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Laboratory Safety Manual

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1. gt Other information d For more information about WHMIS 2015 please refer to the following links WHMIS 2015 Coming into Force Questions and Answers WHMIIS 2015 Health Canada WHMIS ORG EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 27 of 81 2 UNIVERSIT ENVIRONMENTAL Ww Co ncor d l HEALTH AND SAFETY Dn eS qM feier 7 3 Working with Hazardous Chemicals In order to prevent harmful health effects hazards must be eliminated reduced or controlled Such control methods include e Elimination of the danger at the source e Substitution with a less hazardous material or industrial process e Engineering controls use of ventilation encapsulation or other means to limit exposure e Administrative controls training restricted access SOPs e Wearing proper PPE gloves laboratories coat safety glasses respirators 7 3 1 Very Toxic and Toxic Materials Very toxic and toxic materials cause serious health effects by damaging critical body systems These body systems include the lungs nervous system oxygen transport in the blood and kidneys The exposure may be acute immediate effect or within short timeframe or may be chronic delayed effect For example the signs and symptoms of lung injury may not appear until 24 48 hours after exposure Always consult a product s MSDS to identify its target organ s This information is even more essential for people with pre existing conditions i
2. scccccssssssssssssccesssssssscccsecsssssssscceescesssssssnnccesessssssssscecsssessssssnaasosses 72 Appendix Il Segregation of Incompatible Chemical Classes esee eene eene enn nennen nnne nnns nnnnna 73 Appendix III Peroxide forming chemicals and solvents cssssssssssscccsssssssccesceesssssssccesceesssssssccceseessssssssncseses 76 Appendix IV Flammable or Toxic Compressed and Liquefied Gases eese ss 78 Appendix V Typical Laboratory Spill Kits eee eere eene eee eee eene eere nennen nere nno n nnns a sten ssa a assesses en nasa aa 79 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY nee E fe we Abbreviations ANSI American National Standards Institute BSO Biosafety Officer CCOHS Canadian Centre for Occupational Health and Safety CNT Carbon Nanotubes CO Carbon Dioxide CSO Chemical Safety Officer CSA Canadian Standards Association CSBN Centre of Studies in Behavioral Neurobiology CSST Commission de la Sant et de la S curit du Travail EHS Environmental Health and Safety ft Foot feet GHS Globally Harmonized System of Classification and Labelling of Chemicals HEPA High Efficiency Particulate Air IATA International Air Transport Association LPG Liquefied Petroleum Gas LSO LASER Safety Officer MPE Maximum Permissible Exposure MSDS Material Safety Data Sheet NFPA National Fir
3. 4 Responsibilities The University has a responsibility to provide every employee and student with a safe environment in which to work and study Concordia University will make every effort to protect the health safety and physical well being of its students employees and visiting public Compliance with University health and safety policies and procedures is a condition of employment The University is required to comply with all federal provincial and municipal laws legislations standards labor codes and industrial safety acts that affect its employees and property Responsibility for laboratory safety is shared between the PI staff and students the departments and the University As such the PI acts as the manager of the laboratory and is responsible for ensuring a safe work environment for the employees and students working in the laboratory Due to the fact that every employee has the responsibility to comply with health and safety regulations and directives all safety concerns should be reported to the immediate Supervisor The general responsibilities for all employees of Concordia University are described in the VPS 40 policy This policy applies to the following e Senior Administrators Deans and Executive Directors e Managers and or Supervisors e Department Chairs Research and Unit Directors e Faculty members researchers instructors technicians in Academic Departments and Teaching Assistants e Employees and stu
4. All users of nanomaterials must take the Safe Handling of Nanomaterials training This training is available upon request at EHS concordia ca The nanomaterials safety program is led by the Chemical Safety Officer 9 Biological Hazards Separate Biosafety Manual Procedures and Guidelines are available on line from the EHS website The Laboratory Biosafety Standards and Guidelines can be consulted on the Public Health Agency of Canada website Biohazardous materials are defined as material of biological origin that may be potentially harmful to humans animals plants the economy or the environment Biohazardous materials include but are not limited to e Microorganisms such as viruses fungi parasites and bacteria e Biological toxins from microorganisms plants and animals e Human primary tissues blood and body fluids e Materials that may contain the above mentioned agents e g cell cultures specimens from humans and animals environmental samples e Certain proteins nucleic acids siRNA miRNA DNA from pathogenic organisms oncogenes e Genetically modified organisms GMO that may be hazardous to the environment if released All projects involving biological material must be registered with EHS to ensure that the work is compliant with internal policies and the Canadian Biosafety Standards and Guidelines CBSG The biosafety program is under the responsibility of the Biosafety Officer BSO at the EHS Office 10 Radia
5. Appendix IV Flammable or Toxic Compressed and Liquefied Gases COMPRESSED AND LIQUEFIED GASES FLAMMABLE OR TOXIC NFPA HEALTH 3 OR 4 Gas Acetylene Allene Propanediene Ammonia Arsine Boron Trichloride Boron Trifluoride 1 3 Butadiene n Butane iso Butane 1 Butene 2 Butene Carbon Monoxide Carbonyl Chloride Phosgene Carbonyl Fluoride Carbonyl Sulfide Chlorine Chlorine Dioxide Chlorine Monoxide Chlorine Trifluoride 1 Chloro 1 1 difluoroethane Chlorotrifluroethylene Cyanogen Cyanogen Chloride Cyclobutane Cyclopropane Deuterium Diazomethane Diborane 1 1 Difluoroethane Dimethylamine Dimethyl Ether 2 2 Dimethylpropane Ethane Ethylacetylene Ethyl Amine Ethyl Chloride Ethylene Oxide Fluorine Formaldehyde Germane Hexafluoroacetone Hydrogen State Gas Liquid Liquid Liquid Gas Gas Liquid Liquid Liquid Liquid Liquid Gas Gas Gas Liquid Gas Gas Gas Gas Liquid Liquid Liquid Liquid Gas Liquid Gas Gas Gas Liquid Gas Liquid Liquid Gas Liquid Liquid Liquid Liquid Flamm Y Y Y lt lt lt lt ZZ Z lt lt lt lt lt lt Z22 lt lt 2 lt 22 lt 2Z a lt lt lt lt lt lt lt lt lt E z Nf Health Gas Hydrogen Bromide Hydrogen Chloride 3 Hydrogen Cyanide Hydrogen Fluoride 3 1 1 Difluoroethane 3 Hydrogen Selenide Hydrogen Sulfide Ketene Methane Methylacetylene Propyne Methylamine 3 Methylbromide 3 Methyl 1 butene A Me
6. Co ncor d l HEALTH AND SAFETY ne E fe we 7 8 3 LPG Storage Requirements LPG cylinders not in use shall not be stored inside University buildings but in secured locations outside buildings according to the following recommendations e At least 5 ft 1 5m from any doorway or opening in a building frequented by the public where occupants have at least two means of egress e Atleast 10 ft 3m from any doorway or opening in a building or sections of a building that only has one means of egress e Atleast 20 ft 6 1m from air intakes of air conditioning or ventilation systems e Cylinders shall not be stored on building roofs If empty cylinders that have been in LPG service are stored indoors they shall be considered as full cylinders and must therefore be stored outside buildings 7 9 Oxidizing Gases Oxidizing gases are non flammable but in the presence of an ignition source and fuel can support and vigorously accelerate combustion Examples of oxidizing gases include e Oxygen e Chlorine e Fluorine e Nitrous oxide Do not use oil in any apparatus where oxygen will be used Cylinders that contain oxidizers whether full or empty must be stored away from fuel gas cylinders e g propane hydrogen etc at a minimum of 20 feet In the event they are stored together they must be separated by a wall 5 feet high with a fire resistive barrier of at least 30 minutes If the cylinders are stored indoors the area must be ful
7. Demonstrating Due Diligence Records are essential to demonstrate due diligence The EHS office offers a number of safety trainings however the Principal Investigator PI is expected to offer practical hands on training to students and staff under their direct supervision The training attendance form available on the EHS website can be used to document and ensure that the student staff has been appropriately trained As such the following documentation should be kept by Laboratory Supervisors e Training records see template in Appendix Template of Training Record e Inspection reports e Incident reports e Orientation checklists e Standard operating procedures 4 3 Training Training is required to ensure that safe work procedures are in place Supervisors must ensure that all individuals working in their laboratory receive appropriate training EHS offers a number of safety trainings throughout the year Faculties and departments also organize safety trainings at the beginning of each semester EHS routinely offers the following trainings a Workplace Hazardous Materials Information System WHMIS b Hazardous Waste Disposal c Radiation Safety refresher training also available d Introduction to Biosafety e Safe Handling of Blood f Safe Use of Biological Safety Cabinet g LASER Safety h Corrosive Substances i Transportation of Dangerous Goods General j Transportation of Dangerous Goods Class 6 2 Inf
8. Laboratory and Equipment Decommissloning eene eene nnne isses natn a essen asa 8 Bi Laboratory Design ni eege ee eege 8 5 1 Labordtory Ventilation oc cic e et c e e eo SES sd ne de 8 5 1 1 General Laboratory Ventilation sise 8 5 1 2 Laboratory Dote eh REE 8 5 2 S TT vdTeollgTirislieo Lu oc 9 5 2 1 How to Use the Fume Hood 9 5 2 2 FACE VEIOCIEY 9 5 2 3 EMEFZENCY dU eue re 10 5 2 4 E Wang Lu 10 5 3 TL E DEE 10 5 3 1 Emergency Eyewash Stations Safety Showers ener nnn 10 5 3 2 Emergency RIES use ee egetugeeer 11 5 3 3 Fire EXtIngUlSlierS siste ricis ones ces una een nego reus eh nua cost suescedtassedsasastecesbacencessusesaesteateddemsbee 12 5 3 4 dits odi c 13 6 Safe Work Practices inst aies cease a ecce ara e cesa anao ecco ena ete esse casse ae eaa anda Cesena aa eaa eR co cea enun 14 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT UNIVERSITE ENVIRONMENTAL wv Co ncor d l HEALTH AND SAFETY NY UNIVERSITY 6 1 Routes Of EE 14 6 2 Laboratory Conduct E 14 6 2 1 General Safe Laboratory Practices 4 14 6 2 2 ele UE 15 6 2 3 Working AlON E 16 6 2 4 Unattended Experiments rro ceres rues i ca Fede tase EE AER eege 16 6 2 5 berouegt Seege ee eege eelere 17 6 3 Pregnant Students Staff New Mot
9. On Sri S o Do not store gas cylinders e In exits or egress routes or at less than 1m from an exit e In damp areas near salt corrosive chemicals fumes heat or exposed to the weather without roof housing e Longer than one year without use 7 6 4 Cylinders in Use Cylinders when in use shall be connected to gas delivery systems designed by a qualified person A compressed gas cylinder shall be considered to be in use if it is in compliance with one of the following e Connected through a regulator to deliver gas to a laboratory operation e Connected to a manifold being used to deliver gas to a laboratory operation e A single cylinder secured alongside a cylinder connected to gas delivery system which serves as the reserve cylinder for that system Cylinders not in use shall not be stored in the laboratory unit 7 6 5 Storage Limits for Hazardous Gases According to NFPA 55 the amount of hazardous compressed gases permissible within a Laboratory Work Area is outlined in the table 7 6 5 1 Table 7 6 5 1 Maximum Allowable Quantities MAQ for Hazardous Gases Flammable Gas Oxidizing Gas Toxic Gas Compressed e g Compressed e g Compressed e g Hydrogen Methane Oxygen Carbon Monoxide Amount Allowed per 500 ft of Laboratory Work Area Maximum Number of 4 cylinders 9 x51 4 cylinders 9 x51 1 lecture bottle standard cylinders cylinder cylinder EE ET In addition to the maximum
10. A flammable liquid storage cabinet is designed to protect flammable liquid containers from fire for 10 minutes to allow for safe evacuation LPGs usage is severely restricted in buildings because of their rapid evolution of gas from leaks which are orders of magnitude greater than the evolution of vapours from flammable liquids LPG storage and usage are also covered under the CAN CSA B149 2 Propane Storage and Handling Code 7 8 2 LPG Laboratory Use The National Fire Code of Canada 2010 including Quebec modifications and the CAN CSA B149 2 Propane Storage and Handling Code prohibit the use and storage of LPG cylinders within buildings However NFPA 58 allows certain amounts of LPG to be used depending on the building classification If a LPG is used for research purposes in University laboratories the following rules shall apply e the cylinder must be in use see section 7 6 4 e the cylinder must be at least 20 feet away from cylinders containing oxidizing gases e aleak test shall be performed every year and after replacing a cylinder and or any modification of the installation e aleak detection system e g detector must be in place and tested annually or e thecylinder must be placed in a continuously mechanically ventilated gas cabinet Any use or storage of LPG cylinders within laboratories must be assessed and approved by EHS EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 40 of 81 UNIVERSITE ENVIRONMENTAL
11. EE 59 15 6 Hot Plates Ovens and Microwgues rires rnnnnnresses es sennnnessssessseennnnsee 60 157 Water BOTS ioter eegene eege 61 16 Personal Protective Equipment PPE cccssesccceseoscccsesessecssnassccseontcensocetceseocesseeensescontecedcssneneseesmecessessesesenns 61 16 1 better eege 61 16 2 IGIOV S 62 16 2 1 General Guidelines rioris nra aa tres Y Ro E READER REY REOR ER et ged 62 16 2 2 Glove el D ME 63 uL NEC MEP AMER BIOS 2 555 63 16 3 Eye and Face e EE 64 16 3 1 Nee Tel EE 64 16 3 2 CONC LEM 64 16 3 34 Face SME AS EE 64 16 3 4 Contact Lenses in the Laboraton EES 65 16 4 Respiratory RrOtECTION EE 65 16 5 Hearing PFOTCCHION TT 66 17 Emergency e HE 66 171 Injury and Incident Reporting sssssessssssssnsnsnensssneseaeasaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa 66 17 2 Fire and EE 67 T7 2 GE 67 17 2 2 IST 67 REB SI Ja el p 68 174 leegen eege 68 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT pue UNIVERSIT VENUES ENVIRONMENTAL MJ Co ncor d ld HEALTH AND SAFETY nn wg E fe we 17 4 1 Incidental Spill or Minor Spill 68 17 4 2 Emergency Spill or Major Spill 69 aly a SPIKES E 69 18 REFERENCES gesteet eege EES 70 Appendix I Template of Training Record
12. ENER Foe aka asa Feo Pa ea y ar Er or ENEE geen 9 Biological Hazards s SENSES 10 Radiation Hazards nece teres eae e DRE HN BNn HN URN n RN ESSERE NE NONE EN B NN RN URN RR URS E CEN ORE ERE B NR CENE RRRE NER Rn 11 Magnetic Field ILPEI o p lense 12 LASER re E tm c MI LEPIETGIICAERICMTRTRTEEEEe 131 Chemical Waste ccc ee ee co c ey ev cep eo c E ves cere A eot c rcp end 13 1 1 Containers for Chemical Waste 13 1 2 Expired Chemicals iio eroi iei re Pense RENE EER ER SR EE REN ER HER RR SEE OR ERRAER RDESE MEER RARE RER SRRRRUNERERUEO 13 4 3 Empty Chemical Containers 2 rit iio TG o EG GI i o ESTE et nie 13 1 4 Chemical Waste Pick Up Procedure eene nnne nennen nennen nennt nnns nnne 131 5 e E EE 13 2 Biohazardous Waste ii 2 23222 M3 M 2M 22M MM 2 LM 222223 2M 3 2 3 2 3 Y 2 22 22d 2424 13 2 1 Containers for Biohazardous Waste cccccccccccceseceeeeeeeeeeeceeeeeeeeeeseeeeseesseescenseseessssessessseeseenenens 13 2 2 D contamination Prior to Disposal visscsiscsssesacesescsscesssesacesdessssestecsaiesdsesaiesasessiestsesssasdsassiestiessiesdees 13 2 3 Biohazardous Waste Pickup Procedure iii 13 2 4 eU Ira In EROR RERO 13 3 Radioactive Waste inr ERR TR EXE YEN haan AFER AERA Vad de add LYRA YEN Leads ad ed 13 31 Categories Disposal rrt tem ene Rb HR CER ER er encre EAR REOR EAR RERO d ERR EO E kate d dn 13 3 2 Radioacti
13. ES iS 16 2 Gloves Protective gloves should be worn to prevent potential exposure to chemicals or biological material The proper type of glove will depend on the materials being used Different glove types have different chemical permeability Always consult the manufacturer s compatibility chart for proper glove selection MSDS are also an important source of information 16 2 1 General Guidelines The following recommendations are important to consider e Always inspect your gloves for discoloration punctures and tears If unsure as to whether the glove was compromised it should be replaced immediately e Donotreuse disposable gloves e Disposable latex gloves are not recommended for use with chemicals e Rubber or plastic gloves should never be used to pick up hot objects hot objects should be picked up with gloves made of heat resistant materials e Very cold objects such as liquid Ny or CO should only be handled when wearing insulated gloves e Gloves must be removed before leaving the laboratory to prevent contamination of doorknobs telephones light switches computers elevator panels etc e Gloves should be removed before handling personal items cellphones laptops etc e Wash hands after removing gloves and before leaving the lab Fig 16 2 1 Proper Glove Removal Step 3 Place fingers by wrist under glove Step 5 Throw used gloves in proper disposal unit Step Wash hands thoroughly EHS DOC 001 v
14. Products that can corrode metal surfaces or cause burns to skin Products that can be health or safety hazards under certain conditions pressure temperature impact violent reaction with water or air The WHMIS hazard classes for controlled products fall into one or more of six classes where the Toxic Materials Class Class D is further divided into 3 subclasses D1 D3 Symbol Classes PE Fi NION NNI Argon Propane Nitrogen Propane Acetone Kerosene Magnesium Sodium Spray paint Hydrogen peroxide Nitric acid Carbon monoxide Phenol Benzene Di isocyanates Lead AIDS virus Hepatitis B virus Rabies virus Caustic soda Hydrochloric acid Bleach Fluorine Hydrogen cyanide B Chloroprene Page 20 of 81 pue UNIVERSIT VENUES ENVIRONMENTAL Y Co ncor d ld HEALTH AND SAFETY a ee wg feier 7 1 2 Chemical Labels Suppliers employers and workers all have specified responsibilities in the Hazardous Products Act When a supplier produces or imports a product for distribution and sale in Canada that supplier must prepare a supplier label which will typically provide seven pieces of information e product identification e hazard symbols representing the classes and divisions into which the product falls e risk phrases e precautionary statements e first aid measures e astatement advising that a material safety data sheet MSDS is available e supplier s identification Furthermore
15. T CONTAMINATE PERSONAL BELONGINGS o Leave personal items outside of the laboratory in order to prevent contamination cell EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 14 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY nn wg wow phone car keys tablet or laptop MP3 player o Keep work items e g backpacks notebooks pencils pens off of bench areas where experiments are conducted e LEAVE LAB SUPPLIES INSIDE THE LAB e REMOVE GLOVES BEFORE LEAVING THE LAB Laboratory personnel shall e NOT prepare store or consume food or beverages in the laboratory e NOT pipette by mouth e NOT smoke in the laboratory e NOT apply lip balm or cosmetics e NOT handle contact lenses in a laboratory area e NOT wear ear phones or head phones in the laboratory e NOT wear laboratory coats in public areas 6 2 2 Housekeeping L Workplace Organization e All work areas benches and floors must be clean dry and uncluttered e Aisles should be clear of obstacles such as boxes chemical containers and other storage e Drawers and cabinet doors should be kept closed e Electrical cords should be secured off the floor to avoid tripping hazards e Spilled liquids should be cleaned up promptly to avoid slipping hazards e Exitdoors and exit paths must be kept clear at all times e Safety equipment such as fire extinguishers and safety showers must be accessible and must be clear of obstacles e Su
16. a hazardous materials spill response policy and procedures and ensures their compliance with all federal provincial and municipal legislation concerning occupational health and safety and the protection of the environment More details can be found on the Emergency Management webpage Spills can be categorized as either incidental minor or emergency major spills The following definitions are in accordance with the Occupational Safety and Health Administration OSHA of the United States Department of Labor More details can be obtained on the OSHA website Incidental Spill or Minor Spill means a release of hazardous material which does not pose a significant safety or health hazard to employees in the immediate vicinity or to the employee cleaning it up nor does it have the potential to become an emergency within a short time frame Incidental spills are limited in quantity exposure potential or toxicity and present minor safety or health hazards to employees in the immediate work area or those assigned to clean them Emergency Spill or Major Spill means a release of hazardous material which poses a significant safety or health hazard to persons in the immediate vicinity e Due to the properties of hazardous materials toxicity volatility flammability explosiveness corrosiveness etc and or e Due to the particular circumstances of the release quantity location space considerations availability of ventilation heat and igniti
17. aid treatment must be reported to the immediate Supervisor and EHS by filling out an Injury Near Miss Report form EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 13 of 81 UNIVERSITE ENVIRONMENTAL Co ncordia wear anp sarety ne A E feier 6 Safe Work Practices 6 1 Routes of Exposure There are five main routes of exposure by which products can contact and or enter our bodies Many hazardous materials can cause direct effects at the point of contact such as irritation of the skin eyes mouth or nose Some products can also be absorbed into the body and cause harmful effects on other body systems such as the blood liver or nervous system Some products are not harmful by any route of exposure while others are harmful by some or all of the routes of exposure The five main routes of exposure are Inhalation Hazardous products in the air can be inhaled into the body through the mouth or nose in the laboratory and workplace airborne products can occur in different forms such as gases vapours aerosols dusts or mists Contact Skin Hazardous products can cause direct effects at the point of contact with the skin Some chemicals can be absorbed into the body through the skin Contact Eye Hazardous products can also come in contact with the eyes as dusts mists gases vapors or when liquids are splashed some can be absorbed through the eyes causing harmful effects elsewhere in the body Ingestion In workplaces i
18. and Egress 17 2 1 Fire If smoke and or fire are detected follow the instructions below Alert Activate the nearest alarm pull box and call Security by dialling x3717 Give your name and report the exact location of the fire Confine Close all doors in fire area to confine fire and smoke Evacuate Evacuate the area immediately and meet with the security agents do not hesitate to contact Security if fire is suspected Assist the fire response team and security agents as requested Do not use the elevators to evacuate unless directed by the security agents or the Fire Department Follow EXIT signs that identify the nearest route of egress and once outside move away from the building Always alert Security or assign someone to do so before dealing with a fire Fire extinguishers are provided by the University in corridors public areas laboratories and other locations as required by building and safety codes In the event of a fire laboratory users are not expected to extinguish the fire themselves Laboratory users who have been trained to use a fire extinguisher may attempt to extinguish the fire safely To do SO e Make sure a clear escape route is available before attempting to deal with the fire e Ifa laboratory user is trained to use a fire extinguisher and feels that the fire can be controlled they may use the PASS method to extinguish the fire P Pull and turn the locking pin to break the seal A Aim low by pointing
19. are particular hazards and risks associated with working with cryogenic gases Users should assess the risks and take suitable precautions for their personal safety and the safety of those around them Here are some cryogens found at the University e Liquid Helium 269 C e Liquid Nitrogen 196 C e Liquid Argon 186 C e Liquid Oxygen 183 C e Solid Carbon Dioxide Dry Ice 78 C EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 38 of 81 UNIVERSIT ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY en ee wg fe we The main hazards arising from the use of low temperature liquefied gases are e asphyxiation in oxygen deficient atmospheres e cold burns frostbite and hypothermia from the intense cold e fire in oxygen enriched atmospheres e liquid oxygen condensation e over pressurization from the large volume expansion of the liquid e failure or tampering of pressure relief valves 7 7 1 Cold Burns Frostbite and Hypothermia Contact with extremely cold surfaces can cause cold burns and frostbite Low air temperatures can also cause hypothermia or provoke asthma It is essential that protective clothing such as cryogenic gloves and goggles is worn where there is a risk of contact with the cryogenic liquid or cryogenically cooled materials Avoid direct skin contact with cryogenic liquids or compressed gases escaping from the cylinder 7 7 2 Asphyxiation Liquid Nitrogen Argon and Helium Releasing liquid nitro
20. by EHS Fit testing is the only way to ensure that full respiratory protection can be achieved To get a fit test appointment please contact EHS at ehs concordia ca Replace your respirator when it is e Damaged e Soiled e Causing increased breathing resistance EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 65 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY ZWEE A ELE 16 5 Hearing Protection Hearing protection should be worn if average noise levels are greater than University standards 85 dBA over an 8 hour period Short periods of time at noise levels greater than 85 dBA are permissible without hearing protection A hazard evaluation to measure the sound level is required to determine if hearing protection is necessary Ideally reducing the noise at the source is favoured over hearing protection Efforts should be made to include noise reduction measures in the purchase of noisy equipment Furthermore plug type disposable or reusable or muff type hearing protection can also be used 17 Emergency Procedures 17 1 Injury and Incident Reporting There are specific accident reporting procedures at the University as required by the Act Respecting Occupational Health and Safety and the Act Respecting Industrial Accidents and Occupational Diseases and their regulations Everyone working in the laboratory must be aware that accidents and incidents should immediately be reported to Security and to the Su
21. e nactivates manufacturer s warranties or any other certification on the cabinet In the event of fire attempts to extinguish fire should only be done by people trained in fire extinguisher use In all cases people must activate the nearest fire alarm pull station alert Security x3717 and evacuate the laboratory 15 6 Hot Plates Ovens and Microwaves All heating equipment must be in good working order before use Exercise caution when heating liquids as superheating can cause injury The following precautions should be considered when using these types of equipment e Avoid contact between flammable vapours and heating elements or spark producing components of equipment e Avoid heating toxic materials in an oven unless it is properly vented through engineering controls to the outdoors e Donotuse laboratory equipment for the preparation of food e Do not place closed or sealed containers inside microwave ovens heating up materials in sealed containers can lead to a potential explosion and damage to the microwave oven resulting in potential injuries to laboratory users It is therefore important to always assure that vials heated inside of them have a way to vent any excess pressure generated e Most microwave ovens used within research laboratories are typically the ones designed for home use which do not have pressure and or temperature controls and therefore cannot prevent explosions from happening EHS DOC 001 v 1 Laboratory S
22. exhaust duct provided must be a material of equivalent strength or better as the material used for the cabinet s construction a minimum of 18 gauge sheet steel The exhaust duct must also be a material compatible with the liquids stored inside the cabinet e The exhaust duct must be welded The use of stove pipe dryer vent and PVC is prohibited Other considerations concerning flammable storage cabinets e Flammable storage cabinets should never be located by exit doors e Flammable storage cabinets must be listed by Factory Mutual Underwriter s Laboratory or other qualified testing agencies e Materials stored within flammable storage cabinets should be compatible with the cabinet s design and construction e Grounding is not required unless Class IA flammable liquids are being dispensed from the cabinet e Flammable storage cabinets must be clearly labeled with a sign that reads Flammable Keep Fire Away e Flammable storage cabinets are not design to store flammable compressed gases e Flammable storage cabinets should not be used to store corrosives as they may corrode the cabinet and are incompatible with organic solvents 7 5 Peroxide Forming Solvents and Reagents Solvents and reagents that can form hazardous peroxides should be labeled upon arrival with the date received and the expiration date They must be disposed of before the expiration date to avoid any safety hazards Containers of peroxide forming solvents re
23. face velocity stabilizes The display may be showing the values HI or LO at that time it is fine to use the fume hood under these conditions In the event of an alarm condition a red LED will be illuminated and an audible alarm will sound Do not use the fume hood until the alarm condition has been corrected If the alarm condition doesn t correct Some new low flow fume hoods are designed to run as low as 60 ft min EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 9 of 81 EN NIV ER SITE ENVIRONMENTAL Y Co ncor d ld HEALTH AND SAFETY Www wg eee SS RTE itself after a short delay close the sash and contact the Service Center at x2400 Never disconnect the control box this is the only way to know if the fume hood is working within the required standards In the event of a power failure the fume hood may not function anymore Therefore any experiment should be paused or halted 5 2 3 Emergency Purge The fume hood is equipped with an emergency purge button This button can be used to exhaust any excess fumes resulting from a spill an uncontrolled reaction or an explosion Pressing this button will purge the fume hood by increasing the flow volume by one and a half times the normal flow The display will show EEE and a red LED light This will continue until the button is pressed a second time to cancel the purge 5 2 4 Maintenance Standard maintenance and calibration of fume hoods is carried out annually by C
24. minimize this risk It is recommended to exclude combustible materials EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 39 of 81 E Se UNIVERSITE ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY ne ee eee 7 7 5 Over Pressurization Cryogenic systems must be designed with adequate pressure relief measures such as valves This prevents a dangerous build up of pressure as the liquid condenses into a gas in a sealed system Vessels and piping shall sustain at least 150 percent of maximum pressure relief Cryogens Guidelines can be found on the EHS website 7 8 Liquefied Petroleum Gases LPG 7 8 1 Definition and Associated Hazards A liquefied petroleum gas LPG is a flammable mixture of hydrocarbon gases butane iso butane propane propylene butylene and other hydrocarbons of low molecular weight refined from petroleum within a pressurized container which exists both as a liquid and a gas at 20 C 68 F LPGs are mainly used as a fuel in heating appliances and vehicles It is important not to store LPG cylinders inside flammable liquid storage cabinets Storage and usage of LPG is covered in NFPA 58 Liquefied Petroleum Gas Code while storage of flammable liquids is covered in NFPA 30 Flammable and Combustible Liquids Code LPGs are not flammable liquids they are flammable liquefied gases This distinction is very important Flammable liquids and flammable gases have different storage conditions
25. or controls e Issues involving the building electricity must be reported to the Service Centre at x2400 e Access to electrical control panels disconnect switches and transformers must be kept clear of obstructions By code electrical control panels must have a 1m clearance e Electrical modifications and repairs must be made by electricians from Facilities Operations or authorized departmental technicians 14 1 2 Static Electricity The build up or generation of static electricity within certain metallic pieces of equipment can create sparks which cause a significant fire hazard when flammable substances are being stored or used within their vicinity e g solvent cabinets drums etc Therefore static electricity must be dissipated through grounding set ups before the handling or transfer of any flammable substances Grounding must be applied to any metal piping or pump used during flammable solvent transfer operations EHS recommends having the following items grounded even in the absence of dispensing e Flammable solvent storage cabinets e Metal drums or cans containing flammable solvents 14 2 UV Radiation UV radiation is a non ionizing form of radiation and invisible to the eye UV radiation is found in the 100 nm to 400 nm wavelength region of the electromagnetic spectrum Everyday exposure to ultraviolet radiation is typically in the UVA region resulting from exposure to direct sunlight The Earth s atmosphere shields us from
26. standardized sentences that describe the hazards of the product The wording of the hazard statement helps describing the degree of the hazard Some examples of hazard statements include e Extremely flammable gas e Contains gas under pressure may explode if heated e Fatal if inhaled e Causes eye irritation e May cause cancer Precautionary statements provide standardized advice on how to minimize or prevent harmful effects from the product They give instructions about storage use first aid PPE and emergency measures Some examples of precautionary statements include e Keep container tightly closed e Wear protective gloves protective clothing eye protection face protection EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 24 of 81 UNIVERSITE amp Concordia ZWEE feier ENVIRONMENTAL HEALTH AND SAFETY e _lfexposed or concerned get medical advice attention e Fight fire remotely due to risk of explosion e Protect from sunlight The following information will be required on WHMIS 2015 supplier labels 1 Product identifier 2 New hazard pictograms 3 Signal word 4 Hazard statements 5 Precautionary statements 6 Initial supplier identification Figure 7 2 3 1 WHMIS 2015 supplier label Product K1 Produit K1 Danger Fatal if swallowed Causes skin irritation Precautions Wear protective gloves Wash hands thoroughly after handling Do not eat drink or smoke when using this p
27. store these chemicals under a nitrogen blanket Butadiene when stored as a liquid Potassium amide Inorganic Peroxide monomer Former Chloroprene when stored as a liquid Sodium amide Inorganic Peroxide Former monomer Sodamide Inorganic Peroxide Former Diisopropyl ether Tetrafluoroethylene When Stored as a Divinyl acetylene Liquid Monomer Divinyl ether Vinylidene chloride Isopropyl ether Class II Chemicals that form explosive levels of peroxides upon concentration are listed below These chemicals typically accumulate hazardous levels of peroxides when evaporated distilled contaminated or have their peroxide inhibiting compounds compromised After receiving they should not be kept past 12 months or the manufacturer s expiration date After this period the product must be disposed Acetal Acetaldehyde Benzyl alcohol Butadiyne 2 Butanol Cellosolves Chlorofluoroethylene Cumene Cyclohexene Cyclohexanol 2 Cyclohexen 1 ol Cyclooctene Cyclopentene Decahydronaphthalene Decalin Diacetylene Dicyclopentadiene Diethyl ether Diethylene glycol EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Diglyme Dimethyl ether Dioxanes Ethyl ether Ethylene glycol dimethyl ether Ethylene glycol ether acetates Furan Glyme 4 Heptanol 2 Hexanol Isopropyl alcohol Isopropylbenzene Methyl acetylene 3 Methyl 1 butanol Methyl cyclopentane Methyl isobutyl ketone 4 Methyl 2 Pentanol 4 Methyl 2 Pentanone 2 Methyltetrahyd
28. the nozzle or hose at the base of the flames S Squeeze the handle to release the extinguishing agent S Sweep from side to side until the fire is out e Extinguishers work for approximately 30 seconds if the fire has not been extinguished in that time leave the area immediately e When leaving close the door and do not lock it If the fire cannot be controlled with the extinguisher follow evacuation procedures that have been established and practiced during fire drills For additional information refer to the University s Emergency Management webpage 17 2 2 Egress Make certain that all means of egress in the laboratory are unobstructed at all times Become familiar with the area specific fire plan Identify escape routes from the work area EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 67 of 81 2 UNIVERSIT ENVIRONMENTAL Y Co ncor d l HEALTH AND SAFETY GA eX E Np 17 3 Power Failure In the event of a power failure general ventilation may be compromised and laboratory equipment may not function including fume hoods BSC etc Therefore all experiments must be either paused or halted and fume hoods and BSC sashes must be lowered No further laboratory activity should be conducted until power is restored 17 4 Spills Because hazardous materials are used in laboratories studios workshops and service areas a spill or accidental release may occur anywhere in the University The University maintains
29. the specific gas and marked for its maximum cylinder pressure Never use homemade adaptors or force connections between cylinder valve and gas handling equipment Do not apply any lubricant jointing compound or tape to cylinder valves fittings or regulator threads unless specified by the manufacturer The regulator system shall be equipped with two gauges to show both the cylinder pressure and the outlet pressure Where the source cylinder is outside of the laboratory a station regulator and gauge shall be installed at the point of use to show outlet pressure Cylinders shall have a manual shutoff valve 7 6 3 Storage Guidelines Store gas cylinders In an upright position Within a well ventilated area Separated from empty cylinders With a chain or appropriate belt above the midpoint but below the shoulder Laboratory cylinders less than 18 inches tall may be secured by approved stands or wall brackets Away from corrosive chemicals Away from direct sunlight or heat sources Capped when not in use At least 20 feet away from all flammable combustible or incompatible substances Storage areas that have a non combustible wall at least 5 feet in height and with a fire resistance rating of at least 30 minutes may be used to segregate gases of different hazard classes in close proximity to each other EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 36 of 81 KC ei dede iie ENVIRONMENTAL Oncor di ld HEALTH AND SAFETY
30. the text must be in English and French and contained within a hatched boarder Supplier labels from laboratory supply houses packaged in 10 kilogram quantities and intended for laboratory use must have e product identifier e risk phrases e precautionary measures e first aid measures e reference to availability of MSDS Workplace labels are required on containers of controlled products produced on site and on containers in which the product has been transferred from a supplier s container Workplace labels must provide three types of information e product name e safe handling information e reference to the MSDS In Quebec the minimal language requirement for workplace labels is French however English can also be used since it represents the teaching working language at Concordia University Hazard symbols and the use of the hatch mark border are optional A sample workplace label is shown below At Concordia all containers holding hazardous Acetone material must be labelled with a workplace label In addition if the controlled product is transferred to Keep away from heat sparks and flames piping systems reaction vessels etc the employer must ensure the system is properly identified as to its content Workers must be instructed regarding the Wear safety goggles and butyl rubber gloves Use with local exhaust ventilation MSDS available information contained on labels and identifiers The employer must take
31. water supply is appropriate regular and homogenised flow between the outlets e Verify the water temperature e Ensure the water is clear of sediments e Minimize microbial contamination caused by stagnant water The maintenance and calibration of emergency showers and eyewashes is carried out annually by Concordia University Facilities Operations If a particular eyewash station requires maintenance the laboratory supervisor is responsible for contacting Facility Management x2400 to have the eyewash safety shower fixed Note emergency showers can also be used for extinguishing clothing fires or for flushing contaminants off clothing 5 3 2 Emergency Shut Offs Gas and electrical shut offs are found in certain laboratories or on certain equipment They must be clearly labeled Equipment emergency shut offs ESO are large red or yellow buttons generally located on or near the device Laboratory electrical shut offs are wall mounted electrical switches They are generally located near the device and will cut the power to the device Most laboratories are equipped with gas shut offs The gas shut off access is located in the wall near the main laboratory door and is accessible from the laboratory or the corridor In the event of a fire in the laboratory occupants should shut off the gas in the room from the corridor by turning the lever handle to the off position evacuate the laboratory and call Security x3717 EHS DOC 001 v 1 Laborato
32. will depend upon the resistance of the microorganisms convenience stability compatibility with the materials and the health hazards For general decontamination guidelines please refer to the Biosafety Program webpage 13 2 3 Biohazardous Waste Pickup Procedure Once you have biohazardous waste ready to be picked up the following procedure must be followed 1 2 3 4 Make sure to properly close all waste containers to avoid contamination outside the working area once the containers are picked up Clearly identify any containers that contain anatomical waste Send the information for pickup by e mail to hazardouswaste concordia ca Biohazardous waste pickups are generally done 24 48h after reception of request 13 2 4 Guidelines Do not overfill biohazard waste containers Do not try to compact waste with your hands or feet If required research laboratories can use other types of biohazard waste containers at their own expense provided that they are designed for the disposal of such waste These containers will also be picked up during regular pickup rounds EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 48 of 81 rete ENVIRONMENTAL v Co ncor di ld HEALTH AND SAFETY wae ES ese 13 3 Radioactive Waste Radioactive waste is defined as any waste containing radioactive material The radioactive waste management at the University is under the strict control of the Radiation Safety Officer RSO Radioactive wa
33. 1 Laboratory Safety Manual DRAFT Page 62 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY nn wg wow 16 2 2 Glove Selection The following are links to various companies with glove compatibility or chemical resistance charts for gloves supplied by those companies These charts can be used to ensure the gloves selected will provide adequate protection for the wearer when handling a given chemical It is important to note that all chemicals will not be listed on these charts and that two similar gloves supplied by two separate manufacturers may not provide the same level of protection to a specific chemical Therefore it is necessary to consult the manufacturer s specific compatibility chart for the brand of gloves being used Understanding terms used in glove compatibility charts e Breakthrough time time it takes for the chemical to travel through the glove material This is only recorded at the detectable level on the inside surface of the glove e Permeation Rate time it takes for the chemical to pass through the glove once breakthrough has occurred This involves the absorption of the chemical into the glove material migration of the chemical through the material and then de absorption once it is inside the glove e Degradation rating this is the physical change that will happen to the glove material as it is affected by the chemical This includes but is not limited to swelling shrinking hardening c
34. 3717 or 514 848 3717 5 Provide Security with the following information o Location of the spill o Name of hazardous material o Quantity involved o Related health hazards and precautions to be taken 6 Provide Material Safety Data Sheet MSDS or appropriate documentation 7 Remain available to the University Spill Response Team or Security in order to provide assistance 17 4 3 Spill Kits Spill kits and materials should be readily available for staff or students who want to clean up minor spills Kits or spill cleanup materials should be e Located where the hazardous material is being used e g laboratory e Available from the Department or Department Safety Officer or Technical Officer Typical spill kit contents are listed in Appendix V EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 69 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY U La A T E qp 18 References Act Respecting Occupational Health and Safety Quebec R S Q chapter S 2 1 Act respecting pressure vessels Quebec s A 20 01 American Chemical Society Safety in academic chemistry laboratories 7 Edition 2003 American Society of Heating Refrigerating and Air Conditioning Engineers Inc Thermal environmental conditions for human occupancy ASHRAE 55 1992 ANSI standard Z316 5 94 American National Standards Institute Ashbrook P C Renfrew M M Safe Laboratories Principles and practices for design and remodeling
35. ENVIRONMENTAL S C oncor d ia HEALTH AND SAFETY LABORATORY SAFETY MANUAL OCTOBER 2015 la SS v UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY nn wm NN fe ie Table of Contents TEEN EDI ETE n i PII ii 1 Introduction 1 2 KT 1 3 University Health amp Safety Policies i ccicsciccciccccsscccssceccssccesecsdscceessc cesaccsccceececscevesseccssececssnsescceccsecessessesccscorsesses 1 d RESPOnsibilities mec 2 4 1 CIS REI EE 3 4 1 1 Act Respecting Occupational Health and Safety L R Q c S 2 1 3 4 1 2 Regulation Respecting Occupational Health and Safety IcS 31r1901l 3 4 1 3 The Criminal Code R S C 1985 cCAel nennen nennen nenne nenne nennen nene nennen 3 4 1 4 CSST 4 4 2 DUS DING quA 4 4 2 1 Demonstrating Due Diligentce cssteassesvectescasdssescsianssacasdvaabissactvacsdsesnacssacins caine ntdssanzanessenensdsss 5 4 3 Re el GE 5 4 4 EHS External Training Recognition idee EERSTEN EENS ANEREN 6 4 5 laboratory Let EE 6 4 6 labor tory INSPOCHONS w 7 4 7 Hazard Assessments amp Standard Operating Procedures eese eene nnns nna 7 4 8
36. EUN ER ER EE ER EE ER EEN ERE EE ERE Lime E ES DM HDD UN EE GN GER GEN GER DG GR GER DOG GER GR GR GR GR GR GR meme NT a E E EE EES etones 3 surea A GUN ER REN RUN RUN GUN RUN EUR GR DER DER GR RR RE GR SD ELS E E EET EES ELE EIE EE Dx sS SS EL EI E E UE X X X X x EXE NN E E o E mem re sm ee a eem eas 00 5 CS Semer EEE E EE EE RES ES ES ES PE OEE A EE EEN Unsafe storage combination L Safe storage combination A more detailed segregation Table can be found in the APPENDIX II 7 4 3 Storage of Flammable Materials The use and storage of flammable and combustible liquids may be necessary for some research laboratory operations Flammable liquids are defined as liquids with a flash point below 38 C and a vapor pressure that does not exceed 40 psi at 38 C Flammable liquids are subdivided as follows Table 7 4 3 1 Flammable Liquids Classification Flammable liquid Class Definition Exmples Liquids with flash points below 23 C and boiling points below 38 C Diethyl ether n Pentane Acetaldehyde Liquids with flash points below 23 C and boiling points at or above 38 C Liquids with flash points at or Isopropyl alcohol Turpentine above 23 C and below 38 C Xylenes Acetone Acetonitrile Ethanol gt 50 if aqueous EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 32 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY nn ee E feier Combustible Liquids are liquids wit
37. Flammable liquids should be stored in approved flammable safety cabinets spark proof fridges or freezers e All chemicals in a laboratory should have a definite storage place and should be returned to that location after being used e Chemicals should never be stored on the floor or in the fume hood unless the hood is dedicated for that purpose e All containers must have caps and covers that are securely in place whenever the container is not in use e Avoid storing chemicals on bench tops except for those chemicals in use or non hazardous dry chemicals such as salts e g sodium chloride potassium chloride filtering media e g Celite silica sand or drying agents e g magnesium sulfate 7 4 2 Compatibility Incompatible chemicals are those that if mixed would produce toxic gases explosive reactions or spontaneous ignition Such chemicals should never be stored or handled in a manner that might allow contact EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 31 of 81 EECHER ENVIRONMENTAL v Co ncor di ld HEALTH AND SAFETY wmwmtTwESRSS TIT Table 7 4 2 1 is a chart adapted from the CRC Laboratory Handbook which groups various chemicals into 24 different groups with examples and incompatible chemical groups This chart is by no means complete but it will aid in making decisions about storage Table 7 4 2 1 Chemical Group Compatibility for Safe Storage Se IER Ee ES CIE EET EE EE LED DO DC X OXCX DC RURAUX SX LX X kn
38. Lewis Publishers Inc 1991 CCOHS Website www CCOHS ca CSST Website www csst qc ca Concordia University Policy VRS 49 Website ehs concordia ca Controlled Products Regulations SOR 88 66 CNSC Canadian Nuclear Safety Commission Nuclear Safety and Control Act and Nuclear Substances and Radiation Devices Regulation S C 1997 c 9 Crawley Cooper E Laboratory Design Handbook CRC Press 1994 CSA Standard Z316 5 04 Fume hoods and associated exhaust systems Canadian Standards Association CSA Standard Z94 3 07 Eye and Face Protectors Canadian Standards Association Fuscaldo A A Erlick B J Hindman B Laboratory Safety Theory and Practice Academic Press 1980 Hazardous Products Act Federal R S 1985 c H 3 Hazardous Products Act R S C 1985 c H 3 Hazardous Products Regulations SOR 2015 17 Health Canada Website www hc sc gc ca Laboratory Biosafety Guidelines a edition Health Canada 2004 Laboratory Safety Institute Laboratory Health and Safety notebook 2002 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 70 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY GA ek NN gp MD 15128 2013 Laboratory Fume Hoods Guidelines for Building Owners Design Professionals and Maintenance Personnel Public Works and Government Services Canada April 2013 National Academy of Sciences www nasonline org NFPA 10 National Fire Protection Agency Codes and Standards NFPA 30 Nat
39. Mercury Even though the use of metallic mercury at the University is not prohibited EHS strongly suggests minimizing its usage and replacing it with less hazardous alternatives Mercury causes health hazards and has been recognized as an environmental contaminant by several public organisms Health Canada Environment Canada Institut National de Sant Publique du Qu bec Furthermore in the event of a mercury spill special cleaning procedures must be taken Old laboratory equipment using thermometers barometers manometers or other measuring instrumentation are likely to contain mercury However it is now possible to obtain scientific equipment where mercury has been replaced with safer and greener alternatives without compromising the measurements quality and precision Non mercury thermometers contain about 0 15mL of different colored organic liquids kerosene acetone alcohol or vegetable oil which make them less hazardous in the event of a spill Therefore a broken non mercury thermometer can be thrown directly into a puncture proof chemical waste container Electronic thermometers can also represent interesting alternatives to mercury They can measure temperatures from 50 C to 300 C However most thermometers with mercury replacement liquid or electronic cannot measure temperatures above 300 C Therefore other alternatives such as thermocouples should be considered Mercury Safety Guidelines are available from the EHS websit
40. NCE COMPLIANCE RECORD VU N I Y E R 5 IT Y Training with evaluation o TRAINING Training without evaluation D ACTIVITY TITLE Self Training D TRAINER Seminar o Safety Talk B DEPARTMENT Coaching Monitoring D Proof from Other Institution D COMPANY Other activity D Date Time Duration Location pone minutes Date DESCRIBE KEYPOINTS OR ATTACH TRAINING DOCUMENT LAST Name FIRST Name ID NUMBER EMAL DEPARTMENT SUPERVISOR SIGNATURE TRAINING CODE SESSION ID EHS Processed by Date EHS FORM 032 v 2 PLEASE RETURN COMPLETED FORM TO EHS via Internal Mail GM 1100 50 or E Mail ehs concordia ca This form is also available in French on EHS website Back to section 4 3 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 72 of 81 m D WV Concordia ENVIRONMENTAL HEALTH AND SAFETY Appendix II Segregation of Incompatible Chemical Classes Inorganic Acids Organic acids Caustics Amines and Alkanolamines Halogenated Compounds Alcohols Glycols Glycol Ether Hydrochloric acid Hydrofluoric acid Hydrogen chloride Hydrogen fluoride Nitric acid Sulfuric acid Phosphoric acid Acetic acid Butyric acid Formic acid Propionic acid Sodium hydroxide Ammonium hydroxide solution Aminoethylethanolamine Aniline Diethanolamine Diethylamine Dimethylamine Ethylenediamine 2 Methyl 5 ethylpyridine Monoethanolamine Pyridine Triethano
41. NFPA 30 The purpose of a flammable storage cabinet is to prevent the contents from catching fire or exploding for at least 10 minutes in case of fire in order to give personnel a chance to escape A flammable storage cabinet may be required depending upon e The class of flammable or combustible liquid e The total quantity of flammable or combustible liquid e The location of the flammable or combustible liquid According to NFPA 30 it is not a requirement for flammable storage cabinet to be ventilated Doing so could reduce the cabinet s fire protection effectiveness If not vented the vent openings must be sealed by a fireproof material of equivalent fire protection grade for example the bungs provided by the cabinet manufacturer However if researchers choose to vent their cabinets in order to reduce odorous vapors the following criteria must be followed e Mechanical exhaust ventilation must be utilized Exhaust must be discharged above the roof using an existing laboratories exhaust system or an independent system EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 33 of 81 2 UNIVERSIT VERRE em ENVIRONMENTAL MJ Co ncor d ld HEALTH AND SAFETY mn ee E fe ey e The cabinet must be vented from the bottom with fresh air being supplied from the top The flame arrestor must remain in both the lower and upper bung holes The bung holes should be regularly inspected and cleaned to prevent them from becoming blocked e The
42. SAFETY nS gm Now 13 2 Biohazardous Waste Biohazardous biomedical waste refers to any material having the risk of carrying pathogens which can be potentially harmful Biohazardous waste generated at the University includes e Human and animal blood and blood products e Cultures and stocks of etiologic agents and associated biological e Laboratory waste that has come in contact with a biological material this includes but is not limited to culture dishes blood specimen tubes devices used to transfer inoculate and mix cultures and other materials which have come in contact with biological material including disposable personal protective equipment and clothing e Sharps that have been in contact with biological materials e Animal waste animal carcasses and body parts 13 2 1 Containers for Biohazardous Waste Any solid biohazardous waste material should be placed in an appropriate container or bag which bears the biohazard symbol The biohazard waste containers can be obtained either e from the Chemistry Central Store SP 132 02 Loyola Campus or e from EHS upon request Loyola and SGW Campuses The following containers should be used for their disposal For non anatomical waste For anatomical waste For sharps Grey bin with yellow bag inside 20 L red pail 4 L yellow container Gloves plastic pipettes blood carcasses unfixed animal tissues Syringes needles scalpels products other biological fluids any
43. Standards on Fire Protection for Laboratories Using Chemicals e NFPA 55 Compressed Gases and Cryogenic Fluids Code e NFPA 58 Liquefied Petroleum Gas Code e National Fire Code of Canada 2010 including Quebec modifications Always contact EHS for a hazard assessment prior to any cylinder set up EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 35 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY en ee wv 7 6 1 Handling Requirements Obtain proper training and information before using a gas cylinder Never drag or physically carry cylinders lecture cylinders may be carried Never lift cylinders by the cap Do not drop or bang cylinders against each other Use a hand cart designed for the transport of cylinders Secure cylinder caps during transport Leave the cylinder cap in place until the cylinder is secured and ready for use Do not rely on cylinder colour to identify the gas Different suppliers may use different colours for cylinders of the same gas Only transfer cylinders or cryogenic liquid containers across buildings using Distribution Services 7 6 2 Cylinder Set Up Contact EHS prior to any cylinder set up Secure cylinders to a wall a cylinder rack or an appropriate bench in an upright position using a chain or a cylinder belt wires are not acceptable above the midpoint but below the shoulder Cylinders in the laboratory shall be equipped with a pressure regulator designed for
44. The new HPR modified the Workplace Hazardous Materials Information System WHMIS 1988 to incorporate the Globally Harmonized System of Classification and Labelling of Chemicals GHS for workplace chemicals This modified WHMIS is referred to as WHMIS 2015 Even though the GHS system is now ready for worldwide implementation many countries including Canada are only beginning the task of harmonizing existing regulatory regimes within the GHS framework In order to give suppliers employers and workers time to adjust to the new system implementation of WHMIS 2015 will take place over a three stage transition period that is synchronized nationally across federal provincial and territorial jurisdictions During the different transition phases proposed both WHMIS 1988 and WHMIS 2015 versions can be used More details concerning the different WHMIS transition phases can be obtained from Health Canada WHMIS Transition web page 7 2 0 WHMIS 2015 Classification The new WHMIS 2015 legislation proposes new classification rules and hazard classes based on physical and health hazards The environmental hazards proposed by GHS have not been retained under the new WHMIS 2015 legislation even though suppliers are free to identify them on their products Hazard groups are also divided into hazard classes which are further divided into categories and subcategories Table 7 2 2 1 WHMIS 2015 Physical Hazard Classes Physical Hazard Classes Flammable gases Subst
45. UV radiation source e UV enclosures and interlocks supplied by the manufacturer must be used at all times Refer to the manufacturer s safety precautions and user manuals e Never work in a biological safety cabinet while the germicidal lamp is on e UV exposure may be minimized by limiting exposure time and increasing the distance to the UV source e Use appropriate PPE such as safety goggles with UV protection UV face shields long sleeves and tightly woven clothing that cover much of the body and appropriate gloves Application of sunscreen with high sun protection factor against UVA and UVB can provide limited protection but should not be used as the only means of protection e Equipment that emits UV radiation shall have a proper caution label The label should state an appropriate warning such as CAUTION UV RADIATION HAZARD USE ONLY WITH SHIELDING IN PLACE PROTECT EYES AND SKIN FROM EXPOSURE TO UV LIGHT 14 3 Glassware Glassware is used cleaned and stored in all laboratories These are generally used for laboratory experiments and include items such as pipettes burettes graduated cylinders volumetric flasks beakers flasks test tubes etc Glassware can be mishandled and broken causing a workplace injury Glassware should be substituted with non glass laboratory products whenever possible Alternatives can include products made from polymethylpentene PMP high density polyethylene HDPE low density polyethylene LDPE polycarbon
46. afety Manual DRAFT Page 60 of 81 2 UNIVERSIT VERRE em ENVIRONMENTAL Y Co ncor d ld HEALTH AND SAFETY Z A E fe wer 15 7 Water Baths A water bath is a device that maintains water at a constant temperature It is used in the laboratory for incubations Water baths can become contaminated and pose aerosol hazards To prevent contamination the water bath should be cleaned and disinfected regularly The following precautions should be taken into consideration when using a water bath e When operating keep minimum water level according to the manufacturer s recommendation Never operate an empty water bath e The water bath should be disconnected before filling or emptying e Keep away from flammable and combustible materials e Use a non mercury thermometer for visual monitoring of the bath temperature 16 Personal Protective Equipment PPE Personal protective equipment PPE is necessary to work with most hazardous materials and or to perform certain experiments It may also be necessary to supplement the safety equipment in laboratories such as the fume hoods Proper PPE selection is essential for adequate protection from the hazards PPE must be available and supplied to all staff by the laboratory PI or Supervisor The SOP must specify the necessary PPE signage may be posted in the laboratory to indicate mandatory PPE For more details concerning Concordia University policy on personal protective equipment please refer t
47. agents should be periodically inspected Avoid contact if there are signs of crystallization of the chemical Contact Security immediately at x3717 Peroxide forming solvents and reagents are divided into 3 categories of which class 1 is the least dangerous and class 3 is highly dangerous EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 34 of 81 UNIVERSITE WV Concordia Pn eh E fe ie SS ENVIRONMENTAL HEALTH AND SAFETY Table 7 5 1 The Classes of Peroxide Forming Solvents Class Ill Class Il Class Explosive levels of peroxides are formed without a concentration step e g evaporation distillation etc These chemicals can be a particular hazard since peroxides can form even without opening the containers Therefore only small amounts should be ordered and used as soon as possible If stabilizers are present in solution they can be kept for up to one year or up to the manufacturer s expiration date where appropriate With no stabilizer present they should not be kept for over three months after opening When possible store these chemicals under a nitrogen blanket Explosive levels of peroxides are formed upon concentration These chemicals typically accumulate hazardous levels of peroxides when evaporated distilled contaminated or have their peroxide inhibiting compounds compromised After receiving they should not be kept past 12 months or the manufacturer s expira
48. ained on the OSHA website at www osha gov html faqg hazwoper html faq8 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page iii UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY eee T E qp Normal Hours of Operation The hours of operation of each individual location building premises or department at the University which may vary from one department to another refer to Concordia University Policy VPS 6 Supervisor A faculty member director manager principal investigator technical supervisor or any other person having direct responsibility for the activities of an employee or student TDG Transport of Dangerous Goods a national program to promote public safety during the transportation of dangerous goods The TDG Directorate serves as the major source of regulatory development information and guidance on dangerous goods transport for the public industry and government employees University Spill Response Team Environmental Health amp Safety EHS personnel who are certified Technicians of Hazardous Waste Operations and Emergency Response under the Occupational Safety and Health Administration standard OSHA 1910 120 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page iv UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY nee Ng fe we 1 Introduction Concordia University s Laboratory Safety Manual provides the information on the requirements related to safety and the prevent
49. al hazards such as moving parts and noise The following precautions should be considered when using mixing equipment e Equipment that may generate CL2 biohazardous aerosols must be used and opened in the biosafety cabinet e Wait 2 5 minutes after operating to ensure that aerosols have settled before opening containers e Wear appropriate PPE such as lab coat safety glasses goggles respiratory and hearing protection 15 5 Bunsen Burners Bunsen burners produce a single open flame by burning a continuous stream of flammable gas used for heating sterilization and combustion As a result they present a fire hazard and a potential for an accident to occur If possible Bunsen burners should be replaced with safer alternatives such as e Electrical incinerators e Touch plate microburners e Pre sterilized inoculating loops spreaders and needles e Bead Sterilizers Furthermore biological safety cabinets BSCs and disposable sterile items obviate the need for open flames when aseptic conditions are needed If a Bunsen burner cannot be replaced it is important that the following guidelines be observed e Place the Bunsen burner away from any overhead shelving equipment or light fixtures e Remove all papers notebooks combustible materials and excess chemicals from the area e Tie back any long hair dangling jewelry or loose clothing e Wear appropriate PPE flexible gloves e g latex or nitrile should be removed when light
50. ances and mixtures which in contact with water emit flammable gases Flammable aerosols Oxidizing liquids Oxidizing gases Oxidizing solids Gases under pressure Organic peroxides Flammable liquids Corrosive to metals Flammable solids Combustible dust Self reactive substances and mixtures Simple asphyxiants Pyrophoric liquids Pyrophoric gases Pyrophoric solids Physical hazards not otherwise classified PHNOC Self heating substances and mixtures EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 23 of 81 UNIVERSITE ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY On wg NN Table 7 2 2 2 WHMIS 2015 Health Hazard Classes Health Hazard Classes Acute Toxicity Reproductive Toxicity Skin corrosion irritation Specific Target Organ Toxicity Repeated Exposure Carcinogenicity 7 2 3 Supplier Label Requirements Most of the WHMIS 2015 supplier label elements will be standardized and the information must be easily legible without the aid of any device other than corrective lenses Each hazard class and category has a prescribed e Signal word e Hazard statements H phrases e Precautionary statements P phrases e Hazard pictogram s The signal word indicates the severity of the hazard e Danger for more severe hazards e Warning for less severe hazards Only one signal word must appear on the label Some low hazard categories may not have a signal word assigned Hazard statements are brief
51. as in laboratories workshops and studios Every laboratory worker and student must be aware of the location of the emergency eyewash and shower in their work area They must be trained on how to use the eyewash and shower in an emergency and to be prepared to assist others The area around emergency equipment must be kept clear and free of obstructions at all times including around countertop mounted eyewash units A safety equipment is any equipment specifically designed to minimize or reduce harm or death This safety equipment shall conform to the requirements of ANSI standard Z358 1 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 10 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY d E E fe e The first few seconds following exposure to a hazardous material especially corrosive chemicals are critical e Flush the eye s or body immediately for at least 15 minutes delaying this action could result in permanent tissue damage e Remove contaminated clothing while under the shower health has first priority e Do not hesitate to use the eyewash or shower even if the floor has no drains e Have someone call Security x3717 immediately for assistance The victim must seek medical attention as soon as possible after first aid has been given It is the responsibility of the Supervisor of the laboratory to ensure that Emergency eyewash Stations are tested weekly in order to e Verify that the
52. ate PC and Teflon TFE The following precautions should be implemented when using glassware e Ensure that the glassware is designed for its intended use borosilicate glassware is recommended for most laboratory applications Certain applications may require the use of Pyrex shatterproof glassware e Use appropriate PPE such as insulated gloves or tools such as tongs when handling heated glassware Extreme caution should be used when working with glassware at very high or low temperatures e Glassware should be cleaned as soon as possible e Glassware should be rinsed thoroughly to prevent contamination Do not towel dry glassware but allow to air dry Glassware should be inspected before use to ensure it is free from any defects or particulate matter Any glassware with chips cracks or scratches should be removed from service repaired or disposed of properly refer to the waste procedures in Chapter 13 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 54 of 81 EN NIV ER SITE ENVIRONMENTAL Y Co ncor d ld HEALTH AND SAFETY Z A EA fe we SS RTE Hazardous Waste 14 4 Ergonomics Ergonomics is the study of the way in which people work and interact with the characteristics of their work environment It includes finding ways to be more efficient as well as ways to protect people from sustaining injuries from repetitive tasks The goal is to design the job to fit the worker rather than physically forcing the worker s b
53. ave been in contact with any form of biological material blood serum or other body fluids cultures vaccines organs etc should be disposed of in biohazard containers refer to the section 0 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 50 of 81 pu UNIVERSIT VENUES ENVIRONMENTAL MI Co ncor d ld HEALTH AND SAFETY Z A EA fe we Biohazardous Waste i Broken Glass e In order to protect the laboratory and cleaning staff all broken glass free of any contamination should be disposed of in dedicated broken glass boxes labelled BROKEN GLASS e No broken glass contaminated or not should be disposed of in regular garbage e These containers are picked up by the cleaning staff and are not to be re used or recycled e Broken glass containers can be obtained from EHS For more details please refer to the Broken Glass Waste Disposal Procedure 13 4 2 Guidelines e Sharps should never be thrown away in regular garbage bins e Needles should not be bent sheared recapped or removed from the syringe 13 5 Mixed Waste Mixed hazardous waste is composed of materials that have been in contact with various sources of contaminations chemical biological or radioactive 13 5 1 Disposal The following order of priority should be used for disposal of mixed waste containing different types of hazards Radioactive Biological Chemical For example if sharps are contaminated with a mixture of hazardous components
54. boratory users are not expected to extinguish the fire themselves Laboratory users who have been trained to use a fire extinguisher may attempt to extinguish the fire safely To do SO e Use a fire pull station alert security or assign someone to do so before dealing with a fire e Make sure a clear escape route is available before attempting to deal with the fire e If a laboratory user is trained to use a fire extinguisher and feels that the fire can be controlled they may use the PASS method to extinguish the fire P Pull and turn the locking pin to break the seal A Aim low by pointing the nozzle or hose at the base of the flames S Squeeze the handle to release the extinguishing agent S Sweep from side to side until the fire is out e Extinguishers work for approximately 30 seconds if the fire has not been extinguished in that time leave the area immediately e When leaving close the door and do not lock it New fire extinguishers or replacements can be obtained by contacting the Service Centre at x2400 5 3 4 First Aid Kits In accordance with the Concordia University VPS 45 Policy each laboratory must have a properly stocked first aid kit maintained under the responsibility of the Laboratory Supervisor or PI First aid kits and supplies that comply with CSST requirements are available for purchase from the Emergency Management via the online First Aid Supplies Ordering Form Injuries or illnesses which require first
55. cartridges and other e waste for recycling More details about recycling can be obtained at Rethink Waste webpage 13 7 Non Compliance Disposal of hazardous waste is free of charge provided proper waste disposal guidelines are followed In the event that hazardous waste procedures are not respected EHS will take the following actions 1 First Infraction A Non Compliance Notice indicating the nature of the problem s encountered during the hazardous waste pickup 2 Second Infraction A Non Compliance Notice indicating that the requester will be required to attend Hazardous Waste Management Training 3 Third Infraction A Non Compliance Notice indicating all hazardous waste collection for the area is suspended and a meeting request with the individual responsible for the area PI Researcher Supervisor in order to determine the corrective actions necessary to resolve 14 Physical Hazards 14 1 Electrical Safety 14 1 1 General Electrical Safety Living organisms are electrical conductors and electrification occurs when there is a potential difference between two points in the organism The danger of electrical accidents occurs not only from contact with a live conductor but from a simultaneous contact with a live conductor and another body at a different potential Electricity can be fatal even at low voltages and current The risk and severity for injury will depend on the duration of the contact and the voltage involved In addition e
56. ctivities of a laboratory must be reflected in the signage by contacting Facilities Management x2400 Department Emergency Information cards must be completed and posted in each laboratory indicating the hazards present the Laboratory Supervisor s contact information In the event of an emergency in the laboratory the occupants are expected to bring the emergency card to Security in order to facilitate proper coordination and response to the emergency The cards are available from EHS EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 6 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY en ee Ng feier 4 6 Laboratory Inspections EHS conducts periodic laboratory safety inspections The inspections are done in cooperation with Pls or their delegates in order to ensure compliance with all the relevant legislation internal procedures or guidelines and best practices Laboratory inspections provide a snapshot of laboratory safety and compliance A summary and a list of unsafe or unhealthy conditions identified during the inspection are sent to the PI Pls are required to sign the Receipt Acknowledgement form confirming receipt of the inspection findings and return it to EHS either by mail or electronic mail A copy of the Laboratory Safety Inspection Checklist is available on the EHS website 4 7 Hazard Assessments amp Standard Operating Procedures Standard operating procedure SOP development is required fo
57. cups rotors o Decontaminate the outside of the cups rotors before and after centrifugation e Do not open the centrifuge lid during or immediately after operation attempt to stop a spinning rotor by hand or with an object or interfere with the interlock safety device e Clean spills promptly e Prohibit the use of centrifuges in a BSC EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 57 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY neh E fe we 15 3 Autoclaves Autoclaves are used to effectively decontaminate biological waste by killing pathogens by means of superheated steam First time users must receive hands on training prior to using an autoclave a list of the individual s responsible for this training is posted near each autoclave This training must be documented by completing and forwarding the Training Attendance Compliance Record form to EHS Autoclaves must be loaded so that steam is able to penetrate into the innermost areas of autoclave bags containers or equipment Longer processing times are required for larger loads larger volumes of liquids and denser materials Effective operating parameters must be established whenever autoclaves are used to decontaminate biological waste The autoclave efficacy monitory program is overseen by EHS please contact the BSO Please refer to the document Safe Use of Autoclaves posted on the Biosafety webpage 15 3 1 General Guidelines e On
58. d the corridor which can cause chemical vapors to concentrate in the laboratory and escape into the hallways Keeping doors open between rooms will compromise the safety of the laboratory and surrounding areas Closing laboratory doors is required for safety and hazard control EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 8 of 81 EN a NIV ER SITE ENVIRONMENTAL MJ Co ncor d ld HEALTH AND SAFETY WW Y wm Ng feier SS WUE It is important not to cover or block the door windows Emergency and security personnel must be able to see inside the laboratory in order to assist individuals during emergency evacuations and or to assist security personnel in locating people in need of emergency assistance especially after normal working hours Laboratory exits must always be clear and unobstructed 5 2 Chemical Fume Hoods A chemical fume hood is an engineering control used to capture hazardous vapors and gases and eliminate the persons exposure to hazards The use of engineering controls to reduce exposure must be instituted in priority over the use of personal protective equipment 5 2 1 Howto Use the Fume Hood e Keep the sash closed when you are not working directly in front of the hood e Open the sash only when necessary during an experiment e Always keep the sash s opening at a normal operating position leaving enough room for hands while observing your experiment through the lowered sash The normal operating position
59. dents e And others including contractors service providers visitors or any persons involved with the acquisition handling storage removal or disposal of hazardous chemical products on University premises EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 2 of 81 2 UNIVERSIT ENVIRONMENTAL S Co ncor d l HEALTH AND SAFETY NE A E fe we 4 1 Legislation 4 1 1 Act Respecting Occupational Health and Safety L R Q c S 2 1 The objective of the Act is the elimination at the source of dangers to the health safety and physical well being of workers It defines the employer s obligation to protect the health and safety of employees such as 1 Ensure that the workplace is safe for employees to perform their duties 2 Inform employees of their health and safety representative s 3 Ensure that the health and safety of anyone in the workplace is not compromised by the use of hazardous materials or contaminants 4 Provide the necessary personal protective equipment free of charge 5 Identify and eliminate or control the risks which may affect the health or safety of employees Please also refer to the Act Respecting Industrial Accidents and Occupational Diseases A 3 001 available online 4 1 2 Regulation Respecting Occupational Health and Safety c S 2 1 r 19 01 The purpose of this regulation is to establish standards pertaining in particular to air quality temperature humidity heat stress lighting noise a
60. e If thermometers or other equipment containing mercury are to be discarded contact EHS at hazardouswaste concordia ca for a pickup 3 www concordia ca content dam concordia services safety docs EHS DOC 042 Mercury Guidelines pdf EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 28 of 81 2 UNIVERSIT ENVIRONMENTAL S Co ncor d l HEALTH AND SAFETY wWwYwg fe wer ii Hydrogen Fluoride HF Hydrogen fluoride HF or hydrofluoric acid is an extremely corrosive substance and is significantly more hazardous than any other acid HF is a contact poison contact may not be noticed until long after serious damage has been done HF can cause serious burns to the skin with significant complications due to the fluoride toxicity Deaths have been reported from concentrated hydrofluoric acid burns involving as little as 2 5 body surface area BSA an area roughly the size of the hand All laboratory users handling HF must e Follow safe work practices specified by the SOP or the Supervisor e Wear appropriate PPE e Have access to a working emergency shower eyewash station e Have access to calcium gluconate gel Calcium gluconate gel must be replaced before its expiration date Hydrogen Fluoride Safety Guidelines are available from the EHS website P 7 3 2 Carcinogens Mutagens Teratogens and Reproductive Toxins Carcinogens mutagens teratogens and reproductive toxins can cause serious health problems e g canc
61. e Acrylates Carbolic acid Cresote Cresols Phenol Ethylene oxide Propylene oxide Acetone cyanohydrin Ethylene cyanohydrin EHS DOC 001 v 1 Laboratory Safety Manual DRAFT 1 2 3 4 6 8 15 16 17 19 20 23 1 3 4 7 19 20 20 1 20 1 5 20 20 1 3 4 19 20 1 2 3 4 5 6 15 16 19 20 21 23 3 4 7 14 16 19 20 1 2 3 4 6 7 14 15 17 18 19 23 1 2 3 4 5 7 16 19 23 Page 74 of 81 ENVIRONMENTAL v Co ncor di ld HEALTH AND SAFETY UNIVERSITY Nitriles Acetonitrile 1 2 3 4 16 23 Adiponitrile E C ea NEC Halogens Chlorine 3 6 7 8 9 10 11 12 13 14 15 19 21 22 Fluorine Group 22_ Phosphorus Phosphorus Elemental 1 2 3 20 Back to section 7 4 2 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 75 of 81 2 UNIVERSIT V Concordia ne A E feier ENVIRONMENTAL HEALTH AND SAFETY Appendix III Peroxide forming chemicals and solvents Class III Chemicals that form explosive levels of peroxides without a concentration step e g evaporation distillation etc are listed below These chemicals can be a particular hazard since peroxides can form even without opening the containers Therefore only small amounts should be ordered and used as soon as possible If stabilizers are present in solution they can be kept for up to one year or up to the manufacturer s expiration date where appropriate With no stabilizer present they should not be kept for over three months after opening When possible
62. e Protection Association NIOSH National Institute for Occupational Health and Safety PI Principal Investigator PPE Personal Protective Equipment RSO Radiation Safety Officer SDS Safety Data Sheet SOP Standard or Safe Operating Procedure STM Soci t de Transport de Montr al TDG Transportation of Dangerous Goods VPS Vice President Services WHMIS Workplace Hazardous Materials Information System EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Pagei 2 UNIVERSIT ENVIRONMENTAL Ww Co ncor d l HEALTH AND SAFETY ZE A EA fe e Definitions Biohazardous Material Biohazardous materials are defined as materials of biological origin that are potentially harmful to humans animals plants or to the environment Biohazardous materials include but are not limited to Microorganisms such as viruses fungi parasites bacteria and their toxic metabolites Mammalian primary tissues blood and body fluids Materials that may contain the above mentioned agents e g cell cultures specimens from humans and animals environmental samples Certain proteins Certain nucleic acids siRNA miRNA DNA from pathogenic organisms oncogenes Genetically modified organisms GMO that may be hazardous to the environment if released Controlled Product Any product included in the classification established by regulation or meeting the criteria set out in the classification A controlled product could be included in one or mo
63. e and explosion hazard 5 reactivity data 6 toxicological properties health effects 7 preventive measures 8 first aid measures 9 preparation information No MSDS may be more than three years old Most suppliers have adopted a new format following the Globally Harmonized System GHS requirements Under GHS Safety Data Sheets SDSs contain 16 sections rather than 9 and meet all the WHMIS requirements For more details please refer to the next section concerning GHS For more information about WHMIS please refer to the following links e WHMIS Official National Site Health Canada e CSST Quebec EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 22 of 81 UNIVERSITE ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY NH DE A eee 7 2 WHMIS 2015 7 2 4 Summary The Globally Harmonized System of Classification and Labelling of Chemicals GHS was adopted by the UN Economic and Social Council ECOSOC in July 2003 The purpose of this system is to regroup all existing hazard communication systems on chemicals in order to develop a single globally harmonized system to address classification of chemicals according to their hazards and communicate the related information through labels and safety data sheets On February 11 2015 the Government of Canada published the Hazardous Products Regulations HPR SOR 2015 17 repealing at the same time the former Controlled Products Regulations SOR 2015 17 s 21
64. e easier on the skin e Cotton liners for sweaty hands too they put a barrier between the glove and the skin and also absorb some of the moisture which can also give a rash e Neo Pro gloves Neoprene chloroprene EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 63 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY ne gx E fe wer 16 3 Eye and Face Protection Wearing eye and face protection is necessary to protect against splashing chemicals biological materials and flying particles Eye protection in the form of glasses goggles or face shields is available and the choice will depend on the risk involved with the experiment the type and the amount of material being used The experiment s SOP should specify the necessary eye and face protection The following provides general information and precautions Safety glasses shall be worn at all times in the laboratory areas Regular prescription glasses with side shields may not provide sufficient protection Contact EHS for additional information or an evaluation Safety glasses are used to protect against flying particles Safety goggles fit tightly around the face and offer protection against chemical splashes and can better protect against dust and smaller particles When working with chemical vapours that can irritate eyes a non vented goggle with no padding is recommended Anti fog coatings are available on most models Specialized protective eyew
65. e physician with a description of the duties and the list of chemicals used in the laboratory It is also useful to provide the material safety data sheets MSDS and a copy of the chemical inventory If the physician determines that the work or workplace is a risk to the pregnancy the employee will be given a Preventive Withdrawal and Reassignment Certificate EHS Human Resources and the Supervisor must be notified of the preventive withdrawal or reassignment Students can be given an exemption certificate to present to their professor or Supervisor Pregnant employees students and Supervisors can contact EHS to discuss occupational health risks and possible accommodations in confidence Staff should contact Human Resources for questions regarding the Preventive Withdrawal and Reassignment Certificate and indemnities EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 17 of 81 EN NIV ER SITE ENVIRONMENTAL Y Co ncor d ld HEALTH AND SAFETY WW ow a E fe wer SS WUE 6 4 Transportation Shipping of Hazardous Materials 6 4 1 Within Buildings Hazardous products should be transported using a cart equipped with a lip or carried within a secondary container such as a chemical resistant bucket e Always use a sturdy cart with a low center of gravity and spill tray Carts with large wheels are best to navigate irregularities in floors and over the elevator door ledge e Use secondary containers to protect the primary container from
66. ean up and or decontamination procedures e Emergency procedures in the event of a leak or spill e Training requirements A SOP writing training is also available from EHS upon request EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 7 of 81 UNIVERSITE ENVIRONMENTAL wv Co ncor d l HEALTH AND SAFETY Y UNIVERSITY 4 8 Laboratory and Equipment Decommissioning PIs are responsible for their laboratory space and as such must contact EHS prior to leaving a Concordia University laboratory EHS will advise and help with the disposal of unwanted chemicals along with the safe decommissioning of the laboratory A certificate of equipment decommission must be filled out and a copy sent to the EHS office e Laboratories making use of open sources e g radioisotopes must provide a copy of their final wipe test to the Radiation Safety Officer RSO along with a signed copy of their decommissioning report Please refer to the Radiation Safety Manual for more details e Laboratories working with biological materials should notify the Biosafety Officer BSO prior to stopping operation in order to ensure that the laboratory has been decontaminated and that all biological materials have been secured or properly disposed of Please refer to the Biosafety Manual for more details e Laboratory equipment must also be properly decontaminated prior to their transfer donation or disposal in order to remove any potential risk of contami
67. ear is also necessary for working with lasers Consult the MSDS to choose the right type of protection in accordance with the CSA standard for Industrial Eye and Face Protectors CAN CSA Z94 3 16 3 1 Proper Fit Safety glasses should be individually assigned and fitted Ensure safety glasses fit properly Eye size bridge size and temple length all vary Wear safety glasses so that the temples fit comfortably over the ears The frame should be as close to the face as possible and adequately supported by the bridge of the nose 16 3 2 Care Clean safety glasses goggles daily Follow the manufacturer s instructions Avoid rough handling that can scratch lenses Replace scratched pitted broken bent or ill fitting glasses Damaged glasses interfere with vision and do not provide proper protection Store safety glasses in a clean dry place where they cannot fall or be stepped on Keep them in a case when they are not being worn 16 3 3 Face Shields A face shield must be used in combination with and worn over safety glasses or prescription glasses According to CAN CSA Z94 3 face shields are considered secondary protectors only and provide adequate eye protection only when worn with safety glasses or goggles Face shields must be worn in conditions such as laboratory operations using glassware that has a significant hazard of explosion or breakage When conducting experiments that may splash face shield shall be worn in combination w
68. ectious Substances k Transportation of Dangerous Goods Class 7 Radioactive Materials I Safe Handling of Nanomaterials m Laboratory Safety Awareness for non scientific staff More details on EHS training sessions training requirements and training schedule can be found on the EHS Safety Training webpage To be compliant with regulations EHS maintains training and compliance records Each year Supervisors will receive a detailed review of the training sessions attended by staff and students under their responsibility In addition EHS can provide training information to Supervisors upon request Also any laboratory specific training can be entered in this database provided the EHS FORM 032 is used and submitted to EHS see Appendix Template of Training Record EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 5 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY ne UN NE Up The Laboratory Supervisor must also ensure lab specific training that focuses on the hazards present in their laboratory and develop Standard or Safe Operating Procedures SOPs specific to their laboratory activities please refer to Section 4 7 The record of SOP presentation and or orientations can be entered in the training database for convenience of record keeping 4 4 EHS External Training Recognition The Concordia University s EHS office will recognize safety training and or certifications obtained from other institutio
69. email hazardouswaste concordia ca EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 44 of 81 n ENVIRONMENTAL KC oncor di ld HEALTH AND SAFETY en wg E feier Solvent glass bottles 4L and other re sealable chemical containers can be used for waste storage only if e they are in good conditions e their labels have been obliterated e the containers are clearly identified with a waste label Liquid chemical waste include mainly organic solvents acid and base solutions oils and aqueous solutions The following plastic containers should be used for their disposal e 4Lnarrow mouth e 10L e 20L Solid chemical waste includes powders silica sand celite or any other filtering media contaminated paper glassware gloves or any other solid materials that have been contaminated with chemicals The following plastic containers should be used for their disposal e 4Lwide mouth e 20L white pail If chemical waste is generated in large quantities that cannot be easily disposed of in our regular waste containers special drums for bulk chemical waste are required Please contact EHS at hazardouswaste concordia ca to request a drum e Size 210 L plastic or metal e Use liquids oil organic corrosive aqueous solids non corrosive chemicals and other contaminated materials 13 1 2 Expired Chemicals Most chemicals have expiry dates Expired chemicals in their original manufacturers bottles are accepted f
70. emical resistant bags All spill residue and spill clean up material should be placed in a high density polyethylene or polypropylene bag These bags should be made of strong construction e Leak proof e 4mmin thickness Personal protective equipment PPE At least e 2 pairs of chemical splash goggles e 2 pairs of disposable nitrile gloves e 2 pairs of heavy gauge long cuff nitrile Neoprene or butyl rubber gloves e 2Tychem coveralls L or XL e 2pairs chemical resistant shoe covers e 2 disposable masks N95 Universal hazard absorbent pads No gloves are totally chemical proof however some are more resistant to chemicals than others Latex gloves are not resistant to most laboratory chemicals and should not be in the spill kit High Capacity Chemically inert Absorbs aggressive chemicals as well as non aggressive compounds such as water Good for all chemicals e Acids e Bases e Flammable liquids e Formaldehyde e Organic peroxides Plastic clean up tools dust pan or scoop and brush etc For solid chemical spills Should be chemical resistant and non sparling non static A variety of polypropylene tools are available EHS chemical waste labels To properly identify spill waste Neutralizing and treatment materials only if strong acids bases are used Type and quantity are dependent on the laboratory s chemicals e Acid and or base neutralizer e 1 roll of pH paper Mercury sp
71. end the duly completed form to the EHS office at hazardouswaste 9 concordia ca 6 Hazardous waste pickups are generally done within 24 48h after reception of request 7 Request for special hazardous waste pickups emergency bulk quantities drums must be sent directly to the EHS office by e mail to hazardouswaste concordia ca 13 1 5 Guidelines e All persons generating hazardous chemical waste must attend the Hazardous Waste Disposal training and follow the guidelines e Always allow 10 20 free space in liquid hazardous waste containers to allow for solvent expansion Overfilled and or leaking containers cannot be accepted for transport e Waste containers must be provided with a means of second containment in case of spill e Do not mix halogenated with non halogenated organic waste Organic solvents bulked together in the same waste container must be compatible e Segregate all waste according to compatibility following similar criteria as for chemical storage see chart in chapter 7 4 2 e Al full containers should be placed in a designated waste area e Waste containers must not obstruct any exits e When accumulation exceeds the available storage limits within the laboratory area arrange for the transfer of the waste by contacting EHS 7 On the SGW campus waste is collected every Thursday EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 46 of 81 pu UNIVERSIT ENDE ENVIRONMENTAL Y Co ncor d ld HEALTH AND
72. ent 3 University Health amp Safety Policies Environmental Health and Safety EHS provides support to faculty and line management on matters of safety occupational health and environment It develops and oversees comprehensive health and safety programs encompassing all University activities and facilities EHS ensures that the University is in compliance with legislation and accepted standards of practice upholds the academic mission and supports the teaching research and service activities of the University Concordia University has developed the following institutional policies that relate to laboratory safety e Environmental Health amp Safety Policy VPS 40 e Policy on Working Outside The Hours of Operation or in Isolation VPS 6 e Policy on Safety Glasses and Eye Protection Practices VPS 41 e Policy on Injury Incident Reporting and Investigation VPS 42 e Policy on First Aid and Medical Emergency VPS 45 e Radiation Safety Policy VPS 46 e Policy for the Management of Hazardous Materials VPS 47 e Hazardous Materials Spill Response Policy VPS 48 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 1 of 81 UNIVERSITE ENVIRONMENTAL Co NCOrdia neam anp sarety ne NN fe ie e Laser Safety Policy VPS 51 e Biosafety Policy VPS 52 e Magnetic Field Safety Policy VPS 54 All Members of the University Community are responsible for reading and respecting the policies that apply to their specific work
73. er birth defects sterility and genetic mutations in workers and or their unborn children There may be no early warning signs of the harmful and possibly irreversible effects that may occur long after exposure Thus they are regarded as especially hazardous products New and Expectant Mothers are strongly encouraged to contact EHS as soon as possible especially when working with these chemicals e Carcinogens are identified by their ability to cause cancer in humans or animals Many occupational cancers have a long latency period meaning that cancer may develop 10 20 years or longer after exposure to the carcinogen e Mutagens can cause changes mutations in the genetic material DNA of cells which may result in disease or abnormalities in future generations In WHMIS mutagens are classified as very toxic if they are shown to affect cells of the reproductive system Mutagens are classified as toxic if studies show genetic changes only in cells e g skin or lung cells that are not part of the reproductive system e Teratogens and embryotoxins can cause birth defects abnormalities developmental delays or death in developing offspring in the absence of significant harmful effect on the mother e Reproductive toxins can cause sterility or reduced fertility in offspring or other adverse reproductive effects e g the mother s ability to produce milk 5 http www concordia ca content dam concordia services safety docs EHS DOC 008 HF
74. er is to be marked with a unique identification number the name of the responsible person and the date 3 A Radioactive Waste Disposal Form must be filled out 4 Acopy of the form must be provided to the RSO the original must be retained for the logbook 5 Contact the RSO to schedule a waste pickup 6 All radioactive waste is either decayed or removed by a licensed carrier For more details refer to the Radiation Safety Program webpage 13 3 3 General Guidelines e Radioactive waste must never be placed in non radioactive waste containers e All waste containers are to be kept closed and shielded at all times e All radioactive waste is collected by EHS only e Only one type of radioisotope per waste container 13 4 Sharps A sharp is any item having corners edges or projections capable of cutting or piercing the skin The following items whether contaminated with hazardous waste or not are considered sharps and must be disposed in puncture proof containers and managed as sharps waste e Needles and syringes e Scalpel and razor blades e Glass such as Pasteur pipettes e Any other items that are capable of puncturing Broken glassware is not considered a sharp unless it is contaminated with hazardous waste 13 4 1 Categories Disposals i Sharps e Sharps that have been in contact only with chemicals should be disposed of in 4L or 20L containers for solid waste refer to section 13 1 Chemical Waste Only sharps that h
75. ere are different types of fire and there are different types of fire extinguishers Some fire extinguishers contain chemicals that are ineffective in certain situations and cannot be used safely in these circumstances Extinguishers are classified by the type of fire suppressant they contain A few of the most common extinguisher types are listed in next page EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 12 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY Www gm ydq Table 5 3 3 2 Uses of Fire Extinguishers Suitable for class A fires only A water extinguisher must never be used on grease fires electrical fires or class D fires as the flames may spread Used for class B and C fires Carbon Dioxide CO3 CO extinguishers contain carbon dioxide a non flammable gas and are highly pressurized Water extinguishers APW extinguishers Suitable for a combination of class A B and C fires Dry chemical extinguishers come in a variety of types These are filled with foam or powder and pressurized with nitrogen Labs that have the potential for a combination of these classifications may have an ABC type extinguisher These are the most common types of fire extinguishers but there are many others to choose from Security will help select the correct type of extinguisher based on the classification and the extinguisher s compatibility with the work and materials in the laboratory In the event of a fire la
76. gen argon or helium may produce local oxygen deficient atmospheres which will result in asphyxiation Release may be caused by a leak a spill or simply during the process in which the gas is used Oxygen deficiency monitors shall be used whenever the risk of asphyxiation is present Table 7 7 2 1 Oxygen deficiency symptoms Oxygen content vol Effects and symptoms at atmospheric pressure Diminution of physical and intellectual performance without person s knowledge Possibility of fainting after a short period without prior warning Fainting within a few minutes resuscitation possible if carried out immediately Fainting almost immediate death ensues brain damage if rescued 7 7 3 Fire Hazards from Oxygen Enriched Atmosphere If the atmosphere is enriched with oxygen the potential likelihood and intensity of fire are increased Many materials which are not usually combustible in air will burn fiercely in an oxygen enriched atmosphere The required energy to ignite these materials will be reduced the higher the oxygen concentration in the air the lower ignition energy required These materials can be ignited with a level of energy that would not be considered sufficient in normal atmospheric air Some materials may auto ignite in oxygen rich atmospheres 7 7 4 Liquid Oxygen Condensation Liquid nitrogen and helium are cold enough to condense oxygen from the air leading to a risk of combustion Vessels should be insulated to
77. guidelines pdf EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 29 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY a ee Np 7 3 3 Sensitizers Sensitizers are materials that can cause severe skin and or respiratory responses in a worker after exposure to a very small amount of the material Sensitization develops over time When a worker is first exposed to a sensitizer there may be no obvious reaction However future exposures can lead to increasingly severe reactions in sensitized workers Not all exposed workers will react to sensitizing materials Some workers will never become sensitized e Skin sensitization skin sensitizers can cause an allergic reaction with redness rash itching swelling or blisters at the point of contact or elsewhere in the body e Respiratory sensitization respiratory sensitizers can at first cause symptoms similar to a cold or mild hay fever However eventually severe asthmatic symptoms can develop in sensitized workers including wheezing chest tightness shortness of breath difficulty breathing and or coughing A severe asthmatic attack can cause death 7 3 4 Working Safely with Chemicals In order to work safely with toxic products one must e Consult the Material Safety Data Sheet MSDS for information about the hazards and the necessary precautions for handling the material being used e Understand all of the hazards associated with the material incl
78. h a flash point above 38 C Combustible liquids are subdivided as follows Table 7 4 3 2 Combustible Liquids Classification Combustible Liquid Class Definition Examples Liquids with flash points at or E EEN above 38 C and below 60 C Liquids with flash points at or IIA above 60 C and below 93 C Ethanolamine DMSO Aniline m SE MAR ashiipelnts above Ethylene glycol Benzyl alcohol The National Fire Code of Canada sets limits on the use and storage of flammable and combustible liquids It mentions that the quantity of dangerous goods stored in a research laboratory must be restricted to the minimum amount required for normal operation or to 300L of flammable and combustible liquids including a maximum limit of 5OL for flammable liquids class Any quantities of flammable and combustible liquids exceeding those limits must be stored into a flammable storage cabinet while respecting the storage limits of the particular flammable storage cabinet used Any amounts of flammable or combustible liquids exceeding this amount must be stored outside the laboratory in an approved flammable storage area Furthermore the National Fire Code of Canada also limits the total amount of flammable liquids located in the basement of a building to 5L i Flammable Storage Cabinet Flammable Cabinets must meet the construction specifications of the National Fire Protection Association NFPA Flammable and Combustible Liquids Code
79. he drain e DO NOT mix solid or liquid hazardous waste with the regular garbage EHS shall not pick up or handle any hazardous substances that have not been properly identified including unknowns packaged and labelled with the University s waste label Should the laboratory not be able to identify their waste an analysis will be performed at the laboratory s expense 13 1 Chemical Waste Chemical waste is mainly generated as the chemical by products of laboratory work as well as expired chemicals This includes solids liquids or gases containing or contaminated with any of the following e flammable and combustible solvents e g acetone alcohols acetonitrile oils e oxidizers nitrates perchlorates permanganates peroxides e leachate toxic materials e g heavy metals e corrosives e g hydrochloric acid potassium hydroxide pellets e reactives such as oxidizers cyanides sulphides explosives unstable materials and water reactive materials e g sodium metal benzoyl peroxide e toxic materials including mutagenic carcinogenic acute or chronic toxicity materials e g chloroform ethidium bromide e non returnable gas cylinders 13 1 1 Containers for Chemical Waste Collect substances by using the appropriately labeled University standard waste containers The containers and labels are provided e by the Chemistry Central Store SP 132 02 Loyola Campus or e by EHS Loyola and SGW campuses upon request
80. health hazard to persons in the immediate vicinity or Poses a significant risk of environmental damage A spill is classified as an emergency spill due to the properties of the hazardous materials toxicity volatility flammability explosiveness corrosiveness etc and or the circumstances of the release quantity location space considerations availability of ventilation heat and ignition sources etc EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page ii ke 2 UNIVERSIT ENVIRONMENTAL S Co ncor d l HEALTH AND SAFETY en ee wg feier Hazardous Material As per Section 1 Paragraph 21 of the Quebec Environment Quality Act a hazardous material is a material which by reason of its properties is a hazard to health or to the environment and which within the meaning of a regulation under this Act is explosive gaseous flammable poisonous radioactive corrosive oxidizing or leachable or is designated as a hazardous material and any object classed by regulation as a hazardous material Examples of hazardous materials include but are not limited to Flammable solvents e g methanol ethanol acetone hexane toluene benzene acetonitrile diethyl ether mineral spirits Chlorinated halogenated solvents e g chloroform dichloromethane or carbon tetrachloride Acids e g hydrochloric acid sulfuric acid nitric acid Caustics e g sodium hydroxide ammonium hydroxide Fuels e g gasoline d
81. hers cccsscccceesseceseessccesesssesesenseeeceesseeecessesesesaeeecesseeeseeaeseseesaeees 17 6 4 Transportation Shipping of Hazardous Moteriogls eese sesenta 18 6 4 1 HDI cT 18 6 4 2 By Ground Vehicle rosisvecsiteredareeis 18 6 4 3 By Plane Air Shipments cccscccccccccssssesseececcccesesssneeeeeceeeseeseeeeeeeeeeeeeeeaaeeeeceseseeseeaeeeeeeeeeeeeenaea 19 EE ea iiaii 19 7 1 Workplace Hazardous Materials Information System WHMIS 1988 19 7 1 1 Product Classification TEE DIET TETTE TITEL 20 7 1 2 ChemicalEabels sine Ramin cla nu AE ala Due Ee Deet ee en 21 7 1 3 Material Safety Data Sheet MaDS inserer 22 7 2 WHMIS 2015 is E 23 7 2 1 SUMMARY TET TERT EET 23 7 2 2 WHMIS 2015 Classification sise 23 7 2 3 Supplier Label Requlremiehts cos eo ete rone R tex odes vtae eroe o eerte Iren o ee deed e peas Edo 24 7 2 4 SEKR de EE 26 7 2 5 Safety Data Sheet KREE 27 7 3 Working with Hazardous Chemicals res 28 7 3 1 Very Toxic and Toxic Matertals ss 28 7 3 2 Carcinogens Mutagens Teratogens and Reproductive TOXINS 4 29 7 3 3 SENSITIZNS reste 30 7 3 4 Working Safely with Chemicals sisi 30 7 4 EH Eed Sect heen vats Sea dd EE MM DEM MM EIE 31 7 4 1 AAEE EE E E E A E E 31 7 4 2 Compatibility ersan D NEE 31 7 4 3 Storage
82. iesel biodiesel A Paints e g latex acrylic oil based dyes stains varsol and paint thinner Oils greases lubricants and antifreeze Mercury lead arsenic and other heavy metals Batteries lead acid lithium alkaline Laboratory reagents solids liquids and gases Polychlorinated biphenyls PCBs Radioactive materials and waste Biohazardous material see definition and waste Hazardous Waste A Hazardous Product that is intended for disposal or is sold for recycling or recovery Hazardous Products Act R S C 1985 c H 3 Incidental Spill or Minor Spill A release of hazardous material which does not Pose a significant safety or health hazard to persons in the immediate vicinity or to the person cleaning it up Pose a significant hazard to the environment and Have the potential to become an emergency within a short time frame Incidental spills are limited in quantity exposure potential human and environmental and toxicity therefore it represents a minor safety or health hazard to persons in the immediate work area or to the person assigned to clean it up MSDS or SDS Material Safety Data Sheet or Safety Data Sheet an information sheet detailing technical and hazard evaluation information on a hazardous material R Spill definitions are in accordance with the Occupational Safety and Health Administration OSHA of the United States Department of Labor More details can be obt
83. ill kit optional Only if possibility of mercury spill in laboratory A copy of all applicable chemical spill procedures or SOP SS UNIVERSITE ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY ne ee ee Typical Laboratory Biological Biohazardous Spill Kit Items Purpose Details Autoclave bags For collecting biologically contaminated materials during the cleanup Personal protective equipment PPE Latex vinyl or nitrile gloves should be available in multiple sizes At least Disposable N95 masks protect from direct splash and indirect e 2 pairs of chemical splash goggles accidental transfer via hands contact with infectious material or toxins e 2 pairs of disposable gloves during spill cleanup If fit tested N95 masks also provide protection e 2 disposable gowns or lab coats size from aerosols L or XL e 2 pairs chemical resistant shoe covers e 2 disposable masks N95 Absorbent materials Absorbent materials can be e Paper towels or absorbent pads e High absorbency paper towels such as Wypalls e Micro encapsulation absorbent e g BioSorb SafeGuard Absorbent Safetec EZ Cleans Kit etc Plastic clean up tools for example e Polypropylene plastic can be autoclaved e Polypropylene brush and dustpan or e For collecting contaminated materials such as broken glass sharps Scoop e Tweezers or forceps Effective concentrated chemical e Consult your SOP to find the proper pr
84. ing up or working in close proximity to a working Bunsen burner EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 59 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY en ee wq gp e Avoid wearing synthetic clothing e g polyester e Inspect hose for cracks holes pinched points or any other defect and ensure that the hose fits securely on the gas valve and the Bunsen burner e Replace all hoses found to have a defect before using Rubber tubing of 3 8 diameter is usually recommended e Notify others in the laboratory that burner will be in use e Utilize a sparker lighter with extended nozzle to ignite the Bunsen burner Never use a match or pocket size lighter to ignite burner e Adjust the flame by turning the collar to regulate air flow and produce an appropriate flame for the experiment typically a medium blue flame e Donotleave open flames unattended and never leave laboratory while burner is on e Shut off gas when its use is complete e Allow the burner to cool before handling The use of Bunsen burners inside of a biological safety cabinet BSC is prohibited because it e Disrupts airflow compromising the protection of the worker and the product e Causes excessive heat build up within the cabinet e May damage the HEPA filter or melt the adhesive holding the filter together compromising the cabinet s integrity e Presents a potential fire or explosion hazard within the cabinet
85. internal volumes above the total number of lecture bottle cylinders shall be limited to 25 per Laboratory Work Area Furthermore there are no limits set for storage of non flammable inert gases e g argon nitrogen 6 cu ft internal cylinder 6 cu ft internal 0 3 cu ft internal volume cylinder volume cylinder volume 7 6 6 Special Ventilation Requirements i Toxic Gases This section shall not apply to gases that have a health rating of 3 as rated in NFPA 704 if they are rated as such by virtue of it being a cryogen with no other health hazards Lecture bottle sized cylinders of the following gases located in laboratory units shall be kept in a continuously mechanically ventilated enclosure e All gases that have health hazard rating of 3 or 4 e All gases that have a health hazard rating of 2 without physiological warning properties e Pyrophoric gases e g silane EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 37 of 81 UNIVERSITE ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY WW w HS E fe we Cylinders of all gases that are greater than lecture bottle size and have health hazard ratings of 3 or 4 and cylinders of gases that have a health hazard rating of 2 without physiological warning properties that are located in laboratory units shall meet both the following conditions e Storage in approved continuously mechanically ventilated gas cabinets e Compliance with NFPA 45 and NFPA 55 Cylinders of pyro
86. ion of injuries when conducting research working teaching and undertaking other activities involving hazardous materials at the University These requirements are based on federal and provincial legislations Concordia s internal policies and existing best practices Laboratory Supervisors are required to use this manual as a tool to teach safe work practices and procedures to staff and students for whom they are responsible 2 Scope The Laboratory Safety Manual applies to everyone engaged in work involving hazardous materials on University property including laboratories studios and workshops The manual serves to establish minimum requirements for establishing a safe and healthy work environment but must be supplemented with laboratory and task specific information This manual applies to all Members of the University Community e Employees a person who under a contract of lease of personal service or contract of apprenticeship even without remuneration carries out work for the University e Contract Workers an employee working for another employer but carrying out work on University property e Students an individual who has contracted with and is registered at the University for an academic purpose e Interns students performing an internship with or without remuneration for a company or an institution e Visitors Volunteers an individual who is present on University Property who is neither an employee nor a registered stud
87. ional Fire Protection Agency Codes and Standards NFPA 45 National Fire Protection Agency Codes and Standards NFPA 55 National Fire Protection Agency Codes and Standards NFPA 58 National Fire Protection Agency Codes and Standards NFPA 704 National Fire Protection Agency Codes and Standards NRC Prudent practices for handling hazardous chemicals in laboratories National Academy Press 1981 Occupational Safety and Health Administration OSHA www osha gov Purchase R The Laboratory Environment The Royal Society of Chemistry 1994 Regulation Respecting Information on Controlled Products Quebec chapter S 2 1 r 8 Regulation Respecting Occupational Health and Safety Quebec c S 2 1 r 19 1 Regulation Respecting Safety in Public Buildings Quebec R Q S 3 r 4 Saunders G T Laboratory Fume Hoods A user s manual John Wiley amp Sons Inc 1993 Shematek G Wood W La S curit au Laboratoire Directives de la SCTL 4e Edition 1996 Stricoff R S Walters D B Laboratory Health and Safety Handbook A Wiley Interscience publication 1990 Transport Canada Website www tc gc ca Young J A Improving Safety in the Chemical Laboratory Wiley Inter Science 1987 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 71 of 81 ge See hp ENVIRONMENTAL v Co ncor di ld HEALTH AND SAFETY Uae ES ee Appendix I Template of Training Record TEMPLATE OF TRAINING RECORD UNIVER v Concordia Me TRAINING ATTENDA
88. is a specific height typically in the 35 to 50 cm 14 to 20 inches range It should be indicated on the fume hood as a reminder e Always open the sash slowly a sudden opening can cause air turbulence and push contaminants into the main laboratory e Place all equipment at least 15 cm 6 inches inside the fume hood and ensure that experimental apparatus do not obstruct baffles or vents within the fume hood e All large equipment should be elevated 5 cm 2 inches to diminish the effects of eddy currents that may reduce the efficacy of the hood e Heat generating equipment should be placed at the back of the hood e Do not work with flammable materials in a hood that contains hot plates open flames or equipment that may generate electrical sparks e Use of the fume hood for storage should be minimized A one or two day supply of materials should be considered the maximum quantity Fume hoods have limitations and additional PPE may be necessary in certain experiments 5 2 2 Face Velocity Each fume hood is equipped with a display panel or control box Under normal operating conditions the display panel should read between 85 100 ft min and show a green LED light This value represents the face velocity the speed of air entering the fume hood through the sash opening and measured in the plane of the sash Higher or lower face velocities will occur while the sash is being opened or closed A yellow LED will be illuminated while the
89. items soiled with animal Pasteur pipettes slides tissues Animal carcasses must be placed in bags that are then stored in the designated biohazard freezer All the data concerning this waste should also be recorded at the same time in the logbook located near EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 47 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY ne gm Np ii 13 2 2 Decontamination Prior to Disposal Autoclaves Autoclaves are ideal for decontaminating biohazardous waste prior to disposal with other refuse Follow the manufacturer s procedures before autoclaving any biohazardous waste Once autoclaved material such as culture dishes can be disposed of with the regular garbage However the autoclave bag and its content must be placed inside a regular black tied up garbage bag Never put an autoclaved bag or its content directly in the regular garbage Chemical Decontamination Cell culture waste can be destroyed by mixing with 1 10 vol of bleach and letting it sit in a capped container for 24 48 hours at room temperature The waste may then be dumped down the sink in a chemical hood with fresh tap water running for a few minutes after dumping the bleached waste Chemical disinfectants are used for the decontamination of surfaces and equipment that cannot be autoclaved such as specimen containers spill clean up material and certain glassware The choice of disinfectant
90. ith safety goggles Face shield must be used when working with cryogenics and UV sources EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 64 of 81 2 UNIVERSIT ENVIRONMENTAL S Co ncor d l HEALTH AND SAFETY neh E fe we 16 3 4 Contact Lenses in the Laboratory According to the VPS 41 policy on personal protective equipment contact lenses can be worn with the appropriate safety glasses except where chemicals are used or when working with lasers The wearing of contact lenses does not provide protection against chemical hazards and in the event of chemical exposure it might create one of the following situations e Dusts or chemicals can be trapped behind the lens and cause irritation or damage to the cornea or both e Gases and vapours can cause irritation and excessive eye watering e Chemical splash may be more injurious when contact lenses are worn This increased risk is related to the removal of the lenses If removal is delayed first aid treatment may not be as effective and in turn the eye s exposure time to the chemical may be increased If contact lenses are to be worn in a laboratory a written authorization must be provided by the respective supervisor Contact lenses wearers should be aware of the following information e Inserting or removing contact lenses is not permitted in a laboratory e For additional safety it is recommended to have a pair of corrective glasses available e Wear the required and a
91. kplace to identify the hazards and assess the risks of using the chemical product The following figure maps the similarities and differences between the WHMIS 1988 MSDS and WHMIS 2015 GHS format SDS The section numbers are highlighted in yellow while new sections are highlighted in red It has to be noticed that under WHMIS 2015 information in sections 12 to 15 are not required to be displayed Suppliers must still provide SDSs in English and French in Canada However under WHMIS 2015 the 3 year SDS review period requirement has been removed as the SDS must be accurate at each time of sale or importation Figure 7 2 5 1 WHMIS 1998 and WHMIS 2015 SDS Comparison WHMIS MSDS 9 sections GHS SDS 16 sections Product information 5 Identification MM Hazard s identification SS Hazardous ingredients gt Composition information on ingredients 3 First aid measures First aid measures Fire or explosion hazards Fire fighting measures Accidental release measures Handling and storage M Preventive measures Exposure control personal protection ES Physical data Physical and chemical properties 9 Reactivity data Stability and reactivity Toxicological data Toxicological information Ecological information Disposal considerations Sees Transport information binas uem ee appear but section Preparation information
92. lamine Triethylamine Triethylenetetramine Allyl chloride Carbon tetrachloride Chlorobenzene Chloroform Methylene chloride Monochlorodifluoromethane 1 2 4 Trichlorobenzene 1 1 1 Trichloroethane Trichloroethylene Trichlorofluoromethane 1 4 Butanediol Butanol iso n sec tert Diethylene glycol Ethyl alcohol Ethyl butanol Ethylene glycol Furfuryl alcohol Isoamyl alcohol Methyl alcohol Methylamyl alcohol Propylene glycol EHS DOC 001 v 1 Laboratory Safety Manual DRAFT 2 3 4 5 6 7 8 10 13 14 16 17 18 19 21 22 23 1 3 4 7 14 16 17 18 19 22 1 2 6 7 8 13 14 15 16 17 18 20 23 1 2 5 7 8 13 14 15 16 17 18 23 1 3 4 11 14 17 1 7 14 16 20 23 Page 73 of 81 m WV Concordia ENVIRONMENTAL HEALTH AND SAFETY Aldehydes Acetaldehyde Ketones Saturated Hydrocarbons Aromatic Hydrocarbons Olefins Petroleum Oils Esters Monomers Polymerizable Esters Phenols Alkylene Oxides Cyanohydrins Acrolein Butyraldehyde Crotonaldehyde Formaldehyde Furfural Paraformaldehyde Propionaldehyde Acetone Acetophenone Diisobutyl ketone Methyl ethyl ketone Butane Cyclohexane Ethane Heptane Paraffins Paraffin wax Pentane Petroleum ether Benzene Cumene Ethyl benzene Naphtha Naphthalene Toluene Xylene Butylene 1 Decene 1 Dodecene Ethylene Turpentine Gasoline Mineral Oil Amyl acetate Butyl acetates Castor oil Dimethyl sulfate Ethyl acetate Acrylic acid Acrylonitrile Butadien
93. lave Shield or wrap open glassware e Do not seal the bag tightly before autoclaving the steam needs to enter into the bag and be in contact with the waste for proper decontamination e Seals on containers of liquids should be loose to allow for vapour expansion during heating preventing an explosion Never autoclave any flammable or volatile liquids because they could explode EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 58 of 81 UNIVERSITE ENVIRONMENTAL A Co ncor d l HEALTH AND SAFETY NY UNIVERSITY 15 3 3 Autoclave Unloading e Use caution when opening the autoclave door Allow for the superheated steam to cool and pressure to return to normal level before attempting to open the autoclave door e Handle pressurized containers carefully The superheated liquids boil over from closed containers e Broken glass in the autoclave must be cleaned up using tongs forceps or other instruments to recover broken pieces Do not use bare or gloved hands to pick up broken glassware e Allow the autoclave to cool before cleaning e Autoclaved waste shall be placed in a regular black garbage bag and sealed prior to collection by Custodial Services e Any item bearing a biohazard symbol such as red orange yellow biohazardous waste bags will not be picked up 15 4 Sonicators Mixers and Grinders Mixing equipment can pose a number of hazards such as dispersing chemicals generating hazardous aerosols and creating physic
94. lectricity is a potential ignition source which could lead to fire Below are electrical safety precautions applicable in a laboratory environment e Use only approved certified electrical equipment CSA or ULC certified equipment e All electrical equipment must have grounded three prong plugs Never remove the ground pin of a three pronged plug e Electrical outlets must not be overloaded multi outlet adapters should not be used power bars must not be chained e Regularly inspect electrical cords and equipment Tag and remove from service any defective equipment until repairs are completed e Damaged equipment must be reported to the Supervisor or responsible person e Electrical cords must be in good condition frayed or defective cords must be repaired or replaced and reported to the Laboratory Supervisor or responsible person EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 52 of 81 UNIVERSIT VERRE zz ENVIRONMENTAL MJ Co ncordia var an SAFETY na wg oe e When extension cords are used the wire gauge shall be equal to or larger than the size of the cord being supplied by them e When removing electrical cords from outlets grasp and pull from the plug not by the cord All power tools and appliances must be free of cracks fraying heat and insulation damage e Position electrical equipment so as to minimize the possibility of contact with water or chemicals Be aware that condensation could enter the motor
95. ls than others Universal hazard absorbent pads Decontamination solution and scrub brush High Capacity and chemically inert Absorbs aggressive chemicals as well as non aggressive compounds such as water General cleaner detergents such as RadCon spray A scouring powder scrub brush can also be used for a more aggressive decontamination Forceps or tongs For safe handling of any sharps Radioactive waste labels Label Radiation Danger Rayonnement with radiation logo to properly identify radioactive spill waste Wipe testing kit Filter papers and liquid scintillation vials for wipe test A copy of all applicable radioactive spill procedures or SOP EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 81 of 81
96. ly sprinklered 7 10 Acetylene Flashback arresters must be installed on the pressure regulators on both the acetylene cylinder and the oxygen cylinder with check valves for every 15 ft of hose used Acetylene is an extremely flammable gas It is different from other flammable gases because it is also unstable Under certain conditions it can decompose explosively into its constituent elements carbon and hydrogen A flashback can occur if there is a flammable mixture of fuel gas and oxygen in the hoses when the torch is lit If it is not stopped the flame will ignite the mixture and will travel backwards from the torch along the hoses through the regulator and into the cylinder A flashback can trigger decomposition of the acetylene in the fuel hose in the regulator and in the cylinder itself EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 41 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY JA LETS EM 8 Nanomaterials amp Nanoparticles Separate Nanomaterials Guidelines are available on line from the EHS website Engineered nanoparticles are defined as materials purposefully produced with at least one dimension in the 1 100 nm range Nanomaterials safety is in an area where there are a great many unknowns and little to no regulation Hence nanomaterials have to be handled in such a way that the known hazards are mitigated accordingly and unknown toxic effects are reduced by exposure protection means
97. ly trained personnel are authorized to operate the autoclaves The training is usually provided by designated departmental staff and must be recorded EHS FORM 032 may be used to record the training e Autoclave sterility testing should be conducted on a regular basis to monitor efficacy Contact EHS for more information e Do not put sharp or pointy objects into an autoclave bag Place them in an appropriate rigid sharps disposal container e Laboratory waste and lab ware to be sterilized should not be mixed together during an autoclave cycle They require different decontamination times e Proper personal protective equipment such as heat resistant gloves safety glasses and a lab coat must be worn when operating an autoclave e Autoclaves should be placed under preventive maintenance contracts to ensure they are operating properly e Thermometers cannot be autoclaved 15 3 2 Autoclave Loading e Do not overload the autoclave since the steam will not be efficiently distributed Longer sterilization times will be required e Use caution when handling a waste bag e When autoclaving bags lift bags from the bottom to load them into the chamber Use a secondary container tray to catch any potential leakage e Do not overfill an autoclave bag The steam and heat will not go through a densely packed bag therefore only the outer contents of the bag will be treated e Inspect glassware for cracks failures etc before putting them in the autoc
98. n must be given by the Department or Faculty The Laboratory Supervisor must evaluate the risks to visitors prior to the visit especially for visitors such as children and immune suppressed individuals This evaluation must be submitted to EHS For academic visitors please refer to Concordia University on Academic Visitors VPRGS 10 6 3 Pregnant Students Staff New Mothers Hazardous or radioactive products other physical hazards and ergonomic conditions such as lifting or standing may be harmful to a pregnant employee or new mother These must be taken into consideration Thus a staff member working with or near hazardous materials should inform EHS as soon as possible after receiving confirmation of pregnancy This information must be disclosed in order to have adjustments made to the work and the work conditions Early disclosure is preferable as some products or work conditions may affect the pregnancy EHS will conduct a specific risk assessment supplementing any pre existing one Pregnant staff and students are also encouraged to discuss these issues with their immediate Supervisor Supervisors can then take the necessary precautions to remove the hazard or modify the work to accommodate the pregnancy If there are concerns that the work or workplace may constitute a hazard to the pregnancy the employee student is strongly encouraged to consult a physician The employee student should bring the EHS assessment which will provide th
99. nation to external users Also all energies must be removed from the equipment For more information or assistance about laboratory or equipment decommissioning please contact EHS at the extension 4877 or at ehs concordia ca 5 Laboratory Design 5 1 Laboratory Ventilation 5 1 1 General Laboratory Ventilation The laboratories have a dedicated general laboratory ventilation system separate from the ventilation of offices and public spaces 100 of the air extracted from the laboratories is exhausted from the building In addition a laboratory s general ventilation system is balanced to maintain laboratories under negative pressure relative to adjacent areas in order to prevent potential contamination of adjacent areas A laboratory s general ventilation is not designed to control or exhaust volatile or toxic chemicals All volatile and or toxic chemicals must be handled in a chemical fume hood under local ventilation or using another appropriate containment enclosure Avoid handling these hazardous materials on an open laboratory bench 5 1 2 Laboratory Doors To prevent contaminants from leaking into public areas the ventilation system is designed to maintain the laboratories at negative pressure the air flows from the corridor into the laboratories and is then exhausted outside This design can only work efficiently when the laboratory doors are kept closed An open laboratory door alters the air balance between the laboratory an
100. nd other contaminants sanitary facilities ventilation hygiene sanitation and cleanliness in establishments area conditions storage and handling of dangerous substances machine and tool safety certain high risk tasks individual protective equipment and the transportation of workers and to ensure the quality of the work environment to safeguard the health of workers their safety and physical well being 4 1 3 The Criminal Code R S C 1985 c C 46 Bill C 45 was adopted on March 31 2004 and amended the Canadian Criminal Code to include a legal duty regarding health and safety under Section 217 1 of the Criminal Code 217 1 Everyone who undertakes or has the authority to direct how another person does work or performs a task is under a legal duty to take reasonable steps to prevent bodily harm to that person or any other person arising from that work or task The law includes legal duties for workplace health and safety and imposes serious penalties for violations that result in injuries or death It also establishes rules for attributing criminal liability to organizations and corporations for the actions of their representatives It also creates a legal duty for all persons directing work to take reasonable steps to ensure the safety of workers and the public If these duties are carelessly disregarded and bodily harm or death results an organization and or individual could be charged with criminal negligence For more info
101. nd personal protection Employers are responsible to ensure that everyone has been appropriately trained At Concordia EHS regularly offers WHMIS 1988 training which is mandatory for all students staff and faculty members working with hazardous materials EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 19 of 81 UNIVERSITE Concordia ee MN feier ENVIRONMENTAL HEALTH AND SAFETY 7 1 1 Product Classification Table 7 1 1 WHMIS Classification of GE a Products A Compressed gases B Flammable and combustible materials B1 Flammable gases B2 Flammable liquids B3 Combustible liquids B4 Flammable solids B5 Flammable aerosols B6 Reactive flammable materials C Oxidizing materials D1 Materials causing immediate and serious toxic effects D2 Materials causing other toxic effects D3 Biohazardous infectious materials E Corrosive materials F Dangerously reactive materials EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Products held under pressure Products that will burn or catch on fire easily Products that can cause or promote combustion of another material whether or not they are themselves combustible or products that are organic peroxides Products that can rapidly cause harmful health effects including death Products whose health effects generally appear over time following one or several exposures Living organisms or their toxins that can cause disease in people or animals
102. ng the wrist when picking up or ejecting tips e Use electronic pipettes for highly repetitive tasks that require prolonged pipetting e When working in a biosafety cabinet or on the laboratory bench position materials as close as possible to avoid extended reach e Microtome amp cryostat work lower the workstation to keep arms closer to the body apply padding to the front edge of work surfaces to eliminate sharp edges that may prevent adequate blood flow to the hands e Use anti fatigue mats for any work that requires standing for extended periods of time e Take frequent mini breaks these breaks should be used to change position and perform stretching exercises For an office environment or working with computers refer to the EHS Ergonomic Program to set up your office or computer work station Laboratory users should also consult the Laboratory Ergonomics poster EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 55 of 81 UNIVERSIT ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY en ee wg fe we 14 5 Noise In a work environment prolonged or repeated exposure to different noise levels can affect the efficiency with which a task is performed and lead to short and long term hearing loss Noise can often interfere with verbal communications between people and can be distracting to tasks that need a certain level of analytical concentration How we perceive sound depends on the frequency or pitch of the sound We hea
103. ngestion of hazardous products can result from hand to mouth contact consuming contaminated food drink or smoking cigarettes that have come into contact with hazardous products or unclean hands sometimes workplace hazardous products are accidentally swallowed Injection Hazardous products can enter the body via skin punctures or injection by needles or sharp objects contaminated with hazardous materials 6 2 Laboratory Conduct 6 2 1 General Safe Laboratory Practices The contamination of food beverages or smoking material is a potentially important route of exposure to toxic chemicals or biological agents through ingestion Consequently these basic safety rules must be followed by everyone working in or visiting a laboratory WASH HANDS even if gloves are worn Hand washing offers basic protection against inadvertent exposure to toxic chemicals or biological agents o Always wash hands before leaving the lab o Always wash hands after removing gloves o Always wash hands before eating drinking smoking or using the restroom o Wash hands periodically throughout the day CONFINE LONG HAIR LOOSE CLOTHING HEAD COVERING or HEAD SCARF when in the laboratory to keep them from catching fire dipping into chemicals or becoming entangled in moving machinery For similar reasons jewelry should not be worn in the laboratory Remove laboratory coats and gloves before leaving the laboratory to prevent spreading contamination to other areas DON
104. ns if the following criteria are met 1 The training was obtained from a recognized Canadian institution company 2 The course content is equivalent to that given by the Concordia University EHS training program 3 Thetraining was taken less than 3 years ago 4 The requester provides EHS with proof of successful completion of the training e g training certificate or written confirmation However if the individual is unable to provide a proof they should provide EHS with the following information 1 The name of the institution company where the training was obtained 2 His her former student employee ID 3 Thename of the department or person who provided the training Given that each request is evaluated on an individual basis and will take time to be analyzed it is the individual s duty to be aware of the training s required to perform their daily duties and to contact EHS to request validation for any previously completed trainings prior to starting their experiments EHS reserves the right to validate or refuse to recognize the training taken and individuals might be required to take the corresponding Concordia EHS training quiz for validation Any external safety training recognized by EHS is valid for a period of 3 years from the date it was originally taken 4 5 Laboratory Signage Warning signs have been posted outside each laboratory to indicate the type of hazard present within the lab Any changes in the status or a
105. o Concordia University VPS 41 16 1 Laboratory Clothing Lab coats are required in all laboratories These are available in various designs and materials and the choice should depend on the type of work being done and the hazards involved The following recommendations shall be respected e Lab coats shall be worn and closed at all times in the laboratory areas e Lab coats must not be worn in the lunchroom cafeteria public areas or anywhere other than in the laboratory to prevent contamination of non laboratory areas caused by possible absorption and accumulation of chemicals in the material e Long sleeved and long legged clothing should be worn beneath the lab coat to protect the skin in case of a spill Shorts Capri pants and skirts should not be worn in a laboratory e For best protection a lab coat should be knee length and have long sleeves to the wrist e Contaminated lab coats should not be washed at home with other laundry A cleaning service is provided by certain departments e Lab coats should be provided and worn by all visitors entering a laboratory Shoes must be worn at all times sandals high heel shoes flip flops canvas toed shoes crocs as well as open toed and open backed shoes should be avoided due to the danger of spillage of corrosive or irritating chemicals and broken glass EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 61 of 81 KC ded dede bie ENVIRONMENTAL Oncor di ld HEALTH AND SAFETY Uae
106. ocedure disinfectant e Dilute immediately before use e g if chlorine bleach is appropriate dilute household bleach 5 sodium hypochlorite to 1 10 e Replace yearly to ensure efficacy Sharps container A copy of all applicable biological spill procedures or SOP EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 80 of 81 UNIVERSITE V Concordia ne ee D SS GUT ENVIRONMENTAL HEALTH AND SAFETY Typical Laboratory Nuclear Substance Spill Kit Items Purpose Details Polypropylene or high density polyethylene bucket with top 5 gallon size or larger To act as a receptacle for bag liners during a spill clean up and as a storage container for the spill kit components Thickness of pail can better block radiations than plastic bags solely Chemical resistant bags All spill residue and spill clean up material should be placed in a high density polyethylene or polypropylene bag These bags should be made of strong construction e Leak proof e 4mm in thickness Chalk wax pencil or tape To clearly mark or delimitate radioactive spill area Personal protective equipment PPE At least e 2 pairs of chemical splash goggles e 2 pairs of disposable nitrile gloves e 2 disposable gowns or laboratories coats L or XL e 2 pairs chemical resistant shoe covers e 2 disposable masks N95 No gloves are totally chemical proof however some are more resistant to chemica
107. ody to fit the job This can be achieved by creating a comfortable environment with the application of ergonomic principles such as e Avoiding overreaching repetition awkward posture direct pressure to muscles fatigue and force e Understanding how to adjust our work environment to accommodate our individual needs e Applying principles of good posture and habits The height of work surfaces and laboratory benches is often difficult to adjust However chairs and laboratory stools should be adjustable in height and foot stools can be used to accommodate for a person s height Repetitive movements and tasks should be identified and adjustments made for activities that enable changes in posture and motions For example a repetitive task could be rotated between employees Proper lighting is also an important ergonomic factor and task lighting can be used to supplement the general laboratory lighting Laboratory ergonomic tips e Adjust the microscope workstation to support a good work posture avoid leaning forward by adjusting the eyepieces tube length and angle adjust the chair and work surface to provide good back and foot support e Adjust the armrests so that fingers are positioned to reach the height of the microscope dials to avoid elevating the arms and hands without proper support e Use shorter pipettes in order to decrease hand elevation and consequent awkward postures position the tips and discard containers to avoid rotati
108. of Flammable Materialie 32 7 5 Peroxide Forming Solvents and Reagents ss 34 7 6 Compressed GASES Te 1 8 RR 35 7 6 1 Handling D E 36 7 6 2 eI sro icr Uo 36 7 6 3 STORAGE GUIG SNIMES IEEE TETTE EET 36 7 6 4 Cyltridets Eeer 37 7 6 5 Storage Limits for Hazardous Gases ccececsssssceeeeeeeeeenneeeeeceesseeeneeeeeeeceeseeneeeeeeseeseeneaaeeeeeesenses 37 7 6 6 Special Ventilation Requirements esses eene eene nennen enne nnnnnnns seen nennen nnn 37 7 6 7 Asphyxiation Carbon diovide sise 38 7 7 I8 aeo Tft EE 38 7 7 1 Cold Burns Frostbite and Hypothermia ere 39 7 7 2 Asphyxiation Liquid Nitrogen Argon and Helium ss 39 7 7 3 Fire Hazards from Oxygen Enriched Atmosphere ss 39 EHS DOC 001 v 1 Laboratory Safety Manual DRAFT UNIVERSITE ENVIRONMENTAL W Concordia tear ann saret Y UNIVERSITY 7 7 4 Liquid Oxygen CondensatlOn toto o E Re E ER ERE ER NENNEN SENE ERAI RE rates ndlr 7 7 5 Over PressuriZatiON fesses NOESEN nE EEN ENEE socdeeunecsesveercdansueenderce conversaeasieeceeaseete 7 8 Liquefied Petroleum Gases DG 7 8 1 Definition and Associated Hazarde nnne nennen enn senes senes e nenne nnne 7 8 2 LPG Laboratory USe TEE 7 8 3 LPG Storage Requirements 4er geet E enrvdeasa EERSTEN ee 7 9 OXIGIZING GOSCS EEN VEU 8 Nanomaterials amp Nanoparticles co reser eraot ros a rna a ora
109. ograms The following table shows the new WHMIS 2015 pictograms associated with the different hazard classes Table 7 2 4 1 WHMIS 2015 Hazard Pictograms and Classes Pictogram Hazard Classes Flammables gases aerosols liquids solids Self reactive substances and mixtures Pyrophoric liquids solids and gases Self heating substances and mixtures Substances and mixtures which in contact with water emits flammable gas Organic peroxides Gases under pressure Acute toxicity severe Carcinogenicity Respiratory sensitization Reproductive toxicity Specific target organ toxicity repeated exposure Specific target organ toxicity single exposure Categories 1 amp 2 Germ cell mutagenicity Aspiration hazard Biohazardous infectious materials o9 E e E K 6 The environmental hazards classes and the explosives hazard class are not proposed for adoption in Canada FHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 26 of 81 UNIVERSITE ENVIRONMENTAL v Co ncor d l HEALTH AND SAFETY Gebeier 7 2 5 Safety Data Sheet SDS Safety Data Sheets SDSs are replacing Material Safety Data Sheets MSDS They have a new format of 16 standardized headings and must be available for every hazardous product in the workplace covered by WHMIS Safety Data Sheets SDSs provide employers and workers with comprehensive information about chemical products This information can be used in the wor
110. on sources etc 17 4 1 Incidental Spill or Minor Spill Incidental spills can often be safely cleaned up by staff or students However anyone who is not a member of the University Spill Response Team and who is about to clean up an incidental spill must Stay within their comfort zone Be familiar with the hazards of the spilled material Have clean up instructions available on the MSDS e Use appropriate PPE and necessary clean up equipment If these requirements are met staff or students can proceed with the following spill clean up procedure 1 Advise and warn co workers located in spill area 2 Ensure no one enters the spill area 3 Consult the MSDS 4 Don appropriate PPE 5 Clean the spill amp appropriately decontaminate the area 6 Report the spill EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 68 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY a ee EA fe wer o Notify your Supervisor o Complete an Injury Near Miss Report Form o Submit the Injury Near Miss Report Form to EHS 17 4 2 Emergency Spill or Major Spill Emergency spills require higher level of precautions and training They should only be cleaned up by the University Spill Response Team Anyone facing or witnessing an emergency spill must 1 Advise and warn co workers located in spill area 2 Evacuate the area immediately 3 Nottouch or try to clean up the hazardous material spill 4 Notify Security at x
111. oncordia University Facilities Operations When a particular fume hood requires maintenance the laboratory staff is responsible for emptying and properly decontaminating their fume hood prior to the maintenance A detailed list of chemical and biological agents used in the chemical fume hood may be requested for safety evaluation purposes If the fume hood is being used or has not been properly emptied at the time scheduled for its maintenance Facility Operations will leave a notice on the fume hood sash indicating a new scheduled maintenance time Upon a second notice issued to laboratory users by Facility Operations regarding fume hood maintenance immediate action from the Laboratory Supervisor or the department Technical Officer will be required in order to ensure proper and safe conditions for the fume hood maintenance by Facility Operations Facilities Operations may also issue notices of intent to perform maintenance work on the ventilation system These notices shall be observed and chemical fume hoods shall not be used when Facilities Operations is repairing or adjusting the ventilation system 5 3 Safety Equipment 5 3 1 Emergency Eyewash Stations Safety Showers Emergency showers and eyewash stations can provide rapid decontamination following exposure to a chemical or biological substance They are located wherever there is a risk of accidental splashes of corrosive toxic or other hazardous materials to the skin or eyes such
112. ons provide a good starting point for deciding where and how the product should be stored The storage conditions in the workplace should be based on workplace specific factors the hazards of the product health fire and reactivity the amount in storage types of containment bulk or smaller containers and the way the product is used Use chemically resistant structural materials in the storage area and ventilation system e g corrosion resistant The following guidelines should be used when storing any chemical e Ensure that all containers are in good condition and are properly labelled e Use approved containers being aware of any special ventilation requirements e g for flammables corrosives e Do not store incompatible materials together Dangerous combinations include o Acids Bases o Flammables Oxidizers o Water Reactives Aqueous Solutions e Segregate corrosives from flammables e Segregate strong oxidizers from everything e Most organic reactives must be segregated from inorganic reactives metals e Segregate reactives from flammables e Do not store chemicals in alphabetical order except within a grouping of compatible chemicals e Use secondary containment trays to contain potential spills e Maintain good housekeeping practices and minimize clutter e Ensure appropriate spill control and fire protection equipment is readily available in or near the storage area e Liquid chemicals should be placed below eye level e
113. oods or biological safety cabinets unless they have been properly decontaminated In the event of a spill refer to the Emergency Procedures section Chapter 17 Emergency Procedures for more details The laboratory staff is responsible for removing any hazards that Custodial Services might encounter during their activities All chemicals biological materials and waste containers must be moved off the floor to a safe and secure location within the laboratory before Custodial Services enters Laboratories can make arrangements with Custodial Services by contacting x2400 If maintenance or repair on laboratory facilities is required a service call should be sent to x2400 Any equipment should be emptied of its contents and properly decontaminated prior to any work being performed by Facilities Operations In the event of laboratory decommissioning arrangements with Custodial Services can be scheduled for floor and bench cleaning However it is mandatory that laboratory surfaces counter tops shelves etc be decontaminated by laboratory staff prior to any work performed by Custodial Services 6 2 3 Working Alone Working alone should be avoided as much as possible If working alone is unavoidable the direct Supervisor must be informed and specific safety measures must be planned according to the University policy on working outside the hours of operation or in isolation VPS 6 The following are examples of safety measures that labora
114. or disposal as long as the bottle is in good condition and the label is legible Empty chemical bottles with labels that are still legible can also be collected by EHS as chemical waste EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 45 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY GTA E fe we 13 1 3 Empty Chemical Containers Used 4L solvent bottles or containers which are empty can be disposed via regular garbage as long as they are properly cleaned To properly clean a chemical bottle e Triple rinse the bottle see Solvent Bottle Disposal Procedure e Remove original chemical labels and or write rinsed on the label e Remove the cap Bottles and other glass containers which were used to contain or hold chemicals cannot be recycled through regular garbage 13 1 4 Chemical Waste Pick Up Procedure Once you have hazardous chemical waste ready to be picked up the following procedure must be followed 1 Complete the Hazardous Waste Disposal Request Form by including the date room number phone extension and signature 2 Include all the details about the hazardous waste chemical name quantity container size In the case of mixtures please write down approximated percentage of each component 3 Properly fill in the label on the waste container Avoid using abbreviations 4 For mixed waste indicate approximate percentage of contents in order of highest to lowest concentration 5 S
115. pervisor An Injury Near Miss Report must be completed as soon as possible no later than 24 hours after an injury or incident All incidents and accidents are investigated in order to implement the appropriate measures to prevent the incident from reoccurring First aid is available in the event of an accident or incident a list of area first aiders should be available in or near the first aid kit All workplace accidents requiring absence from work must be reported immediately to the Supervisor and Human Resources Injured employees should go to a physician and take along a Temporary Work Assignment Form provided by the Supervisor or department head if time loss is anticipated The physician will fill out these forms All paperwork provided by the physician should be brought to Human Resources to file a CSST claim if necessary Complete and sign the CSST EMPLOYER NOTICE AND REIMBURSEMENT CLAIM Form 1940 and CSST WORKER S CLAIM Form 1939 and bring the forms to Human Resources no later than 24 hours after the injury If the employee is unable to do so they may authorize their Union delegate to represent them Failure to report work related injuries illnesses may result in the denial of benefits under worker s compensation For further information consult the HR Department webpage EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 66 of 81 UNIVERSITE ENVIRONMENTAL W Concordia teatrianp saret Y UNIVERSITY 17 2 Fire
116. phoric gases that are greater than lecture bottle size that are located in laboratory units shall be kept in approved continuously mechanically ventilated sprinklered gas cabinets Common toxic or highly toxic gases are listed in Appendix IV Flammable or Toxic Compressed and Liquefied Gases ii Flammable Gases As for toxic gases EHS strongly recommends that flammable gas cylinders rated 4 under NFPA 704 that are greater than a lecture bottle size should be placed into approved continuously mechanically ventilated gas cabinets 7 6 7 Asphyxiation Carbon dioxide Carbon dioxide is primarily an asphyxiant but also has mild toxic properties The recommended exposure limits for carbon dioxide are e 5 000 ppm 0 5 by volume calculated as an 8h time weighted average concentration in air e 15 000 ppm 1 5 for a 15 minute period For these reasons a carbon dioxide monitor should be used when there is a risk of CO exposure rather than an oxygen deficiency monitor Table 7 6 7 1 Carbon dioxide exposure symptoms Carbon dioxide content vol Effects and symptoms Slight feeling of suffocation and an increased breathing rate Headaches dizziness and sweating can occur after 30 minute exposure Breathing becomes laboured judgement impaired Breathing becomes laboured judgement impaired Fatal after approximately four hours exposure Immediate unconsciousness fatality may occur after a few minutes 7 7 Cryogenic Gases There
117. ping transport reception The transportation of hazardous substances between the University s buildings and campuses should be done through Distribution Services x2400 Never transport hazardous substances on the University s shuttle bus La Soci t de Transport de Montr al STM also prohibits the transport of hazardous substances within buses and the metro For more information concerning TDG please contact EHS at ehs concordia ca You may find useful information and documentation about TDG on the EHS website in the Laboratory Safety Programs webpage EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 18 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY neh MN qr You may also refer to the following links from Transport Canada or CANUTEC e Transport of Dangerous Goods Regulation e Canadian Transport Emergency Centre CANUTEC e Transport of Dangerous Goods Safety Marks PDF 6 43 By Plane Air Shipments If any shipment of hazardous materials or dangerous goods must be done by plane air shipment please contact EHS at ehs concordia ca Air shipments must be compliant with the IATA regulations which are different than TDG regulation requirements concerning packaging labelling shipping documentation exemptions and personnel training Any air shipments must be verified by EHS especially those involving shipment of biological materials on dry ice 7 Chemical Hazards 7 1 Workplace Ha
118. pplies and equipment stored on top shelves must allow a 45 cm 18 inches clearance so that fire sprinkler heads can be effective e Corrosive chemicals should never be stored above eye level i Discarding Material When discarding empty boxes or other containers bearing hazardous material labels the labels must be defaced or removed before disposal Contaminated boxes or containers cannot be disposed of in the regular trash Hazardous waste must be disposed of in accordance with University guidelines as described in Chapter 13 Hazardous Waste iii No Dry Cleaning of Surfaces Dry mopping or dry sweeping must not be done in laboratories using powdered hazardous materials as this could cause the materials to become airborne Cleaning of laboratory equipment including refrigerators freezers fume hoods biological safety cabinets and benches is the responsibility of laboratory personnel and must be conducted regularly in order to prevent accidental contact with hazards EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 15 of 81 EN m NIV ER SITE ENVIRONMENTAL MJ Co ncor d ld HEALTH AND SAFETY a ee Ng grow SS RTE iv Cleaning and Maintenance of Facilities Custodial Services will remove regular garbage and clean floors that are clear and free of chemical roducts and any hazardous materials Custodial Services is prohibited from cleaning up chemical and biological material and therefore cannot clean the interior of any fume h
119. r certain frequencies better than others If we hear two sounds of the same sound pressure but of different frequencies one sound may appear louder than the other This is because we hear high frequency noise much better than low frequency noise Therefore noise measurement readings are adjusted to correspond to this peculiarity of human hearing Measurements are taken using an A weighting filter which is built into the instrument that de emphasizes low frequencies or pitches Decibels measured in this manner are A weighted and are called dB A Examples of workplace noise levels are given in the table 14 5 1 Table 14 5 1 CSA Guidelines Z412 2011 Industrial setting Quebec regulation Industrial customer service area Circulation area Call centre 45 48 Open area cubicle Closed office Videoconference room Conference room Executive office Most laboratory environments do not produce noise levels that require the use of hearing protection Noise level in laboratories generally does not exceed 60 dBA However certain equipment and operations may exceed the recommended provincial limit of 90 decibels dBA Concordia University has even lowered its exposure limit to a value of 85 dBA for a typical 40h work week The most common noisy equipment are sonicators and wind tunnels Laboratories using these types of equipment and operations should have proper hearing protection available to all users dB w 15 Equipment Safe
120. r the use of LASERs radiation sources biological materials strong magnetic fields or any other University Policy controlled activities Specifications concerning specific SOP creation are also described in other different safety manuals e g Biosafety Radiation Safety etc and additional guidelines can be found in the Laboratory Safety Programs section of the EHS website An evaluation of the specific risks involved with the work performed in the laboratory must be done prior to starting any new projects Each laboratory should supplement the general Laboratory Safety Manual with safe handling procedures or SOPs that are specific to their laboratory activities Students and staff must be familiar with all work procedures and be informed of the hazards of the materials present in their work area The evaluation and analysis required in preparing an SOP may help identify previously undetected hazards and further the dialogue between the PI Laboratory Supervisor and staff students Standard Operating Procedures should include e Names of responsible persons emergency contact information reference documents and purpose of the SOP e Detailed procedures and precautions to be used for handling hazardous materials and in particular toxic chemicals and carcinogens e Identification of materials and procedures that should be carried out in a fume hood or biological safety cabinet e Details of necessary Personal Protective Equipment PPE e Cl
121. racking etc of the glove material e Compatibility charts rating systems will vary by the manufacturer s design of their chart Many use a color code where red bad yellow not recommended green good or some variation of this scheme A letter code may be used such as E excellent G Good P poor NR Not Recommended Any combination of these schemes may be used so please understand the chart before making a decision on the glove to be used http ezguide northsafety com IndGlovesMain aspx http www bestglove com site chemrest http www ansellpro com specware guide as www kcproductselector com Gloves aspx http www polyco co uk downloads chemical resistance guide pdf 16 2 3 Allergies As research facilities have increasingly moved away from latex exam gloves because of their sensitization potential other types of skin irritation and allergy to non latex gloves have also increased Some people can potentially develop an allergic contact dermatitis with the use of nitrile gloves mainly caused by chemical accelerators used in the production of nitrile and other latex free gloves While vinyl gloves may be an option in some circumstances they lack the elastic quality of nitrile and latex gloves and may not provide the same level of protection Alternative glove options are available from different suppliers against nitrile and latex allergies such as e Accelerator free nitrile gloves e Nitrile with aloe gloves which ar
122. re of the following classes compressed gas flammable or combustible material oxidizing material poisonous or infectious material corrosive material dangerously reactive material Act Respecting Occupational Health and Safety R S Q chapter S 2 1 The newly proposed Quebec Bill 43 An Act to enhance the communication of hazard related information concerning products present in the workplace and to amend the Act respecting occupational health and safety will amends the Act Respecting Occupational Health and Safety and certain regulations made under it mainly to replace the concept of Controlled Product by that of Hazardous Product The newly modified Act will define a Hazardous Product as Any product mixture material or substance governed by subdivision 5 of Division Il of Chapter III and determined by a regulation made under this Act Until the regulations adopted under the Act Respecting Occupational Health and Safety chapter S 2 1 are amended to harmonize them with the new classification of hazardous products the expressions listed in Schedule of this Act that designate a class of controlled products classified in accordance with the Controlled Products Regulations SOR 88 66 designate the corresponding hazard classes listed in the Hazardous Products Regulations SOR 2015 17 and set out in the Schedule Emergency Spill or Major Spill A release of hazardous material which Poses a significant safety or
123. rkers who owing to a work related injury have sustained a permanent impairment to their physical or mental well being Promotion of occupational health and safety 4 2 Due Diligence In an occupational health and safety perspective due diligence means that an employer shall take all reasonable precautions to prevent injuries or accidents in the workplace Supervisors assume the responsibility of the employer in the context of due diligence In an educational institution maintaining a safe and healthful workplace is considered due diligence for Supervisors A Supervisor is any individual overseeing the work research or studies of a staff or student with or without remuneration They must exercise due diligence with regards to the health and safety of their workers A worker means a person including a student in the cases determined by regulation who under a contract of employment or a contract of apprenticeship even without remuneration carries out work for an employer except e a person employed as manager superintendent foreman or as the agent of the employer in their relations with their workers e a director or officer of a legal person except where a person acts as such in relation to their employer after being designated by the workers or by a certified association EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 4 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY nee E feier 4 2 1
124. rmation on this please have a look at Bill C 45 and Sections 22 1 amp 22 2 of the Criminal Code imposing criminal liability on organizations and its representatives for negligence 22 1 and other offences 22 2 An overview is available at www ccohs ca oshanswers legisl billc45 html EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 3 of 81 pu UNIVERSIT serge ENVIRONMENTAL WV Co ncor d ld HEALTH AND SAFETY AE E feier 4 1 4 CSST La Commission de la Sant et de la S curit du Travail CSST is the organization to which the Government of Qu bec has entrusted the administration of the occupational health and safety plan For this purpose the CSST sees to the application of the following two Acts e the Act respecting occupational health and safety which aims to eliminate at the source dangers to the health safety and physical well being of workers e the Act respecting industrial accidents and occupational diseases which aims to compensate for work related injuries and their consequences for workers as well as the collection of the sums necessary to fund the plan from employers Table 4 1 4 1 CSST Fields of Intervention Prevention and inspection Compensation and rehabilitation VPS 43 Support for workers and employers in their Compensation of workers having sustained a efforts to eliminate at the source the dangers work related injury present in their workplace Inspection of workplaces Rehabilitation of wo
125. roduct Store locked up Dispose of contents containers in accordance with local regulations IF ON SKIN Wash with plenty of water If skin irritation occurs Get medical advice or attention Take off contaminated clothing and wash it before reuse IF SWALLOWED immediately call POISON CENTRE or doctor Rinse mouth The information on labels still needs to be in English and French OD Danger Mortel en cas d ingestion Provoque une irritation cutan e Conseils Porter des gants de protection Se laver les mains soigneusement apr s manipulation Ne pas manger boire ou fumer en manipulant eproduit Garder sous clef Eliminer le contenu r cipient conform ment aux r glements locaux en vigueur EN CAS DE CONTACT AVEC LA PEAU Laver abondamment l eau En cas d imitation cutan e Demander un avis m dicaliconsulter un m decin Enlever les v tements contamin s et les laver avant r utilisation EN CAS D INGESTION Appeler imm diatement un CENTRE ANTIPOISON ou un m decin Rincer la bouche Compagnie XYZ 123 rue Machin St Mytown ON NON ONO 123 456 7890 However the presence of the following items on the supplier labels is not required anymore e ahatched border e astatement that a MSDS or SDS is available EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 25 of 81 UNIVERSITE ENVIRONMENTAL v Co ncor d A HEALTH AND SAFETY Une 2 eee 7 2 4 Hazard Pict
126. rofuran 2 Pentanol Page 76 of 81 UNIVERSITE ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY DE A wg gw 4 Penten 1 ol Tetrahydrofuran 1 Phenylethanol Tetrahydronaphthalene 2 Phenylethanol Tetralin 2 Propanol Vinyl ethers Class Chemicals that may auto polymerize as a result of peroxide accumulation are listed below These chemicals can undergo hazardous polymerization reactions that are initiated by peroxides that have accumulated in solution They are typically stored with polymerization inhibitors to prevent these dangerous reactions Inhibitors do become compromised over time however and thus after receiving these chemicals should not be kept for over 12 months or the manufacturer s expiration date Non inhibited chemicals should not be opened and stored over 24 hours Non inhibited chemicals should be inhibited with the appropriate compounds before the 24 hour mark is exceeded Do not store inhibited chemicals in this category under an inert atmosphere because some of the inhibitors require a small amount of oxygen to work Acrylic acid Indene Acrylonitrile Methyl methacrylate Butadiene Styrene Chlorobutadiene Tetrafluoroethylene Chloroprene Vinyl acetate Chlorotrifluoroethylene Vinyl acetylene Dibenzocyclopentadiene Vinyl chloride 9 10 Dihydroanthracene Vinyl pyridine EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 77 of 81 Ss UNIVERSITE V Concordia nee ears ENVIRONMENTAL HEALTH AND SAFETY
127. ry Safety Manual DRAFT Page 11 of 81 UNIVERSITE ENVIRONMENTAL v Co ncordia var an SAFETY Z A E fei Figure 5 3 2 1 Examples of electrical and gas shut offs CAUTION el wmm GAS SYSTEM CONTROL VALVE NOT CLOSE ze 5 3 3 Fire Extinguishers Laboratories are provided with one or several fire extinguisher s suitable for the hazardous materials used and stored within the space Fire extinguishers must be unobstructed and located in clear view Laboratory staff and students should know the location and proper use of the fire extinguishers in their work areas Fire extinguisher training is available from Security Please consult the Security training webpage There are 4 types of fire extinguishers each efficient to fight a specific type of fire These fires are classified by their fuel source and given identifying letters as showed in table 5 3 3 1 Table 5 3 3 1 Types of Fire Extinguishers Ve Used for fires from combustible materials such as E Class A j paper wood cardboard and plastics LS Used for flammable or combustible liquids such as Class B d E solvents gasoline kerosene grease and oil Used for electrical equipment such as appliances computers wiring circuit breakers and outlets You should never use water to extinguish a class C fire due to the risk of electrical shock Class C Class D Used for combustible metals such as magnesium titanium potassium and sodium gt Th
128. s well as to the general public The University is committed to complying with all federal and provincial guidance documents concerning the safe operation of equipment generating significant magnetic and electromagnetic fields as stated in VPS 54 The magnetic field safety program is under the responsibility of the Radiation Safety Officer RSO at the EHS Office 12 LASER Hazards Separate LASER Safety Manual Procedures and Guidelines are available from the EHS website For additional information you may also consult the webpage of the Laser Institute of America ANSI Z136 Standards Concordia University s LASER safety policy VPS 51 is based on the recommendations of ANSI Z136 1 any other pertinent standards and in compliance with the Federal and Provincial regulations The LASER safety program s primary objective is to ensure that no laser radiation in excess of the maximum permissible exposure MPE reaches the human eye or skin This program is also intended to ensure adequate protection against laser related non beam hazards The LASER safety program covers all class 3B and class 4 lasers Every LASER installation of class 3B or 4 must have a LASER safety plan in place and must be reviewed by the Laser Safety Officer The University s LASER Safety Program issues internal permits to University employees who are either the Principle Investigator or the person responsible of the location where the Class 3B or Class 4 lasers laser s
129. shock during any sudden change of movement Secondary containment is important when hazardous products are transported through public areas such as hallways or elevators where the effects of a spill would be more severe e Freight elevators must be used for moving hazardous products between floors Passenger elevators must not be used for this purpose Do not use stairways or escalators e Do not transport incompatible products together on the same cart unless packaged according to TDG regulations e All containers require a label identifying the contents in accordance with WHMIS regulation 6 4 2 By Ground Vehicle If a hazardous product must be transferred between buildings or campuses by means of a public road or crossing a public road special precautions must be taken according to the Transportation of Dangerous Goods TDG Regulations Unless the specified substance is exempt or present in a quantity exempt by the legislation the following points must be observed for transportation e The substance is placed in an appropriate means of containment e The substance is clearly identified using appropriate TDG labels on the means of containment e The substance is properly stored and or segregated within the transportation vehicle e The driver of the transportation vehicle has received TDG training e The transportation vehicle is properly placarded e All the proper shipping documents are included in every step of the shipment ship
130. ssigned personal protective equipment for the work e Be aware that the material used for contact lenses is permeable to some vapours found in a laboratory Such vapours can be trapped behind the lens and may cause extensive irritation to the eye A contact lens can prevent tears from removing irritants e t may be advisable to remove lenses to perform certain experiments e Laboratory workers who choose to wear contact lenses should advise their Supervisors In an emergency this information must be available to the first aiders e If chemical vapours contact the eyes while wearing contact lenses these steps should be followed o Immediately remove the lens o Continuously flush the eyes for at least 15 to 30 minutes o Seek medical attention 16 4 Respiratory Protection Respiratory hazards in a laboratory can consist of chemical vapours gases and particulates such as dust fumes and biological materials Fume hoods and general laboratory ventilation are generally sufficient to protect workers A risk evaluation or assessment can determine if the engineering safety equipment is sufficient or a respirator is required The specific type of respirator information should be included in the laboratory SOP Good practices dictate that an appropriate respirator should be available and used in an emergency situation such as a hazardous spill Anyone who has to use a respirator full face or half face for their work must first be fit tested annually
131. ste generated at the University is composed of sealed and unsealed radioactive sources such as e Aqueous radioactive solutions e Liquid scintillation counting fluid in vials e Solid materials contaminated with radioactive material 13 3 1 Categories Disposal It is up to the RSO to establish a system of radioactive waste collection in all designated radioisotope laboratories Only solid waste may be transported for disposal e Liquid except scintillation vials waste must be solidified absorbed adsorbed before disposal e Waste containers must bear the radioactive waste disposal tag Fig 13 3 1 1 radioactive waste disposal tag CONCORDIA UNIVERSITY UNIVERSITE CONCORDIA CONTAINER NUMBER PERMIT HOLDER PERMIT ROOM s WEIGHT ISOTOPE ACTIVITY Dry waste and scintillation vials 20 L pail lined with a clear polyethylene bag Any other radioactive liquids 4 5 L container with absorber The radioactive waste containers and waste tags are available from the RSO FHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 49 of 81 UNIVERSITE ENVIRONMENTAL V Co ncor d l HEALTH AND SAFETY LG WEE feier 13 3 2 Radioactive Waste Pickup Procedure Once you have radioactive waste ready to be picked up the following procedure must be followed 1 A properly completed radioactive waste disposal tag must be completed and attached to each container of radioactive waste to be collected 2 Each contain
132. steps to ensure labels are not defaced and are easy to read at all times EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 21 of 81 wey NIV NITE ENVIRONMENTAL MJ Co ncor d ld HEALTH AND SAFETY ne eh Nr feier Table 7 1 2 1 WHMIS Labeling Requirements Workplace WHMIS Labelling Standard Standard Less than 10kg Less than 10 kg and For immediate use Requirements ee product product AND from sample from a H lt 100 ml 2 100ml supply house Tee Vera Product identifier Required Required Required Required Required Supplier identifier Required Required Required Risk phrase Required Required Precautionary Required Required Required measures MSDS reference Required Required Required Required First Aid Required Required Hazardous ingredient Required disclosure Emergency phone Recnici number Hazard symbols Required Required Hatched border Required Required Required Hazardous Lab Required Sample statement 7 1 3 Material Safety Data Sheet MSDS Additional information about a controlled product is provided on its Material Safety Data Sheet They are provided by the supplier to give users detailed information about the hazards and safe use of products Before using any product for the first time students and staff should review the MSDS for information The information on the MSDS is divided into nine sections 1 product information 2 hazardous ingredients 3 physical data 4 fir
133. the more harmful UVC and greater than 9996 of UVB radiation However some common laboratory equipment such as germicidal lamps in biological safety cabinets UV curing lamps black lights trans illumination boxes and nucleic acid cross linkers can generate concentrated UV radiation in all the spectral regions For example Fig 14 2 1 UV components of the electromagnetic spectrum UVC UVB UVA RTI 100 280 315 400 Wavelength nm Ultraviolet Visible Infrared FHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 53 of 81 2 UNIVERSIT ENVIRONMENTAL Co ncor d l HEALTH AND SAFETY ne g Np The use of equipment without the appropriate shielding and personal protective equipment can cause injury to skin and or eyes within seconds of exposure The severity of the effect will depend on the wavelength intensity and duration of exposure The eyes are most sensitive to UV radiation and an exposure of a few seconds can result in photokeratitis and conjunctivitis Photokeratitis is a condition caused by the inflammation of the cornea of the eye Conjunctivitis is the inflammation of the conjunctiva causing discomfort and a watery discharge Chronic skin exposure to UV radiation has been linked to premature skin aging and skin cancers Chronic exposures to the eye can lead to the formation of cataracts The following safety measures should be implemented to limit UV exposure e Never allow the skin or eyes to be exposed to a
134. thyl ether oO P amp o B Natural Gas Nitric Oxide Nitrogen Dioxide Nitrogen Trioxide 4 Nitrosyl Chloride Oxygen Difluoride A5 Ozone Pentaborane 4 Iso Pentane 3 Phosphine Propane 3 Propylene Selenium Hexafluoride Silane Silicon Tetrafluoride Stibine 3 Sulfur Tetrafluoride Sulfuryl Fluoride 3 Tetrafluoroethylene monomer 4 Tetrafluorohydrazine 3 Trimethylamine Vinyl Bromide 3 Vinyl Chloride Vinyl Fluoride Flamm Flammable Y Yes N No SI Spontaneously ignite EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Methyl chloride Methyl Fluoride Methyl Mercaptan 2 Methylpropene State Gas Gas Liquid Gas Liquid Liquid Liquid Gas Gas Liquid Liquid Liquid Liquid Liquid Gas Liquid Liquid Gas Liquid Liquid Gas Liquid Liquid Gas Flamm Health N 3 N 3 Y 4 N 4 Y Y 3 Y 4 Y Y Y Y 3 Y 3 Y Y Y Y Y 4 Y Y N 3 N 3 N 3 N 3 N 4 N 4 SI 4 Y SI 4 Y Y N 3 SI N 4 Y 4 N 4 N Y Y Y 3 Y Y Y Page 78 of 81 2 UNIVERSIT V Concordia Way we db NE NE RP ENVIRONMENTAL HEALTH AND SAFETY Appendix V Typical Laboratory Spill Kits Typical Laboratory Chemical Spill Kit Items Purpose Details Polypropylene or high density polyethylene bucket with top 5 gallon size or larger To act as a receptacle for chemical resistant bag liners during a spill clean up and as a storage container for the spill kit components Ch
135. tion Hazards Separate Radiation Safety Manual Procedures and Guidelines are available on line from the EHS website lonizing radiation emitted from radioisotopes and radiation emitting devices is an essential tool in both the research and teaching activities of the University Since ionizing radiation is hazardous strict regulations have been developed in the form of federal legislation Nuclear Safety and Control Act and institutional policies to protect employees students and the general public from unnecessary or potentially harmful levels of radiation exposure The radiation safety program is under the responsibility of the Radiation Safety Officer RSO at the EHS Office EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 42 of 81 UNIVERSITE ENVIRONMENTAL Co NCOrdia wear anp sarety On eh E S D a 11 Magnetic Field Hazards A separate Magnetic Field Safety Manual is available on line from the EHS website Strong static and time varying magnetic fields are generated by research and other equipment in various locations within University facilities e g NMR MRI etc Although magnetic fields both static and time varying and associated electromagnetic fields do not cause apparent long term health effects there are hazards under some circumstances which need to be recognized and controlled to avoid accidents or injury to equipment operators researchers support staff students visitors and research subjects a
136. tion date After this period the product must be disposed They may auto polymerize as a result of peroxide accumulation They can undergo hazardous polymerization reactions that are initiated by peroxides that have accumulated in solution They are typically stored with polymerization inhibitors to prevent these dangerous reactions Inhibitors do become compromised over time however and thus these chemicals should not be kept for over 12 months after reception or the manufacturer s expiration date Non inhibited chemicals should not be opened and stored over 24 hours Non inhibited chemicals should be inhibited with the appropriate compounds before the 24 hour mark is exceeded For detailed information and list of some common used chemicals please refer to Appendix III Peroxide forming chemicals and solvents 7 6 Compressed Gases Safety A compressed gas is a substance that is a gas at normal room temperature and pressure and is contained under pressure usually in a cylinder Some compressed gases e g acetylene are stabilized in the cylinder by dissolving the gas in a liquid or solid matrix Compressed and liquefied gases are routinely used in laboratories and various other operations at Concordia University They have the potential for creating hazardous working environments Complete guidelines concerning the use of compressed gas can be found within the following NFPA codes and standards e NFPA 45
137. tored in chemical storage refrigerators e Laboratory refrigerators must not be used for food and beverage storage e Laboratory refrigerators must be labelled for their intended purpose such as No Food or Drink or chemicals laboratory use only Each department has a lounge kitchen area with a refrigerator for staff use e All materials in refrigerators or freezers must be labelled according to WHMIS regulations e All containers must be sealed preferably with a cap Containers should be placed in secondary containers or spill proof pans trays 15 2 Centrifuges Please refer to the document Safe Use of Centrifuges posted on the Biosafety webpage Spills leaks tube breakage or improper use of safety cups rotors can result in generation of biohazardous aerosols during centrifugation Recommendations for safe centrifugation of biohazardous material include e Use the centrifuge according to the manufacturer s instructions and laboratory SOP o Ensure that the centrifuge is properly balanced o Use tubes intended for centrifugation e g plastic thick walled tubes with exterior thread screw caps Check tubes for stress lines hairline cracks and chipped rims before use Never fill tubes to the rim e Use sealed centrifuge cups rotors o Inspect cup rotor seal integrity regularly and replace if cracked or dry o Load and unload infectious materials or toxins inside a BSC o Allow time for aerosols to settle before opening
138. tory users can establish e Notify Security x3717 so that a regular patrol can be planned e Arrange for a buddy system with another laboratory user e Organize for a regular phone check in with a buddy or with Supervisor if the check in fails they should call security Working alone is forbidden for undergraduates 6 2 4 Unattended Experiments Leaving experiments unattended should be avoided as much as possible If this is unavoidable the direct Supervisor must be informed and safety measures must be planned according to the following guidelines e The Supervisor must be notified and approve the experiment e Ensure that all containers and equipment are labeled according to WHMIS regulations e Post the Overnight Unattended Experiment form EHS FORM 079 near the experiment e g on fume hood sash e Provide for secondary containment and shielding of the material experiment in the event of containment failure e Keep laboratory door window panes unobstructed EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 16 of 81 UNIVERSITE ENVIRONMENTAL W Concordia teatianp sarerv Y UNIVERSITY 6 2 5 Laboratory Visitors Unauthorized visitors including children and pets are not permitted in laboratories Students or colleagues from other institutions may visit laboratories as part of educational programs However the activity must be supervised by Concordia staff In addition EHS must be advised and authorizatio
139. treat them as follows e Biological and hazardous chemicals do not autoclave and treat it as a biohazardous contaminated sharp e Biological and radioactive to be disposed as radioactive waste e Biological radioactive and hazardous chemicals to be disposed as radioactive waste 13 6 Other Types of Hazardous Waste They consist of any other types of waste materials considered to be dangerous for human health or the environment and cannot be thrown in regular garbage At the University such waste includes e full and or empty paint containers e lead acid or lithium batteries e toner cartridges e fluorescent tubes or bulbs e computers printers and other electronic equipment e waste A comprehensive document about waste handling at Concordia can be found on the Hazardous Waste webpage EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 51 of 81 mm UNIVERSIT QQ ENVIRONMENTAL Y Co ncor d ld HEALTH AND SAFETY Z A E feier 13 6 1 Disposal For any other types of hazardous materials which may be recycled or require special care including heavy items please contact Facilities Management at x2400 to schedule pickups Do not leave such waste in front of the different waste rooms as they can create tripping or spill hazards 13 6 2 Concordia Recycling Depot Locations Special recycling depots are available throughout both campuses You can bring any old alkaline batteries CDs amp DVDs cellular phones ink
140. ty Equipment must be maintained properly in accordance with the manufacturers instructions The safe use of laboratory equipment must be ensured by the PI or Laboratory Supervisor The following precautions should be observed e Read the manufacturer s instructions and keep available in an accessible location for future reference e Use and service equipment according to the manufacturer s instructions e Staff and students must be properly trained in the setup use and cleaning of the equipment The EHS orientation checklist can be used to record that proper training was given e Decontaminate equipment before maintenance is performed or sent out for repair EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 56 of 81 UNIVERSITE ENVIRONMENTAL W Concordia tearianp saret YV UNIVERSITY 15 1 Refrigerators and Freezers Only refrigerators and freezers designed for laboratory use should be used for the storage of chemicals Due to the potential hazards involving vapours and possible spillage laboratory refrigerators freezers are constructed with special design factors Heavy duty cords and corrosion resistant interiors reduce the risk of fire or explosions in a lab In contrast standard domestic refrigerators have electrical fans and motors that make them potential ignition sources for flammable vapours e Do not store flammable liquids in a refrigerator unless it is approved for such storage e Only chemicals are to be s
141. uding additional health concerns e g serious short term health effects or irritation reactivity and flammability e Know how to use the chemicals safely e Ensure engineering controls e g ventilation fume hoods are operating Closed handling systems glove box may be necessary to prevent the release of the material dust mist vapor gas into the workplace e Use the smallest quantity possible and use only in well ventilated areas e Follow safe work practices specified by the SOP or the Supervisor e Wear the appropriate personal protective equipment specified for the work This may include respiratory protection and chemical protective clothing such as an apron and gloves made from materials that protect against the chemicals handled e Report ventilation failures to the service call centre immediately at x2400 e Report all leaks spills incidents and injuries to Security immediately at x3717 e Keep Supervisor informed of all reported issues e Understand and practice emergency procedures to know what to do in case of a spill or other emergency e Wash hands thoroughly after handling and before leaving the laboratory EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 30 of 81 ka UNIVERSIT ENVIRONMENTAL W Co ncor d l HEALTH AND SAFETY Www wg Ng grow 7 4 Chemical Storage 7 4 1 General Guidelines MSDSs contain general recommendations for the safe storage of a hazardous product These recommendati
142. ve Waste Pickup Procedure iii 13 3 3 General Guidelines nenne nennen en ene se sense sensns ses sess sese esses senes senis T3 4 Sh fDSuu ener UII eee ee ee Pee een eee eee eee ee rite 13 4 1 Categories Disposals dee r en eier eer Sege See teen ee saccades Zeie dee Seen vii oud eeng uge 13 4 2 Guidel EE 135 Mixed WSCC EE 13 5 1 DISH OSA 13 6 Other Types Of Hazardous Waste inner ale K oT DISPOSAL ccm 13 6 2 Concordia Recycling Depot Locations 13 7 Non Compliant EE 14 Physical EE DE EHS DOC 001 v 1 Laboratory Safety Manual DRAFT UNIVERSITE ENVIRONMENTAL H Co ncor d l HEALTH AND SAFETY Y UNIVERSITY E E Ee deet 52 14 1 1 General Electrical Safety 52 14 1 2 Static Gd dere E 53 14 2 UV ROGIQTION EE 53 14 3 TEE 54 MAA eeler 55 EAS TEE 56 15 EQUIPMENT Safety ccvciiscssccsdecccekecctesassccecenscacvuasscccessetesevedsscacsorsteseUesausacsedeseueUucuueseseseuasbedstescdesexsantedescsestuesseee 56 15 1 Refrigerators and Freezers inner 57 15 2 SGeDEHfUges oiii en Ee Ever er Ee DER 57 15 3 AULOCIOVES ee e ee ee 58 15 31 General GuidelineSsisecsiccrsicsscesosdsscasniesssvanedsaccsnieaiaes oncssacsndes vous nscssanzad esdcnancdssunvervssetsascanaustccsscvaancs 58 15 3 2 Autoclave Loading EE 58 15 3 3 Autoclave TTT EE 59 15 4 Sonicators Mixers and Grinders eese nnn nensis nnne nested assa ains essaie 59 15 5 BUNSCN
143. ystems are used or stored This program is under the responsibility of the LASER Safety Officer LSO at the EHS Office EHS DOC 001 v 1 Laboratory Safety Manual DRAFT Page 43 of 81 Se UNIVERSITE Gre ENVIRONMENTAL MJ Co ncor d ld HEALTH AND SAFETY GEAR E fe e 13 Hazardous Waste To ensure compliance with regulations and guidelines and for the safe handling and efficiency of operations EHS has established the following standards applicable to the collection labelling and packaging of these substances by each waste generating department and laboratory Under no circumstances will EHS personnel pick up chemical substances that do not follow the procedures and requirements listed in this section To ensure compliance users should follow these general guidelines e DO NOT accept any chemical hazardous substance or item containing hazardous substances as gifts or donations on behalf of the University without notifying EHS prior to the transfer This is to ensure that no unanticipated future hazardous waste costs would result from such a transfer and for the safe transport by Distribution Services personnel e DO NOT give or sell University property and equipment including hazardous substances to any person or organization outside the university except through the legally established procedures of the Purchasing Department or in the instance of hazardous materials through EHS e NEVER dispose any hazardous substance down t
144. zardous Materials Information System WHMIS 1988 WHMIS stands for Workplace Hazardous Materials Information System It is a comprehensive plan for providing information on the safe use of hazardous materials in Canadian workplaces Under the legislation a hazardous material is referred to as a controlled product A controlled product is the name given to products materials and substances that are regulated by WHMIS legislation Information is provided by means of product labels material safety data sheets MSDS and worker education programs The majority of the information requirements and exemptions of WHMIS legislation are under the Hazardous Products Act and the Hazardous Materials Information Review Act and apply to all of Canada In Quebec the CSST is responsible for applying WHMIS according to the provincial regulations WHMIS 1988 was created in response to the Canadian workers right to know about the safety and health hazards that may be associated with the materials or chemicals they use at work As such staff and students that work with or may be exposed to hazardous materials must be trained according to WHMIIS legislation in the following aspects e Education understanding the principles of WHMIS and the meaning of the information on labels and MSDSs e Training workplace specific training on how to apply this information to materials in actual use in the workplace including procedures for storage handling disposal a

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