airtight structures taping may be suffi cient However many buildings require tarping the entire structure Fumigants used in grain storage are very useful for control of stored product insects such as wee 15 vils and various bran bugs Household fumiga tions can help control pests such as drywood ter mites powderpost beetles and other wood boring beetles that are hard to control with other meth ods
4. Because this application method may not provide good distribution of the gas in a grain mass it isn t usually used in grain storage fumigation Magnesium phosphide fumigants can be used effectively for warehouse and processing plant fumigations Sulfuryl Fluoride Sulfuryl fluoride sold under the trade name Vikane is a colorless odorless gas It s sold in canisters as a liquid under pressure that volatilizes readily It s noncorrosive and unreactive to most materials Sulfuryl fluoride also can provide good penetration of wood products and fabrics but it needs fans or blowers to mix well with air Sul fury fluoride is nonflammable but in the presence of an open flame it forms a very corrosive gas It s highly toxic to humans March 2009 Carbon Dioxide Carbon dioxide CO is a colorless odorless and tasteless gas that is about 1 5 times heavier than air It s noncombustible and is used as a fire extinguishing material It s usually found in the air at concentrations of about 0 03 percent However carbon dioxide is poisonous at higher concentra tions and is used for fumigating food products at about 60 percent concentration Using carbon dioxide is desirable because no toxic residues stay in treated materials Also CO doesn t change the germination potential of treated grain and leaves no objectionable odor or flavors However fumigation with carbon dioxide requires fairly long exposure period
5. Chamber Fumigation Since environmental conditions can be care fully controlled and monitored chamber fumiga tion is a superior method for fumigating many ma terials Using a chamber will allow only small amounts of a commodity to be fumigated at a time because of the limited size of the chamber How ever the limited space can be an advantage be cause the fumigant is confined saving the time it takes to fumigate and the amount of fumigant used The ability to carefully control environ mental conditions in a chamber also allows fumi gation to be used to control pests on fragile com modities such as fresh fruits or vegetables without damage Chamber fumigation can also be used to disin fect fresh produce packaged foods bagged or baled agricultural products museum specimens furniture high value garments and similar items Chambers used for fumigation may be either the atmospheric or vacuum type Vacuum cham bers provide the quickest and most thorough fumi gation and are best for finely divided items such as flour Applying a vacuum increases the penetra tion of a fumigant and shortens fumigation time However some materials may be damaged by vacuum and require special precautions Atmos pheric chambers are useful for fumigating materi als that might be damaged in a vacuum chamber 16 Tarpaulin Fumigation Tarpaulin fumigation involves placing a gas tight material over the commodity or structure to be
6. The rate of adsorption is influenced by temperature Fumigants applied while tempera tures are low will adsorb more rapidly than when applied under higher temperatures Adsorbed molecules may be released desorption as the temperature rises and as the concentration of the gas molecules in the surrounding atmosphere de creases Fans and blowers that force air through the commodity can further speed the reversal of fumigant adsorption Temperature Temperature at the treatment site affects both the fumigant and the target pest Low temperature increases the sorption rate of the fumigant so that the concentration of the fumigant is reduced but desorption is slowed by cooler temperatures Fu migants also volatilize and diffuse more slowly at cooler temperatures Insects and other target pests may be less sensitive to effects of fumigants at lower temperatures Dur ing cooler conditions respiration of the target pests is slowed making them less susceptible to poisons that affect respiration Preferred fumiga tion temperatures usually range between 50 and 95 degrees F Check the label of the fumigant be ing used for its optimum temperature and accept able temperature range Also remember that dur ing the course of a fumigation application the temperature of the treated area can decrease or increase due to fluctuations in outside tempera tures and also due to the cooling action of the fu migant being released latent heat of vaporiz
7. dioxide smother asphyxiate the pest by displacing oxygen in the surrounding air The killing action of a fumigant is influenced by its concentration in the atmosphere the length of time it stays in the atmosphere and the tem perature and humidity of the area at the time of fumigation Fumigants enter cracks crevices and other areas where target pests may occur They must be applied in enclosed areas Fumigation has no residual effect and reinfestation may occur after the fumigant has diffused from the area Advantages of Fumigation Fumigation has several advantages over other methods of pest control e Fumigants are usually quick acting and can re sult in total eradication of the pest e Because fumigants are gases they diffuse through all parts of the structure or commodity being treated and can reach pests that couldn t be reached with conventional pest control mate rials or techniques e For certain commodities fumigation is the only practical way to control pests Disadvantages of Fumigation There are several reasons why fumigation sometimes may not be the best means of pest con trol These are e The control achieved through fumigation is tem porary There s no residual action from fumi gants Where untreated populations of the pest remain reinfestation of the treated site can take place quickly Fumigants are toxic and often highly hazardous to the applicator requiring special precautions during a
8. directions for use xX cK x Pesticide Inspections Hawaii s pesticide inspectors may check pesticide users to ensure that they follow the relevant do s and don ts in all forms of labeling So let your pesticide product s labeling be your guide to an effective safe and legal application The do s and don ts specified by the labeling are about preparations transport application fol low up storage and disposal of the pesticide They may include requirements to post signs and notes restrict entry into a treatment site or some zone around it warn and train others and use spe cific tools or equipment Be sure you can comply with the ones that apply to you If there is a differ ence between the labeling and discussions in this study guide assume that the labeling is correct If you want help interpreting labeling consult the product manufacturer s representative or a en vironmental health specialist at one of these Ha waii Department of Agriculture offices e Honolulu 973 9424 for Kauai and Oahu e Kahului 873 3960 for Maui Molokai and Lanai e Hilo 974 4143 for Hawaii 808 is the area code for all of these phone num bers Illness injury or pollution resulting from im proper use storage or disposal of a pesticide will be investigated and the applicator may be held partly or entirely responsible if he or she did not comply with the product s labeling xX K x Introduction to Fumigation A
9. fumigant is a chemical that when released as a gas or vapor diffuse throughout enclosed areas or penetrate objects in concentrations that are lethal to pest organisms This definition does not apply to aerosols such as a smoke cloud fog or mist which are solid or liquid particles suspended in air Fumigants gases or vapors consist of mole cules that will mix with the surrounding air Be cause the molecules are very small compared to particles in aerosols famigants can spread throughout a space penetrate into the material be ing fumigated and diffuse away afterward Aero sols cannot do this Some insecticides applied as aerosols give off a gas after settling on leaves or other surfaces The gas may account for part of the toxic action against the pest This is called the fumigation ef fect However this effect won t be discussed in this study guide This guide s discussions are lim ited to fumigants that are dispensed so that the poison is present as a gas or vapor soon after ap plication and reaches the pest as a gas or vapor Fumigation has many uses in pest control They can be used to control wood destroying in sects in structures and furniture where liquid or dust formulations either are ineffective or may cause damage Under some conditions fumigants can be applied to control burrowing rodents that can t be reached with other types of rodenticides Most commonly fumigants are used to control insects or mi
10. pressure The vapor pressure of the fumigant affects the concentration of the fumigant in the air in a con fined space Fumigants with high vapor pressure will be more concentrated and therefore have bet ter fumigant qualities This can be explained by the concept of equi librium When a volatile liquid or solid chemical is first put into a confined space molecules come off the surface of the liquid or solid and move into the surrounding air The concentration of mole cules in the air is low at first But as the volatiliza tion process continues more molecules do this and the concentration continuous to increase However volatilization appears to stop at some point and the concentration stabilizes This is the point of equilibrium when the every molecule evaporating from the liquid or solid is replaced by a molecule condensing out of the air The specific gravity of a chemical compound is a measure of its weight in a given volume With fumigants it s important to know if the gas is lighter or heavier than air Most commonly used fumigants are heavier than air A heavy gas ina confined area will tend to concentrate in low areas and mix slowly with the air These fumigants usually require mechanical mixing with a fan to distribute the molecules evenly through the fumigated area However once the fumigant is thoroughly mixed with the air set tling takes place very slowly As a result the problem of stratification la
11. series FAO Plant Pro duction and Protection Papers posted at lt http www fao org docrep x5042e x5042E00 htm Contents gt We gratefully acknowledge the efforts of all authors editors and publishers This study guide was developed for the Pesticide Risk Reduction Education program a Cooperative Extension Service program of the College of Tropical Agriculture and Human Resources University of Hawaii at Manoa Please direct any question or comment about this guide to Charles Nagamine Department of Plant and Environmental Protection Sciences 3190 Maile Way Room 307 Honolulu HI 96822 Telephone 808 956 6007 Email cynagami hawaii edu Fumigation Study Guide for Hawaii Table of Contents Purpose of Elwenter 4 Other Study Ee EE 4 Habe lin Eeler Ee ee e eege 5 Pesticide Dee 6 Introduction to Fumigation ee 6 How Pum sans Work oeira hares aare a a aa a a a a E 7 How tO CHOGSEa Fumigant EE 8 Chemical and Physical Characteristics of Fumigant 0 cceseesseeseeeeteeeseeeeneeeeees 9 Type and Nature of Punic ants 2c ee 11 Determining Need for Fumigation ccves sacs basusstwtateceenlecstotarn Mareente tenia 14 Target Pest C nsiderations EE 14 Site Suitability Considerations ee 15 Factors Affecting Fumigant Performance 17 Safety Precautions and Protective Devices ccscccssssccseseeeesceeeeseeecssseecssneeessaees 20 Calc latins USE Rates eege 25 Seant e EE AE Ee 26 Applying the Fumigant e ee EE dean ee
12. sin gle day should not exceed the TLV TWA level for an eight hour work period If the fumigant doesn t specify a maximum exposure value exposures must then be kept be low the Permissible Exposure Limit PEL PELs are set forth in state or federal health and safety regulations These limits usually represent the maximum concentration of an airborne chemical that can be present without being a health hazard to most people The TLV and PEL values should only be used as a guide since these levels may not protect eve ryone under all types of conditions For example there may be a few workers who will be sensitive to effects of the chemical below the TLV or PEL Heavy physical activity which increases the breathing rate increases chemical uptake of air borne chemicals Also the exposure levels are based solely on exposure through inhalation Since some fumigants can be absorbed through 21 the skin or accidentally ingested overall exposure levels may be greater Gas Detection Devices Revised labels for fumigants require the use of sensitive gas monitoring devices during fumigant application and before warning placards can be removed from fumigated storages Devices that provide adequate sensitivity in cludes detector tubes and matching pumps manu factured by Auer Draeger Matheson Kitagawa MSA and Sensidyne Detector tubes are sealed glass tubes filled with a specific reactive solid Both ends of the tube
13. source the tempera ture of an evaporating liquid constantly drops This is shown by the cooling effect of evaporating water on the skin The factor of latent heat has important practical significance High pressure fumigants such as methyl bromide volatilize and lose heat rapidly on release Unless the lost heat is restored the temperature of the fumigant may fall below its boiling point causing the gas to no longer evolve Also as the liquid changing to gas is led through metal pipes and tubes or rubber tubing the drop in temperature may freeze the fumigant in the lines preventing further passage In many applications it s wise to apply heat to the fumigant as it passes from the container into the fumigation space Fumigants that are liquids at normal temperatures and are volatilized from evaporating pans or vaporizing nozzles also lose heat These applications may require a source of heat such as a hot plate so that full concentra tions will take place rapidly Flammability Flammability of a fumigant is another physical characteristic that is very important in its safe use Fumigants that are flammable gases are usually combined with a nonflammable gas such as car bon dioxide to reduce the danger of fire or explo sion Fumigation Study Guide for Hawaii Chemical reactivity Chemical reactivity of some fumigants with other chemicals in the environment may limit some fumigant uses For example methyl
14. such as interfering with the fu migant and damaging commodities by staining spotting and surface corrosion If possible dry out commodities or areas having high moisture before beginning a fumigation Drying can be quickened by heating exposing the materials to sunlight increasing air circulation or in closed buildings running air conditioners before and dur ing tarping to remove moisture With tarpaulin fumigation careful considera tion must be given to the method of obtaining a ground seal If concrete and asphalt surfaces are smooth they are satisfactory Wood surfaces are not suitable With wood and most soil surfaces it s necessary to place a section of the tarp mate rial beneath the commodity as well as over it There are several methods of getting a good ground seal Allow enough tarp material to skirt March 2009 outward to at least 18 inches from the stack Loose sand sand snakes or water snakes can then be used to hold the skirt to the ground surface Occasionally a stack may be too close to a wall to obtain a good ground seal If the wall is well sealed the solution is to seal the tarp directly to the wall with adhesive tape xX CK x 27 Applying the Fumigant Before applying any fumigant notify local fire and police authorities and other security personnel as to the location the chemicals to be used pro posed date and time of the fumigation type of protective equipment required and
15. the Commercial 7a category fumigation pest control review specimen label ing for the following fumigant products e Vikane containing sulfuryl fluoride In addi tion to the label review the booklet titled Struc tural Fumigation Manual It explains how to use the fumigant efficiently and safely Fumigation Study Guide for Hawaii e Chloropicrin Warning Agent containing chloro picrin To learn how to get the specimen labeling for these products read the last two pages of this study guide Appendix Specimen Labeling Commercial 7e category vault fumigation pest control If you are preparing for the certification examination for the Commercial 7e category vault fumigation pest control review specimen labeling for the following fumigant products e Fumitoxin Pellets containing aluminum phosphide e Degesch Fumi Cels containing magnesium phosphide e ProFume containing sulfuryl fluoride In ad dition to the label review the booklet titled Con tainer Label and Applicator Manual for Pro Fume gas fumigant It explains how to use the fumigant efficiently and safely To learn how to get the specimen labeling for these products read the last two pages of this study guide Appendix Specimen Labeling Commercial 9 category regulatory pest con trol If you are preparing for the certification examination for the Commercial 9 category regulatory pest control review spec
16. a tion 18 Humidity The concentration of water vapor in the atmos phere humidity can affect the performance of fumigants that are water soluble such as methyl bromide The water soluble fumigants become unavailable when dissolved in water reducing their concentration Fumigants may not be able to penetrate wet areas allowing insects in those areas to survive High humidity can also create moisture con densation in the fumigated area Condensation can cause spotting of treated surfaces In stored grains condensation can cause wet spots that allow molds and storage heating to develop Diffusion For a fumigant to be effective it must penetrate the entire treatment site quickly and must be in the proper concentration Factors that slow diffusion include heavier fumigant molecules low diffusion potential and cool temperatures Diffusion may also be hampered by dust in the fumigated area a common problem in fumigating grain storage structures A fan or blower will increase diffusion Reaction with Other Chemicals Materials in the treatment area including food products being treated may react chemically with a fumigant Higher temperatures may further speed reaction processes For instance the flame from a pilot light or heat from a glowing electric heating element may cause fumigant molecules to react with other gas molecules in the air Chemical reactions of this type are not reversible under nor mal co
17. a away from occupied buildings and deactivated by atmospheric moisture 32 Disposal of residual dust from reacted pellets or tablets is necessary following a space fumiga tion Residual dust is grayish white and it con tains a small amount of unreacted aluminum phosphide Tablets or pellets that are only par tially reacted remain slightly greenish in color and should be disposed of in the manners described above for spills Residual dust from up to five flasks can be disposed of by on site burial or by spreading over the land surface in a secure area away from inhabited buildings This amount of dust may also be disposed of at a sanitary landfill or an approved pesticide incinerator For larger amounts of residual dust a detergent slurry disposal method described above is recommended See product labels for additional directions Residual dust from up to three flasks can be held in an open one gallon bucket pending dis posal Larger amounts of dust should be held in a porous cloth bag during any storage or transport before disposal Don t put the residual dust from more than eight flasks of tablets or ten flasks of pellets in any one bag before disposal Greater amounts may generate enough gas to risk explo sion Don t pile bags Don t confine dispose of or store residual dust in closed containers such as dumpsters drums or plastic bags Don t dispose of dust in toilets Empty flasks that contained aluminum p
18. acuum Too much of either however may cause structural changes in the commodity being fumigated While creating a vacuum take care to prevent undue expansion of tightly sealed packaged goods Slowly lower the pressure and or stop the decompression process for two to five minutes after each one inch fall of mercury shown by a pressure measuring device xX CK x 19 Safety Precautions and Protective Devices Fumigant Management Plan FMP for Phosphine Fumigants Phosphine fumigants are those pesticide prod ucts that contain hydrogen phosphide phosphine gas aluminum phosphide or magnesium phosphide The applicator who will conduct fumigation with any phosphine product is responsible for working with the owners and or responsible em ployees of the structure and or area to be fumi gated to develop a fumigation management plan FMP The FMP is intended to ensure a safe and effective fumigation The FMP must ad dress characterization of the structure and or area and include appropriate monitoring and noti fication requirements The FMP must be in writing and is required for each site to be fumigated The applicator is re sponsible for assuring that the FMP is completed kept up to date available for review and fol lowed This requirement is written on the labeling of phosphine fumigant products and specifies what should be included in the FMP Prior to writing an FMP the applicator should carefully read
19. adequate and uniform concentrations more than 30 feet below its application site supplemental inser tions may be needed in larger structures These Fumigation Study Guide for Hawaii may sometimes be able to be inserted through the aeration or drying fan Within grain storage facili ties it s best to tarp over the surface of the grain mass If the grain isn t tarped the fumigant rate must be increased to provide adequate concentra tion in the bin headspace as well as within the grain mass Eaves and roof hatches must be tightly sealed if the grain surface isn t covered Liquid Fumigants Liquid fumigants volatilize rapidly into a gas The gas then penetrates through the commodity being treated To assure even distribution apply liquid sprays to commodities as they are being loaded into a storage container or storage building Consult the fumigant label to determine protective clothing and equipment needs for these applica tions Carbon Dioxide Use of carbon dioxide as a fumigant requires special application since the gas must displace much of the existing air to achieve the necessary concentration usually 60 percent This requires introducing large amounts of the gas and venting the structure to allow the normal atmosphere to be expelled A top down purge involves allowing the CO to be introduced at the top of the structure displacing air as it settles downward Bottom in jections of carbon dioxide are sometim
20. are broken off just before use and one end is attached to a calibrated pump Available pumps use a bellows bulb or piston type syringe to draw a precise volume of air through the detector tube Discoloration of the solid material within the tube indicates fumigant concentration gas concentrations can be read di rectly from the glass tube Tubes and pumps manufactured by different companies may be very similar but to get accurate readings it s necessary to match detector tubes and pumps from the same manufacturer Don t mix separate brands of equip ment Low range detector tubes that accurately in dicate low levels of fumigant concentrations are required for label specified monitoring practices that provide information for worker safety High range tubes may be useful for detecting fumigant leaks These tubes are scaled for measuring much higher concentrations of fumigants and they are especially useful for monitoring gas concentra tions within storages during fumigation to deter mine if the necessary levels were reached Other gas monitoring devices such as halide leak detec 22 tors and thermal conductivity meters may be used to detect leaks or determine internal concentra tions of gas during fumigation However these devices don t provide label required levels of sen sitivity necessary for determining safety respiratory protection needs Halide detectors also should not be used around grain storage bui
21. at infest flour grains nuts dried fruits and other agricultural products Fumigation Study Guide for Hawaii These insects usually are brought into the vehicle on the commodity being shipped Some insect pests may hide in empty vehicles feeding on resi dues from previous cargoes Unless controlled by fumigation or removed by thorough cleaning these pests can infest future loads Fumigation of railcars truck trailers and other shipping containers must comply with the regula tions of state and local highway departments and departments of transportation as well as the fumi gant s label instructions In some cases loaded railcars can be fumigated in transit It is not legal to move trucks trailers containers vans etc over public roads or highways until they have been aerated When performing a truck or boxcar fumigation the pesticide applicator must post warning signs on all entrances to warn of the haz ards Because fumigated boxcars or trailers may contain residues of a fumigant after aeration the vehicles need to be monitored with appropriate detection equipment once they reach their destina tion and before they are unloaded The person opening and monitoring fumigated loads must wear respiratory protection and any other protec tive equipment required by the fumigant label x K x March 2009 Factors Affecting Fumigant Performance For a fumigant to work effectively the correct concentration of gas
22. available proper safety equipment Make sure all equipment fits well and that all applicators are trained in and familiar with the use of necessary safety equipment Don t take shortcuts follow through with well planned and thorough application practices Don t become complacent Each job is a new challenge and a new situation in which an emer gency may require rapid and proper reaction xX K x 33 Appendix Specimen Labeling On the next page is a list of fumigant pesticide products and warning agents Most are classified as re stricted use pesticides in Hawaii Specimen labeling including both user manuals and labels for these products can provided by the products manufacturers or its local distributors Most can be viewed on the Internet at the manufacturers and distributors websites A webpage of the State of Hawaii Department of Agriculture provides links to electronic versions of specimen labels for pesticides that it licenses for distribution and sale in Hawaii The webpage is at lt http nawaii gov hdoa pi pest list gt To use this webpage click on the phrase List of Licensed Pesticides by EPA Registration Number After this list appears find the pesticide s product name in the list Beneath the product name there will be a link to the specimen label Click on it to download and view the specimen label The user manual is attached after the last page of some of these specimen labels If a pro
23. both the label and the applicator s manual for the fumigant product to be used Once the FMP is written a copy of this information must be given to the appropriate personnel at the site such as the landowner foreman driver etc The FMP and related documentation including monitoring records must be maintained for a minimum of two 2 years The applicator must comply with any state recordkeeping time frame 20 Fumigation Management Plan FMP for Soil Fumigants Soil fumigants are those pesticide products that contain chloropicrin dazomet metam potassium metam sodium or methyl bromide and are labeled for soil fumigation In 2010 labeling for these soil fumigants will specify a requirement for a fumigation manage ment plan FMP and a post application summary report Soil fumigators will then need to ensure that a site specific FMP is in place before begin ning a fumigant application They will also need to prepare a post application summary report to document any deviations from the FMP that may have been necessary as well as results of air monitoring done during and after the application These additional labeling requirements were set up because of the volatile nature of soil fumi gants By meeting these requirements fumigators will protect the pesticide handlers involved in fu migant applications agricultural workers who re enter fumigated fields and bystanders who may be near treated areas The re
24. bromide combines with sulfur containing compounds such as rubber leather and other animal products and gives off a strong foul odor that is hard to elimi nate Phosphine gas reacts with copper used in electrical wiring motors and plumbing to cause serious corrosion High temperatures around an open flame may cause some fumigants to form corrosive acids Certain fumigants may make pho tographic film and paper unusable because of chemical reaction March 2009 Types and Nature of Fumigants Many of the active ingredients in fumigants used earlier have either been canceled entirely or had their uses restricted All space fumigation prod ucts and several soil fumigant products especially those containing chloropicrin and or methyl bro mide are now restricted use pesticides Active ingredients that are still legal to use in clude 1 Methyl bromide 2 Chloropicrin 3 Aluminum phosphide 4 Magnesium phosphide 5 Sulfuryl fluoride 6 Carbon dioxide A mixture of carbon dioxide and phosphine hydrogen phosphide also available in the U S Methyl Bromide Methyl bromide readily penetrates many mate rials and is in wide use for space fumigation Methyl bromide is also used in agriculture as a soil fumigant to control fungi weeds nematodes and insects Methyl bromide is sold as a liquid under pressure Upon release it vaporizes to form a gas that is about 3 3 times heavier than air Methyl bromide is a colorless odorl
25. btain charts from the fumigant supplier to calculate the optimum release rate for the fumi gant being used Releasing fumigant too fast may cause rapid cooling of the fumigation site and result in poor fumigant distribution Rapid cooling will also pro mote condensation of water vapor Releasing the fumigant too slowly may cause icing of the shoot ing tube and possibly restrict the flow of fumigant As the ice melts it may spot or stain Slow release may also prevent the fumigant from reaching the effective concentration quickly enough to control the target pests Fans or blowers should always be used when the fumigant is heavier than air Continue the use of fans or blowers until the desired concentration of fumigant is achieved uniformly throughout the fumigated space Discontinue their use after this point to reduce potential leaking Pelleted Fumigants Aluminum phosphide for use in protecting bulk grain needs to be evenly distributed to provide adequate fumigant levels Pellets should be in serted deeply within the grain mass at least five feet and no more than 50 pellets or 20 tablets should be inserted per probe Applicators should also wear cotton gloves so that perspiration does n t contact the pellets or tablets and start the re lease of phosphine gas The applicator not making the probes should periodically monitor fumigant hydrogen phosphide phosphine levels Since hydrogen phosphide gas doesn t provide
26. ding stored processed or manufactured products Commercial 9 category regulatory pest con trol for state federal or other government em ployees using or supervising the use of restricted use pesticides in the control of regulated pests prescribed under chapter 150A Hawaii Revised Statutes and the Federal Plant Pest Act xX OOK x Other Study Material A Complete Study Packet This study guide is just one item in a complete set of study items A list of all the items in a com plete set may be viewed at this webpage lt http pestworld stjohn hawaii edu studypackets spcatgor html gt Specimen Labeling In following paragraphs find the certification category that applies to you and read the note about specimen labeling Private 2 category agricultural pest control with fumigants If you are preparing for the certifica tion examination for the Private 2 category agricultural pest control with fumigants review specimen labeling for the following fumigant products e Fumitoxin Pellets containing aluminum phosphide e Degesch Fumi Cels containing magnesium phosphide e Telone C 15 containing 1 3 dichloropropene and chloropicrin To learn how to get the specimen labeling for these products read the last two pages of this study guide Appendix Specimen Labeling Commercial 7a category fumigation pest con trol If you are preparing for the certification examination for
27. duct s label refers to a user manual that cannot be downloaded request a copy from the product s manufacturer or one of its local distributors CAUTION When you handle or use any pesticide refer to the labeling supplied with the pesticide s container instead of its specimen labeling There may be differences between them x cK x 34 Fumigation Study Guide for Hawaii Chloropicrin Chloropicrin Warning Agent Dow AgroSciences Chloropicrin Warning Agent Lacrythor Fumigation Warning Agent Tri Clor Fumigant Dazomet Basamid G DuraFume UltraFume 1 3 Dichloropropene InLine Pic Clor 60 EC Telone C 15 Telone C 17 Telone C 35 Telone C EC Telone CH Metam sodium Osmose WoodFume Pol Fume Sectagon 42 Fumigant Solution For All Crops Vapam HL Soil Fumigant Methyl bromide 67 33 Preplant Soil Fumigant 98 2 Preplant Soil Fumigant Brom O Gas 2 Soil Fumigant Metabrom 100 Metabrom Q Meth O Gas 100 Commodity Fumigant Meth O Gas Q Commodity Fumigant Methyl Bromide 89 5 Methyl Bromide 99 5 Pic Brom 25 Preplant Soil Fumigant March 2009 Pic Brom 67 Preplant Soil Fumigant Terr O Gas Preplant Soil Fumigant Tri Con 57 43 Phosphide aluminum Degesch Phostoxin Pellets Degesch Phostoxin Prepac Rope Degesch Phostoxin Tablets Degesch Phostoxin Tablet Prepacs Fumitoxin Pellets Fumitoxin Tablets Weevil Cide Gas Bags Weevil Cide Pellets Phosphide magnesium Degesch Fumi Cels Degesch Fumi Strips Ph
28. e to use detecting equipment that can relia bly measure fumigant concentrations in the pres ence of the warning agent Note Commodity fu migators must not use chloropicrin as a warning agent since this material isn t permitted for use on most food items and it would result in an illegal residue Protective Equipment Various types of respiratory equipment are available but their effective and safe use requires that the equipment is matched to the specific need For example chemical cartridge respirators used in applying many types of pesticides are not suit able for fumigation work Depending on the gases and their concentration various types of gas masks self contained breathing apparatus or air supplied systems are appropriate Canister and cartridge type gas masks employ a replaceable canister or cartridge that contains chemical components that absorb specific gases Full face canister respirators not half face car tridge respirators should be used as protection where this meets label specifications The effective life of an individual canister var ies according to fumigant concentration and the respiratory rate of the applicator Maximum limits are stated on each canister Under NIOSH MSHA regulations canisters are color coded according to fumigant absorbency For example canisters ap proved for protection from hydrogen phosphide are coded yellow with an orange stripe Canisters effective for methyl brom
29. ean 28 Posting and Securing a Fumigation Site en ies secrese node cosnngecavesorstacennete eaves 29 EE EE 30 Special Considerations for Fumigant and Container and Disposal 31 Use Common SENSE aos ore a E EE 33 Appendix Specimen Labellng eer eet 34 kokok March 2009 Purpose of This Study Guide This study guide was developed for persons pre paring for any of these State of Hawaii restricted use pesticide certification examinations e Private 2 category agricultural pest control with fumigants for private applicators using or su pervising the use of restricted use pesticides for soil fumigation in the production of an agricul tural commodity and the application of restricted use pesticides for fumigation of agricultural products Commercial 7a category fumigation pest con trol for persons using or supervising the use of fumigant restricted use pesticides to control ter mites and other pests in or around food handling establishments human dwellings institutions such as schools and hospitals industrial sites such as warehouses grain elevators and any other structures and adjacent area public or pri vate and for the protection of stored processed or manufactured products Commercial 7e category vault fumigation pest control for persons using or supervising the use of restricted use pesticides and fumigants in vaults or chambers to control pests in agricul tural commodities or structural materials and inclu
30. es used in storages with leaky roof or eave areas Following the purge complete sealing will result in the most successful fumigation Additional injections of small amounts of CO should be made when measurements indicate that concentrations have dropped below 50 to 60 percent xX K x March 2009 Posting and Securing a Fumigation Site Before fumigating fumigated areas must always be clearly posted to direct others to stay away In dividual fumigants include detailed instructions for the posting of warning placards on fumigated structures Labels specify the wording including some information in both English and Spanish and content that must appear on warning placards Placards must be placed around the perimeter of the treatment area and at all entrances On structures all entrances should be locked during fumigation and access allowed only to au thorized persons and even then only in an emer gency Use secondary locks on all doors to further guard against unauthorized entry Areas that cannot be locked or secured must have someone present throughout the fumigation and aeration period to block unauthorized entry Always make sure to inform janitors watchmen and other persons who regularly use the building about the fumigation Warning placards may not be removed and the commodity may not be processed or fed until a certified applicator uses an appropriate gas detec tion device to determine that gas concentratio
31. ess and taste less gas but it s highly toxic as a respiratory poi son and can cause serious eye and skin damage It s usually formulated with a small amount of chloropicrin as a warning agent Early symptoms of overexposure are dizziness headaches nausea and vomiting weakness and collapse Fluids in the lungs and heart irregularities may develop two to 48 hours after exposure These effects can re sult in death 11 Methyl bromide is retained at least for a short time in body tissues Repeated small overexpo sures can cause symptoms such as blurred vision staggering walk and mental imbalances with probable recovery after a period of no exposure If trapped inside tight clothing next to the skin methyl bromide can cause severe skin burns Methyl bromide reacts chemically with sulfur products and should not be used to fumigate mate rials such as fur leather rubber wool and feath ers Chloropicrin Chloropicrin is formulated both as nearly pure products liquids at room temperature and as mixtures with other fumigant pesticide ingredi ents Chloropicrin is by itself highly toxic to insects vertebrates and many soil microbes such as fungi It is also useful as a warning agent be cause it is a powerful tear gas It is highly irri tating to eyes A concentration as low as 1 0 parts per million ppm will cause intense eye irritation The irritating properties explain why it is mixed with o
32. fire hazard rating If necessary provide authorities with perti nent safety literature on the materials to be em ployed In addition to normal equipment needs also arrange for standby equipment replacement parts and an alternate plan of action The release of a fumigant into an enclosed area is referred to as shooting or shooting the fumi gant Methods of application or shooting vary according to the type of fumigant used what is being fumigated and where the fumigation takes place The way fumigants are applied in any situa tion however influences the degree of control of the target pests Incorrect application techniques can damage the area damage the commodity or injure people Gas Fumigants Gas fumigants come packaged under pressure in large steel gas cylinders or small metal cans When using fumigant from a large cylinder sus pend the cylinder from a scale and monitor its weight change over time to calculate the rate of application The total weight of fumigant used will determine the dosage applied Gas is injected into the treatment area through one or more hoses or shooting tubes Rate of ap plication is influenced by the diameter and length of the shooting hose Nozzles attached to the shooting hose further affect the fumigant release rate Cylinder pressure also controls the rate of 28 release the pressure in the cylinder being influ enced by the remaining gas and cylinder tempera ture O
33. fumigated The tarps must be specially made for fumigation such as impregnated nylon or sheet polyethylene Waterproof canvas tarpaulins are not satisfactory Polyethylene tarps can be used in thickness from four to six mils Use gas impervious adhesive tape to join various sections of polyethylene film The tarpaulin method provides thorough pro tection from insect damage at a practical cost Done in place it permits fumigation without the expense of moving huge stores of commodities Tarpaulin fumigation can effectively and eco nomically disinfest materials such as bagged grain dried fruit stacked lumber and other com modities from insects Tarpaulin fumigation may be done in the open on loading docks or in areas of buildings that allow safe aeration when the tarpaulin is removed How ever sites must also be checked for possible haz ards in securing the fumigated area from humans and animals as well as for adequate sealing Railcar and Truck Fumigation Items shipped in rail cars or in large truck trail ers are often fumigated after they are loaded into the vehicle This prevents pests from being trans ported to other locations and protects shipped products from pest damage during transport Most vehicles depending on their condition and on the type of commodity being fumigated require tarping or other sealing to confine the fumigant Pests controlled by railcar and truck fumigation include beetles and moths th
34. hosphide may be recycled or disposed of in a landfill after they have been properly processed To adequately clean flasks before disposal flasks and stoppers may be triple rinsed and then punctured A small number of empty flasks may be punctured and held outdoors in an open and secure area away from oc cupied buildings to allow complete reaction of alu Fumigation Study Guide for Hawaii minum phosphide Where triple rinsing is used rinsate may be disposed of in a landfill xX CK x March 2009 Use Common Sense It s essential that fumigators understand and follow the technical instructions that promote safe and ef fective fumigation of stored grain It s just as im portant that fumigators remember to use good com mon sense when planning and carrying out a fumiga tion Although it may be impossible to teach good common sense by writing instructions in study mate rials the following comments are offered as remind ers to exercise good judgment and to think ahead e Read and understand label directions Demand information from the manufacturer and distributor Don t use a fumigant without adequate training and confidence in your ability to do the job properly Supply local medical personnel with fumigant and poison treatment information before using the fumigant Plan the entire job Think through every step and plan your reactions to possible problems and emergencies Always work in pairs Use or have
35. hould be triple rinsed punctured and disposed of in landfill Consult specific container labels for instructions Unused aluminum phosphide pellets or tablets in opened flasks should not be disposed of Once flasks are resealed these tablets or pellets can be stored safely as long as the label remains intact for future use Don t store flasks at subzero tem peratures as doing so will increase the likelihood of ignition flash when they are opened If aluminum phosphide tablets or pellets are spilled or flasks are punctured hydrogen phosphide phosphine gas is released Persons cleaning up the spill or working in the contami nated area must wear an SCBA unless gas detec tion equipment is used If gas concentrations are measured and if hydrogen phosphide concentra tions range between 0 3 and 15 0 ppm a canister respirator should be used At higher concentra tions an SCBA is required Cleanup personnel should wear cotton or neoprene gloves while han dling spilled material If a spill can be cleaned up immediately spilled pellets or tablets should be used immediately or transferred to an empty flask with an intact label If such a container isn t avail able tablets or pellets can be placed in a sound 31 DRY metal container that should be sealed and labeled as aluminum phosphide Keep the original product label with the substitute container If spilled material has begun to react and de compose or if it
36. ide and chloropicrin are color coded black Always double check the color March 2009 code with written specifications that indicate the canister is effective for the fumigant As a canister empties it becomes hot Breath ing hot air or encountering high resistance to breathing provides a warning that the canister is about to become ineffective for protection When this occurs or when the applicator smells or tastes the fumigant or experiences poi soning symptoms the applicator should immedi ately leave the fumigated area An empty canister should be crushed before it s discarded so that no one will mistakenly use it in the future Canister respirators are inadequate for use in oxygen deficient environments less than 19 5 percent such as that produced by CO fumigation Although canisters may absorb the toxic fumigant in this environment they don t supply necessary oxygen In these situations a self contained breathing apparatus SCBA or a combination air supplied SCBA is needed General Rules on Canister Use Discard any canister that has been used for more than 30 minutes total time in a fumigant atmosphere 1 Discard any canister whenever an odor of fu migant is detected as coming through The absorption material isn t working 2 Discard any canister used for less than 30 min utes if it s more than one year old 3 Discard canisters with expired expiration dates or that have been manufac
37. imen label ing for the following fumigant product e ProFume containing sulfury fluoride In ad dition to the label review the booklet titled Con tainer Label and Applicator Manual for Pro Fume gas fumigant It explains how to use the fumigant efficiently and safely To learn how to get the specimen labeling for this product read the last two pages of this study guide Appendix Specimen Labeling xX OOK x March 2009 Labeling and Labels The words labeling and label mean different things While both specify dos and don ts for handling the product safely and effectively a label is just one kind of labeling A label is the words and pictures placed on or packaged with the pesticide container by the manufacturer A booklet or tag accompanying the container is part of the label A government regulation or a manufac turer s guide such as a leaflet booklet or man ual is labeling if the label refers the pesticide user to it Here s an example of a label reference to government regulations When fumigating observe local state and federal rules and regulations including such things as use of chloropicrin clearing devices positive pressure self contained breathing apparatus security re quirements and placement of warning signs Here s an example of a label reference to a manu facturer s guide Refer to the Applicator s Manual for detailed pre cautions recommendations and
38. ith an odor that smells different to different people The odor is often described as similar to garlic commercial carbide or decaying fish Phosphine is only slightly heavier than air about 1 2 times as heavy Fumigators can t rely on the gas moving through a solid storage such as a grain bin so they need to set up one or more fans to mix the fumigant with the air Aluminum phosphide is used commonly to fu migate grain storage facilities Phosphine gas is highly toxic to all forms of animal life Early symptoms of poisoning can be severe but these symptoms are reversible if exposure stops Initial symptoms of overexposure include tightness in the chest faintness dizziness nausea vomiting Fumigation Study Guide for Hawaii and diarrhea Severe poisoning leads to coma and death Phosphine hydrogen phosphide gas isn t absorbed through the skin and it s not stored in body tissues Aluminum phosphide may explode on contact with water Hydrogen phosphide phosphine gas is reac tive and very corrosive to metals especially cop per silver gold and platinum Magnesium Phosphide Magnesium phosphide is similar to aluminum phosphide releasing hydrogen phosphide gas in reaction with water Release of the gas is faster than occurs with aluminum phosphide Common magnesium phosphide products con tain the solid magnesium phosphide material at tached to a strip or blanket that can be put in place very quickly
39. ive or hard to locate can often be treated successfully with fumigation However it s important to understand the habits of the pest before choosing fumigation For exam ple colonies of drywood termites nest in structural wood above ground and are good targets for fumi gation The highly destructive subterranean ter mites nest underground and are not killed by fumi gation Situations where large reservoirs of the pest will remain outside the treated area can allow quick reinfestation wiping out the benefits of fu migation Life Stages of the Pest An applicator should also consider how various life stages of the pest respond to fumigation For instance many insects are relatively nonsuscepti ble to fumigants or other insecticides during their egg and pupal stages Insects may also be dormant Fumigation Study Guide for Hawaii during certain periods and not be susceptible Be sure to check the fumigant label to see what stages of the target pests the manufacturer claims the product will control xX K x March 2009 Site Suitability Considerations Fumigation may be used in several types of situa tions including structures bulk storage facilities specially designed chambers rail cars trucks and other shipping containers However fumigants should only be used in enclosed areas because the molecules of the fumi gant penetrate throughout the area and escape through openings Fumigants can t be used in lo
40. ldings since the flame may trigger an explo sion of grain dust When measuring fumigant levels after fumiga tion it s important to take readings from several locations Often fumigants may become trapped in localized pockets Different materials will also desorb at varying rates a process called off gassing This can allow toxic levels of the fumi gant to occur in scattered locations Detector tubes are specific for a single fumi gant Auer Draeger Matheson Kitagawa MSA and Sensidyne manufacture detectors that offer adequate sensitivity for label required monitoring of hydrogen phosphide phosphine and or methyl bromide The only currently available detector that of fers adequate sensitivity for label required detec tion of chloropicrin is produced by Matheson Kitagawa and is specified on the chloropicrin la bel Tubes available for measuring CO concentra tions are available from several manufacturers Several types of tubes may be needed since appli cators must be able to measure low below 1 percent CO levels to provide information on worker safety and high concentrations up to 60 minimum to determine the need for continued injection of the gas into the structure Warning agents such as chloropicrin are sometimes added to fumigant gases that otherwise Fumigation Study Guide for Hawaii have little odor Sometimes warning agents may affect the accurate reading of fumigant levels so be sur
41. molecules escape Poorly sealed seams or holes in the tarp allow a quicker drop in concentration Wind may increase the amount of air exchange between the fumigation site and the external environment speeding fumi gant loss As the size of the fumigated area increases a smaller dose per unit of volume is usually needed to achieve the desired concentration xX OK x 26 SEALING In most cases the only way to achieve a suffi ciently high concentration of fumigant is to seal the treatment area with a gas proof barrier The best possible seal should be at the lower sections of the fumigated space since most fumigants are heavier than air Leaks in the lower portion of the fumigated space will allow more fumigant to be lost than leaks in upper areas Sealing can be accomplished in several ways One method is to cover the treatment site with 4 mil or 6 mil polyethylene sheeting or an impreg nated gas proof tarpaulin Some containers such as storage bins may be sufficiently airtight and may only require taping around openings or vents Seams or cracks can sometimes be sealed with a liquid that expands to form a solid foam after be ing applied Sealants that come into contact with food must be approved food grade sealants Fumi gation chambers are built to be airtight so they usually need no additional sealing It may be necessary to wet the soil around the foundation when doing structural or outdoor fumi gations This
42. molecules must be present in the atmosphere surrounding the target pest Mole cule concentration may be affected by several fac tors Some important ones are 1 Sorptive quality of the treated commodity either by absorbing taking fumigant into the commodity or adsorbing fumigant condens ing on the surface of the commodity 2 Temperature and humidity during treatment 3 Speed of diffusion of the fumigant through the commodity 4 Reactions of the fumigant with other chemi cals or articles in the treated area 5 Amount of fumigant applied 6 Susceptibility of the target pests 7 In fumigation chambers the pressure of the gas in the chamber Sorptive Qualities Surfaces or items within the fumigated area may affect the concentration of fumigant mole cules For instances cardboard boxes that contain produce or other food items will absorb some of the fumigant Foam rubber used in upholstery or as carpet padding is also sorptive Building insula tion has large surface areas and therefore will sorb fumigant molecules Molecules can be either absorbed or adsorbed See No 1 in above list Absorption happens when fumigant molecules dissolve into another material such as water oil or other liquid It is not always be reversible and may therefore result in greater problems with chemical residues 17 Adsorption is a molecular attraction between gas molecules and the surface of something in the environment
43. nd condition of the sealing method 4 Texture and moisture content of the soil be neath the fumigation site 5 Wind velocity during the fumigation period 6 The volume of the area being fumigated Some fumigant manufacturers furnish calcula tors charts or slide rules to help figure dose adjustments for these factors Low temperatures may affect dispersal of the fumigant in a treated area Also insects are gener ally more resistant to a fumigant when the tem perature is low because their metabolism slows If a fumigation lasts over a lengthy period there also 25 may be important temperature fluctuations Heat ing the fumigated area and increasing air circula tion can overcome most problems caused by low temperature Sorption of fumigant molecules by commodi ties or surfaces in the treatment area reduces the concentration Little can be done to change sorp tion qualities Therefore the applied dose of fumi gant may need to be increased Whenever fumiga tion takes place over soil such as outdoor bulk commodity fumigation or structure fumigation the texture of the soil and its moisture content will influence fumigant concentration Soils made up of fine clay or loam have less space between parti cles Coarser soils such as silt or sand are much more porous and hold more fumigant Increasing soil moisture by wetting will lower fumigant loss The way a fumigation site is sealed influences how fast fumigant
44. nditions If fumigant molecules react chemically new chemical compounds will be formed This may include corrosive acids such as Fumigation Study Guide for Hawaii result from heating sulfury fluoride Possible resi dues of newly formed chemicals may also stay in the fumigated area or on treated food products For example inorganic bromide compounds are found as residues on some food items that have been fumigated with methyl bromide In addition chemical reaction of fumigants may lower the concentration of the fumigant enough to reduce the effectiveness of the fumigation Check the fumigant label for precautions and inspect the fumigation site thoroughly to eliminate materials or conditions that may allow reactions to occur Concentration and Time How well a fumigant works depend both on the amount that has been applied and how well the concentration of gas molecules is maintained after application The amount of fumigant applied is usually expressed in weight per volume for ex ample pounds per 1 000 cubic feet or grams per cubic meter The concentration of a fumigant is the amount of gas present in a given volume for example ounces per 1 000 cubic feet or milli grams per liter Concentration is influenced by sorptive qualities temperature chemical reac tions and how well the fumigated area is sealed When fumigating grains the applicator needs to adjust the dosage for the intergranular space the amount of s
45. ns have dropped below specified levels for the fumi gant This follow up monitoring is a practice re cently required under newer regulations xX K x 29 Aerating When fumigation is completed the fumigant must be completely dissipated by aeration before allow ing access to anyone or before vehicles can be moved Bulk Grain and Other Commodities Wear respiratory equipment to aerate bulk items that have been covered with a tarpaulin First pull the tarp up from the sides for about 30 minutes then remove the tarp completely If this fumigation was made inside a building open doors and windows and use fans to exhaust the fumigant The air being exhausted from the build ing must be directed away from work areas sensi tive plants and neighboring property Make sure downwind areas in the vicinity are kept clear to prevent people or animals from contacting the fu migant as it disperses Wear respiratory protection if entering the building Check the fumigant level to determine the level at which it s safe to allow reentry with out protective equipment Take measurements at several locations Continue to keep people away until monitoring equipment confirms that the fumigant level is be low the harmful stage Continue to aerate for sev eral hours and leave the building or commodity unsealed this will prevent a fumigant buildup by desorption Vehicles Roll back the tarp that covers boxcars or truck trailer
46. nts such as methyl bromide are nor mally a gas at room temperature Other fumigants exist as a liquid chloropicrin or solid paradichlorobenzene naphthalene at room tem perature Also many of the solid type fumi gants such as aluminum and magnesium phosphide are not fumigants themselves but react with moisture to form give off a fumigant gas phosphine or hydrogen phosphide Molecular weight Molecular weight is a measure of the weight of the atoms that form the fumigant molecule More complex molecules have greater molecular weight because they have more atoms Larger molecules are often less suitable as fumigants since they are less volatile Boiling point The boiling point of the chemical is the tem perature at which its liquid form boils under spe cific atmospheric conditions to become a gas Some materials used as fumigants such as methyl bromide have low boiling points so they become gases at normal temperatures and atmospheric pressure These types of fumigants are usually stored as liquids under high pressure March 2009 The boiling point of a fumigant may influence the type of application equipment required For example fumigants with low boiling points usu ally require heaters to warm the gas as it s being released from its container During this process the fumigant will change from liquid to gas boil and rapidly lose heat These materials may freeze without the added heat Vapor
47. on of a fumigant in parts per million that nearly all workers may be repeatedly exposed to on a daily basis without ad verse effect A TLV is usually established for each fumigant as a guide to prevent health hazards but it should not be considered the distinction between safe and unsafe fumigant concentrations Two types of TLVs are recommended by the ACGIH as guidelines for protecting persons han dling toxic vapors including fumigants These recommendations are not enforceable standards although they contribute to better worker safety The two recommended TLVs are 1 TLV TWA the threshold limit value time weight average is an airborne concentration in parts per million of a fumigant or other toxic gas that most workers can be exposed to March 2009 during an eight hour workday or 40 hour work week without developing health problems Typically the TLV TWA value is the concen tration referred to on fumigant labels that must not be exceeded without appropriate respira tory protection 2 TLV STEL the threshold limit value short term exposure level is the maximum allow able concentration of any fumigant that a per son should be exposed to without respiratory protection It s recommended that exposure to this concentration be for no longer than 15 minutes at a time with a minimum of 60 min utes between exposure periods No more than four exposure periods should be allowed in one workday The total exposure for any
48. ons to fumigant poisoning differ from those of exposure to other pesticides For instance many fumigant reactions simulate drunk enness Symptoms of fumigant exposure can in clude e Slowed body movements e Slurred slowed speech e Dizziness e Numbness of hands or feet e Coughing e Sneezing e Dryness irritation of nose and throat e Breathing difficulty e Nausea e Abdominal pain March 2009 Calculating Use Rates The first step in deciding how much fumigant must be released to achieve the desired concentra tion is to measure the length width and height of the area to be treated and figure its volume Volume measurements on fumigant labels are given in cubic feet If the commodity container or structure to be fumigated is to be tarped the total volume inside the tarp must be determined not just the volume of the structure or commodity This must account for spaces caused by over hangs eaves and other irregular shapes Fumigant labels are the best source of informa tion on calculating the proper amount of fumigant to use for specific situations Always read and fol low label instructions Physical or environmental conditions may in fluence the amount of fumigant that must be ap plied to achieve the required dosage Factors that must be considered include 1 Temperature and temperature fluctuation dur ing fumigation 2 Sorption qualities of the commodity or items in the target site 3 The type a
49. osphide hydrogen phosphine CO ECO Fume Sulfuryl fluoride Drexel Master Fume Specialty Gas Fumigant ProFume Vikane Zythor xX kK x 35 Pesticide Risk Reduction Education is a program of the College of Tropical Agriculture and Human Resources of the University of Hawaii at Manoa The program s staff provides study guides short courses and a newsletter for Hawaii s applicators of restricted use pesticides These education and training activities support the State of Ha waii Department of Agriculture s program for certification of restricted use pesticide applicators Pesticide Risk Reduction Education lt http pestworld stjohn hawaii edu epp pat html gt Certification of Restricted Use Pesticide Applicators lt http hawaii gov hdoa pi pest pesticide applicator certification recertification gt Fumigation Study Guide Hawaii 090306
50. pace between individual grains This factor varies with the type and condition of the grain Read the fumigant label for dosage in formation about these sites It s also important to maintain the critical amount of gas in the area of the target pests for a certain period of time Although most fumigants are fast acting effective concentrations need to be maintained for several hours to days or weeks to March 2009 allow control For example in order to kill 99 per cent of the cadelle beetle larvae in stored grain a concentration of 33 2 milligrams per liter must be maintained for five hours Susceptibility of Target Organisms Target organisms can react very differently to the effects of fumigants This variation may be due to species differences It can also be acquired by development of populations that are genetically resistant to the treatment Variation in susceptibil ity also is affected by the life stage of the pest In addition the way a fumigant is applied can sometimes influence pests susceptibility For in stance some insects can tolerate a higher concen tration of fumigant if they are first exposed to a low concentration for a short time To avoid this problem bring the fumigant level to the lethal concentration quickly then maintain the level throughout the fumigation period Pressure In an airtight chamber penetration rate of fu migants may be controlled by using positive pres sure or v
51. pplication Fumigants must be contained in the treated area for a minimum period of time to be effective often calling for extra supervision Fumigation must never be done by just one per son which requires added labor Some commodities or pieces of equipment may be damaged by certain fumigants and must be removed or otherwise protected Fumigant activity may be greatly affected by temperature and humidity xX K x How to Choose a Fumigant If the need for fumigation has been proven the right fumigant must be chosen Consider all that will control the pest and allow you to do the job as efficiently as possible The fumigant product you choose though must be labeled for the specific fumigation job and the applicator must prepared to comply with all of its relevant labeling Consider such factors as e Toxicity to the target pest e Volatility and ability to penetrate e Corrosiveness flammability and potential for explosion e Warning properties and detection methods e Effect on seed germination and finished product e Quality e Residue tolerances e Availability e Ease of application e Cost xX K x Fumigation Study Guide for Hawaii Chemical and Physical Characteristics of Fumigants Fumigants differ according to the following im portant characteristics Volatility Volatility is the tendency of a chemical to evaporate and become a gas or vapor Volatility increases as temperature rises Some gaseous type fumiga
52. quirements will also address worker protections stewardship and train ing programs good agricultural practices buffer zones posting requirements and emergency pre paredness and response measures Using Two Trained Applicators Recent regulations and changes in warning statements on labels now require the presence of two trained applicators during hazardous stages of fumigant application This strengthens long standing recommendations to always work in pairs Two applicators are to work together when ever the application or gas monitoring requires Fumigation Study Guide for Hawaii entry into or work within the confined space where a fumigant is applied Aluminum phosphide and methyl bromide la bels do allow an applicator to work alone if the fumigant is applied outdoors to a stream of mov ing grain as with aluminum phosphide or in re circulation systems where methyl bromide con centrations don t exceed 5 ppm in the work area Even so the presence of two trained applicators is always a wise investment for safety in the event of accident or emergency Exposure Levels Respiratory protection is required for certain phases of most fumigant applications and other times when the airborne concentration exceeds a set value The American Conference of Govern mental Industrial Hygienists ACGIH recom mends following established exposure limits known as Threshold Limit Values TLVs A TLV is the airborne concentrati
53. rom skin absorption or skin injury by fumigants When using fumigants that have potential to injure the skin or be absorbed by it such as chloropicrin be sure to wear additional protective clothing Respiratory Protection Requirements Fumigant labels require the use of specified types of respiratory protection equipment during most fumigant applications Labels specify maxi mum fumigant concentrations in which applica tors can work without respiratory protection equipment Where gas concentrations are greater than those specified by the label exposed workers should use respiratory protection equipment These levels include the following 1 Workers exposed to hydrogen phosphide phosphine at levels above 0 3 ppm must Fumigation Study Guide for Hawaii wear a canister type gas mask or self contained breathing apparatus SCBA 2 Workers exposed to concentrations of hydro gen phosphide above 15 ppm or where levels are not measured must wear an SCBA 3 Workers exposed to chloropicrin concentra tions above 0 1 ppm must wear a canister type respirator an SCBA or a combination air supplied SCBA respirator 4 Workers exposed to methyl bromide levels above 5 ppm must wear a SCBA or a combi nation air supplied SCBA respirator 5 Workers exposed to carbon dioxide concentra tions exceeding 1 0 percent must wear an SCBA or combination air supplied respirator SCBA Symptoms of Exposure to Fumigants Most reacti
54. rp seams before opening roof seams Pull tarps up or peel them away from the sides of the building rather than dropping them to the ground As soon as tarps are being removed the exhaust fans can be shut off and all doors and windows opened After tarps have been removed use an atmos phere monitoring device to determine when the Fumigation Study Guide for Hawaii fumigant has been dissipated well Check for pockets of the fumigant in low areas and in cor ners closets or other areas where there is poor air circulation Areas where there are porous materi als may have sorbed quantities of fumigant that will be more slowly dissipated Longer aeration periods will be needed under these conditions To hasten the desorption process increase the tem perature inside the structure and maintain good air circulation Be sure to ventilate refrigerators and freezers as well as attics and crawl spaces xX CK x March 2009 Special Considerations for Fumigant and Container Disposal Fumigants are hazardous materials Empty con tainers and any excess or unused fumigants must be handled appropriately The correct method of handling fumigant containers differs among fumi gant products Empty canisters or tanks that were used to hold methyl bromide or CO under pres sure should be returned through the original ship per to the manufacturer for refilling Some chloro picrin containers should be handled in the same manner while others s
55. s and open the doors and ventilators for 30 to 60 minutes then remove the tarps Measure the fumigant level before entering the fumigated area and wear protective equipment until the fumigant 30 has dispersed To prevent injury notify people who will open the vehicle at its destination that they must wear respiratory protection Instruct them not to unload the vehicle until fumigant levels have been monitored again and are determined to be in the safe range Buildings Wear the label recommended respiratory pro tection when beginning the aeration of structures Use fans to force the fumigant out of the structure Fans should be installed during tarping and before the fumigant is applied Connect electrical cords to a remote power source so the fans can be started without entering the fumigated area Be sure the exhaust from the fans is directed away from work areas sensitive plants and neighboring work areas Begin by starting the fans which will pull the tarps up against the sides of the structure When the tarps have drawn up tight slightly open a seam on the opposite side of the building from the fans Wearing respirator equipment enter the structure and close outside doors and most windows to pre vent fumigant inside the building from getting into the space between the tarp and the building s exte rior Next remove the bottom seal working in both directions away from the exhaust fans Open all lower ta
56. s contaminated by other sub stances so that it can t be safely stored it should be gathered and placed into open top perforated gallon cans and processed immediately Don t use water to clean up an aluminum phosphide spill Water will react with tablets or pellets to rapidly release hydrogen phosphide gas and the rapid production of gas can result in spontaneous igni tion and explosion To deactivate unreacted or partially reacted pellets transport them by hand or in an open vehi cle to a location in the open air away from occu pied structures Fill a drum two thirds full of wa ter and add one fourth cup of low sudsing deter gent or surfactant for each gallon of water Mix each flask of tablets or pellets with no less than one gallon of the water detergent mixture Wear respiratory protection equipment and slowly add the aluminum phosphide product to the drum while stirring Stir occasionally thereafter for at least 36 hours DON T COVER THE CON TAINER Covering the container will confine the hydrogen phosphide gas that is generated and the resulting high concentrations may explode This wet method of deactivation is preferred when five or more flasks of materials must be deactivated The resulting slurry may be disposed of at an ap proved landfill An alternative to slurry deactivation is dry de activation for small quantities not exceeding five flasks Pellets or tablets can be spread out in an open secured are
57. s to be effec tive Effectiveness is greatly reduced by low tem peratures so if temperatures are below 60 F fu migation periods three to four weeks or more may be too long to be practical xX CK x 13 Determining Need for Fumigation Several criteria should be considered in determin ing the need and suitability of fumigation for pest control These include 1 Characteristics and habits of the pest 2 Life stages of the pest 3 Characteristics of the treatment area 4 Hazards located in the treatment area 5 Available pest management alternative 6 Established pesticide residue tolerances xX K x 14 Target Pest Considerations Fumigants used in pest control tend to affect all forms of life Almost any pest in an enclosed area can be destroyed when exposed to an adequate concentration of a fumigant Fumigations are most often used to treat pests that infest harvested com modities such as bulk grain greenhouse insects etc Inaccessible pests such as wood boring bee tles and drywood termites are also targets for fu migation Fumigation may sometimes be the best choice for controlling heavy infestations of insects such as cockroaches especially when it s hard to gain access to all of the pest s hiding places Fu migation is also useful to avoid toxic residues as sociated with application of other pesticide formu lations to food clothing and similar materials Habits of the Pest Pests that are reclus
58. tes in fresh and stored food products such as grains fruits vegetables nuts and dried fruit Fumigation may take place at a home or storage facility or it may occur in a carrier such as a truck railway car or other shipping con tainer Fumigation Study Guide for Hawaii Controlled atmosphere storage of certain food products is a unique form of fumigation In a con trolled atmosphere most of the air in an enclosed storage area is replaced with a gas such as carbon dioxide Before performing a fumigation the applicator needs to clearly understand the hazards and poten tial problems associated with the use of fumigants Most fumigants are highly toxic to all forms of life including humans animals plants and even microbes Fumigation is a highly specialized op eration that requires equipment techniques and skills not generally used for applying other types of pesticides Applying a fumigant may be time consuming and expensive usually requiring more labor than other pest control methods Structural fumigation is disruptive since ten ants and other occupants must leave the building This is just one of the many specific legal require ments must be met because of the special hazards of fumigation March 2009 How Fumigants Work Fumigants kill pests by interfering with their res piratory functions Most fumigants interfere with the enzymes necessary for normal respiration Other fumigants such as carbon
59. ther fumigant pesticide ingredients either by the manufacturer during formulation or by the applicator near the beginning of a fumigation job In Hawaii the nearly pure products are regu lated as restricted use pesticides when used with any pesticide as an irritant or warning agent This true whether or not the product labeling show an EPA registration number So Hawaii users of these chloropicrin products must make and keep records of each application according to the pesti cide regulation of the State of Hawaii Department of Agriculture 12 Chloropicrin volatilizes to form a dense gas that is about 5 7 times heavier than air Prolonged breathing of chloropicrin vapor will cause severe lung injury Chloropicrin can also cause severe injury upon skin contact Uses of chloropicrin on foodstuffs have been restricted in recent years Right now use is pro hibited on most food Grain treatment uses are under review Aluminum Phosphide Aluminum phosphide fumigants include prod ucts marketed under the trade names Detia Fumi toxin Gastoxin Phostek and Phostoxin These products contain aluminum phosphide in combi nation with inert ingredients such as ammonium carbamate and urea The formulated material is a solid molded into pellets or tablets The active in gredient aluminum phosphide reacts with atmos pheric water to produce hydrogen phosphide gas This gas is also known as phosphine Phosphine is a colorless gas w
60. tured more than two years earlier even if unused unless the in struction sheet specifically says otherwise 4 DON T use a canister type gas mask to enter a recently fumigated or oxygen deficient area 23 The self contained breathing apparatus SCBA commonly used for fumigation is the air pack Air packs comprise a full face mask at tached to a tank of air carried on the applicator s back An air pack supplies up to 25 to 30 minutes of air supply and allows work in an oxygen deficient environment This time period may be considerably shorter if overexertion increases the rate of breathing A warning bell can be set to sig nal the depletion of the air supply In a fumigant laden storage safe exits may re quire uninterrupted respiratory protection For this reason carrying an approved canister respirator when using an air pack is recommended for situa tions where oxygen concentrations remain ade quate The canister respirator will allow emer gency escape if the SCBA expires or malfunc tions Methyl bromide and chloropicrin label direc tions concerning respiratory protection include reference to combination air supplied SCBA res pirators Air supplied respirators employ an out side air source pumped to the applicator through an air line The major advantage of the air line system is that the air supply doesn t expire in a limited time Disadvantages include the need to tow the air line throughout the storage
61. will reduce the amount of fumigant that will pass into the soil and will help achieve a good seal Concrete or asphalt surfaces provide a satisfactory seal In structural fumigations look for potential problems associated with tarping such as land scape plants Plants can interfere with sealing and they may be damaged by the fumigant Fragile roofs or roof mounted structures can also be dam aged in the sealing process unless special care is taken Structural fumigation may also require sealing of areas within the structure Materials that may Fumigation Study Guide for Hawaii be damaged by the fumigation and that can t be removed should be sealed off to exclude the fumi gant gas Drains and other conduits for the fumi gant may also need to be blocked However it should be recognized that these areas may also provide refuges and if not exposed to the fumi gant allow some of the target pests to survive the treatment Seal seams and holes in the tarp with durable tape or clamps Cover sharp edges of a vehicle container or structure with protective material such as foam rubber to keep them from tearing the tarp Moisture may condense inside the tarp or on surfaces or commodities being fumigated Con densation is greatest during periods of high hu midity or falling temperature High humidity may be due to a recent rainfall or because of high hu midity of the commodity Condensation can cause several problems
62. yering of heavier than air fumigants doesn t have much practical mean ing for the exposure periods usually required in fumigation work All gases become lighter as they become warmer This is because warm molecules take up more space so fewer molecules can be contained in a given space at the same pressure Diffusion potential Diffusion potential is a measure of how fast gas molecules disperse through the atmosphere After a while the molecules become evenly dis tributed The speed with which molecules disperse is affected by the molecular weight of the gas Gases that are heavier diffuse more slowly and it may be important to disperse these types of gases with fans or blowers Water solubility The water solubility of a fumigant becomes an important consideration if items in a fumigated area contain even small amounts of water The water will tie up water soluble fumigant mole cules reducing the fumigant concentration in the atmosphere Toxic molecules also may be incor porated into the water of fumigated materials and may remain as undesirable residues Suitable fu migants for most applications are those that are insoluble or only slightly soluble in water 10 Latent heat of vaporization Latent heat of vaporization the extra heat re quired to change the liquid to a gas must be con sidered when using fumigants that have boiling points below room temperature Unless sustained by warming from an outside

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