Sharp MX-B201D MSDS
Contents
1. Personal Precautions None Environmental Precautions None Methods for Cleaning Up Wipe off with paper or cloth Do not use vacuum cleaner when a large amount is released It like most finely divided organic powders is capable of creating a dust explosion SHARP MATERIAL SAFETY DATA SHEET Page 3 5 Date Issued Sep 14 2010 MSDS No F 01981 7 HANDLING AND STORAGE Handling Technical Measures Precautions Safe Handling Advice Storage Technical Measures Storage Conditions Incompatible Products None None Use of a dust mask is recommended when handling a large quantity of toner or during long term exposure as with any non toxic dust Try not to disperse the particles None Keep container closed and Store in a cool and dry place Keep out of the reach of children None 8 EXPOSURE CONTROLS PERSONAL PROTECTION Engineering Measures Ventilation Exposure Limit Values OSHA PEL USA ACGIH TLV USA Not required under intended use 15mg m Total Dust 5mg m Respirable Dust 10mg m Total Dust 3mg m Respirable Dust Personal Protective Equipment Respiratory Protection Hand Protection Eye Protection Skin Protection Not required under intended use Not required under intended use Not required under intended use Not required under intended use Other Protective Equipment Use of a dust mask and goggles are recommended when handling a large qu2. as hazardous for transport 15 REGULATORY INFORMATION US Information TSCA Toxic Substances Control Act All chemical substances in this product comply with all applicable rules or order under TSCA SARA Superfund Amendments and Reauthorization Act Title II 302 Extreme Hazardous Substance None 311 312 Hazard Classification None EU Information 1999 45 EC and 67 548 EEC Symbol amp Indication Not required R Phrase Not required 76 769 EEC All chemical substances in this product comply with all applicable rules or order under 76 769 EEC SHARP MATERIAL SAFETY DATA SHEET Page 5 5 Date Issued Sep 14 2010 MSDS No F 01981 16 OTHER INFORMATION NFPA Rating USA Health 1 Flammability 1 Reactivity 0 WHMIS Legislation Canada This product is not a controlled product References IARC 1996 IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans Vol 65 Printing Process And Printing Inks Carbon Black and Some Nitro Compounds Lyon pp 149 261 H Muhle B Bellmann O Creutzenberg C Dasenbrock H Ernst R Kilpper J C MacKenzie P Morrow U Mohr S Takenaka and R Mermelstein 1991 Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats Fundamental and Applied Toxicology 17 pp 280 299 The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions However all materials may present
3. SHARP MATERIAL SAFETY DATA SHEET Date Issued Sep 14 2010 MSDS No F 01981 1 PRODUCT AND COMPANY IDENTIFICATION Product Name MX B20NT1 MX B20BT1 MX B20GT1 MX B20FT1 MX B20AT1 MX B20CT1 Supplier Identification Black Toner Sharp Corporation 22 22 Nagaike cho Abeno ku Osaka Japan Local suppliers are listed below Please contact the nearest supplier for additional information Area Country Local suppliers North America U S A Sharp Electronics Corporation Sharp Plaza Mahwah New Jersey 07495 1163 Telephone number 800 237 4277 Emergency telephone number 800 255 3924 Canada Sharp Electronics of Canada Ltd 335 Britannia Road East Mississauga Ontario L4Z 1W9 Telephone number 905 890 2100 Emergency telephone number 1 800 255 3924 Oceania Australia Sharp Corporation of Australia PTY Ltd No1 Huntingwood Drive Huntingwood Blacktown N S W Telephone number 1300 13 50 22 Europe Germany Sharp Electronics Europe GMBH Sonninstrasse 3 20097 Hamburg Telephone number 040 2376 2185 United Kingdom Sharp Electronics U K Ltd 4 Furzeground Way Stockley Park Uxbridge Middlesex UB11 1EZ Telephone number 08705 274 277 France Sharp Electronics France S A 22 Avenue des Nations Paris Nord 2 BP 52094 95948 Roissy Charles de Gaulle Cedex Telephone number 01 49 90 34 00 Austria Sharp Electronics Europe GmbH Handel
4. antity of toner or during long term exposure as with any non toxic dust 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Solid Ph Boiling Melting Point Softening Point C Flash Point C Ignition Point C Explosion Properties Density g cm Solubility in Water Form Powder Color Black Odor odorless Not applicable Not applicable 100 130 Not applicable gt 350 No data 1 1 bulk density approx 0 35 Negligible 10 STABILITY AND REACTIVITY Stability Hazardous Reactions Conditions to Avoid Materials to Avoid Stable Dust explosion like most finely divided organic powders Electric discharge throwing into fire Oxidizing Materials Hazardous Decomposition Products CO CO and NOx Further Information None Dermal SHARP MATERIAL SAFETY DATA SHEET Page 4 5 Date Issued Sep 14 2010 MSDS No F 01981 11 TOXICOLOGICAL INFORMATION Acute Toxicity Ingestion oral LD5 gt 2000mg kg Rats Inhalation LCs9 gt 5 0mg L Rats Eye irritation Not an irritant Rabbits Skin irritation Not an irritant Rabbits Skin sensitizer No sensitized Mutagenicity Negative Ames Test Carcinogenicity In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen possible human carcinogen This classification is given to chemicals for which there is inadequate human evidence but sufficient animal evidence on which to base an opinion of
5. carcinogenicity The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung Studies performed in animal models other than rats did not show any association between carbon black and lung tumors Moreover a two year cancer bioassay using a typical toner preparation where carbon black is bound in a resin matrix demonstrated no association between toner exposure and tumor development in rats Chronic Effect In a study in rats of chronic inhalation exposure to a typical toner a mild to moderate degree of lung fibrosis was observed in 92 of the rats in the high concentration 16mg m exposure group and a minimal to mild degree of fibrosis was noted in 22 of the animals in the middle 4mg m exposure group but no pulmonary change was reported in the lowest 1mg m exposure group the most relevant level to potential human exposures 12 ECOLOGICAL INFORMATION Ecotoxicity On available data toner is not harmful to aquatic organisms 13 DISPOSAL CONSIDERATIONS Waste from Residues Waste material may be dumped or incinerated under conditions which meet all federal state and local environmental regulations Contaminated Packaging Waste may be disposed or incinerated under conditions which meet all federal state and local environmental regulations 14 TRANSPORT INFORMATION UN Classification None Not classified
6. d ___Notllisted 3 HAZARDS IDENTIFICATION Most Important Hazards and Effects of the Products Human Health Effects There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner When used as intended according to instructions studies do not indicate any symptoms of fibrosis will occur Environmental Effects Not toxic to aquatic organisms Specific Hazards Dust explosion like most finely divided organic powders Directive 1999 45 EC Europe Not classified as dangerous Australian Information Not classified as hazardous according to criteria of NOHSC 4 FIRST AID MEASURES Route s of Entry Inhalation Skin Ingestion Yes No Possible but very unusual Inhalation Remove to fresh air If symptoms occur consult medical personnel Skin Contact Wash with soap and water for 15 minutes or until particle is removed If irritation does occur consult medical personnel Eye Contact Flush eyes immediately with water for 15 minutes If irritation does occur consult medical personnel Ingestion Rinse with water and drink several glasses of water If irritation or discomfort does occur consult medical personnel 5 FIRE FIGHTING MEASURES Extinguishing Media Water CO2 foam and dry chemicals Special Fire Fighting Procedures None Fire and Explosion Hazards Toner material like most finely divided organic powders may form an explosive mixture 6 ACCIDENTAL RELEASE MEASURES
7. skai 342 1020 Wien Telephone number 01 727 19 0 Italy Sharp Electronics Italy S P A Via Lampedusa 13 20141 Milano Telephone number 02895951 Spain Sharp Electronics Espana S A Calle Sena 2 10 Poligono Industrial Can Sant Joan Parcela 8 08174 Sant Cugat Del Valles Telephone number 93 581 97 00 Netherlands Sharp Electronics Benelux B V P B 900 Meidoornkade 10 3992 AE Houten Telephone number 30 6359500 Sweden Sharp Electronics Nordic AB Box 14098 Gustavslundsvagen 12 SE 167 14 Bromma Telephone number 08 634 36 00 Switzerland Sharp Electronics Schweiz AG Moosstrasse 2 Postfach 321 8803 Ruschlikon Telephone number 01 846 6111 Middle East U A E Sharp Middle East FZE P O Box 17115 Jebel Ali Dubai Telephone number 04 8815311 Page 1 5 SHARP MATERIAL SAFETY DATA SHEET Page 2 5 Date Issued Sep 14 2010 MSDS No F 01981 2 COMPOSITION INFORMATION ON INGREDIENTS Substance Preparation X Ingredient CAS No Proportion OSHAPEL ACGIHTLV MAK TWA NOHSC TWA Styrene Acrylate Confidential 80 90 Not listed Not listed Not listed Not listed copolymer Carbon black 1333 86 4 5 10 3 5mg m 3 5mg m _ Not listed 3mg m Charge control agent Confidential 1 5 Not listed Not listed Not listed Not listed Iron Oxide 1309 38 2 1 5 Not listed Not listed Not listed Not listed ___Amorphous silica 68611 44 9____0 1 1 80 mg m _______2mg m Not liste
8. unknown hazards and should be used with caution Although certain hazards are described herein we do not guarantee that these are the only hazards which exist
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