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トリクロロエチレン - クロロカーボン衛生協会 JAHCS

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1.
2. 4 13 26 2014 10 1
3. 5 993 3 26 2014 10 1 13 13
4. 6 13 pH n 99 1 0 26 2014 10 1 84 8 C 4 5 8 84 77C0 D 86 4 C 25 86 9 0 87 2 C 1 2 25
5. GHS 1 2 13 26 2014 10 1
6. 15
7. 1 0 18
8. 1 0 5 13 26 2014 10 1
9. 10 ppm 2013 25 ppm 135 mg m3 ACGIH 2014 8 TWA 10 ppm 54 mg m3 15 STEL 25 ppm 135 mg m3 0SHA 2014 8 TWA PEL 100 ppm 6 200 ppm 8 2 5 300 ppm
10. 8
11. 13 8 2 30 30 4 5
12. 259 24 8 5 26 KR 90 C closed cup 4 8 32CV7 25 25 C n 1 00 6 39 8 10 5 vol9 25 C 0 8 7 8 52 vol 100 C 9 7 9 vol 9 9 3 44 8 vol 80 3 C 8 0 vol9 6 80 3 C 79 0 vol9 90 3 C 7 7 kPa 57 8 mmHg 20 C WO 7 8 kPa 20 C 9 69mmHg 20 4 C 0 4 4 54 1 2 4 53 1 1 4642 20 4 C 99909 1 465 20 4 C A 1 5459 25 4 C 8 0 11 g 100 g H20 25 C 1 280mg L H20 25 9C V5 8 G8 log P ow 2 29 4 G6 2 61 a 2 42 970 2 61 7 logKow 2 42 2 47 SRC KowWin 2002 425 C
13. 160 9 15 1 75 2 35 1 2 4 2 57 18 21 0 1 57 2 18 2 9 384 0 1 1 6 6 2 36 70 10ppm 2014 8 2 11 1 3 2 2 4
14. 1 Y UN1710 3 6 1 3 1 UN1710 5 6 1 Il 40 C
15. PRTR Pollutant Release and Transfer Register 11 13 26 2014 10 1 1 2 2 1 1 281 5 6 4 2 4 101 7 2 2 2 1 8 12 2 9 4 9 V0C VOC 2 4 2 13 10 2 1 1 1 18 11
16. 1 1 LD50 5 400 7 200 mg kg ATSDR 1997 EU RAR No 31 2004 LC50 4 26 mg L NICNAS No 8 2000 64 mg L EU RAR No 31 2004 LC50 4 4 800ppm 7 8 kPa 20 C IPCS 2004 77 000 ppm LC50 90 ppm 4 LD50 29 000 mg kg NICNAS No 8 2000 EU RAR No 31 2004 severe
17. 2 5 12 Y 3 3 1 2 1 2 13 2 1 1 1 W 14 21 2 15 16 1 6 1 2 3 4 5 6 7 8 Vol 6 No 1 1967 1992 NITE GHS ID161 http www safe nite go jp ghs 0161 html NITE CHRIP http www safe nite go jp japan db html Maryadele J O Neil Ed The Merck Index 14th Edition PRTR 3
18. O CERI NITE No 37 2004 3 CERI NITE No 37 2004 1 NITE GHS 2 JIS Z 7250 2012 1 1 2 48 EC50 7 40mg L CERI NITE
19. 2 EU RAR No 31 2004 7 2 2A EU RAR No 31 2004 EU RAR No 31 2004 2
20. 30 10ppm 4 5 S DS S DS
21. 850 03 mg L 03 mg L 03 mg L 2 mg m 1 4 IMO UN No UN1710 Shipping Name TRICHLOROETHYLENE Class 6 1 TOXIO Packing Marine Pollutant MARPOL IBC ICAO IATA 10 13 26 2014 10 1 UN No UN1710 Proper Shipping Name TRICHLOROETHYLENE Class 6 1 TOXIC Packing Group
22. 3 13 26 2014 10 1 6 2
23. 26 2014 10 1 SDS 1 5 1993 3 1 26 2014 10 1 2 GHS 4 2
24. http www safe nite go jp apan sougou data pdf hazard sheet 96 12 pdf 18 ERI NITE No 37 2004 http www safe nite go jp apan sougou data pdf hazard hyokasyo No 37_1 1 pdf 19 4 2014 20 The Merck Index 11th Ed Merck amp Co Inc 1989 21 Richardson M L et al The Dictionary of Substances and Their Effects Roya Society of Chemistry 1993 22 C Log P 23 1995 24 RIIS SRR NO 12 23 31 1993 25 26 Merck SDS 2013 12 4 http www emdmillipore com DE en product Trichloroethylene MDA_ CHEM 111872 anc hor_MSD 27 H Sidebottom J Franklin The atmospheric fate and impact of hydro chlorofluorocarbons and chlorinated solvents Pure amp Appl Chem 68 9 1757 1769 1996
25. SDS
26. BCF 4 3 17 0 6 70g L 4 0 16 0 6 7g L 99 9 13 26 2014 10 1 Koc 188 IPCS Environmental Health Criteria 1985 Koc 68 SRC PcKocWin 2002 0 018 HGWP CFC 11 1 0 001 2 7 13 7
27. 2A 2 1B 1B 3 1 2 2 1 13 GHS 1 26 2014 10 1
28. 5 3 CHCI CCI C1 C C C1 H CAS 79 01 6 OO 2 105 TSCA EINECS No 201 167 4 4 m
29. 2004 2 2 BCF 17 BOD 2 4 2 2 49 BOD 2 30mg L 100mg L 10 V 17 OH 2 0 lt 2 9x10 2cm sec OH 5 0 x 10 cm 6 8 lt 3 x 10 23 C 6x10 cm sec 25 C 2 26 lt 2 51x 10 cm 3 8 3 5 19 4 17 5
30. 24 25 410 9C 9 18 26 420 9C08 396 C 24 25 0 566mPa s 20C 0 55mPa s 25 C 131 398 2 7 13 26 2014 10 1
31. EPA 2014 Likely to be Carcinogenic to Humans 2014 NTP 2014 R 8 13 26 2014 10 1 ECHA REACH CLP 2014 Carc 1 B DFG 2014 Category 1 causes cancer in man CERI NITE No 37 2004 Taylor et al 1B CERI NITE No 37 2004
32. Hansch C A Leo and D Hoekman 1995 Exploring QSAR Hydrophobic Electronic and S teric International Uniform Chemical Information Database IUCLID Data Set 12 13 26 2014 10 1 9 International Chemical Safety Cards ICSC0081 10 Fire Hazard Properties of Flammable Liquids Gases and Volatile Solids 1994 E dition NFPA325 11 2 15 3 No 44 http www env go jpD chemi report h15 01 pdf chap01 02 3 44 pdf 12 Lide D R ed CRC Handbook of Chemistry and Physics 79th ed Boca Raton F L CRC Press Inc 1998 1999 p 3 164 Hazardous Substances Data Bank HSDB 13 Budavari S ed The Merck Index An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 1643 HSDB 14 Boublik T Fried V and Hala E The Vapour Pressures of Pure Substances Second Revised Edition Amsterdam Elsevier 1984 87 HSDB 15 Horvath AL et al J Phys Chem Ref Data 28 449 1999 HSDB 16 JETOC 1992 17 1997
33. EU RAR CERI NITE No 37 2004 EU RARNo 31 2004 ATSDR 1997 in vivo in vivo in vivo 2 1B IARC 2014 Group 1 2013 2 B ACGIH 2014 A 2

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