Karcher RM 69 ASF User's Manual
Contents
1. 1 22 36 38 Danger 3 1 0 3 3 1 D 3 3 1 1 4 3 2 2 3 3 2A Contd on page 2 IRL Page 2 6 Safety Data Sheet VKARCHER according to 1907 2006 EC Article 31 at tn Printing date 19 06 2008 Revision 19 06 2008 Trade name RM 69 ASF Contd of page 1 CAS 69011 36 5 _ isotridecanolethoxylate 8 EO lt 2 5 BB Xn BB Xi R 22 41 Danger amp 3 1 0 3 gt 3 3 1 CAS 68411 31 4 _ triethanolammonium C10C13 alkylbenzene sulfonate 50 EINECS 270 116 6 Xi R 38 41 aliphatic alcohols C12 C18 mainly linear ethoxylated butoxylated R Xi R 36 38 Warning 3 2 2 3 3 2A Additional information For the wording of the listed risk phrases refer to section 16 4 First aid measures General information No special measures required After inhalation Supply fresh air consult doctor in case of complaints After skin contact Generally the product does not irritate the skin Rinse with warm water After eye contact Rinse opened eye for several minutes under running water If symptoms persist consult a doctor After swallowing If symptoms persist consult doctor Rinse out mouth and then drink plenty of water 5 Fire fighting measures Suitable extinguishing agents CO2 powder or water spray Fight larger fires with water spray or alcohol resistant foam Protective equipment No special measures required 6 Accidental release measures Person related2. 246 mg m 50 ppm Long term value 98 mg m 20 ppm Sk IOELV Additional information The lists valid during the making were used as basis Personal protective equipment General protective and hygienic measures Do not inhale gases fumes aerosols Respiratory protection Not necessary if room is well ventilated Protection of hands chemical resistant protective gloves EN 374 Material of gloves The selection of the suitable gloves does not only depend on the material but also on further marks of quality and varies from manufacturer to manufacturer Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed For the permanent contact gloves made of the following materials are suitable butyl rubber 0 7 mm 480 min As protection from splashes gloves made of the following materials are suitable nitril rubber 0 4 mm 30 min Eye protection Goggles recommended during refilling 9 Physical and chemical properties General Information Form Fluid Colour Blue Odour Characteristic Contd on page 4 IRL Page 4 6 Safety Data Sheet VKARCHER aa eae according to 1907 2006 EC Article 31 Printing date 19 06 2008 Revision 19 06 2008 Trade name RM 69 ASF Contd of page 3 Change in condition Melting point Melting range undetermined Boiling point Boiling
3. 6 2008 Revision 19 06 2008 Trade name RM 69 ASF Contd of page 4 12 Ecological information Information about elimination persistence and degradability Other information The product is biodegradable Additional ecological information CSB value 255 000 mg l General notes The contained organic complexing agents reach a DOC elimination grade of 80 corresponding to No 406 of Annex Analytic and measuring methods and with this meet the tightened demands of Annex 49 of the revised Direction on ligid waste The product does not contain organically bounded halogens AOX free The surfactant s contained in this preparation complies comply with the biodegradability criteria as laid down in Regulation EC No 648 2004 on detergents Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them at their direct request or at the request of a detergent manufacturer Water hazard class I German Regulation Self assessment slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water water course or sewage system 13 Disposal considerations Product Recommendation Small amounts may be diluted with plenty of water and washed away Dispose of bigger amounts in accordance with Local Authority requirements European waste catalogue 07 06 01 aqueous washing liquids and mother l
4. Page 1 6 Safety Data Sheet VIKARCHER according to 1907 2006 EC Article 31 reenter enemy Printing date 19 06 2008 Revision 19 06 2008 1 Identification of substance Product details Trade name RM 69 ASF Application of the substance the preparation Floor cleaner Manufacturer Supplier Alfred K rcher GmbH amp Co KG Alfred Kdrcher Str 28 40 Postfach 160 D 71364 Winnenden D 71349 Winnenden Tel 49 7195 14 0 Fax 49 7195 14 2212 Internet www karcher com Karcher Limited Ireland 12 Willow Business Park Nangor Road Clondalkin Dublin 12 Tel 01 409 7777 Fax 01 409 7775 Further information obtainable from Department PDE D Tel 49 7195 14 2548 Fax 49 7195 14 3391 safetydata karcher com Information in case of emergency Tel 49 30 19240 2 Hazards identification Hazard description not applicable Information concerning to particular hazards to man and environment The product does not have to be labelled due to the calculation procedure of the General Classification guideline for preparations of the EU in the latest valid version GHS label elements Additional information The product does not contain any organic halogen compounds AOX nitrates heavy metal compounds 3 Composition information on ingredients Chemical characterization Description Cleaning agent Dangerous components CAS 111 76 2 2 butoxyethanol EINECS 203 905 0 R Xn Xi R 20 2
5. hall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship A product information sheet can be provided if requested Relevant R phrases 20 21 22 Harmful by inhalation in contact with skin and if swallowed 22 Harmful if swallowed 36 38 Irritating to eyes and skin 38 Irritating to skin 41 Risk of serious damage to eyes Department issuing MSDS Department PDE D Contact Frau Kuehner Herr Kurz Abbreviations and acronyms ADR Accord europ en sur le transport des marchandises Dangereuses par Route European Agreement concerning the International Carriage of Dangerous Goods by Road RID Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer Regulations Concerning the International Transport of Dangerous Goods by Rail IMDG International Maritime Code for Dangerous Goods IATA International Air Transport Association IATA DGR Dangerous Goods Regulations by the International Air Transport Association IATA ICAO International Civil Aviation Organization ICAO TI Technical Instructions by the International Civil Aviation Organization ICAO Data compared to the previous version altered 0 011 938 RM 69 15 1
6. iquors Uncleaned packaging Recommendation Non contaminated packagings may be recycled Recommended cleansing agents Water if necessary together with cleaning agents 14 Transport information Land transport ADR RID cross border ADR RID class Maritime transport IMDG IMDG Class Marine pollutant No Air transport ICAO TI and IATA DGR ICAO IATA Class UN Model Regulation Transport Additional information Not dangerous according to the above specifications IRL Contd on page 6 Page 6 6 Safety Data Sheet VKARCHER according to 1907 2006 EC Article 31 ea at Printing date 19 06 2008 Revision 19 06 2008 Trade name RM 69 ASF Contd of page 5 5 Regulations Labelling according to EU guidelines Observe the general safety regulations when handling chemicals The product has not been classified and marked in accordance with EU Directives respective national laws Safety phrases 23 Do not breathe fumes aerosol 51 Use only in well ventilated areas Special labelling of certain preparations Safety data sheet available for professional user on request National regulations Technical instructions air Class Share in NK 5 0 Waterhazard class Water hazard class 1 Self assessment slightly hazardous for water 16 Other information This information is based on our present knowledge However this s
7. range 100 C Flash point Not applicable Self igniting Product is not selfigniting Danger of explosion Product does not present an explosion hazard Vapour pressure at 20 C 23 hPa Density at 20 C 1 026 g cm Solubility in Miscibility with Water Fully miscible pH value at 20 C 12 2 1 9 Viscosity dynamic at 20 C 3 mPas Solvent content Organic solvents 0 7 Water 86 3 Solids content 13 0 10 Stability and reactivity Thermal decomposition conditions to be avoided No decomposition if used according to specifications Dangerous reactions No dangerous reactions known Dangerous decomposition products No dangerous decomposition products known 11 Toxicological information Acute toxicity Primary irritant effect on the skin No irritant effect on the eye No irritating effect Sensitization No sensitizing effects known Additional toxicological information The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version When used and handled according to specifications the product does not have any harmful effects to our experience and the information provided to us IRL Contd on page 5 Page 5 6 Safety Data Sheet VKARCHER according to 1907 2006 EC Article 31 pent erent Printing date 19 0
8. safety precautions Wear protective clothing Measures for environmental protection Dilute with plenty of water Do not allow to penetrate the ground soil Do not allow to enter sewers surface or ground water Measures for cleaning collecting Absorb with liquid binding material sand diatomite acid binders universal binders Ensure adequate ventilation Additional information No dangerous substances are released IRL Contd on page 3 Page 3 6 Safety Data Sheet VKARCHER according to 1907 2006 EC Article 31 penitent Printing date 19 06 2008 Revision 19 06 2008 Trade name RM 69 ASF Contd of page 2 7 Handling and storage Handling Information for safe handling No special measures required Ensure good ventilation exhaustion at the workplace Prevent formation of aerosols Information about fire and explosion protection No special measures required Storage Requirements to be met by storerooms and receptacles No special requirements Information about storage in one common storage facility Do not store together with acids Further information about storage conditions None Storage class VCI storage class 12 8 Exposure controls and personal protection gear Additional information about design of technical facilities No further data see item 7 Ingredients with limit values that require monitoring at the workplace 111 76 2 2 butoxyethanol OEL Short term value
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