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Contents
1. CO gt HO2. TiO 3 12 1
3. a op Wo wy 5 4 3 3 3 8 n p
4. E Ef H TE 4 52 4 es Pa 2 es warn ee 4 1 42 4 3 TiO 4 4 4 5 TiO 4 6 4 7 4 8 TiO
5. M O M M M M O M
6. 70 80 6
7. 1 TiO gt 400nm
8. QD 3
9. 8 153 8 2 1 PP et em y
10. 1 3 a b c
11. 4 66 OH 4 4 Es TiCL Ti a TO Ti O iso CaHz 4 TART SiCl Si OCH SiO gt Si OCH3 4 Al OOCH Al se AbO3 Al O iso CaHz TA Zr O tso CaH US Zr ZrO gt Zr OC4H B B OCH B2O3 Na NaOCH Na O 4 8 TiO
12. 5
13. 5 3 5 75 S 1 22 3 Ny gt Ar He
14. 5 6 2
15. equilibrium SKC 1 KC Slag 3 31 S a g s g C 3 41 C C 1 1 C KC 1 s
16. 1
17. 2 4 2 2 2 2 OH
18. 2 4 GT 14 16 3 CC
19. 4 62 3 aioe 50
20. ee a gt Pe 3 2 3 3 3 2
21. 100 1000uu 100h 5 4 5 4 1 ON ON dle ee ona so nn ane ee
22. TO K M Kubelka Munk Function K M
23. 4 64 CT SO 4 7 2 1
24. 5 83 2 2 5 545x 5 8 W W W 0 9394x 9 amp HETP 5 10 N M2 ZZ mm fn A a 5 12 GC 5 12 Win
25. 4 3 1 4 3 2 A M A A P A P A C C 3 3 4 C C 3 4 C C C 3C 3 5 4 C P C 3 6 C
26. 3 37 Ce 3 25 absorbed photon flux 1 0 1 0 100
27. He 3 kgcm 14 1Smlmin 76 5 5
28. 8 2 8 2 1 3 SiO 3 SiO gt AbO 3
29. 2 2 2 8 172 155000 145000 135000 CO ppmV 125000 115000 105000 95000 8 17 1 CO CO 60 000ppmV 2 2 1 70000 65000 60000 55000 CO ppmV S0000 45000 40000 35000 30000 25000 20000 0 40 0 50 0 60 0 70 0 80 0 90 1 00 8 18 1
30. H2 9 177 6 6 32 6 36 7 7 10 9 2 6 32 6 36 0 24 23SppmV hour 7 10 GT 0 240 24 144 30 000ppmV 216
31. 2 Ba OC H Ti O CH BaTiO
32. Si OC H CH Si OC H Si 2mX5m
33. 4 2 4 2 TiO TiO 2 TiO TiO 350 600C TiO P
34. 4 71 5 A re Ra kh a a TR Rl a we Ps PO EE Ne EE OO eee ee we S 1 3 2 S 3 S 4 S S S 6 X 5 73 S 1
35. CO CO CO CO 178 aa 9 1 300 2 250 S E re 200 150 100 50 0 9 2 179 NNE 180
36. As Si As As n Ga Si Si Ga Si p 3 28 n p
37. _4 6 TiO TiO TO 2 TiO
38. 2 TiO TiO TiO CO gt TO Pd TSENG CO gt Cu 9 Pt 6 6 2 6 16 TO Degussa P 25 TiO 1
39. Pd Cu Pt Pd 2 2 FD 180s 6 114 CO CH4 FD FD 420s 180s FD 420s Pd 72
40. 7 3 6 CO mv 5 FT 7 133 7 3 1 CO CO gt
41. 6
42. N TO Re 1960 RR 1970 J 1 1980 hi em es 4 2000 2 1 2 16 2 3
43. 3 X 6 5 19 X 5 20 2gsin 4 X X X X X X X
44. 3 2
45. 8 6 3 8 11 8 12 8 11 8 12 8 5 3 8 5 4 8 11 CO 2 30 000ppmV CO 0 90 0 48 68 000ppmV 2 3 CO CO s0
46. 2 8 157 8 S
47. 3 49 Dal D 3 59 3 60 3 17 3 3 56 k hex Et 3 61 B EFE Ez gt 0 7 3 6 ed 3 62 B AH AH lt 0
48. 1 1000 1 1000
49. 30 000 ppmV 3 M 7 FT TiO R 7 7 2 CO
50. CO CO CO CO 1 1 19 ED CO CO a 2 tn tN Bake 0
51. 3 16 1 TiO TiO 3 12 Pt A a a XX XX 3 12 3 44 3 16 2 MAA Me
52. 1 rn 321 3 22 3 23 3 13 2 quantum yield quantum yield quantum efficiency SD 2 mol Einstein 6 0X10 1
53. 7 2 3 9 1 5 4 2B BF 1 VR 5 5 P 7 1 Pi Po 5 82 _L cm sec sec 60zr 4 fem J cm 5 6 5 7 to fR 11 5 11 2 2
54. 1 50mmL X41 3mmO D X1 2mmT JWWA H101 40A Cu 99 90 41 3mmO D X1 2mmT X4 000mmL 0mmL HCI 200ml H2O 1 000m 4 67 3L 7 2 200ml Ti OrCaHz 4 284 22gmol TIP 0 3mol CH sOH 46gmol 2 4mol HO 18gmol 0 3mol HCL 36 5gmol 0 07mol
55. 4 60 5 4 5 5 a b c d e N N M a b 0 e 45 4 6 Deposited Film 0 Film Collapse and or Pore Formation NN Alcohol Walter evaDOraliOn D KN
56. 7 1 7 9 75 7 9 7 7 3 7 4 O CO gt TiO hv under380nm ht e 7 1 HJO h gt OH H 7 2 TiO Cu OH H2O 3h O 3H 7 3 TiO Cu HO gt 2HT 6 7 4 Ti0 Cu 2 CO 2H 2e gt CO H O 7 5 Ti0 Cu CO 4H 4e CH H O 7 6 TiO CH 2H 2e gt CH 7 7 TiO Cu CH CH gt CH 7 8 TiO Cu TiO Cu 2 CO O O 7
57. Rodriguez Pd CO Pd Pd MM CO gt CO Electron Spin Resonance ESR OT 2 CH4 ee FAERIE CH FR 2 C H 14 10ppmV
58. 3 23 3 2
59. 72 19 2 3 4mW cm 3mW cm 100W 300W
60. 26 30ml min 44 30mlmin 0 24 18ppmV hour 24 48 10ppmVhour 48 72 17ppmV hour 10 50ml min 144 3 7 138 7 6 R 1wt N 3 FD 180s FD 623K 7 3 6 Pd R Ilwt 6 W 3 7 180s 77 623K
61. 1 S TiO 1 2 3 4 15W FL 1SBLB 2 5 3 0mW cm TiO UV 101kPa 293K COz HzO 352nm
62. ii 7 iii 4 10 FB1314M s K 6 Firing Duration Time 7 Firing Temperature FT iv TiO 4 70 os 449 4 10 FB1314M 4 0 02 0 1pm D ii
63. FID He Skgfcm HL 3kgf cm Air 4kgfrcm 02 gt 1 mm 2 We RT LP FI ww Fa 5 5 4 FID 5 78 5 4 4 TCD CO CO FID CO 5 5 GL MT221 Ni
64. 2 4 59 TiO TiO TiO
65. 2 1 O 2 7 12 10 30 50mlmin 7 3 4 7 3 7 12 GT 15 50mlmin 7 4 60mlmin
66. 4 4 UV 2 5
67. CO 1 11 CO 3 CO CO
68. 1 1 1 2 1 2 1 20 30 60
69. 6 115 6 9 2 TiO XRD Gi XRD XRD 10mm X10mm X 6 23 6 24 TiO R lwt W 3 7 623K FD 180s 6 23 420s 6 24 Cu 0843 50 73 TIO gt ose lt lt 20 30 40 50 60 70 80 2 9 6 23 Cu TiO X R lwt N 3 FT 623K FD 180s 6 116 9 4
70. n n n IM yen Schottky barrier AV WN gt AV 3 9
71. 130 33 1 ER Q ee CR OE 100 1 5 km 22 1 1 3000 Q0 3X102 J 100
72. TO TiO 3 42 Roped Nat 3 11
73. 2 3
74. 3 8 S 1 M40 3000 M40 3000 3 8 3 8 4 8 8 8 3 a 0 2 TR He am Pm ET 025m 50 8 158 8 4 X10 cm cm sec cm cmHg 8 8 M40 3000 8 S 2 2
75. 90 DD OI DW 19 9 9 ec sn 2 dsin A 5 20 Bragg 4 4 X 8 2 XX X Z X 2 X 10 5 10 X X X Ce 0 5 91 X 5 21 a
76. CO CH4 400C 1
77. 7 10 7 2 CO CO 7 1 7 2 7 3 7 134 _ Ag 7 10 7 10 NA DAB cm s p kg m 0 7 mm 7 10 Na kg m s 7 1 2 EN om cm 2 87 0 109 326 css OE 00069 oem ri mm 35 7 5 10 cov g 7 2 AAlkg m s 7 2 7 3 _ 6 33E 05 1 58E 06 1 53E 00 3 83E 02 7 135 TiO
78. 1990 TO gt 1970 1984 NO 1992 1997 Graetzel 1 TiO 2 14 2003
79. 3 37 3 38 le Aa kle JIhr 3 37 v hk h D k e h 3 38 gt v g7 7 3 39 3 40 IA le Ai 3 39 d D hh Da 3 40 le h 3 37 3 38 3 37 3 40 7 k h D s k e 1h 3 41 le A bh J Dsaal 3 42 4 D IDT b 3 43 3 41 3 43
80. X X X AB A B AB X A B A B AxB2y X AJB AxByy X
81. 1 2 3 1 TO 140A m 2 3 TiO 4 6 2
82. FD FD FD CO CH4 CO CH4 FD 60 180s FD 420 540s CO CH4 FD 420s 180s 6 7 2 6 21 FD R 1wt W 1 FT 623K FD 180s
83. 10 1000A 4 4 M OR n M R M OR zH O gt M OH nROH 4 2 M OH MO 7H20 4 3 Mx nH O gt M OH nHx 4 4 M OH gt MO H O 4 5 x
84. O Fe O CO GT O GT 7 146 7 12 8 147 8 RA li SS 8 1 8 2 8 3 8 4 8 5 8 6 1 CO 3vol CO 97vol 8 7 1 CO 6vol CO 94vol 8 8 2 2
85. 3 32 ee a i TiO lt 400nm e Lh 3 10 UTV lt 200 300ns e TiO Ti Ti Ti He TO gt O O O h er ET Ti 3 11 h 0 0 3 12 2 1 2
86. 0 20 C 100 C 20C 100 C CO mmHg 8 2 NaY Na Cu CO CO 80 57 CO gt 10 36 N H O gt Pressure Swing Adsorption PSA CO CO 99 96 N 0 04 70C 49kPa 6 13kPa HIRAI Cu 10g 101kPa 20C CO N gt 9 1 latm 20 120C 20C 53Pa CO
87. S 3 5 1 5 2
88. 10 30 50mlmin 4 7 7 10mlmin 30mlmin 7 6 40 1 3 30mlmin 13 30ml min 1 3 0 24 158ppmV hour 24 48 20ppmV hour 48 72 38ppmV hour 87 84 50mi min 0 24 24 48 48 72 6SppmV hour 61ppmV hour 44ppmV hour 6 28 17 30mlmin 1 3 50mlmin 17 7 139
89. 18 000ppmV CO 90 CO 12 5vol 2 2 1 2 8 164 CO ppmV 4A X 0 40 0 50 0 60 0 70 0 80 0 90 1 00 8 11 CO CO 30 000ppmV CO ppmV 8 12 CO CO 30 000ppmV
90. LL 2 3 2 3 C O 0 CO O O GT 15 O gt 15ml 7 7 GT 15 O gt 153ml 40 mm X30mm OC HOC 0 C O C 0 ul 1 20 gt HJO 6 HC HCOH HOCH HOCH HOCH CH OH HOH CH OH 2 3 L ascorbic acid dehydro L ascorbic acid 2 3 diketo gulonic acid 778 GT 7 142 7 4 3 GT
91. 3 3 Photon 4 3 1 4 UV Ultra violet 4 10 400 nm 6 3 7 s 4 nm c 2 99792458X10 m s 6 6262X10 js
92. 1 200ppmV 1 400ppmV 17 6 13 2000 1800 1600 1400 ppmV 1200 1000 800 600 400 200 0 R 0 M d 0 0 M d R N 1 N 3 N 3 5 N 6 13 R 0wt FD 420s F7 623K 6 106 2000 D CO CH Total 1800 1600 1400 1200 IppmV 1000 800 600 400 200 R R 1 M d R N 3 N 3 N TH es Ss 6 14 R lwt FD 420s FT 623K 6 S 4 CO 6 13 6 14
93. FD 420s XRD FD FD FD 1 CO FD 1 CO 6 9 4
94. 6 2 6 97 QD CO HzO H20
95. Pd 6 122 6 10 24 72 CO gt 6 10 1 6 29 Pd R 1wt M 1 FT 623K FD 180s 6 7 384 CO CH4 Total 120 CO
96. 6 GT CO GT L 7 9 CO CH Total 388ppmV 45SppmV 67ppmV gt G
97. K M x 3 28 3 27 3 28 2 3 29 TiO
98. CO Fe O FeCO FeCO 7 12 H H2O HH 100ul HO 5 66X10 mol CO 2 53 x10 mol 2 8 19X10 mol HO CO gt H 69vol GC GL CP 4900 H H H
99. 3 TiO 4 8 TIP CHsOH 10 ii CH OH HO HCI 1 2 TIP C2HsOH Qi iii G G 10 2 1 1
100. TiO CVD 4 6 1 1 2 1 2 CVD
101. 450nm TO 0 TiO 0 TIO TIO 3 10 gt lt CE 3 39 J 39 EE Y 3 10 2 1
102. 4 5 THiO TiO 1 5 TIO 1 TiO 2 4 58 THiO gt 3 TiO 100C TiO
103. 0 24 24 48 48 72 0 24 24 48 24 48 48 72 0 24 15ppmV hour 24 48 13ppmV hour 48 72 8ppmV hour 3 15 13ppmVhour 13 13 8ppmV 38 26 CO gt CO 0
104. a b lt 1 3 1 4 1 1 2 3 4
105. 20C CO N 9 1 1 CO CO 8 1 9 8 151 8 1 CO CO y C a eee ar 300 400 16ml g STP 21 0ml g wih ys 2 in Le TA 24 1ml g 1mol 60min 8 3 Rl 8 3 1 MS 7 ee i
106. ZrO SiO Zr iso C Si OC H ZrO SiO 5 1
107. 2 6 96 NA HOE 110L X34O D X 2T ISW UV lamp 436L 26O D yt ml TR Ea hak A A TIO 50L X 41 3O D X 1 2T 90L Xx 90W x 20T 6 1 6 2 6 2 2
108. 1 1 1 pe 1 2 1 2 1 hv hy 3 2 3 20 3 5
109. 3 33 3 8 3 12 2 TiO 1 ps TiO 3 9 0 H O 3 34 O e gt 0 0 2SV 3 13 HT e H 0 4V 3 14 O gt H O
110. 6 15 6 5 2 Pd TO TiO 6 15 Pd TiO 6 107 6 6 6 6 1 TiO gt Degussa P 2 TO
111. Ground state Excited state Excitation 3 8 E E hv 3 8 3 2 Ej 3 8 3 2
112. 4 6 7 6 0 14 CH4 CH C gt H4 5 15 NanciCHROMAT324 15 02 DEC 04 2006 Ssmple 541 ATTN 32 POSI 0 6 00 CH6 055 C2B6 1 514 C2H4 080 Cenc Leve Cajc NMetbod 4 Ert Std PAiji 00000 PB 00000 NO NAME RT AREA HARY CONC EIGHT CH4 1 055 932664 97 038 50838 2 CZ2M5 514 533875 96 1555 100039 CEB4 2 090 503969 97 107 7615 4 TOTAL 1576508 292 4043 229099 5 15 1 2 3 CHL4 CH4 CH RT 5 5 2 RT min l CH
113. FT EI 4A En 5 6 a gt A hi Ley i Em i 4 2 MN 7 7 80 S S S S 1 5 8 5 9 5 9
114. 1 2 2 1 4
115. 1998 p 69 71 2004 p 59 2005 p 36 37 2 16 p 14 1998 p 29 dt 182 3 11 3 2 p 74 76 3 12 3 2 p 76 80 3 13 3 2 p 53 56 3 14 3 7 p 120 122 3 15 2000 p 8 3 16 1 9 p 69 77 3 17 2000 p 18 19 3 18 3 7 p 95 106 4 4 1 3 10 p 69 77 4 2 1 12 p 23 29 4 3 HB II 1995 4 4 2001 4 5 1 12 p 29 4 6 3 8 p 75 76 4 7 1 12 p 45 4 8 3 10 p 105 4 9 3 10 p 106 4 10 H Dislich and E Hussmann Thin Solid Films 77 1981 p 129 4 11 3 7 p149 152 4 12 C J Brinker G
116. 5 2 5 2 FID Flame Ionization Detector ECD Electron Capture Detector S N O FPD Flame Photometric Detector KR P MS Mass Spectrometer 4 2 77 S 4 3 Flame Ionization Detector FID TCD FID TCD 5 4
117. C 1 CO Mg 1 2 Sw a ED 1 3 1 2 2
118. EN 2 2 CO CHL etc 2 3 3 21 3 wma cs ee ee ng RY ea we as Oo EE mana Ta 3 1 3 12 3 2 3 13 3 3 3 14 3 4 3 1S 3 S 3 16 3 6 3 16 1 3 7 3 16 2 3 8 mn p 3 17 3 9 3 10 3 11 3 3 1 39
119. O O 2 O Fe 1 7 144 2 2 1 Fe CO Fe CO FeCO HL 7 12 Fe CO gt HO Fe CO gt HO gt FeCO3 HD 7 12
120. 11 ppmV hour CO CH 60s 2 79 300s 6 77 540s 8 00 3 300s 7 420s 11 340s TiO gt TO HO 1 wt 6 3 0wt 11 TiO ppmV hour 1wt 3 0wt 11 60s 1 01 300s 1 43 1 0wt 11 1 6 CO CO gt CO 125 000 ppmV 12 Svol CH4 53 000 ppmV 5 3vol
121. 2 2 8 7 1 8 6 CO 60 000ppmV 6vol CO gt 940 000ppmV 94vol 1 8 9 8 6 1 CO 6vol CO gt 94vol 1 15 3 x 10 cm cm sec cm cmHe 2 gt Cn NS z O O Ps kPa 00 VO P SO y Pn 77 50 73 00 70 00 65 0 62 0 60 0 58 0 56 0 53 0 51 0 48 0 46 0 43 Fs ml min SS 9 25 50 75 100 1 a 125 150 175 200 225 9 F Fr 0 10 0 90 ee CO 1 CO 2 6 vol 8 7 2 8 13
122. W Pd R 1 Pd d W 1 3 3 591ppmV 7 137ppmV 98 R 1Iwt M 3 77 623K FD 180s Pd Pd TiO R 1lwt W 3 FT 623K FD 180s 85 6 113 7500 gt co CH 6000 3 Total 4500 3000 1500 R 1 Pd d 1 Pd d 1 Cu d R 1 Cu d R 1 Pt d R 1 Pt d FD 420s FD 180s FD 420s FD 180s FD 420s FD 180s 6 22 R lwt N 3 FT 623K 6 8
123. 3 15 TiO 3 14 3 11 N ry gt Ee 1 a05 Bg 3 11 3 11
124. CO gt FD 420s W Pd Cu Pt 3 Pd FD 180s 3 CO CH4 Pd R Ilwt M 3 FD 180s FT 623K 72 7 137ppmV 85 c b FD CO gt
125. ra ra 2 3 14 3 40 Substrate Adsorption 2
126. 8 4 2 8 154 8 4 A A A i eT 1 Re M C 8 5 i te Yn Fim 4 3 29 Cr 9
127. CH Cu CH4 Cu CO 1 Pd CO gt 6 5 CH OH HO gt CO 3H 6 5 CO Iwasa Pd Zn HCOOCH3 Pd CO
128. 1 3 30 2 3 30 ye 3 30 1 100 0 1
129. 7 11 7 141 4F 3Ox 6H O 4Fe OH 7 11 Fe O z HzO HO 0 7 4 2 GT GT 7 7 GT 7 8
130. C H O 6 3 6 3 6 2 3 6 4 6 6 20mm 30mm O
131. CO CH4 C H4 C gt H CO 30 000 ppmV CO 97vol CO 3vol CH4 100ppmV CH 100ppmV CH4 101ppmV 1 CH4 100 2 3 1 2 4 3 ax 2 13 CO 4 CF CF 5 11 CF CO S 85
132. He H 300V CH CH O CHOT e 1 HH HO 10
133. 6 2 6 2 1 CO H O CO HO 2 6 1 6 2
134. FD 180s 3 16 6 10 3 TiO gt TO CO FD 420s FD TiO TiO
135. N 3 6 105 1 500ppmV 1 700ppmV 13 6 14 TiO TiO gt R lwt M 7 77 Pd 1 M d R 1 W M 5 W 5
136. 0 80 2 1 0 80 0 51 2 0 80 CO 12 Svol9 b 2 a 2 2 2 0 50 0 70 0 85 0 81 CO 12 5vol 0 60 0 84 CO 150 000ppmV 15vol 2 1 2 2 2 Pd R Ilwt NM 3 77 623K 7
137. ZnO TiO gt NiO CuO ZnS CdS HgS CdSe ZnO 1972 1969 1972 Nature 1973
138. 2001 3 2007 4 PH 1861 0 6 0 2C 2 0 1 C 20 0 1 0 2m MK 2 0 1 0 25 m 2 30 21 540 970ppm 1990 2100 1 4 5 8 C 2 1 0 3 C 21 oe 1990 2100
139. gt 6000 i 5000 CH4 Total 4000 3000 2000 1000 0 0 24 48 72 96 120 144 168 192 216 240 264 288 312 336 360 384 hour 6 29 R 1 Pd d N 1 FT 623K FD 180s 6 123 6 30 6 32 Pd R lwt W 3 77 623K FD 180s 6 7 600 CO CH4 Total 6 30 CO 6 31 CH 6 32 240 24 240 72 3 1 6 30
140. S S 2 tr 10 A B C 3 6
141. Pd CO Pd 6 12 6 S 3 6 13 6 14 Pd TiO gt 2 0wt W 1 3 3 7 420s 77 623K Pd R 0 M d R 0 72 CO CH 6 13 W M 3
142. V Vi VetVn V Vp 3 6 3 31 L1d 1 1 ly vi RA 4 9 3 7 3 12 5
143. TiO CYP 4 16km 0 46 100 10 4 10 1 FeTiO3 TiO TiO IV TiO gt 5 TiO TiO
144. cm7 s De 5 2 X tx s s Qa 5 3 mol s cm s
145. CO a FT 323 623 723K CO R 1w9 M 3 FD 420s F7 623K 323K 723K 623K FT b Pd CO gt
146. CO CO CH C H4 CH s TiO wte4 3 SEM EDX TiO gt ppm V hour 1 3 29 1 7 80 1 11 139 SEM EDX AFM
147. 1 2 3 1 2 1 1 2 4 6COz 6HO 6Oz C Hi2O CO HbOG2H CO CaCO
148. oo 107 6 6 1 om 107 6 6 2 D ee 107 6 6 3 ooo 109 6 7 et 111 6 7 1 oo 111 6 7 2 ooo 111 6 8 et 113 6 9 114 6 9 1 114 6 9 2 TiO gt XRD 115 6 9 3 oo 119 6 9 4 re 120 6 9 S CO ii 120 6 10 122 6 10 1 122 6 10 2 ho 12S 7 pe 130 7 1 131 7 2 ie 132 7 2 1 ooo 132 7 2 2 132 7 3 eo 132 7 3 1 133 7 3 2
149. CO gt 6 CO 1 RITTE CO 20 2 CO gt N 1 000 5 000 CO 50 8 3 3
150. ooo 4 1 3 oo 7 1 4 io 8 1 5 eeeeeeeeeese sseseseee see ses res ee ee seeeeeeeeeeeeeeeeee see see 00000 9 1 6 eeeeeseseseseeeeeeses eeee ee see eeeeeeeeeeee ee ee eeeeeeee ee eeeee ne 10 2 12 2 1 2 2 2 3 2 4 2 5 RN A 13 BD RGR ESE 13 SE A 16 uuueeeereesesrseeeessseessseeeeessseressereseetessseesesttesssetsseetesersesttsssesessoeeersseereseersesereseeee 18 eumeeeererrsseeeerrreessessseseeeeesssssesseesesessomeeerreereereeeseseeer 18 3 21 3 1 ememaeeererseesseeceteceesseesseesserseesseeeseeersereereserseerretessseseseteseteseeeseeersesesestesseseeseeresteseeeees 22 3 2 meeeeereersesserserssereeesseesserseesseseseersseesereseseeesseesteetesereeerretereetesereesteeeesersseseereeeeeeeeeee 23 3 23 3 4 tm 24 3 S OD eeeeeeeeeeeeee ee ee eeeee seeeeeee see ee ee 26 3 6 eos 26 3 7 eeeeveeeeereeeessseseesssssseessreseesseeseessrssseesessssesesesesesseeeesreeeesrrreeesesrereeeeeesseeesereeeeess 26 3 8 n
151. O O gt 7 4 1 1 FeO FexO FeaO 79 Fe2O Fe FesO Fe II HI 2 II III FeO FezO 300C Fe Fe CO NaCl
152. 1 2 1 2 1 400mlmin CO 17 000ppmV 2 50mlmin CO 60 000ppmV 420mlmin CO 22 000ppmV 2 90 8 170 160000 150000 140000 CO ppmV 130000 120000 110000 100000 90000 80000 70000 60000 0 40 0 50 0 60 0 70 0 80 0 90 1 00 8 15 2 CO CO 30 000ppmV 1 0 80 65000 S CO ppmV LA LA S0000 45000 40000 35000 0 40 0 50 0 60 0 70 0 80 0 90 1 00 8 16 2 CO
153. R _ kr KplDsa Sp Jo ol 3 54 Ur kpDD Vk np 1 ks kr Spo 3 55 Rp A DD 3 56 ko D 3 50 Langmuir Hinshelwood 3 56 Rp kp Kp D app 3 57 D lt lt D 1 Rp 1 D 3 17 1 3 56 D 1 lt lt Kp D Rp D 3 58 D D haot 3 58 3
154. 2 2 8 167 1 LN 1 LA Eo al 1 joa 0 amp Lb CO CO SS O mssskg 8 14 2 8 8 2 8 7 8 8 2 8 7 1 8 8 2 1 0 80 2 0 50 0 90 8 8 2 CO CO 8 5 3 1 CO 3vol9 CO 97vol9 2 1
155. 3 21 gt mol 1 TON 1 100 3 22 CA 3 23
156. 8 7 1 CO 6vol CO 94vol 1 0 80 0 51 8 V 165 30 000ppmV CO 60 000ppmV CO 2 2 CO 60 000ppmV 6vol CO 940 000ppmV 94vol 1 2 2 2 2 2 CO 6vol CO 94vol 1 CO 12 5 2 2 CO 6vol CO 94vol
157. 2 8 9 8 V 159 Oi 1 cm cm sec cm cmHgs 2 cm cm sec cm cmHg 4 Im 6 mm Pn kPa Pi kPa Fr ml min Pu ml min ml min xr 1 ppmV x 1 ppmV yp 1 ppmV Fe Xe F
158. 41 11 766 770 1993 1 15 L Inoue A Fujishima S Konishi and K Honda Nature 277 637 1979 1 16 Vol 39 No 1 24 31 1997 1 17 Vol 35 No 8 506 12 1993 1 18 21 2001 p 27 1 19 CO H16 1 20 TiO CO gt H16 2 2 1 2000 p 6 9 2 2 2 1 p 49 2 3 1987 p 71 74 181 2 4 2 5 2 6 27 2 8 2 9 2 10 2 11 2 12 3 2 14 2 15 2 16 2 17 A Fujishima and K Honda Nature 238 37 1972 T kawai and T Sakata Nature 286 474 1980 K Domen S Naito M Soma T Onishi K Tamaru JCS Chem Comm 543 1980 M Anpo N Aikawa Y Kubokawa Che M Louis C Giamello E J Phys Chem 89 5017 1985 R Cai Y Kubota
159. 2006 10 2 10 2 2 520nm 1m 180mh 2 1 2 1 2 1 3 214 2 13 Tvon Grotthus Grotthus Draper E Becquerel ZnO J Stark Titanium Pigment
160. CO O gt N CO gt SS 100 90 EK K S 70 60 50 40 30 20 10 0 6 7 72 6 100 6 8 CO 72 CO CH4 CH4 CH
161. CO gt Pd lwt W 1 FT 623K FD 180s 96 M 3 3 1 312 328 a b CO
162. Pix Dy 8 8 Fp 1 y6 O40 Opr 1 x6 Pl yp 8 9 Fp xo yp 4 8 8 8 9 yp _ Qi pn xo Piyp 8 10 l y Mi 1 xo pl y 2 h 1 2 Jp e x 7 8 11 LI CI f xr XO 8 12 Fr FotFpsFrxt Foxot Fpy x 8 13 Jp a xe Gy 8 13 1 y xe Q y 7Y 0 70 8 13 y D2 lt DD yo tOUWT lt 8 14 8 161 a DG Jr1 Na 10 6 x 1F 48 a lo yp i 8 14 8 S 4 24
163. 24 0 24 96 144 120 144 192 CO gt 240 6 126 CO il CH4 Il Total ppmV hour mm _24 8 72 96 hourl 6 33 R 1 Pd d N 1 FT 623K FD 180s 6 33 M 3 CO CH4 6 34 6 36 6 30 6 32 28 671ppmV 528 15 307ppmV
164. CD 0 4 4 Ti OH TI OH Ti Ti OH OH OH TiO TiO gt Ti ICO H OH uu 7 Op OR 4 4 TiO 7 4 4
165. 24 4 2 17 1 5ugyl
166. 8 13 0 80 2 8 166 0 90 0 43 CO 190 000ppmV 0 70 0 80 2 1 0 80 0 51 2 0 80 2
167. HCOOH CH OH CH4 2 CO CO 2 1 2 2 3 HO H CO 2 20
168. ero 83 S 6 2 ooo S4 S 7 te S6 S 8 X oo 89 5 8 1 X eeereeeeeeereseeeseeseeseeseeseseesssesoresesessersessessssssseorsesseseeressesserereeseesessesseseereeeeereerreeeeeeeeereeee 89 5 8 2 X DD e see seee seen ee 90 5 8 3 Scherrer DE EIT TT 92 5 6 0 6 1 95 6 2 TT 95 6 2 1 esse 95 6 2 2 omoenoeeeoenoneeeneeesoeoeeeeeeseeeeseseeeseseeseeseseeeeesseseseessessesesossoreseeseeeeseereree 96 6 2 3 esses 97 6 2 4 99 6 3 100 6 4 TOTmT 101 6 4 1 io 101 6 4 2 101 102 6 5 gt ee 103 6 S 1 em 103 6 S 2 ireoroe 104 6 S 3 mmt 104 6 5 4 106 6 6
169. 5 74 5 1 2 2 1 2 3
170. CO CO 2 12 i eA eh A NE NL NL KN dL Yama CC Ra as rer am ra ae 2 1 2 2 2 3 2 4 2 S 2 13 2 1 CO gt 23 2 2 HCI
171. 0 16V 0 046V V sss 2ma a 2 0 3 0 4 0 3 6 3 11 2 3 7 ls lp
172. X X 2 9 0 180 X 5 21 b X NA a X 5 21 X 5 22 X X X X X X 5 23 XRD
173. 6 8 ppmV 2000 6 8 72 6 3 UV lamp 99 99Svol CO 15
174. 7 1 1013 f 1fs lt 50fs 10 12 ps lt 260ns 50ns 0 O 103 O BBO 109 8 103 ks 7 1 7 7 1 ns fs 72 9 97X10 260fs CO 2 300ppmV CO 260fs
175. sotherm Langmuir 3 1 1
176. Shell CO 5 CO CO 8 10 CO CO gt Shell 8 6 2 8 5 1 CO 3vol CO 97vol 8 163 8 5 1 CO 3vol CO gt 97vol Mm 9 0 mm 1 cm cm sec cm cmHg kPa kPa O 22 51 Py 1S133 ka 90 83 86 33 82 33 77 83 72 83 ka y PP 0Oe0 037 054 05L048 200 CO 2 8
177. 6 98 110L X34O DX 2T 1 PD 2LX480DX3T 15W UVlamp ee 436L X 26O D K 1 20 G30 CO y FN 1 90LX90W X20T TiO 50L D X 1T 0L X 41O D X 1T 6 4 6 6 99 0 6 6 6 2 4 6 7 CO 72 TCD GL GC353B
178. MO Molecular Orbital MO Highest Occupied Molecular Orbital HOMO we Conduction band Valance band Multipliciry M 2S 1 S 1 2 1 2 S 1 2 1 2 0 M 2s 1 1 1 2 172 1 2 1 2 S 1 M 2S 1 3 M 1
179. 2 19 3 1 2 3 CO HO CO H 0 C H O06 0 479kJimol 2 1 479kJ mol GE HzO HzO
180. R 1 Pd d 2 000ppmV R 0 1 40 49 N 1 3 2 CO 6 20 Pd Cu Pt TiO TiO R 1wt W 1 3 FD 420s FT 623K 6 20 72 CO CH 6 110 6 19 CO 6 20 3 000ppmV 6 19 R 1 A 1 R 1 N 3
181. 6 104 6 5 2 6 12 H2O 220ml CHjOH 99 17 5ml Pd 1 000ppmV 12 5ml Pd Pd S0ppmV 250ml UV lamp 352nm 3mW cm 6 Pd 3
182. A 8 149 8 2 2 8 1 CO CO CH un ml 20 8 1 2 1g 288K 8 150 1atm 1kg CO 66L 3 8 2
183. CO CO 10mlmin 5 81 X10 cm s 30ml min 8 1 74 Xx 10 cm 0mllmin CO RAR i 50ml min 175ml min 1 02cm s CO 7 4 O O CO Fe
184. Singlet state S M 3 Triplet state T So So HOMO LUMO S S S S Ti Si Ti SG Ti S T S12 T ST 3 6 TiO 1 4
185. 5 16 UIT 150 UVD S365 310 390nm 0 00 99 99mW cm 0 50 1 5 16 UIT 130 5 17 1 6 25mm 3 1 2 1 12 5 87 12mm 110L X 34O D X 2T 7mm UV lamp 436L X 26O D 5 17
186. TO a c a TiO gt 3 iv TIP 4 68 284 22g mol 0 3mol 83 2g 6 R 85 2g R 1wt 0 83g b 30 c TiO iv
187. dh ce Qe piy 8 15 dF 9 a0 y 919 _ 6 iF 8 17 8 6 1 CO 3vol CO 97vol 8 6 1 8 9 1 __ 2 1 KOR hd ye 6 CO CO AN LO 7 8 9 1 8 162 8 9 CO CO 6 30 000ppmV CO 30 000ppmV 3vol CO
188. 4 63 4 7 4 7 1
189. 3 3 le h 3 42 k Asa kt Dal 3 48 3 47 Rp pq 3 49 3 49 D 12 3 49 D Sp D D gt D Sb Ds 3 50 Ky _ Dal 3 51 DJISp D Sp D Splo Sp Sp Da 3 32 3 51 3 52 D EPp 3 53 1 ID 3 49
190. CO gt CO 3vol CO 97vol 0 90 0 48 68 000ppmV 6 8vol 9 176 2 3 CO 12 Svol 2 2 CO 6vol CO 94vol9 1 2 2 CO 6vol CO 94vol 0 90 0 43 CO 190 000ppmV 19vol 0 70
191. 19 Grotthus 1818 Stark Einstein 90 1922 Frank Condon O N20 ZnO N20 1971 ZnO 1865 TiO 1917 TiO gt 1940 20 1965
192. 20 30 40 50 60 70 80 20 1 6 24 Cu TiO X R 1wt N 3 FT 623K FD 420s TiO gt 1 0 02um Cu Cu TiO 12 000 TiO 4 TiO 383K TiO HO CHsOH TiO TiO TiO TiO XRD X Rigaku RU 200 X CuK 40kV 120mA 2 min TiO XRD Cu
193. 4 7 6 4 7 TiO 4 69 HO 0 3mol CH OH 1 2mol HCI 0 07mol Ti O i C HL 0 3mol CH OH 1 2mol 4 8 4 i 449 3 LINEAR HEAD 2LF2SN 2GEAR HEAD 2GN10XK SPEED CONTROL MOTOR MSM206 411 1 5mm s 900rpm 1 0 25mm s 120rpm
194. HCI HCI iv TiO TiO TiO
195. pn 3 4 n p pn PA pn Ch 3 9 E MM lt 7 NN A a ao p on 3 4
196. 3 10 n p 3 5 n n n Si n n 3 29 n
197. Fischer Fischer 3 3 CO CO CH H O 2 lll 3 45 CO CO gt C H HO 2 3 17 3 13 A D CB _ 0 SV 0 42V 2 7V 1 VB
198. M O M M O M 1 0 1um i gt
199. 3 3 3 4 TiO phase
200. Pd XRD FD 1805 6 FD 420s TO d 175 p ED FD FD CO Pd CO gt CO CO gt b
201. 1 000ppmV Cu 1 000ppmV CO gt 6 4 3 TiO Z 1wt NM 1 3 FD 420s FT 623K 6 17 6 5 2 6 18 Pd Cu Pt lt 6 108 Pd 6 16 TiO TiO TiO es te OU
202. 3 TiO 70 300nm 1600C 650C
203. CO CH 6 129 250 2 li 1 E200 I1 NX lt 150 xg 100 50 0 LE i la LL ll 24 48 72 120 144 168 1 216 240 312 ss 456 528 600 50 hour 6 36 R 1 Pd d N 3 FT 623K FD 180s 7 130 7 i Se es tM a a da dd ee 7 1 7 2 7 3 7 4 7 5 ce 7 131 7 1 1 CO gt CO
204. FD 180s 6 1 6 4 CO H e CO 2 H e gt CO H O 6 1 CO 8 HT e gt 2H O CH 6 2 2CO 12 H e gt 4H O C H 6 3 2CO 14 HT e gt 4H 0 C H 6 4 CO CH4 CsH4 C H FD 420s TiO CO CO 6 120 TiO 2 CO
205. M 3 R 0 Iwt FT 523 623 723K FD 300 420s 72 CO CH4 6 9 R 0wt 6 10 1wt N 3 R 1wt FD 420s 77 623K CO CH4 CH4 CH 4 000ppmV CO 3 800ppmV 6 9 77 523K 7 420s 3 400ppmV CO 3 300ppmV FT FT FD 300s 420s FT 300s 77 6 102 523K 523K 6
206. TiO CO 6 20 Pd 4000 CO ucr Totm 3000 Ota 2500 2000 1500 1000 500 0 R 0 R R R 1 Pd d R 1 Pd d N 3 1 N N N 3 R N 6 19 FD 420s FT 623K 3000 CO oa 2500 D CH4 Total 2000 1500 1000 500 1 Pd d R 1 Pd d R 1 Cu d R 1 Cu d R 1 Pt d R 1 Pt d N N 3 N 1 N 3 N 1 3 R V 6 20 3 FD 420s FT 623K 6 111 6 7 6 7 1 2
207. 80ppmV hour 48 72 Fe 100 90 80 70 ppmV hour 60 50 40 30 20 0 24 48 72 hour 7 10 O R 1wt Pd d N 3 FD 180s FD 623K 7 4 5 7 11 7 3 4 Fe GT 15 GT 15 8 28 Fe 26 Fe GT 1 1 2 8 Fe 1 27 2 25 GT 15
208. 101kPa 293 298K CO 100pul 0 UV lamp 6 101 24 72 6 4 6 4 1 4 1 W 2 FD 3
209. 9 9 1 URL http www mizuho ir co jp 9 2 1999 p 27 185 186
210. TO AFM ii X EDX CI TiO gt 573K FD Gii X XRD FD X Cu CuO TiO gt Ti FD
211. I Iversl YR Master s Thesis 1 IIHHHHHHHHHHL Speclal gt CO2 Speclal IIHHHHHHHHHHHHHHHHHL UE 2007 HHHHHHHHHHHHHHHHHHHHHHHH http hdl handle ne 10076 9064 18 2006 18 CO 2007 19 2 6 ee 1 1 sseseeeeeese sse sse see see ee see se ee ee seeeeeeee ee ee nes ee 2 1 2 e 3 1 2 1 7 eeeenssnesnssnsensoneeeeseeeeseseesesesssesnssssnsns0ennnnn0nn00nnnnn 3 1 2 2 eo 3 1 2 3 ooo it 4 1 2 4
212. 5 18 UV lamp UV lamp 1 rs 23mm 30mm zemw D 2 lL 5 18 12 UV lamp UV lamp UV lamp 3 5 4 5 9 5 6 5 9 total UV lamp 1 88 5 4 Law is se EI EE 5 5 VC ave 5 7 3
213. 7 000ppmV 85 6 9 6 5 4 FD Pd CO Pd FD Pd CO gt 6 9 1 FD CO CH i
214. CO CO gt CH4 FID FID CH CO CO CO 450 100 3 5 S 4 5 FID FID CO 5 5 2 CO CH 1 2 5 6 3 7 FID FID 5
215. tx CO CH4 C2H4 He Total 7 9 72 7 4 4 Fe GT 15 O Pd lwt W 3 FT 623K FD 180s 7 10 3 0 72 GT 15 7 143 O Fe O gt 0 24 0 24 3 75SppmV hour 24 48 Fe
216. v Dislish xy x 4 1 273 _ 094 0 I 0 ZrLv6 pg hi 4 1 Pa s p kg cm g m s xy Nm
217. a
218. 3 7 3 24 1 1 CO 100 400 760 10000 3 1 3 4
219. 200000 180000 4 160000 X 140000 CO IppmV 120000 100000 80000 60000 0 00 0 10 0 20 0 30 0 40 0 50 0 60 0 70 0 80 0 90 1 00 8 13 CO CO 60 000ppmV 8 8 2 2 CO 3vol CO gt 97vol 2 1 2 2 2 8 8 1 2 8 14 2 1 1 1 2
220. 26 50mlmin 10 Pd 34 50ml min 17 50mlmin 7 140 CO CO 0 Im 1 53 X10 s 9 84s 6 54X10 1 02cm s 7 3 1 50ml min 2 87cm 2 90X 10 cmys CO CO gt CO 6 54X10 cms CO 1 02cm s CO
221. 5 8 3 5 9 3 a 89 3 86mW cm 3 63mW cm 3 753mW cm 3 UV lamp 2 3 2 35mW cm 2 21mW cm 2 27mW cm 3 75smW cm 38 S 8 X X Ray Diffraction XRD S 8 1 XX 6
222. 7 7 R lwt Pd d N 3 FD 180s FD 623K 7 3 6 7 3 4 7 3 5 Pd 2 26 54 30mlmin 44 1 3 30ml min 10 17 10mlmin 65 7 4 72 7 4 ppmV 72 10mMmin 30ml min 50ml min 869 Pd 869ppmV 50mlmin 1 080ppmV Pd 3 88SppmV 30ml min 3 672ppmV 7 6 7 7
223. CH CH AREA CONC 10 HEIGHT 5 86 5 3 CF CF CONCIAREA CO 1 64 X107 CFF CONC S 7 15W UV lamp
224. sec x kmol m m kPa IUPAC m kmo s m kPa cm STP cm s cm cmHg 9 cm STP 1 0 Barrer lx10 cm STP cm scm cmHg 1Barrer Fick Henry QO D S 8 2 D cm sec S
225. 2
226. 501mhl min 72 349 13 O O gt Fe GT 72 Fe 26 Fe HO CO O GT O 8 a 1 CO 3
227. A Einstein S Teichner TiO H Gerischer ZnO A J Bard Kolbe J M Lehn RuCb S Sato J M White J M Lehn TO NO TiO 2 15 ML Graetzel
228. HETP 1 HETP S 6 S 6 1 0 1 84
229. lt 4 53 4 1 TiO TiO gt TiO TiO 4 2 HO 4 1 leVl
230. 2 1 8 17 8 18 CO CO 8 15 8 16 2 0 50 0 70 0 80 0 90 D CO
231. 140 000ppmV 0 80 0 90 95 000ppmV 8 16 0 50 0 70 CO 58 000ppmV 2 CO 0 80 0 90 CO 44 000ppmV CO 0 30 0 70 0 80 1 CO CO 0 80 0 90 CO 2 1 1 0 80 CO 17 000ppmV 2 0 50 CO 60 000ppmV
232. 3 16 6 9 5 CO 3 16 9 CO Pd Pd TiO CO 6 121 CO
233. 40 000ppmV 2 2 1 42W 2 84W 2 500ml min 1 0 80 0 30 2 0 30 0 85 CO 14vol 50mlmin 1 1 4Wh 5 040J CO 2 0 37kg CO gt kWh 1 18X10 mol 14vol S0ml CO 2 91X10 mol CO 2 12 63MJ m W 82J CO 41 61
234. 67 OO OD 2 1 2
235. 4 2 TiO 30 4 2 TiO TiO TiO UV TIO TiO 43 4 3 4 1 TiO 2 4 900 4 2gcm 3 9g cm ZnO 5 47g cm
236. 7 136 7 3 2 7 4 MP 1973D 32TR 6 387 14 6 CO 7 5 7 3 3 5 90ml min CO gt KOF
237. 3 7 3 3 3 27
238. TAN Zn Zn 0O Zn O ZnO CO gt ZnCO Zn Zn Fe Zn O CO gt GT O 7 145 7 11 R lwt Pd d N 3 FD 180s FD 623K 7 5
239. 328 384 312 CO 17 923ppmV 328 10 394ppmV 600 11 906ppmV 312 8 ppmV 0 72 144 216 288 360 432 504 576 hour 6 30 CO 1 Pd d N 3 FT 623K FD 180s 6 31 CH 312 0ppmV 144 312 2 000ppmV 312 CH4 CO gt 10 762ppmV 600 5 422ppmV 312 10 111ppmV 240 6 124 8 ppmV
240. 6 CO 2 1 Pd 6 4 Pd Pd 2 1 FD 420s TiO TiO TiO
241. C H O 77 723K 6 11 TiO Robert 77 700K 7 10 TiO gt FT 723K FD 10 623K 2 W TiO gt FD
242. O H Ag e TiO Ag TiO TiO 2 TiO pH 0 3 V Cb 1 396 V O 2 43 V F 30 53 V TiO OH OH HO hT gt OH HT 3 15 O O O OH OH 0 h gt O 3 16
243. too 136 7 3 3 ti 136 7 3 4 ooncuucuncuscususuusussussssseesessossessessessosseeseeeeeeee 137 7 3 5 ummuouuuuuuuuuuuuuuuusosssssssosseesseesesseeseseessesesseseoeeee 138 7 5 6 oo 139 7 4 eo 140 7 4 1 2 140 7 4 2 GT 141 7 4 3 hm 142 7 4 4 RNN0RN dd 142 7 4 5 oo 143 7 145 8 8 1 148 8 2 enneeeeeeesesesosossssssesesosseseresseseseseseseseseseseesessesesssseseeseseseseeessesesesseseseeeeeeeeseeseseseseeee 148 2 1 eo 148 8 2 2 eo 149 3 1S1 8 3 1 oo 1S1 8 3 2 eeeeeeeeeeeseeeessessessssssss ses i 152 8 3 3 ett 153 3 4 Ao 1S4 8 4 0 1S6 1S7 8 S 1
244. 0 50 0 70 0 85 0 81 CO 12 5Svol 0 60 0 84 CO 150 000ppmV 0 80 0 80 0 90 8 169 CO 46 000 68 000ppmV 0 80 0 90 0 50 0 70 8 15 CO 0 50 0 70
245. 2PbCO 6 5gcm TiO gt 4 55 C 4 3 TiO 4 1 TiO Anatase Rutile 22050 500 00 500 A a3 785 c9 514 c 9 514 ad4593 c2959 c 2 959 1 C a 7 19x10 25 c 9 94x10 0 0200 0 0216 c cal cm sec C 0 0124 0 1136 c 4 56 cal mol C 2 12 96 13 2 200 1000 cal C 13 16 25 C mho cm 500C 1200C 10 10 0 12 TiO
246. CO 30 000ppmV 1 0 80 8 8 4 1 2 2 8 15 8 16 8 7 8 171 CO 6vol CO gt 94vol 1 8 7 151kPa 250mlmin 2 2 106kPa 100mlmin 1 2 8 9 8 9 1 CO 6vol CO gt 94vol 9 4 mm lt lt 1 Ce CN 10 cm 1 a 3 a 1 0 m R00 5 PyP 08508408L078 026 0 FF 030060070080090 CO 6 vw 8 9 8 8 CO CO 2
247. U V la mp 7 2 UV lamp TiO 4 7 3 7 3 s 9 01E 01 1 53E 03 79E 03 9 84E 00 7 3 CO CO 7 1 CO ms CO 10 s
248. cm STP cm cmHg O i j e eg 8 156 8 3 Os 7 8 3 F G 10 10 cm STP cm cm sec cmHg Si 10 8 4
249. 6 6 5S 2 5 2 1 1
250. 0 2 144 216 288 360 432 504 5376 hourl 6 32 R 1 Pd d N 3 77 623K FD 180s 6 10 2 6 33 Pd R lwt M 1 77 623K FD 180s 6 29 6 6 6 33 6 6 ppmV hour 2 ppmV ppm hour hour 6 6 6 33 24 0 24
251. 6 34 CO R 1 Pd d N 3 FT 623K FD 180s 6 35 CH4 144 216 240 312 368 6 34 6 35 216 240 368 CO CH4 CO CH4 CH4 CO 6 128 120 pp
252. CO CH4 W TiO R 1wt FD 420s 77 623K TTT 6 11 723K 6 5 6 S 1 CO 3 2 2
253. 132 7 2 2 7 2 1 6 24 72 72 7 2 2 24 72 0 24 24 48 48 72 3 0 24
254. 7 lt n 3 5 3 11 3 11 1 7 nm 3 6 TO Tio 4 3 04V 1 23V 3 30
255. M TiO 194ppmV hour R 0wt NM 11 77 623K FD 180s 48 72 0 24 210ppmV hour 23SppmV hour 194ppmV hour TiO 312 31 273ppmV 23 317ppmV 312 62ppmV hour 0 312 58ppmV hour 0 312 194ppmV hour 100ppmV hour 0 312
256. 3 740ppmV CHL4 1 811ppmV 5 639ppmV 96 192 5 000ppmV 96 120 216 192 CO 30ml CO CO gt CO 240
257. A A IUPAC a ee MF 0 1um UF 0 1um 2nm NF 2nm RO ee es 1nm 8 152 nm Ia 200 0 1 Wm HOGrm IT 7 SL 20 lt 130 12 1 Orm 5
258. M40 3000 ee 157 8 5 2 ooo 1SS 8 S 3 160 8 5 4 oo 161 8 6 1 CO 3vol CO WAN DL reeseerersesssessssssssossssesesseeres 162 8 6 1 162 6 2 oo 163 8 6 3 OS 164 8 7 1 CO 6vol CO gt 4 165 8 7 1 eo 166 8 7 2 ee 166 8 8 2 2 CO 3vol CO 97vo1 ee 167 S 8 1 2 167 8 8 2 ero 168 8 8 3 169 8 8 4 1 2 2 eee 171 973 NS A A 1 oo AD EC 0 20 gt a OE MBK We me i hth ee 3 3 ERP W EMRJP RPMP JRN NEW WE_NP PR Pk Ps 1 1 1 2 1 3 1 4 1 5 1 6 1 1
259. URL http www nucleng kyoto u ac jp people ikujiedu vac index html 6 2 3 2 p 108 6 3 D Robert A Piscopo O Heintz J V Weber Catalysis Today VOL 54 293 1999 6 4 TSEING I H CHANG W C WU JC S Appl Catal B Envion VOL 37 NO 1 43 2002 6 No 28 2002 19 22 6 6 2 43 48 2004 6 7 CVD http www2 ashitech ac jp mech ando tio2 1 pdf 6 8 VOL 70 NO 7 375 376 2006 6 9 N Iwasa and N takezawa Topics in Catalysis Vol 22 Nos 3 4 215 224 2003 6 10 Y Suwa S Ito S Kameoka K Tomoshige and K Kunimori Applied Catalysis A General 267 9 16 2004 6 11 J A Rodriguez J Phys Chem 98 1994 5758 6 12 J A Rodriguez and M Kuhn J Phys Chem 100 1994 381 7 7 1 Photocatalytic Reduction of Carbon Dioxide to Hydrocarbon Using Copper Loaded Titanium Dioxide Kenji Adachi Kiyohisa Ohta and Takayuki Mizuno Solar Energy Vol 53 No 2 pp187 190 1994 7 2 Photocatalysed Reduction of CO gt in Aqueous TiO gt Suspension Mixed with Copper Powder K Hirano K Inoue
260. 1 2 1 2 3 4 57 4 5 TiO
261. 1 1 URL http www env go jp 1 2 ECCJ 2001L 3 3 2 URL http wwwr ecc or jp databook 2001 13 2 html 1 3 URL http www fepc orjjp index fEhtml 1 4 URL http vww enecho meti go jp index htm 1 5 2006 p102 p134 1 6 RITE URL http wwwrrite orjp 1 7 1 8 2001 p 683 700 1 9 1994 p152 159 1 10 CO gt 2000 p 131 132 1 11 URL http www d7 dion ne jp shinri 1 12 1998 p 37 1 13 O Ishatani T Inoue K Suzuki and Y Ibusuki J Photochem Photobiol A Chem 72 269 271 1993 1 14
262. 180s O CO 1 0 80 0 30 2 0 50 0 70 0 85 0 81 2 CO 9 1 CO CO CO gt 2
263. 2005 2 16 6 2008 2012 1990 5 6 2005 12 9700 tCO 1990 11 4400 CO 6 13 3 7 8 14 2004 12 26 2005 8 29 IPCC Intergovernmmental Panel on Climate Change
264. FD 420s 72 CO CH4 CO CH FD CH4 Pd R 1 Pd d CH4 107ppmV 7 420s 687ppmV 7 180s Cu 1 Cu d Pt R 1 PLd Pd CH Cu 49ppmV 7 420s 271ppmV FD 180s Pt 70ppmV FD 420s 333ppmV 7 180s 6 112 R Pd d R 1 Pd d R 1 Cu d R 1 Cu d R 1 Pt d R 1 Pt d FD 420s FD 180s FD 420s FD 180s FD 420s 7 180s A 7 6 21 R lwt N 1 FT 623K 4000 3500 3000 ppmV 2500 2000
265. O O CO HO 2 2 6 O H H H HO H CO 2 3 H20 CO
266. TOC Total Organic Carbon TOC TOC 400 2010 3000 7 ISO 2 18
267. ft tI Ok YY 3x5 2nm A a 0 98x1 3 4 xU dxU 8 0 U Sxi ZxU 6 a SN Li 05Nar 0 45 HS H20 0 35 N2 CO2 0 31 0 33 8 3 D 5nm D 2nm 0 1nm 1H2 0 23 8 3 2
268. 0 09 0 88m 1 2004 16X10 J 1 4 1 46 9 23 5 12 6 12 6 4 4 270 80C 1 600m 19 2km 41 164
269. 300nm apparent quantum yield 3 26 3 38 photonic effciency x 3 27
270. 4 1 4 1 HO HO 0 046V H 1 23V O CB H OO VB 0 VB CB 4 54 4 3 TiO TiO2 7 4 1 1 33 1 TIO TiO 400
271. 6 25 6 26 TiO XRD 6 25 6 26 TiO W 0wt 77 623K FD 180s 6 25 420s 6 26 FD 180s FD 420s TIO 25 35 48 33 6 117 20 30 40 50 60 70 20 80 6 25 TiO DX R 0wt FT 623K FD 180s 20 30 40 50 60 20 6 26 TiO X R 0wt FT 623K FD 420s 70 80 TiO TiO gt TiO gt XRD 6 27 6 28 FD
272. CO 3vol CO 97vol 8 148 8 1 CO 6 CO 12 5Svol CH4 5 3vol 6 225ppmV hour CO 600 CO
273. 180s TiO 6 118 FD 420s 6 26 TIO 20 30 40 50 60 70 80 2 6 27 TO X R 1wt FT 623K FD 180s 0 94409909 20 30 40 50 60 70 80 29 1 6 28 TiO X R 1wt FT 623K FD 420s 6 119 XRD TiO FD 180s 7 420s TiO FD 180s FD 420s 4 6 9 3 6 25 T
274. 5 92 5 22 X 5 23 XRD S 8 3 Scherrer XRD TiO 5 24 Scherrer 2 12 2Dsing m 1 4 2Dsing m 1 4 5 13 5 13 sin 2 sin 5 14 5 93 zo 2 0 ai 52 1 5 16 2 n 20p sn 2 5 17 16 2 oa 4 5 12 2 18 coy 2 2 2 2 5 24 6 94 6 ee a gt De a ao a aa a nm me mh dmg en we Cy ee a ee me ae gt ea re a Ro L Le 6 1
275. FT 4 9 5 6 R 1 2 6 1 2 3 6 6 TiO gt FT 623K WV 1 3 TO R 0 1wt FD 300 4205 FT 323 623 723K TiO 6 4 2 6 9 6 10
276. le i i 4 1 NEN A bt Ce 1 1 tf 0 am i i 2 i 1 7 il et Bis RY bh pr i eres EE 0 in ut T cre i i 7 1 i a 1 HN We i 1 3 so 8 7 8 3 4 1 2 3 8 155 2 8 1 8 1 cm STP O cm STP cm cm sec cmHg 4p cmHg 6 cm 4 cm
277. 1200 800 4 65 4 1000 1500
278. O 0 3 17 OH h OH 3 18 e O 0O gt O O O 2h 20 3 19 O h gt O 3 20 0 0 gt Oj O OH TiO 3 35 3 9 3 13 1 3 36
279. 1965 p 192 195 C L Mantell 1965 p 131 Web http irws eng nilgata u aC jD chem itou resource res home html No 117 103 105 1987 H HIRAI K WADA and M KOMIYAMA CHEMISTRY LETTERS pp 361 364 1983 1999 D 351 358 http irws eng ntigata u ac jD chem itou resource res home html CO SA213 1988 http wwwr rite or jD Japanese labo kagaku kagakutop html NAGASEP p 6 10 p 8 9 HI13 2 10 p 10 Excel 2006 16 p 295 1990 3 1994 p 38 41
280. 3 48 el 3 44 kk ALDa sj 3 44 1 3 44 1 1 7 3 44 0 1 GS Rp _aD 1_ DI_ Olg 3 45 7 0 S 1 Ao QIN 3 46 lt 1 3 44 3 45 Ra a gy 3 47 7 1 2
281. 6 2 0 3 0 4 0 S 0 0 0 S 6 9 6 10 6 95 6 1 COz FHzO 1 FT
282. T Shuin H Sakai K Hashimoto and A Fujishima Induction of Cytotoxicity by Photoexcited TiO Particles Cancer Research 52 2346 1992 R Wang K Hashimoto A Fujishima T Watanabe et al Nature 388 431 1997 B O Regan M Graetzel Nature 353 737 1991 URL http wwwr jSt go jp erato announce 20051026 html 2006 7 27 http www jpo go j pP indexj htm 1 11 15 2005 p 24 URL http vww newkast or jp index html 3 3 1 3 2 3 3 3 4 3 5 3 6 3 7 3 8 3 9 3 10 1 12 p 17 36 2003 p 22 98 1988 p 7 83 URL http www okawa denshi jp techdoc 1 9 p 62 68
283. 1 io 59 4 6 2 eeeeeeeeereeseeeeeeeeseseseosseessssereerereereereeseereseesserereeeeeerereeereeeeserereeeeereeeer 59 4 7 63 4 7 1 63 4 7 2 oo 64 4 8 TiO 66 gt 9 A 5 1 73 5 2 73 s 2 1 oe 73 s 2 2 io 74 5S 3 i ie 74 4 76 5 4 1 ot 76 s 4 2 nnn 76 s 4 3 ooo 77 hy emoeerereeeeeeseseresesesesesssesseseseessseesseeseseeseesseseseeseseseesssesesesseseeeeeserereseeeeeseesereeeseseesee 78 s 4 5 78 s S ooo 80 S S 1 io 80 s S 2 io 80 S S 3 OO 82 5 6 oo 83 S 6 1
284. 1500 1000 S00 6 22 FD Z lwt M 3 FT 623K FD 180s FD 420s 72 CO CH CO CH CH4 Pd R 1 Pd d 533ppmV FD 420s 2 494ppmV FD 180s Pd CO gt Pd CO gt 6 21 6 22 FD 180s
285. 3 13 a DTiO ecp h ve b GO TiO et c 3 46 TO ht d c d 1 a TiO gt e hT 3 32 b e A
286. 3 33 c h D gt D 3 34 d 3 35 e h gt TiO a TO e h gt b Ad TiO Ti 0 Ti O 3 36 7 6 10 M s M mol dm c 3 47 Dag 20ns 3 32 3 3
287. 600 22 121ppmV 240 87 6 34 6 36 6 34 CO 72 192 216 192 192 216 1ppmV hour 312 6 127 150 n 1 E 120 1 60 _ ll ul i ll pl 120 144 192 he 240 312 TP 4S6 35328 600 30 60 hour
288. 80g HzO 559 2ml CHaOH 99 50ml Pd 1 000ppmV Pd 0 1wv 35 8ml Pd 705ml UV lamp 352nm 3 33mW cm 6 70 2 300um TiO Pd Pd Pd TO 0 058g 1 80g 0 031 3 1wt 1mass 4mass Iwt TiO 0 031 Pd Pt
289. CO CO 60 000ppmV 2 2 1 173 ke nM 4 et 3 2 2 a a ws ee A Pr ee i Pa et ot We er A PO 2 YYZ 9 174 CO 3 TiO gt 2 CO gt O 2
290. D ee RR PAR ts 27 3 9 eeeeeeeeeeeeeeee se ee ee eeeeeeeeeeee ee 28 3 10 eeeeeeeeeee 0 28 3 11 eeeeeeeeeeeeeeeeeeeeeeeeee se e ee eeee seeeeee seeeee ee neo oo 29 3 11 1 TOPT TTY TTY 29 3 11 2 30 3 12 0 31 3 12 1 ooo 31 3 12 2 io 33 3 13 imememt 35 3 13 2 ooo 36 3 14 omeeesereresesessssseserssssessssseseseseeseseeseesessesesesesreseseserereeseeeeeeesseeesereeeeeeeereroeeeeeereereererrerereeereeeereeereeee 39 3 15 ooo 41 3 16 43 3 16 1 io 43 3 16 2 ooo 44 3 17 4S 3 17 1 50 3 17 2 50 3 17 3 ee ee S1 I v 4 52 4 1 53 4 2 ooo S3 4 3 TiO S4 4 5 TiO gt 7 4 6 eeeeeseeeeeeeeeeseee ssesesee see seeeeeeeeee ee see see ee ee eeeeeeee ee ee SS 4 6
291. gt 970 000ppmV 97vol 8 10 CO CO CO Shell Tube
292. 1 168 8 8 7 2 1 CO 3vol CO 97vol 0 2 x O9 51 Fy PP 030 1 0 0 B VO ml min FF 00 GO 1 0 2 9 8 8 2 2 CO 8vol CO 94 2vol e 7 8 10633 Pi 90 33 89 33 86 33 83 33 81 33 VO P P 0 85 0 84 0 81 0 78 0 76 7 1 9f 030060070080090 8 8 3 8 15 8 16 2 8 15 2
293. 2 3 3 0 7 144 216 288 360 432 504 576 hour 6 31 CH4 1 Pd d N 3 FT 623K FD 180s 6 32 6 30 6 31 312 528 312 28 671ppmV 528 15 307ppmV 600 22 121ppmV 240 CO CO CO CH4 1000ppmV CO CH 1 1 1 2 CH4 6 125
294. 23K 623K 723K 723K 300s 420s 300s 420s 300s 420s FT FD 6 9 R 0wt N 3 3500 523K 523K 623K 623K 723K 723K 300s 420s 300s 420s 300s 420s FT FD 6 10 R lwt N 3 6 4 3 24 M 3 R 1wt 7 420s 77 623K TO TiO 373K 6 103 523K
295. 55 7 3 46 7 3 58 7 3 17 2 1 gt gt Kp D 0 3 59 dt PP D Djexp app Kd 3 60 Dj 3 51 1 pKp Sp 2
296. 8 530nm BET 3 1 3 1 TiO BET A oig nm 1068 371 5 7 48 X10 3 43 3 16 2 1 1 CO 3 13 CO CO 4 TiO
297. Gravitational raining LN LO Evaporation 7 UQ p8g 12 ntrained Dilute Sol eSeTVOIT urtace Dilute Sol 446 4 61 4 3 6 Didlish 2 3 4 3
298. LOC MODEL3660 0 60mlmin 7 137 7 3 4 6 Pd R 1wt M 3 FD 180s fT 623K 24 2 7 6 3
299. TiO 6 17 6 109 Pd Cu Pt 6 18 6 6 3 6 19 6 20 Pd 6 19 Pd R 0 1 72 CO CH Pd R 1 Pd d R 0 1 W 3 R 0 1 3 300ppmV 3 900ppmV Pd
300. W Scherer Sol Gel Science Academic Press p789 1990 4 13 2000 p 64 69 4 14 4 13 p 66 67 4 15 4 13 p 6 7 4 16 24 658 1968 4 17 4 18 1989 28 3 5 1 3 8 p 126 136 5 2 QGC GL 3 2 183 4 5 5 1987 p 1 43 6 3 1990 p 1 65 7 HP URL http www tsuhttp wwwr tsuyama ct ac jp nakamura kenkyu node9 html 5 8 X 1961 p 98 104 6 6 1
301. and T Yatsu J Photochem Photobiol A Chem 64 p255 258 1992 7 3 H13 7 4 5 2005 D 3 7 K HH 184 7 6 7 7 7 8 7 9 7 10 7 11 http irws eng niigata u ac jp chem itou ce diff html II 2004 I 68 TB II 1996 p 394 2006 CO Hs NIMS NOW 2006 Vol 6 No 12 December 2004 Seng Sing Tan Re cycling Carbon Dioxide into Fuel like Hydrocarbons by Photocatalytic Process Doctor thesis of Deakin University 2006 8 8 1 8 2 8 3 8 4 8 5 8 6 8 7 8 8 8 9 8 10 8 11 8 12 8 13 8 14 8 15 8 16
302. iO 6 27 XRD TiO CO 3 3 11 3 15 TiO TiO 1
303. mV hour 2 S ll I20 144 168 192 216 312 Be 456 528 30 hour 6 35 CH R 1 Pd d N 3 FT 623K FD 180s 6 36 CO CH 6 34 6 35 CO CH4 6 32 528 312 600 312 6 29 W 1
304. s Xo ph Xo ME pF p y 7 5 ET 8 9 8 160 8 S 3 8 9 4 x 1 bp 8 4 2 pn l xo pi yo 8 5 1 F fFi F 8 6 Fpyp Fexe Foxo 8 7 1 2 8 8 8 9
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