Epson MSDS S050187 User's Manual
Contents
1. EPSON Material Safety Data Sheet 1 Article and Corporate Identification Product Epson Yellow Toner Cartridge S050187 for use with Epson AcuLaser CX11N and CX11NF Printers Manufacturer Distributor Epson America Inc 3840 Kilroy Airport Way Long Beach CA 90806 United States TEL 562 276 1369 FAX 562 997 5799 The EPSON S050187 Toner Cartridge 2 Composition Information Toner is a moist powdered formulation Ink Composition CAS No By Weight Styrene acrylate copolymer mixture 60 70 Mn Mg Sr ferrite powder 10 20 Proprietary acrylic resin 1 10 Proprietary yellow pigment 1 10 Amorphous silica 1 10 Carbon Black 1333 86 4 1 10 3 Hazard Identification 3 1 Emergency Overview Toner is a moist yellow powder that may cause eye irritation Avoid contact with eyes or clothing In the case of skin contact wash with soap and water Keep out of reach of children 3 2 Potential Health Effects Toner contact with eye may be mildly irritating See Section 11 for Toxicology Eyes Skin Toner contact with skin may cause irritation swelling or redness It is not expected to cause an allergic skin reaction See Section 11 for Toxicology Inhalation Intentional exposure to toner may cause respiratory irritation See Section 11 for Toxicology MSDS S050187 Version 3 5 USA Page 1 of 4 Release Date 10 05 EPSON Ingestion May cause upset stomach See Secti2. SON 12 13 14 15 16 Ecological Information Acute Toxicity 96hr LC 50 gt 500 mg L practically non toxic 48hr EC 50 Daphnia magma gt 100 mg L practically non toxic Disposal Considerations Used and unused cartridges are not a federal RCRA hazardous waste Disposal should be in accordance with federal state and local requirements Transportation Information Not regulated as a Hazardous Material by DOT IMO or IATA Regulatory Considerations U S DOT Hazard Class Regulated NO U S OSHA Inhalation Hazard NO In U S NFPA HMIS Hazard Rating Health 1 Flammability 1 Instability Reactivity 0 Other 0 Other Information This MSDS adheres to U S regulatory requirements and standards and may not meet the regulatory requirements in other locations This is a revised Material Safety Data Sheet which replaces all prior U S MSDS for this product This Material Safety Data Sheet contains health safety and environmental information It does not replace any precautionary language or use and disposal information which accompanies the product The information contained herein is believed to be accurate at the time of preparation but should only be used as a guide EPSON does not warrant the completeness or accuracy of the information contained herein It is subject to revision from time to time MSDS S050187 Version 3 5 USA Page 4 of 4 Release Date 10 05
3. ly irritating e Overexposure of skin to toner contact may cause irritation and in some people swelling and redness e Intentional or accidental inhalation overexposure to toner may result in respiratory tract irritation e Intentional or accidental oral ingestion may cause an upset stomach Chronic Health Hazards Use of this product as intended does not result in inhalation of fugitive excessive dust In an inhalation study with rats chronically exposed to a typical developer a mild to moderate degree of lung fibrosis was observed in approximately 90 of rats in the high concentration exposure group 16mg cubic meter and a minimal to mid degree of fibrosis was noted in approximately 20 of the animal in the middle exposure group 4mg cubic meter But no pulmonary change was reported in the lowest exposure group 1mg cubic meter the most relevant level to potential human exposure Carcinogenicity With excessive exposure carbon black has been listed as a possible human carcinogen However as engineered within this toner cartridge emissions to air of carbon black during normal printing use have not been found IARC the International Agency for Research on Cancer has found printing toners to be not classifiable as human carcinogens Toxicity Data Oral LD50 Dermal LD50 Inhalant LC50 OSHA Regulated gt 5000mg kg Rats gt 5000mg kg Rats 4 1mg L 4hr Rats Not Established MSDS S050187 Version 3 5 USA Page 3 of 4 Release Date 10 05 EP
4. on 11 for Toxicology 4 First Aid Measures 4 1 Eyes Immediately flush with room temperature low pressure clean water for at least 15 minutes Seek medical attention if eye irritation continues 4 2 Skin Wash surface areas with soap and water Wash soiled clothing before rewearing Seek medical attention if irritation continues 4 3 Inhalation Remove subject to ventilated fresh air Consult physician if necessary or if cough develops 4 4 Ingestion Rinse mouth with water Seek medical attention if stomach continues to be upset 5 Fire Fighting Measures 5 1 Flammability Flash point is greater than 230 F 110 C closed cup in accordance with ASTM D3278 5 2 Extinguishing Media Dry chemical or carbon dioxide 5 3 Fire Fighting Instructions No special fire fighting procedures are required other than breathing apparatus No special explosion hazards are known 6 Accidental Release Measures Shut off ignition sources If a spill occurs use moist sponges to wipe up toner then rinse area with damp cloth Place waste in closed container for disposal Use proper ventilation Do not dispose of waste to the sewer No eye or skin protection required during clean up if toner is not dispersed into air Wash hands with soap and water 7 Precautions for Safe Handling and Use Keep out of reach of children do not dismantle and do not incinerate cartridge Keep cartridge in dark cool dry and well ventilated area Do not store cartridges wi
5. th oxidizing agents Make sure cartridge is dry before insertion into printer housing Avoid dispersing toner 8 Exposure Controls and Personal Protection 8 1 Engineering Controls None required when cartridges are used as intended 8 2 Exposure Controls None required when cartridges are used as intended Otherwise ACGIH TLV 2003 10mg cubic meter total 3mg cubic meter respirable 8 3 Personal Protection None required when cartridges are used as intended MSDS S050187 Version 3 5 USA Page 2 of 4 Release Date 10 05 EPSON 9 Physical and Chemical Properties of Ink Formulation Appearance Moist Yellow Powder Odor Slight pH Organically neutral Boiling point Not applicable Freezing point Not applicable Softening point 120 130 C Flash point gt 230 F 110 C CC Autoflammability Over 300 C Explosive properties None Oxidizing properties None Vapor density Not applicable Relative density 1 12 at 68 F 20 C Solubility in water Negligible Solubility in fat No data available Partition coefficient No data available Viscosity Less than 5 mPa s 10 Stability and Reactivity Stability Stable Hazardous polymerization Will not occur Hazardous decomposition products None Incompatible materials Oxidizers and explosives 11 Toxicology and Health Hazards Routes Of Overexposure Eye skin inhalation and oral Acute Health Hazards e Overexposure of eye surface to toner may be mild
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